Abstract: A PROCESS FOR PREPARATION OF Z-7-DECENYL ACETATE A process for preparation of Z-7-decenyl acetate, a sex pheromone component of groundnut leaf miner (Aproaerema modicella), is disclosed. The process includes (a) preparation of 7-hydroxyheptanal: from oxidative cleavage of aleuritic acid with sodium periodate in presence of base(s); (b) preparation of phosphonium salt: from primary halides of propane with triphenylphosphine in suitable organic solvent(s); (c) preparation of Z-7-decenol: by combining the phosphonium salt with 7-hydroxyheptanal in suitable base(s) and organic solvent(s); and (d) formation of Z-7-decenyl acetate: from acylation of Z-7-decenol with acylating agent(s) in presence of suitable organic base(s) and solvent(s). The present invention is capable of economic large scale synthetic production of Z-7-decenyl acetate while using inexpensive raw materials. Figure 1
SOFT COPY ATTACHED IN PDF
| # | Name | Date |
|---|---|---|
| 1 | Form-2(Online).pdf | 2016-09-29 |
| 1 | FORM28 [11-09-2015(online)].pdf_7.pdf | 2015-09-11 |
| 2 | abstract 4849-CHE-2015 .jpg | 2016-09-21 |
| 2 | FORM28 [11-09-2015(online)].pdf | 2015-09-11 |
| 3 | Description(Complete) [17-08-2016(online)].pdf | 2016-08-17 |
| 3 | EVIDENCE FOR SSI [11-09-2015(online)].pdf_6.pdf | 2015-09-11 |
| 4 | Drawing [17-08-2016(online)].pdf | 2016-08-17 |
| 4 | EVIDENCE FOR SSI [11-09-2015(online)].pdf | 2015-09-11 |
| 5 | OTHERS [17-08-2016(online)].pdf | 2016-08-17 |
| 5 | Description(Provisional) [11-09-2015(online)].pdf | 2015-09-11 |
| 6 | Description(Provisional) [11-09-2015(online)].pdf | 2015-09-11 |
| 6 | OTHERS [17-08-2016(online)].pdf | 2016-08-17 |
| 7 | Drawing [17-08-2016(online)].pdf | 2016-08-17 |
| 7 | EVIDENCE FOR SSI [11-09-2015(online)].pdf | 2015-09-11 |
| 8 | Description(Complete) [17-08-2016(online)].pdf | 2016-08-17 |
| 8 | EVIDENCE FOR SSI [11-09-2015(online)].pdf_6.pdf | 2015-09-11 |
| 9 | abstract 4849-CHE-2015 .jpg | 2016-09-21 |
| 9 | FORM28 [11-09-2015(online)].pdf | 2015-09-11 |
| 10 | FORM28 [11-09-2015(online)].pdf_7.pdf | 2015-09-11 |
| 10 | Form-2(Online).pdf | 2016-09-29 |