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Polyester Composition And Film Using Same,Sheet Like Structure,Electric Insulation Sheet,And Solar Cell Back Sheet,And Manufacturing Methods Therefor

Abstract: Provided is a polyester composition having polyester as a main component. The polyester composition is characterized by: comprising phosphoric acid and an alkali metal phosphate with a phosphorous element content P (mol/t) at 1.8 mol/t 5.0 mol/t with respect to the whole polyester composition; containing one type of metal element of either Mn and Ca with the respective contents of divalent metal elements other than Mn and Ca of 5 ppm or lower with respect to the whole polyester composition; wherein if the alkali metal element content with respect to the whole polyester composition is M1 (mol/t) and the total sum of the Mn element content and the Ca element content with respect to the whole polyester composition is M2 (mol/t) a metal content M (mol/t) and the phosphorous element content P (mol/t) in the polyester composition found using formula (i) satisfy formula (ii). (i) M=M1/2+M2 (ii) 1.1=M/P=3.0. Further provided is a film using the polyester compound a sheet like structure an electric insulation sheet and a solar cell back sheet for use with the polyester composition and manufacturing method therefor. The polyester composition and the film the sheet like structure the electric insulation sheet and the solar cell back sheet using the polyester composition exhibit excellent heat resistance and moist heat resistance.

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
26 August 2013
Publication Number
39/2014
Publication Type
INA
Invention Field
POLYMER TECHNOLOGY
Status
Email
patent@depenning.com
Parent Application
Patent Number
Legal Status
Grant Date
2019-09-24
Renewal Date

Applicants

Toray Industries Inc.
1 1 Nihonbashi Muromachi 2 chome Chuo ku Tokyo 1038666

Inventors

1. SUZUKI Tadamasa
c/o Shiga Plant Toray Industries Inc. 1 1 Sonoyama 1 chome Otsu shi Shiga 5208558
2. AOYAMA Shigeru
c/o Shiga Plant Toray Industries Inc. 1 1 Sonoyama 1 chome Otsu shi Shiga 5208558
3. KOJIMA Hiroji
c/o Mishima Plant Toray Industries Inc. 4845 Mishima shi Shizuoka 4118652
4. TAKAHASHI Kozo
c/o Shiga Plant Toray Industries Inc. 1 1 Sonoyama 1 chome Otsu shi Shiga 5208558

Specification

We Claim:
1. A polyester composition comprising polyester as a main component, wherein:
said polyester composition contains a phosphoric acid and an alkali metal phosphate,
a phosphorus element content P (mol/t) is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of said polyester composition,
said polyester composition contains at least one kind of metal element of Mn or Ca,
any divalent metal element content other than Mn and Ca is 5 ppm or less relative to the whole of said polyester composition, and
when an alkali metal element content relative to the whole of said polyester composition is denoted by M1 (mol/t), and a total amount of Mn element content and Ca element content relative to the whole of said polyester composition is denoted by M2 (mol/t), a metal element content M (mol/t) in said polyester composition which is calculated by expression (i) below and said phosphorus element content P (mol/t) satisfy expression (ii):
M=M1/2+M2 (i)
1.1≦M/P≦3.0 (ii).
2. The polyester composition according to claim 1, wherein said polyester which is the main component of said polyester composition contains a constituent ingredient having at least three carboxylic acid groups and/or hydroxyl groups as a copolymerization ingredient, and an amount of said constituent ingredient is 0.025 mol % or more and 1.5 mol % or less relative to the whole of constituent ingredients in said polyester.
3. A polyester film having a layer (layer P) containing a polyester composition comprising polyester as a main component, wherein:
said polyester is biaxially oriented,
said polyester composition contains a phosphoric acid and an alkali metal phosphate,
a phosphorus element content P (mol/t) in said polyester composition is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of said polyester composition,

said polyester composition contains at least one kind of metal element of Mn or Ca, any divalent metal element content other than Mn and Ca is 5 ppm or less relative to the whole of said polyester composition, and
when an alkali metal element content relative to the whole of said polyester composition is denoted by M1 (mol/t), and a total amount of Mn element content and Ca element content relative to the whole of said polyester composition is denoted by M2 (mol/t), a metal element content M (mol/t) in said polyester composition which is calculated by expression (i) below and said phosphorus element content P (mol/t) satisfy expression (ii):
M=M1/2+M2 (i)
1.1≦M/P≦3.0 (ii) .
4. The film according to claim 3, wherein said layer P is layer P′ containing a coloring pigment, and, a content amount of white pigment as said coloring pigment is 1 wt % or more and 20 wt % or less relative to the whole of said layer P′, or a content amount of black pigment as said coloring pigment is 0.5 wt % or more and 5 wt % or less relative to the whole of said layer P′.
5. A solar cell back sheet comprising a polyester composition comprising polyester as a main component, wherein:
said polyester composition contains a phosphoric acid and an alkali metal phosphate,
a phosphorus element content P (mol/t) in said polyester composition is 1.8 mol/t or more and 5.0 mol/t or less relative to the whole of said polyester composition,
said polyester composition contains at least one kind of metal element of Mn or Ca,
any divalent metal element content other than Mn and Ca is 5 ppm or less relative to the whole of said polyester composition, and
when an alkali metal element content relative to the whole of said polyester composition is represented by M1 (mol/t) and a total amount of Mn element content and Ca element content relative to the whole of said polyester composition is represented by M2 (mol/t), a metal element content M (mol/t) in said polyester composition which is

calculated by expression (i) below and said phosphorus element content P (mol/t) satisfy
expression (ii):
M=M1/2+M2 (i)
1.1≦M/P≦3.0 (ii).
6. A process for producing the polyester composition according to claim 1, comprising:
an ester exchange process in which an ester exchange reaction is performed by
using a dicarboxylic acid dimethyl ester and a dialcohol in a presence of manganese acetate
and/or calcium acetate as a catalyst, and
a polymerization process in which a polymerization is performed after an alkali
metal phosphate of 0.5 mol/t or more and 3.0 mol/t or less is added to a composition
obtained by said ester exchange process and a phosphorus acid of 0.4 times or more and
1.5 times or less in terms of the number of moles relative to said alkali metal phosphate is
added.

Documents

Application Documents

# Name Date
1 6877-CHENP-2013-RELEVANT DOCUMENTS [30-09-2023(online)].pdf 2023-09-30
1 6877-CHENP-2013.pdf 2013-08-28
2 6877-CHENP-2013-RELEVANT DOCUMENTS [24-09-2022(online)].pdf 2022-09-24
2 GPA.pdf 2013-09-03
3 FORM-5.pdf 2013-09-03
3 6877-CHENP-2013-RELEVANT DOCUMENTS [27-07-2021(online)].pdf 2021-07-27
4 FORM-3.pdf 2013-09-03
4 6877-CHENP-2013-RELEVANT DOCUMENTS [21-02-2020(online)].pdf 2020-02-21
5 6877-CHENP-2013-PatentCertificate24-09-2019.pdf 2019-09-24
5 4113-2013-COMPLETE SPECIFICATION.pdf 2013-09-03
6 Abstract_Granted 321239_24-09-2019.pdf 2019-09-24
6 6877-CHENP-2013 CORRESPONDENCE OTHERS 21-02-2014.pdf 2014-02-21
7 Claims_Granted 321239_24-09-2019.pdf 2019-09-24
7 6877-CHENP-2013 FORM-3 21-02-2014.pdf 2014-02-21
8 ENGLISH TRANSLATION.pdf 2014-08-22
8 Description_Granted 321239_24-09-2019.pdf 2019-09-24
9 6877-CHENP-2013 FORM-3 27-05-2015.pdf 2015-05-27
9 Marked up Claims_Granted 321239_24-09-2019.pdf 2019-09-24
10 6877-CHENP-2013 CORRESPONDENCE OTHERS 27-05-2015.pdf 2015-05-27
10 Correspondence By Agent_Proof of Right_09-05-2019.pdf 2019-05-09
11 6877-CHENP-2013-ABSTRACT [07-05-2019(online)].pdf 2019-05-07
11 6877-CHENP-2013-FORM 3 [08-01-2018(online)].pdf 2018-01-08
12 6877-CHENP-2013-CLAIMS [07-05-2019(online)].pdf 2019-05-07
12 6877-CHENP-2013-FER.pdf 2018-11-12
13 6877-CHENP-2013-certified copy of translation (MANDATORY) [11-01-2019(online)].pdf 2019-01-11
13 6877-CHENP-2013-COMPLETE SPECIFICATION [07-05-2019(online)].pdf 2019-05-07
14 6877-CHENP-2013-FER_SER_REPLY [07-05-2019(online)].pdf 2019-05-07
14 6877-CHENP-2013-Proof of Right (MANDATORY) [07-05-2019(online)].pdf 2019-05-07
15 6877-CHENP-2013-FORM 3 [07-05-2019(online)].pdf 2019-05-07
15 6877-CHENP-2013-PETITION UNDER RULE 137 [07-05-2019(online)].pdf 2019-05-07
16 6877-CHENP-2013-FORM-26 [07-05-2019(online)].pdf 2019-05-07
16 6877-CHENP-2013-OTHERS [07-05-2019(online)].pdf 2019-05-07
17 6877-CHENP-2013-Information under section 8(2) (MANDATORY) [07-05-2019(online)].pdf 2019-05-07
18 6877-CHENP-2013-OTHERS [07-05-2019(online)].pdf 2019-05-07
18 6877-CHENP-2013-FORM-26 [07-05-2019(online)].pdf 2019-05-07
19 6877-CHENP-2013-FORM 3 [07-05-2019(online)].pdf 2019-05-07
19 6877-CHENP-2013-PETITION UNDER RULE 137 [07-05-2019(online)].pdf 2019-05-07
20 6877-CHENP-2013-FER_SER_REPLY [07-05-2019(online)].pdf 2019-05-07
20 6877-CHENP-2013-Proof of Right (MANDATORY) [07-05-2019(online)].pdf 2019-05-07
21 6877-CHENP-2013-certified copy of translation (MANDATORY) [11-01-2019(online)].pdf 2019-01-11
21 6877-CHENP-2013-COMPLETE SPECIFICATION [07-05-2019(online)].pdf 2019-05-07
22 6877-CHENP-2013-CLAIMS [07-05-2019(online)].pdf 2019-05-07
22 6877-CHENP-2013-FER.pdf 2018-11-12
23 6877-CHENP-2013-ABSTRACT [07-05-2019(online)].pdf 2019-05-07
23 6877-CHENP-2013-FORM 3 [08-01-2018(online)].pdf 2018-01-08
24 Correspondence By Agent_Proof of Right_09-05-2019.pdf 2019-05-09
24 6877-CHENP-2013 CORRESPONDENCE OTHERS 27-05-2015.pdf 2015-05-27
25 6877-CHENP-2013 FORM-3 27-05-2015.pdf 2015-05-27
25 Marked up Claims_Granted 321239_24-09-2019.pdf 2019-09-24
26 Description_Granted 321239_24-09-2019.pdf 2019-09-24
26 ENGLISH TRANSLATION.pdf 2014-08-22
27 6877-CHENP-2013 FORM-3 21-02-2014.pdf 2014-02-21
27 Claims_Granted 321239_24-09-2019.pdf 2019-09-24
28 6877-CHENP-2013 CORRESPONDENCE OTHERS 21-02-2014.pdf 2014-02-21
28 Abstract_Granted 321239_24-09-2019.pdf 2019-09-24
29 4113-2013-COMPLETE SPECIFICATION.pdf 2013-09-03
29 6877-CHENP-2013-PatentCertificate24-09-2019.pdf 2019-09-24
30 6877-CHENP-2013-RELEVANT DOCUMENTS [21-02-2020(online)].pdf 2020-02-21
30 FORM-3.pdf 2013-09-03
31 FORM-5.pdf 2013-09-03
31 6877-CHENP-2013-RELEVANT DOCUMENTS [27-07-2021(online)].pdf 2021-07-27
32 GPA.pdf 2013-09-03
32 6877-CHENP-2013-RELEVANT DOCUMENTS [24-09-2022(online)].pdf 2022-09-24
33 6877-CHENP-2013.pdf 2013-08-28
33 6877-CHENP-2013-RELEVANT DOCUMENTS [30-09-2023(online)].pdf 2023-09-30

Search Strategy

1 2018-10-09_09-10-2018.pdf

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