Abstract: A polymetalloxane according to an embodiment of the present invention has a structural unit represented by general formula (1). (In general formula (1), R1 is a hydrogen atom or a C1-10 alkyl group. R2 and R3 are independently a hydrogen atom, a C1-12 alkyl group, a C5-12 alicyclic alkyl group, a C6-30 aromatic group, or a C1-12 acyl group. R2 and R3 are connected by a carbon-carbon saturated bond or a carbon-carbon unsaturated bond, and may form a ring structure. a is an integer of 0 or 1. M represents a metal atom selected from the group consisting of Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Zr, Nb, Mo, Ru, Rh, Pd, Ag, In, Sn, Sb, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, and Bi. m is an integer representing the valence of the metal atom M. b is an integer from 1 to (m-2).)
1. A polymetalloxane comprising a constituent unit represented by the following
general formula (1):
wherein,
R1 is a hydrogen atom or an alkyl group having 1 to 10 carbon atoms;
9 ^
R and R are each independently a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, an alicyclic alkyl group having 5 to 12 carbon atoms, an aromatic group having 6 to 30 carbon atoms, or an acyl group having 1 to 12 carbon atoms;
9 ^
R and R are optionally linked together via a carbon-carbon saturated or a carbon-carbon unsaturated bond to form a ring structure;
a is an integer of 0 or 1;
M represents a metal atom selected from the group consisting of Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, Zr, Nb, Mo, Ru, Rh, Pd, Ag, In, Sn, Sb, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, and Bi;
m is an integer indicating the valence of the metal atom M; and
b is an integer of 1 to (m-2).
2. The polymetalloxane according to claim 1, wherein the constituent unit
represented by the general formula (1) is a constituent unit represented by the following general formula (2);
wherein,
R4 is a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, an alicyclic alkyl group having 5 to 12 carbon atoms, an aromatic group having 6 to 30 carbon atoms, or an acyl group having 1 to 12 carbon atoms;
R5 is, independently from R4, a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, an alicyclic alkyl group having 5 to 12 carbon atoms, or an aromatic group having 6 to 30 carbon atoms; and
R4 and R5 are optionally linked together via a carbon-carbon saturated or a carbon-carbon unsaturated bond to form a ring structure.
3. The polymetalloxane according to claim 1, wherein the constituent unit
represented by the general formula (1) is a constituent unit represented by the following general formula (3);
wherein,
R6 and R7 are each independently a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, an alicyclic alkyl group having 5 to 12 carbon atoms, or an aromatic group having 6 to 30 carbon atoms; and
R6 and R7 are optionally linked together via a carbon-carbon saturated or a carbon-carbon unsaturated bond to form a ring structure.
4. The polymetalloxane according to any one of claims 1 to 3, wherein the integer a is 1.
5. The polymetalloxane according to any one of claims 1 to 4, wherein the metal atom M comprises at least one metal atom selected from the group consisting of Al, Ti, Zr, and Sn.
6. A composition comprising the polymetalloxane according to any one of claims 1 to 5.
7. The composition according to claim 6, further comprising a metal element-containing compound.
8. A cured film comprising the polymetalloxane according to any one of claims 1 to 5.
9. A cured film comprising the composition according to claim 6 or 7.
10. A method of producing a cured film, comprising the step of heating the polymetalloxane according to any one of claims 1 to 5 or the composition according to claim 6 or 7.
11. A member comprising the cured film according to claim 8 or 9.
12. An electronic component comprising the member according to claim 11.
13. A fiber comprising the polymetalloxane according to any one of claims 1 to 5.
14 A fiber comprising the composition according to claim 6 or 7.
15. A method of producing a fiber, comprising the step of spinning the polymetalloxane according to any one of claims 1 to 5 or the composition according to claim 6 or 7 into a fiber.
16. The method of producing a fiber according to claim 15, comprising the step of firing the fiber obtained by the spinning step.
17. A binder for ceramic molding comprising the polymetalloxane according to any one of claims 1 to 5.
| Section | Controller | Decision Date |
|---|---|---|
| # | Name | Date |
|---|---|---|
| 1 | 202047045911-Correspondence to notify the Controller [27-01-2023(online)].pdf | 2023-01-27 |
| 1 | 202047045911-STATEMENT OF UNDERTAKING (FORM 3) [21-10-2020(online)].pdf | 2020-10-21 |
| 2 | 202047045911-US(14)-HearingNotice-(HearingDate-30-01-2023).pdf | 2023-01-20 |
| 2 | 202047045911-PROOF OF RIGHT [21-10-2020(online)].pdf | 2020-10-21 |
| 3 | 202047045911-Response to office action [19-01-2023(online)].pdf | 2023-01-19 |
| 3 | 202047045911-PRIORITY DOCUMENTS [21-10-2020(online)].pdf | 2020-10-21 |
| 4 | 202047045911-FORM 1 [21-10-2020(online)].pdf | 2020-10-21 |
| 4 | 202047045911-ABSTRACT [30-06-2022(online)].pdf | 2022-06-30 |
| 5 | 202047045911-DECLARATION OF INVENTORSHIP (FORM 5) [21-10-2020(online)].pdf | 2020-10-21 |
| 5 | 202047045911-CLAIMS [30-06-2022(online)].pdf | 2022-06-30 |
| 6 | 202047045911-FER_SER_REPLY [30-06-2022(online)].pdf | 2022-06-30 |
| 6 | 202047045911-COMPLETE SPECIFICATION [21-10-2020(online)].pdf | 2020-10-21 |
| 7 | 202047045911-FORM-26 [05-11-2020(online)].pdf | 2020-11-05 |
| 7 | 202047045911-FORM 3 [30-06-2022(online)].pdf | 2022-06-30 |
| 8 | 202047045911-FORM-26 [30-06-2022(online)].pdf | 2022-06-30 |
| 8 | 202047045911-FORM 3 [20-03-2021(online)].pdf | 2021-03-20 |
| 9 | 202047045911.pdf | 2021-10-18 |
| 9 | 202047045911-Information under section 8(2) [30-06-2022(online)].pdf | 2022-06-30 |
| 10 | 202047045911-Correspondence_Form1(Proof of Right),GPOA_27-10-2021.pdf | 2021-10-27 |
| 10 | 202047045911-OTHERS [30-06-2022(online)].pdf | 2022-06-30 |
| 11 | 202047045911-FER.pdf | 2022-01-03 |
| 11 | 202047045911-FORM 18 [23-12-2021(online)].pdf | 2021-12-23 |
| 12 | 202047045911-FORM 3 [30-12-2021(online)].pdf | 2021-12-30 |
| 13 | 202047045911-FER.pdf | 2022-01-03 |
| 13 | 202047045911-FORM 18 [23-12-2021(online)].pdf | 2021-12-23 |
| 14 | 202047045911-Correspondence_Form1(Proof of Right),GPOA_27-10-2021.pdf | 2021-10-27 |
| 14 | 202047045911-OTHERS [30-06-2022(online)].pdf | 2022-06-30 |
| 15 | 202047045911-Information under section 8(2) [30-06-2022(online)].pdf | 2022-06-30 |
| 15 | 202047045911.pdf | 2021-10-18 |
| 16 | 202047045911-FORM 3 [20-03-2021(online)].pdf | 2021-03-20 |
| 16 | 202047045911-FORM-26 [30-06-2022(online)].pdf | 2022-06-30 |
| 17 | 202047045911-FORM 3 [30-06-2022(online)].pdf | 2022-06-30 |
| 17 | 202047045911-FORM-26 [05-11-2020(online)].pdf | 2020-11-05 |
| 18 | 202047045911-COMPLETE SPECIFICATION [21-10-2020(online)].pdf | 2020-10-21 |
| 18 | 202047045911-FER_SER_REPLY [30-06-2022(online)].pdf | 2022-06-30 |
| 19 | 202047045911-CLAIMS [30-06-2022(online)].pdf | 2022-06-30 |
| 19 | 202047045911-DECLARATION OF INVENTORSHIP (FORM 5) [21-10-2020(online)].pdf | 2020-10-21 |
| 20 | 202047045911-FORM 1 [21-10-2020(online)].pdf | 2020-10-21 |
| 20 | 202047045911-ABSTRACT [30-06-2022(online)].pdf | 2022-06-30 |
| 21 | 202047045911-Response to office action [19-01-2023(online)].pdf | 2023-01-19 |
| 21 | 202047045911-PRIORITY DOCUMENTS [21-10-2020(online)].pdf | 2020-10-21 |
| 22 | 202047045911-US(14)-HearingNotice-(HearingDate-30-01-2023).pdf | 2023-01-20 |
| 22 | 202047045911-PROOF OF RIGHT [21-10-2020(online)].pdf | 2020-10-21 |
| 23 | 202047045911-STATEMENT OF UNDERTAKING (FORM 3) [21-10-2020(online)].pdf | 2020-10-21 |
| 23 | 202047045911-Correspondence to notify the Controller [27-01-2023(online)].pdf | 2023-01-27 |
| 1 | SEARCHstrategyE_31-12-2021.pdf |