Positive Electrode Active Material For Lithium Secondary Battery Preparation Method For Same And Lithium Secondary Battery Comprising Same
Abstract:
The present invention relates to a positive electrode active material for a lithium secondary battery and to a lithium secondary battery comprising same the positive electrode active material comprising lithium cobalt oxide particles wherein the lithium cobalt oxide particles comprise therein lithium cobalt oxide having Li/Co of which the mole ratio is less than 1 thereby showing excellent rate properties and life without the fear of decreased initial capacity.
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Notices, Deadlines & Correspondence
LG Chem Research Park 188 Munji ro
Yuseong gu
Daejeon 34122
2. JO Chi Ho
LG Chem Research Park 188 Munji ro
Yuseong gu
Daejeon 34122
3. RYU Ji Hoon
LG Chem Research Park 188 Munji ro
Yuseong gu
Daejeon 34122
4. SHIN Sun Sik
LG Chem Research Park 188 Munji ro
Yuseong gu
Daejeon 34122
5. JUNG Wang Mo
LG Chem Research Park 188 Munji ro
Yuseong gu
Daejeon 34122
Specification
【TECHNICAL FIELD】
[CROSS-REFERENCE TO RELATED APPLICATIONS]
[0001] This application claims the benefits of priority from
Korean Patent Application No. 2014-0133474, filed on October
2, 2014, and No.2015-0138717, filed on October 1, 2015, the
entire contents described in the disclosure of corresponding
Korean patent applications are hereby incorporated as a part
of the present specification.
[TECHNICAL FIELD]
[0002] The present invention relates to a positive electrode
active material for a lithium secondary battery, a method of
preparing the same, and a lithium secondary battery including
the same.
【BACKGROUND ART】
[0003] As technical developments and demands on mobile
devices are increasing, demands on secondary batteries as an
energy source is being rapidly increasing. Among the
secondary batteries, lithium secondary batteries having high
energy density and voltage, long cycle life, and low selfdischarge
rate are commercialized and widely used.
[0004] However, the lithium secondary battery has a
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limitation that the life thereof decreases rapidly via
repeating charge and discharge. Particularly, the limitation
is more serious at high temperatures. The reason is that an
electrolyte may be decomposed due to moisture in the battery
or other factors, an active material may be deteriorated, or
the internal resistance of the battery may increase.
[0005] A positive electrode active material for a lithium
secondary battery, which is being actively researched,
developed and used, is LiCoO2 with a layered structure.
LiCoO2 may be easily synthesized and has good electrochemical
properties including life property, and is the most widely
used material. However, LiCoO2 has low structural stability,
and the application thereof to a battery with high capacity
is limited.
[0006] As the substituents of the positive electrode active
material, various lithium transition metal oxides such as
LiNiO2, LiMnO2, LiMn2O4, LiFePO4, and Li(NixCoyMnz)O2, have been
developed. LiNiO2 has merits of providing the battery
properties of high discharge capacity, however is hardly
synthesized by a simple solid phase reaction and has low
thermal stability and cycle property. In addition, lithium
manganese oxides such as LiMnO2 or LiMn2O4 have merits of good
thermal stability and low cost, however have limitations of a
small capacity and inferior properties at high temperatures.
Particularly, for LiMn2O4, some products are commercialized
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at low cost, however the life property thereof is not good
due to Jahn-Teller distortion owing to Mn3+. Since LiFePO4 is
inexpensive and safe, a lot of research is being conducted
for the use in a hybrid electric vehicle (HEV), however the
application thereof to another fields is hard due to low
conductivity.
[0007] Due to such circumstances, a lithium nickel manganese
cobalt oxide, Li(NixCoyMnz)O2 (where x, y, and z are atomic
partial ratios of each independent oxide composite elements
and satisfy 0