Abstract: Provided is a polyester composition having polyester as a main component. The polyester composition is characterized by: comprising phosphoric acid and an alkali metal phosphate with a phosphorous element content P (mol/t) at 1.8 mol/t 5.0 mol/t with respect to the whole polyester composition; containing one type of metal element of either Mn and Ca with the respective contents of divalent metal elements other than Mn and Ca of 5 ppm or lower with respect to the whole polyester composition; wherein if the alkali metal element content with respect to the whole polyester composition is M1 (mol/t) and the total sum of the Mn element content and the Ca element content with respect to the whole polyester composition is M2 (mol/t) a metal content M (mol/t) and the phosphorous element content P (mol/t) in the polyester composition found using formula (i) satisfy formula (ii). (i) M=M1/2+M2 (ii) 1.1=M/P=3.0. Further provided is a film using the polyester compound a sheet like structure an electric insulation sheet and a solar cell back sheet for use with the polyester composition and manufacturing method therefor. The polyester composition and the film the sheet like structure the electric insulation sheet and the solar cell back sheet using the polyester composition exhibit excellent heat resistance and moist heat resistance.
We Claim:
1. A polyester composition comprising polyester as a main component, wherein:
said polyester composition contains a phosphoric acid and an alkali metal phosphate,
a phosphorus element content P (mol/t) is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of said polyester composition,
said polyester composition contains at least one kind of metal element of Mn or Ca,
any divalent metal element content other than Mn and Ca is 5 ppm or less relative to the whole of said polyester composition, and
when an alkali metal element content relative to the whole of said polyester composition is denoted by M1 (mol/t), and a total amount of Mn element content and Ca element content relative to the whole of said polyester composition is denoted by M2 (mol/t), a metal element content M (mol/t) in said polyester composition which is calculated by expression (i) below and said phosphorus element content P (mol/t) satisfy expression (ii):
M=M1/2+M2 (i)
1.1≦M/P≦3.0 (ii).
2. The polyester composition according to claim 1, wherein said polyester which is the main component of said polyester composition contains a constituent ingredient having at least three carboxylic acid groups and/or hydroxyl groups as a copolymerization ingredient, and an amount of said constituent ingredient is 0.025 mol % or more and 1.5 mol % or less relative to the whole of constituent ingredients in said polyester.
3. A polyester film having a layer (layer P) containing a polyester composition comprising polyester as a main component, wherein:
said polyester is biaxially oriented,
said polyester composition contains a phosphoric acid and an alkali metal phosphate,
a phosphorus element content P (mol/t) in said polyester composition is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of said polyester composition,
said polyester composition contains at least one kind of metal element of Mn or Ca, any divalent metal element content other than Mn and Ca is 5 ppm or less relative to the whole of said polyester composition, and
when an alkali metal element content relative to the whole of said polyester composition is denoted by M1 (mol/t), and a total amount of Mn element content and Ca element content relative to the whole of said polyester composition is denoted by M2 (mol/t), a metal element content M (mol/t) in said polyester composition which is calculated by expression (i) below and said phosphorus element content P (mol/t) satisfy expression (ii):
M=M1/2+M2 (i)
1.1≦M/P≦3.0 (ii) .
4. The film according to claim 3, wherein said layer P is layer P′ containing a coloring pigment, and, a content amount of white pigment as said coloring pigment is 1 wt % or more and 20 wt % or less relative to the whole of said layer P′, or a content amount of black pigment as said coloring pigment is 0.5 wt % or more and 5 wt % or less relative to the whole of said layer P′.
5. A solar cell back sheet comprising a polyester composition comprising polyester as a main component, wherein:
said polyester composition contains a phosphoric acid and an alkali metal phosphate,
a phosphorus element content P (mol/t) in said polyester composition is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of said polyester composition,
said polyester composition contains at least one kind of metal element of Mn or Ca,
any divalent metal element content other than Mn and Ca is 5 ppm or less relative to the whole of said polyester composition, and
when an alkali metal element content relative to the whole of said polyester composition is represented by M1 (mol/t) and a total amount of Mn element content and Ca element content relative to the whole of said polyester composition is represented by M2 (mol/t), a metal element content M (mol/t) in said polyester composition which is
calculated by expression (i) below and said phosphorus element content P (mol/t) satisfy
expression (ii):
M=M1/2+M2 (i)
1.1≦M/P≦3.0 (ii).
6. A process for producing the polyester composition according to claim 1, comprising:
an ester exchange process in which an ester exchange reaction is performed by
using a dicarboxylic acid dimethyl ester and a dialcohol in a presence of manganese acetate
and/or calcium acetate as a catalyst, and
a polymerization process in which a polymerization is performed after an alkali
metal phosphate of 0.5 mol/t or more and 3.0 mol/t or less is added to a composition
obtained by said ester exchange process and a phosphorus acid of 0.4 times or more and
1.5 times or less in terms of the number of moles relative to said alkali metal phosphate is
added.
| # | Name | Date |
|---|---|---|
| 1 | 6877-CHENP-2013-RELEVANT DOCUMENTS [30-09-2023(online)].pdf | 2023-09-30 |
| 1 | 6877-CHENP-2013.pdf | 2013-08-28 |
| 2 | 6877-CHENP-2013-RELEVANT DOCUMENTS [24-09-2022(online)].pdf | 2022-09-24 |
| 2 | GPA.pdf | 2013-09-03 |
| 3 | FORM-5.pdf | 2013-09-03 |
| 3 | 6877-CHENP-2013-RELEVANT DOCUMENTS [27-07-2021(online)].pdf | 2021-07-27 |
| 4 | FORM-3.pdf | 2013-09-03 |
| 4 | 6877-CHENP-2013-RELEVANT DOCUMENTS [21-02-2020(online)].pdf | 2020-02-21 |
| 5 | 6877-CHENP-2013-PatentCertificate24-09-2019.pdf | 2019-09-24 |
| 5 | 4113-2013-COMPLETE SPECIFICATION.pdf | 2013-09-03 |
| 6 | Abstract_Granted 321239_24-09-2019.pdf | 2019-09-24 |
| 6 | 6877-CHENP-2013 CORRESPONDENCE OTHERS 21-02-2014.pdf | 2014-02-21 |
| 7 | Claims_Granted 321239_24-09-2019.pdf | 2019-09-24 |
| 7 | 6877-CHENP-2013 FORM-3 21-02-2014.pdf | 2014-02-21 |
| 8 | ENGLISH TRANSLATION.pdf | 2014-08-22 |
| 8 | Description_Granted 321239_24-09-2019.pdf | 2019-09-24 |
| 9 | 6877-CHENP-2013 FORM-3 27-05-2015.pdf | 2015-05-27 |
| 9 | Marked up Claims_Granted 321239_24-09-2019.pdf | 2019-09-24 |
| 10 | 6877-CHENP-2013 CORRESPONDENCE OTHERS 27-05-2015.pdf | 2015-05-27 |
| 10 | Correspondence By Agent_Proof of Right_09-05-2019.pdf | 2019-05-09 |
| 11 | 6877-CHENP-2013-ABSTRACT [07-05-2019(online)].pdf | 2019-05-07 |
| 11 | 6877-CHENP-2013-FORM 3 [08-01-2018(online)].pdf | 2018-01-08 |
| 12 | 6877-CHENP-2013-CLAIMS [07-05-2019(online)].pdf | 2019-05-07 |
| 12 | 6877-CHENP-2013-FER.pdf | 2018-11-12 |
| 13 | 6877-CHENP-2013-certified copy of translation (MANDATORY) [11-01-2019(online)].pdf | 2019-01-11 |
| 13 | 6877-CHENP-2013-COMPLETE SPECIFICATION [07-05-2019(online)].pdf | 2019-05-07 |
| 14 | 6877-CHENP-2013-FER_SER_REPLY [07-05-2019(online)].pdf | 2019-05-07 |
| 14 | 6877-CHENP-2013-Proof of Right (MANDATORY) [07-05-2019(online)].pdf | 2019-05-07 |
| 15 | 6877-CHENP-2013-FORM 3 [07-05-2019(online)].pdf | 2019-05-07 |
| 15 | 6877-CHENP-2013-PETITION UNDER RULE 137 [07-05-2019(online)].pdf | 2019-05-07 |
| 16 | 6877-CHENP-2013-FORM-26 [07-05-2019(online)].pdf | 2019-05-07 |
| 16 | 6877-CHENP-2013-OTHERS [07-05-2019(online)].pdf | 2019-05-07 |
| 17 | 6877-CHENP-2013-Information under section 8(2) (MANDATORY) [07-05-2019(online)].pdf | 2019-05-07 |
| 18 | 6877-CHENP-2013-OTHERS [07-05-2019(online)].pdf | 2019-05-07 |
| 18 | 6877-CHENP-2013-FORM-26 [07-05-2019(online)].pdf | 2019-05-07 |
| 19 | 6877-CHENP-2013-FORM 3 [07-05-2019(online)].pdf | 2019-05-07 |
| 19 | 6877-CHENP-2013-PETITION UNDER RULE 137 [07-05-2019(online)].pdf | 2019-05-07 |
| 20 | 6877-CHENP-2013-FER_SER_REPLY [07-05-2019(online)].pdf | 2019-05-07 |
| 20 | 6877-CHENP-2013-Proof of Right (MANDATORY) [07-05-2019(online)].pdf | 2019-05-07 |
| 21 | 6877-CHENP-2013-certified copy of translation (MANDATORY) [11-01-2019(online)].pdf | 2019-01-11 |
| 21 | 6877-CHENP-2013-COMPLETE SPECIFICATION [07-05-2019(online)].pdf | 2019-05-07 |
| 22 | 6877-CHENP-2013-CLAIMS [07-05-2019(online)].pdf | 2019-05-07 |
| 22 | 6877-CHENP-2013-FER.pdf | 2018-11-12 |
| 23 | 6877-CHENP-2013-ABSTRACT [07-05-2019(online)].pdf | 2019-05-07 |
| 23 | 6877-CHENP-2013-FORM 3 [08-01-2018(online)].pdf | 2018-01-08 |
| 24 | Correspondence By Agent_Proof of Right_09-05-2019.pdf | 2019-05-09 |
| 24 | 6877-CHENP-2013 CORRESPONDENCE OTHERS 27-05-2015.pdf | 2015-05-27 |
| 25 | 6877-CHENP-2013 FORM-3 27-05-2015.pdf | 2015-05-27 |
| 25 | Marked up Claims_Granted 321239_24-09-2019.pdf | 2019-09-24 |
| 26 | Description_Granted 321239_24-09-2019.pdf | 2019-09-24 |
| 26 | ENGLISH TRANSLATION.pdf | 2014-08-22 |
| 27 | 6877-CHENP-2013 FORM-3 21-02-2014.pdf | 2014-02-21 |
| 27 | Claims_Granted 321239_24-09-2019.pdf | 2019-09-24 |
| 28 | 6877-CHENP-2013 CORRESPONDENCE OTHERS 21-02-2014.pdf | 2014-02-21 |
| 28 | Abstract_Granted 321239_24-09-2019.pdf | 2019-09-24 |
| 29 | 4113-2013-COMPLETE SPECIFICATION.pdf | 2013-09-03 |
| 29 | 6877-CHENP-2013-PatentCertificate24-09-2019.pdf | 2019-09-24 |
| 30 | 6877-CHENP-2013-RELEVANT DOCUMENTS [21-02-2020(online)].pdf | 2020-02-21 |
| 30 | FORM-3.pdf | 2013-09-03 |
| 31 | FORM-5.pdf | 2013-09-03 |
| 31 | 6877-CHENP-2013-RELEVANT DOCUMENTS [27-07-2021(online)].pdf | 2021-07-27 |
| 32 | GPA.pdf | 2013-09-03 |
| 32 | 6877-CHENP-2013-RELEVANT DOCUMENTS [24-09-2022(online)].pdf | 2022-09-24 |
| 33 | 6877-CHENP-2013.pdf | 2013-08-28 |
| 33 | 6877-CHENP-2013-RELEVANT DOCUMENTS [30-09-2023(online)].pdf | 2023-09-30 |
| 1 | 2018-10-09_09-10-2018.pdf |