FORM - 2
THE PATENTS ACT, 1970
(39 of 1970)
&
The Patents Rules, 2003
COMPLETE SPECIFICATION
(See Section 10 and Rule 13)
PROCESS FOR PREPARING A TEA PRODUCT
HINDUSTAN UNILEVER LIMITED, a company incorporated under
the Indian Companies Act, 1913 and having its registered office
at 165/166, Backbay Reclamation, Mumbai -400 020, Maharashtra, India
The following specification particularly describes the invention and the manner in which it is to be performed.

Technical Field
The present invention relates to a tea product and process of preparation thereof. It particularly relates to a black tea product.
Background and prior art
Off-colour (light coloured) teas are available at low cost as their appearance is not acceptable to consumers, in particular to consumers who are habituated to brewing tea directly without using tea bags. One of the problems addressed by the present invention is to darken the colour of tea product, particularly a black leaf tea.
Indian patent IN187547 (Hindustan Lever Limited, published in 2002) discloses a method of preparing a granulated tea based product comprising granulating a mixture of 15 - 70% by weight dust tea with a particle size ranging from 0.1 to 1.0 mm, 30-85% by weight of sugar based additives and optional ingredients such as chicory and at least one flavour agent. Jaggery or gur is disclosed as a preferred sugar-based additive.
Indian patent application 1750/MUM/2007 (Hindustan Unilever Limited, published in 2009) discloses a composition comprising 30 to 95 wt% black tea, 0.5 to 30 wt% chicory, 0.5 to 40 wt% binder, and 0.01 to 5 wt% of a micronutrient selected from a vitamin, calcium, zinc, iron or a combination thereof. The binder is preferably sugar, maltodextrin, gum acacia, jaggery or mixture thereof.
EP 1092349 (Unilever, published in 2001) discloses a tea product with enhanced aroma and flavour comprising 15-95% by weight by weight black tea, up to 5% by weight of a mixture comprising fructose and glucose, up to 5% by weight of roasted nut powder and optionally roasted chicory and flavouring agents, dairy or non-diary whiteners, starch, preservatives at an optimal level.
US4880649 (Firmenich, 1987) describes a process for flavouring a composition chosen from among products for infusion or decoction selected from the group

consisting of tea, camomile, verbena and mint in the form of leaves, powders or particles, said process comprising the steps of: directly spraying said composition with an emulsion comprising: 5to 30% by weight of a solid film-building vehicle selected from the group consisting of polyvinyl acetate, polyvinyl alcohol, dextrins, natural or modified starch, natural or modified proteins, vegetable gums, pectins, xanthanes, carboxymethyl cellulose, methyl cellulose, hydroxyethyl cellulose and lipoheterosaccharides; 0.1 to 20% by weight of an emulsifying agent selected from the group consisting of fatty-acid mono- or diglycerides, esters derived from a combination of fatty acids with sorbitol or a saccharide or alkoxylated derivatives thereof, or an ester of tartaric, citric, ascorbic or lactic acid; and 0.5 to 20% by weight of an active volatile flavouring substance which is non-miscible with water with the remainder of the emulsion being water; and subsequently drying the emulsion-sprayed composition such that the flavouring substance is in direct contact with the leaves, powders or particles of the composition and is retained in the form of droplets coated with a protective water soluble layer consisting of said film-building vehicle.
None of the prior art described above relates to improvement of the appearance or colour of a tea product.
It is therefore an object of the present invention to provide a tea product with darker colour by treating the off coloured tea product.
It is another object of the present invention to increase the economic value of THE off coloured tea product thereby satisfying consumer needs.
Present inventors have surprisingly found that off-colur black leaf tea or dust tea, after addition of aqueous solutions of specific substances followed by drying results into a tea product with darker colour acceptable to consumers.
Summary of the Invention
According to the present invention, there is provided a process for preparing a tea product comprising the steps of:

a. Adding an aqueous solution or dispersion of a substance selected from
the group consisting of sugars, starches, vegetable gums, chicory
extract and enzymes or a mixture thereof to black leaf tea to obtain a
mixture, and;
b. Drying the mixture to a moisture content of less than 10% by weight to
obtain a tea product,
characterized in that the surface reflectance of the black leaf tea measured with amber tristimulus filter under D65 illuminant is greater than 12%.
Detailed Description of the Invention
The step (a)
The step (a) includes adding an aqueous solution or dispersion of a substance selected from the group consisting of sugars, starches or vegetable gums or enzymes or a mixture thereof to black leaf tea to obtain a mixture. Preferably, the addition of the aqueous solution or dispersion is by spraying. It is further preferred that the step (a) includes mixing the aqueous solution or dispersion with the black leaf tea. The mixing is preferably carried out in any suitable mixer. Preferred mixers include planetary mixer, screw mixer, paddle mixer or sigrna mixer.
Black leaf tea
The term "black leaf tea" as used herein means a tea produced by promoting the
aerobic oxidation of fresh leaf catechins in reactions catalyzed by tea polyphenol
oxidase. The term "fermentation" is also commonly used to refer to aerobic oxidation of
fresh leaf tea catechins in reactions catalyzed by tea polyphenol oxidase. The term
"fresh leaf as used herein includes buds, leaves, and/or stem of the plant Camellia
sinensis.
The term "dust tea" as used herein means a black leaf tea having mean particle size in the range 0.1-1 mm.

The term "instant black tea" means a product that is obtained from extraction of the black leaf tea in hot (80-100 °C) water, followed by filtration of insoluble solids to obtain a supernatant and after removing water from the supernatant. The term "black leaf tea" as used herein does not include "black instant tea".
Black leaf tea is preferably produced by a process comprising the steps of providing fresh tea leaf, macerating fresh tea leaf, withering the tea leaf, fermenting the tea leaf and drying the tea leaf to water content less than 10% by weight.
The substance
The substance in the step (a) is selected from the group consisting of sugars, starches, vegetable gums , chicory extract and enzymes or a mixture thereof. Preferably, the substance is selected from the group consisting of sugars, starches, chicory extract and vegetable gums or a mixture thereof. More preferably, the substance is selected from sugars, chicory extract and vegetable gums. Most preferably, the substance is selected from vegetable gums, chicory extract and starches or a mixture thereof.
The substance is preferably mixed with water to form the aqueous solution or dispersion. The mixing is preferably carried out under stirring.
The concentration of the substance in the aqueous solution or dispersion may vary widely depending on specific substance being used. In general the substance is preferably 0.05-80% by weight of the aqueous solution or the dispersion.
Temperature of the aqueous solution or dispersion is preferably in the range 1-95 °C, more preferably 10-80 °C, most preferably in the range 20-60 °C.
Sugars
The preferred sugars include a monosaccharide, a disaccharide, a sugar alcohol, or a
mixture thereof.

Monosaccharide is a chemical compound of general formula CnH2nOn where n = 3-7, and disaccharide is a condensation product of any two identical or different monosaccharides. Sugars also include corn syrups, which are mixtures of mono-, di-and higher saccharides and sugar alcohols.
Preferred sugars include disaccharides. A particularly preferred disaccharide is sucrose.
When sugar is used, the tea product comprises preferably 1-50% by weight more preferably 5-45% by weight and most preferably 10-40% by weight sugars. It is particularly preferred that the tea product comprises 15-35% by weight or even more preferably 20-30% by weight sugars.
Starches
Starch may be a natural starch or a modified starch, although modified starches are preferred. Some non-limiting examples of preferred modified starches include EmCap® (Cargill) and HICAP® (National Starch).
When starch is used, the starch is preferably 0.5-10% by weight, more preferably 1-8% by weight, most preferably 3-6% by weight of the tea product.
Gums
Any vegetable gum may be used in the present invention. The vegetable gum is preferably selected from guar gum, locust bean gum, gum acacia or mixtures thereof. It is particularly preferred that the vegetable gum is gum acacia.
When gums are used, the vegetable gum is preferably 0.5 -10% by weight, more preferably 1-8% by weight, and most preferably from 3-6% by weight of the tea product.

Chicory extract
Chicory is a flowering plant of the genus Chichorium of the family Asteraceae. Many species of chicory are known. It is grown in most continents including Europe, North and South America. It is preferred that the chicory is roasted. Roasting of the chicory can be light, medium or dark as known by one skilled in the art. The most preferred is the medium roasted chicory.
The roasted chicory is then extracted with water at 75 - 100°C. After the extraction the resulting solution was separated to obtain the chicory extract.
Enzymes
Preferred enzymes include pectinase, cellulase, tannase or a mixture thereof.
When enzymes are used, the enzyme is preferably 0.05-10% by weight, more preferably 0.1-0.5% by weight of the tea product.
The step (b)
The step (b) includes drying the mixture obtained in the step (a) to a moisture content of less than 10% by weight to obtain a tea product. Preferably, during the step of drying, the mixture is contacted with a gas which is generally air. The gas temperature is in the range of preferably 10-200 °C, more preferably 50-120 °C, most preferably 60-90 °C.
The moisture content of the tea product is preferably less than 9% by weight, more preferably less than 8% by weight, and further preferably less than 7% by weight. There is no particular lower limit on the moisture content of the tea product, and the moisture content may be as low as 0% by weight
The step of drying is preferably carried out in a tray dryer, vacuum dryer, of a fluidized bed dryer.

Colour of the black leaf tea and the tea product
Surface reflectance of the starting black leaf tea measured with amber tristimulus filter under D65 illuminant is greater than 12%, preferably greater than 12.2%, more preferably greater than 14%, and most preferably greater than 16%. There is no particular upper limit and the surface reflectance of the black tea may be as high as 80%. The surface reflectance has been found to be a good indicator of lightness/darkness of the black leaf tea or the end tea product, with lower values of the surface reflectance indicating darker colour of the black leaf tea or the end tea product and higher values of the surface reflectance indicating lighter colour of the black leaf tea or the end tea product. The surface reflectance may be measured by any commercially available measuring instrument. A preferred instrument for the surface reflectance measurement is Photovolt model 577 Reflectometer available from Photovolt Instruments, USA.
D65 is a standard illuminant defined by the International Commission on Illumination (CIE). The D65 illuminant is intended to represent average daylight throughout the visible spectrum. The surface reflectance measurements are carried out under D65 illuminant.
Surface reflectance of the tea product of the invention measured with amber tristimulus filter under D65 illuminant is preferably less than 13%, more preferably less than12.2%, further preferably less than 12% and most preferably less than 11%. There is no particular lower limit and the surface reflectance of the tea product may be as low as 1%.
The invention will now be illustrated with help of examples. The examples are for the purpose of illustration only and do not limit the scope of the invention in any manner.
Examples
Materials and Methods
Following materials were used in the experiments: Modifiied corn starch, EmCap®
(Cargill International, USA), Gum acacia powder (Collides Naturels International,

France), sucrose (E.I.D Parry (India) Limited, Chennai, India). Viscozyme® L {Novozymes, Denmark).
Black leaf tea (dust and leaf form) were obtained from North India tea gardens
Aqueous solution/dispersion of the substance (gum, starch, sugar or enzyme) was prepared by adding requisite amount of the substance to water, filtering through 100 micron mesh filter and heating if required to achieve specified temperature.
Black leaf tea was transferred to a Hobart mixer and the aqueous solution/dispersion was sprayed on to the black leaf tea, and the resultant mixture was mixed for about 10 minutes. The wet mixed mass was dried in a tray dryer at 80 °C for 20-40 minutes til! the moisture content of the final tea product was less than 6% by weight.
Surface reflectance measurements
Photovolt Model 577 Reflectometer from Photovolt Instruments, USA, was used for the measurements of surface reflectance.
Search units (Y/T) were used with amber filter set. Standard plaque (26-577-01 719 ) was used for calibration.
Procedure:
1. Install the Amber filter into the search unit for the reflectance measurement
2. Select the appropriate filter channel ('A' out of A, B, or G) by pressing the corresponding filter on the 577 front panel.
3. Place the black cavity standard on the search unit.
4. Depress the CHANGE key - the display goes black.
5. Depress the ZERO key - the display reads .0 (=/- 0.1).
6. Place a standard plaque on the search unit {Amber coloured plaque used is 26-577-01 719 (Green 8.5).

7. Depress the STD key - the display reads "75.0" or the last standard value entered for this filter channel. The STD, CHANGE, A, B and G LED's will all be lit.
8. Enter the standard plaque value by using the A, B, and G keys to increment the display's digits to the value printed on the back of the plaque for the selected filter (71.8)
9. Depress the STD key again - all LED's expect the selected filter channel LED (A, B, or G) will go out.This display should now be in the normal display mode and should display the value entered for the standard plaque (+/-0.2).
10. Fill the cuvet about 2/3rd with sample (the black leaf tea or tea product) and tap gently to settle the powder/tea sample. Use the PRESS (Plastic part) to firmly press the sample into place or manually compress the powder. Observe the bottom of the cuvet and ensure that there are no air spaces, etc. Wipe the externa! surface of the cuvet clean.
11. Place the filled cuvet on the search unit.
12. Obtain reflectance values.
Black leaf tea coated with starch
Black leaf tea (lot CB11) obtained from north Indian garden was coated with EmCap at various levels to obtain final tea products having various compositions as tabulated below. Also tabulated are reflectance values. Temperature of the coating solution was 25 °C in all the cases. Moisture content of the final dried tea product was less than 6% by weight in all the cases.

Table 1: Black leaf tea coated with starch

Example No EmCap concentration in the coating solution (% by weight) % by weight EmCap in the tea product Surface reflectance (%) Remark
Uncoated CB11 15.3 Light gray
1 8.6 1 11.5 Dark
2 15.8 2 11.0 Dark
3 22.0 3 10.4 Dark
4 27.2 4 9.4 Dark
5 31.8 5 9.4 Dark
6 3.8 1 10.7 Dark
7 7.3 2 10.7 Dark
8 10.6 3 10.4 Dark
9 13.6 4 10.2 Dark
10 16.4 5 9.9 Dark
From the results it is clear that the coating with starch solution results into relatively dark end product.
Black dust tea coated with gum acacia
Starting tea was black dust tea (lot CB12) obtained from tea gardens in north India.
Coating solution was at 25 °C in all the cases.

Table 2: Black dust tea coated with gum acacia

Example No Gum % by weight Surface reflectance Remark
concentration in the coating solution (% by weight) Gum in the tea product (%)
Uncoated - - 12.3 Light gray
CB12
11 3.8 1 12.1 Dark
12 7.3 3 10.2 Dark
13 16.4 5 10.2 Dark
From the results it is clear that the coating with gum acacia solution results into relatively dark end product.
Black leaf tea coated with glucose syrup
Starting tea was black dust tea (lot CB12) obtained from tea gardens in north India.
Coating solution was at 25 °C in all the cases.
Table 3: Black leaf tea coated with glucose syrup

Example Glucose %by %by Surface Remark
No concentration weight weight reflectance {%)
in the coating Glucose in lumps in
solution {% by weight) the tea product tea product
Uncoated - - - 12.3 Light gray
CB12
14 12.7 15 0 7.2 Dark
15 46.4 30 28 7.0 Dark

Black leaf tea coated with sucrose
Starting tea was black leaf tea (lot CB10) obtained from tea gardens in north India. Large size lumps were segregated by sieving and weighed to measure % by weight lumps in the tea product.
Table 4: Black leaf tea coated with sucrose

Example Sucrose Temperatur %by %by Surface Remark
No concentration e of coating weight weight reflectance
in the coating solution (% by weight) solution (°C) Sucrose in the tea product Lumps in tea product (%)
Uncoated - - - - 21.7 Light
CB10
16 30.3 25 15 0 12.1 Dark
17 46.4 25 30 6.8 3.2 Dark
18 46.4 55 30 5.0 3.5 Dark
19 46.4 75 30 1.0 5.1 Dark
It is clear that increasing the concentration of the coating solution increases the darkness of the tea product as compared to that of uncoated black tea. Furthermore, with increase in concentration of the coating solution, the energy required for drying would be relatively lower. However, with increasing concentration of the coating solution, there is a tendency of formation of lumps. The problem related to the lump formation whilst using relatively high concentration of the coating solution is significantly reduced by increasing the temperature of the coating solution.

Black leaf tea coated with enzyme
Base black dust tea (CB09) and black leaf tea (Cb06) were coated with Viscozyme® as tabulated below.
Table 5:

Example No Viscozyme® Temperature %by Surface Remark
concentration in of coating weight reflectance
the coating coating sofution (% by weight) solution (°C) Enzyme in the tea product (%)
CB09 dust - - - 18.8 Light
20 (Coated 2.0 25 0.29 6.4 Dark
CB09)
CB06 black - - - 14.5 Light
leaf tea
Coated 0.8 50 0.12 11.3 Dark
CB06
From the results, it is clear that enzyme coating darkens the colour of the base tea.
Black leaf tea coated with chicory extract
Starting tea was black leaf tea (lot CB10) obtained from tea gardens in north India. Large size lumps were segregated by sieving and weighed to measure % by weight lumps in the tea product.

Table 6:

Example Chicory Temperature %by Surface % Remark
No concentration in of coating weight reflectance Lumps (light or
the coating solution (% by weight) solution (oC) chicory in the tea product (%) dark)
Uncoated- - - - 21.4 - Light
CB10
21 12.7 25 5.0 11.3 0 Dark
22 30.3 25 15.0 7.6 0 Dark
23 46.4 25 30.0 3.7 35.7 Dark
24 46.4 50 30.0 2.7 12.5 Dark
25 46.4 75 30.0 2.4 4.3 Dark
From the above table it is clear that coating the tea leaf with chicory extract darken the colour of the leaf. With the increased concentration of the chicory the darkening effect is much pronounced. With lower concentration chicory (example 21, 22) there is no lump formation. For higher concentration of chicory (example 23, 24, 25) although there are formation of lumps but with the increase in temperature lump formation reduces.
Therefore by way of present invention it is now possible to provide a tea product with darker colour by treating the off coloured tea product.

Claims
1. A process for preparing a tea product comprising the steps of:
a. Adding an aqueous solution or dispersion of a substance selected from
the group consisting of sugars, starches, vegetable gums, chicory
extract and enzymes or a mixture thereof to black leaf tea to obtain a
mixture, and;
b. Drying the mixture to a moisture content of less than 10% by weight to
obtain a tea product,
characterized in that the surface reflectance of the black leaf tea measured with amber tristimulus filter under D65 illuminant is greater than 12%.
2. A process as claimed in claim 1 wherein said substance is 0.05-50% by weight of said aqueous solution or dispersion.
3. A process as claimed in claim 1 or claim 2 characterized in that surface reflectance of the tea product measured with amber tristimulus filter under D65 illuminant is less than 12.2%.
4. A process as claimed in any one of the preceding claims wherein when said substance is sugar, the tea composition comprises 1-80 % by weight sugar.
5. A process as claimed in any one of the preceding claims wherein when said substance is chicory extract, the tea composition comprises 1-60 % by weight of chicory.
6. A process as claimed in any one of the preceding claims wherein when said substance is starch, the tea composition comprises 0.5-10 % by weight starch.
7. A process as claimed in any one of the preceding claims wherein when said substance is vegetable gum, the tea composition comprises 0.5-10% by weight vegetable gum.

8. A process as claimed in any one of the preceding claims wherein when said substance is enzyme, the tea composition comprises 0.05-10% by weight enzyme.
9. A process as claimed in any one of the preceding claims wherein temperature of said aqueous solution or dispersion is in the range 1-95 °C.
10. A process as claimed in any one of the preceding claims wherein said substance is selected from the group consisting of sugars, starches, chicory extract and vegetable gums.
11. A process as claimed in any one of the preceding claims wherein said substance is selected from the group consisting of vegetable gums , chicory extract and starches.