Title of the invention: Plasticizer composition containing cyclohexane polyester-based material and resin composition containing the same
Technical field
[One]
Mutual citation with related applications
[2]
This application claims the benefit of priority based on Korean Patent Application No. 10-2018-0081209 filed on July 12, 2018, and all contents disclosed in the documents of the Korean patent application are incorporated as part of this specification.
[3]
[4]
Technical field
[5]
The present invention relates to a plasticizer composition including a cyclohexane polyester-based material, but including a specific type of perhydride, and a resin composition including the same.
[6]
Background
[7]
Typically plasticizers react with alcohols with polycarboxylic acids such as phthalic acid and adipic acid to form corresponding esters. In addition, in consideration of domestic and foreign regulations of phthalate plasticizers that are harmful to the human body, studies on plasticizer compositions that can replace phthalate plasticizers such as terephthalate, adipate, and other polymers are continuing.
[8]
[9]
On the other hand, regardless of the plastisol industry such as flooring, wallpaper, soft and hard sheets, the calendering industry, and the extrusion/injection compound industry, the demand for these eco-friendly products is increasing, and the quality characteristics, processability and In order to enhance productivity, appropriate plasticizers should be used in consideration of discoloration, migration, and mechanical properties.
[10]
In these various fields of use, sub-materials such as plasticizers, fillers, stabilizers, viscosity reducing agents, dispersants, defoaming agents, foaming agents, etc. are mixed with the PVC resin according to the properties required for each industry, such as tensile strength, elongation, light resistance, transferability, gelling property or absorption rate Is done.
[11]
For example, in the case of applying di(2-ethylhexyl) terephthalate (DEHTP), which is the most widely used plasticizer composition with relatively inexpensive price among plasticizer compositions applicable to PVC, the hardness or sol viscosity is high and the plasticizer absorption rate Was relatively slow, and the transferability and stress transferability were not good.
[12]
As an improvement to this, di(2-ethylhexyl) cyclohexane 1,4-diester (1,4-DEHCH), which is a hydrogenated substance of DEHTP, can be considered, but while the plasticization efficiency is improved, transferability or thermal stability, etc. There is currently no solution except for adopting a method of supplementing it through mixing with other secondary plasticizers because improvement of physical properties such as this poor and mechanical properties slightly deteriorates.
[13]
Further, the above-described problems of 1,4-DEHCH obtained by hydrogenating DEHTP are the same in DEHIP and 1,3-DEHCH, and are also present in the trimyptate-based material. In addition, terephthalate-based (or isophthalate, or trimellitate) plasticizers are hydrogenated to commercialize, and in the case of terephthalate-based substances derived from lower alcohols with poor transferability, the degree of deterioration becomes worse when hydrogenated. , In the case of terephthalate-based substances derived from higher alcohols with a somewhat poor elongation, there is a problem that only the cost increases without improving the elongation during hydrogenation.For dicarboxylic acid-based hydrogenated substances, the use of alcohol with 8 or 9 carbon atoms is not recommended. It is a limited situation.
[14]
In this situation, if the transition, thermal stability, and mechanical properties due to hydrogenation and carbon number of the hydrogenated material can be improved, cost reduction due to product simplification and no blending process, reduction of plasticization efficiency due to mixing The demand for development of such a single plasticizer is steady, and in the case of a plasticizer that can be used alone, there are advantages such as the prevention of risk, increased cost competitiveness due to the use of alcohols having various carbon numbers, and ease of supply and demand of raw materials. Since it exhibits more excellent effects even in mixed use, the development of such plasticizers is continuously required.
[15]
Detailed description of the invention
Technical challenge
[16]
In the present invention, when cyclohexane polyester is used as a plasticizer, perhydrides are mixed together, but mixed in a specific amount or less, thereby improving elongation and tensile strength as the above problems such as heating loss and thermal stability, and mechanical properties. It is intended to provide a plasticizer composition, and furthermore, to provide a method of manufacturing a plasticizer composition that can be expected to improve cost competitiveness by simplifying the purification process.
[17]
Means of solving the task
[18]
According to an embodiment of the present invention in order to solve the above problems, a cyclohexane polyester-based material which is a compound represented by the following formula (1); And a compound perhydride represented by the following Formula 2; wherein the perhydride is contained in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of a cyclohexane polyester-based material.
[19]
[Formula 1]
[20]

[21]
[Formula 2]
[22]

[23]
In Formulas 1 and 2, R 1 and R 2 are each independently an alkyl group having 4 to 10 carbon atoms, R 3 is a methyl group, n is 2 or 3, m is an integer of 0 to 2, and p is 0 Is an integer of 3, m+p is an integer of 0 to 3, and nm is an integer of 1 to 3.
[24]
According to another embodiment of the present invention in order to solve the above problem, 100 parts by weight of a resin; And 5 to 150 parts by weight of the plasticizer composition described above; is provided a resin composition comprising.
[25]
The resin may be one or more selected from the group consisting of ethylene vinyl acetate, polyethylene, polypropylene, polyketone, polyvinyl chloride, polystyrene, polyurethane, synthetic rubber, natural rubber and thermoplastic elastomer.
[26]
Effects of the Invention
[27]
The plasticizer composition according to an embodiment of the present invention, when used in a resin composition, improves mechanical properties such as tensile strength and elongation, and properties such as heating loss to an equivalent level or higher compared to existing products while securing eco-friendliness. In addition, cost competitiveness can be significantly improved due to simplification of the manufacturing process.
[28]
Mode for carrying out the invention
[29]
The terms or words used in the specification and claims should not be construed as being limited to their usual or dictionary meanings, and the inventor may appropriately define the concept of terms in order to describe his own invention in the best way It should be interpreted as a meaning and concept consistent with the technical idea of ​​the present invention based on the principle that there is.
[30]
[31]
Definition of Terms
[32]
The term "composition" as used herein includes reaction products and decomposition products formed from the materials of the composition as well as mixtures of materials comprising the composition.
[33]
The term "polymer" as used herein, whether of the same or a different kind, refers to a polymer compound prepared by polymerizing monomers. In this way the generic term polymer encompasses the term homopolymer, which is commonly used to refer to polymers made from only one monomer, and the term interpolymer as defined below.
[34]
The term “interpolymer” as used herein refers to a polymer prepared by polymerization of at least two different monomers. In this way, the generic term interpolymer includes copolymers commonly used to refer to polymers made from two different monomers, and polymers made from two or more different monomers.
[35]
The prefix "iso-" as used in the present specification refers to collectively an alkyl group in which a methyl group or an ethyl group is bonded in a branched chain to the main chain of the alkyl group, and in the present specification, it is bonded to the terminal as long as there is no alkyl group otherwise called Including, it may be used as a generic term for an alkyl group in which a methyl group or an ethyl group is bonded to the main chain as a branched chain.
[36]
"Cyclohexane polyester-based material" as used herein refers to a material in which two or more ester groups are bonded to a cyclohexane ring, and "aromatic polyester-based material" is an aromatic ring such as an aromatic compound such as benzene It refers to a material in which two or more ester groups are bonded to the ring, and does not mean'polyester' as a polymer. That is, the cyclohexane polyester-based material refers to a material in which two or more ester groups, for example, 3 to 6 ester groups, are bonded to the cyclohexane ring, and in particular, "cyclohexane diester-based material" refers to a cyclohexane ring. It may refer to a material in which two ester groups are bonded.
[37]
"Cyclohexane polycarboxylic acid" as used herein refers to a material in which two or more carboxyl groups are bonded to a cyclohexane ring, and "aromatic polycarboxylic acid" refers to a carboxyl group in an aromatic ring, for example, a ring such as benzene. Refers to a material in which two or more are combined.
[38]
The term "straight vinyl chloride polymer" as used herein, as one of the types of vinyl chloride polymer, may mean polymerization through suspension polymerization or bulk polymerization, and having a size of tens to hundreds of micrometers. It has the form of porous particles in which a large amount of pores are distributed, has no cohesiveness, and has excellent flowability.
[39]
The term "paste vinyl chloride polymer" as used herein, as one of the types of vinyl chloride polymers, may mean polymerized through microsuspension polymerization, seed emulsion polymerization, or pure emulsion polymerization, and dozens of It refers to a polymer having a cohesive property and poor flowability as particles without fine and dense pores having a size of from several thousand nanometers.
[40]
The terms'comprising','having' and their derivatives, whether specifically disclosed or not, are not intended to exclude the presence of any additional components, steps or procedures. For the avoidance of any uncertainty, all compositions claimed through the use of the term'comprising', whether polymer or otherwise, may contain any additional additives, adjuvants, or compounds, unless stated to the contrary. Can include. In contrast, the term'consisting essentially of' excludes from the scope of any subsequent description any other component, step or procedure, except that it is not essential to operability. The term'consisting of' excludes any component, step or procedure not specifically described or listed.
[41]
[42]
How to measure
[43]
In the present specification, analysis of the content of the components in the composition is performed through gas chromatography measurement, and Agilent's gas chromatography instrument (product name: Agilent 7890 GC, column: HP-5, carrier gas: helium (flow rate 2.4 mL/min)) , Detector: FID, injection volume: 1uL, initial value: 70℃/4,2min, final value: 280℃/7.8min, program rate: 15℃/min).
[44]
In this specification,'hardness' refers to Shore hardness at 25°C (Shore "A" and/or Shore "D") using ASTM D2240, and is measured under the conditions of 3T 10s, and plasticized It can be an index to evaluate the efficiency, and the lower it means the plasticization efficiency is excellent.
[45]
In this specification, the'tensile strength' is a cross head speed of 200 mm/min (1T) using UTM (manufacturer; Instron, model name; 4466) as a test device according to ASTM D638 method. After pulling with ), the point at which the specimen is cut is measured and calculated by Equation 1 below.
[46]
[Equation 1]
[47]
Tensile strength (kgf/cm 2 ) = load (kgf) / thickness (cm) x width (cm)
[48]
In this specification, the'elongation rate' is measured at the point where the specimen is cut after pulling the cross head speed to 200 mm/min (1T) using the UTM according to the ASTM D638 method. Then, it is calculated by the following equation (2).
[49]
[Equation 2]
[50]
Elongation (%) = Length after elongation / Initial length x 100
[51]
In this specification, the'migration loss' is obtained by obtaining a test piece with a thickness of 2 mm or more according to KSM-3156, attaching a glass plate to both sides of the test piece, and applying a load of 1 kgf/cm 2 . After leaving the test piece in a hot air circulation oven (80℃) for 72 hours, take it out and cool it at room temperature for 4 hours. Then, after removing the glass plate attached to both sides of the test piece, measure the weight before and after leaving the glass plate and the specimen plate in an oven, and calculate the transition loss amount by the following equation (3).
[52]
[Equation 3]
[53]
Transition loss (%) = {(initial weight of test piece at room temperature-weight of test piece after leaving the oven) / initial weight of test piece at room temperature} x 100
[54]
In the present specification,'volatile loss' refers to the weight of the specimen after working at 80°C for 72 hours.
[55]
[Equation 4]
[56]
Heating loss (% by weight) = {(Initial specimen weight-specimen weight after work) / Initial specimen weight} x 100
[57]
In this specification, the'absorption speed' is evaluated by measuring the time taken to stabilize the torque of the mixer by mixing the resin and the plasticizer using a planatary mixer (Brabender, P600) under conditions of 77℃ and 60rpm. do.
[58]
[59]
Hereinafter, the present invention will be described in more detail to aid in understanding the present invention.
[60]
[61]
Plasticizer composition
[62]
According to an embodiment of the present invention, the plasticizer composition is a cyclohexane polyester-based material, which is a compound represented by the following formula (1); And a perhydride comprising a compound represented by the following formula (2), wherein the perhydride is contained in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of a cyclohexane polyester-based material.
[63]
[Formula 1]
[64]

[65]
[Formula 2]
[66]

[67]
In Formulas 1 and 2, R 1 and R 2 are each independently an alkyl group having 4 to 10 carbon atoms, R 3 is a methyl group, n is 2 or 3, m is an integer of 0 to 2, and p is 0 Is an integer of 3, m+p is an integer of 0 to 3, and nm is an integer of 1 to 3.
[68]
[69]
According to an embodiment of the present invention, the cyclohexane polyester-based material has two or three ester groups (n), and in the case of two, the ester groups are bonded to positions 1,3 or 1,4 of cyclohexane. In the case of three, ester groups may be bonded to positions 1,2,4, and may refer to a target product included in the plasticizer composition according to the present invention.
[70]
Specifically, the cyclohexane polyester-based material may include a compound selected from compounds represented by Formulas 1-1 to 1-3 below.
[71]
[Formula 1-1]
[72]

[73]
[Formula 1-2]
[74]

[75]
[Formula 1-3]
[76]

[77]
In Formulas 1-1 to 1-3, R 11 to R 15 are each independently an alkyl group having 4 to 10 carbon atoms.
[78]
Formula 1-1 to R 1-3 in the general formula 11 to R 15 is R in the formula (1) 1 , and an alkyl group having 4 to 10 carbon atoms as may be defined in the same way as in definition, the alkyl group in this case is It may be a straight-chain alkyl group or a branched-chain alkyl group in which a branch is bonded to the main chain, and the definition and specification of R 1 made below may be applied equally to the R 11 to R 15 .
[79]
Cyclohexane polyester-based materials in which R 1 has an alkyl group having 4 to 10 carbon atoms have an excellent balance of physical properties compared to those having an alkyl group having a carbon number outside the range. In the case of loss, there is a possibility that the transferability, heating loss, and tensile strength and elongation may be considerably poor, and if the number of carbons is greater than 10, the plasticization efficiency, elongation, and absorption rate are likely to be poor. It is preferable to apply a cyclohexane polyester-based material in which a 10-membered alkyl group is bonded to an ester group.
[80]
R 1 is, for example, n-butyl group (abbreviation: B), isobutyl group (abbreviation: IB), n-pentyl group (P), isopentyl group (IP), n-hexyl group (abbreviation: Hx), isohexyl group (abbreviation: IHx), n-heptyl group (abbreviation: Hp), isoheptyl group (abbreviation: IHp), n-octyl group (abbreviation: nO), isooctyl group (abbreviation: IO), 2 -Ethylhexyl group (abbreviation: EH), n-nonyl group (abbreviation: N), isononyl group (abbreviation: IN), n-decyl group (abbreviation: nD), isodecyl group (abbreviation: ID) or 2- A propylheptyl group (abbreviation: PH) or the like may be applied, and it is more preferable to apply the alkyl groups listed above among the linear or branched alkyl groups having 4 to 10 carbon atoms in consideration of the supply and demand of raw materials.
[81]
The R 1 may preferably be an alkyl group having 5 to 10 carbon atoms, for example, n-pentyl group, isopentyl group, n-hexyl group, isohexyl group, isoheptyl group, 2-ethylhexyl group, n-no A nil group, an isononyl group or a 2-propylheptyl group may be applied. When these substituents are applied, not only can the manufacturing cost be lowered in terms of supply and demand of raw materials, but also it may be desirable in consideration of the balance of properties that can be commercialized, such as transferability, thermal stability, and plasticization efficiency.
[82]
[83]
According to an embodiment of the present invention, the perhydride includes one or more compounds represented by the following formula (2).
[84]
[Formula 2]
[85]

[86]
In Formula 2, R 2 is each independently an alkyl group having 4 to 10 carbon atoms, R 3 is a methyl group, m is an integer of 0 to 2, p is an integer of 0 to 3, and m+p is 1 to It is an integer of 3.
[87]
The perhydride is one containing one or more compounds, preferably two or more, and when such a perhydride is included in the plasticizer composition, plasticization efficiency can be improved, and compression transfer and stress transferability can be improved. It can be expected, and further, since there is no need to perform the separation and purification process, cost competitiveness of finished products can be improved through simplification of the process.
[88]
That is, since the perhydride is a compound derived from the compound represented by Formula 1 and includes the compound represented by Formula 2, it may have a relatively small molecular weight or less steric hindrance compared to a cyclohexane polyester-based material. have.
[89]
Since the plasticizer composition contains a certain amount of these perhydrides together with the cyclohexane polyester-based material, it may be advantageous to maintain the overall quality level even if hydrogenation of a hydrogenated raw material having a large molecular weight is not perfect. In using it as a plasticizer raw material, not only can you obtain the effect of expanding the quality range, but also simplification of the hydrogenation process can be obtained, and the purification process of the reactant can be omitted. You can get the effect.
[90]
In the compound represented by Formula 2, R 2 may be defined the same as R 1 in Formula 1, and substantially the same substituent as R 1 may be selected.
[91]
In addition, in the relationship with the compound represented by Formula 1, when n is 2, m is 0 or 1, p is an integer of 0 to 2, m+p is an integer of 0 to 2, and nm is It may be 1 or 2, and when n is 3, m is an integer of 0 to 2, and p is an integer of 0 to 3, m+p is an integer of 0 to 3, and nm is an integer of 1 to 3 I can.
[92]
In addition, the compound represented by Formula 2 may have 1 or 2 fewer ester groups than the compound represented by Formula 1, and specifically, when the compound represented by Formula 1 is a diester, the material represented by Formula 2 There may be no or one ester (if n is 2, m is 0 or 1 (p is an integer from 0 to 2), nm is 1 or 2), and if it is a triester, then there is no or 1 or 2 esters. Can be (when n is 3, m is an integer of 0 to 2 (p is an integer of 0 to 3), and nm is an integer of 1 to 3). In addition, the sum (m+p) of the number of substitutions of ester groups and alkyl groups in the compound represented by Formula 2 may be equal to or less than 1 or 2 as the number of ester groups (n) of the compound represented by Formula 1.
[93]
Specifically, the compound represented by Chemical Formula 2 may be derived from a by-product generated through a hydrogenation reaction of cyclohexane polycarboxylic acid, which may be a raw material of the compound represented by Chemical Formula 1 in the manufacturing process. That is, while 2 or 3 carboxyl groups are reduced, 1 to 3 carboxyl groups (1 or 2 in the case of diester and 1, 2 or 3 in the case of triester) are hydrogen due to over-reduction. (when p is 0) or a methyl group (when p is 1 to 3-p is 1 or 2 for diester, and p is 1, 2 or 3 for triester), and the overreduced material is an ester It may be a compound produced by being included in the reaction product of the reaction.
[94]
More specifically, the perhydride may include at least one selected from compounds represented by the following Chemical Formulas 2-1 to 2-11, typically.
[95]
[Formula 2-1]
[96]

[97]
[Formula 2-2]
[98]

[99]
[Formula 2-3]
[100]

[101]
[Formula 2-4]
[102]

[103]
[Formula 2-5]
[104]

[105]
[Formula 2-6]
[106]

[107]
[Formula 2-7]
[108]

[109]
[Formula 2-8]
[110]

[111]
[Formula 2-9]
[112]

[113]
[Formula 2-10]
[114]

[115]
[Formula 2-11]
[116]

[117]
In Formulas 2-1 to 2-11, R 21 , R 23 and R 26 are each independently an alkyl group having 4 to 10 carbon atoms, and R 22 , R 24 , R 25 , R 22 ′, R 23 ′, R 24 'And R 25 ' are each independently hydrogen or a methyl group.
[118]
R 21 , R 23 and R 26 in Formulas 2-1 to 2-11 may be defined the same as R 2 in Formula 2, and thus R 1 in Formula 1 and its definition and specification Both of these can be applied.
[119]
In addition, the R 22 , R 24 , R 25 , R 22 ′, R 23 ′, R 24 ′ and R 25 ′ may each independently be hydrogen or a methyl group, which may be equivalent to R 3 in Formula 2 .
[120]
When p is 1, R 22 in Formula 2-1 or Formula 2-3 may be a methyl group, and in Formula 2-2 or Formula 2-4, only one of R 22 and R 22 ′ may be a methyl group, In Formulas 2-5 to 2-10, any one of R 24 and R 25 may be hydrogen, and any one may be a methyl group, and in Formula 2-11, any one of R 23 ′, R 24 ′ and R 25 ′ is a methyl group It can be.
[121]
When p is 2, R 24 and R 25 in Formulas 2-5 to 2-10 may be methyl groups, and in Formula 2-11, two of R 23 ′, R 24 ′ and R 25 ′ may be methyl groups. have. In addition, when p is 0, hydrogen is bonded to the position of R 3 , and in each of Formulas 2-1 to 2-11, R 22 , R 24 , R 25 , R 22 ′, R 23 ′, R 24 ' and R 25 ' can be hydrogen.
[122]
[123]
According to an embodiment of the present invention, the perhydride is contained in an amount of 0.1 to 10 parts by weight based on 100 parts by weight of a cyclohexane polyester-based material. When perhydride is included in an amount within the above range, the effect of improving thermal stability, tensile strength, and elongation is maximized, and a remarkable increase in the effect can be expected beyond the equivalent level.
[124]
Specifically, the perhydride may be preferably contained in an amount of 0.1 to 8.0 parts by weight based on 100 parts by weight of a cyclohexane polyester-based material, more preferably 0.1 to 6.0 parts by weight, 0.1 to 5.0 parts by weight, more preferably 0.5 To 4.0 parts by weight.
[125]
For example, the perhydride may contain two or more types, for example, in the case of the compound represented by Formula 2-1, in this case, cyclohexane monoalkylester and 4-methyl cyclohexane monoalkylester are included. In the case of the compound represented by Chemical Formula 2-2, the same as above, but 4-methyl cyclohexane monoalkylester may be changed to 3-methyl cyclohexane monoalkylester, and further, Chemical Formula 2- When selected from the compounds represented by Formulas 5 to 2-10, the total amount may be appropriately controlled so as to be included in the range of the total amount of the perhydride described above. For reference, the alkyl of the'monoalkylester' may correspond to the substituent R 2 of Formula 2 described above .
[126]
As described above, if one or more, preferably two or more types of perhydrides are included, and the content of these perhydrides is controlled to a specific content, the above-described effect can be further maximized, and in this case, the most optimal physical properties can be realized. A plasticizer composition that can be obtained can be obtained.
[127]
[128]
According to an embodiment of the present invention, the plasticizer composition is a mixture of a cyclohexane polyester-based material and a perhydride, and specifically, a cyclohexane polyester-based material and a perhydride are organically connected to each other, and consist of a specific combination. I can.
[129]
Specifically, in the plasticizer composition, the cyclohexane polyester-based material is a compound represented by Formula 1-1, and the perhydride may include one or more compounds represented by Formula 2-1, , It may also include a compound represented by Formula 2-2.
[130]
In this case, the cyclohexane polyester-based material, which is the compound represented by Formula 1-1, may exist as a mixture of isomers, and may be a mixture of isomers represented by the following structure.
[131]
[trans isomer]
[132]

[133]
[cis isomer]
[134]

[135]
That is, when the cyclohexane polyester-based material included in the plasticizer composition according to the present invention is a compound represented by Formula 1-1, it may be a mixture in which the above isomers are mixed.
[136]
In addition, in the plasticizer composition, the cyclohexane polyester-based material is a compound represented by Chemical Formula 1-2, and the perhydride may include at least one compound represented by Chemical Formula 2-3, It may also include a compound represented by Formula 2-4.
[137]
In addition, the cyclohexane polyester-based material is a compound represented by Formula 1-3, and the perhydride may be one containing at least one compound selected from compounds represented by Formulas 2-5 to 2-10. And, it may also include a compound represented by Formula 2-11.
[138]
The above combination may be obtained as a product by a combination of interrelated substances according to a manufacturing method to be described later, and does not exclude the case of combining differently from the above combination.
[139]
According to an embodiment of the present invention, the plasticizer composition may further include an aromatic polyester-based material, and the aromatic polyester-based material may be derived from the presence of unreacted materials in the hydrogenation reaction of the raw material. At this time, it is preferable that the aromatic polyester-based material remains at least 0.5% by weight relative to the total weight of the plasticizer composition, and it may be preferable that the amount does not exceed 15% by weight of the total weight. When an aromatic polyester-based material is included in such a range, plasticization efficiency, processability, and melting properties are excellent, and the hydrogenation process conditions are mild, so that the manufacturing process can be simplified.
[140]
[141]
Method for producing plasticizer composition
[142]
According to an embodiment of the present invention, a method for preparing a plasticizer composition is provided, which method comprises hydrogenating any one aromatic polycarboxylic acid selected from the group consisting of isophthalic acid, terephthalic acid and trimellitic acid to Obtaining a hydride containing an acid; And esterification reaction of the hydride and the primary alkyl alcohol, wherein the primary alkyl alcohol has 4 to 10 alkyl carbon atoms, and the cyclohexane polycarboxylic acid is cyclohexane 1,3-dicarboxyl As an acid, cyclohexane 1,4-dicarboxylic acid or cyclohexane 1,2,4-tricarboxylic acid, this is a method of preparing a plasticizer composition as described above.
[143]
[144]
According to an embodiment of the present invention, the step of hydrogenating any one aromatic polycarboxylic acid selected from the group consisting of isophthalic acid, terephthalic acid, and trimellitic acid to obtain a hydride containing cyclohexane polycarboxylic acid is primarily performed. Can be done with
[145]
Specifically, the reactant used for the hydrogenation is an aromatic polycarboxylic acid, isophthalic acid, terephthalic acid, or trimellitic acid, derivatives thereof are also included, and cyclohexane polycarboxylic acid can be produced by reduction by hydrogenation reaction. If it is a derivative, it can be applied as a raw material.
[146]
The hydrogenation reaction may be a hydrogenation reaction of an aromatic polycarboxylic acid in the presence of a metal catalyst to remove all of the aromaticity of the benzene ring and convert it to cyclohexane. The aromatic carboxylic acid used in the hydrogenation reaction can be applied without any particular problem if it is a material commercially available in the art.
[147]
The hydrogenation reaction is a reaction in which hydrogen is added to remove all double bonds of the benzene ring of the aromatic carboxylic acid in the presence of a metal catalyst, and may be a kind of reduction reaction, and the reaction may be carried out under a metal catalyst. The conditions may include all conventional reaction conditions capable of hydrogenating only the benzene ring without affecting the carboxylic acid bonded to the benzene.
[148]
The hydrogenation reaction may be carried out by further including an organic solvent such as ethanol, but is not limited thereto. As the metal catalyst, a catalyst generally used to hydrogenate a benzene ring may be used by supporting noble metals such as Ru, Pt, Pd, etc., such as carbon or alumina, but is not limited thereto as long as the hydrogenation reaction is possible.
[149]
On the other hand, since the hydrogenation reaction is performed in the presence of hydrogen and a metal catalyst, and is generally performed at high pressure, it is not easy to control the reaction. Accordingly, various kinds of by-products may be generated, and the above-described perhydrogenate may be derived from these by-products.
[150]
[151]
In the present invention, among various by-products, it is necessary to pay attention to substances produced by overreduction of the carboxyl group of the aromatic polycarboxylic acid.
[152]
In general, in the case of hydrogenation of an aromatic polycarboxylic acid, the most desired reaction is that only the unsaturated bonds of the aromatic ring other than the polycarboxylic acid are hydrogenated. It is common to include unreacted products that are not included together, but these by-products are usually controlled so as not to be produced as much as possible by removing all except the desired product or by adjusting the reaction conditions.
[153]
That is, since these by-products are substances that affect the purity of the product, cyclohexane polycarboxylic acid, they are generally removed, but in the present invention, it was found that the perhydride affects the performance of the plasticizer. Therefore, by participating in the reaction together without removing it, it is possible to improve the performance of the product using the hydrogenated material as a plasticizer, and at the same time, there is no need to remove by-products. The advantage of securing cost competitiveness of finished products was also gained.
[154]
As the perhydride of the aromatic polycarboxylic acid, when isophthalic acid is applied, it is selected from cyclohexane, methyl cyclohexane, 1,3-dimethyl cyclohexane, cyclohexane monocarboxylic acid, and 3-methyl cyclohexane monocarboxylic acid. It may be one or more types of substances, and when terephthalic acid is applied, one selected from cyclohexane, methyl cyclohexane, 1,4-dimethyl cyclohexane, cyclohexane monocarboxylic acid, and 4-methyl cyclohexane monocarboxylic acid It may be any of the above substances, and when trimellitic acid is applied, one to three of the three carboxyl groups may be all substances that can be generated by participating in the reduction reaction, and the reduced one to three carboxyl groups are hydrogen or methyl groups. It may have been converted.
[155]
Since these perhydrides are substances that are converted into perhydrides containing the compound represented by the above-described formula (2) in the product, the content of this perhydride is 0.1 to 10 parts by weight relative to 100 parts by weight of the cyclohexane polyester-based material. Considering that it is preferable, the content of the perhydride contained in the final product can be appropriately adjusted by controlling the content of the per-reduced product through the control of the reaction conditions of the hydrogenation reaction.
[156]
That is, in the case of the perhydride of the aromatic polycarboxylic acid, since each is included together with the cyclohexane polycarboxylic acid, the effect of the present invention can be implemented through the same mechanism as mentioned in the description of the plasticizer composition, which Departing from the common technical knowledge in the art, there is considerable technical significance in that the by-product is applied as an additive that can improve the performance of the hydrogenated plasticizer product.
[157]
According to an embodiment of the present invention, as an unreacted product not subjected to a hydrogenation reaction other than the hydride generated by the hydrogenation reaction, an aromatic polycarboxylic acid may be further included, and an unreacted aromatic polycarboxylic acid that is not hydrogenated The weight ratio of the acid to the hydride may be 99:1 to 1:99, and may further contain an aromatic polycarboxylic acid in addition to the hydride within this range, which may be controlled according to the conversion rate of the hydrogenation reaction. However, in the present invention, the same effects as described above may be exhibited depending on the components and content in the hydrogenated material, so it may be irrelevant to how much aromatic polycarboxylic acid is substantially included.
[158]
[159]
According to an embodiment of the present invention, the step of esterifying the hydride and the primary alkyl alcohol may be performed after the hydrogenation reaction.
[160]
Specifically, it is a step of directly esterifying a hydride including the cyclohexane polycarboxylic acid and a perhydride thereof using a primary alkyl alcohol, and at this time, the carboxyl group and perhydride of the cyclohexane polycarboxylic acid One or two carboxyl groups present are esterified with a primary alkyl alcohol.
[161]
Among the perhydrides, cyclohexane, methyl cyclohexane, or dimethyl cyclohexane in which all ester groups in the aromatic polycarboxylic acid are hydrogenated may also be included.These substances are included in the reaction raw material but do not participate in the esterification reaction. . These perhydrides do not substantially participate in the reaction, but since they have a low boiling point, they can serve as entrained substances that can remove water generated during the esterification reaction out of the system within a short time at a relatively low temperature. Through this, it is possible to obtain effects such as improvement of alcohol and esterification reactivity and improvement of manufacturing cost through energy saving.
[162]
The alkyl group bonded by esterification of the carboxyl groups is derived from the primary alkyl alcohol, in which case the'alkyl' of the primary alkyl alcohol may be the same as R 1 and R 2 defined in Formulas 1 and 2 above. In addition, since descriptions of specifics and features are redundant, they are omitted below.
[163]
The esterification reaction may include adding a hydride to a primary alkyl alcohol, then adding a catalyst and reacting under a nitrogen atmosphere; Removing unreacted alcohol and neutralizing unreacted carboxylic acid; And dehydrating and filtering by distillation under reduced pressure;
[164]
The primary alkyl alcohol may be used in the range of 150 to 500 mol%, 200 to 400 mol%, 200 to 350 mol%, 250 to 400 mol%, or 270 to 330 mol% based on 100 mol% of hydride.
[165]
On the other hand, the catalyst may be, for example, sulfuric acid, hydrochloric acid, phosphoric acid, nitric acid, paratoluenesulfonic acid, methanesulfonic acid, ethanesulfonic acid, propanesulfonic acid, butanesulfonic acid, an acid catalyst such as alkyl sulfuric acid, aluminum lactate, lithium fluoride, potassium chloride, cesium chloride, Metal salts such as calcium chloride, iron chloride, and aluminum phosphate, metal oxides such as heteropoly acids, natural/synthetic zeolites, cation and anion exchange resins, tetraalkyl titanate, and organic metals such as polymers. . As a specific example, the catalyst may be tetraalkyl titanate.
[166]
The amount of catalyst used may vary depending on the type, for example, in the case of a homogeneous catalyst, in the range of 0.01 to 5% by weight, 0.01 to 3% by weight, 1 to 5% by weight, or 2 to 4% by weight based on the total 100% by weight of the reactants. In the case of inner and heterogeneous catalysts, it may be in the range of 5 to 200% by weight, 5 to 100% by weight, 20 to 200% by weight, or 20 to 150% by weight of the total amount of the reactant.
[167]
The esterification reaction is performed in a temperature range of 80°C to 270°C, preferably in a temperature range of 150°C to 250°C for 10 minutes to 10 hours, preferably 30 minutes to 8 hours, and more preferably 1 to 6 hours. It is preferably carried out. The plasticizer composition can be effectively obtained in the above temperature and time range.
[168]
[169]
Further, according to an embodiment of the present invention, the plasticizer composition may further contain 0.5 parts by weight or less of an aromatic polyalkyl ester-based material relative to 100 parts by weight of the plasticizer composition.
[170]
The meaning that the aromatic polyalkyl ester-based material is included in an amount of 0.5 parts by weight or less may mean that it is substantially present as a by-product in the final plasticizer composition, and may not mean an aromatic polyalkyl ester-based material that is further included, In addition, it does not exclude a plasticizer composition further comprising an aromatic polyalkyl ester-based material.
[171]
Since the aromatic polyalkyl ester-based material may be derived from an unreacted product that does not react when hydrogenating an aromatic carboxylic acid, dialkyl isophthalate derived from isophthalic acid, dialkyl terephthalate derived from terephthalic acid, trimellitic acid It may be a trialkyl trimellitate derived from.
[172]
At this time, the alkyl is the same alkyl group as R 1 and R 2 in Formulas 1 and 2, and may be an alkyl derived from a primary alkyl alcohol, so details regarding the kind and characteristics of the alkyl group are the same as described above, and thus will be omitted below. do.
[173]
[174]
Resin composition
[175]
According to another embodiment of the present invention, there is provided a resin composition including the plasticizer composition and the resin described above.
[176]
As the resin, a resin known in the art may be used. For example, at least one selected from the group consisting of straight vinyl chloride polymer, paste vinyl chloride polymer, ethylene vinyl acetate copolymer, ethylene polymer, propylene polymer, polyketone, polystyrene, polyurethane, natural rubber, synthetic rubber and thermoplastic elastomer. Mixtures and the like may be used, but are not limited thereto.
[177]
The plasticizer composition may be included in an amount of 5 to 150 parts by weight, preferably 5 to 130 parts by weight, or 10 to 120 parts by weight based on 100 parts by weight of the resin.
[178]
In general, the resin in which the plasticizer composition is used may be manufactured into a resin product through melt processing or plastisol processing, and the melt processing resin and plastisol processing resin may be produced differently according to each polymerization method.
[179]
For example, when a vinyl chloride polymer is used for melt processing, a solid resin particle having a large average particle diameter is used because it is prepared by suspension polymerization, and this vinyl chloride polymer is called a straight vinyl chloride polymer, and is used for plastisol processing. In this case, a resin in a sol state is used as a fine resin particle produced by emulsion polymerization or the like, and such a vinyl chloride polymer is called a paste vinyl chloride resin.
[180]
In this case, in the case of the straight vinyl chloride polymer, the plasticizer is preferably included in the range of 5 to 80 parts by weight based on 100 parts by weight of the polymer, and in the case of the paste vinyl chloride polymer, 40 to 120 parts by weight based on 100 parts by weight of the polymer. It is preferably included in.
[181]
The resin composition may further include a filler. The filler may be 0 to 300 parts by weight, preferably 50 to 200 parts by weight, more preferably 100 to 200 parts by weight, based on 100 parts by weight of the resin.
[182]
The filler may be a filler known in the art, and is not particularly limited. For example, it may be a mixture of at least one selected from silica, magnesium carbonate, calcium carbonate, hard coal, talc, magnesium hydroxide, titanium dioxide, magnesium oxide, calcium hydroxide, aluminum hydroxide, aluminum silicate, magnesium silicate and barium sulfate.
[183]
In addition, the resin composition may further include other additives such as stabilizers, if necessary. Other additives such as the stabilizer may be, for example, 0 to 20 parts by weight, preferably 1 to 15 parts by weight, based on 100 parts by weight of the resin, respectively.
[184]
The stabilizer may be a calcium-zinc-based (Ca-Zn-based) stabilizer or a barium-zinc-based (Ba-Zn-based) stabilizer such as a calcium-zinc complex stearic acid salt, but is specifically limited thereto. It is not.
[185]
The resin composition may be applied to both melt processing and plastisol processing as described above, for example, melt processing may be applied to calendering processing, extrusion processing, or injection processing, and plastisol processing may be applied to coating processing, etc. Can be applied.
[186]
[187]
Example
[188]
Hereinafter, embodiments of the present invention will be described in detail so that those skilled in the art can easily implement the present invention. However, the present invention may be implemented in various different forms, and is not limited to the embodiments described herein.
[189]
[190]
1-1. Cyclohexane 1,4-diester-based material
[191]
Example 1-1
[192]
A palladium catalyst supported on a certain volume of silica is placed in a 1.5L pressure vessel with a stirrer, 25 g of terephthalic acid and 1 L of water are injected, and hydrogen is injected through a mass flow meter for stirring. The reactor was reacted for 1 hour while raising the internal temperature to 200°C and maintaining the internal hydrogen pressure of 80 bar. After completion of the reaction, the reaction product in the reactor was recovered and purified using methanol. Thereafter, an ester reaction was performed under a Ti-based catalyst using 300 mol% of 2-ethylhexanol compared to the hydrogenation reaction product, and an ester product in the form of a composition was obtained through a purification process.
[193]
[194]
Example 1-2
[195]
A palladium catalyst supported on a certain volume of silica is placed in a 1.5L pressure vessel with a stirrer, 25 g of terephthalic acid and 1 L of water are injected, and hydrogen is injected through a mass flow meter for stirring. The reactor was reacted for 1 hour while raising the internal temperature to 230°C and maintaining the internal hydrogen pressure of 80 bar. After completion of the reaction, the reaction product in the reactor was recovered and purified using methanol. Thereafter, an ester reaction was performed under a Ti-based catalyst using 300 mol% of 2-ethylhexanol compared to the hydrogenation reaction product, and an ester product in the form of a composition was obtained through a purification process.
[196]
[197]
Examples 1-3 and 1-4
[198]
A palladium catalyst supported on a certain volume of silica is placed in a 1.5L pressure vessel with a stirrer, 25 g of terephthalic acid and 1 L of water are injected, and hydrogen is injected through a mass flow meter for stirring. The reactor was reacted for 2 hours while raising the internal temperature to 230°C and maintaining the internal hydrogen pressure of 80 bar. After the reaction was completed, the reaction result in the reactor was recovered using methanol, and the reaction product was distilled under reduced pressure to adjust the content of perhydrogen as shown in Table 1 below, and then 2-ethylhexanol was used in an amount of 300 mol% compared to the hydrogenation reaction product. The ester reaction was carried out under a Ti-based catalyst, and through a purification process, an ester product in the form of a composition was obtained.
[199]
[200]
Comparative Example 1-1
[201]
As an existing plasticizer product, GL300 (di(2-ethylhexyl) terephthalate), manufactured by LG Chemical Co., Ltd., was applied.
[202]
[203]
Comparative Example 1-2
[204]
A palladium catalyst supported on a certain volume of silica is placed in a 1.5L pressure vessel with a stirrer, 25 g of terephthalic acid and 1 L of water are injected, and hydrogen is injected through a mass flow meter for stirring. The reactor was reacted for 2 hours while raising the internal temperature to 230°C and maintaining the internal hydrogen pressure of 80 bar. After the reaction was completed, the reaction result in the reactor was recovered using methanol, and the reaction product was distilled under reduced pressure to adjust the content of perhydrogen as shown in Table 1 below, and then 2-ethylhexanol was used in an amount of 300 mol% compared to the hydrogenation reaction product. The ester reaction was carried out under a Ti-based catalyst, and through a purification process, an ester product in the form of a composition was obtained.
[205]
[206]
Comparative Example 1-3
[207]
A palladium catalyst supported on a certain volume of silica is placed in a 1.5L pressure vessel with a stirrer, 25 g of terephthalic acid and 1 L of water are injected, and hydrogen is injected through a mass flow meter for stirring. The reactor was reacted for 2 hours while raising the internal temperature to 260°C and maintaining the internal hydrogen pressure of 80 bar. After completion of the reaction, the reaction product in the reactor was recovered using methanol and analyzed through GC.
[208]
[209]
Comparative Example 1-4
[210]
In a 3L flask equipped with a stirrer, condenser and decanter, 510 g of 1,4-Cyclohexanedicarboxylic acid (TCI), 1170 g of 2-ethylhexanol, and 1.5 g of TiPT (Tetraisopropyl titanate) as a catalyst were added, and the temperature was gradually raised to start the ester reaction. , When the acid value of the final reactant reached 0.1, the reaction was terminated, and 1,160 g of 1,4-diethylhexyl cyclohexanoate was obtained through distillation, neutralization/washing, dehydration and filtration processes.
[211]
[212]
The compositions of the plasticizer compositions of the Examples and Comparative Examples are shown in Table 1 below.
[213]
[Table 1]
Desired product 1) Perhydrogen 2-2)
Example 1-1 86.1 1.631
Example 1-2 85.8 3.741
Example 1-3 87.2 0.583
Example 1-4 82.3 9.588
Comparative Example 1-1 - -
Comparative Example 1-2 78.6 12.646
Comparative Example 1-3 89.5 11.596
Comparative Example 1-4 99.7 0.027
[214]
1) Di(2-ethylhexyl) cyclohexane 1,4-diester (wt%) 2) Cyclohexyl (2-ethyl) hexanoate and 4-methylcyclohexyl-1-(2-ethyl)hexanoate Mixed content of (di(2-ethylhexyl) cyclohexane 1,4-diester 100 parts by weight based on 100 parts by weight)
[215]
[216]
1-2. Evaluation of plasticizer composition
[217]
According to ASTM D638, polyvinyl chloride (brand name: LS100, manufacturer: LG Chem) 100 parts by weight, 40 parts by weight of the plasticizer composition prepared in the Examples and Comparative Examples, and a stabilizer (brand name: BZ153T, manufacturer) : Songwon Industries) 3 parts by weight are mixed, stirred at 98°C at a speed of 700 rpm, mixed, roll milled at 160°C for 4 minutes, and pressed at 180°C for 3 minutes (low pressure) and 2.5 minutes (high pressure) A specimen having a thickness of 1 mm and a specimen having a thickness of 3 mm were produced respectively.
[218]

[219]
Hardness (shore'A', Shore'D') measurement
[220]
According to ASTM D2240, the hardness of a 3 mm thick specimen was measured for 10 seconds.
[221]
[222]
Measurement of migration loss (%)
[223]
According to KSM-3156, after attaching a glass plate to both sides of a specimen having a thickness of 1 mm, a load of 1 kgf/cm 2 was applied. The specimen was left in a hot air circulation oven (80°C) for 72 hours, then taken out and cooled at room temperature. Thereafter, the glass plates adhered to both sides of the specimen were removed, and the weight of the specimen before and after leaving the specimen in an oven was measured, and substituted into Equation 1 below to calculate the transition loss value.
[224]

[225]
Transition loss (%) = [(initial weight of specimen before leaving the oven)-(weight of specimen after leaving the oven)]/ (initial weight of specimen before leaving the oven) × 100
[226]
[227]
Heating loss measurement (%)
[228]
After exposing the specimen having a thickness of 1 mm at 80° C. for 72 hours, the weight of the specimen was measured and substituted into Equation 2 below to calculate the heating loss value.
[229]

[230]
Heating loss (%) = [(Initial specimen weight)-(Specimen weight after work)]/ (Initial weight of specimen before leaving the oven) × 100
[231]
[232]
Tensile strength measurement (㎏/㎠)
[233]
According to ASTM D638, a specimen having a thickness of 1 mm was pulled at a cross head speed of 200 mm/min using a UTM (brand name: 4466, manufacturer: instron), and the time point at which the specimen was cut was measured.
[234]
[235]
Elongation measurement (%)
[236]
According to ASTM D638, a specimen having a thickness of 1 mm was pulled at a cross head speed of 200 mm/min using a UTM (brand name: 4466, manufacturer: instron), and the time point at which the specimen was cut was measured. And it was substituted into the following formula 3, and the elongation was calculated.
[237]

[238]
Elongation (%): [(length at the time the specimen is cut)/(initial length)]×100
[239]
[240]
Measurement of UV resistance
[241]
According to the ASTM D4329 method, a test instrument, QUV Accelerated Weathering Tester (manufacturer; Q-LAB, model name; QUV/se), is fixed to the specimen holder inside the specimen and UV (UVA-340) for a certain temperature (60 degrees) and time. Exposed to After 400 hours of the test, the specimen was taken out and the color change before and after the test was measured, and a lower value means that there is little discoloration, so a lower value is evaluated as excellent.
[242]
[Table 2]
division Hardness Performance loss (%) Heating loss (%) Tensile strength (kgf/㎠) Elongation (%) Light fastness (ΔE)
Shore'A' Shore'D'
Example 1-1 90.9 45.3 3.37 0.73 243.5 342.1 1.4
Example 1-2 90.7 45.2 3.40 0.92 241.7 337.0 1.4
Example 1-3 90.7 45.3 3.02 0.58 245.1 349.1 1.3
Example 1-4 90.8 45.4 3.56 1.84 244.0 338.1 1.6
Comparative Example 1-1 94.2 50.3 4.78 0.70 238.6 320.4 7.6
Comparative Example 1-2 90.8 45.4 4.69 3.22 228.0 319.5 2.0
Comparative Example 1-3 90.7 45.5 4.32 3.08 237.9 326.9 2.1
Comparative Example 1-4 90.8 45.2 3.52 0.98 242.5 324.5 1.3
[243]
Referring to Table 2, in the case of Comparative Example 1-1, which is a di(2-ethylhexyl) terephthalate plasticizer as an eco-friendly product that is conventionally used, it is poor in terms of plasticization efficiency and light resistance compared to the present examples. It was conspicuously appeared, and it was confirmed that it showed inferiority in transitional properties, tensile strength, and elongation.
[244]
In addition, in the case of Comparative Examples 1-2 and 1-3, in which the content of perhydride exceeded 10 parts by weight relative to 100 parts by weight of the target product, it was confirmed that the tensile strength and elongation were inferior, and the transition loss and heating loss were also significantly inferior. have. In addition, as in Comparative Example 1-4, in the case of the existing hydrogenated product containing a very small amount of perhydride, it can be confirmed that the elongation is poor, and other physical properties can be viewed at a similar level, but the amount of the product to obtain the same effect When comparing the product cost based on the standard, the plasticizer of Comparative Example 1-4 is about 1.3 times or more compared to the plasticizer of the Examples, and if the product cost is considered, the difference in effect can be seen that there is a significant difference over elongation.
[245]
Through this, in order to improve the plasticization efficiency and light resistance of existing products, it is expected to improve physical properties in various aspects as well as plasticization efficiency and light resistance by intentionally including perhydrides generated in the manufacturing process when converting to hydrogenated products. In addition, it can be seen that cost competitiveness compared to existing hydrogenated products can be secured through simplification of the purification process.
[246]
[247]
2-1. Cyclohexane 1,3-diester-based material
[248]
Example 2-1
[249]
In Example 1-1, it was prepared in the same manner, except that isophthalic acid (1,3-dicarboxylic acid) was used instead of terephthalic acid.
[250]
[251]
Example 2-2
[252]
In Example 1-2, it was prepared in the same manner, except that isophthalic acid (1,3-dicarboxylic acid) was used instead of terephthalic acid.
[253]
[254]
Example 2-3
[255]
In Example 1-4, it was prepared in the same manner, except that isophthalic acid (1,3-dicarboxylic acid) was used instead of terephthalic acid.
[256]
[257]
Comparative Example 2-1
[258]
As an existing plasticizer product, GL300 (di(2-ethylhexyl) terephthalate), manufactured by LG Chemical Co., Ltd., was applied.
[259]
[260]
Comparative Example 2-2
[261]
In Comparative Example 1-3, it was prepared in the same manner, except that isophthalic acid (1,3-dicarboxylic acid) was used instead of terephthalic acid.
[262]
[263]
Comparative Example 2-3
[264]
In Comparative Example 1-4, it was prepared in the same manner, except that isophthalic acid (1,3-dicarboxylic acid) was used instead of terephthalic acid.
[265]
[266]
The compositions of the plasticizer compositions of the Examples and Comparative Examples are shown in Table 3 below.
[267]
[Table 3]
Desired product 1) Perhydrogen 2)
Example 2-1 87.3 1.45
Example 2-2 82.8 5.56
Example 2-3 79.2 9.23
Comparative Example 2-1 - -
Comparative Example 2-2 77.5 13.50
Comparative Example 2-3 99.8 0.01
[268]
1) Di(2-ethylhexyl) cyclohexane 1,3-diester (% by weight) 2) Cyclohexyl (2-ethyl) hexanoate and 3-methylcyclohexyl-1-(2-ethyl)hexanoate (Di(2-ethylhexyl) cyclohexane 1,3-diester 100 parts by weight based on weight part)
[269]
[270]
2-2. Evaluation of plasticizer composition
[271]
According to ASTM D638, polyvinyl chloride (brand name: LS100, manufacturer: LG Chem) 100 parts by weight, 40 parts by weight of the plasticizer composition prepared in the Examples and Comparative Examples, and a stabilizer (brand name: BZ153T, manufacturer) : Songwon Industries) 3 parts by weight are mixed, stirred at 98°C at a speed of 700 rpm, mixed, roll milled at 160°C for 4 minutes, and pressed at 180°C for 3 minutes (low pressure) and 2.5 minutes (high pressure) A specimen having a thickness of 1 mm and a specimen having a thickness of 3 mm were produced respectively.
[272]
In addition, the evaluation was performed in the same manner as in 1-1, and the stress test was evaluated as follows.
[273]
[274]
Stress test (stress resistance)
[275]
After a specimen with a thickness of 2 mm was allowed to stand at 23°C for 72 hours in a bent state, the degree of migration (the degree of bleeding) was observed, and the result was recorded as a value between 0 and 3, and the closer to 0, the better properties Indicated.
[276]
[Table 4]
division Hardness Performance loss (%) Heating loss (%) Tensile strength (kgf/㎠) Elongation (%) Stress test
Shore'A' Shore'D'
Example 2-1 91.2 45.6 3.28 1.32 221.6 281.3 0.5
Example 2-2 91.3 45.7 3.26 1.52 224.4 282.8 0.5
Example 2-3 91.0 45.2 3.24 2.01 223.0 286.5 0.5
Comparative Example 2-1 94.4 50.4 4.25 1.02 220.6 278.4 3.0
Comparative Example 2-2 91.0 45.1 3.42 3.21 204.6 283.0 1.0
Comparative Example 2-3 92.0 45.9 4.20 1.34 218.7 268.4 3.0
[277]
Referring to Table 4 above, when comparing Comparative Example 2-1, which is an existing eco-friendly product, with Examples, it can be seen that there is a significant improvement in plasticization efficiency and stress resistance. In addition, in the case of Comparative Example 2-2 in which the content of the perhydride exceeds 10 parts by weight, it can be confirmed that the heating loss and tensile strength are quite inferior. If it is less, it is confirmed that the elongation and stress resistance are poor, and the transition loss is also poor.
[278]
Through this, in order to improve plasticization efficiency and stress resistance of existing products, by intentionally including perhydrides generated in the manufacturing process when converting to hydrogenated products, as well as plasticization efficiency and stress resistance, It can be seen that improvement in physical properties can be expected, and further, cost competitiveness compared to existing hydrogenated products can be secured through simplification of the purification process.
[279]
[280]
3-1. Cyclohexane 1,2,4-triester-based material
[281]
Example 3-1
[282]
It was prepared in the same manner as in Example 1-1, except that trimellitic acid (1,2,4-Benzenetricarboxylic acid) was used instead of terephthalic acid.
[283]
[284]
Example 3-2
[285]
Except for using trimellitic acid (1,2,4-Benzenetricarboxylic acid) in place of terephthalic acid in Example 1-2, it was prepared in the same manner.
[286]
[287]
Example 3-3
[288]
In Example 1-4, it was prepared in the same manner, except that trimellitic acid (1,2,4-Benzenetricarboxylic acid) was used instead of terephthalic acid.
[289]
[290]
Comparative Example 3-1
[291]
As an existing plasticizer product, LGflex TOTM (tri(2-ethylhexyl) trimellitate), manufactured by LG Chemical Co., Ltd., was applied.
[292]
[293]
Comparative Example 3-2
[294]
In Comparative Example 1-3, it was prepared in the same manner, except that trimellitic acid (1,2,4-Benzenetricarboxylic acid) was used instead of terephthalic acid.
[295]
[296]
Comparative Example 3-3
[297]
In Comparative Example 1-4, it was prepared in the same manner, except that trimellitic acid (1,2,4-Benzenetricarboxylic acid) was used instead of terephthalic acid.
[298]
[299]
The compositions of the plasticizer compositions of the Examples and Comparative Examples are shown in Table 5 below.
[300]
[Table 5]
Desired product 1) Perhydrogen 2)
Example 3-1 86.0 2.23
Example 3-2 81.2 7.52
Example 3-3 80.5 9.10
Comparative Example 3-1 - -
Comparative Example 3-2 78.4 12.02
Comparative Example 3-3 99.6 0.03
[301]
1) Tri(2-ethylhexyl) cyclohexane 1,2,4-diester (wt%) 2) Tri(2-ethylhexyl) cyclohexane 1,2,4-diester 100 parts by weight based on 100 parts by weight
[302]
[303]
3-2. Evaluation of plasticizer composition
[304]
According to ASTM D638, polyvinyl chloride (brand name: LS100, manufacturer: LG Chem) 100 parts by weight, 40 parts by weight of the plasticizer composition prepared in the Examples and Comparative Examples, and a stabilizer (brand name: BZ153T, manufacturer) : Songwon Industries) 3 parts by weight are mixed, stirred at 98°C at a speed of 700 rpm, mixed, roll milled at 160°C for 4 minutes, and pressed at 180°C for 3 minutes (low pressure) and 2.5 minutes (high pressure) A specimen having a thickness of 1 mm and a specimen having a thickness of 3 mm were produced respectively.
[305]
In addition, evaluation was performed in the same manner as in 1-1.
[306]
[307]
Stress test (stress resistance)
[308]
After a specimen with a thickness of 2 mm was allowed to stand at 23°C for 72 hours in a bent state, the degree of migration (the degree of bleeding) was observed, and the result was recorded as a value between 0 and 3, and the closer to 0, the better properties Indicated.
[309]
[Table 6]
division Hardness Performance loss (%) Heating loss (%) Tensile strength (kgf/㎠) Elongation (%) Stress test Light resistance (△E)
Shore'A' Shore'D'
Example 3-1 96.1 53.9 1.69 0.47 223.7 294.6 0 1.6
Example 3-2 96.0 53.4 1.60 0.60 224.5 295.6 0 1.8
Example 3-3 95.9 53.4 1.55 0.65 223.0 301.2 0 1.8
Comparative Example 3-1 98.7 55.4 2.13 0.42 222.7 294.5 One 6.5
Comparative Example 3-2 95.9 53.3 1.98 1.12 217.3 281.4 0 2.2
Comparative Example 3-3 96.8 54.5 1.56 0.45 223.1 280.6 0.5 1.6
[310]
Referring to Table 6, when comparing Comparative Example 3-1, which is an existing product, with Examples, it can be seen that there is a significant improvement in plasticization efficiency and light resistance. In addition, in the case of Comparative Example 3-2 in which the content of the perhydride exceeds 10 parts by weight, it can be confirmed that it is inferior in all physical properties, particularly the heating loss and elongation, and the content of the perhydride generally applied as in Comparative Example 3-3 is 0.1 If it is less than parts by weight, it is confirmed that the elongation and stress resistance are poor, and the plasticization efficiency is also poor.
[311]
Through this, in order to improve plasticization efficiency and light resistance of existing products, by intentionally including perhydrides generated in the manufacturing process when converting to hydrogenated products, not only plasticization efficiency and stress resistance, but also physical properties in various aspects are improved. In addition, it can be seen that cost competitiveness compared to existing hydrogenated products can be secured through simplification of the purification process.
Claims
[Claim 1]
Cyclohexane polyester-based material, which is a compound represented by the following Chemical Formula 1; And a compound fruit hydride represented by the formula (2); the plasticizer composition the fruit package, includes the cyclohexane polyester material 100 that is an amount of 0.1 to 10 parts by weight parts by weight of contrast: [Formula 1] [Chemical Formula 2] wherein In Formulas 1 and 2, R 1 and R 2 are each independently an alkyl group having 4 to 10 carbon atoms, R 3 is a methyl group, n is 2 or 3, m is an integer of 0 to 2, and p is 0 Is an integer of 3, m+p is an integer of 0 to 3, and nm is an integer of 1 to 3.
[Claim 2]
The method of claim 1 wherein the plasticizer composition of the compound represented by Formula 1 is selected from the compounds represented by the following formulas 1-1 to 1-3 to the formula: [Chemical Formula 1-1] [Formula 1-2] [Chemical Formula 1-3] In Formulas 1-1 to 1-3, R 11 to R 15 are each independently an alkyl group having 4 to 10 carbon atoms.
[Claim 3]
The method of claim 1, wherein in Formulas 1 and 2, R 1 and R 2 are each independently an alkyl group having 5 to 10 carbon atoms, R 3 is a methyl group, and when n is 2, m is 0 or 1 , p is an integer of 0 to 2, m+p is an integer of 0 to 2, nm is 1 or 2, when n is 3, m is an integer of 0 to 2, and p is an integer of 0 to 3 And m+p is an integer of 0 to 3, and nm is an integer of 1 to 3.
[Claim 4]
The plasticizer composition of claim 1, wherein the cyclohexane polyester-based material is a compound represented by the following Formula 1-1, and the perhydride comprises at least one compound represented by the following Formula 2-1: [ Formula 1-1] [Chemical Formula 2-1] In Formulas 1-1 and 2-1, R 11 , R 12 and R 21 are each independently an alkyl group having 4 to 10 carbon atoms, and R 22 is hydrogen or a methyl group.
[Claim 5]
The plasticizer composition of claim 1, wherein the cyclohexane polyester-based material is a compound represented by Formula 1-2 below, and the perhydride comprises at least one compound represented by Formula 2-3 below: [ Formula 1-2] [Formula 2-3] In Formula 1-2 and Formula 2-3, R 11 , R 12 and R 21 are each independently an alkyl group having 4 to 10 carbon atoms, and R 22 is hydrogen or a methyl group. .
[Claim 6]
The method of claim 1, wherein the cyclohexane polyester-based material is a compound represented by the following Formula 1-3, and the perhydride is at least one compound selected from compounds represented by the following Formulas 2-5 to 2-10. Plasticizer composition comprising: [Formula 1-3] In Formula 1-3, R 13 to R 15 are each independently an alkyl group having 4 to 10 carbon atoms. [Formula 2-5] [Formula 2-6] [Formula 2-7] [Formula 2-8] [Formula 2-9] [Formula 2-10] In Formulas 2-5 to 2-10, R 23 and R 26 is each independently an alkyl group having 4 to 10 carbon atoms, and R 24 and R 25 are each independently hydrogen or a methyl group.
[Claim 7]
The method of claim 1, wherein in Formulas 1 and 2, R 1 and R 2 are each independently n-butyl group, isobutyl group, n-pentyl group, isopentyl group, n-hexyl group, isohexyl group, n -Selected from the group consisting of heptyl group, isoheptyl group, n-octyl group, isooctyl group, 2-ethylhexyl group, n-nonyl group, isononyl group, n-decyl group, isodecyl group and 2-propylheptyl group Which plasticizer composition.
[Claim 8]
The method of claim 1, wherein in Formulas 1 and 2, R 1 and R 2 are each independently selected from the group consisting of isoheptyl group, 2-ethylhexyl group, n-nonyl group, isononyl group and 2-propylheptyl group Plasticizer composition.
[Claim 9]
Hydrogenating any one aromatic carboxylic acid selected from the group consisting of isophthalic acid, terephthalic acid, and trimellitic acid to obtain a hydride containing cyclohexane polycarboxylic acid; And an esterification reaction of the hydride and the primary alkyl alcohol, wherein the primary alkyl alcohol has 4 to 10 alkyl carbon atoms, and the cyclohexane polycarboxylic acid is cyclohexane 1,3-dicarboxyl The method for producing the plasticizer composition of claim 1, which is an acid, cyclohexane 1,4-dicarboxylic acid or cyclohexane 1,2,4-tricarboxylic acid.
[Claim 10]
100 parts by weight of resin; And 5 to 150 parts by weight of the plasticizer composition of claim 1.
[Claim 11]
The resin composition of claim 10, wherein the resin is at least one selected from the group consisting of ethylene vinyl acetate, polyethylene, polypropylene, polyketone, polyvinyl chloride, polystyrene, polyurethane, natural rubber, synthetic rubber and thermoplastic elastomer. .