DESC:TECHNICAL FIELD OF THE INVENTION:
The present invention relates to a composition comprising a novel combination of Oragnometalo compounds with specific antimicrobial and antioxidant property for agricultural and non-agricultural applications. More particularly, the present invention relates to organometalo composition comprising Zinc octoate and copper octoates with ratio of metal to organic compound to be 0.05 to 99.05 %.

BACKGROUND AND PRIOR ART OF THE INVENTION:
Earlier organo metal complexes such as zinc octoates are reported to be used as hydrogen sulfide scavengers. Petroleum asphalt is produced as a residue of a thermal separation refinery process as per the teachings of European Patent Publication No. 0121377 and 000 421 683 A1.
US5000835 describes use of oil soluble metal carboxylates as hydrogen sulphide scavengers. This patent describes the reaction between H2S and metal carboxylates with 6 to 24 carbon atoms. In these metal carboxylates, the carbonyl group functions as a carrier for the oppositely charged metal and places the metal into a form which is soluble in an organic environment and able to make contact with dissolved hydrogen sulfide. When the metal in the metal carboxylates reacts with dissolved hydrogen sulfide, the two forms an insoluble metal sulfide, which eliminates the toxic and corrosive properties of the hydrogen sulfide.
The organo metallic complexes of Arsenic, Antimony and Bismuth reported to be used as pesticides from early 60’s (Agricultural and Biocidal Applications of Organometalics. Richard J. Daum. M&T Chemicals, Inc., Research laboratory, Rahway, N.J).

SUMMARY OF THE INVENTION:
The present invention discloses a organometalo composition comprising novel combination of organo metal compounds having antimicrobial and antioxidant property for agriculture and non-agriculture applications with a specific ratio of metal to organic molecules.
In a preferred aspect, the organometalo composition of the present invention comprises Zinc octoate and copper octoates wherein, the ratio of metal to organic compound ranging from 0.05 to 99.05.

DESCRIPTION OF DRAWINGS:
Figure 1 shows 3M (enterobactereaceae) plates test for various pronos initially.
Figure 2 shows 3M (enterobactereaceae) plates test for various pronos after 24 hrs.
Figure 3 shows3M (enterobactereaceae) plates test for various pronos after 48 hrs.

DETAILED DESCRIPTION OF INVENTION:
The invention will now be described in detail in connection with certain preferred and optional embodiments, so that various aspects thereof may be fully understood and appreciated.
Accordingly, the present invention provides a composition comprising novel combination of one or more oragnometalo compounds with specific antimicrobial and antioxidant property for agricultural and non-agricultural applications.
In a specific embodiment, the organometalo compounds of the present invention comprises Zinc octoate and copper octoates with a ratio of metal to organic compound ranging from 0.05 to 99.05.
Accordingly, the organometalo composition of the present invention comprises Zinc octoate and copper octoate along with other organometalo compounds having antimicrobial and antioxidant property, wherein, the metal concentration is preferably in the range of 0.5 to 25 % and the organic molecules concentration in the range of 75 to 99.5 %, for agricultural and non-agricultural applications.

In one preferred embodiment the organometalo composition comprising Zinc octoate and copper octoates in a ratio of 1:1.
In another embodiment, the other organometalo compounds are selected from the group consisting of silicates, phosphate/phosphites and benzoates of Zinc and copper.
In another preferred embodiment, the oragnometalo composition optionally comprises trace metals selected from iron, manganese, magnesium, ammonium, calcium, potassium, boron, molybdenum; non-metals such as nitrogen, phosphorous, sulphur and organic moieties such as acetates, propionates, benzoates, gallates etc, to improve plant resistance to reduce plant efficacy disorders or symptoms thereof mediated by such metallo enzymes.

Accordingly, in another preferred embodiment, the present invention provides a composition of Zinc and Copper octoates optionally with Iron and Manganese to activate Super Oxide Dismutage-(SOD) thereby providing methods of treating diseases, disorders or symptoms thereof mediated by such metallo enzymes.

In another preferred embodiment, the present invention provides a composition of Zinc and Copper octoates optionally with Benzoates, acetates, gallates and propionates of metals to improve plant resistance to reduce plant efficacy disorders or symptoms thereof mediated by such metallo enzymes.

In yet another preferred embodiment, the present invention provides a composition of Zinc and Copper octoates alongwith silicates and Phosphates/phosphites.

Accordingly, in another preferred embodiment, the present invention provides the composition of Zinc and Copper octoates with silicates and Phosphates with Silicates: Phosphates: octoates having ratios of 5:3:2 to improve plant resistance to disorders or symptoms thereof.
In another embodiment, the composition of the present invention comprises the combination of Zinc and copper silicates, Phosphites and octoates in the ratio of 5: 3:2 to improve plant resistance to disorders or symptoms thereof.

In yet another embodiment, the composition of the present invention the combination of Zinc and copper silicates, Phosphates, phosphites and octoates in the ratio of 5: 1.5: 1.5: 2 to improve plant resistance to disorders or symptoms thereof.

In a further embodiment, the composition comprises the combination of Zinc and copper silicates, Phosphates, octoates and benzoates in the ratio of 5: 3: 1: 1 to improve plant resistance to disorders or symptoms thereof.

In yet another embodiment, the present invention has demonstrated the anti-microbial property of the organometalo compositions of the present invention. The use of copper and zinc octoates even in 10% in the composition also effectively ingibits the growth of the mycobacteriumenterobacteria and E-coli, as shown in table 3 and figures 1 to 3, indicating that the claimed compositions can be used as foliar application for the treatement of bacterial and funagl deseases from the plants.

Other features and embodiments of the invention will become apparent by the following examples which are given only for the purpose of illustration of the invention rather than limiting its intended scope. Various changes and modifications to the disclosed embodiments will be apparent to those skilled in the art.

EXAMPLES
Example-1:
Oraganometalo compositions comprising Zinc and Copper Octoates with Metal silicates and Metal phosphates in a specific ratio in 5:3:2 ratio is shown in table 1 below.
Table 1
COMPOSITION WEIGHT IN G THEORITICAL %Zn & % Cu
Zinc and Copper silicates in 1:1 50 G EACH 3 %
Zinc and Copper Phosphates in 1:1 30 G EACH 6 %
Zinc and Copper Octoates in 1:1 20 G EACH 2 %

Example-2:
Composition comprising Zinc and Copper Octoates with silicates and Phosphates and with or without Iron and Manganese alongwith specific ratio of Nitrogen, Phosphorous and Potassium having ratios of 5:3:2 and with Trace elements, as shown in table 2, to improve plant resistance to disorders or symptoms thereof.
Table 2
ORGANOMETALLIC COMPOUND ALONG WITH NPK
s.no Name of raw material Chilli Vegetable grades (brinjal, okra, cabbage, cauliflower, beans,gaurds)
Chilli flowering 7-3-23 Fruit development and maturity 8-2-27

Weight in grams Weight in grams
1 SILICATES 100 100
2 PHOSPHATES 60 60
3 OCTOATES 40 40
4 UREA 22 50
5 KNO3 13-0-45 511 444
6 SOP 00-00-50(Sulphate of potash) 0 0
7 MAP(Monoammonium phosphate) 0 0
8 MKP(Mono Potassium Phosphate) 0 0
9 Ca- PROPIONATE 33.3 33.3
10 Ca-ACETATE 33.3 33.3
11 Ca-PHOSPHATE (HAP) 33.3 33.3
12 BOROVIN 120 120
13 MgSO4 anhydrous 13 26
14 MnSO4.H2O 28 0
15 FeSO4.7H2O 0 0
16 BORIC ACID 0 0
17 Fe-EDTA 0 10
18 Mn-EDTA 0 40
19 AMMONIUM MOLYBDATE 0 0.02
20 ANTI CAKING 6 10
TOTAL 1000 1000

Example 3:
The anti-microbial property of the organometalo compositions of the present invention is demonstrated in the below table 3 and shown in figures 1 to 3. The use of combination of copper and zinc octoates(1:1) even in 10% in the compositions of copper and zinc (1:1) silicates, phosphates, phosphites and benzoates, effectively inhibits the growth of the enterobacteria and E-coli, when compared to silicates, phosphates, phosphites and benzoates alone or their combinations. Therefore, the combination of copper and zinc octoates (1:1) even in 10% in the compositions of silicates, phosphates, phosphites and benzoates effectively inhibits the growth of the enterobacteria and E-coli, when compared to the compositions that are devoid of octoates as demonstrated in table 3 below.

Table 3:
3M (ENTEROBACTEREACEAE) PLATES TEST FOR VARIOUS PRONOS

S.NO DESCRIPTION with Ratios of
SILICATES-PHOSPHATES-OCTOATES DILUTION FOR 3 M % of Anti microbial property
1 50-30-20 SILICATES-PHOSPHATES-OCTOATES(PRONOS-1) 1G/LIT 100 %
2 50-30-20 SILICATES-PHOSPHITES –OCTOATES(PRONOS-2) 1G/LIT 100 %
3 50-15-15-20 SILICATES-PHOSPHATES-PHOSPHITES-OCTOATES(PRONOS-3) 1G/LIT 100 %
4 50-30-20 SILICATES-PHOSPHATES-BENZOATES(PRONOS-4) 1G/LIT 90 %
5 50-30-10-10 SILICATES-PHOSPHATES-OCTOATES-BENZOATES(PRONOS-5) 1G/LIT 100 %
6 COPPER AND ZINC SILICATES -50-50 (1:1) 1G/LIT 80%
7 COPPER AND ZINC PHOSPHATES-50-50 (1:1) 1G/LIT NIL
8 COPPER AND ZINC PHOSPHITES-50-50 (1:1) 1G/LIT NIL
9. COPPER AND ZINC BENZOATES -50-50 (1:1) 1G/LIT 80%
10. COPPER OCTOATE-100 1G/LIT 70%
11. ZINC OCTOATE-100 1G/LIT 60%
12 COPPER AND ZINC OCTOATE-50-50 (1:1) 1G/LIT 100%

Procedure:
Various formulation(Pronos) as referred above in table 3 was prepared by dissolving 1gm of the formulation in one litre of contaminated water containing Ecoli or Enterobactereacea. The samples were placed on the 3M plates(3M Petrifilm Enterobacteriaceae Count Plate) and incubated all the plates for 24 hours period. After 24 hours a clear indication of Anti-Microbial property was observed from the color change in the 3M paltes.

Each 3M –Plate have self-indicated with selected Media for Ecoli and Entero bacteacea. These 3M Petrifilm Enterobacteriaceae Count Plate is a sample-ready-culture medium system that contains modified Violet Red Bile Glucose (VRBG) nutrients, a cold-watersoluble gelling agent, and a tetrazolium indicator that facilitates colony enumeration. 3M Petrifilm Enterobacteriaceae Count Plates are used for the enumeration of Enterobacteriaceae in the food, beverage and bottled water industries. Enterobacteriaceae are oxidase-negative, Gram-negative rods that ferment glucose to produce acid and/or gas. Enterobacteriaceae colonies will appear as red colonies associated with yellow zones, red colonies associated with gas bubbles, red colonies associated with yellow zones and with gas bubbles (source: 3M PetrifilmTM).

Color Indication plate for Microbial species:

3M-Plate-Violet color for Entero Bactreacea
3-M Plate-Pink color for E-COLI

As the count of the Enterobacteriaceae increases, the color of the gel lightens
from violet to yellow or cream colored. Similarly, As the count of the e-coli increases, the color of the gel lightens from dark pink to light pink colored.

Results:
Above all formulations containing copper and zinc octoate(1:1) gives clear indication of 100 % Anti microbial property against Enterobacteriaceae and E. Coli.
Based on the above results the claimed compositions can be used as foliar application in agriculture fileds for the treatment of bacterial and funagl deseases from the plants like phytopathogens are tested and found its controlled.

Example 4:
Example 4, illustrates various formulation prepared using octoates of zinc and copper along with phosphates, silicates, benzoates, propionates and NPK, for agricultural applications as provided under tables 4 to 10.
Table 4

CP: Calcium Phosphate; ZP: Zinc phosphate; ZS: Zinc silicate; CS: Calcium silicate

Table 5:
Various combinations of copper and zinc silicates, phosphates and octoates are prepared and provided below as samples 12 to 15 as above in table 5.

Table 6:
Table 6 shows various combinations of Zn and Cu Octoates along with P2O5.

CONTENTS
Sample code % Zn % Cu % P2O5 % Zn+Cu Octoates
sample-1 11 10 0 100
sample-2 0 20 0 100
sample-3 0 26.2 18 0+1
sample-4 0 26.1 18 0+1
sample-5 0.2 26 18 1+0
sample-6 0.1 26 18 0.5+0
sample-7 26 0 18 0
sample-9A 13.1 13.1 18 0.5+0.5
sample-9B 13.2 13.2 18 1+1
sample-9C 11 11 13.5 0.25+0.25
sample-10 0 26 18 0
sample-11 100
sample-12 12.54 10.54 13 9+0
sample-13 10.54 12.54 13 0+9
sample-14 13.4 9 10.8 20+0
sample-15 9 13.4 10.8 0+20
sample-1(1:1 Zn Octoate + Copper Octoate) 11 10 0
sample-2 (Copper Octoate) 0 20 0
SAMPLE-16 (60-40-10) 10.54 12.54 13 0.9+0.9
SAMPLE-17 (50-30-20) 9 9 10.8 1.8+1.8

Table 7: Table 7 shows various combinations of Zn and Cu silicates, phosphates and Octoates.

1:1 silicates 1:1 phosphates Zn-Octoate Cu-Octoate Sample weight
sample-1 (1:1 Zn Octoate + Copper Octoate) 0 0 50 50 100
sample-2 (Copper Octoate) 0 0 0 100 100
SAMPLE-16
(60-40-10) 54.4 36.4 4.6 4.6 100
SAMPLE-17
(50-30-20) 50 30 10 10 100

Table 8:
Table 8 shows various compositions of zinc octoate, copper octoate without Zinc/copper Phosphate and Zinc/copper Silicates either alone or in combination thereof.

PER ACRE DOSE
S NO Composition 1-A 1-B
Sample-1 Zinc Octoate 0.5 gm 1 gm
Copper Octoate 0.5 gm 1 gm

2-A 2-B
Sample-2 Copper Octoate 1 gm 2 gm

Sample-3 (CS + CP) = 100 gm / acre with Copper Octoate 1 gm

Sample-4 (CS + CP) = 200 gm / acre with Copper Octoate 1 gm

Sample-5 (CS + CP) = 100 gm / acre with Zinc Octoate 1 gm

Sample-6 (CS + CP) = 200 gm / acre with Zinc Octoate 1 gm

Sample-7 Zinc Phosphate + Zinc Silicate=100 gm / acre

Sample-8 Zinc Phosphate + Zinc Silicate=200 gm / acre
9-A 9-B 9-C
Sample-9 CS/ ZS 50 gm 50 gm 125gm
CP/ ZP 50 gm 50 gm 75 gm
Copper Octoate 0.5 gm 1 gm 0.5 gm
Zinc Octoate 0.5 gm 1 gm 0.5 gm

Sample-10 CS+CP(1:1)

Sample-11 Sucrose Octoate Insect & Microbes

Table 9
Table 9 discloses a composition containing pronos 1 to 3 along with other agricultural ingredients with Stevia extract.
DORMULIN-3 VEGETATIVE WITH BIO FILM BREAKERS + STEVIA EXTRCT
S.NO RAW MATERIAL Qty/MT
1 Pronos -1 100
2 Pronos-2 60
3 Pronos-3 40
4 MgSO4.H2O 110
5 MnSO4.H2O 100
6 FeSO4.7H2O 50
7 AMMONIUM MOLYBDATE 5
8 FULVIC ACID 200
9 UREA 30
10 Roxite 100
11 SOP 100
12 BOROVIN 12
13 STEVIA EXT-CHLOROFORM 1 ML
14 STICKING AGENT(JEEMOX) 3
15 DISPERSANT(JEEMOL DW) 90
16 TOTAL WEIGHT 1000

Table 10: DORMULIN-3 FLOWERING VARIANTS
2. stevia extract 3. KOH & urea 4. Pot.benzoate & Pot.peroxy mono sulfate 5. Calcium thio sulfate
S.NO RAW MATERIAL Qty IN G Qty IN G Qty IN G Qty IN G
1 Pronos -1 100 100 100 100
2 Pronos-2 60 60 60 60
3 Pronos-3 40 40 40 40
4 Calcium ACETATE 50 50 50 50
5 AMMONIUM MOLYBDATE 5 5 5 5
6 FULVIC ACID 250 250 250 250
7 calcium propionate 50 50 50 50
8 SOP 200 0 0 199
9 KOH FLAKES 0 100 0 0
10 BOROVIN 120 120 120 120
11 UREA 0 100 0 0
12 10 % STEVIA EXT-CHLOROFORM 1 ML 1 ML 1 ML
13 POTASSIUM BENZOATE 100 0
14 POTASSIUM PEROXY MONO SULFATE 100 0
15 CALCIUM THIOSULFATE 1
16 STICKING AGENT(JEEMOX) 0 0 0 0
17 DISPERSANT(JEEMOL DW) 120 120 120 120
18 Jeesperse 5 5 5 5
TOTAL WEIGHT 1000 1000 1000 1000

,CLAIMS:1. Organometalo composition comprising Zinc octoate and copper octoate along with other organometalo compounds having antimicrobial and antioxidant property, wherein, the metal concentration is in the range of 0.5 to 25 % and the organic molecules concentration in the range of 75 to 99.5 % for agricultural and non-agricultural applications.
2. The oragnometalo composition as claimed in claim 1, wherein, the Zinc octoate and copper octoates is in a ratio of 1:1, to improve plant resistance to disorders or symptoms thereof.
3. The oragnometalo composition as claimed in claim 1, wherein, the composition optionally comprises trace metals selected from iron, manganese, magnesium, ammonium, calcium, potassium, boron, molybdenum; non-metals such as nitrogen, phosphorous, sulphur and organic moieties such as acetates, propionates, benzoates, etc, to improve plant resistance to reduce plant efficacy disorders or symptoms thereof mediated by such metallo enzymes.
4. The composition as claimed in claim 1, wherein, the other organometalo compounds are selected from the group consisting of silicates, phosphate/phosphites and benzoates of Zinc and copper.
5. The composition as claimed in claim 4, wherein, the composition comprises the combination of Zinc and copper silicates, Phosphates and octoates in the ratio of 5: 3:2 to improve plant resistance to disorders or symptoms thereof.
6. The composition as claimed in claim 4, wherein, the composition comprises the combination of Zinc and copper silicates, Phosphites and octoates in the ratio of 5: 3:2 to improve plant resistance to disorders or symptoms thereof.
7. The composition as claimed in claim 4, wherein, the composition comprises the combination of Zinc and copper silicates, Phosphates, phosphites and octoates in the ratio of 5: 1.5: 1.5: 2 to improve plant resistance to disorders or symptoms thereof.
8. The composition as claimed in claim 4, wherein, the composition comprises the combination of Zinc and copper silicates, Phosphates, octoates and benzoates in the ratio of 5: 3: 1: 1 to improve plant resistance to disorders or symptoms thereof.