Abstract: Natural dark brown cocoa products are disclosed. Processes for producing such natural dark brown cocoa products are also disclosed as well as foods including such cocoa products. In each of various embodiments the present invention helps fulfill these needs and discloses processes for producing "natural" cocoa products that have the color of alkalized cocoa products. Cocoa products produced by such methods are also disclosed.
PROCESSES FOR PRODUCING DARK BROWN NATURAL COCOA
CROSS-REFERENCE TO RELATED APPLICATIONS
[0001] This application claims priority to US Provisional Patent Application
61/839,100 filed June 25, 2013, the contents of the entirety of which is incorporated by this
reference.
TECHNICAL FIELD
[0002] Methods for producing natural cocoa products are disclosed. Natural cocoa
products including, but not limited to, cocoa cakes, cocoa powders, and food products including
such cocoa products are disclosed.
BACKGROUND OF THE FNVENTION
[0003] Cocoa bean processing includes fermenting harvested beans, drying the beans,
de-hulling the beans to produce nibs, sterilizing the nibs, roasting the nibs, crushing the nibs into
cocoa liquor, and optionally pressing the cocoa liquor to obtain cocoa butter and cocoa powder.
[0004] Traditionally, natural cocoa products are light brown in color and have a pH in
the range of 5.1 to 6.0. A typical L-value of 10 grams of a natural cocoa in 30 grams of water
measured with a Hunterlab colorimeter is 20 or higher, and a- and b- values are 8.5 and higher.
[0005] In order to generate darker and more reddish colors in cocoa products, a certain
amount and type of alkali is added in an alkalization process. Alkalization is a process where
cocoa products are alkalized under a certain amount of moisture, at a certain temperature,
optionally under pressure, and for a certain amount of time. The alkalization process occurs in
the presence of sodium, potassium, ammonium, or magnesium hydroxide or carbonate, for
example and without limitation, potash (K2CO3) . The alkalization process alters the flavor, color,
and solubility of the cocoa powder in water
[0006] Current commercial demands require a cocoa manufacturer to produce cocoa
products in a broad palette of colors, flavors, or both. While each manufacturer understands that
manipulation of processing conditions such as temperature, water content, duration of processing
time, and pH will affect the color and flavor of the cocoa product, there is no general consensus
as to how to produce a cocoa product of a consistently desirable color, flavor, or both.
[0007] While the alkalization process may be used to produce darker and/or more
reddish cocoa products, the presence of the alkalizing agent also affects the labeling of such
cocoa products. Such alkalized cocoa products are often labeled as being "processed with alkali."
Thus, the presence of the alkalizing agent means such cocoa product cannot be considered
"natural" and consumers are demanding "all natural" products which are typically lighter brown
in color.
[0008] Thus, a growing need exists for cocoa products that possess the color of
alkalized cocoa products, yet are considered "natural."
SUMMARY OF THE INVENTION
[0009] In each of various embodiments, the present invention helps fulfill these needs
and discloses processes for producing "natural" cocoa products that have the color of alkalized
cocoa products. Cocoa products produced by such methods are also disclosed.
[0010] In one embodiment, a process for producing a dark brown, natural cocoa
product includes mixing cocoa cake and water, thus producing a mixture. Subjecting the mixture
to an elevated pressure, and drying the mixture. The dark brown, natural cocoa product is not
alkalized.
[0011] In a further embodiment, a natural, cocoa product has an L-value of between
about 10 and about 15, an a-value of between about 4 and about 6.2, a b-value of between about
3.5 and about 6.0, and a pH of less than about 6.
BRIEF DESCRIPTION OF THE DRAWINGS
[0012] Figure 1 shows the L-values of various embodiments of dark brown, natural
cocoas of the present invention in a compound coating.
[0013] Figure 2 shows the a-values of various embodiments of dark brown, natural
cocoas of the present invention in a compound coating.
[0014] Figure 3 shows the b-values of various embodiments of dark brown, natural
cocoas of the present invention in a compound coating.
[0015] Figure 4 shows a spider graph of a taste evaluation of compound coatings
produced with various embodiments of dark brown, natural cocoas of the present invention.
[0016] Figure 5 shows a spider graph of a taste evaluation of cakes produced with
various embodiments of dark brown, natural cocoas of the present invention.
[0017] Figure 6 shows a spider graph of a taste evaluation of puddings produced with
various embodiments of dark brown, natural cocoas of the present invention.
[0018] Figure 7 shows a spider graph of a taste evaluation of ice creams produced with
various embodiments of dark brown, natural cocoas of the present invention.
DETAILED DESCRIPTION OF THE INVENTION
[0019] In one embodiment, dark, natural cocoa is produced. The dark, natural cocoa
may be dark brown. The cocoa may be cocoa cake or cocoa powder.
[0020] In a further embodiment, a process for producing the dark, natural cocoas
includes mixing cocoa cake with water, thus producing a mixture, subjecting the mixture to an
elevated pressure, and/or drying the mixture. The moisture of the mixture may be between about
26% and about 35%. The water may also be heated to a temperature of less than about 125°C, a
temperature of between about 85°C and 120°C, or a temperature of about 190°F to about 250°F.
[0021] In another embodiment, the mixture of the cocoa cake and the water may be
subjected to pressure, such as between about 5 and about 25 psi. The mixture may be reacted at
the pressure for a time of between about 30 and about 200 minutes. The mixture may be dried,
such as at atmospheric pressure or under vacuum. The cocoa cake may also be ground into a
cocoa powder, which may have a fineness of a minimum of 98% through a 200 mesh screen.
[0022] In an embodiment, the cocoa cake may be of a West African origin and in other
embodiment, may be of other origins.
[0023] In yet an additional embodiment, the nibs, the de-shelled beans, or the
combination thereof are sterilized.
[0024] In yet a further embodiment, the cocoa nibs, the de-shelled beans, or the
combination thereof are ground, thus producing cocoa liquor. The cocoa liquor may be separated
into cocoa butter and cocoa presscake, or the cocoa liquor may be defatted. The cocoa presscake
may be further ground into cocoa powder.
[0025] In another embodiment, the natural cocoa products of the present invention may
have a dark color which refers to cocoa products with an L-value less than about 15.0, 14.0, 13.0,
12.0, 11.0, 10.0, 9.0, 8.0, 7.0, 6.0, 5.0, 4.0, or lower, inclusive of intervals between those values.
The L-value may also be between about 10 and about 15. The a-values may be between about 4
and about 6.2. The b-values may be between about 3.5 and about 6.5. The calculated C-values
may be between about 5 and about 10. The calculated H-values may be between about 42 and
about 49.
[0026] In yet an additional embodiment, a natural cocoa product of the present
invention has a pH of less than about 6, between about 3 to about 6, a pH of between about 4.5 to
about 6, or a pH of between about 5 to about 6.
[0027] In one embodiment, a starting material for the processes described herein may
be de-shelled cocoa beans which refers to any suitable cocoa bean fraction/product having the
shells substantially removed, broken, and/or winnowed. Non-limiting examples of de-shelled
cocoa beans include, but are not limited to, nibs, kernels, and cotyledons. De-shelled cocoa beans
typically contain a small fraction of contaminating shells that are within commercially acceptable
tolerances since no de-shelling process is 100% complete.
[0028] In an additional embodiment, the cocoa beans used to produce the natural cocoa
products of the present invention are good fermented. In a further embodiment, the cocoa beans
used to produce the natural cocoa products of the present invention are under- or un- fermented.
[0029] In one embodiment, the natural cocoa products produced herein are suitable for
many commercial purposes, including, without limitation, food products. Examples of food
products include, but are not limited to, chocolate, dark chocolate, milk chocolate, semi-sweetchocolate,
baking chocolate, candies, pralines, truffles, candy bars, flavoring syrup,
confectionary coatings, compound coatings, fillings, beverages, dairy products, milk, ice cream,
beverage mixes, smoothies, soy milk, cakes, cheesecakes, cookies, pies, diet bars, meal-substitute
solid foods and beverages, energy bars, chocolate chips, yogurt, yogurt drinks, pudding, mousse,
mole, chocolates with lower bitterness, chocolate with fillings such as yogurt, and/or cheesecake.
[0030] A number of objective methods for measuring the color of cocoa products are
known. In one method, the Hunter color system or CIE 1976 (CIELAB) and like systems, color
may be described in terms of three parameters: Lightness (L)—the light or dark aspect of a color,
where the lower the L-value, the darker the cocoa powder will appear; Chroma (C)—the intensity
of a color by which one distinguishes a bright or gray color, where the higher the C-value, the
brighter the powder will be; and Hue (H)~ referring to color in daily speech, such as red, yellow,
or blue. For cocoa powders, a low H value indicates a red color and a high H-value indicates a
brown color.
[0031] The CIE 1976 color system describes colors in terms of coordinates L, "a*" and
"b*". The L coordinate is consistent with the Value of Lightness, and from the a* and b*
coordinates, the Chroma and Hue can be calculated as follows: C*= {square root over
(a* +b*2)}; H=arctan(b*/a*).
[0032] The spectral color is the result of the source of light and the reflecting surface.
For a good reproducible measurement of color, the source of light is standardized. There are two
basic approaches for measuring color: visually or by instrumentation. There is a natural human
tendency to trust only "one's own eyes." For this reason, colors are still frequently judged
visually. To be able to do this in a reproducible manner, certain standard conditions should be
met: the light source, for example and without limitation, a CIE standard light source; the
positions of the sample, relative to the light source, which are preferably at an angle of 45° to
each other; the background of the sample, uniform and preferably gray; the distance between the
eyes and the sample and position of the eyes relative to the sample; and the size of the sample.
[0033] In practice, color cabinets are used with standard light sources for visual color
determinations. Color meters and spectrophotometers are used for instrument color readings.
Instrument color measurements were made in the Examples herein using 10 grams of a natural
cocoa in 30 grams of water measured with a Hunterlab colorimeter. Unless otherwise indicated,
the color values described in the Examples, and all reference herein to color values L, a and b
are readings using the Hunterlab colorimeter. The color parameters described herein refer to the
L, a, and b readings, and C values and H values were calculated. The color values recited herein
are approximate in the sense that color measurements may vary from spectrophotometer-tospectrophotometer,
typically in the range of +/- 0.5 for L, a, b, C, and H values.
[0034] The following examples illustrate various non-limiting embodiments of the
compositions within the present disclosure and are not restrictive of the invention as otherwise
described or claimed herein.
EXAMPLES
[0035] Example 1.
[0036] Non-alkalized cocoa cake was treated with water at levels between 27 and 35%,
at pressure levels of between 5 and 22 psi, and a treatment time of about 30 minutes. The
treatments were carried out in an industrial size reactor typically used for cake alkalization
processes. The conditions of the various trials are shown in Table 1.
[0037] Table 1. Cocoa cake treatment conditions.
Amount of water (lbs) 6500 6000 4200
Moisture (%) 27.7 35.3 27.6
Pressure (psi) 22 22 5
Max. temp. (F) 239 239 192
Max. temp. (C) 115 115 89
Time (minutes) 30 30 30
[0038] After the treatment, the treated cocoa cake was dried under vacuum and ground
into a fine powder. The fine powder was analyzed for: pH (in a 10% water solution); color in
water (using Hunterlab at a 25% slurry of the powder in the water); color in milk (visually at a
4% solution of the powder in milk); for fineness (wet as determined by the percent through a 75
mih screen); and for flavor in hot water (using 4% of the powder, 5% sugar, and hot water). The
pH, color, and fineness are shown in Table 2. Table 3 shows the pH and color value ranges of
typical cocoa powders.
[0039] Table 2. Analytical results of treated cocoa cake.
[0040] Table 3. pH and color ranges of typical cocoa powders.
Natural Light Medium Red Dark brown
alkalized alkalized (alkalized) (alkalized)
pH 5.7 7.2 7.6 8 8.1
L 22.1 17.42 15.54 13.18 9.77
a 10 9.42 8.8 7.85 4.24
b 9.88 7.84 6.91 5.72 3.23
C 14.1 12.3 11.2 9.7 5.3
(calculated)
H 44.79 39.77 38.14 36.08 37.3
(calculated)
[0041] The color values of Table 2 indicate a strong color development of the cocoa
cake treated with water. Trials 1 and 2 show L values between that of a typical alkalized, red and
typical alkalized, dark brown cocoa, and the L value of Trial 3 has an L value between that of an
alkalized red and a medium, alkalized brown cocoa. The lower C value corresponds to a lower
brightness and grayish hue. The H value did not change significantly during the water treatment
indicating that the powder stayed brown and didn't show the red tones that are typical for
alkalized cocoa powders. Overall, the color values show the natural, dark cocoa of the present
invention are truly dark brown as compared to traditional natural cocoas. The observed color in
milk confirms the results of the measured cocoa values.
[0042] The flavor of the dark, natural cocoas is significantly different from regular,
natural cocoas and alkalized cocoas. Typical natural cocoas are acidic, astringent, bitter, may
have some fruity notes, and may have some additional origin specific notes. In typical alkalized
cocoas, the acidic notes of natural cocoas are replaced by an increased alkaline impact the overall
cocoa impact becomes more intense and the astringency is reduced. The degree of alkalization
determines the intensity of these notes.
[0043] The dark, natural cocoas of the present invention have a mild cocoa impact,
show slight spicy, slight sour, and very slight astringent notes. Trial 2 had some roasted notes and
Trial 1 had slightly more intense roasted notes. The natural, dark cocoas of the present invention
are different from the flavor of traditional, natural cocoa or alkalized cocoa products. The color
of the natural, dark cocoas of the present invention is also on the dark side of the overall color
spectrum and may be mixed with a traditional, natural cocoa, such as at a ratio of 1 to 2 in order
to create a color impact similar to that of a medium, alkalized cocoa, yet having the flavor of a
natural cocoa.
[0044] Example 2.
[0045] A compound coating was prepared using the dark, natural cocoa products of
Example 1. The formulations in Table 4 were used to prepare a white base and a cocoa base.
[0046] Table 4. Formulations of white base and cocoa base.
White base Cocoa base
Sugar (%) 70.44 55.44
Fat, 95 PK (%) 27.95 27.95
Nonfat dry milk (%) 1 1
Soy lecithin (%) 0.55 0.55
Vanillin (%) 0.06 0.06
Cocoa (%) 0 15
[0047] The cocoa powders used were a commercially available natural cocoa (N), a
commercially available red cocoa (R), a commercially available black cocoa (B), the cocoa of
Trial 1, the cocoa of Trial 2, and the cocoa of Trial 3 of Example 1. The white base and the cocoa
base were mixed to create products having cocoa contents of between 1 and 15%. The L-values
of the various products was evaluated and are shown in FIG. 1.
[0048] FIG. 1 shows the color strength in the compound coatings of the dark, natural
cocoas as compared to coatings prepared with the commercially available natural cocoa (N), the
commercially available red cocoa (R), and the commercially available black cocoa (B). The Lvalue
of the compound coating with the cocoa of Trial 3 is between the coatings produced with
the natural (N) and red (R) cocoa. Between 75-85% of the cocoa of Trial 3 is required to produce
the same L value as the coating with the natural (N) cocoa. The L-value of the cocoa of Trial 2 in
the coating is lower than the L-value of the red (R) cocoa in the coating, and between 60-80% of
the Trial 2 cocoa is needed to achieve the same L-value in a coating as the natural (N) cocoa. The
coating with the cocoa from Trial 1 is the darkest of the coatings produced with the dark, natural
cocoas of Example 1, and between 50 and 70% of the cocoa of Trial 1 is needed to achieve the
same L-value as the natural (N) cocoa in the coating.
[0049] a- and b- measurements were also taken of the compound coatings produced in
this Example and are shown in FIG. 2 and FIG. 3, respectively. The a-values of the coatings
including the dark, natural cocoas of Trials 1, 2, and 3 are lower than the a-value of the coatings
having the red (R) cocoa and the natural (N) cocoa. The b-value of the coating including the
cocoa of Trial 3 is almost the same as the coating having the red (R) cocoa and lower than the bvalue
of the coating with the natural (N) cocoa. The b-values for coatings having the dark, natural
cocoas of Trials 1 and 2 are lower than the b-value of the coating having the red (R) cocoa.
[0050] The calculated C- and H-values show that the coatings having the dark, natural
cocoas of Trials 1 and 2 are fairly similar in brightness and hue, while the coating with the cocoa
of Trial 3 is less gray than the coatings with the cocoas of Trials 1 and 2. The three coatings with
the dark, natural cocoas of Example 1 are dark brown, with no development of a red hue as
typically seen with alkalized cocoas.
[0051] The data in this Example shows that in a compound coating, a lower amount of
the dark, natural cocoa of the present invention is needed to achieve a certain L-value as
compared to the commercially available natural (N) cocoa. This would be beneficial since a cost
savings could be realized by using less cocoa when manufacturing a food containing such cocoa
products.
[0052] Example 3.
[0053] The flavors of compound coatings produced with the dark, natural cocoas of
Example 1 were compared against a commercially available cocoa as the reference. The
following blends were used: reference included 10% of a commercially available natural cocoa
plus 5% of a commercially available red cocoa; Trial 1 included 10% of a commercially
available natural cocoa plus 5% of the cocoa of Trial 1; Trial 2 included 10% of a commercially
available natural cocoa plus 5% of the cocoa of Trial 2; and Trial 3 included 10% of a
commercially available natural cocoa plus 5% of the cocoa of Trial 3. The three trials were tasted
against the reference.
[0054] A group of 17 experienced panelists were asked to use a scale ranging from -6 to
+6 for a range of descriptors typical for compound coatings. The average of the evaluations was
calculated and the results are presented in the spider graph of FIG. 4.
[0055] The blends including cocoas from Trials 2 and 3 scored very similar and except
for the sour/acidic impact, were very similar to the reference coating including the reference
cocoa. The blend including the cocoa from Trial 1 was less sweet and had a higher impact for
cocoa/chocolate, sour/acidic, and roasted notes.
[0056] Example 4.
[0057] The blends of Example 3 including the dark, natural cocoas of Trials 1, 2, and 3,
a reference natural cocoa powder (Ref), and a reference natural cocoa powder mixed with a red
cocoa (Red), and an all red cocoa were also tested in chocolate flavored cakes. The cakes were
made using a conventional recipe and having 5.4%> cocoa. The blends evaluated included 2/3
(3.6% of recipe) of a reference natural cocoa blended with a reference red cocoa or a dark,
natural cocoa of Example 1, or 5.4% red cocoa.
[0058] All of the cakes evaluated in this Example had similar baking performances,
height, and shapes. The only exception was the cake made with the reference natural cocoa,
which had a lower height. The color of the cake with the cocoa of Trial 1 was the darkest and had
more brown than reddish tones as compared to the reference blends. The cakes with the cocoas of
Trials 2 and 3 were similar in color, darker, and more brown than one of the reference cocoas,
and a bit lighter and more brown than the other reference cocoa.
[0059] The flavor of the cakes was evaluated with a group of seven experienced tasters.
A spider graph of the results of the taste evaluate is shown in FIG. 5. The cake with the Ref blend
cocoa (3.6% standard natural cocoa and 1.8% standard red cocoa) was more acidic and had some
bitter and earthy notes not present in the Red blend. The cake with the cocoa of Trial 1was more
acidic, had notes of bitter, burnt, and woody not present in the Ref sample. The cake having the
cocoa of Trial 2 had more chocolate notes than the Ref sample and also had spicy, wood, burnt,
and fruity notes. The cake with the cocoa of Trial 3 has more chocolate notes, but was otherwise
similar to the Ref sample.
[0060] The cocoa from Trial 1was also used in a cookie and compared to cookies
produced with cocoas of medium/red alkalization. The cookies produced with the cocoa of Trial
1 were more brown than the alkalized powders.
[0061] Example 5.
[0062] The same blends of cocoas evaluated in the compound coatings of Example 3
(Trial 1, Trial 2, Trial 3, and Ref) were also evaluated in pudding and compared to lightly
alkalized cocoa (LA). The pudding recipe used was: 1 package of JELL-0 brand vanilla instant
pudding; 3 cups of 2% milk; and 25 grams of cocoa (2.7% by weight). As seen in the previous
examples, the cocoa of Trial 1was darker and more brown than the Ref blend in the puddings.
The cocoa of Trial 2 in the pudding was darker and more brown than the Ref blend in the
pudding. The puddings produced with the cocoas of Trials 1 and 2 were clearly darker and more
brown than the pudding produced with the lightly alkalized cocoa.
[0063] Flavor evaluations were also performed in the puddings and the results are
presented in the spider graph of FIG. 6. Consistent with the previous examples, the cocoa from
Trial 1 in the pudding was more acidic and has less chocolate and milky notes than the Ref
cocoa. The pudding with the cocoa of Trial 2 was sweeter and lower in cocoa/chocolate, milky,
and roasted notes than the pudding with the Ref cocoa. The pudding with the Trial 3 cocoa was
less sweet and more intense in chocolate and milky notes than the pudding with the Ref cocoa.
[0064] Example 6.
[0065] The natural, dark cocoas of Example 1 were also evaluated in Greek yogurt.
CHOBANI brand Greek yogurt was mixed with blends of a reference cocoa and the cocoas of
Trials 1 and 2 at levels of 3% and 5% of the cocoa. In a couple of samples, 4% and 6% sugar was
also added to compensate for the bitterness. The five samples evaluated included: 3% of a
reference cocoa; 1.5% of the reference cocoa and 1.5% of the Trial 1 cocoa; 1.5% of the
reference cocoa and 1.5% of the Trial 2 cocoa; 2% of the reference cocoa, 1% of the Trial 1
cocoa, and 4% sugar; and 2.6% of the reference cocoa, 1.3% of the Trial 1 cocoa, and 6% sugar.
An evaluation of the various samples resulted in the last sample, 2.6% of the reference cocoa,
1.3% of the Trial 1 cocoa, and 6% sugar, being the favorite because of the color and pleasant
chocolate flavor.
[0066] Example 7.
[0067] Five samples of cocoas were prepared. A commercially available natural cocoa
(Sample 1), a blend of 2/3 of the commercially available natural cocoa and 1/3 of a reference red
cocoa (Ref), a blend of 2/3 of the commercially available natural cocoa and 1/3 of the natural,
dark cocoa of Trial 2 (Sample 2), a blend of 2/3 of the commercially available natural cocoa and
1/3 of the natural, dark cocoa of Trial 1 Sample 3) were evaluated in ice cream. The ice cream
was prepared using the following formulation: 315 ml of half & half; 315 ml of heavy whipping
cream; 115 grams of sugar; 0.5 teaspoons of vanilla extract; and 15 grams of the cocoa samples.
The ingredients were mixed, scraped, and frozen in an ice cream maker for about 30-40 minutes.
[0068] The ice creams made with the cocoas of Trials 1 and 2 were darker than the ice
cream made with the reference mix, where the ice cream including the cocoa of Trial 1 was the
darkest. The colors of the ice creams made with the cocoas of Trials 1 and 2 were similar to ice
creams made with lightly, alkalized cocoas.
[0069] A sensory evaluation by a panel of 14 experienced tasters was performed with
the ice creams prepared in this Example. A spider graph of the results of the evaluation is shown
in FIG. 7. Ice cream made with the natural cocoa (Sample 1) was the most acidic, the ice cream
made with the cocoa of Trial 2 (Sample 2) had prominent maple, caramel, and/or spice notes, and
the ice cream made with the cocoa of Trial 1 (Sample 3) was a bit lower in chocolate/cocoa
impact as compared to the rest of the ice creams.
[0070] This disclosure has been described with reference to certain exemplary
embodiments, compositions and uses thereof. However, it will be recognized by those of
ordinary skill in the art that various substitutions, modifications or combinations of any of the
exemplary embodiments may be made without departing from the spirit and scope of the
disclosure. Thus, the disclosure is not limited by the description of the exemplary embodiments,
but rather by the appended claims as originally filed.
CLAIMS
What is claimed is:
1. A process for producing a dark brown, natural cocoa product, comprising:
mixing cocoa cake and water, thus producing a mixture;
subjecting the mixture to an elevated pressure; and
drying the mixture, thus producing a dried cocoa cake;
wherein the dark brown, natural cocoa product is not alkalized.
2. The process of claim 1, further comprising grinding the dried cocoa cake into a
dark brown, natural cocoa powder.
3. The process of claim 1 or claim 2, wherein the mixture has a moisture content
between about 27% and about 35%.
4. The process of claim 1 or claim 2, wherein the elevated pressure is between about
5 and about 22 psi.
5. The process of claim 1 or claim 2, wherein the mixture is subjected to the elevated
pressure for a time of between about 20 and 40 minutes.
6. The process of claim 1 or claim 2, wherein the mixture is at a temperature of less
than about 125°C.
7. The process of claim 1 or claim 2, wherein the mixture is at a temperature of
between about 85°C and 120°C.
8. The process of claim 1 or claim 2, further comprising:
grinding cocoa nibs, de-shelled cocoa beans, or a combination thereof, thus producing cocoa
liquor; and
pressing the cocoa liquor, thus producing cocoa butter and the cocoa cake.
9. The process of claim 8, further comprising roasting the cocoa nibs, the de-shelled
cocoa beans, or the combination thereof.
10. The process of claim 2, further comprising mixing the dark brown, natural cocoa
powder with a cocoa powder.
11. The process of claim 10, wherein the cocoa powder is natural.
12. The process of claim 10, wherein the cocoa powder is alkalized.
13. A natural, cocoa product comprising:
an L-value of between about 10 and about 15;
an a-value of between about 4 and about 6.2;
a b-value of between about 3.5 and about 6.0; and
a pH of less than about 6.
14. The natural, cocoa product of claim 13, wherein the pH is between about 5.1 and
about 6.0.
15. The natural, cocoa product of claim 13 or 14, wherein the cocoa product is a
cocoa powder.
16. The natural, cocoa product of claim 15, wherein the powder has a fineness of at
least 98% of the cocoa power passing through a 200 mesh screen.
17. The natural, cocoa product of claim 13 or 14, wherein the natural, cocoa product
has a calculated C-value of between about 5 and about 10.
18. The natural, cocoa product of claim 13 or 14, wherein the natural, cocoa product
has a calculated H-value of between about 42 and about 49.
| # | Name | Date |
|---|---|---|
| 1 | Priority Document [08-01-2016(online)].pdf | 2016-01-08 |
| 2 | Form 5 [08-01-2016(online)].pdf | 2016-01-08 |
| 3 | Form 3 [08-01-2016(online)].pdf | 2016-01-08 |
| 4 | Drawing [08-01-2016(online)].pdf | 2016-01-08 |
| 5 | Description(Complete) [08-01-2016(online)].pdf | 2016-01-08 |
| 6 | 201617000814.pdf | 2016-01-09 |
| 7 | 201617000814-PCT-(28-01-2016).pdf | 2016-01-28 |
| 8 | 201617000814-Correspondence Others-(28-01-2016).pdf | 2016-01-28 |
| 9 | 201617000814-GPA-(18-02-2016).pdf | 2016-02-18 |
| 10 | 201617000814-Correspondence Others-(18-02-2016).pdf | 2016-02-18 |
| 11 | 201617000814-Assignment-(18-02-2016).pdf | 2016-02-18 |
| 12 | Form 3 [17-05-2016(online)].pdf | 2016-05-17 |
| 13 | abstract.jpg | 2016-06-23 |
| 14 | Form 3 [10-11-2016(online)].pdf | 2016-11-10 |
| 15 | Form 18 [02-06-2017(online)].pdf | 2017-06-02 |
| 16 | 201617000814-FORM 3 [01-12-2017(online)].pdf | 2017-12-01 |
| 17 | 201617000814-FORM 3 [11-10-2018(online)].pdf | 2018-10-11 |
| 18 | 201617000814-FER.pdf | 2019-01-23 |
| 19 | 201617000814-FORM 3 [15-07-2019(online)].pdf | 2019-07-15 |
| 20 | 201617000814-Information under section 8(2) (MANDATORY) [16-07-2019(online)].pdf | 2019-07-16 |
| 21 | 201617000814-OTHERS [20-07-2019(online)].pdf | 2019-07-20 |
| 22 | 201617000814-FER_SER_REPLY [20-07-2019(online)].pdf | 2019-07-20 |
| 23 | 201617000814-DRAWING [20-07-2019(online)].pdf | 2019-07-20 |
| 24 | 201617000814-CORRESPONDENCE [20-07-2019(online)].pdf | 2019-07-20 |
| 25 | 201617000814-COMPLETE SPECIFICATION [20-07-2019(online)].pdf | 2019-07-20 |
| 26 | 201617000814-CLAIMS [20-07-2019(online)].pdf | 2019-07-20 |
| 27 | 201617000814-ABSTRACT [20-07-2019(online)].pdf | 2019-07-20 |
| 28 | 201617000814-PatentCertificate23-08-2019.pdf | 2019-08-23 |
| 29 | 201617000814-IntimationOfGrant23-08-2019.pdf | 2019-08-23 |
| 30 | 201617000814-FORM 4 [29-11-2019(online)].pdf | 2019-11-29 |
| 31 | 201617000814-RELEVANT DOCUMENTS [17-03-2020(online)].pdf | 2020-03-17 |
| 32 | 201617000814-RELEVANT DOCUMENTS [25-03-2020(online)].pdf | 2020-03-25 |
| 33 | 201617000814-POST GRANT EVIDENCE OPPOSITION [22-08-2020(online)].pdf | 2020-08-22 |
| 34 | 201617000814_(E-9-5-2020-DEL)-Notice_US25(3)-(24-08-2020).pdf | 2020-08-24 |
| 35 | 201617000814-FORM-26 [19-10-2020(online)].pdf | 2020-10-19 |
| 36 | 201617000814-Statement and Evidence [22-10-2020(online)].pdf | 2020-10-22 |
| 37 | 201617000814-MARKED COPIES OF AMENDEMENTS [22-10-2020(online)].pdf | 2020-10-22 |
| 38 | 201617000814-FORM 13 [22-10-2020(online)].pdf | 2020-10-22 |
| 39 | 201617000814-AMENDED DOCUMENTS [22-10-2020(online)].pdf | 2020-10-22 |
| 40 | 201617000814-Response to office action [07-12-2020(online)].pdf | 2020-12-07 |
| 41 | 201617000814-RELEVANT DOCUMENTS [16-03-2021(online)].pdf | 2021-03-16 |
| 42 | 201617000814-FORM-14 [16-03-2021(online)].pdf | 2021-03-16 |
| 43 | 201617000814-FORM-26 [28-04-2021(online)].pdf | 2021-04-28 |
| 44 | 201617000814-Statement and Evidence [13-05-2021(online)].pdf | 2021-05-13 |
| 45 | 201617000814-Further Evidence [05-07-2021(online)].pdf | 2021-07-05 |
| 46 | 201617000814-RELEVANT DOCUMENTS [20-09-2021(online)].pdf | 2021-09-20 |
| 47 | 201617000814-RELEVANT DOCUMENTS [28-09-2021(online)].pdf | 2021-09-28 |
| 48 | 318800-Power of Attorney-200521.pdf | 2021-10-17 |
| 49 | 318800-Correspondence-200521.pdf | 2021-10-17 |
| 50 | 201617000814-RELEVANT DOCUMENTS [05-09-2022(online)].pdf | 2022-09-05 |
| 51 | 201617000814-RELEVANT DOCUMENTS [09-05-2023(online)].pdf | 2023-05-09 |
| 52 | 201617000814-FORM 4 [12-07-2023(online)].pdf | 2023-07-12 |
| 1 | search_22-01-2019.pdf |