TECHNICAL FIELD [0001]
The present invention relates to a photosensitive resin composition for thin film transistors, a cured film, a thin film transistor, a liquid crystal display device or an organic electroluminescent display device, a method for producing a cured film, a method for manufacturing a thin film transistor, and a method for manufacturing a liquid crystal display device or an organic electroluminescent display device.
BACKGROUND ART [0002]
A mainstream of display devices such as liquid crystal display devices and organic EL display devices is those of an active matrix driving system in which the display devices are driven with a thin film transistor (hereinafter sometimes

referred to as TFT) disposed in each pixel. Various insulating layers used in a TFT, such as a gate insulating layer and an interlayer insulating layer, are generally produced by forming a film of an inorganic material such as silicon nitride or silicon oxide by vapor deposition. [0003]
The vapor deposition method, however, has a problem that the vacuum equipment required for vapor deposition is very expensive. Furthermore, patterning of the deposited inorganic film requires complicated steps such as application, exposure, and development of a resist material, etching of an inorganic material, and removal of the resist material. Moreover, a flexible display device including a plastic substrate, which has been actively developed in recent years, has problems that cracks tend to occur in a conventional insulating layer made from an inorganic material and the durability of the insulating layer is insufficient. [0004]
In order to solve such problems, studies have been made about the use of a photosensitive resin composition as an organic material in a gate insulating layer and an interlayer insulating layer. An insulating layer made from a photosensitive resin composition can reduce the production cost because expensive vacuum deposition equipment is unnecessary. Further, patterning of the insulating layer can be performed

by applying, exposing, and developing the photosensitive resin, so that it is possible to process the insulating layer easily without requiring a resist material. Furthermore, since the photosensitive resin layer has higher film toughness than an inorganic film does, crack generation can be suppressed when the layer is used in a flexible display device. [0005]
As a photosensitive resin composition for an insulating layer of a TFT, for example, materials containing a polyimide resin are proposed from the viewpoint of heat resistance (Patent Documents 1 and 2) .
PRIOR ART DOCUMENTS PATENT DOCUMENTS [0006]
Patent Document 1: Japanese Patent Laid-open Publication
No. 64-24231
Patent Document 2: Japanese Patent Laid-open Publication
No. 2011-222787
SUMMARY OF THE INVENTION
PROBLEMS TO BE SOLVED BY THE INVENTION
[0007]
However, these materials cannot be said to have sufficient performance from the viewpoint of suppression of

outgassing, and have a problem that the driving performance is lowered due to outgassing components generated from the thermally cured insulating layer. In view of the above-mentioned problem, it is an object of the present invention to provide a photosensitive resin composition for thin film transistors with which it is possible to form an insulating layer for thin film transistors that is extremely little in outgassing from a cured film and that is excellent in driving performance.
SOLUTIONS TO THE PROBLEMS [0008]
The present invention provides a photosensitive resin composition for thin film transistors, containing (A) an amide group- and/or imide group-containing alkali-soluble resin, (B) a photosensitive compound, and (C) an organic solvent, wherein the organic solvent (C) contains 1% by mass or less of a nitrogen atom-containing organic solvent based on the organic solvent in total.
EFFECTS OF THE INVENTION [0009]
The present invention can provide a photosensitive resin composition for thin film transistors with which it is possible to form an insulating layer for thin film transistors that is

extremely little in outgassing from a cured film and that is excellent in driving performance.
BRIEF DESCRIPTION OF THE DRAWINGS [0010]
Fig. 1 is a cross-sectional view showing an example of a thin film transistor of the present invention.
Fig. 2 is a cross-sectional view showing another example of the thin film transistor of the present invention.
Fig. 3 is a cross-sectional view of a thin film transistor according to examples of the present invention.
EMBODIMENTS OF THE INVENTION [0011]
The resin composition for thin film transistors of the present invention is a photosensitive resin composition for thin film transistors containing (A) an amide group- and/or imide group-containing alkali-soluble resin, (B) a photosensitive compound, and (C) an organic solvent, wherein the organic solvent (C) contains 1% by mass or less of a nitrogen atom-containing organic solvent based on the organic solvent in total. [0012]
The photosensitive resin composition for thin film transistors of the present invention contains the amide group-

and/or imide group-containing alkali-soluble resin (A). As used herein, the term "alkali-soluble" means that the resin has a dissolution rate of 50 nm/min or more, the dissolution rate being obtained from a decrease in film thickness when a solution prepared by dissolving the resin in y-butyrolactone is applied to a silicon wafer and pre-baked at 120°C for 4 minutes to form a pre-baked film having a thickness of 10 |0,m ± 0.5 ^m, the pre-baked film is immersed in a 2.38% by mass aqueous tetramethylammonium hydroxide solution at 23 + 1°C for 1 minute, and then the pre-baked film is rinsed with pure water.
[0013]
The amide group- and/or imide group-containing alkali-soluble resin (A) may be a polyimide, a polyimide precursor, a polybenzoxazole, a polybenzoxazole precursor, a polyaminoamide, or a polyamide, but is not limited thereto. The alkali-soluble resin may contain two or more of these resins. Among these alkali-soluble resins, those that are excellent in heat resistance and small in the amount of outgassing at high temperature are preferred. Specifically, at least one alkali-soluble resin selected from a polyimide, a polyimide precursor, and a polybenzoxazole precursor, or a copolymer thereof is preferred.
[0014]
The alkali-soluble resin selected from a polyimide, a polyimide precursor, and a polybenzoxazole precursor, or a

copolymer thereof, which can be used as the amide group- and/or imide group-containing alkali-soluble resin (A) of the present invention, preferably has an acidic group in the structural unit of the resin and/or the main chain end of the resin in order to have the alkali solubility. Examples of the acidic group include a carboxyl group, a phenolic hydroxyl group, a sulfonic acid group, and a thiol group. The alkali-soluble resin or a copolymer thereof preferably has a fluorine atom. The fluorine atom can impart water repellency to the interface between the resin film and the base material and suppress the infiltration of an alkaline aqueous solution into the interface when the resin film is developed with the alkaline aqueous solution. The fluorine atom content in the alkali-soluble resin or a copolymer thereof is preferably 5% by mass or more from the viewpoint of the effect of preventing the infiltration of the alkaline aqueous solution into the interface, and is preferably 20% by mass or less from the viewpoint of solubility in an alkaline aqueous solution.
[0015]
The above-mentioned polyimide preferably has a structural unit represented by the following general formula
(1), and the polyimide precursor and the polybenzoxazole precursor each preferably have a structural unit represented by the following general formula (2) . The alkali-soluble resin may contain two or more of these, or a resin obtained by

copolymerizing a structural unit represented by the general formula (1) with a structural unit represented by the general formula (2) may be used. [0016]
In the general formula (1), R1 represents a tetravalent to decavalent organic group, and R2 represents a divalent to octavalent organic group. R3 and R4 each represent a phenolic hydroxyl group, a carboxy group, a sulfonic acid group, or a thiol group, and each may be a single group or a combination of different groups, p and q each represent an integer of 0 to 6.

In the general formula (2), R5 represents a divalent to octavalent organic group, and R6 represents a divalent to octavalent organic group. R7 and R8 each represent a phenolic
q
hydroxyl group, a sulfonic acid group, a thiol group, or COOR , and each may be a single group or a combination of different groups. R9 represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 20 carbon atoms, r and s each represent an integer of 0 to 6, provided that r + s > 0. [0020]
The alkali-soluble resin selected from a polyimide, a polyimide precursor, and a polybenzoxazole precursor, or a copolymer thereof preferably has 5 to 100,000 structural units represented by the general formula (1) and/or (2). In addition to the structural units represented by the general formula (1) and/or (2) , the alkali-soluble resin or a copolymer thereof may have another structural unit. In this case, it is preferred that the structural units represented by the general formula (1) and/or (2) are contained in an amount of 50 mol% or more of the total number of structural units. [0021]
In the general formula (1), RMR3)? represents a residue of an acid dianhydride. R1 is a tetravalent to decavalent organic group, and is particularly preferably an organic group having 5 to 40 carbon atoms and containing an aromatic ring or a cycloaliphatic group.

[0022]
Specific examples of the acid dianhydride include pyromellitic dianhydride, 3,3',4,4'-biphenyltetracarboxylic dianhydride, 2,3,3',4'-biphenyltetracarboxylic dianhydride, 2,2',3,3'-biphenyltetracarboxylic dianhydride, 3,3',4,4'-benzophenonetetracarboxylic dianhydride, 2,2',3,3'-benzophenonetetracarboxylic dianhydride, 2,2-bis(3,4-dicarboxyphenyl)propane dianhydride, 2,2-bis(2,3-dicarboxyphenyl)propane dianhydride, 1,1-bis(3,4-dicarboxyphenyl)ethane dianhydride, 1,1-bis(2,3-dicarboxyphenyl)ethane dianhydride, bis(3,4-dicarboxyphenyl)methane dianhydride, bis(2,3-dicarboxyphenyl)methane dianhydride, bis(3,4-dicarboxyphenyl)ether dianhydride, 1,2,5,6-naphthalenetetracarboxylic dianhydride, 9,9-bis(3,4-dicarboxyphenyl)fluorenic dianhydride, 9,9-bis{4-(3,4-dicarboxyphenoxy)phenyl}fluorenic dianhydride, 2,3,6, 7-naphthalenetetracarboxylic dianhydride, 2,3,5,6-pyridinetetracarboxylic dianhydride, 3,4,9,10-perylenetetracarboxylic dianhydride, 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride, aromatic tetracarboxylic dianhydrides such as an acid dianhydride having the structure shown below, and aliphatic tetracarboxylic dianhydrides such as butane tetracarboxylic dianhydride and 1,2,3,4-cyclopentanetetracarboxylic

dianhydride. Two or more of these may be used. [0023]
[0024]
R10 represents an oxygen atom, C(CF3)2, or C(CH3)2- R11 and R12 each represent a hydrogen atom or a hydroxyl group. [0025]
In the general formula (2) , R5-(R7)r represents a residue of an acid. R5 is a divalent to octavalent organic group, and is particularly preferably an organic group having 5 to 40 carbon atoms and containing an aromatic ring or a cycloaliphatic group. [0026]
Examples of the acid component include dicarboxylic acids such as terephthalic acid, isophthalic acid, diphenyl ether dicarboxylic acid, bis(carboxyphenyl)hexafluoropropane, biphenyldicarboxylic acid, benzophenone dicarboxylic acid, and triphenyldicarboxylic acid, tricarboxylic acids such as trimellitic acid, trimesic acid, diphenyl ether tricarboxylic acid, and biphenyltricarboxylic acid, and tetracarboxylic acids such as pyromellitic acid, 3,3',4,4'-biphenyltetracarboxylic acid,

2,3,3',4'-biphenyltetracarboxylic acid,
2,2',3,3'-biphenyltetracarboxylic acid,
3, 3' , 4, 4' -benzophenonetetracarboxylic acid,
2,2',3,3'-benzophenonetetracarboxylic acid,
2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane,
2,2-bis(2,3-dicarboxyphenyl)hexatluoropropane,
1,1-bis(3,4-dicarboxyphenyl)ethane,
1,1-bis(2,3-dicarboxyphenyl)ethane,
bis (3,4-dicarboxyphenyl)methane,
bis(2,3-dicarboxyphenyl)methane,
bis(3,4-dicarboxyphenyl)ether,
1,2,5,6-naphthalenetetracarboxylic acid,
2,3,6,7-naphthalenetetracarboxylic acid,
2,3,5,6-pyridinetetracarboxylic acid,
3,4,9,10-perylenetetracarboxylic acid, aromatic
tetracarboxylic acids having the structure shown below, and
aliphatic tetracarboxylic acids such as butane tetracarboxylic
acid and 1,2,3,4-cyclopentanetetracarboxylic acid. Two or
more of these may be used.
[0027]
[Chemical Formula 4]

R10 represents an oxygen atom, C(CF3)2, orC(CH3)2. R11 and R12 each represent a hydrogen atom or a hydroxyl group. [0029]
Among them, in the tricarboxylic acids and the tetracarboxylic acids, one or two carboxyl groups correspond to the R7 group in the general formula (2) . Further, it is more preferred that 1 to 4 hydrogen atoms of the dicarboxylic acids, tricarboxylic acids, or tetracarboxylic acids mentioned above are substituted with the R7 group in the general formula (2), preferably a phenolic hydroxyl group. These acids can be used as they are, or as acid anhydrides or active esters. [0030]
R2-(R4)q in the general formula (1) and R6-(R8)S in the general formula (2) each represent a residue of a diamine. R and R8 are each a divalent to octavalent organic group, and are particularly preferably each an organic group having 5 to 40 carbon atoms and containing an aromatic ring or a cycloaliphatic group. [0031]
Specific examples of the diamine include 3,4'-diaminodiphenyl ether, 4,4'-diaminodiphenyl ether, 3, 4'-diaminodiphenylmethane, 4,4'-diaminodiphenylmethane, 1,4-bis(4-aminophenoxy)benzene, benzidine, m-phenylenediamine, p-phenylenediamine, 1,5-naphthalenediamine, 2,6-naphthalenediamine,

bis(4-aminophenoxy)biphenyl, bis{4-(4-aminophenoxy)phenyl}ether, 1,4-bis(4-aminophenoxy)benzene, 2,2'-dimethyl-4,4'-diaminobiphenyl, 2,2'-diethyl-4,4'-diaminobiphenyl, 3,3'-dimethyl-4,4'-diaminobiphenyl, 3,3'-diethyl-4,4'-diaminobiphenyl, 2,2',3,3'-tetramethyl-4,4'-diaminobiphenyl, 3,3',4,4'-tetramethyl-4,4'-diaminobiphenyl, 2,2'-di(trifluoromethyl)-4,4'-diaminobiphenyl, 9,9-bis(4-aminophenyl)fluorene, compounds obtained by substituting at least part of hydrogen atoms of aromatic rings of these compounds with alkyl groups or halogen atoms, aliphatic cyclohexyldiamine, methylenebis cyclohexylamine, and diamines having the structure shown below. Two or more of these may be used. [0032] [Chemical Formula 5]

[0033]
R10 represents an oxygen atom, C(CF3)2, or C(CH3)2- R11 to R14 each independently represent a hydrogen atom or a hydroxyl group. [0034]
These diamines can be used as diamines, or as corresponding diisocyanate compounds or trimethylsilylated diamines. [0035]
Moreover, resins having an acidic group at the main chain end can be obtained by capping the end of the above-mentioned resins with a monoamine having an acidic group, an acid anhydride, a monocarboxylic acid monoacid chloride, or a mono-active ester. [0036]
Preferred examples of the monoamine having an acidic group include 5-amino-8-hydroxyquinoline,

l-hydroxy-7-aminonaphthalene, l-hydroxy-6-aminonaphthalene, l-hydroxy-5-aminonaphthalene, l-hydroxy-4-aminonaphthalene, 2-hydroxy-7-aminonaphthalene, 2-hydroxy-6-aminonaphthalene, 2-hydroxy-5-aminonaphthalene, l-carboxy-7-aminonaphthalene, l-carboxy-6-aminonaphthalene, l-carboxy-5-aminonaphthalene, 2-carboxy-7-aminonaphthalene, 2-carboxy-6-aminonaphthalene, 2-carboxy-5-aminonaphthalene, 2-aminobenzoic acid, 3-aminobenzoic acid, 4-aminobenzoic acid, 4-aminosalicylic acid, 5-aminosalicylic acid, 6-aminosalicylic acid, 3-amino-4,6-dihydroxypyrimidine, 2-aminophenol, 3-aminophenol, 4-aminophenol, 2-aminothiophenol, 3-aminothiophenol, and 4-aminothiophenol. Two or more of these may be used. [0037]
Preferred examples of the acid anhydride, acid chloride, and monocarboxylic acid include acid anhydrides such as phthalic anhydride, maleic anhydride, nadic anhydride, cyclohexanedicarboxylic anhydride, and 3-hydroxyphthalic anhydride, monocarboxylic acids such as 3-carboxyphenol, 4-carboxyphenol, 3-carboxythiophenol, 4-carboxythiophenol, 1-hydroxy-7-carboxynaphthalene, 1-hydroxy-6-carboxynaphthalene, 1-hydroxy-5-carboxynaphthalene, 1-mercapto-7-carboxynaphthalene, l-mercapto-6-carboxynaphthalene, and

l-mercapto-5-carboxynaphthalene, monoacid chlorides in which
a carboxyl group of these compounds is converted to an acid
chloride, monoacid chlorides in which only one carboxyl group
of dicarboxylic acids, such as terephthalic acid, phthalic acid,
maleic acid, cyclohexanedicarboxylic acid,
1,5-dicarboxynaphthalene, 1,6-dicarboxynaphthalene,
1,7-dicarboxynaphthalene, and 2,6-dicarboxynaphthalene is
converted to an acid chloride, and mono-active esters obtained
by reaction of a monoacid chloride with N-hydroxybenzotriazole
or N-hydroxy-5-norbornene-2,3-dicarboximide. Two or more of
these may be used.
[0038]
The content of the end-capping agent such as the monoamine, acid anhydride, monocarboxylic acid, monoacid chloride, and mono-active ester is preferably 2 to 25 mol% based on 100 mol% in total of the acid component and the amine component constituting the resin. [0039]
The end-capping agent introduced into the resin can be easily detected by the following method. The end-capping agent can be easily detected by dissolving a resin containing the end-capping agent introduced therein in an acidic solution to decompose the resin into an amine component and an acid component which are constituent units of the resin, and analyzing the components by gas chromatography (GC) or NMR, for

example. Alternatively, it is also possible to detect the end-capping agent by directly analyzing the resin containing the end-capping agent introduced therein through pyrolysis gas chromatograph (PGC), infrared spectrum, and 13C-NMR spectrum. [0040]
The amide group- and/or imide group-containing alkali-soluble resin (A) used in the present invention can be synthesized by a known method. [0041]
In the case of a polyamic acid or a polyamic acid ester, for example, the amide group- and/or imide group-containing alkali-soluble resin can be synthesized by a method of reacting a tetracarboxylic dianhydride with a diamine compound at low temperature, a method of obtaining a diester from a tetracarboxylic dianhydride and an alcohol, and then reacting the diester in the presence of an amine and a condensing agent, or a method of obtaining a diester from a tetracarboxylic dianhydride and an alcohol, then converting the remaining dicarboxylic acid to an acid chloride, and reacting the acid chloride with an amine. [0042]
In the case of the polybenzoxazole precursor, for example, it can be obtained by condensing a bisaminophenol compound with a dicarboxylic acid. Specifically, there is a method of reacting a dehydrating condensing agent such as

dicyclohexylcarbodiimide (DCC) with an acid, and adding a bisaminophenol compound to the resultant mixture, and a method of dropwise adding a solution of a dicarboxylic acid dichloride to a solution of a bisaminophenol compound containing a tertiary amine such as pyridine. [0043]
In the case of the polyimide, for example, it can be obtained by dehydration ring closure of a polyamic acid or a polyamic acid ester, which is obtained by the above-mentioned method, through heating or chemical treatment with an acid or a base. [0044]
The photosensitive resin composition for thin film transistors of the present invention contains the photosensitive compound (B) . The photosensitive compound is a compound whose chemical structure changes when the compound senses ultraviolet rays. Specific examples of the photosensitive compound include photoacid generators, photobase generators, and photoradical generators . Among them, a photoacid generator generates an acid in a light irradiated part and increases the solubility of the light irradiated part in an alkaline aqueous solution, so that it can give a positive pattern in which the light irradiated part is soluble. A photobase generator generates a base in a light irradiated part and decreases the solubility of the light irradiated part in

an alkaline aqueous solution, so that it can give a negative pattern in which the light irradiated part is insolubilized. A photoradical generator generates a radical in a light irradiated part and decreases the solubility of the light irradiated part in an alkaline aqueous solution when used in combination with a radical reactive compound such as an ethylenic double bond, so that it can give a negative pattern in which the light irradiated part is insolubilized. [0045]
Among the examples of the photosensitive compound (B), a photoacid generator is preferred from the viewpoint that it is easy to give a pattern with high sensitivity and high resolution. Examples of the photoacid generator include quinonediazide compounds, sulfonium salts, phosphonium salts, diazonium salts, and iodonium salts. The photosensitive compound (B) is more preferably a quinonediazide compound among photoacid generators, since the compound easily gives a pattern with high sensitivity and high resolution without undergoing heat treatment after exposure. [0046]
A preferred quinonediazide compound is a compound in which a sulfonic acid of naphthoquinonediazidesulfonic acid is ester-bonded to a phenolic hydroxyl group-containing compound. Examples of the phenolic hydroxyl group-containing compound used in the present invention include Bis-Z, BisP-EZ,

TekP-4HBPA, TrisP-HAP, TrisP-PA, TrisP-SA, TrisOCR-PA, BisOCHP-Z, BisP-MZ, BisP-PZ, BisP-IPZ, BisOCP-IPZ, BisP-CP, BisRS-2P, BisRS-3P, BisP-OCHP, methylenetris-FR-CR, BisRS-26X, DML-MBPC, DML-MBOC, DML-OCHP, DML-PCHP, DML-PC, DML-PTBP, DML-34X, DML-EP, DML-POP, dimethylol-BisOC-P, DML-PFP, DML-PSBP, DML-MTrisPC, TriML-P, TriML-35XL, TML-BP, TML-HQ, TML-pp-BPF, TML-BPA, TMOM-BP, HML-TPPHBA, and HML-TPHAP (trade names, all available from Honshu Chemical Industry Co. , Ltd.), BIR-OC, BIP-PC, BIR-PC, BIR-PTBP, BIR-PCHP, BIP-BIOC-F, 4PC, BIR-BIPC-F, TEP-BIP-A, 46DMOC, 46DMOEP, and TM-BIP-A (trade names, all available from ASAHI YUKIZAI CORPORATION), and 2,6-dimethoxymethyl-4-tert-butylphenol,
2,6-dimethoxymethyl-p-cresol, 2,6-diacetoxymethyl-p-cresol, naphthol, tetrahydroxybenzophenone, gallic acid methyl ester, bisphenol A, bisphenol E, methylene bisphenol, and BisP-AP (trade names, all available from Honshu Chemical Industry Co., Ltd. ) . Preferred examples of the quinonediazide compound used in the present invention include those obtained by introducing 4-naphthoquinonediazidesulfonic acid or 5-naphthoquinonediazidesulfonic acid into the phenolic hydroxyl group-containing compound by an ester bond, but compounds other than these can also be used. [0047]
The 4-naphthoquinone diazide sulf onyl ester compound has absorption in the i-line region of a mercury lamp, and is

suitable for i-line exposure. Absorption of the 5-naphthoquinone diazide sulfonyl ester compound is extended to the g-line region of a mercury lamp, and the compound is suitable for g-line exposure. In the present invention, both the 4-naphthoquinone diazide sulfonyl ester compound and 5-naphthoquinone diazide sulfonyl ester compound can be preferably used, and it is preferred to select either the 4-naphthoquinone diazide sulfonyl ester compound or 5-naphthoquinone diazide sulfonyl ester compound depending on the wavelength during exposure. Further, a naphthoquinone diazide sulfonyl ester compound containing both a 4-naphthoquinonediazidesulfonyl group and a
5-naphthoquinonediazidesulfonyl group in one molecule can be obtained, or a mixture of a 4-naphthoquinone diazide sulfonyl ester compound and a 5-naphthoquinone diazide sulfonyl ester compound can be used. [0048]
More preferably,, the quinonediazide compound contains a 4-naphthoquinone diazide sulfonyl ester compound. The quinone diazide structure and the sulfonyl ester structure of the ' 4-naphthoquinone diazide sulfonyl ester compound are more easily thermally decomposed than those structures of the 5-naphthoquinone diazide sulfonyl ester compound. Therefore, incorporation of the 4-naphthoquinone diazide sulfonyl ester compound makes it easier for components low in heat resistance

to be removed outside the film in the thermal curing step to reduce the components originated from outgassing remaining in the cured film. As a result, it becomes easier to provide a thin film transistor that is extremely small in the amount of outgassing from the insulating layer and is excellent in driving performance. The content of the 4-naphthoguinone diazide sulfonyl ester compound in the total content of the photosensitive compound (B) is preferably 50% by mass or more, more preferably 70% by mass, further preferably 100% by mass. [0049]
The naphthoquinone diazide sulfonyl ester compound can be synthesized by an esterification reaction of a phenolic hydroxyl group-containing compound and a naphthoquinonediazidesulfonic acid compound, and can be synthesized by a known method. Use of such naphthoquinone diazide sulfonyl ester compound further improves the resolution, sensitivity, and residual film ratio. [0050]
The content of the photosensitive compound (B) used in the present invention is preferably 0.1 parts by mass or more, more preferably 1 part by mass or more, further preferably 2 parts by mass or more, and is preferably 20 parts by mass or less, more preferably 14 parts by mass or less, further preferably 10 parts by mass or less based on 100 parts by mass of the amide group- and/or imide group-containing

alkali-soluble resin (A) . When the content is 0 .1 parts by mass or more, pattern formation is facilitated, whereas when the content is 20 parts by mass or less, the amount of outgassing from the photosensitive compound can be easily suppressed. [0051]
The photosensitive resin composition for thin film transistors of the present invention contains the organic solvent (C) . The organic solvent may be used singly, or it may be a mixed solvent of two or more solvents. It is essential that the content of the nitrogen atom-containing organic solvent is 1% by mass or less based on the organic solvent in total.
[0052]
As a result of intensive studies, the inventors have found the following matter: a nitrogen atom-containing organic solvent has very high affinity with an amide group and/or an imide group contained in a resin skeleton of the amide group-and/or imide group-containing alkali-soluble resin (A), and thus the organic solvent is hardly removed in the thermal curing step even when contained in a small amount and remains in the cured insulating layer, so that the driving performance of the thin film transistor especially at high temperature is lowered.
[0053]
Examples of the nitrogen atom-containing organic solvent include those having a functional group such as an amide group,

a urethane group, and a urea group. Specific examples thereof include 2-pyrrolidone, N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N-propyl-2-pyrrolidone, N-butyl-2-pyrrolidone, N-cyclohexyl-2-pyrrolidone, N-(2-hydroxyethyl)-2-pyrrolidone, N-phenyl-2-pyrrolidone, N-vinyl-2-pyrrolidone, N,N'-dimethylpropyleneurea, 1,3-dimethyl-2-imidazolidinone, 2-piperidone, e-caprolactam, N,N-dimethylformamide, N,N-diethylformamide, N,N-dimethylacetamide, N,N-diethylacetamide, N,N-dimethylmethoxyacetamide, N,N-dimethylisobutyramide, N,N-dimethylmethoxyethylamide, 3-methoxy-N,N-dimethylpropionamide,
3-butoxy-N,N-dimethylpropionamide, acetamide, benzamide, naphthamide, isophthalamide, terephthalamide, nicotinamide, isonicotinamide, formamide, propionamide, butyramide, isobutyramide, oxamide, benzylamide, triacetamide, dibenzamide, tribenzamide, urea, butylurea, dibutylurea, 1,3-dimethylurea, 1,3-diethylurea, glutaramide, butanediamide, hexanediamide, 1,3-dimethyl-2-imidazolidinone, ethyl N-methylcarbamate, urea, butylurea, dibutylurea, 1,3-dimethylurea, 1,3-diethylurea,
N,N'-dimethylpropyleneurea, methoxy-N,N-dimethylpropion, butoxy-N,N-dimethylpropion, and derivatives thereof. These nitrogen atom-containing organic solvents all have high polarity and well dissolve the amide group- and/or imide

group-containing alkali-soluble resin (A), and thus are suitably used as organic solvents for such resin. However, the inventors found that, in the application to the insulating layer of the thin film transistor of the present invention, the nitrogen atom-containing organic solvent remains in the cured insulating layer even when thermally cured at a temperature higher than the boiling point of the solvent. The inventors also found that this trace amount of residual solvent lowers the driving performance of the thin film transistor. Therefore, in the present invention, it is essential that the content of the nitrogen atom-containing organic solvent is 1% by mass or less based on the organic solvent in total. [0054]
The content of the nitrogen atom-containing organic solvent in the organic solvent (C) is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, essentially 1% by mass or less, and is preferably 0.5% by mass or less, more preferably 0.3% by mass or less based on the organic solvent in total. Setting the content to 0.01% by mass or more makes it possible to suppress the deposition of foreign matters to reduce the occurrence of defective characteristics of the insulating film caused by the foreign matters even when the photosensitive resin composition for thin film transistors is stored at low temperature of -10°C or lower for a long period of time. As used herein, the term "foreign matters" refers to

organic fine particles produced by agglomeration and insolubilization of part of the photosensitive resin composition components dissolved in an organic solvent, in particular, the amide group- and/or imide group-containing alkali-soluble resin (A) . The nitrogen atom-containing organic solvent has very high affinity with the amide group and/or imide group contained in the resin skeleton of the amide group- and/or imide group-containing alkali-soluble resin (A) . It is considered that incorporation of a nitrogen atom-containing organic solvent in a very small amount at which the driving performance of the thin film transistor is not lowered suppresses agglomeration of resin components even when the photosensitive resin composition for thin film transistors is stored at' low temperature for a long period of time.
[0055]
Among the nitrogen atom-containing organic solvents, examples of solvents that are particularly excellent in the effect of suppressing the deposition of foreign matters include N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N,N-dimethylformamide, N,N-diethylformamide, N,N-dimethylacetam.ide, N, N-diethylacetamide, 1,3-dimethyl-2-imidazolidinone, and N,N-dimethylisobutyramide.
[0056]
Further, it is preferred that the content of the organic

solvent satisfying the following (1) and (2) in the organic solvent (C) is 80% by mass or more based on the organic solvent in total:
(1) a solubility parameter of 8. 0 or more and 11. 0 or less
[unit: (cal/cm3)1/2] ; and
(2) an organic compound composed of a carbon atom, a
hydrogen atom, and an oxygen atom.
First, an organic solvent having (1) a solubility parameter of 8.0 or more and 11.0 or less, which is the first requirement for the organic solvent, will be described. Herein, the solubility parameter is used as an index of compatibility and affinity among a plurality of substances, and is defined by the expression represented by the following (Formula 1). [0057]
8 = (AEv/V0)1/2/2.046 [ (cal/cm3)1/2] • • (Formula 1) In Formula 1, AEV [106N'm*mol_1] is the heat of evaporation, and V0 [m3*mol_1] is the volume per mole. Values of the solubility parameter are smaller for those with lower polarity and larger for those with higher polarity. For example, solubility parameters of n-hexane, ethanol, and water are 7.3, 12.7, and 23.4, respectively. A difference in solubility parameter between two substances is closely related to the energy required for the two substances to be compatible with each other. As the difference in solubility parameter is smaller, the energy required for the two substances to be

compatible with each other is smaller. That is, when there are two substances, in general, the smaller the difference in solubility parameter is, the higher the affinity and compatibility are between the two substances. [0058]
The solubility parameter can be determined experimentally, and can also be determined by calculation. A method of determining the solubility parameter by calculation maybe, for example, a method proposed by Fedors et al. (POLYMER ENGINEERING AND SCIENCE, FEBRUARY, 1974, Vol. 14, No. 2, ROBERT F. FEDORS.). In addition, data on solubility parameters of various organic solvents are described in "POLYMER HANDBOOK FORTH EDITION" (WILEY-INTERSCIENCE). [0059]
In the present invention, a preferred range of the solubility parameter is 8 . 0 or more, more preferably 8 . 4 or more, and is 11.0 or less, more preferably 10.6 or less. Setting the solubility parameter to 8.0 or more makes it possible to sufficiently dissolve the amide group- and/or imide group-containing alkali-soluble resin (A). Selecting an organic solvent which has a solubility parameter of 11.0 or less and satisfies the second requirement makes it possible to easily remove the organic solvent in the step of thermally curing the photosensitive resin and sufficiently reduce the organic solvent remaining in the cured insulating layer, so that

excellent driving performance can be easily exerted. The
reason therefor will be further described below.
[0060]
In general, when there are two substances, the smaller the difference in solubility parameter is, the higher the affinity and compatibility are between the two substances. Therefore, it is preferred to select an organic solvent having a-solubility parameter close to that of the resin. The amide group- and/or imide group-containing alkali-soluble resin (A) used in the present invention is a highly polar resin because it has an amide group and/or an imide group, and many polar groups for imparting alkali solubility, such as a carboxyl group,'a phenolic hydroxyl group, a sulfonic acid group, and a thiol group in its skeleton, and thus has high solubility parameter. In the case of a polyimide, a polyimide precursor, or a polybenzoxazole precursor which can be used as an alkali-soluble resin, the solubility parameter is generally in the range of 12 . 0 to 16.0. A highly polar solvent having high affinity with the resin, that is, a highly polar solvent having a solubility parameter close to that of the resin is excellent in terms of solubility, but it is difficult to remove the organic solvent in the step of thermally curing the photosensitive resin due to the high affinity. [0061]
In contrast, the organic solvent preferably used in the

present invention has a solubility parameter of 11.0 or less, and an organic solvent having a solubility parameter separate from that of the resin is selected. This means that the affinity between the organic solvent and the resin is relatively low. Since the affinity is low, the organic solvent is easily removed in the step of thermally curing the photosensitive resin, and the organic solvent remaining in the cured insulating layer can be sufficiently reduced. This makes it easier to give a thin film transistor with less outgassing from the insulating layer and excellent in driving performance. [0062]
Next, the second requirement for the organic solvent, ' that is, the organic solvent is (2) an organic compound composed of a carbon atom, a hydrogen atom, and an oxygen atom will be described. The organic solvent can moderately improve the solubility of the amide group- and/or imide group-containing alkali-soluble resin (A) used in the present invention because of a solvation capability originating from a lone pair of the oxygen atom in the molecular structure of the solvent. On the other hand, in an organic solvent having a nitrogen atom in the molecular structure, examples of which include those having a functional group such as an amide group, a urethane group, and a urea group, the organic solvent is hardly removed in the step of thermally curing the resin because the functional group is very high in affinity with an amide group or an imide group

contained in the resin skeleton, and the organic solvent remains in the cured insulating layer, so that the driving performance of the thin film transistor is adversely affected. Therefore, it is preferred that the organic solvent is an organic compound composed of a carbon atom, a hydrogen atom, and an oxygen atom. Examples of such a chemical structure include an ether group, an alcohol group, an ester group, and a ketone group. [0063]
Examples of the organic solvent satisfying (1) and (2) include ethylene glycol mono-n-butyl ether (9.5, 171°C) , diethylene glycol monomethyl ether (10.7, 194°C), diethylene glycol monoethyl ether (10.4, 202°C), diethylene glycol mono-n-butyl ether (9.5, 230°C) , diethylene glycol dimethyl ether (8.8, 162°C) , diethylene glycol, ethyl methyl ether (8.7, 176°C), diethylene glycol diethyl ether (8.6, 189°C) , propylene glycol monomethyl ether (10.1, 120°C) , dipropylene glycol monomethyl ether (9.3, 188°C), dipropylene glycol dimethyl ether (8.2, 171°C) , cyclohexanone (9.9, 156°C) , cyclopentanone (10.4, 130°C) , 2-hexanone (8.9, 128°C), diacetone alcohol (9.2, 166°C) , propylene glycol monomethyl acetate (8.7, 146°C) , ethyl lactate (10.0, 155°C) , butyl lactate (9.4, 185°C) , n-butyl acetate (8.5, 126°C) , 3-methoxybutyl acetate (8.7, 173°C) , 3-methyl-3-methylbutyl acetate (9.3, 188°C), and ethyl ethoxypropionate (8.9, 166°C) . The numerical values in the parentheses after the names of the organic solvents indicate

the solubility parameter [unit: (cal/cm3)1/2] and the boiling point at atmospheric pressure in order. [0064]
The content of the organic solvent satisfying (1) and (2) in the organic solvent (C) is preferably 80% by mass or more, more preferably 90% by mass or more, further preferably 99% by mass or more based on the organic solvent in total. When the content is 80% by mass or more, the organic solvent remaining in the cured insulating layer can be sufficiently reduced. [0065]
As the organic solvent (C) used in the present invention, an organic solvent other than the organic solvent satisfying (1) and (2) can be used together according to the purpose. [0066]
In the photosensitive resin composition for thin film
transistors of the present invention, the organic solvent (C)
satisfying (1) and (2) preferably further satisfies the
following (3):
(3) a boiling point at atmospheric pressure of 100°C or
higher and 18 0°C or lower.
Selecting an organic solvent having a boiling point at
atmospheric pressure of 100°C or higher makes it possible to prevent poor coating due to too high solvent volatility, and selecting an organic solvent having a boiling point at atmospheric pressure of 180°C or lower makes it possible to

further reduce the organic solvent remaining in the cured
insulating layer.
[0067]
The content of the organic solvent (C) used in the present invention is preferably 100 to 2,000 parts by mass based on 100 parts by mass of the amide group- and/or imide group-containing alkali-soluble resin (A) . [0068]
Incidentally, the organic solvent (C) used in the present invention includes not only organic solvents intentionally added for dissolving the resin composition but also organic solvents contained as impurities in the photosensitive resin composition for thin film transistors. [0069]
The photosensitive resin composition for thin film transistors of the present invention can contain a thermal crosslinking agent. The term "thermal crosslinking agent" refers to a compound having at least two thermally reactive functional groups, such as an alkoxymethyl group, a methylol group, an epoxy group, and an oxetanyl group in the molecule. The thermal crosslinking agent can crosslink the amide group-and/or imide group-containing alkali-soluble resin (A) or other additive components to improve the heat resistance, chemical resistance, and hardness of the thermally cured film. [0070]

Preferred examples of the compound having at least two alkoxymethyl groups or methylol groups include DML-PC, DML-PEP, DML-OC, DML-OEP, DML-34X, DML-PTBP, DML-PCHP, DML-OCHP, DML-PFP, DML-PSBP, DML-POP, DML-MBOC, DML-MBPC, DML-MTrisPC, DML-BisOC-Z, DML-BisOCHP-Z, DML-BPC, DML-BisOC-P, DMOM-PC, DMOM-PTBP, DMOM-MBPC, TriML-P, TriML-35XL, TML-HQ, TML-BP, TML-pp-BPF, TML-BPE, TML-BPA, TML-BPAF, TML-BPAP, TMOM-BP, TMOM-BPE, TMOM-BPA, TMOM-BPAF, TMOM-BPAP, HML-TPPHBA, HML-TPHAP, HMOM-TPPHBA, and HMOM-TPHAP (trade names, all manufactured by Honshu Chemical Industry Co., Ltd.), and NIKALAC (registered trademark) MX-290, NIKALAC MX-280, NIKALAC MX-270, NIKALAC MX-279, NIKALAC MW-100 LM, and NIKALAC MX-750 LM (trade names, all manufactured by SANWA Chemical Co. , Ltd. ) , which are available from the respective companies mentioned above. [0071]
Preferred examples of the compound having at least two epoxy groups include Epolight 40E, Epolight 100E, Epolight 200E, Epolight 400E, Epolight 70P, Epolight 200P, Epolight 400P, Epolight 1500NP, Epolight 80MF, Epolight 4000, and Epolight 3002 (all manufactured by Kyoeisha Chemical Co. , Ltd.), Denacol (registered trademark) EX-212L, Denacol EX-214L, Denacol EX-216L, Denacol EX-321L, and Denacol EX-850L (all manufactured by Nagase ChemteX Corporation), Epikote 828, Epikote 1002, Epikote 1750, Epikote 1007, YX8100-BH30, E1256, E4250, and

E4275 (all manufactured by Japan Epoxy Resin Co. , Ltd.), EPICLON (registered trademark) EXA-9583, HP4032, HP7300, and N695 (all manufactured by DIC Corporation), VG 3101 (manufactured by Mitsui Chemicals, Inc.), TEPIC (registered trademark) S, TEPIC G, and TEPIC P (all manufactured by Nissan Chemical Industries, Ltd.), EPOTOHTO (registered trademark) YH-434L (manufactured by NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.) , and EPPN 502 H, NC3000, NC 6000, GAN, and GOT (all manufactured by Nippon Kayaku Co., Ltd.), which are available from the respective companies mentioned above. [0072]
Preferred examples of the compound having at least two oxetanyl groups include ETERNACOLL (registered trademark) EHO, ETERNACOLL OXBP, ETERNACOLL OXTP, and ETERNACOLL OXMA (all manufactured by Ube Industries, Ltd.), and oxetanized phenol novolac. [0073]
Two or more kinds of thermal crosslinking agents may be used in combination. [0074]
The content of the thermal crosslinking agent is preferably 0.1 parts by mass or more and 30 parts by mass or less based on 100 parts by mass of the amide group- and/or imide group-containing alkali-soluble resin (A) . When the content of the thermal crosslinking agent is 0.1 parts by mass or more

and 30 parts by mass or less, the chemical resistance and hardness of the film after firing or after curing can be improved easily, and the storage stability of the photosensitive resin composition for thin film transistors can also be improved easily. [0075]
The photosensitive resin composition for thin film transistors of the present invention preferably further contains (D) an adhesion improver. Examples of the adhesion improver (D) include silane coupling agents such as vinyltrimethoxysilane, vinyltriethoxysilane, epoxycyclohexylethyltrimethoxysilane, 3-glycidoxypropyltrimethoxysilane,
3-glycidoxypropyltriethoxysilane, p-styryltrimethoxysilane, 3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane, and N-phenyl-3-aminopropyltrimethoxysilane, a titanium chelating agent, an aluminum chelating agent, and a compound obtained by reacting an aromatic amine compound with an alkoxy group-containing silicon compound. The photosensitive resin composition for thin film transistors may contain two or more of these. Incorporation of the adhesion improver (D) makes it possible to enhance the adhesion to an underlying base material such as a silicon wafer, ITO, Si02, and silicon nitride at the time of development of the photosensitive resin film. In addition, resistance to oxygen plasma and UV ozone treatment

used for cleaning and the like can be enhanced. Further, the driving performance of the thin film transistor can be further improved. Although the mechanism is not clear, it is presumed that the driving performance of the thin film transistor is further improved by the incorporation of an adhesion improver since the adhesion improver increases the adhesion to the underlying base material and makes it difficult for the resin composition to peel off the underlying base material even under severe conditions such as high temperature and high humidity. [0076]
The adhesion improver (D) preferably contains a nitrogen atom-containing silane coupling agent. This is because the nitrogen atom-containing silane coupling agent has high affinity with the amide group- and/or imide group-containing alkali-soluble resin (A) , and has a particularly high adhesion improving effect. Examples of the nitrogen atom-containing silane coupling agent include 3-aminopropyltrimethoxysilane, 3-aminopropyltriethoxysilane,
3-triethoxysilyl-N-(1,3-dimethylbutylidene)propylamine, N-phenyl-3-aminopropyltrimethoxysilane, 3-ureidopropyltriethoxysilane,
3-(2-aminoethyl)aminopropyltrimethoxysilane, and 3-(2-aminoethyl)aminopropylmethyldimethoxysilane. [0077]
The content of the adhesion improver (D) is preferably

0.1 parts by mass or more and 10 parts by mass or less based on 100 parts by mass of the amide group- and/or imide group-containing alkali-soluble resin (A). [0078]
The photosensitive resin composition for thin film transistors of the present invention may optionally contain a surfactant for the purpose of improving the wettability with the substrate and improving the thickness uniformity of the coating film. The surfactant can be a commercially available compound. Specific examples of the surfactant include silicone surfactants such as SH series, SD series, and ST series manufactured by Dow Corning Toray Silicone Company, Ltd., BYK series manufactured by BYK Japan KK, KP series manufactured by Shin-Etsu Silicone, DISFOAM series manufactured by NOF Corporation, and TSF series manufactured by Toshiba Silicone Co., Ltd., fluorine-containing surfactants such as "Megafac (registered trademark)" series manufactured by Dainippon Ink & Chemicals, Inc., FLUORAD series manufacture by Sumitomo 3M Limited, "SURFLON (registered trademark)" series and "AsahiGuard (registered trademark)" series manufactured by Asahi Glass Co., Ltd., EF series manufactured by Shin-Akita Kasei K.K. , and PolyFox series manufactured by OMNOVA Solutions, and surfactants made from an acrylic and/or methacrylic polymer such as POLYFLOW series manufactured by KYOEISHA CHEMICAL Co. , LTD., and "DISPARLON (registered trademark)" series

manufactured by Kusumoto Chemicals, Ltd., which are available from the respective companies mentioned above, but are not particularly limited thereto. [0079]
The content of the surfactant is preferably 0.001 parts by mass or more and 1 part by mass or less based on 100 parts by mass of the amide group- and/or imide group-containing alkali-soluble resin (A). Setting the content in the above-mentioned range makes it possible to improve the wettability with the substrate and the thickness uniformity of the coating film without causing defects such as air bubbles and pinholes. [0080]
The photosensitive resin composition for thin film transistors of the present invention may optionally contain a phenolic hydroxyl group-containing compound for the purpose of supplementing the alkali developability of the photosensitive resin composition for thin film transistors. Examples of the phenolic hydroxyl group-containing compound include Bis-Z, BisOC-Z, BisOPP-Z, BisP-CP, Bis26X-Z, BisOTBP-Z, BisOCHP-Z, BisOCR-CP, BisP-MZ, BisP-EZ, Bis26X-CP, BisP-PZ, BisP-IPZ, BisCRIPZ, BisOCP-IPZ, BisOIPP-CP, Bis26X-IPZ, BisOTBP-CP, TekP-4HBPA (tetrakis P-DO-BPA), TrisPHAP, TrisP-PA, TrisP-PHBA, TrisP-SA, TrisOCR-PA, BisOFP-Z, BisRS-2P, BisPG-26X, BisRS-3P, BisOC-OCHP, BisPC-OCHP, Bis25X-OCHP,

Bis26X-OCHP, BisOCHP-OC, Bis236T-OCHP, methylenetris-FR-CR, BisRS-26X, and BisRS-OCHP (trade names, all available from Honshu Chemical Industry Co., Ltd.), BIR-OC, BIP-PCBIR-PC, BIR-PTBP, BIR-PCHP, BIP-BIOC-F, 4PC, BIR-BIPC-F, and TEP-BIP-A (trade names, all available from ASAHI YUKIZAI CORPORATION), 1, 4-dihydroxynaphthalene, 1,5-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, 2,3-dihydroxynaphthalene, 2,6-dihydroxynaphthalene, 2,7-dihydroxynaphthalene, 2,4-dihydroxyquinoline, 2,6-dihydroxyquinoline, 2,3-dihydroxyquinoxaline, anthracene-1,2,10-triol, anthracene-1,8,9-triol, and 8-quinolinol. Incorporation of these phenolic hydroxyl group-containing compounds makes the resultant photosensitive resin composition for thin film transistors hardly soluble in an alkali developer before exposure and easily soluble in an alkali developer after exposure. Thus, film reduction due to development is small, and the photosensitive resin composition is easily developed in a short time. Therefore, the sensitivity is easily improved. [0081]
The content of the phenolic hydroxyl group-containing compound is preferably 1 part by mass or more and 20 parts by mass or less based on 100 parts by mass of the amide group- and/or imide group-containing alkali-soluble resin (A). When the content is within the above-mentioned range, it is possible to

enhance the alkali developability of the photosensitive resin composition for thin film transistors while maintaining high heat resistance. [0082]
The photosensitive resin composition for thin film transistors of the present invention may contain inorganic particles for the purpose of improving the relative permittivity and hardness of the cured film, and reducing the coefficient of linear thermal expansion thereof. Preferred specific examples of the inorganic particles include silicon oxide, titanium oxide, barium titanate, barium sulfate, barium oxide, zirconium oxide, hafnium oxide, tantalum oxide, tungsten oxide, yttrium oxide, alumina, and talc. In particular, for the purpose of improving the relative permittivity of the cured film, those having a relative permittivity (sr) of 20 or more, such as titanium oxide (sr - 115), zirconium oxide (er = 30), barium titanate (sr = 400) , and hafnium oxide (sr = 25) can be mentioned as particularly preferred examples, but the inorganic particles are not limited thereto. The primary particle size of the inorganic particles is preferably 100 nm or less, more preferably 60 nm or less. [0083]
The content of the inorganic particles is preferably 5 parts by mass or more and 500 parts by mass or less based on 100 parts by mass of the amide group- and/or imide

group-containing alkali-soluble resin (A). Setting the content in the above-mentioned range makes it possible to develop the above-mentioned effects of adding the inorganic particles, such as improvement in the relative permittivity with the alkali developing performance being maintained. [0084]
The photosensitive resin composition for thin film transistors of the present invention may contain a thermal acid generator. The thermal acid generator generates an acid by heating, and accelerates the crosslinking reaction of the thermal crosslinking agent. Moreover, when the amide group-and/or imide group-containing alkali-soluble resin (A) has an imide ring structure or an oxazole ring structure that are not closed, the thermal acid generator can promote the cyclization of these structures and further improve the mechanical properties of the cured film. [0085]
The thermal acid generator used in the present invention preferably has a thermal decomposition starting temperature of 50°C to 270°C, more preferably 250°C or lower. It is preferred to select a thermal acid generator that does not generate an acid in the drying (pre-baking: about 70 to 140°C) after the photosensitive resin composition for thin film transistors of the present invention is applied to the substrate, and generates an acid in the final heating (curing: about 100 to 400°C) after

the patterning including exposure and development, because the reduction in sensitivity at the time of development can be suppressed. [0086]
The acid generated from the thermal acid generator used in the present invention is preferably a strong acid. Preferred examples of the strong acid include arylsulfonic acids such as p-toluenesulfonic acid and benzenesulfonic acid, alkylsulfonic acids such as methanesulfonic acid, ethanesulfonic acid, propanesulfonic acid, and butanesulfonic acid, and haloalkylsulfonic acids such as
trifluoromethylsulfonic acid. They are used as a salt such as an onium salt or as a covalent compound such as an imidosulf onate. The photosensitive resin composition for thin film transistors may contain two or more of these.
[0087]
The content of the thermal acid generator used in the present invention is preferably 0.01 parts by mass or/more and 10 parts by mass or less based on 100 parts by mass of the amide group- and/or imide group-containing alkali-soluble resin (A) . Setting the content in the above-mentioned range makes it possible to develop the above-mentioned effects of adding the thermal acid generator with the high heat resistance being maintained.
[0088]

Next, a method for preparing the photosensitive resin composition for thin film transistors of the present invention will be described. For example, the photosensitive resin composition for thin film transistors can be obtained by dissolving the components (A) to (C) and, if necessary, a thermal crosslinking agent, an adhesion improver, a surfactant, a phenolic hydroxyl group-containing compound, inorganic particles, a thermal acid generator, and the like. As a dissolution method, stirring and heating can be mentioned. In the case of heating, the heating temperature is preferably set within a range in which the performance of the photosensitive resin composition for thin film transistors is not impaired, and the heating temperature is usually from room temperature to 80°C. In addition, the order of dissolving the components is not particularly limited, and for example, there is a method of sequentially dissolving the components starting from a compound having low solubility. Further, as for components which tend to generate air bubbles at the time of dissolution by stirring, such as a surfactant and some kind of adhesion improver, poor dissolution of other components caused by generation of air bubbles can be prevented by first dissolving such other components and lastly adding the relevant components. [0089]
It is preferred that the resultant photosensitive resin

composition for thin film transistors is filtered using a filtration filter to remove dust and particles . The filter pore size is, for example, 0.5 |jm, 0.2 |jm, 0.1 \xm, 0.07 \im, 0.05 \mf or 0.02 |am, but it is not limited thereto. Materials of the filtration filter include polypropylene (PP), polyethylene (PE), nylon (NY), polytetrafluoroethylene (PTFE) and the like, with polyethylene and nylon being preferred. [0090]
The cured film of the present invention is obtained by curing the photosensitive resin composition for thin film transistors of the present invention. Hereinafter, the method for producing the cured film of the present invention will be described in detail. [0091]
The method for producing a cured film of the present invention includes the steps of applying the photosensitive resin composition for thin film transistors of the present invention to form a photosensitive resin film, drying the photosensitive resin film, exposing the photosensitive resin film, developing the exposed photosensitive resin film, and thermally curing the photosensitive resin film. Details of the steps will be described below. In the present invention, as for the film formed on a substrate, the film after the application of the photosensitive resin composition for thin film transistors to the substrate and before the thermal curing

is referred to as a photosensitive resin film, and the film after the thermal curing is referred to as a cured film. The photosensitive resin film after the application of the photosensitive resin composition for thin film transistors and before the drying is sometimes referred to as a coating film. [0092]
First, the step of applying a photosensitive resin composition for thin film transistors to a substrate to form a photosensitive resin film will be described. In this step, the photosensitive resin composition for thin film transistors of the present invention is applied by a spin coating method, a slit coating method, a dip coating method, a spray coating method, a printing method or the like to give a coating film of the photosensitive resin composition for thin film transistors. Among them, the slit coating method is preferably used. The slit coating method is advantageous in terms of cost reduction because the resin composition can be applied with a small amount of coating liquid. The amount of the coating liquid required for the slit coating method is, for example, about 1/5 to 1/10 that of the spin coating method. The slit nozzle used for the application is not particularly limited, and those which are on the market from several manufacturers can be used. Specific examples of the slit nozzle include "Linear Coater" manufactured by Dainippon Screen Mfg. Co., Ltd., "Spinless" manufactured by TOKYO OHKA KOGYO CO., LTD., "TS

Coater" manufactured by Toray Engineering Co., Ltd., "Table Coater" manufactured by CHUGAI RO CO., LTD., "CS series" and "CL series" manufactured by Tokyo Electron Limited, "In-line type slit coater" manufactured by Thermatronics Trading, and "Head Coater HC series" manufactured by Hirata Corporation. The coating speed is generally in the range of 10 mm/sec to 400 mm/sec. The thickness of the coating film varies depending on the solid content concentration, viscosity, and the like of the photosensitive resin composition for thin film transistors, and the photosensitive resin composition is usually applied so that the film thickness after drying is 0.1 to 10 jxm, preferably 0.3 to 5 fjm. [0093]
Prior to the application, the base material to which the photosensitive resin composition for thin film transistors is applied may be pretreated with the above-mentioned adhesion improver in advance. For example, there is a method in which a solution prepared by dissolving 0.5 to 20% by mass of an adhesion improver in a solvent such as isopropanol, ethanol, methanol, water, tetrahydrofuran, propylene glycol monomethyl ether acetate, propylene glycol monomethyl ether, ethyl lactate, or diethyl adipate is used to treat a base material surface. Examples of methods for treating the base material surface include spin coating, slit die coating, bar coating, dip coating, spray coating, and steam treatment.

[0094]
Next, the step of drying the coating film, that is, the photosensitive resin film will be described. In this step, the coating film, which is obtained after application of the photosensitive resin composition for thin film transistors, is dried. Drying in this step refers to reduced-pressure drying or heat drying. Both the reduced-pressure drying and heat drying may be carried out, or only one of them may be used. [0095]
First, the reduced-pressure drying will be described. In the reduced-pressure drying, for example, a substrate having a coating film formed thereon is placed on a proxy pin disposed in a vacuum chamber, and the pressure in the vacuum chamber is reduced to dry the coating film. In this case, when the interval between the substrate and the vacuum chamber top plate is large, the air located between the substrate and the vacuum chamber top plate flows in a large quantity in connection with the reduced-pressure drying, so that fog or haze is likely to occur. Therefore, it is preferred to adjust the height of the proxy pin so as to narrow the interval. The distance between the substrate and the vacuum chamber top plate is preferably about 2 to 20 mm, more preferably 2 to 10 mm. [0096]
The reduced-pressure drying speed depends on the vacuum chamber capacity, capability of the vacuum pump, and diameter

[0210] Pilot signal generator 1430 may transmit pilot signals for the one or more UEs in one or more pilot regions of the control resource set, the one or more pilot regions spanning a bandwidth of the single carrier waveform transmission.
[0211] Control channel signal generator 1435 may transmit control channel signals for the one or more UEs in one or more control channel regions of the control resource set, the control channel signals corresponding to the pilot signals for the one or more UEs, and the one or more control channel regions spanning the bandwidth of the single carrier waveform transmission.
[0212] Transmitter 1420 may transmit signals generated by other components of the device. In some examples, the transmitter 1420 may be collocated with a receiver 1410 in a transceiver module. For example, the transmitter 1420 may be an example of aspects of the transceiver 1635 described with reference to FIG. 16. The transmitter 1420 may utilize a single antenna or a set of antennas.
[0213J FIG. 15 shows a block diagram 1500 of a base station coreset manager 1515 that supports control resource set design under single carrier waveform in accordance with aspects of the present disclosure. The base station coreset manager 1515 may be an example of aspects of a base station coreset manager 1615 described with reference to FIGs. 13, 14, and 16. The base station coreset manager 1515 may include configuration identifier 1520, pilot signal generator 1525, control channel signal generator 1530, time division multiplexer 1535, separator 1540, and configuration indicator 1545. Each of these modules may communicate, directly or indirectly, with one another (e.g., via one or more buses).
[0214] Configuration identifier 1520 may identify, at the base station, a configuration for a control resource set used to transmit control data to one or more UEs using a single carrier waveform transmission. In some cases, a first control resource set includes a first pilot region and a first control channel region, the first control channel region for a first portion of a control channel signal for a single UE, and the first pilot region for a first pilot signal corresponding to the first portion of the control channel signal for the single UE. In some cases, a second control resource set includes a second pilot region and a second control channel region, the second control channel region for a second portion of the control channel signal for the single UE, and the second pilot region for a second pilot signal corresponding to the second portion of the control channel signal for the single UE.