DESC:FIELD OF THE INVENTION:

The present invention relates to pesticidal compositions comprising of bioactive amount of anthranilamide insecticides and fungicide(s) wherein anthranilamide insecticide may be selected from Chlorantraniliprole or Flubendiamide and at least one fungicide(s) may be selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl. The present invention also relates to process of preparing the said compositions.

BACKGROUND OF THE INVENTION

Chlorantraniliprole was first disclosed WO 03/015518. Chlorantraniliprole is chemically known as 3-bromo-4'-chloro-1- (3-chloro-2-pyridyl) -2'-methyl-6'-(methylcarbamoyl) pyrazole-5-carboxanilide and having chemical structure as below;

Chlorantraniliprole has efficient mechanism which is activated by ryanodine receptor, excessive release of intracellular stores of calcium ions, resulting in the death of the insect paralysis. Chlorantraniliprole is efficient broad-spectrum, for the purpose of Noctuidae phosphorus wing, bore fruit moth, leaf roller Branch, flour moth and other mouth ColeopteraCurculionidae, Chrysomelidae, DipteraAgromyzidae etc. are good control effect.

Flubendiamide was first disclosed in US6603044B1. Flubendiamide is chemically known as 3-iodo-N'-(2-mesyl-1,1-dimethylethyl)-N-{4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]-o-tolyl}phthalamideand having chemical structure as below;

The insecticidal and acaricidal action of flubendiamide and its suitability as pest control agent have been known for a long time and were described for the first time in EP1006107B1. It is also known that the activity of flubendiamide can be increased by combining it with other chemicals such as, for example, insecticides. Thus, for example, EP380209 and WO2004/034786 describe the enhanced activity of combinations comprising flubendiamide and other insecticides. An increased insecticidal and acaricidal activity of flubendiamide by addition of ammonium or phosphonium salts has also been described (WO2007/068357).

CN103109823A relates to novel composition butene-fipronil and chlorantraniliprole pesticide composition. The butene-fipronil and chlorantraniliprole pesticide composition comprises the components of butene-fipronil and chlorantraniliprole serving as active ingredients, as well as the balance of a pesticide adjuvant, wherein the weight ratio of the butene-fipronil and the chlorantraniliprole is (1:20)-(20:1), and the sum of the weight of the butene-fipronil and the chlorantraniliprole accounts for 0.1-80% of the weight of the composition.

CN102484994B relates to novel composition of matrine and Chlorantraniliprole, quality ratio matrine and Chlorantraniliprole of 50:1 to 1:50. The compositions include Matrine, oxymatrine and matrine mixture, or a series of alkaloids obtained from Sophora, bitter beans, broad beans and other plant roots extract and its preparations.

CN101720769A relates to novel composition and a preparation method and application thereof, wherein the insecticidal composition is a mixture comprising a compound (A), i.e. pymetrozine and a compound (B), i.e. chlorantraniliprole.

CN102318611A relates to a novel synergistic insecticidal composition which is a mixture of a compound (A) flubendiamide and a compound (B) chlorantraniliprole. The insecticidal composition can be processed in missible oils, suspending agents, wettable powders and water dispersible granules. The weight ratio of the compound (A) flubendiamide to the compound (B) chlorantraniliprole is (1-100) :( 1-100).

CN 200910069468 relates to novel composition comprising chlorantraniliprole with synergistic effective dose, abamectin or emamectin benzoate, and one of cyhalothrin, dursban, diazinon, acetamiprid, cypermethrin, alpha cypermethrin, thiamethoxam, thiacloprid, fenvalerate, propargite, diafenthiuron, benfuracarb, azocyclotin, buprofezin, ethofenprox, phonamiphos, fipronil, flufenoxuron, monosultap, dimehypo, imidacloprid, flufenoxuron, chlorfluazuron, pleocidin and tebufenozide, wherein the mass percentage of the three compositions is that: the chlorantraniliprole is 1 to 35 percent, the abamectin or the emamectin benzoate is 1 to 10 percent, and any one of the insecticides is 1 to 50 percent. The invention discloses a process for processing the compositions and application of the compositions in preparing insecticides for controlling agricultural, forestry and gardening insect pests.

US7901700B2 relates to method for controlling general household pests selected from the group consisting of German cockroaches, house flies, red imported fire ants and bed bugs comprising applying an insecticidally effective amount of a formulation comprising a mixture of i) bifenthrin and ii) acetamiprid; and iii) an aqueous medium to a locus where general household pest control is needed or expected to be needed wherein the amount of the bifenthrin in the composition is equal to from 0.001% by weight to 0.12% by weight of the formulation and the amount of the acetamiprid is equal to from 0.001% by weight to 0.20% by weight of the formulation.

It is an object of the present invention, with a view to reducing the application rates and broadening the activity spectrum of the known compounds, to provide mixtures which, at a reduced total amount of active compounds applied, have improved activity against pests.

One typical problem arising in the field of pest control lies in the need to reduce the dosage rates of the active ingredient in order to reduce or avoid unfavorable environmental or toxicological effects whilst still allowing effective pest control.

In regard to the instant invention the term pests embrace animal pests, and harmful fungi. Another problem encountered concerns the need to have available pest control agents which are effective against a broad spectrum of pests. There also exists the need for pest control agents that combine knock-down activity with prolonged control, that is, fast action with long lasting action.

Another difficulty in relation to the use of pesticides is that the repeated and exclusive application of an individual pesticidal compound leads in many cases to a rapid selection of pests, that means animal pests, and harmful fungi, which have developed natural or adapted resistance against the active compound in question. Therefore there is a need for pest control agents that help prevent or overcome resistance.

It was therefore an object of the present invention to provide pesticidal mixtures which solve the problems of reducing the dosage rate and/or enhancing the spectrum of activity and/or combining knock-down activity with prolonged control and/or to resistance management.

We have found that this object is in part or in whole achieved by the combination of active compounds defined at the outset. Moreover, we have found that simultaneous, that is application of a compound I and one or more compounds II or successive application of a compound I and one or more compounds II allows enhanced control of pests that means animal pests, and harmful fungi, compared to the control rates that are possible with the individual compounds (synergistic mixtures).

However still there is a need for a composition of specific pesticide which overcomes some of the existing problems and can be prepared easily without much complex manufacturing process.

The objective of the present invention is that time of pest appearance i.e. insects and fungal diseases are the same; hence such compositions would have dual benefit. In addition the mixture will significantly reduce labour dependence and costs.

SUMMARY OF THE INVENTION

The present invention relates to pesticidal composition comprising, as active components,
1) an anthranilamide insecticide compound of I selected from Chlorantraniliprole or Flubendiamide;
2) at least one fungicidal compound II selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl
3) optionally one or more inactive excipients

Further the present invention also relates to process for preparing the agrochemical compositions comprising of bioactive amounts of anthranilamide insecticide, and fungicide wherein anthranilamide insecticide may be selected from Chlorantraniliprole or Flubendiamide and atleast one fungicide may be selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl and at least one or more inactive excipient.

The present invention also relates to agrochemical compositions comprising anthranilamide insecticide, and fungicide wherein anthranilamide insecticide may be selected from Chlorantraniliprole or Flubendiamide and fungicide may be selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl, wherein anthranilamide insecticide and fungicide are in ratio of 1:15 to 5:1.

Further the present invention also relates to the process for preparing the said agrochemical compositions of anthranilamide insecticide, and fungicide.

DETAILED DESCRIPTION OF THE INVENTION

The present invention relates to pesticidal composition comprising, as active components,
1) an anthranilamide insecticide compound of I selected from Chlorantraniliprole and Flubendiamide;
2) at least one fungicidal compound II selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl
3) optionally one or more inactive excipient.

Moreover, the invention relates to a method for controlling pests, this includes animal pests and harmful fungi, using mixtures of a compound I with active compound II and to the use of the compounds I with the active compound II for preparing such mixtures, and also to compositions comprising such mixtures.

In one embodiment the present invention provides methods for the control of anthranilamide insecticides and fungicides comprising contacting the anthranilamide insecticides and fungicides or their food supply, habitat, breeding grounds or their locus with a pesticidally effective amount of mixtures of a compound I with one or more compounds II.

Moreover, in another embodiment the present invention also relates to a method of protecting plants from attack or infestation by anthranilamide insecticides and fungicides comprising contacting the plant, or the soil or water in which the plant is growing, with a pesticidally effective amount of a mixture of a compound I with one or more compounds II.

This invention also provides a method for treating, controlling, preventing or protecting an animal against infestation or infection by parasites which comprises orally or topically administering or applying to the animals a parasiticidally effective amount of a mixture of a compound I with one or more compounds II.

The invention also provides a process for the preparation of a composition for treating, controlling, preventing or protecting a warm-blooded animal or a fish against infestation or infection by anthranilamide insecticides and fungicides which comprises a pesticidally effective amount of a mixture of a compound I with one or more compounds II.

Moreover, the invention relates to a method for controlling harmful fungi using mixtures of a compound I with active compounds II and to the use of a compound I with active compounds II for preparing such mixtures, and also to compositions comprising these mixtures.

The pesticidal composition of present invention can be in form of Suspension Concentrate (SC), Suspo emulsion (SE), Water dispersible grnules (WDG), Emulsifiable concentrate (EC), Oil dispersion (OD), capsule suspenson (CS), Zean Concentrate (ZC. Preferably the pesticidal composition of the present invention is in the form of Suspension Concentrate (SC), Suspo emulsion (SE), Water dispersible grnules (WDG).
Composition of the present invention can be in any of the form described above the agrochemical compositions comprising anthranilamide insecticides, and fungicides will be used for control of mixed infestation of Insect-pests and fungal diseases in the agricultural crops like Cotton (Gossypium spp.), Jute (Corchorus oliotorus), Paddy (Oryza sativa), Wheat (Triticum aestavum), Barley (Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Ragi (Eleusine coracana), Pearl millet (Pennisetum glaucum), Sugarcane (Saccharum officinarum) , Sugarbeet (Beta vulgaris), Soybean (Glycin max), Peanut (Arachis hypogaea), Sunflower (Helianthus annuus) , Mustard (Brassica juncea), Rape seed (Brassica napus), Linseed (Linum usitatissimum), Sesame (Sesamum indicum), Castor (Ricinus communis), Green gram (Vigna radiate), Black gram (Vigna mungo), Chickpea (Cicer aritinum), Cowpea (Vigna unguiculata), Redgram (Cajanus cajan), Frenchbean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotyloma uniflorum), Field pea (Pisum sativum), Cluster bean (Cyamopsis tetragonoloba), Lentils (Lens culinaris), Brinjal (Solanum melongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschus esculentus) , Onion (Allium cepa L.), Tomato (Solanum lycopersicun) , Potato (Solanum tuberosum) , Sweet potato (Ipomoea batatas), Chilly (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumis sativus), Muskmelons (Cucumis melo), Watermelon (Citrullus lanatus), Bottle gourd (Lagenaria siceraria), Bitter gourd (Momordica charantia), Radish (Raphanus sativus), Carrot (Dacus carota subsp. sativus), Turnip (Brassica rapa subsp rapa), Apple (Melus domestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitis vinifera), Guava (Psidium guajava), Litchi (Litchi chinensis), Mango (Mangifera indica), Papaya (Carica papaya), Pineapple (Ananas comosus), Pomegranate (Punica granatum) , Sapota (Manilkara zapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiber officinale), Cumin (Cuminum cyminum), Fenugreek (Trigonella foenum-graecum), Fennel (Foeniculum vulgare), Coriander (Coriandrum sativum), Ajwain (Trachyspermum ammi), Psyllium (Plantago ovate), Black Pepper (Piper nigrum), Stevia (Stevia rebaudiana), Safed musli (Chlorophytum tuberosum), Drum stick (Moringa oleifera), Coconut (Coco nucifera), Mentha ( Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold ( Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera ( Gerbera jamesonii), Carnation (Dianthus caryophyllus).
The agrochemical or pesticidal compositions as per the present invention comprising anthranilamide insecticides, and fungicides will be used for control of mixed infestation of Insects belongs to class of lepidopterans (Lepidoptera), for example Agrotis ypsilon, Agrotis segetum, Alabama argillacea, Anticarsia gemmatalis, Argyresthia conjugella, Autographa gamma, Bupalus piniarius, Cacoecia murinana, Capua reticulana, Cheima-tobia brumata, Choristoneura fumiferana, Choristoneura occidentalis, Cirphis unipuncta, Cnaphalocrocis medinalis, Cydia pomonella, Dendrolimus pini, Diaphania nitidalis, , Earias insulana, Elasmopalpus lignosellus, Eupoecilia ambiguella, Evetria bou-liana, Feltia subterranea, Galleria mellonella, Grapholitha funebrana, Grapholitha mo-lesta, Heliothis armigera, Heliothis virescens, Heliothis zea, Hellula undalis, Hibernia defoliaria, Hyphantria cunea, Hyponomeuta malinellus, Keiferia lycopersicella, Lamb-dina fiscellaria, Laphygma exigua, Leucoptera coffeella, Leucoptera scitella, Lithocol-letis blancardella, Lobesia botrana, Loxostege sticticalis, Lymantria dispar, Lymantria monacha, Lyonetia clerkella, Malacosoma neustria, Mamestra brassicae, Orgyia pseu-dotsugata, Ostrinia nubilalis, Panolis flammea, Pectinophora gossypiella, Peridroma saucia, Phalera bucephala, Phthorimaea operculella, Phyllocnistis citrella, Pieris bras-sicae, Plathypena scabra, Plutella xylostella, Pseudoplusia includens, Rhyacionia frus-trana, Scirpophaga incertulas, Sesamia inferens, Chilo suppressalis, Scrobipalpula absoluta, Sitotroga cerealella, Sparganothis pilleriana, Spodoptera frugiperda, Spodoptera exigua, Spodoptera littoralis, Spodoptera litura, Thaumatopoea pityocampa, Tortrix viridana, Trichoplusia ni and Zeiraphera canadensis, beetles (Coleoptera), for example Agrilus sinuatus, Agriotes lineatus, Agriotes obscu-rus, Amphimallus solstitialis, Anisandrus dispar, Anthonomus grandis, Anthonomus pomorum, Aphthona euphoridae, Athous haemorrhoidalis, Atomaria linearis, Blasto-phagus piniperda, Blitophaga undata, Bruchus rufimanus, Bruchus pisorum, Bruchus lentis, Byctiscus betulae, Cassida nebulosa, Cerotoma trifurcata, Cetonia aurata, Ceuthorrhynchus assimilis, Ceuthorrhynchus napi, Chaetocnema tibialis, Conoderus vespertinus, Crioceris asparagi, Ctenicera ssp., Diabrotica longicornis, Diabrotica semipunctata, Diabrotica 12-punctata Diabrotica speciosa, Diabrotica virgifera, Epila-chna varivestis, Epitrix hirtipennis, Eutinobothrus brasiliensis, Hylobius abietis, Hypera brunneipennis, Hypera postica, Ips typographus, Lema bilineata, Lema melanopus, Leptinotarsa decemlineata, Limonius califomicus, Lissorhoptrus oryzophilus, Melanotus communis, Meligethes aeneus, Melolontha hippocastani, Melolontha melolontha, Oulema oryzae, Ortiorrhynchus sulcatus, Otiorrhynchus ovatus, Phaedon cochleariae, Phyllobius pyri, Phyllotreta chrysocephala, Phyllophaga sp., Phyllopertha horticola, Phyllotreta nemorum, Phyllotreta striolata, Popillia japonica, Sitona lineatus and Sito-philus gran aria, flies, mosquitoes (Diptera), e.g. Liriomyza sativae, Liriomyza trifolii, true bugs (Hemiptera), e.g. Amrasca biguttula biguttula, Amrasca devastans, Dysdercus cingulatus, Dysdercus intermedius, Eurygaster integriceps, Lygus lineolaris, Lygus pratensis, Aphis fabae, Aphis pomi, Aphis gossypii, Aphis crassivora, Acyrtho-siphon pisum, Bemisia argentifolii, Bemisia tabaci, Brevicoryne brassicae, Empoasca fabae, Macrosiphum avenae, Macrosiphum euphorbiae, My-zus persicae, Nilaparvata lugens, Psylla mail, Rhopalosiphum maidis, Rhopalosi-phum padi, Sitobion avenae, Trialeurodes vaporariorum, Toxoptera aurantiia Amritodus atkinsoni, Idioscopus spp., ants, bees, wasps, sawflies (Hymenoptera), e.g. Athalia lugen proxima. Plant parasitic nematodes such as root-knot nematodes, Meloidogyne incognita, Meloidogyne javanica and other Meloidogyne species; cyst nematodes, Globodera rostochiensis, and other Globodera species, Heterodera avenae, and other Heterodera species; seed gall nematodes, Anguina tritici and other Anguina species; stem and foliar nematodes, Aphelenchoides besseyi, and other Aphelenchoides species; sting nematodes, Belonolaimus longicaudatus and other Belonolaimus species; pine nematodes, Bursaphelenchus xylophilus and other Bursaphelenchus species; stem and bulb nematodes, Ditylenchus destructor, and other Ditylenchus species; lesion nematodes, Pratylenchus brachyurus, and other Pratylenchus species; burrowing nematodes, Radopholus similis and other Radopholus species; reniform nematodes, Rotylenchulus reniformis and other Rotylenchulus species; stunt nematodes, Tylenchorhynchus claytoni, Tylenchorhyn and fungal diseases caused by fungi belongs to class .
The agrochemical or pesticidal compositions as per the present invention comprising anthranilamide insecticides, and fungicides willalso be used to control fungal diseases like, in wheat crop: Alternaria leaf blight Alternaria triticina, Anthracnose Colletotrichum graminicola,Ascochyta leaf spot Ascochyta tritici, Aureobasidium decay Microdochium bolleyi, Black head molds (sooty molds) Alternaria spp., Cladosporium spp., Epicoccum spp., Sporobolomyces spp., Stemphylium spp., Common bunt/ stinking smut Tilletia tritici,Common root rot Bipolaris sorokiniana, Cottony snow mold Coprinus psychromorbidus, Crown rot (foot rot, seedling blight, dryland root rot) Fusarium spp., Fusarium pseudograminearum, Fusarium graminearum, Fusarium culmorum,Dilophospora leaf spot Dilophospora alopecuri, Downy mildew = crazy top Sclerophthora macrospora, Dwarf bunt Tilletia controversa,Ergot Claviceps purpurea, Eyespot = foot rot, Tapesia yallundae, False eyespot Gibellina cerealis,Flag smut Urocystis agropyri, Foot rot Fusarium spp., Karnal bunt = partial bunt Tilletia indica =Neovossia indica, Leaf rust = brown rust Puccinia triticina,Puccinia recondite,Leptosphaeria leaf spot Phaeosphaeria herpotrichoides = Leptosphaeria herpotrichoides,Loose smut Ustilago tritici,Microscopica leaf spot Phaeosphaeria microscopica, Phoma spot Phoma spp., Pink snow mold = Fusarium patch Microdochium nivale,Platyspora leaf spot Clathrospora pentamera,Powdery mildew Erysiphe graminis, Blumeria graminis,Pythium root rot Pythium aphanidermatum, Pythium arrhenomanes, Pythium graminicola, Pythium myriotylum,Rhizoctonia root rot Rhizoctonia solani, Scab = head blight Fusarium graminearum, Sclerotinia snow mold = snow scald Sclerotinia borealis,Sclerotium wilt Sclerotium rolfsii,Septoria blotch Septoria tritici,Sharp eyespot Rhizoctonia cerealis, Snow rot Pythium spp., Speckled snow mold = gray snow mold or Typhula blight Typhula idahoensis,Spot blotch Bipolaris sorokiniana,Stagonospora blotch Phaeosphaeria avenaria, Stagonospora avenae, Septoria avenae, Septoria nodorum , Stem rust = black rust Puccinia graminis,Storage molds Aspergillus spp., Penicillium spp., Stripe rust = yellow rust Puccinia striiformis,Take-all Gaeumannomyces graminis,Tan spot = yellow leaf spot, red smudge Pyrenophora tritici-repentis, Drechslera tritici-repentis,Tar spot Phyllachora graminis. Diseases of Rice : Aggregate sheath spot Ceratobasidium oryzae (anamorph: Rhizoctonia oryzae-sativae), Black kernel Curvularia lunata, Blast (leaf, neck [rotten neck], nodal and collar) Pyricularia grisea=P.oryzae, Brown spot Cochliobolus miyabeanus (anamorph: Bipolaris oryzae),Crown sheath rot Gaeumannomyces graminis,Downy mildew Sclerophthora macrospora, Eyespot Drechslera gigantean,False smut Ustilaginoidea virens,Kernel smut Tilletia barclayana =Neovossia horrid, Leaf smut Entyloma oryzae, Leaf scald Microdochium oryzae, Narrow brown leaf spot Cercospora janseana, Pecky rice (kernel spotting) Damage by many fungi including Cochliobolus miyabeanus, Curvularia spp., Fusarium spp., Microdochium oryzae, Sarocladium oryzae, Root rots Fusarium spp., Pythium spp., P. dissotocum, P. spinosum,Seedling blight Cochliobolus miyabeanus, Curvularia spp., Fusarium spp., Rhizoctonia solani, Sclerotium rolfsii,Sheath blight Thanatephorus cucumeris (anamorph: Rhizoctonia solani), Sheath rot Sarocladium oryzae = Acrocylindrium oryzae, Sheath spot Rhizoctonia oryzae, Stackburn (Alternaria leaf spot) Alternaria padwickii, Stem rot Magnaporthe salvinii= Sclerotium oryzae, Water-mold (seed-rot and seedling disease) Achlya conspicua, A. klebsiana, Fusarium spp., Pythium spp., P. dissotocum, P. spinosum. Diseases of Corn or Maize : Anthracnose leaf blight and anthracnose stalk rot Colletotrichum graminicola, Aspergillus ear and kernel rot Aspergillus flavus, Banded leaf and sheath spot Rhizoctonia solani= Rhizoctonia microsclerotia), Black bundle disease Acremonium strictum, Black kernel rot Lasiodiplodia theobromae = Botryodiplodia theobromae, Brown spot (black spot, stalk rot) Physoderma maydis, Cephalosporium kernel rot Acremonium strictum= Cephalosporium acremonium, Charcoal rot Macrophomina phaseolina, Corticium ear rot Thanatephorus cucumeris= Corticium sasaki, Curvularia leaf spot Curvularia clavata,C. eragrostidis, Curvularia inaequalis, C. intermedia, Curvularia lunata, Curvularia pallescens , Curvularia senegalensis, C. tuberculata, Didymella leaf spot Didymella exitalis, Diplodia ear rot and stalk rot Diplodia frumenti,Diplodia ear rot, stalk rot, seed rot and seedling blight Diplodia maydis, Diplodia leaf spot or leaf streak Stenocarpella macrospora=Diplodia macrospora, Downy mildews:Brown stripe downy mildew Sclerophthora rayssiae, Crazy top downy mildew Sclerophthora macrospora= Sclerospora macrospora, Green ear downy mildew (graminicola downy mildew) Sclerospora graminicola, Java downy mildew Peronosclerospora maydis = Sclerospora maydis, Sorghum downy mildew Peronosclerospora sorghi= Sclerospora sorghi, Spontaneum downy mildew Peronosclerospora spontanea=Sclerospora spontanea, Sugarcane downy mildew Peronosclerospora sacchari= Sclerospora sacchari, Dry ear rot (cob, kernel and stalk rot) Nigrospora oryzae, Ear rots, minor Alternaria alternata= A. tenuis, Aspergillus glaucus, A. niger, Aspergillus spp., Botrytis cinerea, Doratomyces stemonitis=Cephalotrichum stemonitis, Fusarium culmorum,Gonatobotrys simplex , Pithomyces maydicus, Rhizopus microspores, R. stolonifer= R.nigricans, Scopulariopsis brumptii, Ergot Claviceps gigantean, Eyespot Aureobasidium zeae= Kabatiella zeae, Fusarium ear and stalk rot Fusarium subglutinans = F. moniliforme, Fusarium kernel, root and stalk rot, seed rot and seedling blight Fusarium moniliforme, Fusarium stalk rot, seedling root rot Fusarium avenaceum, Gibberella ear and stalk rot Gibberella zeae, Gray ear rot Botryosphaeria zeae= Physalospora zeae, Gray leaf spot (Cercospora leaf spot) Cercospora sorghi= C. sorghi, C. zeae-maydis, Helminthosporium root rot Exserohilum pedicellatum=Helminthosporium pedicellatum, Hormodendrum ear rot (Cladosporium rot) Cladosporium cladosporioides = Hormodendrum cladosporioides, C. herbarum, Hyalothyridium leaf spot Hyalothyridium maydis Late wilt Cephalosporium maydis, Leaf spots, minor Alternaria alternate, Ascochyta maydis, A. tritici, A. zeicola, Bipolaris victoriae= Helminthosporium victoriae,Epicoccum nigrum, Exserohilum prolatum= Drechslera prolata, Graphium penicillioides, Leptosphaeria maydis, Leptothyrium zeae, Ophiosphaerella herpotricha, Paraphaeosphaeria michotii, Phoma sp., Septoria zeae, S. zeicola, S. zeina, Northern corn leaf blight (white blast, crown stalk rot, stripe) Setosphaeria turcica, Helminthosporium turcicum, Northern corn leaf spot, Helminthosporium ear rot Cochliobolus carbonum (anamorph: Bipolaris zeicola). Diseases of Soybeans : Alternaria leaf spot Alternaria spp. Anthracnose Colletotrichum truncatum, Black root rot Thielaviopsis basicola,Brown spot Septoria glycines,Brown stem rot Cephalosporium gregat, Charcoal rot Macrophomina phaseolina, Choanephora leaf blight Choanephora infundibulifera,Damping-off Rhizoctonia solani, Pythium aphanidermatum,P. ultimum, Downy mildew Peronospora manshurica, Drechslera blight Drechslera glycines, Frogeye leaf spot Cercospora sojina, Fusarium root rot Fusarium spp., Phomopsis seed decay Phomopsis spp., Phytophthora root and stem rot Phytophthora sojae, Pod and stem blight Diaporthe phaseolorum, Powdery mildew Microsphaera diffusa, Pythium rot, Rhizoctonia aerial blight Rhizoctonia solani, Rhioctonia root and stem rot Rhizoctonia solani, Rust Phakopsora pachyrhizi, Sclerotinia stem rot Sclerotinia sclerotiorum, Southern blight (damping-off and stem rot) = Sclerotium blight Sclerotium rolfsii, Stemphylium leaf blight Stemphylium botryosum, Sudden death syndrome Fusarium solani. Diseases of Peanut: Alternaria leaf blight Alternaria tenuissima, Alternaria leaf spot Alternaria arachidis,Alternaria alternate, Anthracnose Colletotrichum arachidis,Aspergillus crown rot Aspergillus niger, Botrytis blight Botrytis cinerea, Charcoal rot and Macrophomina leaf spot Macrophomina phaseolina, Choanephora leaf spot Choanephora spp. Collar rot Diplodia gossypina, Colletotrichum leaf spot Colletotrichum gloeosporioides,Cylindrocladium black rot & leaf spot Cylindrocladium crotalariae, Damping-off, Aspergillus flavus, A. niger, Fusarium spp., Pythium spp., Rhizoctonia spp., Rhizopus spp., Drechslera leaf spot Bipolaris spicifera=Drechslera spicifera, Fusarium peg and root rot Fusarium spp., Fusarium wilt Fusarium oxysporum, Leaf spot, early Cercospora arachidicola (teleomorph: Mycosphaerella arachidis), Leaf spot, late Paeoisariopsis personata= Cercosporidium personatum, Myrothecium leaf blight Myrothecium roridum, Peanut Smut Thecaphora frezii, Phoma leaf blight Phoma microspora, Phomopsis foliar blight Phomopsis phaseoli, Phomopsis leaf spot, Pod rot (pod breakdown) Fusarium equiseti, F. solani, Pythium myriotylum, Rhizoctonia solani, Powdery mildew Oidium arachidis, Pythium peg and root rot, Pythium myriotylum,P. aphanidermatum, P. debaryanum, P. irregulare, P. ultimum, Pythium wilt Pythium myriotylum, Rhizoctonia foliar blight, peg and root rot Rhizoctonia solani, Rust Puccinia arachidis, Sclerotinia blight Sclerotinia minor, S. sclerotiorum, Stem rot (southern blight) Sclerotium rolfsii, Verticillium wilt Verticillium albo-atrum, V. dahliae, Web blotch (net blotch) Phoma arachidicola= Ascochyta adzamethica, Yellow mold Aspergillus flavus, A. parasiticus. Diseases of Sunflower : Alternaria leaf blight, stem spot and head rot Alternaria alternate, A. tenuis, A. helianthi, Botrytis head rot (gray mold) Botrytis cinerea, Charcoal rot Macrophomina phaseolina= Sclerotium bataticola=Rhizoctonia bataticola, Downy mildew Plasmopara halstedii, Fusarium stalk rot Fusarium equiseti, F. solani, Fusarium tabacinum, Fusarium wilt Fusarium moniliforme, F. oxysporum,Myrothecium leaf and stem spot Myrothecium roridum,Phoma black stem Phoma macdonaldii, Phomopsis brown stem canker Phomopsis spp., P. helianthi, Phymatotrichum root rot (cotton root rot) Phymatotrichopsis omnivora=Phymatotrichum omnivorum, Phytophthora stem rot Phytophthora spp., Powdery mildew Erysiphe cichoracearum (anamorph: Oidium asteris-punicei), Leveillula compositarum, L. taurica (anamorph: Oidiopsis sicula), Sphaerotheca fuliginea, Pythium seedling blight and root rot Pythium spp., Rhizoctonia seedling blight Rhizoctonia solani, Rhizopus head rot Rhizopus arrhizus, R. nodosus, R. microspores, R. stolonifer, R. nigricans, Rust Puccinia helianthi, Uromyces junci, Sclerotinia basal stalk rot and wilt, mid-stalk rot, head rot Sclerotinia sclerotiorum, Sclerotinia minor, Sclerotium rolfsii, Septoria leaf spot Septoria helianthi , Verticillium wilt Verticillium albo-atrum, White rust, Albugo tragopogonis, Yellow rust Coleosporium helianthi (Schwein.). Diseases of Mustard, Canola & Rape seed : Alternaria black spot Alternaria brassicae, A. brassicicola, A. raphani, Anthracnose Colletotrichum gloeosporioides (teleomorph: Glomerella cingulata), Black leg (leaf, root and stem rot) Leptosphaeria maculans (anamorph: Phoma lingam), Black root Aphanomyces raphani, Cercospora leaf spot Cercospora brassicicola, Clubroot Plasmodiophora brassicae, Damping-off Fusarium spp., Rhizoctonia solani, Downy mildew Peronospora parasitica, Head rot Rhizoctonia solani, Leaf spot Myrothecium roridum Phyllosticta brassicae, Powdery mildew Erysiphe polygoni, Sclerotinia stem rot Sclerotinia sclerotiorum White rust Albugo candida, White leaf spot Pseudocercosporella capsellae, Black mold rot Rhizopus stolonifer, Black root Aphanomyces raphani, Cercospora leaf spot Cercospora brassicicola, Clubroot Plasmodiophora brassicae, Downy mildew Peronospora parasitica, Fusarium wilt Fusarium oxysporum, Gray mold Botrytis cinerea, Head rot Rhizoctonia solani, Light leaf spot Pyrenopeziza brassicae, Pod rot Alternaria alternate, Cladosporium sp., Ring spot Mycosphaerella brassicicola, Root rot Alternaria alternate, Fusarium spp., Macrophomina phaseolina, Phymatotrichopsis omnivore, Phytophthora megasperma, Pythium debaryanum, Rhizoctonia solani, Sclerotium rolfsii, Sclerotinia stem rot Sclerotinia sclerotiorum, Seed rot, damping-off Alternaria spp., Fusarium spp., Gliocladium roseum, Nectria ochroleuca, Pythium spp., Rhizoctonia solani, Rhizopus stolonifer, Verticillium wilt Verticillium longisporum, White leaf spot = grey stem Pseudocercosporella capsellae = Cercosporella brassicae, White rust = staghead Albugo candida. Diseases of Cotton: Anthracnose Glomerella gossypii, Colletotrichum gossypii, Areolate mildew Ramularia gossypii = Cercosporella gossypii, Ascochyta blight Ascochyta gossypii, Black root rot Thielaviopsis basicola, Boll rot Ascochyta gossypii , Colletotrichum gossypii , Southworth Glomerella gossypii, Fusarium spp., Phytophthora spp., Rhizoctonia solani, Charcoal rot Macrophomina phaseolina, Fusarium wilt Fusarium oxysporum, Leaf spot Alternaria macrospora, A. alternate, Cercospora gossypina, Mycosphaerella gossypina, Cochliobolus spicifer, Bipolaris spicifera = Curvularia spicifera, Myrothecium roridum, Rhizoctonia solani, Stemphylium solani, Lint contamination Aspergillus flavus, Nematospora spp., Nigrospora oryzae, Phymatotrichum root rot = cotton root rot Phymatotrichopsis omnivore = Phymatotrichum omnivorum, Powdery mildew Leveillula taurica, Oidiopsis sicula = Oidiopsis gossypii, Rust Cotton rust Puccinia schedonnardi, Sclerotium stem and root rot = southern blight Sclerotium rolfsii, Seedling disease complex Colletotrichum gossypii, Fusarium spp., Pythium spp., Rhizoctonia solani, Thielaviopsis basicola, Stem canker Phoma exigua, Verticillium wilt Verticillium dahliae. Diseases of Bean (Phaseolus vulgaris L.): Alternaria leaf and pod spot Alternaria alternate, Alternaria brassicae, Alternaria brassicicola, Angular leaf spot Phaeoisariopsis griseola, Anthracnose Colletotrichum lindemuthianum,Aphanomyces root and hypocotyl rot Aphanomyces euteiches, Ashy stem blight (charcoal rot) Macrophomina phaseolina, Black node disease (Ascochyta leaf spot) Phoma exigua= Ascochyta phaseolorum, Black root rot Thielaviopsis basicola, Cercospora leaf spot and blotch Pseudocercospora cruenta, Mycosphaerella cruenta, Cercospora canescens, Cercospora phaseoli, Cercospora caracallae, Chaetoseptoria leaf spot Chaetoseptoria wellmanii, Damping-off and stem rot, Rhizoctonia Rhizoctonia solani, Damping-off, Pythium spp., Diaporthe pod blight Diaporthe phaseolorum , Downy mildew Phytophthora nicotianae, Entyloma leaf smut Entyloma petunia, Floury leaf spot Mycovellosiella phaseoli, Fusarium root rot Fusarium solani, Gray leaf spot Cercospora vanderysti, Gray mold Botrytis cinerea, Botryotinia fuckeliana, Pink pod rot Trichothecium roseum, Powdery mildew Erysiphe polygoni, Rust Uromyces appendiculatus, Scab Elsinoe phaseoli, Soybean rust Phakopsora pachyrhizi {Asian Soybean Rust}. Diseases of Chickpea: Acrophialophora wilt Acrophialophora fusispora, Alternaria blight Alternaria alternate, Alternaria tenuissima, Aphanomyces root rot Aphanomyces euteiches, Ascochyta blight Ascochyta rabiei, Black root rot Fusarium solani, Black streak root rot Thielaviopsis basicola, Botrytis gray mold Botrytis cinerea , Collar rot Sclerotium rolfsii, Colletotrichum blight Colletotrichum capsici, Colletotrichum dematium, Cylindrocladium root rot Cylindrocladium clavatum, Downy mildew Peronospora sp., Dry root rot Macrophomina phaseolina, Fusarium root rot Fusarium acuminatum, Fusarium arthrosporioides, Fusarium avenaceum, Fusarium equiseti, Fusarium solani, Fusarium wilt Fusarium oxysporum, Neocosmospora root rot Neocosmospora vasinfecta, Phoma blight Phoma medicaginis, Phytophthora root rot Phytophthora citrophthora, Phytophthora cryptogea,Phytophthora drechslera, Phytophthora megasperma, Pleospora leaf spot Pleospora herbarum, Powdery mildewLeveillula taurica, Erysiphe sp., Rust Uromyces ciceris-arietini, Uromyces striatus, Sclerotinia stem rot Sclerotinia sclerotiorum, Sclerotinia trifoliorum, Scopulariopsis leaf spot Scopulariopsis brevicaulis, Seedling or seed rot Aspergillus flavus, Trichothecium roseum, Stemphylium blight Stemphylium sarciniforme, Verticillium wilt Verticillium albo-atrum, Verticillium dahliae, Wet root rot Rhizoctonia solani. Diseases of Lentil & Peas : Alternaria blight Alternaria alternate, Anthracnose Colletotrichum lindemuthianum, Colletotrichum truncatum, Aphanomyces root rot Aphanomyces euteiches, Ascochyta blight Ascochyta fabae, Black root rot Fusarium solani, Black streak root rot Thielaviopsis basicola, Botrytis gray mold Botrytis cinerea, Cercospora leaf spot Cercospora cruenta, Cercospora lensii, Cercospora zonata, Collar rot Sclerotium rolfsii, Cylindrosporium leaf spot and stem canker Cylindrosporium sp., Downy mildew Peronospora lentis, Peronospora viciae, Dry root rot Macrophomina phaseolina= Rhizoctonia bataticola, Fusarium wilt Fusarium oxysporum, Helminthosporium leaf spot Helminthosporium sp., Leaf rot Choanephora sp., Leaf yellowing Cladosporium herbarum, Phoma leaf spot Phoma medicaginis, Powdery mildew Erysiphe pisi= Erysiphe polygoni, Leveillula taurica= Leveillula leguminosarum, Pythium root and seedling rot Pythium aphanidermatum, Pythium ultimum, Rust Uromyces craccae, Uromyces viciae-fabae, Sclerotinia stem rot Sclerotinia sclerotiorum, Stemphylium blight Stemphylium botryosum, Stemphylium sarciniforme. Diseases of Pigeonpea : Alternaria blight Alternaria alternate, Alternaria tenuissima, Anthracnose Colletotrichum cajani, Colletotrichum truncatum, Armillaria root rot Armillaria mellea, Botryodiplodia blight Lasiodiplodia theobromae= Botryodiplodia theobromae, Botrytis gray mold Botrytis cinerea, Cercoseptoria leaf spot Cercoseptoria cajanicola, Cercospora leaf spot Mycovellosiella cajani= Cercospora cajani, Cercospora indica, Cercospora instabilis, Cercospora thirumalacharii, Cladosporium leaf blight Cladosporium oxysporum, Collar rot Sclerotium rolfsii= Corticium rolfsii, Colletotrichum stem canker Colletotrichum crassipes, Damping-off Pythium aphanidermatum, Dieback and stem canker Colletotrichum capsici, Diplodia stem canker Diplodia cajani, Dry root rot Macrophomina phaseolina, Fusarium leaf blight Fusarium pallidoroseum, Fusarium seedling rot Fusarium avenaceum, Fusarium equiseti, Fusarium wilt Fusarium udum, Halo blight Pseudomonas syringae, Macrophomina stem canker Macrophomina phaseolina, Myrothecium leaf spot Myrothecium gramineum, Periconia leaf spot Periconia byssoides, Phaeoisariopsis leaf spot Phaeoisariopsis griseola, Phoma stem canker Phoma cajani, Phyllosticta leaf spot Phyllosticta cajani, Phytophthora root rot and stem blight Phytophthora drechslera, Powdery mildew Leveillula taurica, Rust Uredo cajani, Sclerotinia stem rot Sclerotinia sclerotiorum, Seedling or seed rot Aspergillus flavus, Aspergillus niger, Wet root rot Rhizoctonia solani. Diseases of Sugarcane : Black rot Ceratocystis adipose, Black stripe Cercospora atrofiliformis, Brown spot Cercospora longipes, Downy mildew Peronosclerospora sacchari, Fusarium sett and stem rot Gibberella fujikuroi, Leaf blast Didymosphaeria taiwanensis, Leaf blight Leptosphaeria taiwanensis,Red leaf spot (purple spot) Dimeriella sacchari, Red rot Glomerella tucumanensis, Red rot of leaf sheath and sprout rot Athelia rolfsii, Rhizoctonia sheath and shoot rot Rhizoctonia solani, Rust, common Puccinia melanocephala, Seedling blight Alternaria alternate, Bipolaris sacchari, Cochliobolus hawaiiensis, Curvularia lunata, Setosphaeria rostrata, Drechslera halodes, Sheath rot Cytospora sacchari, Smut Ustilago scitaminea, Wilt Fusarium sacchari, Zonate leaf spot Gloeocercospora sorghi. Diseases of Carrot : Alternaria leaf blight Alternaria dauci, Black root rot Thielaviopsis basicola , Black rot (black carrot root dieback) Alternaria radicina=Stemphylium radicinum , Brown rot (Phoma disease) Leptosphaeria libanotis, Phoma rostrupii, Cavity spot Pythium spp., Pythium violae, Rhizoctonia spp., Cercospora leaf spot Cercospora carotae, Cottony rot Sclerotinia minor, Crown rot Rhizoctonia spp., Downy mildew Plasmopara crustosa, Leaf spot Ramularia spp., Powdery mildew Erysiphe heraclei, E. polygoni, E. umbelliferaum. Diseases of Cucurbits : Alternaria leaf blight Alternaria cucumerina, Alternaria leaf spot Alternaria alternata f. sp. Cucurbitae, Anthracnose (stem, leaf and fruit) Colletotrichum orbiculare, Belly rot Rhizoctonia solani, Black root rot Thielaviopsis basicola, Blue mold rot Penicillium spp., P. digitatum, Cephalosporium root and hypocotyl rot, stem streak and dieback Acremonium spp.= Cephalosporium spp., Cercospora leaf spot Cercospora citrullina, Charcoal rot (vine decline and fruit rot) Macrophomina phaseolina, Choanephora fruit rot Choanephora cucurbitarum, Crown and foot rot Fusarium solani, Damping-off Acremonium spp., Fusarium spp., F. equiseti, Phytophthora sp., Pythium spp., Rhizoctonia solani, Downy mildew Pseudoperonospora cubensis, Fusarium fruit rot Fusarium equiseti,Fusarium wilt Fusarium oxysporum, Gray mold Botrytis cinerea, Gummy stem blight (vine decline) Didymella bryoniae= Mycosphaerella melonis, Powdery mildew Sphaerotheca fuliginea, Erysiphe cichoracearum, Pythium fruit rot (cottony leak) Pythium spp., Rhizopus soft rot (fruit) Rhizopus stolonifer, Scab/gummosis Cladosporium cucumerinum, Sclerotinia stem rot Sclerotinia sclerotiorum, Septoria leaf blight Septoria cucurbitacearum, Sudden wilt Pythium aphanidermatum, Ulocladium leaf spot Ulocladium consortiale, Verticillium wilt Verticillium albo-atrum, V. dahliae, Web blight Rhizoctonia solani. Diseases of Onion and Garlic : Black mold Aspergillus niger, Blue mold Penicillium aurantiogriseum, = Penicillium cyclopium, Penicillium citrinum, Penicillium digitatum, Penicillium expansum, Penicillium hirsutum, Penicillium funiculosum, Penicillium oxalicum, Botrytis brown stain Botrytis cinerea, Botryotinia fuckeliana, Botrytis leaf blight Botrytis squamosa, Botrytis rot of garlic Botrytis porri , Botryotinia porri, Cercospora leaf spot Cercospora duddiae, Charcoal rot Macrophomina phaseolina =Sclerotium bataticola, Diplodia stain Lasiodiplodia theobromae = Diplodia natalensis= Botryodiplodia theobromae, Downy mildew Peronospora destructor, Flower and capsule blight Botrytis aclada, Botrytis allii, Botrytis squamosa, Botryotinia squamosa, Botrytis cinerea, Botryotinia fuckeliana, Fusarium basal rot Fusarium oxysporum,Fusarium bulb rot of onion and garlic Fusarium proliferatum, Fusarium damping-off Fusarium oxysporum, Fusarium verticillioides= Fusarium moniliforme, Fusarium subglutinans, Fusarium proliferatum= Cephalosporium proliferatum, Fusarium solani, Fusarium equiseti, Fusarium tricinctum, Leaf blotch Cladosporium allii-cepae, Mycosphaerella allii-cepae, Mushy rot Rhizopus microspores, Rhizopus stolonifer, Mycelial neck rot Botrytis byssoidea, Botryotinia allii, Neck rot Botrytis aclada, Botrytis allii, Penicillium decay of garlic Penicillium hirsutum, Pink root Phoma terrestris, Powdery mildew Leveillula taurica, Oidiopsis sicula Scalia, Purple blotch Alternaria porri, Pythium seed rot and damping-off Pythium irregulare, Pythium coloratum, Pythium graminicola, Pythium mamillatum, Pythium paroecandrum, Pythium rostratum, Pythium spinosum, Pythium sylvaticum , Pythium torulosum, Pythium ultimum, Pythium vexans, Rhizoctonia seed rot and seedling disease Rhizoctonia solani, Rust Puccinia allii, Scape blight Botrytis aclada, Botrytis allii, Botrytis porri, Botrytis squamosa, Sclerotinia rot Sclerotinia sclerotiorum, Smudge Colletotrichum circinans, Smut Urocystis colchici, Stemphylium leaf blight and stalk rot Stemphylium vesicarium, White rot Sclerotium cepivorum. Diseases of Pepper (Capsicum spp.) : Anthracnose Colletotrichum gloeosporioides, C. capsici, Glomerella cingulata, Cercospora (frogeye) leaf spot Cercospora capsici, Charcoal rot Macrophomina phaseolina, Choanephora blight (wet rot) Choanephora cucurbitarum, Damping-off and root rot Rhizoctonia solani, Phytophthora spp., Fusarium spp., Pythium spp., Downy mildew Peronospora tabacina, Fusarium stem rot Fusarium solani, Fusarium wilt Fusarium oxysporum f. sp. Capsici,Gray leaf spot Stemphylium solani, Gray mold Botrytis cinerea, Phytophthora blight Phytophthora capsici, Powdery mildew Oidiopsis sicula, Leveillula taurica, Southern blight Sclerotium rolfsii, Verticillium wilt erticillium dahliae, White mold Sclerotinia sclerotiorum. Diseases of Potato (Solanum tuberosum L.) : Brown spot and Black pit Alternaria alternate, Cercospora leaf blotch Mycovellosiella concors= Cercospora concors, Cercospora solani, Early blight Alternaria solani, Gray mold Botrytis cinerea, Late blight Phytophthora infestans, Phoma leaf spot Phoma andigena, Powdery mildew Erysiphe cichoracearum, Powdery scab Spongospora subterranean, Rhizoctonia canker and black scurf Rhizoctonia solani, Septoria leaf spot Septoria lycopersici, Silver scurf Helminthosporium solani, Verticillium wilt Verticillium albo-atrum. Diseases of Tomato (Solanum lycopersicum L.) : Alternaria stem canker Alternaria alternate f. sp. Lycopersici, , Anthracnose Colletotrichum coccodes, Black mold Alternaria alternate, Buckeye rot Phytophthora capsici, Charcoal rot Macrophomina phaseolina, Didymella stem rot Didymella lycopersici, Early blight Alternaria tomatophila, Fusarium foot rot Fusarium solani, Gray leaf spot Stemphylium botryosum f. sp. Lycopersici,Gray mold Botrytis cinerea, Gray mold rot (Botrytis fruit rot) Botrytis cinerea, Late blight Phytophthora infestans,Phoma rot Phoma destructiva var. destructive, Phytophthora root rot Phytophthora capsici, Powdery mildew, Leveillula taurica, Pythium damping-off and stem rot Pythium aphanidermatum, P. debaryanum, P. ultimum, Rhizoctonia damping-off, root rot, stem rot, sem canker, foliar blight, fruit rot Rhizoctonia solani, Septoria leaf spot Septoria lycopersici, Verticillium wilt Verticillium albo-atrum, V. dahliae, White mold Sclerotinia minor, S. sclerotiorum. Diseases of Apple : Alternaria blotch Alternaria mali, Alternaria rot Alternaria alternate, American brown rot Monilinia fructicola, Anthracnose canker and bull's-eye rot Cryptosporiopsis curvispora, Apple scab Venturia inaequalis, Apple ring rot and canker Botryosphaeria berengeriana, Armillaria root rot = shoestring root rot Armillaria mellea, Bitter rot Glomerella cingulata, Black pox Helminthosporium papulosum, Black root rot Xylaria mali, Black rot, frogeye leafspot and canker Botryosphaeria obtuse, Blister canker = nailhead canker Biscogniauxia marginata, Blue mold Penicillium spp., Brooks fruit spot Mycosphaerella pomi, Brown rot blossom blight and spur infection Monilinia laxa, (Aderhold & Ruhland) Honey, Clitocybe root rot Armillaria tabescens = Clitocybe tabescens, Diaporthe canker Diaporthe tanakae, Phomopsis tanakae, Diplodia canker Botryosphaeria stevensii, Diplodia mutila, Fruit blotch, leaf spot and twig canker Phyllosticta solitaria, Glomerella leaf spot Glomerella cingulata, Colletotrichum gloeosporioides, Gray mold rot = dry eye rot, blossom-end rot Botrytis cinerea, Leptosphaeria canker and fruit rot Diapleella coniothyrium = Leptosphaeria coniothyrium, Leucostoma canker and dieback Leucostoma cincta, Cytospora cincta, Marssonina blotch Diplocarpon mali, Marssonina coronaria, Moldy core and core rot Alternaria spp., Cladosporium spp., Coniothyrium sp., Epicoccum spp., Pleospora herbarum, Stemphylium spp., Ulocladium spp., Monilia leaf blight Monilinia mali, Monochaetia twig canker Seiridium unicorne =Monochaetia mali, Perennial canker Neofabrae perennans, Cryptosporiopsis perennans, Phomopsis canker, fruit decay and rough bark Phomopsis mali, Phymatotrichum root rot = cotton root rot Phymatotrichopsis omnivore, Phytophthora crown, collar and root rot = sprinkler rot Phytophthora spp., Pink mold rot Trichothecium roseum = Cephalothecium roseum, Powdery mildew Podosphaera leucotricha. Diseases of Banana : Anthracnose Colletotrichum musae, Armillaria corn rot Armillaria mellea,Black leaf streak (black Sigatoka) Mycosphaerella fijiensis, Black root rot Rosellinia bunodes, Brown spot Cercospora hayi, Ceratocystis fruit rot Ceratocystis paradoxa, Cigar-end Verticillium theobromae, Crown rot Fusarium pallidoroseum, Colletotrichum musae, Verticillium theobromae, Fusarium spp., Cylindrocladium root rot Cylindrocladium spp., Eyespot Dreschslera gigantean, Fruit rot Botryosphaeria ribis, Fungal root-rot Fusarium solani, Fusarium wilt (Panama disease) Fusarium oxysporum, Leaf spot Curvularia eragrostidis, Drechslera musae-sapientum, Leptosphaeria musarum, Pestalotiopsis disseminate, Ceratocystis paradoxa, Sigatoka (yellow Sigatoka) Mycosphaerella musicola. Diseases of Citrus (Citrus spp.) : Alternaria brown spot Alternaria alternate, Anthracnose = wither-tip Glomerella cingulata, Colletotrichum gloeosporioides, Black mold rot Aspergillus niger, Botrytis blossom and twig blight, gummosis Botrytis cinerea, Brown rot (fruit) Phytophthora citricola, P. citrophthora, Diplodia gummosis and stem-end rot Lasiodiplodia theobromae = Botryodiplodia theobromae, Leaf spot Mycosphaerella horii, Phytophthora foot rot, gummosis and root rot Phytophthora citrophthora. Diseases of Grape (Vitis spp.) : Alternaria rot Alternaria alternate, Anthracnose and bird's-eye rot Elsinoe ampelina (anamorph: Sphaceloma ampelinum), Berry rots and raisin molds Ascochyta sp., Aspergillus aculeatus, Aspergillus spp.,Cladosporium spp., Fusarium spp., Helminthosporium spp., Monilia sp., Stemphylium botryosum, Botrytis bunch rot and blight (Gray mold) Botrytis cinerea (teleomorph: Botryotinia fuckeliana) Cercospora leaf spot (cercosporiose) Phaeoramularia dissiliens = Cercospora sp., Diplodia cane dieback and bunch rot (Cane-tip blight) Lasiodiplodia theobromae =Diplodia natalensis, Downy mildew Plasmopara viticola, Powdery mildew Uncinula necator, Wood rot (decay) Cephalosporium spp., Phellinus igniarius, Stereum hirsutum. Diseases of Mango (Mangifera indica L.) : Alternaria leaf spots Alternaria alternate, Anthracnose Colletotrichum gloeosporioides, Black mold rot Aspergillus niger, Black rot Ceratocystis paradoxa, Blossom blight Botrytis cinerea, Branch canker Botryosphaeria ribis, Fusicoccum sp., Ceratocystis wilt Ceratocystis fimbriata, Dieback Botryosphaeria disrupta, Fruit rot Alternaria alternate, Phytophthora nicotianae, Leaf blight Bipolaris hawaiiensis, Leaf spot Curvularia lunata, Leptosphaeria sp., Macrophoma sp., Phaeosphaerella mangiferae, Phoma sorghina, Pseudocercospora mali, Septoria sp., Verticillium lecanii. Mango malformation Fusarium subglutinans, Powdery mildew Erysiphe cichoracearum, Stem canker Phoma sp., Stem end rot Botryosphaeria rhodina, Twig blight Diaporthe spp. Diseases of Papaya : Alternaria fruit spot Alternaria alternate, Angular leaf spot Leveillula taurica, Anthracnose Colletotrichum gloeosporioides, Black spot Asperisporium caricae, Cercospora papaya, Brown spot Corynespora cassiicola, Collar rot Cylindrocladium crotalariae, Damping off/ Root rot Colletotrichum gloeosporioides, Phytophthora palmivora, Pythium aphanidermatum,Pythium debaryanum, Rhizoctonia solani, Dry rot Phoma caricae-papayae, Fruit rot Monilia sp., Fruit spot Cercospora mamaonis, Fusarium fruit rot Fusarium solani, Greasy spot Corynespora cassiicola, Leaf spot Alternaria sp., Cercospora mamaonis, Choanephora cucurbitarum, Curvularia carica-papayae, Powdery mildew Erysiphe cichoracearum, Oidium caricae, Rhizopus soft rot Rhizopus stolonifer.
The present invention relates to agrochemical compositions which comprise of bioactive amounts of anthranilamide insecticide, and fungicide wherein anthranilamide insecticide may be selected from Chlorantraniliprole or Flubendiamide and at least one fungicide may be selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl.

Further the present invention also relates to process for preparing the agrochemical compositions comprising of bioactive amounts of anthranilamide insecticide, and fungicide and optionally at least one agrochemically acceptable excipient.

For use according to the present invention, the mixtures according to the invention, or a compound I and an active compound II, can be converted into the customary formulations, for example solutions, emulsions, suspensions, dusts, powders, pastes and granules. The use form depends on the particular intended purpose; in each case, it should ensure a fine and even distribution of the compound according to the invention.

The formulations are prepared in a known manner, for example by extending the active compound with solvents and/or carriers, if desired using emulsifiers and dispersants. Solvents/auxiliaries which are suitable are essentially:

Suitable solvents arewater, aromatic solvents xylene, paraffins alcohols (for example methanol, butanol, pentanol, benzyl alcohol), ketones (for example cyclohexanone, gamma-butyrolactone), pyrrolidones (NMP, NOP), acetates (glycol diacetate), glycols, fatty acid dimethyl-amides, fatty acids and fatty acid esters. In principle, solvent mixtures may also be used,

Suitable carriers such as ground natural minerals (for example kaolins, clays, talc, chalk) and ground synthetic minerals (for example highly disperse silica, silicates); Suitable emulsifiers such as nonionic and anionic emulsifiers (for example polyoxyethylene fatty alcohol ethers, alkylsulfonates and arylsulfonates) and dispersants such as lignosulfite waste liquors and methylcellulose.

Suitable surfactants are alkali metal, alkaline earth metal and ammonium salts of lignosulfonic acid, naphthalenesulfonic acid, phenolsulfonic acid, dibutylnaphthalenesulfonic acid, alkylarylsulfonates, alkyl sulfates, alkylsulfonates, fatty alcohol sulfates, fatty acids and sulfated fatty alcohol glycol ethers, furthermore condensates of sulfonated naphthalene and naphthalene derivatives with formaldehyde, condensates of naphthalene or of naphthalenesulfonic acid with phenol and formaldehyde, polyoxyethyleneoctylphenol ethers, ethoxylatedisooctylphenol, octylphenol, nonylphenol, alkylphenolpolyglycol ethers, tributylphenylpolyglycol ethers, tristearylphenylpolyglycol ethers, alkylaryl polyether alcohols, alcohol and fatty alcohol ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers, ethoxylatedpolyoxypropylene, lauryl alcohol polyglycol ether acetal, sorbitol esters, lignosulfite waste liquors and methylcellulose.

Suitable for the preparation of directly sprayable solutions, emulsions, pastes or oil dispersions are mineral oil fractions of medium to high boiling point, such as kerosene or diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalenes or their derivatives, methanol, ethanol, propanol, butanol, cyclohexanol, cyclohexanone, isophorone, strongly polar solvents, for example dimethyl sulfoxide, N-methylpyrrolidone and water.

Also anti-freezing agents such as glycerin, ethylene glycol, propylene glycol and bactericides such as can be added to the formulation.

Suitable antifoaming agents are for example antifoaming agents based on silicon or magnesium stearate.

Suitable preservatives are for example Dichlorophen and enzylalkoholhemiformal. Seed Treatment formulations may additionally comprise binders and optionally colorants.

Binders can be added to improve the adhesion of the active materials on the seeds after treatment. Suitable binders are block copolymers EO/PO surfactants but also polyvinylalcoholsl, polyvinylpyrrolidones, polyacrylates, polymethacrylates, polybutenes, polyisoutylenes, polystyrene, polyethyleneamines, polyethyleneamides, polyethyleneimines (Lupasol®, Polymin®), polyethers, polyurethans, polyvinylacetate, tylose and copolymers derived from these polymers.

Optionally, also colorants can be included in the formulation. Suitable colorants or dyes for seed treatment formulations are Rhodamin B, C.I. Pigment Red 112, C.I. Solvent Red 1, pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue 15:1, pigment blue 80, pigment yellow 1, pigment yellow 13, pigment red 112, pigment red 48:2, pigment red 48:1, pigment red 57:1, pigment red 53:1, pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51, acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108.

"Bioactive amounts” as mentioned herein means that amount which, when applied treatment of crops, is sufficient to effect such treatment.

The Synergistic composition of anthranilamide insecticide, and fungicide wherein anthranilamide insecticide may be selected from Chlorantraniliprole or Flubendiamide and at least one fungicide may be selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl are, WP – Wettable powders: A solid pesticide formulation – micronized to powder form and typically applied as suspended particles after dispersion in water. WG or WDG – Water dispersible granule: A pesticidal formulation consisting of granules to be applied after disintegration and dispersion in water. Water dispersible granules can be formed by a) agglomeration, b) spray drying, or c) extrusion techniques. It can also be termed as water soluble granules (WSG) or soluble granules (SG). Liquid Sprayable (LS) – Soluble Concentrate: A soluble concentrate is in powder form intended for dilution with water or directly in solution from. In both the case, the end result will be clear solution of the insecticide in the water without any visible un-dissolved particles. SC – Suspension Concentrate: A stable suspension of solid pesticide(s) in a fluid usually intended for dilution with water before use. For a good formulation or ideal SC formulation, it should be stable and do not sediment over time. EC – Emulsifiable Concentrate: A solution of a pesticide with emulsifying agents in a water insoluble organic solvent which will form an emulsion when added to water. In most of the case it is oil in water type emulsion to make it easy for application. EC formulation should be storage stable without any visible cracking of emulsion. ME – Microemulsion: A solution of a pesticide with emulsifying agents in a water insoluble organic solvent which will form a solution/emulsion when added to water. The difference between EC and ME is the particle size of the actives in the final form. OD – Oil Dispersion: Oil dispersions (OD) are one type of liquid formulation which is stable suspensions of active ingredients in a water-immiscible fluid which may contain other dissolved active ingredients and is intended for dilution with water before use. CS – Capsule Suspension: Suspension of micro-encapsulated active ingredient in an aqueous continuous phase, intended for dilution with water before use. SE- Suspension emulsion: A suspension emulsion or suspo emulsion (SE) consists of an organic phase with a dissolved active ingredient and an aqueous suspension phase, in which the active ingredient is dispersed in water. Dispersible concentrate (DC): Dispersible concentrate (DC) is a liquid homogeneous formulation to be applied as a solid dispersion after dilution in water. There are many formulations which contains the part characteristics of EC and part characteristics of DC. Dry – Spreadable Granule: Dry spreadable granules are dry granules which can be applied with a dry spreader to a target area and later when such granules get exposed to water via, for example, rain or irrigation, will not only readily disintegrate, but actively spread on solid substrates so as to achieve disintegration area diameter to original granule diameter ratios. Dry spreadable granules should possess good hardness and an ability to maintain integrity upon normal, commercial handling in a dry spreading operation and yet be capable of quickly disintegrating or scattering upon what may be a minimal exposure to water, such as, for example, a light rain. GR – Soil applied Granule on inert or fertilizer carrier: This formulation is in the form of granules which can be applied on inert carrier or the carrier which is fertilizer. ZC Formulation (Mix of CS and SC): “ZC formulation” is the international denominations adopted by the FAO (Food and Agricultural Organization of the United Nations) to designate "stable aqueous suspension of microcapsules and solid fine particles". ZC is a mixed formulation of CS and SC and is a stable aqueous suspension of microcapsules and solid fine particles, each of which contains one or more active ingredients. The formulation is intended for dilution into water prior to spray application. Formulating the active ingredients together eliminates the need for tank mixing, which can lead to incompatibility, and facilitates control of a wider range of pests with fewer applications. Like other aqueous liquid formulations, ZC formulations are easy to handle and measure, dust free, non-flammable and offer good miscibility with water.

Formulations of the present invention can be in any of the form selected from Suspension Concentrate (SC), Emulsifiable Concentrate (EC), Wettable powder (WP), Soluble powder (SP) and Water dispersible granules (WDG).

Compositions comprising of bioactive amounts of anthranilamide insecticide, and fungicide wherein anthranilamide insecticide may be selected from Chlorantraniliprole or Flubendiamide and at least one fungicide may be selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl and at least one agrochemically acceptable excipient. According to the present invention, the ratio composition Anthranilamide insecticide to fungicide is 1: 15 to 5: 1.

The agrochemical composition of the present invention in addition to anthranilamide insecticide, and fungicide may also have optoionally at least one agrochemically acceptable excipient including but not limited to dispersant, anti-freezing agent, anti-foam agent,wetting agent, suspension aid,anti-microbial agent, thickener, quick coating agent or sticking agents (also referred to as “stickers” or “binders”) and buffering agent.

Dispersants are added to agrochemical compositions to facilitate dispersion and suspension during manufacture, and to ensure the particles re-disperse into water in a spray tank. They are widely used in wettable powders, suspension concentrates and water-dispersible granules. Surfactants that are used as dispersants have the ability to adsorb strongly onto a particle surface and provide a charged or steric barrier to re-aggregation of particles. The most commonly used surfactants are anionic, non-ionic, or mixtures of the two types. For wettable powder compositions, the most common dispersants are sodium lignosulphonates. For suspension concentrates, very good adsorption and stabilization are obtained using polyelectrolytes, such as sodium naphthalene sulphonate formaldehyde condensates. Tristyrylphenolethoxylate phosphate esters are also used. Nonionics such as alkylarylethylene oxide condensates and EO-PO block copolymers are sometimes combined with anionics as dispersants for suspension concentrates. In recent years, new types of very high molecular weight polymeric surfactants have been developed as dispersants. These have very long hydrophobic ‘backbones’ and a large number of ethylene oxide chains forming the ‘teeth’ of a ‘comb’ surfactant. These high molecular weight polymers can give very good long-term stability to suspension concentrates because the hydrophobic backbones have many anchoring points onto the particle surfaces. Examples of dispersants used herein include but not limited to sodium lignosulphonates; sodium naphthalene sulphonate formaldehyde condensates; tristyrylphenolethoxylate phosphate esters; aliphatic alcohol ethoxylates; alky ethoxylates; EO-PO block copolymers; and graft copolymers or mixtures thereof.

Anti-freezing agent as used herein can be selected from the group consisting of polyethylene glycols, methoxypolyethylene glycols, polypropylene glycols, polybutylene glycols, glycerin and ethylene glycol.

Water-based compositions often cause foam during mixing operations in production. In order to reduce the tendency to foam, anti-foam agents are often added either during the production stage or before filling into bottles. Generally, there are two types of anti-foam agents, namely silicones and non-silicones. Silicones are usually aqueous emulsions of dimethyl polysiloxane while the non-silicone anti-foam agents are water-insoluble oils, such as octanol and nonanol, or silica. In both cases, the function of the anti-foam agent is to displace the surfactant from the air-water interface.

Examples of wetting agents used in wettable powder, suspension concentrate, and water-dispersible granule compositions include but not limited to sodium lauryl sulphate; sodium dioctylsulphosuccinate; alkyl phenol ethoxylates; and aliphatic alcohol ethoxylates or mixtures thereof.

Suspension aid in the present description denotes a natural or synthetic, organic or inorganic material with which the active substance is combined in order to facilitate its application to the plant, to the seeds or to the soil. This carrier is hence generally inert, and it must be agriculturally acceptable, in particular to the plant being treated. The carrier may be solid (clays, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, and the like or mixtures thereof) or liquid (water, alcohols, ketones, petroleum fractions, aromatic or paraffinic hydrocarbons, chlorinated hydrocarbons, liquefied gases, and the like or mixtures thereof).

Biocides / Microorganisms cause spoilage of formulated products. Therefore anti-microbial agents are used to eliminate or reduce their effect. Examples of such agents include, but are not limited to: propionic acid and its sodium salt; sorbic acid and its sodium or potassium salts; benzoic acid and its sodium salt; p-hydroxy benzoic acid sodium salt; methyl p-hydroxy benzoate; and biocide such as sodium benzoate, 1,2-benzisothiazoline-3-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, potassium sorbate, parahydroxy benzoates or mixtures thereof.

Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers. It is possible to produce suspension concentrate compositions using clays and silicas. Examples of these types of materials, include, but are limited to, montmorillonite, e.g. bentonite; magnesium aluminum silicate; and attapulgite. Water-soluble polysaccharides have been used as thickening-gelling agents for many years. The types of polysaccharides most commonly used are natural extracts of seeds and seaweeds are synthetic derivatives of cellulose or mixtures thereof. Examples of these types of materials include, but are not limited to, guar gum; locust bean gum; carrageenam; xanthan gum; alginates; methyl cellulose; sodium carboxymethyl cellulose (SCMC); hydroxyethyl cellulose (HEC) or mixtures thereof. Other types of anti-settling agents are based on modified starches, polyacrylates, polyvinyl alcohol and polyethylene oxide or mixtures.

The quick coating agentcan be a conventionally available sticker, for example polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylate polymers and copolymers, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol, vinylacetate and vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins and define copolymersand mixtures thereof. Examples of preferred polymers are acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these. Polymers that are biodegradable are also useful in the present invention. As used herein, a polymer is biodegradable if is not water soluble, but is degraded over a period of several weeks when placed in an application environment. Examples of biodegradable polymers that are useful in the present invention include biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof.

Buffering agent as used herein is selected from group consisting of calcium hydroxyapatite, Potasium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.

The solvent for the composition of the present invention may include water, water-soluble alcohols and dihydroxy alcohol ethers. The water-soluble alcohol which can be used in the present invention may be lower alcohols or water-soluble macromolecular alcohols. The term "lower alcohol", as used herein, represents an alcohol having 1-4 carbon atoms, such as methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol, etc. Macromolecular alcohol is not limited, as long as it may be dissolved in water in a suitable amount range, e.g., polyethylene glycol, sorbitol, glucitol, etc. The examples of suitable dihydroxy alcohol ethers used in the present invention may be dihydroxy alcohol alkyl ethers or dihydroxy alcohol aryl ethers. The examples of dihydroxy alcohol alkyl ether include ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, dipropylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, dipropylene glycol ethyl ether, etc. The examples of dihydroxy alcohol aryl ethers include ethylene glycol phenyl ether, diethylene glycol phenyl ether, propylene glycol phenyl ether, dipropylene glycol phenyl ether, and the like. Any of the above mentioned solvent can be used either alone or in combination thereof.

The wettable dry granules (WDG) can be applied after disintegration and dispersion in water. Water dispersible granules can be formed by a) agglomeration, b) spray drying, or c) extrusion techniques.

WDG compositions offer a number of advantages in packaging, ease of handling and safety. The WDG are preferably of uniform size and which are free flowing, low dusting and readily disperse in water to form a homogenous solution of very small particles which may pass through conventional spray nozzles. Ideally WDG compositions when dispersed in water under gentle agitation for five minutes have residues of less than 0.01% on a 150 µm sieve screen and less than 0.5% on a 53 µm screen. The granules can usually be measured accurately by volume which is convenient for the end user.

Wettable powders can be prepared by dissolving insecticide in sufficient solvent with or without heating to give a solution and spraying the resulting solution onto a solid carrier or diluent. Alternatively insecticides which are solid and of a friable nature may be blended and ground with mineral diluents. The carriers generally used for wettable powders are sorbent inorganic materials commonly of mineral origin such as the kaolinites, montmorillonites, attapulgites, diatomaceous earths and vermiculites. Diluents generally used in toxicant formulations are such inert solids as talc, pyrophyllite, frianite, pumice and as per the knowledge of a person skilled in the art.

Oil dispersion (OD) formulation can be prepared by below mentioned general process; The organic solvent is charged into a vessel and the clay or silica type rheology modifier is added into the vessel with high shear mixing to allow complete wetting of the rheology modifier. The insecticide, safener, dispersants, and emulsifier may then be added to the vessel under shearing conditions until the formation of uniform oil dispersion is achieved. The polymer or oligomer capable of hydrogen bonding may be introduced into the oil dispersion at a point where the desired thickening effect is achieved.

The SC composition can be prepared by below described method;
STEP-I: Adding anti-microbial agentand gum in water under continuous stirring followed by slow addition. Continuing stirring until homogeneous dispersion is formed.

STEP-II: Mixing anti-freezing agent, dispersant, wetting agent, anti-microbial agentand anti-foaming agent in water for 30 minute until homogeneous solution is formed. Finally add anthranilamide insecticide, and fungicide wherein anthranilamide insecticide may be selected from Chlorantraniliprole or Flubendiamide and fungicide may be selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl and at least one agrochemically acceptable excipient which is added slowly under continuous stirring at 30 minute till homogeneous dispersion is obtained. Milling the slurry through bead mill until required particle size is achieved.

Step-III: Adding rest of water, anti-foaming agent and gum solutionunder continuous stirring to get desired viscosity of the suspension. Continue stirring for about 4 hr to obtain homogeneous composition.

Emulsifiable concentrate (EC) formulations are a blend of insecticide, organic solvent, and surfactants. When the solution is diluted into water, a spontaneous milky emulsion forms with dispersed phase droplets. When sprayed, this dilute emulsion gives a uniform and accurate application of insecticide on the crop, which is essential for effective pest control. The formulation of the insecticide into an Emulsifiable Concentrate can ensure uniform spreading and wetting under normal spray and weather conditions.

ZC is a mixed formulation of CS and SC and is a stable aqueous suspension of microcapsules and solid fine particles, each of which contains anthranilamide insecticide, and fungicide wherein anthranilamide insecticide may be selected from Chlorantraniliprole and Flubendiamide and fungicide may be selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl and at least one agrochemically acceptable excipient. The formulation is intended for dilution into water prior to spray application. Formulating the active ingredients together eliminates the need for tank mixing, which can lead to incompatibility, and facilitates control of a wider range of pests with fewer applications. Like other aqueous liquid formulations, ZC formulations are easy to handle and measure, dust free, non-flammable and offer good miscibility with water. Anthranilamide insecticide, and fungicide wherein anthranilamide insecticide may be selected from Chlorantraniliprole or Flubendiamide and at least one fungicide may be selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl is encapsulated for various purposes, such as to increase the residual biological activity, or to reduce the acute toxicity, or to obtain a physical or chemically stable water-based formulation. The purpose determines whether the “free” active ingredient and the “release rate” are relevant properties of a specific product.

The above invention can be illustrated with suitable working examples and can be modified accordingly by any person skilled in the art based on the knowledge of the manufacturing the composition. However all such variation and modification is still covered by the scope of present invention.

EXAMPLES
Example 1: Chlorantraniliprole 3% and Propiconazole 10% SE (Suspo Emulsion)
Composition %
1 Chlorantraniliprole (95%) 3.70
2 Propiconazole (95%) 11.00
3 n-Octanol 11.00
4 Copolymer butanol EO/PO 2.00
5 Tristrylphenol with 16 moles EO 2.00
6 Tristrylphenol polyethoxyester phosphate 1.50
7 Acrylic graft copolymer 1.00
8 Polydimethyl siloxane 0.50
9 1,2-benzisothiazol-3-one 0.10
10 Naphthalene sulfonic acid,sodium salt condensate with formaldehyde 0.50
11 Xanthan Gum 0.10
12 DL-propanediol-(1,2) 5.00
13 Water 61.60
TOTAL 100.00
Procedure:
Step 1 Gum Solution should be made 12-18 hour prior to use. Take required quantity of water, biocide, and defoamer and homogenise, then slowly add gum powder to it and stir till complete dissolution.
Step 2 Oil phase is made by mixing required quantity of oil soluble emulsifier in required quantity of N-Octanol and technical
Step 3 Simultaneously make aqueous phase by mixing surfactants, antifreeze, antifoam, filler/ suspending agent in water. Once homogenise add technical (water insoluble) to this solution and form a slurry using high shear homogeniser for 60 minutes and then milled through Sand Mill
Step 4 Once both phases are ready add Oil phase to aqueous phase slowly under high shear homogenization.
Step 5 After complete addition stir the mixture for 60 more minutes under high shear stirring.
Step 6 Upon approval for particle form lab, gum solution was addded and final sample is provided to QC for approval.
Step 7 After approval material is packed in requied pack sizes.

Example 2: Flubendiamide 6% + Propiconazole 10% SE (Suspo Emulsion)
Composition %
1 Flubendiamide (95%) 6.80
2 Propiconazole (95%) 11.00
3 n-Octanol 11.00
4 Copolymer butanol EO/PO 2.00
5 Tristrylphenol with 16 moles EO 2.00
6 Tristrylphenol polyethoxyester phosphate 1.50
7 Acrylic graft copolymer 1.00
8 Polydimethyl siloxane 0.50
9 1,2-benzisothiazol-3-one 0.10
10 Naphthalene sulfonic acid,sodium salt condensate with formaldehyde 0.50
11 Xanthan Gum 0.10
12 DL-propanediol-(1,2) 5.00
13 Water 58.50
TOTAL 100.00

Procedure: Similar to the process as per Example 1.

Example 3: Chlorantraniliprole 6% + Tebuconazole 25% SE (Suspo Emulsion)
Composition %
1 Chlorantraniliprole (95%) 6.80
2 Tebuconazole (95%) 26.80
3 Soyabean Oil 10.00
4 Copolymer butanol EO/PO 2.00
5 Tristrylphenol with 16 moles EO 2.00
6 Tristrylphenol polyethoxyester phosphate 1.50
7 Acrylic graft copolymer 1.00
8 Polydimethyl siloxane 0.50
9 1,2-benzisothiazol-3-one 0.10
10 Naphthalene sulfonic acid,sodium salt condensate with formaldehyde 0.50
11 Xanthan Gum 0.10
12 DL-propanediol-(1,2) 5.00
13 Water 43.70
TOTAL 100.00

Procedure: Similar to the process as per Example 1.

Example 4: Chlorantraniliprole 3% + Propiconazole 10% SC (Suspension Concentrate)
Composition %
1 Chlorantraniliprole (95%) 3.70
2 Propiconazole (95%) 11.00
3 Acrylic graft copolymer 3.00
4 Block copolymer on butanol 4.00
6 Lignosulfonic acid, ethoxylated, sodium salts 1.00
5 Silicone antifoam 0.50
6 Benzisothiazoline 0.10
7 Glycol 5.00
8 Polysaccharides 0.10
9 DM water 71.60
TOTAL 100.00

Step 1 Gum Solution should be made 12-18 hour prior to use. Take required quantity of water, biocide, and defoamer and homogenise, then slowly add gum powder to it and stir till complete dissolution.
Step 2 Charge required quantity of DM water need to be taken in designated vessel for Flowable concentrate/ Suspension concentrate/ Flowable slurry production.
Step 3 Add required quantity of Wetting agent, dispersing agent & suspending agents, colourant/deye and homogenise the contents for 45 – 60 minutes using high shear homogeniser.
Step 4 Then add technical and other remaining adjuvants excluding ‘antifreeze & thickeners’ are added to it and homogenised to get uniform slurry ready for grinding.
Step 5 Before grinding half the quantity of antifoam was added and then material was subjected to three cycles of grinding in Dyno mill.
Step 6 Half quantity of the antifoam was added along with antifreeze after grinding process completes and before sampling for in process analysis.
Step 7 Finally add gum solution to this formulation and dend to QC for quality check

Example 5 to 19: Suspension Concentrate of below combinations can be prepared as per process of example 4:
SC (Suspension Concentrate) Active compound %
Example 5 Flubendiamide (95%) 6.80
Propiconazole (95%) 11.00
Example 6 Chlorantraniliprole (95%) 6.80
Tebuconazole (95%) 26.80
Example 7 Flubendiamide (95%) 13.10
Tebuconazole (95%) 26.80
Example 8 Chlorantraniliprole (95%) 3.70
Tricyclazole (95%) 32.10
Example 9 Flubendiamide (95%) 6.80
Tricyclazole (95%) 32.10
Example 10 Chlorantraniliprole (95%) 13.15
Hexaconazole (95%) 21.60
Example 11 Flubendiamide (95%) 13.15
Hexaconazole (95%) 11.00
Example 12 Chlorantraniliprole (95%) 6.80
Trifloxystrobin (95%) 26.80
Example 13 Flubendiamide (95%) 13.15
Trifloxystrobin (95%) 26.80
Example 14 Chlorantraniliprole (95%) 6.80
Metaminostrobin (95%) 26.80
Example 15 Flubendiamide (95%) 13.15
Metaminostrobin (95%) 26.80
Example 16 Chlorantraniliprole (95%) 6.80
Thifluzamide (95%) 21.60
Example 17 Flubendiamide (95%) 13.15
Thifluzamide (95%) 21.60
Example 18 Chlorantraniliprole (95%) 3.15
Thiophenate Methyl (95%) 42.60
Example 19 Flubendiamide (95%) 5.60
Thiophenate Methyl (95%) 42.60

Example 20: Chlorantraniliprole 12% + Tebuconazole 50% WG (Water Dispersible Granules)
Composition %
1 Chlorantraniliprole (95%) 13.15
2 Tebuconazole (95%) 53.15
3 Sodium Polycarboxylate 7.00
4 Sodium Lauryl Sulfate 3.00
5 Sodium alkyl naphthalene sulfonate blend 3.00
6 Sodium alkylnaphthalenesulfonate, formaldehyde condensate 2.00
7 Silicone based antifoam 0.50
8 Starch 5.00
9 Lactose anhydrous 13.20
TOTAL 100.00

Procedure:
Step 1 Charge the required quantity of filler, wetting agent, dispersing agent, and suspending agent, & technical in premixing blender for homogenization for 30 minutes.
Step 2 Pre-blended material is than grinded through Jet mill/ air classifier mills. Finely grinded material is blended in post blender till it becomes homogeneous. (for approx 1.5 hr)
Step 3 Homogeneous material is analysed. After getting approval from QC dept. material is unloaded into 25 kg. HDPE bag with LDPE liner inside.
Step 4 Finely grinded powder is mixer with required quantity of water to form extrudable dough.
Step 5 Dough is passed through extruder to get granules of required size.
Step 6 Wet granuleas are passed through Fluidised bed drier and further graded using vibrating screens.
Step 7 Final product is sent for QC approval.
Step 8 After approval material is packed in requied pack sizes.

Water Dispersible Granules of below combinations can similarly be prepared as per example 20.
WG (Water Dispersible Granules) Active compound %
Example 21 Flubendiamide (95%) 25.80
Tebuconazole (95%) 53.15
Example 22 Chlorantraniliprole (95%) 6.80
Tricyclazole (95%) 63.70
Example 23 Flubendiamide (95%) 13.15
Tricyclazole (95%) 63.70
Example 24 Chlorantraniliprole (95%) 25.80
Hexaconazole (95%) 42.60
Example 25 Flubendiamide (95%) 25.80
Hexaconazole (95%) 21.60
Example 26 Chlorantraniliprole (95%) 13.15
Trifloxystrobin (95%) 53.15
Example 27 Flubendiamide (95%) 25.80
Trifloxystrobin (95%) 53.15
Example 28 Chlorantraniliprole (95%) 13.15
Metaminostrobin (95%) 53.15
Example 29 Flubendiamide (95%) 25.80
Metaminostrobin (95%) 53.15
Example 30 Chlorantraniliprole (95%) 13.15
Thifluzamide (95%) 42.60
Example 31 Flubendiamide (95%) 25.80
Thifluzamide (95%) 42.60
Example 32 Chlorantraniliprole (95%) 4.50
Thiophenate Methyl (95%) 66.30
Example 33 Flubendiamide (95%) 8.40
Thiophenate Methyl (95%) 66.30

EXAMPLE 34: STORAGE STABILITY DATA
Comparison of the stability of formulations
The stability of each of the fromulation of Example 1 to Example 33 were tested for 1 month to 24 months stability at room temperature and at elevated temperature study under the following conditions: Heat stability study at 54 + 2 0C for 14 days and Cold storage stability at 0 + 2 0C for 14 days. The required parameters studied are active content, pH, Persistent Foaming, Suspensibility, Pourability and Viscosity was studied Respective amounts were measured using different instruments and parametes. The results are shown in the Table below of Examples 1 to 33. The results were found satisfactory and this formulation is passing in all physicochemical properties.
Storage stability study of formulation of Example 1 to Example 33
Specification Initial Heat stability study at 54 + 2 0C for 14 days Cold storage stability at 0 + 2 0C for 14 days
Parameters In House
Description Off-white to Beige liquid Complies Complies Complies
Active Component 1 Content Complies Complies Complies
Active Component 1 Suspensibility Mini 80% Complies Complies Complies
Active Component 1 Content Complies Complies Complies
Active Component 2 Suspensibility Mini 80% Complies Complies Complies
pH 5.0-9.0 Complies Complies Complies
Particle size D50 <3, D90 <10 Complies Complies Complies
Pourability 95 % min Complies Complies Complies
Specific gravity 1.05 – 1.15 Complies Complies Complies
Viscosity 350 -900 cps Complies Complies Complies

Room temperature storage data of the formulation of Example 1 to Example 33
Specification Study Duration
Parameters In House 1 month 3 month 6 month 9 months 12 months 18 months 24 months
Description Off-white to Beige liquid Com* Com* Com* Com* Com* Com* Com*
Active Component 1 Content Com* Com* Com* Com* Com* Com* Com*
Active Component 1 Suspensibility Mini 80% Com* Com* Com* Com* Com* Com* Com*
Active Component 2 Content Com* Com* Com* Com* Com* Com* Com*
Active Component 2 Suspensibility Mini 80% Com* Com* Com* Com* Com* Com* Com*
pH 5.0-9.0 Com* Com* Com* Com* Com* Com* Com*
Particle size D50 <3, D90 <10 Com* Com* Com* Com* Com* Com* Com*
Pourability 95 % min Com* Com* Com* Com* Com* Com* Com*
Specific gravity 1.05 – 1.15 Com* Com* Com* Com* Com* Com* 1.1
Viscosity 350 -900 cps Com* Com* Com* Com* Com* Com* 510
[Note Comp* =Complies]
The synergistic pesticidal action of the inventive mixtures can be demonstrated by the experiments below. A synergistic effect exists wherever the action of a combination (ready-mix) of active ingredient is greater than the sum of the action of each of the components alone. Therefore a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater fungicidal activity than the sum of the fungicidal activities of the individual components. In the field of agriculture, it is often understood that the term “synergy” is as defined by Colby S.R. in an article entitled “ Calculation of the synergistic and antagonistic responses of herbicide combinations” published in the journal Weeds, 1967, 15, p.20-22, incorporated herein by reference in its entirety. The action expected for a given combination of two active components can be calculated as follows:
XY
E = X + Y - -----------
100
in which E represents the expected percentage of Insecticidal or fungicidal control for the combination of the two insecticide or fungicides at defined dose (for example equal to x and y respectively), X is the percentage of insecticidal or fungicidal control observed by active ingredient I at defined dose (equal to x) and Y is the percentage of insecticidal or fungicidal control observed by Active Ingredient II (equal to Y). When the percentage of insecticidal or fungicidal control observed for the combination is greater than the expected percentage, there is a synergistic effect. (Ratio of O/E > 1, means synergism observed.)

Example 35
To study the synergistic effect of Chlorantraniliprole or Flubendiamide with Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate Methyl, various sets of experiments were conducted in micro plot (5m x 4m). The paddy seedling were transplanted and raised as per the normal agronomic practices. The insects, Leaffolder Cnaphalocrosis medinalis and diseases Sheath blight Rhizoctonia solani and Leaf blast, Pyricularia oryzae were allowed to build up, multiply and establish on paddy seedlings. The spraying was done manually with knapsack sprayer with 500 liter water per hectare. The assessment was done by counting the number of insect at before and 5 days after spraying. The percent insect control calculated as below:

% Insect control = 100 – 100 x (Number of insect observed in treated / Number of Insect in Untreated check.

The synergistic effect was calculated by Colby’s formula.
The observations on sheath blight disease severity were recorded at 10 days after foliar application and percent disease index calculated by below formula. The percent disease controls were calculated by disease severity in untreated plot.
Assessment for Sheath Blight:
Observed 100 tillers per plot and rated visually as per the ratings below.

Score Description
0 No infection
1 Vertical spread of the disease up to 20% of plant height
3 Vertical spread of the disease up to 21-30% of plant height
5 Vertical spread of the disease up to 31- 45% of plant height
7 Vertical spread of the disease up to 46 - 65% of plant height
9 Vertical spread of the disease more than 66% of plant height

Sum of numerical rating x 100
Percent Disease Index = --------------------------------------------------------------------
Total number of tiller observed x Maximum rating

% Disease Control = 100 – (100 - Disease Index in treatment / Disease index in Untreated plot)

Table 1: Paddy Leaffolder and Sheath blight control with SE and SC formulations of Chlorantraniliprole+Propiconazole
Sr no. Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Chlorantraniliprole 20% SC 150 ml 30 90.2 20.2
2 Propiconazole 25% EC 400 ml 100 15.6 86.4
3 Chlorantraniliprole 20% SC + Propiconazole 25% EC tank mix 150 ml+ 400 ml 30+100 87.5 91.7 0.95 82.8 89.1 0.93
4 Chlorantraniliprole 3% + Propiconazole 10% SE 1000 ml 30+100 92.6 91.7 1.01 91.8 89.1 1.03
5 Chlorantraniliprole 3% + Propiconazole 10% SC 1000 ml 30+100 94.8 91.7 1.03 92.6 89.1 1.04
O- Observed value, E- Expected / Calculated value, O/E (Synergistic ration) – Ratio of observed value/Expected value SC- Suspension Concentrate, EC Emulsifiable Concentrate, SE Suspo Emulsion, WG Water Dispersible Granules, WP Wettable Powder

Table 2: Paddy Leaffolder and Sheath blight control with SE, SC and WG formulations of Chlorantraniliprole+Tebuconazole
Sr no Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Chlorantraniliprole 20% SC 150 ml 30 91.2 16.8
2 Tebuconazole 25% EC 500 ml 125 17.4 86.4
3 Chlorantraniliprole 20% SC + Tebuconazole 25% EC tank mix 150 ml + 500 ml 30+ 125 88.6 92.7 0.96 86.8 88.7 0.98
4 Chlorantraniliprole 6% + Tebuconazole 25% SE 500 ml 30+ 125 94.8 92.7 1.02 92.8 88.7 1.05
5 Chlorantraniliprole 6% + Tebuconazole 25% SC 500 ml 30+ 125 94.2 92.7 1.02 91.6 88.7 1.03
6 Chlorantraniliprole 12% + Tebuconazole 50% WG 250 g 30+125 93.2 92.7 1.01 90.6 88.7 1.02

Table 3: Paddy Leaffolder and Leaf blast control with SC and WG formulations of Chlorantraniliprole+Tricyclazole
Sr no Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Leaf blast Control (%) caused by Pyricularia oryzae
O E Ratio O/E O E Ratio O/E
1 Chlorantraniliprole 20% SC 150 ml 30 93.4 10.4
2 Tricyclazole 75% WP 400 g 300 14.6 86.6
3 Chlorantraniliprole 20% SC + Tricyclazole 75% WP tank mix 150 ml + 400 g 30+ 300 92.6 94.4 0.98 85.4 88.0 0.97
4 Chlorantraniliprole 3% + Tricyclazole 30% SC 1000 ml 30+ 300 95.8 94.4 1.02 91.6 88.0 1.04
5 Chlorantraniliprole 6% + Tricyclazole 60% WG 500 g 30+ 300 95.2 94.4 1.01 94.2 88.0 1.07

Table 4: Paddy Leaffolder and Sheath blight control with SC and WG formulations of Chlorantraniliprole+Hexaconazole
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Chlorantraniliprole 20% SC 150 ml 30 88.2 10.2
2 Hexaconazole 5% EC 1000 ml 50 12.6 82.6
3 Chlorantraniliprole 20% SC + Hexaconazole 5% EC tank mix 150 ml + 1000 ml 30+50 84.2 89.7 0.94 80.6 84.4 0.96
4 Chlorantraniliprole 12% + Hexaconazole 20% SC 250 ml 30+50 94.2 89.7 1.05 88.8 84.4 1.05
5 Chlorantraniliprole 24% + Hexaconazole 40% WG 125 g 30+50 93.6 89.7 1.04 87.6 84.4 1.04

Table 5: Paddy Leaffolder and Sheath blight control with SC and WG formulations of Chlorantraniliprole+Trifloxystrobin
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Chlorantraniliprole 20% SC 150 ml 30 87.2 9.6
2 Trifloxystrobin 25% WG 500 g 125 16.8 85.2
3 Chlorantraniliprole 20% SC + Trifloxystrobin 25% WG tank mix 150 ml + 1000 ml 30+125 82.4 89.4 0.92 80.6 86.6 0.93
4 Chlorantraniliprole 6% + Trifloxystrobin 25% SC 500 ml 30+125 93 89.4 1.04 94.8 86.6 1.09
5 Chlorantraniliprole 12% + Trifloxystrobin 50% WG 250 g 30+125 94.2 89.4 1.05 96.2 86.6 1.11

Table 6: Paddy Leaffolder and Leaf blast control with SC and WG formulations of Chlorantraniliprole+Metominostrobin
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Leaf blast Control (%) caused by Pyricularia oryzae
O E Ratio O/E O E Ratio O/E
1 Chlorantraniliprole 20% SC 150 ml 30 92.6 14.2
2 Metominostrobin 20% SC 625 ml 125 12.6 90.6
3 Chlorantraniliprole 20% SC + Metominostrobin 20% SC tank mix 150 ml +
625 ml 30+125 86.4 93.5 0.92 83.4 91.9 0.91
4 Chlorantraniliprole 6% + Metominostrobin 25% SC 500 ml 30+125 94.8 93.5 1.01 94.2 91.9 1.02
5 Chlorantraniliprole 12% + Metominostrobin 50% WG 250 g 30+125 95.2 93.5 1.02 93.6 91.9 1.02

Table 7: Paddy Leaffolder and Sheath blight control with SC and WG formulations of Chlorantraniliprole+Thifluzamide
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Chlorantraniliprole 20% SC 150 ml 30 87.4 0
2 Thifluzamide 24% SC 417 ml 100 2.6 82.6
3 Chlorantraniliprole 20% SC + Thifluzamide 24% SC tank mix 150 ml +
417 ml 30+100 84.2 87.7 0.96 80.6 82.6 0.98
4 Chlorantraniliprole 6% + Thifluzamide 20% SC 500 ml 30+100 96.2 87.7 1.10 89.8 82.6 1.09
5 Chlorantraniliprole 12% + Thifluzamide 40% WG 250 g 30+100 94.4 87.7 1.08 91.4 82.6 1.11

Table 8: Paddy Leaffolder and Sheath blight control with SC and WG formulations of Chlorantraniliprole+Thiophanate Methyl
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Chlorantraniliprole 20% SC 150 ml 30 90.6 0
2 Thiophanate Methyl 70% WP 715 g 500 0 84.6
3 Chlorantraniliprole 20% SC + Thiophanate Methyl 70% WP tank mix 150 ml + 715 g 30+500 82.6 90.6 0.91 80.2 84.6 0.95
4 Chlorantraniliprole 2.4% + Thiophanate Methyl 40% SC 1250 ml 30+500 94.6 90.6 1.04 90.6 84.6 1.07
5 Chlorantraniliprole 3.8% + Thiophanate Methyl 62.5% WG 800 g 30+500 96.2 90.6 1.06 91.4 84.6 1.08

Table 9 : Paddy Leaffolder and Sheath blight control with SE and SC formulations of Flubendiamide+Propiconazole
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Flubendiamide 48% SC 125 ml 60 91.6 2.6
2 Propiconazole 25% EC 400 ml 100 11.2 85.2
3 Flubendiamide 20% SC + Propiconazole 25% EC tank mix 125 ml + 400 ml 60+100 85.4 92.5 0.92 80.6 85.6 0.94
4 Flubendiamide 6% + Propiconazole 10% SE 1000 ml 60+100 94.8 92.5 1.02 94.6 85.6 1.11
5 Flubendiamide 6% + Propiconazole 10% SC 1000 ml 60+100 95.2 92.5 1.03 95.2 85.6 1.11

Table 10: Paddy Leaffolder and Sheath blight control with SC and WG formulations of Flubendiamide+Tebuconazole
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Flubendiamide 48% SC 125 ml 60 89.4 0
2 Tebuconazole 25% EC 500 ml 125 8.4 87.2
3 Flubendiamide 20% SC + Tebuconazole 25% EC tank mix 125 ml + 500 ml 60+125 85.2 90.3 0.94 84.6 87.2 0.97
4 Flubendiamide 12% + Tebuconazole 25% SC 500 ml 60+125 93.8 90.3 1.04 93.2 87.2 1.07
5 Flubendiamide 24% + Tebuconazole 50% WG 250 g 60+125 95.2 90.3 1.05 91.2 87.2 1.05

Table 11: Paddy Leaffolder and Leaf blast control with SC and WG formulations of Flubendiamide+Tricyclazole
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Leaf blast Control (%) caused by Pyricularia oryzae
O E Ratio O/E O E Ratio O/E
1 Flubendiamide 48% SC 125 ml 60 89.4 0
2 Tricyclazole 75% WP 400 g 300 2.4 88.4
3 Flubendiamide 20% SC + Tricyclazole 75% WP tank mix 125 ml + 400 g 60+300 93.5 89.7 1.04 83.2 88.4 0.94
4 Flubendiamide 6% + Tricyclazole 30% SC 1000 ml 60+300 96.2 89.7 1.07 92.6 88.4 1.05
5 Flubendiamide 12% + Tricyclazole 60% WG 500 g 60+300 94.8 89.7 1.06 95.6 88.4 1.08

Table 12: Paddy Leaffolder and Sheath blight control with SC and WG formulations of Flubendiamide+Hexaconazole
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Flubendiamide 48% SC 125 ml 60 91.4 4.2
2 Hexaconazole 5% EC 1000 ml 50 4.6 87.8
3 Flubendiamide 20% SC + Hexaconazole 5% EC tank mix 125 ml + 1000 ml 60+50 86.4 91.8 0.94 85.2 88.3 0.96
4 Flubendiamide 12% + Hexaconazole 10% SC 500 ml 60+50 93.6 91.8 1.02 93.4 88.3 1.06
5 Flubendiamide 24% + Hexaconazole 20% WG 250 g 60+50 95.2 91.8 1.04 92.8 88.3 1.05

Table 13: Paddy Leaffolder and Sheath blight control with SC and WG formulations of Flubendiamide+Trifloxystrobin
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Flubendiamide 48% SC 125 ml 60 92.2 0
2 Trifloxystrobin 25% WG 500 g 125 0 86.2
3 Flubendiamide 20% SC + Trifloxystrobin 25% WG tank mix 125 ml + 1000 ml 60+125 89.2 92.2 0.97 82.6 86.2 0.96
4 Flubendiamide 12% + Trifloxystrobin 25% SC 500 ml 60+125 95.2 92.2 1.03 94.6 86.2 1.10
5 Flubendiamide 24% + Trifloxystrobin 50% WG 250 g 60+125 96.4 92.2 1.05 93.2 86.2 1.08

Table 14: Paddy Leaffolder and Leaf blast control with SC and WG formulations of Flubendiamide+Metominostrobin
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Leaf blast Control (%) caused by Pyricularia oryzae
O E Ratio O/E O E Ratio O/E
1 Flubendiamide 48% SC 125 ml 60 90.2 0
2 Metominostrobin 20% SC 625 ml 125 0 84.6
3 Flubendiamide 20% SC + Metominostrobin 20% SC tank mix 125 ml + 625 ml 60+125 84.6 90.2 0.94 80.2 84.6 0.95
4 Flubendiamide 12% + Metominostrobin 25% SC 500 ml 60+125 94.2 90.2 1.04 94.2 84.6 1.11
5 Flubendiamide 24% + Metominostrobin 50% WG 250 g 60+125 93.8 90.2 1.04 92.4 84.6 1.09

Table 15: Paddy Leaffolder and Sheath blight control with SC and WG formulations of Flubendiamide+Thifluzamide
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Flubendiamide 48% SC 125 ml 60 88.4 0
2 Thifluzamide 24% SC 417 ml 100 4.2 88.6
3 Flubendiamide 20% SC + Thifluzamide 24% SC tank mix 125 ml + 417 ml 60+100 84.6 88.9 0.95 80.2 88.6 0.91
4 Flubendiamide 12% + Thifluzamide 20% SC 500 ml 60+100 93.4 88.9 1.05 93.4 88.6 1.05
5 Flubendiamide 24% + Thifluzamide 40% WG 250 g 60+100 92.8 88.9 1.04 91.4 88.6 1.03

Table 16: Paddy Leaffolder and Sheath blight control with SC and WG formulations of Flubendiamide+Thiophanate Methyl
Sr No Treatments Formulation (g or ml/h) Rate g.a.i./h % Leaf folder control Sheath blight Control (%) caused by Rhizoctonia solani
O E Ratio O/E O E Ratio O/E
1 Flubendiamide 48% SC 125 ml 60 92.6 0
2 Thiophanate Methyl 70% WP 715 g 500 0 87.8
3 Flubendiamide 20% SC + Thiophanate Methyl 70% WP tank mix 125 ml + 715 g 30+500 84.6 92.6 0.91 80.4 87.8 0.92
4 Flubendiamide 4.8% + Thiophanate Methyl 40% SC 1250 ml 30+500 93.8 92.6 1.01 94.6 87.8 1.08
5 Flubendiamide 7.5% + Thiophanate Methyl 62.5% WG 800 g 30+500 94.6 92.6 1.02 95.2 87.8 1.08

All the ready mix formulation of Anthranilamide with fungicides shows synergistic activity in terms of insect control as well diseases control as compared to their individual / solo applications as well as their tank mix combinations.

,CLAIMS:WE CLAIMS

1. A pesticidal composition comprising 1) an anthranilamide insecticide compound of I selected from Chlorantraniliprole or Flubendiamide 2) at least one fungicidal compound II selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl and optionally 3) one more more inactive excipients.

2. The pesticidal composition as claimed in claim 1 wherein the ratio of anthranilamide insecticide compound of I and fungicidal compound II is 1:15 to 5:1.

3. The pesticidal composition according to claim 1, wherein inactive excipients can be selected from the group consisting of dispersant, anti-freezing agent, anti-foam agent, wetting agent, suspension aid, anti-microbial agent, thickener, quick coating agent or sticking agents and buffering agent.

4. The pesticidal composition as claimed in claims 1-3, wherein the formulation can be selected from Suspension Concentrate (SC), Suspo emulsion (SE), Water dispersible grnules (WDG).

5. The pesticidal composition as claimed in any of the preceding claims, wherein the said formulation is used for control of pests and diseases of powdery mildew, Blumeria species, Blumeria graminis; Podosphaera species Podosphaera leucotricha; Sphaerotheca Sphaerotheca fuliginea; Uncinula species Uncinula necator; Leveillula species Leveillula taurica, Erysiphe species Erysiphe polygoni, pathogens of rust Gymnosporangium species Gymnosporangium sabinae, Hemileia species Hemileia vastatrix; Phakopsora species Phakopsora pachyrhizi and Phakopsora meibomiae; Puccinia species Puccinia graminis, Puccinia recondita or Puccinia triticina, Puccinia striiformis; Uromyces species Uromyces phaseoli; pathogens of smut Sporisorium species Sporisorium scitamineum; Ustilago species Ustilago maydis, Tilletia species Tilletia tritici, Ustilaginoidea species Ustilaginoidea virens, pathogens of ergot Claviceps species, Claviceps purpurea; pathogens Oomycetes, Bremia species, Bremia lactucae; Peronospora species, Peronospora pisi or P. brassicae; Phytophthora species, Phytophthora infestans; Plasmopara species, Plasmopara viticola; Pseudoperonospora species, Pseudoperonospora humuli or Pseudoperonospora cubensis; Pythium species , Pythium ultimum; leaf spot diseases and leaf wilt, Alternaria species , Alternaria solani; Cercospora species , Cercospora beticola; Cladiosporum species , Cladiosporium cucumerinum; Cochliobolus species , Cochliobolus sativus (conidial form: Drechslera, syn: Helminthosporium); Colletotrichum species , Colletotrichum lindemuthanium; Cycloconium species , Cycloconium oleaginum; Diaporthe species , Diaporthe citri; Elsinoe species , Elsinoe fawcettii; Gloeosporium species , Gloeosporium laeticolor; Glomerella species , Glomerella cingulata; Guignardia species , Guignardia bidwelli; Leptosphaeria species , Leptosphaeria maculans; Magnaporthe species , Magnaporthe grisea; Mycosphaerella species , Mycosphaerella graminicola; Phaeosphaeria species , Phaeosphaeria nodorum; Pyrenophora species , Pyrenophora teres; Ramularia species , Ramularia collo-cygni; Rhynchosporium species , Rhynchosporium secalis; Septoria species , Septoria apii; Typhula species , Typhula incarnata; Venturia species , Venturia inaequalis; root and stalk diseases, , Corticium species , Corticium graminearum; Fusarium species , Fusarium oxysporum; Gaeumannomyces species , Gaeumannomyces graminis; Rhizoctonia species , Rhizoctonia solani; Tapesia species , Tapesia acuformis; Thielaviopsis species , Thielaviopsis basicola; ear and panicle diseases (including maize cobs), , Alternaria species , Alternaria spp.; Aspergillus species , Aspergillus flavus; Cladosporium species , Cladosporium spp.; Claviceps species , Claviceps purpurea; Fusarium species , Fusarium culmorum; Gibberella species , Gibberella zeae; Monographella species , Monographella nivalis; diseases caused by smuts , Sphacelotheca species , Sphacelotheca reiliana; Tilletia species , Tilletia caries; Urocystis species , Urocystis occulta; Ustilago species , Ustilago nuda; fruit rot , Aspergillus species , Aspergillus flavus; Botrytis species , Botrytis cinerea; Penicillium species , Penicillium expansum; Sclerotinia species , Sclerotinia sclerotiorum; Verticilium species , Verticilium alboatrum; seed- and soil-borne rots and wilts, and seedling diseases, , Fusarium species , Fusarium culmorum; Phytophthora species , Phytophthora cactorum; Pythium species , Pythium ultimum; Rhizoctonia species , Rhizoctonia solani; Sclerotium species , Sclerotium rolfsii; cankers, galls and witches' broom diseases, , Nectria species , Nectria galligena; wilts , Monilinia species , Monilinia laxa; deformations of leaves, flowers and fruits, , Taphrina species , Taphrina deformans; degenerative diseases of woody species, , Esca species , Phaemoniella clamydospora; flower and seed diseases, , Botrytis species , Botrytis cinerea; diseases of plant tubers , Rhizoctonia species , Rhizoctonia solani; diseases caused by bacterial pathogens , Xanthomonas species , Xanthomonas campestris pv. oryzae; Pseudomonas species , Pseudomonas syringae pv. lachrymans; Erwinia species , Erwinia amylovora; by preference, the following diseases of soya beans can be controlled: fungal diseases on leaves, stems, pods and seeds , alternaria leaf spot (Alternaria spec, atrans tenuissima), anthracnose (Colletotrichum gloeosporoides dematium var. truncatum), brown spot (Septoria glycines), cercospora leaf spot and blight (Cercospora kikuchii), choanephora leaf blight (Choanephora infundibulifera trispora (Syn.)), dactuliophora leaf spot (Dactuliophora glycines), downy mildew (Peronospora manshurica), drechslera blight (Drechslera glycini), frogeye leaf spot (Cercospora sojina), leptosphaerulina leaf spot (Leptosphaerulina trifolii), phyllostica leaf spot (Phyllosticta sojaecola), powdery mildew (Microsphaera diffusa), pyrenochaeta leaf spot (Pyrenochaeta glycines), rhizoctonia aerial, foliage, and web blight (Rhizoctonia solani), rust (Phakopsora pachyrhizi), scab (Sphaceloma glycines), stemphylium leaf blight (Stemphylium botryosum), target spot (Corynespora cassiicola) fungal diseases on roots and the stem base , black root rot (Calonectria crotalariae), charcoal rot (Macrophomina phaseolina), fusarium blight or wilt, root rot, and pod and collar rot (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), mycoleptodiscus root rot (Mycoleptodiscus terrestris), neocosmospora (Neocosmopspora vasinfecta), pod and stem blight (Diaporthe phaseolorum), stem canker (Diaporthe phaseolorum var. caulivora), phytophthora rot (Phytophthora megasperma), brown stem rot (Phialophora gregata), pythium rot (Pythium aphanidermatum, Pythium irregulare, Pythium debaryanum, Pythium myriotylum, Pythium ultimum), rhizoctonia root rot, stem decay, and damping-off (Rhizoctonia solani), sclerotinia stem decay (Sclerotinia sclerotiorum), sclerotinia southern blight (Sclerotinia rolfsii), thielaviopsis root rot (Thielaviopsis basicola).

6. The pesticidal composition as claimed in claim 5, wherein the said formulation is used to control pest in crops Cotton (Gossypium spp.), Jute (Corchorus oliotorus), Paddy (Oryza sativa), Wheat (Triticum aestavum), Barley (Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Ragi (Eleusine coracana), Pearl millet (Pennisetum glaucum), Sugarcane (Saccharum officinarum) , Sugarbeet (Beta vulgaris), Soybean (Glycin max), Peanut (Arachis hypogaea), Sunflower (Helianthus annuus) , Mustard (Brassica juncea), Rape seed (Brassica napus), Linseed (Linum usitatissimum), Sesame (Sesamum indicum), Castor (Ricinus communis), Green gram (Vigna radiate), Black gram (Vigna mungo), Chickpea (Cicer aritinum), Cowpea (Vigna unguiculata), Redgram (Cajanus cajan), Frenchbean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotyloma uniflorum), Field pea (Pisum sativum), Cluster bean (Cyamopsis tetragonoloba), Lentils (Lens culinaris), Brinjal (Solanum melongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschus esculentus), Onion (Allium cepa L.), Tomato (Solanum lycopersicun) , Potato (Solanum tuberosum), Sweet potato (Ipomoea batatas), Chilly (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumis sativus), Muskmelons (Cucumis melo), Watermelon (Citrullus lanatus), Bottle gourd (Lagenaria siceraria), Bitter gourd (Momordica charantia), Radish (Raphanus sativus), Carrot (Dacus carota subsp. sativus), Turnip (Brassica rapa subsp rapa), Apple (Melus domestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitis vinifera), Guava (Psidium guajava), Litchi (Litchi chinensis), Mango (Mangifera indica), Papaya (Carica papaya), Pineapple (Ananas comosus), Pomegranate (Punica granatum) , Sapota (Manilkara zapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiber officinale), Cumin (Cuminum cyminum), Fenugreek (Trigonella foenum-graecum), Fennel (Foeniculum vulgare), Coriander (Coriandrum sativum), Ajwain (Trachyspermum ammi), Psyllium (Plantago ovate), Black Pepper (Piper nigrum), Stevia (Stevia rebaudiana), Safed musli (Chlorophytum tuberosum), Drum stick (Moringa oleifera), Coconut (Coco nucifera), Mentha ( Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold ( Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera ( Gerbera jamesonii), Carnation (Dianthus caryophyllus)

7. The pesticidal composition as claimed in claim 5, wherein the said formulation is used to control insects lepidopterans (Lepidoptera), Agrotis ypsilon, Agrotis segetum, Alabama argillacea, Anticarsia gemmatalis, Argyresthia conjugella, Autographa gamma, Bupalus piniarius, Cacoecia murinana, Capua reticulana, Cheima-tobia brumata, Choristoneura fumiferana, Choristoneura occidentalis, Cirphis unipuncta, Cydia pomonella, Dendrolimus pini, Diaphania nitidalis, , Earias insulana, Elasmopalpus lignosellus, Eupoecilia ambiguella, Evetria bou-liana, Feltia subterranea, Galleria mellonella, Grapholitha funebrana, Grapholitha mo-lesta, Heliothis armigera, Heliothis virescens, Heliothis zea, Hellula undalis, Hibernia defoliaria, Hyphantria cunea, Hyponomeuta malinellus, Keiferia lycopersicella, Lamb-dina fiscellaria, Laphygma exigua, Leucoptera coffeella, Leucoptera scitella, Lithocol-letis blancardella, Lobesia botrana, Loxostege sticticalis, Lymantria dispar, Lymantria monacha, Lyonetia clerkella, Malacosoma neustria, Mamestra brassicae, Orgyia pseu-dotsugata, Ostrinia nubilalis, Panolis flammea, Pectinophora gossypiella, Peridroma saucia, Phalera bucephala, Phthorimaea operculella, Phyllocnistis citrella, Pieris bras-sicae, Plathypena scabra, Plutella xylostella, Pseudoplusia includens, Rhyacionia frus-trana, Scrobipalpula absoluta, Sitotroga cerealella, Sparganothis pilleriana, Spodoptera frugiperda, Spodoptera littoralis, Spodoptera litura, Thaumatopoea pityocampa, Tortrix viridana, Trichoplusia ni and Zeiraphera canadensis, beetles (Coleoptera), for example Agrilus sinuatus, Agriotes lineatus, Agriotes obscu-rus, Amphimallus solstitialis, Anisandrus dispar, Anthonomus grandis, Anthonomus pomorum, Aphthona euphoridae, Athous haemorrhoidalis, Atomaria linearis, Blasto-phagus piniperda, Blitophaga undata, Bruchus rufimanus, Bruchus pisorum, Bruchus lentis, Byctiscus betulae, Cassida nebulosa, Cerotoma trifurcata, Cetonia aurata, Ceuthorrhynchus assimilis, Ceuthorrhynchus napi, Chaetocnema tibialis, Conoderus vespertinus, Crioceris asparagi, Ctenicera ssp., Diabrotica longicornis, Diabrotica semipunctata, Diabrotica 12-punctata Diabrotica speciosa, Diabrotica virgifera, Epila-chna varivestis, Epitrix hirtipennis, Eutinobothrus brasiliensis, Hylobius abietis, Hypera brunneipennis, Hypera postica, Ips typographus, Lema bilineata, Lema melanopus, Leptinotarsa decemlineata, Limonius califomicus, Lissorhoptrus oryzophilus, Melanotus communis, Meligethes aeneus, Melolontha hippocastani, Melolontha melolontha, Oulema oryzae, Ortiorrhynchus sulcatus, Otiorrhynchus ovatus, Phaedon cochleariae, Phyllobius pyri, Phyllotreta chrysocephala, Phyllophaga sp., Phyllopertha horticola, Phyllotreta nemorum, Phyllotreta striolata, Popillia japonica, Sitona lineatus and Sito-philus gran aria, flies, mosquitoes (Diptera), e.g. Aedes aegypti, Aedes albopictus, Aedes vexans, An-astrepha ludens, Anopheles maculipennis, Anopheles crucians, Anopheles albimanus, Anopheles gambiae, Anopheles freeborni, Anopheles leucosphyrus, Anopheles mini-mus, Anopheles quadrimaculatus, Calliphora vicina, Ceratitis capitata, Chrysomya bezziana, Chrysomya hominivorax, Chrysomya macellaria, Chrysops discalis, Chrysops silacea, Chrysops atlanticus, Cochliomyia hominivorax, Contarinia sorghicola Cordylobia anthropophaga, Culicoides furens, Culex pipiens, Culex nigripalpus, Culex quinquefasciatus, Culex tarsalis, Culiseta inornata, Culiseta melanura, Dacus cucurbi-tae, Dacus oleae, Dasineura brassicae, Delia antique, Delia coarctata, Delia platura, Delia radicum, Dermatobia hominis, Fannia canicularis, Geomyza Tripunctata, Gaster-ophilus intestinalis, Glossina morsitans, Glossina palpalis, Glossina fuscipes, Glossina tachinoides, Haematobia irritans, Haplodiplosis equestris, Hippelates spp., Hylemyia platura, Hypoderma lineata, Leptoconops torrens, Liriomyza sativae, Liriomyza trifolii, Lucilia caprina, Lucilia cuprina, Lucilia sericata, Lycoria pectoralis, Mansonia titillanus, Mayetiola destructor, Musca domestica, Muscina stabulans, Oestrus ovis, Opomyza florum, Oscinella frit, Pegomya hysocyami, Phorbia antiqua, Phorbia brassicae, Phor-bia coarctata, Phlebotomus argentipes, Psorophora columbiae, Psila rosae, Psoro-phora discolor, Prosimulium mixtum, Rhagoletis cerasi, Rhagoletis pomonella, Sar-cophaga haemorrhoidalis, Sarcophaga sp., Simulium vittatum, Stomoxys calcitrans, Tabanus bovinus, Tabanus atratus, Tabanus lineola, and Tabanus similis, Tipula ol-eracea, and Tipula paludosa thrips (Thysanoptera), e.g. Dichromothrips corbetti, Dichromothrips ssp , Frankliniella fusca, Frankliniella occidentalis, Frankliniella tritici, Scirtothrips citri, Scirtothrips dorsalis, Thrips oryzae, Thrips palmi and Thrips tabaci, termites (Isoptera), e.g. Calotermes flavicollis, Leucotermes flavipes, Heterotermes aureus, Reticulitermes flavipes, Reticulitermes virginicus, Reticulitermes lucifugus, Termes natalensis, and Coptotermes formosanus, cockroaches (Blattaria - Blattodea), e.g. Blattella germanica, Blattella asahinae, Penplaneta americana, Periplaneta japonica, Periplaneta brunnea, Periplaneta fuligginosa, Periplaneta australasiae, and Blatta orientalis, true bugs (Hemiptera), e.g. Acrosternum hilare, Amrasca biguttula biguttula, Amrasca devastans, Blissus leucopterus, Cyrtopeltis nota-tus, Dysdercus cingulatus, Dysdercus intermedius, Eurygaster integriceps, Euschistus impictiventris, Leptoglossus phyllopus, Lygus lineolaris, Lygus pratensis, Nezara viridu-la, Piesma quadrata, Solubea insularis , Thyanta perditor, Acyrthosiphon onobrychis, Adelges laricis, Aphidula nasturtii, Aphis fabae, Aphis forbesi, Aphis pomi, Aphis gossypii, Aphis crassivora, Aphis grossulariae, Aphis schneideri, Aphis spiraecola, Aphis sambuci, Acyrtho-siphon pisum, Aulacorthum solani, Bemisia argentifolii, Bemisia tabaci, Brachycaudus cardui, Brachy-caudus helichrysi, Brachycaudus persicae, Brachycaudus prunicola, Brevicoryne brassicae, Capitophorus horni, Cerosipha gossypii, Chaetosiphon fragaefolii, Cryptomyzus ribis, Dreyfusia nordmannianae, Dreyfusia piceae, Dysaphis radicola, Dysaulacorthum pseudosolani, Dysaphis plantaginea, Dysaphis pyri, Empoasca fabae, Hyalopterus pruni, Hyperomyzus lactucae, Macrosiphum avenae, Macrosiphum euphorbiae, Ma-crosiphon rosae, Megoura viciae, Melanaphis pyrarius, Metopolophium dirhodum, My-zus persicae, Myzus ascalonicus, Myzus cerasi, Myzus varians, Nasonovia ribis-nigri, Nilaparvata lugens, Pemphigus bursarius, Perkinsiella saccharicida, Phorodon humuli, Psylla mail, Psylla piri, Rhopalomyzus ascalonicus, Rhopalosiphum maidis, Rhopalosi-phum padi, Rhopalosiphum insertum, Sappaphis mala, Sappaphis mail, Schizaphis graminum, Schizoneura lanuginosa, Sitobion avenae, Trialeurodes vaporariorum, Toxoptera aurantiia d, Viteus vitifolii, Cimex lectularius, Cimex hemipterus, Reduvius senilis, Triatoma spp., and Arilus critatus, Trialeurodes vaporariorum, Amrasca biguttula, Empoasca spp., Myzus spp., Nephotettix spp., Nilaparvata spp., Planococcus spp., Pseudococcus spp., Psylla spp., Rhopalosiphum spp., Sitobion spp., Amritodus atkinsoni, Idioscopus spp. ants, bees, wasps, sawflies (Hymenoptera), e.g. Athalia rosae, Atta cephalotes, Atta capiguara, Atta cephalotes, Atta laevigata, Atta robusta, Atta sexdens, Atta texana, Crematogaster spp., Hoplocampa minuta, Hoplocampa testudinea, Monomorium pha-raonis, Solenopsis geminata, Solenopsis invicta, Solenopsis richteri, Solenopsis xyloni, Pogonomyrmex barbatus, Pogonomyrmex californicus, Pheidole megacephala, Dasy-mutilla occidentalis, Bombus spp. Vespula squamosa, Paravespula vulgaris, Paraves-pula pennsylvanica, Paravespula germanica, Dolichovespula maculata, Vespa crabro, Polistes rubiginosa, Camponotus floridanus, and Linepithema humile, crickets, grasshoppers, locusts (Orthoptera), e.g. Acheta domestica, Gryllotalpa gryllo-talpa, Locusta migratoria, Melanoplus bivittatus, Melanoplus femurrubrum, Melanoplus mexicanus, Melanoplus sanguinipes, Melanoplus spretus, Nomadacris septemfasciata, Schistocerca americana, Schistocerca gregaria, Dociostaurus maroccanus, Tachycines asynamorus, Oedaleus senegalensis, Zonozerus variegatus, Hieroglyphus daganensis, Kraussaria angulifera, Calliptamus italicus, Chortoicetes terminifera, and Locustana pardalina,

8. The pesticidal composition of 1) an anthranilamide insecticide compound of I selected from Chlorantraniliprole and Flubendiamide 2) at least one fungicidal compound II selected from Propiconazole, Tebuconazole, Tricyclazole, Hexaconazole, Trifloxystrobin, Metominostrobin, Thifluzamide and Thiophanate methyl as claimed in any of the preceding claims and exemplified with working examples as disclosed.