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Process For Separating A Hydrophobic Material From A Mixture Of Hydrophobic And Hydrophilic Material

Abstract: In accordance with the present subject matter there is provided a process for separating hydrophobic material from a mixture of hydrophobic and hydrophilic material using peptide-based amphiphilic organogelators.

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
30 November 2015
Publication Number
22/2017
Publication Type
INA
Invention Field
GENERAL ENGINEERING
Status
Email
iprdel@lakshmisri.com
Parent Application
Patent Number
Legal Status
Grant Date
2020-02-05
Renewal Date

Applicants

HINDUSTAN PETROLEUM CORPORATION LIMITED
Hindustan Petroleum Corporation Ltd, Petroleum House, 17 Jamshedji Tata Road, Churchgate, Mumbai 400020, Maharashtra, India

Inventors

1. RAVISHANKAR, Raman
Hindustan Petroleum Corporation Limited, Hindustan Petroleum Green R&D Center (HPGRDC), KIADB Industrial Area, Tarabahalli, Devanagundi, Hoskote Taluk, Bengaluru Karnataka 560067, India
2. RAJU, Chinthalapati Sivakesava
Hindustan Petroleum Corporation Limited, Hindustan Petroleum Green R&D Center (HPGRDC), KIADB Industrial Area, Tarabahalli, Devanagundi, Hoskote Taluk, Bengaluru Karnataka 560067, India
3. BHARALI, Jitalaxmi
Hindustan Petroleum Corporation Limited, Hindustan Petroleum Green R&D Center (HPGRDC), KIADB Industrial Area, Tarabahalli, Devanagundi, Hoskote Taluk, Bengaluru Karnataka 560067, India
4. NARASIMHA, Sheshachala Srinivasa
Hindustan Petroleum Corporation Limited, Hindustan Petroleum Green R&D Center (HPGRDC), KIADB Industrial Area, Tarabahalli, Devanagundi, Hoskote Taluk, Bengaluru Karnataka 560067, India
5. RAO, Peddy Venkat Chalapathi
Hindustan Petroleum Corporation Limited, Hindustan Petroleum Green R&D Center (HPGRDC), KIADB Industrial Area, Tarabahalli, Devanagundi, Hoskote Taluk, Bengaluru Karnataka 560067, India
6. CHOUDARY, Nettem Venkateswarlu
Hindustan Petroleum Corporation Limited, Hindustan Petroleum Green R&D Center (HPGRDC), KIADB Industrial Area, Tarabahalli, Devanagundi, Hoskote Taluk, Bengaluru Karnataka 560067, India

Specification

Claims:1. A process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material, said process comprising the steps of:
a. contacting a compound of Formula I:

Formula I
wherein,R1 is substituted or unsubstituted C10 to C25 alkyl; R2 is independently substituted C1 to C10 alkyl; n is 1 to 3, with an aromatic solvent at a temperature in the range of 40-90°C to obtain a gelator solution;
b. contacting the gelator solution with a mixture of hydrophobic and hydrophilic material to obtain a gel comprising the hydrophobic material and a residue of hydrophilic material;
c. separating the gel from the residue of hydrophilic material;
d. heating the gel to a temperature in the range of 50-150°C to obtain the hydrophobic material and to reclaim the compound of Formula I.
2. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 1, wherein the hydrophobic material is a hydrocarbon.
3. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 1, wherein the hydrophobic material is oil selected from the group of synthetic oil, natural oil, crude oil, fuel oil, petroleum fractions, combinations thereof.
4. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 1, wherein the hydrophilic material is selected from the group consisting of water, polar solvents, sludge, and combinations thereof.
5. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 1, wherein the aromatic solvent is selected from the group consisting of toluene, xylene, ethylbenzene, petroleum fractions, and combinations thereof.
6. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 1, wherein the compound of Formula I weight % in the gelator solution is in the range of 0.1-20%.
7. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 1, wherein the mixture of hydrophobic and hydrophilic material is a biphasic mixture, wherein the biphasic mixture comprises of oil selected from the group of synthetic oil, natural oil, crude oil, fuel oil, petroleum fractions, and combinations thereof and water.
8. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 1, wherein the mixture of hydrophobic and hydrophilic material is a triphasic mixture, wherein the triphasic mixture comprises of oil selected from the group of synthetic oil, natural oil, crude oil, fuel oil, petroleum fractions, combinations thereof, water, and sludge.
9. A process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material, said process comprising the steps of:
a. contacting a compound of formula I:

Formula I
wherein, R1 is substituted or unsubstituted C10 to C25 alkyl; R2 is independently substituted C1 to C10 alkyl; n is 1 to 3, with a base and a hydrophilic solvent at a temperature in the range of 40-90°C to obtain a polar gelator solution;
b. contacting the polar gelator solution with a mixture of hydrophobic and hydrophilic material to obtain a gel comprising the hydrophilic material and a residue of hydrophobic material;
c. separating the residue of hydrophobic material from the gel to obtain the hydrophobic material; and
d. heating the gel to a temperature in the range of 50-100°C to reclaim the compound of Formula I.
10. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 9, wherein the hydrophobic material is a hydrocarbon.
11. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 9, wherein the hydrophobic material is oil selected from the group of synthetic oil, natural oil, crude oil, fuel oil, petroleum fractions, combinations thereof.
12. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 9, wherein the hydrophilic material is selected from the group consisting of water, polar solvents, sludge, and combinations thereof.
13. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 9, wherein the base is selected from the group consisting of sodium hydroxide, potassium hydroxide, and combinations thereof.
14. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 9, wherein the compound of Formula I weight % in the polar gelator solution is in the range of 0.1-20%..
15. The process for separating a hydrophobic material from a mixture of hydrophobic and hydrophilic material as claimed in claim 9, wherein the mixture of hydrophobic and hydrophilic material is a biphasic mixture, wherein the biphasic mixture comprises of oil and water.
16. A process for separating a oil from a mixture of oil and water, said process comprising the steps of:
a. contacting a compound of formula I:

Formula I
wherein, R1 is substituted or unsubstituted C10 to C25 alkyl; R2 is independently substituted C1 to C10 alkyl; n is 1 to 3, with toluene in a weight ratio of 1:99 at a temperature in the range of 60°C to obtain a gelator solution;
b. contacting the gelator solution with a mixture of oil and water to obtain a gel and a residue of aqueous material;
c. separating the gel from the residue of aqueous material; and
d. heating the gel to a temperature in the range of 120°C to obtain oil and to reclaim the compound of Formula I.
17. A process for separating a oil from a mixture of oil, water, and sludge, said process comprising the steps of:
a. contacting a compound of formula I:

Formula I
wherein,
R1 is substituted or unsubstituted C10 to C25 alkyl; R2 is independently substituted C1 to C10 alkyl; n is 1 to 3,
with toluene in a weight ratio of 1:99 at a temperature in the range of 60°C to obtain a gelator solution;
b. contacting the gelator solution with a mixture of oil, water, and sludge to obtain a gel and a residue of aqueous material;
c. separating the gel from the residue of aqueous material; and
d. heating the gel to a temperature in the range of 120°C to obtain oil and the gelator solution and to reclaim the compound of Formula I.
18. A process for separating oil from a mixture of oil and water, said process comprising the steps of:
a. contacting a compound of formula I:

Formula I
wherein,
R1 is substituted or unsubstituted C10 to C25 alkyl; R2 is independently substituted C1 to C10 alkyl; n is 1 to 3,
with sodium hydroxide and water at a temperature in the range of 60°C to obtain a polar gelator solution;
b. contacting the polar gelator solution with a mixture of oil and water to obtain a gel and a residue of oil;
c. separating the residue of oil from the gel to obtain the oil; and
d. heating the gel to a temperature in the range of 70°C to reclaim the compound of Formula I.
19. A process of containing oil spillage, said process comprising the steps of:
a. contacting a compound of Formula I:

Formula I
wherein,R1 is substituted or unsubstituted C10 to C25 alkyl; R2 is independently substituted C1 to C10 alkyl; n is 1 to 3, with an aromatic solvent at a temperature in the range of 40-90°C to obtain a gelator solution;
b. contacting the gelator solution with spilled oil on a surface to obtain a gel comprising the oil on the surface, wherein the spilled oil is selected from the group of synthetic oil, natural oil, crude oil, fuel oil, petroleum fractions, combinations thereof;
c. gathering the gel from surface;
d. heating the gel to a temperature in the range of 50-150°C to obtain the oil and to reclaim the compound of Formula I.
20. The process as claimed in 19, wherein the surface is land surface, sea water surface, or fresh water surface.
, Description:As Attached

Documents

Orders

Section Controller Decision Date

Application Documents

# Name Date
1 4503-MUM-2015-PROOF OF ALTERATION [21-01-2022(online)].pdf 2022-01-21
1 Form 5 [30-11-2015(online)].pdf 2015-11-30
2 4503-MUM-2015-RELEVANT DOCUMENTS [15-12-2021(online)].pdf 2021-12-15
2 Form 3 [30-11-2015(online)].pdf 2015-11-30
3 Description(Complete) [30-11-2015(online)].pdf 2015-11-30
3 4503-MUM-2015-IntimationOfGrant05-02-2020.pdf 2020-02-05
4 Form 18 [16-08-2016(online)].pdf 2016-08-16
4 4503-MUM-2015-PatentCertificate05-02-2020.pdf 2020-02-05
5 Other Patent Document [27-09-2016(online)].pdf 2016-09-27
5 4503-MUM-2015-FORM 3 [31-01-2020(online)].pdf 2020-01-31
6 CERTIFIED COPIES TRANSMISSION TO IB [17-11-2016(online)].pdf 2016-11-17
6 4503-MUM-2015-PETITION UNDER RULE 137 [31-01-2020(online)].pdf 2020-01-31
7 Form 3 [18-04-2017(online)].pdf 2017-04-18
7 4503-MUM-2015-Written submissions and relevant documents [31-01-2020(online)].pdf 2020-01-31
8 4503-MUM-2015-FORM 3 [03-04-2018(online)].pdf 2018-04-03
8 4503-MUM-2015-Correspondence to notify the Controller (Mandatory) [21-01-2020(online)].pdf 2020-01-21
9 4503-MUM-2015-Form 1-300916.pdf 2018-08-11
9 4503-MUM-2015-HearingNoticeLetter-(DateOfHearing-24-01-2020).pdf 2019-12-23
10 4503-MUM-2015-Correspondence-300916.pdf 2018-08-11
10 4503-MUM-2015-ORIGINAL UR 6(1A) FORM 26-131219.pdf 2019-12-16
11 4503-MUM-2015-CLAIMS [29-11-2019(online)].pdf 2019-11-29
11 4503-MUM-2015-FORM 3 [24-10-2018(online)].pdf 2018-10-24
12 4503-MUM-2015-FER.pdf 2019-05-29
12 4503-MUM-2015-FER_SER_REPLY [29-11-2019(online)].pdf 2019-11-29
13 4503-MUM-2015-FORM-26 [29-11-2019(online)].pdf 2019-11-29
13 4503-MUM-2015-PETITION UNDER RULE 137 [29-11-2019(online)].pdf 2019-11-29
14 4503-MUM-2015-Information under section 8(2) (MANDATORY) [29-11-2019(online)].pdf 2019-11-29
14 4503-MUM-2015-OTHERS [29-11-2019(online)].pdf 2019-11-29
15 4503-MUM-2015-Information under section 8(2) (MANDATORY) [29-11-2019(online)].pdf 2019-11-29
15 4503-MUM-2015-OTHERS [29-11-2019(online)].pdf 2019-11-29
16 4503-MUM-2015-FORM-26 [29-11-2019(online)].pdf 2019-11-29
16 4503-MUM-2015-PETITION UNDER RULE 137 [29-11-2019(online)].pdf 2019-11-29
17 4503-MUM-2015-FER_SER_REPLY [29-11-2019(online)].pdf 2019-11-29
17 4503-MUM-2015-FER.pdf 2019-05-29
18 4503-MUM-2015-CLAIMS [29-11-2019(online)].pdf 2019-11-29
18 4503-MUM-2015-FORM 3 [24-10-2018(online)].pdf 2018-10-24
19 4503-MUM-2015-Correspondence-300916.pdf 2018-08-11
19 4503-MUM-2015-ORIGINAL UR 6(1A) FORM 26-131219.pdf 2019-12-16
20 4503-MUM-2015-Form 1-300916.pdf 2018-08-11
20 4503-MUM-2015-HearingNoticeLetter-(DateOfHearing-24-01-2020).pdf 2019-12-23
21 4503-MUM-2015-Correspondence to notify the Controller (Mandatory) [21-01-2020(online)].pdf 2020-01-21
21 4503-MUM-2015-FORM 3 [03-04-2018(online)].pdf 2018-04-03
22 4503-MUM-2015-Written submissions and relevant documents [31-01-2020(online)].pdf 2020-01-31
22 Form 3 [18-04-2017(online)].pdf 2017-04-18
23 4503-MUM-2015-PETITION UNDER RULE 137 [31-01-2020(online)].pdf 2020-01-31
23 CERTIFIED COPIES TRANSMISSION TO IB [17-11-2016(online)].pdf 2016-11-17
24 4503-MUM-2015-FORM 3 [31-01-2020(online)].pdf 2020-01-31
24 Other Patent Document [27-09-2016(online)].pdf 2016-09-27
25 Form 18 [16-08-2016(online)].pdf 2016-08-16
25 4503-MUM-2015-PatentCertificate05-02-2020.pdf 2020-02-05
26 Description(Complete) [30-11-2015(online)].pdf 2015-11-30
26 4503-MUM-2015-IntimationOfGrant05-02-2020.pdf 2020-02-05
27 Form 3 [30-11-2015(online)].pdf 2015-11-30
27 4503-MUM-2015-RELEVANT DOCUMENTS [15-12-2021(online)].pdf 2021-12-15
28 Form 5 [30-11-2015(online)].pdf 2015-11-30
28 4503-MUM-2015-PROOF OF ALTERATION [21-01-2022(online)].pdf 2022-01-21

Search Strategy

1 ss4503_28-05-2019.pdf

ERegister / Renewals

3rd: 17 Apr 2020

From 30/11/2017 - To 30/11/2018

4th: 17 Apr 2020

From 30/11/2018 - To 30/11/2019

5th: 17 Apr 2020

From 30/11/2019 - To 30/11/2020

6th: 03 Dec 2020

From 30/11/2020 - To 30/11/2021