Technical field [0001] 　The present invention is a polypropylene resin composition and relates to monolayer and multilayer films, more particularly, food packaging materials and building materials, a single layer suitably used for exterior materials such as lithium-ion batteries and multilayer films, as well as their It relates polypropylene resin composition contained in the film. BACKGROUND [0002] 　Polypropylene conventionally, rigidity, heat resistance, are widely used as thermoplastic molding materials with excellent and transparency. The polypropylene for a non-polar material, for example, poor adhesion to polar materials such as ethylene-vinyl alcohol copolymer, a polypropylene for the purpose of improving adhesion modified technique widely with an unsaturated carboxylic acid or its derivative Are known. Further, polypropylene is inferior in flexibility, when used as an adhesive is usually blended with soft rubber components to polypropylene. [0003] 　Thus polypropylene compounding soft rubber components, although the adhesive of the polypropylene which adhesion is improved can be obtained (e.g. Patent Documents 1 and 2), while the soft rubber components are deep drawing and bending it will cause whitening upon secondary processing such as was also required improvement in whitening resistance. Especially deep drawing or bending concrete applications as food packaging materials and building materials required include packaging material such as a lithium ion battery. [0004] 　Lithium ion batteries Among these is expanding the use of the like in recent years portable electronic devices and automobiles, further by responding to flexibility and miniaturization of the shape in the lithium ion battery, a pouch type in which the multilayer film and packaging material use of or emboss type of exterior body is expanding. Packaging material formed of the multilayer film, at least a base material layer, a metal foil layer and the heat-adhesive resin layer, and comprised of an adhesive layer for bonding the two layers adjacent of these layers. Since the multilayer film has a large degree of freedom in shape and easily processed in making the exterior body of a pouch type or embossed type, when deforming the multi-layer film, there are cases where deformation portion is whitened. Since there is a whitening places the outer body causing a short, are required material excellent in whitening resistance. [0005] 　Patent Document 3, a substrate layer, a metal foil layer having at least one surface to chemical conversion treatment layer, and an acid-modified polyolefin layer, and a heat seal layer made of a refractory polypropylene layer and an ethylene-propylene random copolymer layer, in packaging materials for at least sequentially stacked cell, wherein the refractory polypropylene layer is said from ethylene-propylene random copolymer layer disposed on the metal foil layer side is described battery packaging material having a melting point of 0.99 ° C. or higher . In the battery packaging material having a melting point that high-speed steel in the metal foil layer side of the high-melting polypropylene layer is 0.99 ° C. or higher ethylene-propylene random copolymer layer, the temperature rise inside the exterior body by overcharge or the like occurs even if the high-melting-point polypropylene layer is not dissolved, is prevented from contact with the metal terminal and the metal foil layer, it is possible to suppress the occurrence of internal short circuit. However, it is impossible to expect a sufficient whitening resistance against the battery packaging material. [0006] 　Patent Document 4 obtained by multistage polymerization, certain conditions propylene-based polymer component such as the ethylene content (A1) and propylene - propylene and an ethylene random copolymer component (A2) - ethylene block copolymerization battery packaging film polypropylene resin composition comprising a polymer (A) is described. Film formed from this composition, excellent heat resistance, sealability and formability, has a high sealing strength and impact resistance, and whitening resistance and cracking resistance during deformation, good balance across the board improvement It has been described as having the effect of being. However, with regard to the whitening resistance, not yet reached until the required level is reality. CITATION Patent Document [0007] Patent Document 1: JP-A-9-111069 Publication Patent Document 2: JP-A 4-300933 Patent Publication Patent Document 3: JP 2007-273398 Patent Publication Patent Document 4: JP 2015-230777 JP Summary of the Invention Problems that the Invention is to Solve [0008] 　In view of the above problems, food packaging, it can be used in exterior body or the like of the building materials and lithium-ion batteries, to provide an excellent packaging material whitening resistance at the time of deformation, in particular co extrusion and lamination coating, can be created by molding methods such as lamination, which aims to provide a hard packaging material cause whitening even during high-speed molding. . Means for Solving the Problems [0009] 　The present invention, to achieve the above object 　propylene polymer satisfying the following (a) and (A), 　the following soft propylene copolymer satisfying (b) (B), 　unsaturated carboxylic acids and / or derivatives thereof a polyolefin (C) containing a structural unit derived from 　containing a polypropylene resin composition. [0010] 　(A) a melting point observed in differential scanning calorimetry is 100 ° C. or higher. [0011] 　(B) according to ASTM D-1238 and 230 ° C., MFR measured at 2.16kg load is in the range of 0.01 ~ 100 g / 10 min, and the following requirements (b-1) and (b-2 ) of satisfying at least any one. [0012] 　(B-1) 13 C-NMR method syndiotactic triad fraction measured by (rr fraction) is 60% or more. [0013] 　(B-2) structural units derived from propylene contained 55-90 mol%, of the carbon atoms 2 - 20 alpha-olefin (excluding propylene) 10 to the structural units derived from at least one olefin selected from 45 mol% (the total of the proviso structural units derived from the structural units and 2 to 20 carbon atoms derived from propylene α- olefin (excluding propylene) is 100 mol%) containing, measured at 135 ° C. in decalin an intrinsic viscosity [η] (dL / g) and the MFR (g / 10 min, 230 ° C., 2.16 kg load) and relational 　expression: 1.50 × MFR -0.20 ≦ [eta] ≦ 2.65 × MFR -0.20 　meet. [0014] 　Wherein the polypropylene-based resin composition, 　the propylene polymer (A) and 50 to 80 parts by weight, 　the soft propylene copolymer (B) and 1 to 40 parts by weight, 　the polyolefin (C) 0.1 ~ 10 parts by weight (However, (a), (B) , ( total is 100 parts by weight of C)) preferably includes a. [0015] 　In the polypropylene-based resin composition, the polyolefin (C) is 0.01 to 5 mass% of structural units derived from an unsaturated carboxylic acid structural units in terms of maleic anhydride-derived, furthermore, the polyolefin (C), wherein it is preferred that the content ratio of structural units derived from propylene in the unsaturated carboxylic acid-derived structural units excluding the structural unit is 90 to 100 mol%. [0016] 　Monolayer or multilayer films of the present invention comprises at least one layer containing the polypropylene resin composition. [0017] 　One embodiment of the multilayer film of the present invention includes a layer containing the polypropylene resin composition of at least one layer, and a layer other than the layer containing the composition of at least two layers, the layer containing the composition can be mentioned a multilayer film both surfaces of which in contact with the other layer. [0018] 　One embodiment of the multilayer film of the present invention includes a layer containing the polypropylene resin composition of at least one layer, the metal-containing layer of at least one layer, and a layer of selected from the polyolefin layer and a polar resin layer, the composition layer containing things, the metal-containing layer can include a multilayer film which is in contact with at least one layer of polyolefin layer and a polar resin layer. [0019] 　Monolayer or multilayer films of the present invention can for food packaging, and for buildings materials and battery packaging film to. [0020] 　In the production process of the present originated monolayer or multilayer films, melt extruding the polypropylene-based resin composition. Effect of the invention [0021] 　Monolayer or multilayer films comprising a layer formed from the polypropylene resin composition of the present invention is excellent in whitening resistance during deformation, the food packaging and building materials and exterior and the like of a lithium ion battery it can be suitably used as a packaging material for forming. Also shows good whitening resistance in deforming and deep drawing at a high speed. DESCRIPTION OF THE INVENTION [0022] 　Polypropylene resin composition of the present invention, propylene-based polymer (A) and the soft propylene copolymer (B) an unsaturated carboxylic acid and / or a polyolefin containing a structural unit derived from a derivative thereof (C) containing. Propylene polymer (A) 　The propylene polymer (A), a propylene homopolymer or propylene with at least one of the number of carbon atoms other than propylene include copolymers of a 2 ~ 20 alpha-olefin be able to. Here, as the α- olefin carbon atoms other than propylene is 2 to 20, ethylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene, 1-hexadecene, 1-octadecene, 1-eicosene and the like, alpha-olefin ethylene or carbon atoms 4-10 are preferred. [0023] 　Propylene and copolymers of these α- olefins may be a random copolymer, or a block copolymer. Structural units derived from these alpha-olefins, alpha-olefins 35 mol% in the copolymer of propylene or less, preferably in a proportion of 30 mol% or less. [0024] 　Propylene polymer (A) satisfies the following requirements (a). (A) a melting point observed in differential scanning calorimetry is 100 ° C. or higher. [0025] 　The melting point is preferably 100 ~ 170 ° C., more preferably 110 ~ 165 ° C.. [0026] 　The propylene polymer (A) is, 230 ° C. in conformity with ASTM D 1238, melt flow rate (MFR) of 0.01 ~ 1000 g / 10 min as measured under a load of 2.16 kg, preferably 0.05 ~ 100 g / it is preferably in the range of 10 minutes. [0027] 　The propylene polymer (A) is an isotactic structure, it may be either a syndiotactic structure, either a structure in consideration of compatibility with the soft propylene copolymer (B) as described below it can be selected. [0028] 　That is, isotactic propylene polymer (A1) and syndiotactic propylene polymer (A2) can be mentioned as forms of the propylene polymer (A). [0029] 　The isotactic propylene-based polymer (A1), the block having an excellent balance of homopolypropylene excellent in heat resistance, for example, a known homopolypropylene copolymerization component other than the normal propylene is not more than 3 mol%, the heat resistance and flexibility polypropylene, for example, a known block polypropylene having a normal decane elution rubber component usually 3 to 30% by weight, and a random polypropylene excellent in balance between flexibility and transparency, melting peak for example as measured by conventional differential scanning calorimeter DSC 100 ° C. or higher, preferably include known random polypropylenes in the range of 110 ° C. ~ 0.99 ° C., can be appropriately selected to obtain objective physical properties from these, or melting point and rigidity different two併 more of the polypropylene component It is possible to. [0030] 　Such isotactic propylene polymer (A1) is, for example, magnesium, titanium, a solid catalyst component containing as essential components a halogen and an electron donor and an organoaluminum compound and an electron donor Ziegler catalyst system or a metallocene, compounds can be prepared by copolymerizing a polymerizable or propylene and other α- olefins propylene with metallocene catalyst system using as a component of the catalyst. [0031] 　Syndiotactic propylene polymer (A2) comprises structural units 90 mol% or more derived from propylene and structural units derived from one or more selected from α- olefins ethylene and 4 to 20 carbon atoms or less 10 mol% the sum of preferably the structural units 91 mol% or more derived from propylene, comprising structural units derived from one or more selected from α- olefins ethylene and 4 to 20 carbon atoms or less 9 mol% (provided that both structural units of is referred to as 100mol%). [0032] 　The α- olefin having 4 to 20 carbon atoms, ethylene, 1-butene, 3-methyl-1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-decene , 1-dodecene, 1-tetradecene, 1-hexadecene, 1-octadecene, and 1-eicosene. [0033] 　Syndiotactic propylene polymer (A2) is below requirements [1] and preferably satisfies both the [2]. [0034] 　[1]　 13 syndiotactic pentad fraction measured by C-NMR (rrrr fraction, pentad syndiotacticity chromatography) is 85% or more. [0035] 　[2] the melting point as determined by differential scanning calorimetry (hereinafter referred to as DSC) (Tm) is the 100 ° C.. [0036] 　Hereinafter, the requirements [1] and [2] will be described in detail. [0037] 　Requirement [1] 　of the syndiotactic propylene polymer (A2) 13 rrrr fraction measured by C-NMR method is 85% or more, preferably 90% or more, more preferably 93% or more, more preferably it is 94% or more. polymer rrrr fraction in this range (A2), the moldability, heat resistance, excellent transparency and rigidity, is preferably a good characteristics as crystalline polypropylene. Using a catalyst system as described later, by setting the polymerization conditions as described later, rrrr fraction may be produced a polymer (A2) in this range. Although no particular upper limit of the rrrr fraction is not more than 100%, usually less than for example 99%. [0038] 　rrrr fraction is measured as follows. [0039] 　rrrr fraction, 13 total methyl groups C-NMR Prrrr in the spectrum (the absorption intensity derived from methyl groups of the third unit in the site in propylene units continuously 5 units and syndiotactic bond) and Pw (propylene unit obtained by the following equation (1) from the absorption intensity of absorption intensity) derived from. [0040] 　rrrr fraction Prrrr = / Pw · · · 　(1) NMR measurement is carried out, for example, in the following manner. It is heated dissolve the sample 0.35g hexachlorobutadiene 2.0 mL. After the solution was filtered with a glass filter (G2), added deuterated benzene 0.5 mL, charged to an NMR tube having an inner diameter of 10 mm. Then using a JEOL GX-500 NMR measuring apparatus, at 120 ° C. 13 performs C-NMR measurement. Integration number is 10,000 times or more. [0041] 　Requirement [2] 　syndiotactic propylene polymer (A2) melting point obtained by differential scanning calorimetry (DSC) of (Tm) is preferably higher, specifically 156 ° C. or higher, 155 ° C. or higher, 0.99 ° C. or higher, 147 ° C. or higher, 145 ° C. or higher, 115 ° C. or higher, preferably in the order of more than 100 ° C.. The melting point maximum (Tm) is not specifically, usually 170 ° C.. [0042] 　Additionally and a melting point (Tm) of simultaneously measured heat of fusion (△ H) of the syndiotactic propylene polymer (A2) is preferably larger, particularly 55 mJ / mg or more, 52 mJ / mg or more, 40 mJ / mg or more, 20mJ / mg or more, preferably in the order of more than 10mJ / mg. Note upper limit of the amount of heat of fusion (△ H) is not particularly, usually, for example, 120 mJ / mg. [0043] 　Differential scanning calorimetry for example performed as follows. Packed about specimen 5mg dedicated aluminum pan, then holding with Corporation Perkin Elmer DSCPyris1 or DSC7, heated up to 200 ° C. from 30 ° C. at 320 ° C. / min, at 200 ° C. 5 min, 200 ° C. up to 30 ° C. and cooled at 10 ° C. / min from and held for a further 5 minutes at 30 ° C., then determine the melting endothermic curve at the time of raising the temperature at 10 ° C. / min. During DSC measurement, if multiple peaks are detected, to define the peak temperature detected by the highest temperature side as the melting point (Tm). Polymer melting point (Tm) is within this range (A2), the moldability, excellent heat resistance and mechanical properties, preferably a good characteristics as crystalline polypropylene. Using a catalyst system as described later, by setting the polymerization conditions as described later and a melting point (Tm) of can be produced a polymer (A2) in this range. [0044] 　The syndiotactic propylene polymer (A2), in addition to the requirements [1] and [2] preferably further satisfies the following requirement [3]. [0045] 　[3] normal decane soluble part amount is at most 1 mass%. Will be specifically described below requirement [3]. [0046] 　Requirement [3] 　The syndiotactic propylene polymer normal decane-soluble part of (A2) is 1 wt% or less, preferably 0.8 wt% or less, more preferably less 0.6 wt%. Normal decane-soluble fraction content is an index close contact with the blocking characteristics of the molded article obtained from syndiotactic propylene polymer or polymer, is that usually normal decane soluble part amount is small low crystalline component amount which means that less. That requirement [3] also satisfy the syndiotactic propylene polymer (A2) is provided with very good blocking resistance. [0047] 　n- decane soluble content and its monomer composition can be determined as follows. [0048] 　After dissolved by heating the sample to n- decane, allowed to cool to cool to room temperature. Component dissolved in n- decane at this state is the n- decane-soluble component. To analyze the monomer composition of n- decane soluble portion, After precipitation of the mixed polymer components acetone to this solution, method of measuring the IR of the obtained polymer is used. [0049] 　The syndiotactic propylene polymer (A2) is below requirements [4] to [7] also preferably satisfy. [0050] 　[4] tensile modulus is in the range of 0.99 ~ 2000 MPa. [0051] 　[5] tensile strength is greater than or equal to 15MPa. [0052] 　[6] Internal haze value of a press sheet having a thickness of 1mm is 50% or less. [0053] 　[7] the needle penetration temperature is 100 ° C. or higher. Below, it will be described in detail requirements [4] to [7]. [0054] 　Requirement [4] 　The syndiotactic propylene polymer tensile modulus of (A2) is 150 MPa ~ 2000 MPa, preferably 300 MPa ~ 1800 MPa, more preferably 500 MPa ~ 1500 MPa. [0055] 　Specifically, the tensile elastic modulus is a value measured by the following procedure. The 1mm thick pressed sheet in compliance with JIS K6301, providing punching, in the evaluation sample by the order down bell for JIS3 dumbbell. Measurements using, for example, Instron Corporation Co. tensile tester Inston1123, perform span 30 mm, 3 times at 23 ° C. at a tensile speed of 30 mm / min, to adopt the mean value of three measurements as tensile modulus. [0056] 　Syndiotactic propylene polymer tensile modulus is within this range (A2) is excellent in mechanical properties and strength, is preferably excellent properties as a crystalline polypropylene. Using a catalyst system as described later, by setting the polymerization conditions as described later, the tensile modulus may be produced a polymer (A2) in this range. [0057] 　Requirement [5] 　Tensile strength at break of the syndiotactic propylene polymer (A2) is not less than 15 MPa, preferably at least 18 MPa, more preferably 20MPa or more, more preferably 30MPa or more. [0058] 　Specifically, the tensile break strength is a value measured by the following procedure. The 1mm thick pressed sheet in compliance with JIS K6301, providing punching, in the evaluation sample by the order down bell for JIS3 dumbbell. Measurements using, for example, Instron Corporation Co. tensile tester Inston1123, three times at 23 ° C. with a span 30 mm, a tensile rate of 30 mm / min, is employed as the tensile breaking strength average values ​​of three measurements. [0059] 　Syndiotactic propylene polymer tensile strength at break is within this range (A2), it is good preferred characteristics as crystalline polypropylene. Using a catalyst system as described later, by setting the polymerization conditions as described later, the tensile strength at break can be produced polymer (A2) in this range. [0060] 　Requirement [6] 　Internal haze of the press sheet having a thickness of 1mm of the syndiotactic propylene polymer (A2) is less than 50%, preferably 45% or less. [0061] 　The value of the internal haze, using a press sheet specimen having a thickness of 1 mm, as measured by Nippon Denshoku Industries Co., Ltd. digital turbidimeter at "NDH-20D" twice, two measurements which is the average value. [0062] 　Syndiotactic propylene polymer internal haze is within this range (A2) is excellent in transparency, preferably good characteristics as crystalline polypropylene. Using a catalyst system as described later, by setting the polymerization conditions as described later, the internal haze may be produced a polymer (A2) in this range. [0063] 　Requirement [7] 　the needle penetration temperature of the syndiotactic propylene polymer (A2) is at 100 ° C. or higher, preferably in the range of more than 115 ° C.. (Sometimes referred softening point determined by TMA measurement) needle penetration temperature can be measured as follows. [0064] 　Seiko Co., Ltd. SS-120 or, by using a TA Instrument Inc. Q-400, a pressed sheet test piece having a thickness of 1 mm, 2 kgf at heating rate 5 ° C. / min with 1.8mmφ plane indenter / cm 2 under a pressure of, from TMA curve to determine the needle penetration temperature (° C.). [0065] 　Needle penetration temperature syndiotactic propylene polymer in this range (A2) is excellent in heat resistance, preferably good characteristics as crystalline polypropylene. Using a catalyst system as described later, by setting the polymerization conditions as described later, the polymer needle penetration temperature is in the range (A2) can be produced. [0066] 　Syndiotactic propylene polymer (A2) is a differential scanning calorimeter (DSC) isothermal crystallization temperature determined by measuring Tiso, the half-crystallization time at the isothermal crystallization temperature Tiso t 1/2 If a, 110 ≦ the following formula (Eq-1) satisfies the range of Tiso ≦ 150 (℃), [0067] [Number 1] 　preferably satisfies the following formula (Eq-2), [0068] [Number 2] 　and more preferably satisfies the following formula (Eq-3). [0069] [Equation 3] 　isothermal crystallization half-crystallization time which is determined by measurement (t 1/2 ) if the area between the DSC heat quantity curve and the base line of the isothermal crystallization process was total heat, the 50% heat the time has been reached. [New Polymer Experimental Course 8 polymer physical properties (Kyoritsu Shuppan Co., Ltd.) reference] 　the crystallization half time (T 1/2 ) measurements are carried out in the following manner. Packed about specimen 5mg dedicated aluminum pan, using Ltd. Perkin Elmer DSCPyris1 or DSC7, it was raised at 320 ° C. / min up to 200 ° C. from 30 ° C., then held at 200 ° C. 5 min, the temperature ( from 200 ° C.) to each isothermal crystallization temperature was lowered at 320 ° C. / min, half-crystallization time (t a DSC curve obtained by holding its isothermal crystallization temperature 1/2 Request). Here the semi-crystallization time (t 1/2 ) is obtained as t = 0 (time to reach the isothermal crystallization temperature from 200 ° C.) to isothermal crystallization process start time. For syndiotactic propylene polymer used in the present invention (A2) is t as the half case can be obtained, there isothermal crystallization temperature, which do not crystallize, for example 110 ° C., the convenience the measurement at 110 ° C. or less isothermal crystallization temperature was performed at several points, half-crystallization time (t from the extrapolated value 1/2 Request). [0070] 　The syndiotactic propylene polymer satisfying (Eq-1) (A2), the moldability as compared with conventional ones superior remarkably. Here, the moldability is excellent shows injection, inflation, blow, when forming is carried out in the extrusion or pressing, etc., is shorter the time until solidification from the molten state. Also, such syndiotactic propylene polymer (A2) is the molding cycle properties, shape stability, and long-term productivity is excellent. [0071] 　The catalyst used in the production of syndiotactic propylene polymer (A2), 　cross-linked metallocene compound represented by the following general formula [1] and (K), 　the organoaluminum oxy-compound (L1), 　the bridged metallocene compound ( compound K) react with to form an ion pair (L2), and 　the organoaluminum compound (L3) 　at least one compound selected from (L) from the composed polymerization catalyst (cat-1), or the catalyst (cat-1) is polymerization catalyst supported on a particulate carrier (P) (cat-2) but is preferably used, as long as the polymer produced satisfies the requirements of the propylene polymer component (a) not limited to any catalyst. [0072] [Formula 1] 　In the general formula [1], R 1 , R 2 , R 3 and R 4 are selected from hydrogen atoms and hydrocarbon group and a silicon-containing group, R 2 and R 3 are bonded to each other with the ring may form a, R 5 , R 6 , R 8 , R 9 , R 11 and R 12 are selected from hydrogen, a hydrocarbon group and a silicon-containing group, R 7 and R 10 2 one group of hydrogen rather than atoms, each selected from a hydrocarbon group and a silicon-containing group may be the same or different, R 5 and R 6 , R 7 and R 8 , R 8 and R 9 , R 9 and R 10 , and R 11 and R 12 the adjacent group in one or more contiguous groups combination selected from may form a ring with each other. [0073] 　R 17 and R 18 is a hydrogen atom, a hydrocarbon group or a silicon atom-containing group having 1 to 20 carbon atoms, may be the same or different from each other, a substituent bonded to each other to form a ring good. [0074] 　M is Ti, Zr or Hf, Y is carbon, Q is halogen, hydrocarbon group, an anionic ligand, and a neutral ligand capable of coordination by lone pair same or in different combinations selected, j is an integer of 1-4. [0075] 　Specific examples of the compound (K) satisfying this definition, cyclopropylidene (cyclopentadienyl) (3,6-di-tert- fluorenyl) zirconium dichloride, cyclobutylidene (cyclopentadienyl) (3,6 di tert- fluorenyl) zirconium dichloride, cyclopentylidene (cyclopentadienyl) (3,6-di-tert- fluorenyl) zirconium dichloride, cyclohexylidene (cyclopentadienyl) (3,6-di-tert- fluorenyl) zirconium dichloride, cycloheptylidene (cyclopentadienyl) (3,6-di-tert- fluorenyl) zirconium dichloride, dibenzyl methylene (cyclopentadienyl) (3,6-di-tert- butyl fluorenyl) zirconium dichloride, dibenzyl methylene (cyclopentadienyl) (octamethyloctahydrodibenzofluorenyl) zirconium Umujikurorido, di n- butylmethylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di-n- butyl methylene (cyclopentadienyl (2,7 - di (2,4,6-trimethylphenyl) -3,6-di-tert- butylfluorenyl) zirconium dichloride, di-n- butyl methylene (cyclopentadienyl) (2,7-diphenyl-3,6 di tert- butyl fluorenyl) zirconium dichloride, di-n- butyl methylene (cyclopentadienyl) (2,7-di (3,5-dimethylphenyl) -3,6-di-tert- butylfluorenyl) zirconium dichloride, di-n- butyl methylene (cyclopentadienyl) (2,3,6,7-tetra-tert- butyl fluorenyl) zirconium dichloride, di-n- butyl methylene (cyclopentadienyl) (2,7-di (4-methylphenyl) -3,6-di-tert- butylfluorenyl) zirconium Mujikurorido, di n- butylmethylene (cyclopentadienyl) (2,7-dinaphthyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di-n- butyl methylene (cyclopentadienyl) (2,7 - di (4-tert- butylphenyl) -3,6-tert- butyl fluorenyl) zirconium dichloride, diisobutylmethylene (cyclopentadienyl) (2,7-dimethyl-3,6-di tert- Buchirufuru Oreniru) zirconium dichloride, diisobutylmethylene (cyclopentadienyl (2,7-di (2,4,6-trimethylphenyl) -3,6-di-tert- butylfluorenyl) zirconium dichloride, diisobutylmethylene (cyclopenta dienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, diisobutylmethylene (cyclopentadienyl) (2,7-di (3,5-dimethylphenyl) -3, 6-di-tert- Buchirufuruore ) Zirconium dichloride, diisobutylmethylene (cyclopentadienyl) (2,3,6,7-tetra-tert- butyl fluorenyl) zirconium dichloride, diisobutylmethylene (cyclopentadienyl) (2,7-di (4- methylphenyl) -3,6-di-tert- butylfluorenyl) zirconium dichloride, diisobutylmethylene (cyclopentadienyl) (2,7-dinaphthyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, diisobutyl methylene (cyclopentadienyl) (2,7-di (4-tert- butylphenyl) -3,6-tert- butyl fluorenyl) zirconium dichloride, dibenzyl methylene (cyclopentadienyl) (2,7 - dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride [other 1,3-diphenyl isopropylidene (cyclopentadienyl) (2,7-dimethyl-3,6-di tert- Buchirufuru Oreniru ) Is also referred to as zirconium dichloride. Alias omitted] for less, dibenzyl methylene (cyclopentadienyl (2,7-di (2,4,6-trimethylphenyl) -3,6-di-tert- butylfluorenyl) zirconium dichloride, dibenzyl methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, dibenzyl methylene (cyclopentadienyl) (2,7-di (3,5-dimethylphenyl ) -3,6-di-tert- butylfluorenyl) zirconium dichloride, dibenzyl methylene (cyclopentadienyl) (2,3,6,7-tetra-tert- butyl fluorenyl) zirconium dichloride, dibenzyl methylene ( cyclopentadienyl) (2,7-di (4-methylphenyl) -3,6-di-tert- butylfluorenyl) zirconium dichloride, dibenzyl methylene (cyclopentadienyl) (2,7-dinaphthyl -3 , 6-di-tert- butylfluorenyl) di Benzalkonium dichloride, dibenzyl methylene (cyclopentadienyl) (2,7-di (4-tert- butylphenyl) -3,6-tert- butyl fluorenyl) zirconium dichloride, di phenethyl methylene (Shikuropentaji enyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di phenethyl methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di tert- Buchirufuruore ) zirconium dichloride, di (benzhydryl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (benzhydryl) methylene (cyclopentadienyl) ( 2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (cumyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl ) zirconium Dichloride, di (cumyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (1-phenyl - ethyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (1-phenyl - ethyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di tert - butyl fluorenyl) zirconium dichloride, di (cyclohexylmethyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (cyclohexylmethyl) methylene ( cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (cyclopentylmethyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6 di-tert- butyl Rufuruoreniru) zirconium dichloride, di (cyclopentylmethyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (naphthylmethyl) methylene (cyclopentadienyl ) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (naphthylmethyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di tert- butyl fluorenyl) zirconium dichloride, di (biphenylmethyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (biphenylmethyl) methylene (cyclopenta dienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, (benzyl) (n-butyl) methylene (cyclopentadienyl Eni Le) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, (benzyl) (n-butyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6 di tert- butyl fluorenyl) zirconium dichloride, (benzyl) (cumyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, (benzyl) ( cumyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, cyclopropylidene (cyclopentadienyl) (2,7-dimethyl-3,6 - di-tert- butyl fluorenyl) zirconium dichloride, cyclopropylidene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, cyclobutylidene (Shikuropentaji enyl) (2,7-dimethylol Le-3,6-di tert- butyl fluorenyl) zirconium dichloride, cyclobutylidene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, cyclopentyl isopropylidene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, cyclopentylidene (cyclopentadienyl) (2,7-diphenyl-3,6-di tert- butyl fluorenyl) zirconium dichloride, cyclohexylidene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, cyclohexylidene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, cycloheptylidene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl ) zirconium dichloride , Cycloheptylidene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, dibenzyl methylene (cyclopentadienyl) (2,7-dimethyl-3 , 6-dimethyl - butyl fluorenyl) zirconium dichloride, di-n- butyl methylene (cyclopentadienyl) (2,7-dimethyl-3,6-dimethyl - butyl fluorenyl) zirconium dichloride, dibenzyl methylene (cyclo pentadienyl) (2,7-dimethyl-3,6-dicumyl - butyl fluorenyl) zirconium dichloride, di-n- butyl methylene (cyclopentadienyl) (2,7-dimethyl-3,6-dicumyl - butyl fluorenyl) zirconium dichloride, dibenzyl methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di (trimethylsilyl) - butyl fluorenyl) zirconium dichloride, di n- Buchirumechire (Cyclopentadienyl) (2,7-dimethyl-3,6-di (trimethylsilyl) - butyl fluorenyl) zirconium dichloride, dibenzyl methylene (cyclopentadienyl) (2,7-dimethyl-3,6 diphenyl - butylfluorenyl) zirconium dichloride, di-n- butyl methylene (cyclopentadienyl) (2,7-dimethyl-3,6-diphenyl - butyl fluorenyl) zirconium dichloride, dibenzyl methylene (cyclopentadienyl ) (2,7-dimethyl-3,6-dibenzyl - butyl fluorenyl) zirconium dichloride, di-n- butyl methylene (cyclopentadienyl) (2,7-dimethyl-3,6-dibenzyl - butyl fluorenyl ) zirconium dichloride, dibenzyl methylene (cyclopentadienyl) (2,7-dimethyl-3,6-dimethyl - butyl fluorenyl) zirconium dichloride, di-n- butyl methylene (cyclopentyl Tajieniru) (2,7-dimethyl-3,6-dimethyl - butyl fluorenyl) zirconium dichloride, diphenylmethylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, diphenylmethylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p- tolyl) methylene (cyclopentadienyl) (2,7 - dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p- tolyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p- chlorophenyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p- chlorophenyl) methylene (cyclopentadienyl ) (2,7-diphenyl-3,6 tert- butyl fluorenyl) zirconium dichloride, di (m-chlorophenyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (m-chlorophenyl ) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p- bromophenyl) methylene (cyclopentadienyl) (2,7-dimethyl 3,6-di tert- butyl fluorenyl) zirconium dichloride, di (p- bromophenyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (m-trifluoromethyl - phenyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (m-trifluoromethyl - phenyl ) methylene (cyclopentyl Tajieniru) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p- trifluoromethyl - phenyl) methylene (cyclopentadienyl) (2,7-dimethyl-3, 6- di tert- butyl fluorenyl) zirconium dichloride, di (p- trifluoromethyl - phenyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p-tert- butyl - phenyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butyl fluorenyl) zirconium dichloride, di (p-tert- butyl - phenyl ) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p-n-butyl - phenyl) methylene (cyclopentadienyl) (2, 3,7-dimethyl-3,6-di-tert- butyl fluorenyl) zirconium dichloride , Di (pn-butyl - phenyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p- biphenyl) methylene (cyclopentadienyl ) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p- biphenyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di tert- butylfluorenyl) zirconium dichloride, di (1-naphthyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (1-naphthyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (2-naphthyl) methylene (cyclopentadienyl) (2,7-dimethyl-3, 6- di tert- butyl fluorenyl) zirconium dichloride, di (2-naphthyl) methylene Down (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (naphthylmethyl) methylene (cyclopentadienyl) (2,7-dimethyl-3, 6- di tert- butyl fluorenyl) zirconium dichloride, di (naphthylmethyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p - isopropylphenyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (p- isopropylphenyl) methylene (cyclopentadienyl) (2, 7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (biphenylmethyl) methylene (cyclopentadienyl) (2,7-dimethyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, di (biphenylene Methyl) methylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, diphenylsilylene (cyclopentadienyl) (2,7-dimethyl-3,6 di tert- butyl fluorenyl) zirconium dichloride, diphenylsilylene (cyclopentadienyl) (2,7-diphenyl-3,6-di-tert- butylfluorenyl) zirconium dichloride, and the like. [0076] 　Among the above exemplified compounds, R in the formula [1] 6 , R 11 is an aryl group or a substituted aryl group such as phenyl group, tolyl group, t- butyl phenyl, dimethylphenyl group, trimethylphenyl group, a biphenyl group what is preferred because it provides a syndiotactic propylene polymer exhibiting a high melting point (A2). [0077] 　Further and compounds obtained by changing the "zirconium" in the above-exemplified compounds "hafnium" or "titanium", "dichloride" is "difluoride", "dibromide", and bridged metallocene compounds is "diiodide", "dichloride" is bridged metallocene compound becomes "dimethyl" or "methylethyl" also may be exemplified similarly. [0078] 　Bridged metallocene compound described above (K) is be produced by a known method, not particularly manufacturing method is limited. For example a known production method may include a manufacturing method described in Patent WO2001 / 27124 Patent and WO2004 / 087 775 by the present applicant. Moreover, the metallocene compounds can be used alone or in combination of two or more. [0079] 　Hereinafter, an organoaluminum oxy-compound (L1), a compound capable of reacting with the bridged metallocene compound (K) to form an ion pair (L2), will be specifically described organic aluminum compound (L3) and particulate carrier (P). [0080] 　The organoaluminum oxy compound (L1) 　The organoaluminum oxy-compound (L1), conventionally known aluminoxane can be used as it is. Specifically, the following general formula [2] [0081] [Formula 2] (In the above formula [2], R each independently represent a hydrocarbon group having 1 to 10 carbon atoms, n represents an integer of 2 or more.) 　And / or the general formula [3] [0082] [Formula 3] (In the above formula [3], R is a hydrocarbon radical, n is an integer of 2 or more. 1 to 10 carbon atoms) can be exemplified compounds represented by, in particular, R is a methyl group in it, n is 3 or more, preferably utilized more than 10 methylaluminoxane. No problem even with some organoaluminum compounds in these aluminoxanes is not contaminated. [0083] 　Furthermore, modified methyl aluminoxane as follows [4] can be cited as the organoaluminum oxy compound (L1). [0084] [Formula 4] (In the general formula [4], R represents a hydrocarbon group having 1 to 10 carbon atoms, each independently m, n is an integer of 2 or more.). [0085] 　This modified methyl aluminoxane is prepared by using an alkyl aluminum other than trimethyl aluminum and trimethyl aluminum. Such compounds [4] are generally referred to as MMAO. Such MMAO for example, may be prepared by the method listed in US4960878 and the like, can be used as it is commercially available. [0086] 　Bridged metallocene compound compound react to form an ion pair and (K) (L2) 　bridged metallocene compound compound react to form an ion pair and (K) (L2) (hereinafter, sometimes abbreviated as "ionic compound" there. the) include Lewis acids such as those described in JP-a No. and No. US5321106 1-501950, ionic compounds, borane compounds and carborane compounds and the like. Further, mention may be made also heteropoly compounds and isopoly compounds. [0087] 　The organic aluminum compound (L3) 　Examples of the organoaluminum compound to form the olefin polymerization catalyst (L3), and the like for example an organoaluminum compound represented by the following general formula [5]. [0088] 　R a m Al (OR b ) n H p X q · · · · [5] (In the formula, R a and R b may be the same or different from each other, hydrocarbon group of 1 to 15 carbon atoms, preferably represents 1 to 4 hydrocarbon group, X represents a halogen atom, m is 0