Abstract: The purpose of the present invention is to provide: a polypropylene film exhibiting high dielectric breakdown voltage even in a high temperature environment whereby voltage resistance and reliability can be realized in a capacitor even in a high temperature environment; a metal membrane layered film and a film capacitor using the polypropylene film; and a method for manufacturing the same. In order to achieve this purpose the present invention is configured as described below. A polypropylene film in which the degree of crystal orientation in the a crystal (110) plane measured by wide angle X ray diffraction is 0.78 or greater and the sum of the heat shrinkages in the width direction and the longitudinal direction after 10 minutes of heat treatment at 120°C is 4.0% or less. A polypropylene film in which the unevenness of thickness in the longitudinal direction is 0.1 6.0% and the sum of the maximum point strength in the longitudinal direction and the maximum point strength in the width direction is 400 MPa or greater.
CLAIMS
1. A polypropylene film having a crystal orientation degree of an a-crystal (110) plane measured by wide-angle X-ray diffractometry of 0.78 or more, and having a sum of thermal shrinkage rates in a width direction and a longitudinal direction after being subjected to heat treatment at 120°C for 10 minutes of 4.0% or less.
2. The polypropylene film according to claim 1, having a relationship between a stress at 5% elongation in the width direction (TD-F5 value) and a stress at 5% elongation in the longitudinal direction (MD-F5 value) of (MD-F5 value)/(TD-F5 value) > 0.4.
3. The polypropylene film according to claim 1 or 2, having a relationship between a maximum strength (St) and a maximum elongation (El) in the longitudinal direction of (St)/(El) > 1.2.
4. The polypropylene film according to any one of claims 1
to 3, having a stress at 50% elongation in the longitudinal
direction at 125°C (F50 value) of 13 MPa or more.
5. The polypropylene film according to any one of claims 1 to 4, having a volume resistivity at 110°C of 5 x 1014 Q-cm or more.
6. The polypropylene film according to any one of claims 1 to 5, having a glossiness of at least one surface of 130% or more and less than 150%, and having, when being stacked, a coefficient of static friction (|is) of 0.1 or more and 1.5 or less.
7. The polypropylene film according to any one of claims 1 to 6, having a nitrogen element composition amount detected by X-ray photoelectron spectroscopy (XPS) of 1 atomic% or more in at least one surface.
8. The polypropylene film according to any one of claims 1 to 7, which is obtained by subjecting at least one surface to plasma treatment.
9. A polypropylene film having a thickness unevenness in a longitudinal direction of 0.1 to 6.0%, and having a sum of a maximum strength in the longitudinal direction and a maximum strength in a width direction of 400 MPa or more.
10. The polypropylene film according to claim 9, having a
thermal shrinkage rate in the longitudinal direction after heat treatment at 125°C for 15 minutes and a thermal shrinkage rate in the width direction after heat treatment at 125°C for 15 minutes of both 2% or less.
11. The polypropylene film according to claim 9 or 10, having a total haze of 0.01 to 1.0%.
12. The polypropylene film according to any one of claims 9 to 11, which is obtained by stretching an unstretched polypropylene film having a mesomorphic phase structure 2 times or more in at least one direction.
13. A metal membrane layered film comprising the polypropylene film according to any one of claims 1 to 12, and a metal membrane provided on at least one surface of the polypropylene film.
14. A film capacitor comprising the metal membrane layered film according to claim 13.
15. A method for manufacturing a polypropylene film, the method comprising a step of subjecting at least one surface of the polypropylene film according to any one of claims 1 to 7 to plasma treatment.
16. A method for manufacturing the polypropylene film according to any one of claims 9 to 11, the method comprising a step of stretching an unstretched polypropylene film having a mesomorphic phase structure 2 times or more in at least one direction.
17 . A method for manufacturing a metal membrane layered film, the method comprising a metal membrane providing step of providing a metal membrane to at least one surface of a polypropylene film obtained by the manufacturing method according to claim 15 or 16.
18. A method for manufacturing a film capacitor, the method comprising using a metal membrane layered film obtained by the manufacturing method according to claim 17.
| # | Name | Date |
|---|---|---|
| 1 | 201747041654-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [21-11-2017(online)].pdf | 2017-11-21 |
| 2 | 201747041654-STATEMENT OF UNDERTAKING (FORM 3) [21-11-2017(online)].pdf | 2017-11-21 |
| 3 | 201747041654-PROOF OF RIGHT [21-11-2017(online)].pdf | 2017-11-21 |
| 4 | 201747041654-PRIORITY DOCUMENTS [21-11-2017(online)].pdf | 2017-11-21 |
| 5 | 201747041654-POWER OF AUTHORITY [21-11-2017(online)].pdf | 2017-11-21 |
| 6 | 201747041654-FORM 1 [21-11-2017(online)].pdf | 2017-11-21 |
| 7 | 201747041654-DRAWINGS [21-11-2017(online)].pdf | 2017-11-21 |
| 8 | 201747041654-DECLARATION OF INVENTORSHIP (FORM 5) [21-11-2017(online)].pdf | 2017-11-21 |
| 9 | 201747041654-COMPLETE SPECIFICATION [21-11-2017(online)].pdf | 2017-11-21 |
| 10 | 201747041654-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [21-11-2017(online)].pdf | 2017-11-21 |
| 11 | 201747041654.pdf | 2017-11-24 |
| 12 | 201747041654-FORM 3 [28-11-2017(online)].pdf | 2017-11-28 |
| 13 | Correspondence by Agent_Executed Form1_04-12-2017.pdf | 2017-12-04 |
| 14 | 201747041654-FORM 3 [28-05-2018(online)].pdf | 2018-05-28 |
| 15 | 201747041654-FORM 3 [11-12-2018(online)].pdf | 2018-12-11 |
| 16 | 201747041654-FORM 18 [15-04-2019(online)].pdf | 2019-04-15 |
| 17 | 201747041654-FORM 3 [23-05-2019(online)].pdf | 2019-05-23 |
| 18 | 201747041654-FORM 3 [17-12-2019(online)].pdf | 2019-12-17 |
| 19 | 201747041654-FER.pdf | 2020-03-09 |
| 20 | 201747041654-certified copy of translation [03-06-2020(online)].pdf | 2020-06-03 |
| 21 | 201747041654-OTHERS [14-07-2020(online)].pdf | 2020-07-14 |
| 22 | 201747041654-FORM-26 [14-07-2020(online)].pdf | 2020-07-14 |
| 23 | 201747041654-FORM 3 [14-07-2020(online)].pdf | 2020-07-14 |
| 24 | 201747041654-FER_SER_REPLY [14-07-2020(online)].pdf | 2020-07-14 |
| 25 | 201747041654-DRAWING [14-07-2020(online)].pdf | 2020-07-14 |
| 26 | 201747041654-CLAIMS [14-07-2020(online)].pdf | 2020-07-14 |
| 27 | 201747041654-ABSTRACT [14-07-2020(online)].pdf | 2020-07-14 |
| 28 | 201747041654-Written submissions and relevant documents [14-12-2020(online)].pdf | 2020-12-14 |
| 29 | 201747041654-Retyped Pages under Rule 14(1) [14-12-2020(online)].pdf | 2020-12-14 |
| 30 | 201747041654-2. Marked Copy under Rule 14(2) [14-12-2020(online)].pdf | 2020-12-14 |
| 31 | 201747041654-PatentCertificate09-02-2021.pdf | 2021-02-09 |
| 32 | 201747041654-IntimationOfGrant09-02-2021.pdf | 2021-02-09 |
| 33 | 201747041654-US(14)-HearingNotice-(HearingDate-14-12-2020).pdf | 2021-10-17 |
| 34 | 201747041654-RELEVANT DOCUMENTS [24-09-2022(online)].pdf | 2022-09-24 |
| 35 | 201747041654-RELEVANT DOCUMENTS [30-09-2023(online)].pdf | 2023-09-30 |
| 1 | SEARCHSTRATEGYE_04-03-2020.pdf |