FORM 2
THE PATENTS ACT, 1970
(39 of 1970)
8B
The Patent Rules, 2003
COMPLETE SPECIFICATION
(See section 10 and rule 13)
TITLE OF THE INVENTION
"NOVEL BITUMEN PACKAGING AND METHOD"

We, BHARAT PETROLEUM CORPORATION LTD., a Government of India Company incorporated under the Companies Act, of 1956, of Bharat Bhawan, 4 6s 6 Currimbhoy Road, Ballard Estate, Mumbai- 400 001, India.
The following specification particularly describes the nature of the invention and the manner in which it is performed:



Field of the Invention
The present invention relates to bitumen package comprising of paving bitumen binder enclosed within a multilayered polymer film encasement. More specifically, the invention relates to methods of packaging the paving bitumen binder compositions for storage and/or, shipping from the refinery site where such bitumen binder products are produced and transported. The present invention also relates improved paving bitumen compositions Background of the invention and Prior Art
Bitumen is a very versatile construction material, which has been used for thousands of years (Reference: J. Read and D. Whiteoak, "The Shell Bitumen Hand Book", Fifth Ed., Shell Bitumen, 2003, p2). World market for bitumen in 2003-04 was 130 millions t/year. The demand in India and USA for bitumen binder products in 2003-04 was 3.2 and 38.0 million t/year respectively. Though bitumen binder find a variety of applications, about 80 to 90% are used in pavements and remaining in roofing, waterproofing and for other applications.
For most part bitumen binder has been produced in oil refineries from a variety of specific crudes. The largest portion of paving bitumen compositions are the residual fractions (as vacuum residues with the cut point usually between 425°C and 580°C) derived from such crudes as Mexican, Venzenuelan, Arabian Heavy, Kuwait, and Iraq. The bitumen compositions are produced at refinery in molten condition and pumped through steam traced lines at temperatures sufficiently high so that the pumps can handle the molten materials. Such materials are usually shipped to the user site by tankers and in metal drums. When bitumen is shipped in tankers, the tankers are equipped with internal heating coils and the tanks can also be insulated so that it is easy to discharge the bitumen in liquid form from its shipping containers. As most uses of bitumen require elevated temperatures for applications, bitumen binder when transported by tankers needs to be maintained at elevated temperatures till its final application. When bitumen is shipped in metal drums, the drums need to be heated to elevated temperatures to bring it to molten state for actual applications.
There are disadvantages in both modes of shipping explained above. When shipped in tankers, expensive tankers dedicated for bitumen product shipping are required and significant amount of energy in the form of heat must be spent in order to maintain the bitumen in a fluid state. Also, the properties of bitumen can be adversely affected by prolonged storage at elevated temperatures, Transportation by drums has the following disadvantages. The daims need to be heated to elevated temperatures to convert the bitumen to molten state before loading into hot mixer for converting into hot mix concrete. Inherent

ORIGIN
stickiness of bitumen binder makes it difficult to recover all the bitumen binder in the drum and about 2% of the bitumen is lost. It is also difficult to avoid spillage while trying to use the hot molten bitumen from the drum. Drums are generally used only once and disposal of empty drums is not eco-friendly and expensive metal (usually steel) is lost. On storage the drums get rusted and bitumen can leak resulting in cleaning problem. Bitumen may also get deteriorated as it gets exposed to atmosphere. Handling of drums, generally each weighing about 160-200 Kg, is also difficult.
Pavements can be made with bitumen concretes, which are dust-free^ smooth and which offer the strength required for modern automobile and heavy truck traffic. Bitumen concrete is generally made by pumping the hot (fluid) bitumen binder into a mixing device where it is brought into contact with hot aggregate (sand and gravel or crushed stone) particles in a turbulent mixing environment. The fluid bitumen, which remains fluid due to the aggregate temperature, coats the aggregate particles. This material known as hot mix bitumen concrete is used as paving material. It is then spread uniformly by a layering machine or paver over the intended surface being paved, and compacted to form a dense layer. When the bitumen concrete cools, bitumen returns to a viscous semi-solid material which functions as a binder for the aggregates. The resultant pavement can then support loads.
Bitumen concrete pavements can be made to be very smooth which offers outstanding frictional resistance for vehicles operating thereon. Such bitumen concrete pavement can also be repaired easily by adding additional hot bitumen concrete to holes and other types of defects, which develop in the surface.
Though bitumen concrete offers many benefits as a paving material, there are certain problems associated with it. One major problem encountered with bitumen concrete pavements is the loss of the adhesive bond between the aggregate surface and the bitumen. This breaking of the adhesive bond between the bitumen and the aggregate surface is known as "stripping". The stripping of asphalt binder from aggregate surfaces results in shorter pavement life and lot of expenditure on maintenance of bitumen pavements each year. Reduction of stripping tendency is of great interest when trying to improve conditions of road and lowering the maintenance costs. The manner in which viscosity of bitumen changes with temperature can significantly affect the behavior of the pavement made with that bitumen. At high service temperatures, such as those experienced on hot summer days, due to low viscosity, bitumen concrete can experience rutting and shoving. Under such conditions, bitumen cannot bind the aggregates together well enough to support loads without permanent

ORIGINAL
deformation. This permanent deformation forms a rut in the pavement at the loading point (wheel path). On the other hand, at low service temperatures, such as those experienced during cold winter nights, bitumen concrete can experience low temperature cracking.
Over the years, different methods have been developed to reduce stripping tendencies. For example, amines and lime are known to act as anti-stripping agents and are frequently applied to the surface of the aggregate prior to mixing it with the bitumen in making hot mix bitumen concrete. U.S. Patent No. 5,219,901 discloses a method for reducing stripping tendencies which involves coating the aggregates with a thin continuous film of a water-insoluble high molecular weight organic polymer, such as an acrylic polymer or a styrene-acrylic polymer.
Many polymers have been added to bitumen binder in an attempt to change the viscosity-temperature relationship of asphalt to preclude having too high or too low bitumen viscosity in the operating temperature range for a particular bitumen use. The polymers used to modify the asphalt viscosity-temperature relationship can generally be classified as thermoplastics, elastomers (rubbers) or polymers designed to have some properties of both.
To be effective, polymers and/or chemicals must be dispersed uniformly throughout the asphalt. Many of these polymers and chemicals will degrade, decompose or experience a reduction in effectiveness with prolonged storage in hot bitumen. The degradation process depends on time and temperature. The higher the temperature of the bitumen polymer/chemical blend, the faster is the degradation. Reducing the temperature to ambient, will eliminate or greatly retard degradation. Further, some polymers and chemicals will separate from the bitumen binder without constant agitation of the fluid blend. As the temperature is decreased to ambient, the resulting increase in the viscosity of the blend leads to reduction in separation (Ref. U.S. Patent No. 5,331,028). Objects of the Invention
It is therefore, one of the objects of the present invention to provide a package for packing bitumen binders for easy handling, storing and transporting of bitumen binder wherein no removal of packaging is required before its use at job site.
It is a further object of this invention to provide a package having a polymer film, which is fully compatible with bitumen and melts to form homogeneous mass under the conditions of ultimate use.
It is yet another object of this invention to provide packaging for bitumen, which is fully incorporated into the bitumen under the conditions of ultimate use and forms a homogeneous mass so as to modify bitumen to improve the properties of paving bitumen.

It is still a further object of this invention to provide a secondary package to improve ease of handling and provide additional strength.
It is yet another object of this invention to provide a secondary package having film which melts and gets incorporated into molten paving bitumen to improve its properties.
It is still further object of this invention to provide complete system and method for packaging hot molten bitumen and other bitumen like materials, cooling and sealing which can be easily handled, shipped and stored without degrading the quality of bitumen.
These and other objects of the invention will become apparent upon a fuller understanding of the invention described below. SUMMARY OF THE INVENTION
It has now been found that molten bitumen can be packed at high temperature using
polymer bag formed from, a multilayered film, each layer consisting of polypropylene or
polyethylene or other suitable polymers. The bitumen packs thus formed are easy to handle
and the polymer packaging material used for packaging bitumen fully melts and gets
incorporated into bitumen. j
Accordingly, the present invention provides a bitumen package comprising of paving bitumen binder having a softening point in the range of 30-65°C enclosed within a multilayered polymer film encasement, each layer being a thin flexible continuous self-sustaining polymer film, such that upon melting, the polymer becomes homogeneous with the paving bitumen binder contained therein.
In a preferred feature, the weight of the paving bitumen binder package is in the range of 0.1 to 100kg, preferably, in the range of 1 to 50kg.
In another preferred feature, the multilayer polymer encasement melts in the temperature range of 140 to 280°C, preferably, in the temperature range of 150 to 200°C.
In another preferred feature, the multilayered encasement is a three layered polymer bag, all the layers being polyethylene or polypropylene or n In another preferred feature, the multilayered encasement is a three layered polymer bag, the inner layer being polypropylene and the outer two layers being polyethylene.
In another preferred feature, the multilayered encasement is a three layered polymer bag, the inner layer and one outer layer which is in contact with bitumen binder being polypropylene and the other outer layer which is not in contact with bitumen being polyethylene.

ORIGINAL
In another preferred feature, the multilayered encasement is a three layered polymer bag, the inner layer and one outer layer which is not in contact with bitumen binder being polypropylene and the other out layer which is in contact with bitumen being polyethylene.
In another preferred feature, the multilayer polymer encasement forms 0.5 to 10 wt% of the total package the remaining being paving bitumen binder.
In another preferred feature, the polymer encasement when forming more than 2 wt% of the total jjackage, upon melting the polymer becomes homogeneous, gets incorporated with paving bitumen binder and improves the properties of the binder significantly.
In another preferred feature, the present invention discloses a method of packing bitumen wherein bitumen binder having softening point in the range of 30-65°C, is filled in a multilayered polymer encasement, -each layer being a thin flexible continuous self-sustaining polymer film, upon melting the polymer becomes homogeneous with the paving bitumen binder contained therein.
Preferably, the multilayered polymer encasement is a preformed bag sealed from all sides except from top into which hot molten bitumen is filled and heat sealed at the top.
Preferably, the polymer encasement is supported by a perforated metal mould during filling and cooling.
In another preferred feature, the multilayered polymer encasement is a bag sealed from all sides and formed in-situ from a multilayered polymer film in a filling machine into which hot molten bitumen is filled and hot sealed.
In another preferred feature, during filling, the molten bitumen is maintained at temperatures below 140°C, preferably below 120°C.
In another preferred feature, the multilayered polymer encasement along with the bitumen is cooled during filling by immersing in cold fluid.
In another preferred feature, the multilayered polymer encasement along with the bitumen inside is cooled during filling by spraying cold fluid.
In another preferred feature, the cold fluid is maintained at a temperature below 30°C and preferably, at below 10°C.
In another preferred feature, the weight of the bitumen binder package is in the range of 0.1 to 100kg, preferably in the range of 1 to 50kg.
In another preferred feature, the multilayer polymer encasement melts in the temperature range of 140 to 280 °C, preferably in the temperature range of 150 to 200 °C.
The present invention also provides a mould for packing bitumen in a rnulti layer polymer encasement which comprises a bottom wall, a pair of horizontal walls mounted on

said horizontal plate, so that at least one of the horizontal walls open outwardly, away from the other in an open position and stand vertically, parallel to each other in a closed position, thereby providing a space therebetween for positioning a bag to be filled and packed with bitumen, locking means located on the top of at least one wall so that the walls are maintained in a locked position while the bag is being filed with bitumen.
Preferably, the horizontal walls are perforated.
In a preferred embodiment, both the vertical walls are hingedly mounted on said bottom wall.
In another preferred embodiment, one vertical wall is hingedly mounted on said bottom plate while the other wall is fixedly mounted on said bottom wall.
In another preferred embodiment, the locking means comprise a hook and eye mechanism. Brief description of the accompanying drawings
The present invention will now be described with reference to the accompanying drawings in which:
Fig. la: shows an assembled mould used for filling and packing bitumen in accordance with the present invention;
Fig. lb. shows the mould being assembled
Fig. lc: shows the mould being assembled with Hook & Eye mechanism in an open condition;
Fig. 2 :shows bags used for filling bitumen;
DETAILED DESCRIPTION OF THE INVENTION
The packaging of the present invention consists of (a) polymer film or sheet either in the form of preformed bag sealed on three sides or a tube sealed at the bottom (pouch), (b) filling of hot paving grade bitumen binder having softening point of about 30-65°C and PEN (penetration at 25°C) of about 20-250 into the polymer bag/pouch, (c) sealing and cooling the bag with its contents which can then be stacked, shipped and used at the user site without removing the packing. The package of the invention can be manufactured by any suitable method.
The polymer bag/pouch or tube is made of polymer film which is made from any polymeric material having sufficient heat resistance i.e. does not melt at least up to 90°C, preferably up to 120°C, has enough mechanical strength (Dart Impact Strength > 900 gm as measured by test method IS:2508) and melts in the temperature range of 140°C to 2S0°C, preferably in the temperature range of 150-200°C. The preferred multilayer film is made,

ORIGINAL
preferably two or three layers. The film thickness can range from 50 to 500 u.m, preferred range between 90 to 450 um. The preferred polymeric materials are polypropylene, polyethylene and copolymers of ethylene, propylene, nylons, etc. The polymeric materials, which can be made into film form and having the desired properties as described earlier can also be used. Different layers can be made from different polymeric materials. For example in a three layered film the outer layers can be made from polyethylene and the inner core can be made from polypropylene.
The preferred film for packaging bitumen binders should have the following properties:
• Temperature susceptibility
• impact performance
• Flexibility and softness
• Compatibility with bitumen binder
• Rigidity and Creep resistance
• Sealing through contaminant capability
• Tear resistance
• Melts at the temperature at which bitumen is converted to molten state at end user application
Monolayer polymer films lack some of the above-mentioned properties. It is now invented that a multilayered film, preferably three layered film with suitable polymeric material for each layer provides desired properties for the film. For example, when a three layered film is made from polypropylene, polyethylene, nylon etc. Polypropylene and nylon provides rigidity, temperature performance, mechanical strength, puncture and impact resistance, while polyethylene gives excellent sealing capability and softness.
Some of the compositions of three layered film using polyethylene and polypropylene which give desired properties are polyethylene in the outer layers and propylene in the inner core. The weight ratios could be 1 : m : n where in 1, m, n vary from 0 to 100%. Manual method of bitumen packaging
Bulk bitumen was first melted and maintained at a temperature range of about below 140°C, preferably below 120°C in a suitable container.
Metallic mould in rectangular box shape having three walls made of perforated sheets for fast heat transfer was designed and fabricated. The three rigid rectangular walls (1,2,8) which form a mould are placed in such a way that one is at the bottom (8) and two are

ORIGINAL
vertical (1, 2) and parallel to each other. In the preferred embodiment shown, one of the vertical walls (1) is welded to the horizontal bottom wall (8) and the other vertical wall (2) is fixed to the bottom wall (8) with hinges (5,6,7) for flexibility. The hinges (5,6,7) allow the flexible wall (2) to freely rotate along the axis of the hinges (Figure - 1 a, lb and 1c). The two vertical walls (1,2) can be held together in parallel with the help of hook and eye mechanism (3,4). The surfaces and corners, which get in contact with film encasement are made smooth (devoid of pointed and sharp edges).
Prefabricated empty polymer bags as shown in Figure. 2a, 2b and 2c can be placed in the mould and firmly held in the mould the help of suitable fixture such as clamp. The mould is then placed in a coolant tank, which is maintained at a temperature below 30°C, preferably below 10°C.
Required quantity of molten bitumen heated earlier is then poured into the bag from the top opening with the help of a funnel. The filled bag along with mould is left in the water tank for more than 2 minutes so as to cool it below 70 °C, preferably below 50 °C. The sealed bag is then placed on pallet which can be further moved for the stacking and storage. Automatic Method of bitumen packaging
In an automatic machine, polymer film in the form of either sheet or cylinder is continuously fed to the machine where the film is sealed in such a way that a bag is formed having opening at the top. Desired quantity of hot bitumen binder in molten state maintained at a temperature in the range of 40 to 140°C, preferably, in the range of 70 to 120°C is filled into the polymer bag. The desired quantity of bitumen filling can be achieved either by measurement and control of volume or mass. The filled bag is then sealed at the top and separated from the rest of the film by cutting above the seal. When hot bitumen binder is filled in the polymer bag, the bag may get damaged/punctured/deformed due to high temperature. To avoid such damage to the film the bag is cooled from outside either by immersing the bag in a cold fluid such as water or by spraying cold fluid such as water or vapor or gas. The temperature of the fluid used for cooling is maintained below 30°C, preferably below 10°C. The sealed bag containing bitumen then carried in a conveyer that is submerged in a cold fluid maintained at temperature below 30°C, preferably below 10°C. The bag remains in the conveyer for a period of more than 2 minutes so as to cool the hot bitumen binder contained in the polymer bag to below 70°C, preferably to below 50°C.
Alternatively, during filling and sealing damage to the film/bag can also be prevent by supporting the bag using a specially designed mould/case and cooling it. The mould was designed so as to provide enough exposure to bag for fast heat transfer. The mould is so

designed that it automatically opens from front after filling, sealing and cutting is complete. Right mould dimensions are selected so as to fit the bag/pouch/tube well. The mould is fixed bellow bitumen filling point. After filling the bag with bitumen and sealing front side of the mould is automatically opened so as to allow the bag to fall out of the mould. Further, during bitumen filling and sealing the bag can be cooled as explained above either by immersing in cold fluid or by spraying cold fluid, on the mould/bag.
The bitumen binder bag can now be handled for secondary package, stacking or for shipping. Semi-automatic method of bitumen packaging
A semi automatic filling machine with the features described is designed and fabricated for filling bitumen binder in polymer bags. The machine consists of bitumen storage tank having capacity 50 Kg (can also have other capacities either lower or higher), a temperature control and measurement facility, pneumatically controlled bitumen inlet valve, a non contact bitumen level sensor, bag holding fixtures and an injection nozzle having adjustable timer control. Sensing the level of the bitumen in the tank the inlet valve allows/stops the flow of bitumen in to the tank. A over flow line is also provided to remove excess bitumen from the tank in the eventuality of non-operation of the inlet valve such as non-closure when the tank is filled to the desired level. Sufficient heat insulation was provided to bitumen contact parts to reduce heat loss and smooth opening and closing of valves. The open/shut of the injection nozzle was based on timer controlled, which can be adjusted according to the quantity of the bitumen to be filled. The injection nozzle was designed to avoid spraying of bitumen and total cut of mechanism to stop the dripping of bitumen. An additional mechanism for operating the injection valve through remote foot pedal switch was provided to increase the personal safety during operations.
The bitumen storage tank is connected to the bitumen inlet line, and bitumen at 40-140°C, preferably at 70-140°C is filled in the filling machine tank of 50-250kg capacity, as the level in the tank reached desired height, the inlet valve get closed with the help of level sensor. The filling machine tank temperature is maintained the desired level. Below the injection valve a water tank of filled with water maintained below 30°C is placed. The polymer bags were fixed in the moulds as explained in manual method. The timer for injection valve is set at desired quantity. The mould was placed in cold water below the injection valve and foot pedal was operated. Preset quantity of hot molten bitumen is filled in bag and the valve got closed. The filled bag along with mould was shifted ahead inside the same water tank and kept for more than 2 minutes for cooling the bitumen to the desired


temperature. In similar way filling of other bags were continued. The other operations such as removing the mould/bag, sealing etc., were carried out sequentially as explained for manual filling operations.
The weight of each packed bitumen bag/pouch can be in the range of 0.1kg to 100kg; preferably in the range of 1kg to 50kg in weight. When the pack size is small (less than 25kg), two or more bags can be packed/wrapped together (called secondary package) to produce a final pack of 50kg or more for easy handling, stacking, loading, shipping and usage. Secondary packaging
The secondary packaging is done for ease of handling and transportation. Secondary packaging provides additional strength. In the present invention, two types of secondary packaging material are used viz., (1) removable packaging in which single layer of high density polyethylene film having thickness in the range of 150-500 u.m preferably in the range of 200-300 urn or any other suitable material is used. This material does not dissolve completely in molten bitumen at the end use application and hence, this secondary package has to be removed prior to the use of bitumen for pavement or any other application. Any other suitable material can also be used for secondary packaging. (2) non removable packaging in which a suitable single, double or multilayer layered polymer film comprising of thickness of about 150-500 jim preferably 200-300 urn is used. In this case film material gets completely dissolved in hot molten bitumen during its end use and hence, there is no need for the removal of secondary packaging.
In one of the inventions, a secondary packing is done using prefabricated polymer bag in a box shape of desired size by stitching, keeping a flip type opening at top. Desired number of individual primary bitumen bags is placed in the secondary bag and stitched the open end using portable stitching machine. The secondary packaging can also be done is an automatic machine. The secondary packing material is removed at the time of end use at the user site as the material does not melt or mix with bitumen at the temperature at which bitumen concrete is prepared.
However, if the secondary bag made with polymeric material such as low density polyethylene or any other polymeric material which dissolves and mixes with bitumen binder at the temperature at which bitumen concrete is prepared, the bitumen binder packed in secondary package can be directly used without removing material to the hot mixer to produce bitumen concrete at user site.

ORIGINAL
The temperature at which bitumen is converted to molten state if the polymer used for package fully melts and gets incorporated, and the polymer used in the packaging is sufficiently high i.e. more than 2wt% by weight, the bitumen obtained on melting along with the packaging material at the user site is polymer modified bitumen (PMB). The polymer modified bitumen thus obtained possesses superior properties. The PMB thus obtained by the method of present invention is from drawbacks such as degradation/decomposition of polymers as the material is not subjected to prolonged heating.
The packaging of the present invention is suitable both for unmodified and modified bitumen binders. The various grades of bitumen binders having softening point in the range of 30T'65°C can be packed using'the present invention. Present invention is not restricted to any particular bitumen grade but suitable for packaging any material in molten or liquid state.
The invention will now be further illustrated by the following Examples. Each one of the experiment described in the examples was carried out under conditions of strict confidentiality. Particularly, the trials mentioned in above examples, including manufacturing, transport worthiness, melting, hot mix preparation, road laying and other related experiments were conducted in a closed area and by maintaining confidentiality and secrecy.
Bitumen products are characterized for various properties like penetration, softening point, elastic recovery etc: following the standard tests by Bureau of Indian Standard (BIS) designated IS 1203:1978, IS 1205:1978 and IS 15462:2004 respectively. The Drop test data given in examples for the packed bitumen bag is measured by the BIS method IS-12724. Dissolution of packed bitumen bag data given in the examples is measured as described below:
Base bitumen sufficient to immerse the packed bitumen bag is melted in a suitable container by heating and maintaining at a temperature in the range of 140 to 280°C. The bag is then immersed in the above molten bitumen and the dissolution/melting of the polymeric bag in the base bitumen is observed with occasional mixing and by recording the time required for dissolution / melting of the entire polymeric material to form a homogeneous mixture.
All of the given Examples are merely for the purpose of illustration and are not to be regarded as limiting the scope of the invention or the manner in which it can be practised. Example -1
Mould of dimensions 22" x 18" x 4" in a box shape made up of light weight perforated aluminum sheet walls was fabricated. The design of the mould was made in such a

way that it has smooth surfaces and corners. The empty bag can be easily fixed in the mould, filled with hot bitumen and cooled bags are removed easily. The empty bag can be fixed in the mould with the help of clamps at top and bottom. Example - 2
A preformed polymer bag of dimensions 23" x 18" formed from a three layered film of thickness 150 u.m, melting at 160°C and having polyethylene in the outer layers and polypropylene in the inner core in the weight ratio 1:1:1 is fixed in the mould fabricated as per described in Example 1. The mould along with the bag is immersed in a water tank maintained at 5°C temperature in such a way that about 19 inches of the bag is immersed in water. About 10kg of accurately weighed hot molten bitumen having penetration and softening point of 66 and 50°C respectively, maintained at a temperature of 110°C is poured in the bag with the help of a funnel. Bitumen is filled in the bag up .to a mark of about 19". The cooling of the bitumen inside the bag was continued in the water tank for additional 12 minutes during which the bitumen temperature is reduced to 50°C. The mould along with bag is then removed from the tank. The bitumen containing bag is removed from the mould and sealed using hot seal. The bag thus prepared is dropped from a height of 4" and examined for any damage. The bag remained intact and no rupture/damage was observed. The bag is then immersed in molten bitumen in a drum maintained at 190 ± 10°C. The polymer bag with bitumen fully melted in 20min time. The bitumen product thus obtained showed penetration and softening point 64 and 51°C respectively. Example - 3
A multi layered polymer film of polyethylene in outer layers and polypropylene in inner core having a melting point of 160°C, and film thickness of 100 j.un is taken and a bag of dimensions 9" x 12" is formed by sealing three sides of the film. The bag thus formed is fixed in a mould of suitable size fabricated as described in Example 1. The mould with empty bag is immersed in cold water maintained at temperature of 7°C and a pre-weighed (500 gms) hot molten bitumen having softening point of 50°C, at a temperature of about 115°C is poured into the above bag. The filled bag is left inside the cold water for about 5 minutes and then removed, sealed and stacked. Example - 4
A polymer bag of 28" x 22" dimensions is formed from a three layered polymer film of polypropylene in outer layers and polyethylene in inner core in the weight ratio 1:2:1 and having a melting point of 175°C The bag thus formed is fixed in the mould of suitable size fabricated as described in Example 1 and immersed in cold water maintained at temperature

ORIGINAL
of 5°C. Pre-weighed hot molten bitumen of 30kg at a temperature of 110°C having softening point of 48°C and penetration of 68 is poured into the above bag. The filled bag is left inside the cold water for about 15 minutes and then removed and sealed. The bag thus formed could be folly melted. Polymeric material used for packaging the bitumen is folly dissolved in molten bitumen at 200°C. Example - 5
A multi layered polymer film of polyethylene and polypropylene having characteristics as mentioned in Example 2 and having film thickness of 250 am is used to form a bag. The bag is then fixed in the a mould of suitable size fabricated as described in Example 1 and immersed in cold water maintained at temperature of 3°C. Pre-weighed (lOKg) quantity of hot molten bitumen having penetration of 65, at a temperature of about 110°C is poured into the above bag. The filled bag is left inside the cold water for about 10 minutes and then removed, sealed and stacked. The bag thus formed was dropped from a height of 6 feet. No damage to the bag was observed. The bag with bitumen could be fully melted at 190°C and brought to molten state. Example - 6
A pillow shaped bag is formed by cutting and sealing a three layered polymer film having melting point of 145°C in dimensions of 18" x 23". The bag thus formed is fixed in a mould and immersed in a water tank maintained at a temperature of about 5°C. Pre-weighed (10KG) of hot molten bitumen was poured into the bag from the top opening with the help of a funnel. The bag filled with bitumen is continued in cold water till the temperature of bitumen in the bag dropped to less than 50°C. The mould is then removed from the water bath and the bag is sealed from top. Example - 7 ■
A three layered polymer film of polyethylene in outer layers and polypropylene in inner core in the weight ratio 1:1:1 having a melting point of 210°C, and having film thickness of about 90 um is taken and a bag is formed as per the procedure mentioned in Example 2. Filling of hot molten bitumen of a quantity of 10KG having softening point of 50°C and penetration of 60/70 is performed as per the procedure mentioned in Example 2. The filled bag is left inside the cold water for about 15 minutes cooling and then removed and sealed. Example - 8
A two-layered polymer film of thickness 150 u.m made from polyethylene and polypropylene in weight ratio of 1:1 and melting point of 130°C is used to make a bag. About


lkg of accurately weighed bitumen having penetration and softening point of 100 and 45°C respectively and maintained at a temperature of 85°C is poured in the bag with the help of a funnel. The bag along with bitumen was cooled for another 5 minutes to reduce the bitumen temperature to 50°C. The mould along with bag was then removed from the tank and sealed. The bag thus formed could be fully melted. Polymeric material used for packaging the bitumen is fully dissolved in molten bitumen at 200°C. Example - 9
A bag is formed using single layered polymer film made from polyethylene having film thickness of 90 (am. Hot bitumen at 120°C could not be filled in the bag thus formed as the bag got punctured during filling. Example -10
A polymer bag is prepared from a nylon film 100 u.m of thick. Hot molten bitumen of quantity 10 KG is filled and sealed as described in Example 2. The bag when heated at 180°C did not fully melt. However, on further heating it was found that the bag along with bitumen could be fully melted at 265°C. Example-11
A preformed polymer bag of dimensions 23" x 18" formed from a three layered film of thickness 150 u,m, melting at 160°C and having polyethylene in the outer layers and polypropylene in the inner core is fixed in the mould fabricated as described in Example 1. The mould along with the empty bag is immersed in a water tank maintained at a temperature of about 5°C. 10kg of Polymer Modified Bitumen (PMB), having softening point of 60°C and elastic recovery of 70 percent, maintained at 120°C is poured in the bag with the help of a funnel. The cooling of the bitumen inside the bag was continued in the water tank for 10 minutes to reduce the bag temperature to 50°C. The mould along with bag is then removed from the tank and sealed. The bag thus prepared is dropped from a height of 4" and examined for any damage. The bag remained intact and no rupture/damage was observed. The bag is then immersed in molten PMB in a drum maintained at 190 ± 10°C. The polymer bag with bitumen fully melted in 20min time. The product thus obtained did not show any change in the softening point and elastic recovery. Example- 12
A bag is formed from a multi layered polymer film of polyethylene and polypropylene having characteristics and dimensions as mentioned in Example 2. This bag is then fixed in the mould fabricated as described in Example 1. The mould along with the bag is immersed in a water tank maintained at 5°C temperature in such a way that about 19 inches

ORIGINAL
of the bag is immersed in water. About 10kg of accurately weighed hot molten PMB having softening point of 55°C and elastic recovery of 40 percent is filled, cooled and sealed. Polymeric material used for packaging the bitumen is fully dissolved in molten bitumen at 200°C. The product thus obtained did not show any change in the softening point and elastic recovery. Example - 13
For easily handling of bitumen packed polymer bags, a secondary packaging is provided as described below:
A two layer polymer film made from low density polyethylene and high density polyethylene melting above 250°C and having thickness of 400 urn is used to fabricated bags in box shape having dimensions 22" x 18" x 12" closed on all sides keeping flip type opening at top. For easy handling of the bags handles are also provided on either side along the length of the bag. The bag thus formed is hereinafter called a secondary bag. Five numbers of individual bitumen packed bags of 10 KG capacity prepared as described in Example 2 are placed in the secondary bag and the open end is closed by using a stitching. 500 numbers of such secondary bags are packed and subjected to the loading and unloading operations. The polymeric material, design and dimensions of secondary bags are convenient to handle and also sturdy enough to take the load of 50KG. Further these secondary bags are stacked up to a height of 8" one above other for 24 hrs to observe any damage of outer secondary bag and inside individual bags. No damage on the sealing area, bursting of bags is observed during handling, stacking and storage.
As the polymeric material used for making secondary bags does not dissolve completely at the end use application temperature, it is to be removed prior to the use of bitumen. Example- 14
A multilayer layered polymer film described in Example 2 having film thickness of 250 urn is used for making secondary bags as described below.
A prefabricated bag is formed in a box shape of dimensions 20" x 15" x 4" closed on all sides, keeping a flip type opening at the top. Three numbers of individual bitumen bags of 10 KG capacity each prepared as described in Example 2 are placed in the secondary bag and sealed. 100 numbers of secondary bags thus prepared are heated in a container maintained at a temperature of 180±10°C. Bag along with bitumen melted and the polymer bag material completely dissolved. The molten bitumen thus obtained contained 5 wt% of polymeric material. The resultant bitumen product showed significant improvement in softening point,

ORIGINAL
penetration and elastic recovery. The penetration reduced from 64 to 35, softening point increased from 50°C to 78°C and elastic recovery increased to 38%. Example 15
Four numbers of individual bitumen bags of 10 KG capacity each prepared as described in Example 2 are wrapped together with the help of a three layered polymer film of thickness 50 um. The effect of polymeric content on bitumen quality is studied by adjusting the weight content of the entire polymeric packaging material to 3 % of the packed bitumen quantity. The bag thus formed could be fully melted. Polymeric material used for both primary and secondary packaging is fully dissolved in molten bitumen at 200°C. The resultant bitumen showed an improvement in penetration and softening point to 64.2 and 51.5°C as against 65 and 50°C respectively. Example - 16
Packaging of 11MT bitumen in primary polymeric bags of capacity 10KG each (total 1100 nos.) is done as described in Example 2 however the filling activity is carried out using a semi-automatic filling machine and the system as described in the present invention. The primary bags thus formed are packed in secondary bags of capacity 50KG each (total 220 nos.) as described in Example 13:. Bitumen Bag Endurance in Transit:-
Transport worthiness study of bitumen bags is completed by transporting the entire 11MT poly packed bitumen by road over more than 600 KMS, it is observed that there is no damage, spillage of bitumen from the bags. The packaging material (individual and secondary as well) is strong enough to undertake the road transportation conditions such as weather, handling, loading and unloading, etc. Further it is observed that the stacking of the bitumen secondary bags required less space as compared to conventionally packed bitumen. An increased quantity of bitumen bags can be transported at one time compared to drum packed bitumen. Bitumen bag is also fully resistant to extreme humid environmental condition vis-a-vis commonly faced problem of rusting of metallic drum packed bitumen.
Miscibilitv of Bitumen Bag While Heating / Melting at End AppHcation:-
Melting / dissolution of 11 MT packed bitumen bags is conducted in a commercial scale Hot Mix Plant (bitumen tank having about 50% of molten bulk bitumen, maintained at a temperature range of about 180-200°C). It is observed that the polymer film material got dissolved / mixed with the bitumen completely and easily in the existing set-up without any modifications and damage. The molten bitumen behaved exactly in similar way as of bulk

ORIGINAL
bitumen and no operational difficulties could be encountered as against the use of bulk bitumen in Hot Mix Plant.
Road Laving Using Poly Bag Packed bitumen:-
The hot molten bitumen obtained from the example described above is then spray mixed with aggregate to form bitumen concrete as per the required ratio. This bitumen concrete is then tested for Marshall Stability (as per ASTM D1559), A higher Marshall strength of 15Nm2 is observed for polymer bag packed bitumen as compared to bulk bitumen of 12 Nm2 and during this no operational differences encountered as compared with the road lying using bitumen concrete prepared from bulk / drum packed bitumen.


We claim:
1. A bitumen package comprising paving bitumen binder having a softening point in the
range of 30-65 C enclosed within a multilayered polymer film encasement consisting
of at least three layers, the multilayer polymer encasement forming from 0.5 to 10
wt% of the total package, the remaining being paving bitumen binder, said multilayer
polymer encasement melting at a temperature in the range of 160°C to 280°C, each
layer being a thin flexible continuous self-sustaining polymer film, such that upon
melting, the polymer becomes homogeneous with the paving bitumen binder
contained therein, get incorporated with the binder and improves its properties
significantly.
2. A package as claimed in Claim 1 wherein the weight of the paving bitumen binder
package is in the range of 0.1 to 100kg, preferably in the range of 1 to 50kg.
3. A package as claimed in Claim 1 or 2, wherein the multilayer polymer encasement
melts in the temperature range of 170 °C to 200 °C.
4. A package as claimed in any one of Claims 1 to 3 wherein the multilayered
encasement is a three layered polymer bag, all the layers being polyethylene or
polypropylene or nylon.
5. A package as claimed in any one of Claims 1 to 3 wherein the multilayered
encasement is a three layered polymer bag, the inner layer being polypropylene and
the outer two layers being polyethylene.
6. A package as claimed in any one of Claims 1 to 3 wherein the multilayered
encasement is a three layered polymer bag, the inner layer and one outer layer which
is in contact with bitumen binder being polypropylene and the other outer layer which
is not in contact with bitumen being polyethylene.
7. A package as claimed in any one of Claims 1 to 3 wherein the multilayered
encasement is a three layered polymer bag, the inner layer and one outer layer which

ORIGINAl
is not in contact with bitumen binder being polypropylene and the other out layer which is in contact with bitumen being polyethylene.
8. A method for packaging paving bitumen which comprises filling bitumen binder having softening point in the rage of 30-65°C, in a multilayered polymer encasement consisting of at least three layers, which encasement melts at a temperature in the range of 160 °C to 210°C, each layer being a thin flexible continuous self-sustaining polymer film, upon melting the polymer becomes homogeneous with the paving bitumen binder contained therein.
9. A method as claimed in Claim 8 wherein the multilayered polymer encasement is a preformed bag sealed from all sides except from top into which hot molten bitumen is filled and heat sealed at the top.
10. A method claimed in Claim 9 wherein the polymer encasement is supported by a perforated metal mould during filling and cooling.
11. A method as claimed in Claim 8 wherein the multilayered polymer encasement is a bag sealed from all sides and formed in-situ from a multilayered polymer film in a filling machine into which hot molten bitumen is filled and hot sealed.
12. A method as claimed in Claim 9 or 11 wherein during filling, the molten bitumen is maintained at temperatures below 10O°C, preferably below 90 °C.
13. A method as claimed in Claim 12 wherein the multilayered polymer encasement along with the bitumen is cooled during filling by immersing in cold fluid or by spraying cold fluid.
14. A method as claimed in Claim 13 wherein the cold fluid is maintained at a temperature below 30°C and preferably, at below 10°C.
15. A method as claimed in claims 8 to 14 wherein the weight of the bitumen binder package is in the rage of 0.1 to 100kg, preferably in the range of 1 to 50kg.


16. A method as claimed in Claim 8 wherein the multilayer polymer encasement melts in
the temperature range of 170 °C to 200 °C.
17. A method as claimed in Claim 8 wherein the multilayered encasement is a three
layered polymer bag, all the layers being polyethylene or polypropylene or nylon.
18. A method as claimed in Claim 8 wherein the multilayered encasement is a three
layered polymer bag, the inner layer being polypropylene and the outer two layers
being polyethylene.
19. A method as claimed in Claim 8 wherein the multilayered encasement is a three
layered polymer bag, the inner layer and one outer layer which is in contact with
bitumen binder being polypropylene and the other out layer which is not in contact
with bitumen being polyethylene.
20. A method as claimed in Claim 8 wherein the multilayered encasement is a three
layered polymer bag, the inner layer and one outer layer which is not in contact with
bitumen binder being polypropylene and the other outer layer which is in contact with
bitumen being polyethylene.
21. A method as method as claimed in Claim 8 wherein the multilayer polymer
encasement forms 0.5 to 10 wt% of the total package, the remaining being paving
bitumen binder.
22. A method as method as claimed in Claim 8 where in the polymer encasement when
forms more than 2wt% of the total package, upon melting the polymer becomes
homogeneous, gets incorporated with paving bitumen binder and improves the
properties of the binder.
23. A method as claimed in claims 8 to 23 wherein one or more multilayered encasement
is covered by a secondary encasement.


24. A method as claimed in claim 23 wherein said secondary encasement is made of a
material which upon melting becomes homogeneous with the paving bitumen binder
contained therein.
25. A mould for packing bitumen in a multi layer polymer encasement the mould comprising a bottom wall(8) and a pair of horizontal side walls(l, 2) mounted on said bottom wall(8), the horizontal side walls(l,2) mount, so that at least one of the horizontal side walls(l,2) open outwardly, away from the other in an open position so that they and stand vertically, parallel to each other in a closed position, thereby providing a space there between for positioning a bag to be filled and packed with the mould further comprising bitumen, locking means(3,4) located on the top of at least one side wall(l,2) so that the side walls are maintained in a locked position while the bag is being filled with bitumen.
26. A mould as claimed in claim 25, wherein the side walls(l,2) are perforated.
27. A mould as claimed in claim 25 or 26 wherein both the side walls are hingedly
mounted(5,6,7) on said bottom wall(8).
28. A mould as claimed in claim27 wherein one side wall(2) is hingedly mounted on said bottom wall(8) while the other side wall(l) is fixedly mounted on said bottom wall.
29. A mould as claimed in claims 25 to 28 wherein the locking means(3,4) comprise a hook and eye mechanism.
Dated this the 17th day of August 2009