Title of invention: Manufacturing method of grain-oriented electrical steel sheet and grain-oriented electrical steel sheet
Technical field
[0001]
　The present invention relates to a method for manufacturing a grain-oriented electrical steel sheet and a grain-oriented electrical steel sheet.
　The present application claims priority based on Japanese Patent Application No. 2018-052900 filed in Japan on March 20, 2018, the contents of which are incorporated herein by reference.
Background technology
[0002]
　The grain-oriented electrical steel sheet contains about 2% by mass to 5% by mass of Si, and the orientation of the crystal grains of the steel sheet is highly integrated in the {110} <001> orientation called the Goss orientation. Since the grain-oriented electrical steel sheet has excellent magnetic characteristics, it is used, for example, as an iron core material for a static induction device such as a transformer.
[0003]
　The crystal orientation of grain-oriented electrical steel sheets can be controlled by utilizing a catastrophic grain growth phenomenon called secondary recrystallization. Further, in the heating process of the primary recrystallization annealing performed prior to the secondary recrystallization, the steel sheet is rapidly heated to increase the number of crystal grains in the Goss orientation having good magnetic characteristics after the primary recrystallization annealing. It has been confirmed that
[0004]
　Therefore, in order to improve the magnetic properties of grain-oriented electrical steel sheets, various rapid temperature rise conditions have been studied in the temperature rise process of primary recrystallization annealing.
[0005]
　For example, Patent Document 1 discloses a technique for uniforming the temperature distribution in the sheet width direction of a steel sheet and improving the product quality of the grain-oriented electrical steel sheet by defining the arrangement position of the rapid heating device in the continuous annealing device. Has been done. Patent Document 2 discloses a technique of suppressing temperature variation inside a steel sheet and suppressing iron loss variation of a grain-oriented electrical steel sheet by controlling the heat pattern and atmosphere in the temperature rise process of primary recrystallization annealing. There is. According to Patent Document 3, in the primary recrystallization annealing, the average particle size of the crystal grains after the secondary recrystallization and the deviation angle from the ideal orientation are strictly controlled by rapidly heating the steel sheet and then rapidly cooling it. The technology is disclosed. Patent Document 4 discloses a technique for reducing iron loss of grain-oriented electrical steel sheets by rapidly heating them at the heating stage of decarburization annealing.
Prior art literature
Patent documents
[0006]
Patent Document 1: Japanese Patent Application Laid-Open No. 2014-47411
Patent Document 2: Japanese Patent Application Laid-Open No. 2014-152392
Patent Document 3: Japanese Patent Application Laid-Open No. 7-268567
Patent Document 4: Japanese Patent Application Laid-Open No. 10-280041 Gazette
Outline of the invention
Problems to be solved by the invention
[0007]
　In the conventional technique as described above, unevenness (also referred to as wrinkles) may occur on the surface of the finally obtained grain-oriented electrical steel sheet depending on the conditions of rapid temperature rise in the primary recrystallization annealing. Since the grain-oriented electrical steel sheets having irregularities on the surface have gaps between the steel sheets when they are stacked, the space factor of the core material is lowered and the performance of the transformer is deteriorated. Although Patent Document 4 evaluates the surface shape of grain-oriented electrical steel sheets, the technique described in Patent Document 4 may not be able to sufficiently suppress the occurrence of finer irregularities.
[0008]
　The present invention has been made in view of the above problems, and manufactures a grain-oriented electrical steel sheet having a better surface shape when a rapid temperature rise is performed at a faster temperature rise rate than before by primary recrystallization annealing. It is an object of the present invention to provide a method for producing a new and improved grain-oriented electrical steel sheet, and a grain-oriented electrical steel sheet produced by the method. Another object of the present invention is to provide a method for manufacturing a grain-oriented electrical steel sheet in which the iron loss value is reduced even if the magnetic domain control treatment is not performed, and a grain-oriented electrical steel sheet manufactured by the manufacturing method.
Means to solve problems
[0009]
　The gist of the present invention is as follows.
[1] In the method for producing a directional electromagnetic steel sheet according to one aspect of the present invention, the
　component composition is mass%,
C: 0.02% or more and 0.10% or less,
Si: 2.5% or more and 4.5. %
Or less, Mn: 0.01% or more and 0.15% or less,
total of S and Se: 0.001% or more and 0.050% or less,
acid-soluble Al: 0.01% or more and 0.05% or less,
N: A step
of heating a slab containing 0.002% or more and 0.015% or less and the balance of Fe and impurities to 1280 ° C. to 1450 ° C. and hot rolling to obtain a hot-rolled steel sheet, and the
　above-mentioned step. A step of obtaining a cold-rolled steel sheet by subjecting the hot-rolled steel sheet to hot-rolling and then performing cold rolling once or two or more times of cold rolling sandwiching intermediate quenching,
　and a primary re- rolling of the cold-rolled steel sheet. A step of crystallizing, a step of applying
　a quenching separator containing MgO to the surface of the cold-rolled steel sheet after primary recrystallizing, and then performing a finish annealing to obtain a
　finish annealed sheet, and an insulation on the finish annealed sheet. Including the step of applying flattening and annealing after applying the coating,
　In the temperature raising process of the primary recrystallization annealing, the average temperature rising rate V (° C./s) in the temperature range of 550 ° C. to 700 ° C. is 400 ° C./s or more, and the temperature range rises from 550 ° C. to 700 ° C. T / L (° C./mm), which is the ratio of the amount of temperature rise T (° C.) in a series of temperature rise processes including temperature to the heating length L (mm) in the series of temperature rise processes, is 0.1 ≦ T. / L ≦ 4.0, and the tension S (N / mm 2 ) applied in the sheet-passing direction of the cold-rolled steel sheet is 1.96 ≦ S ≦ (19.6-1.96 × T / L). If there is and V ≦ 1000, the tension S is 1.96 ≦ S ≦ (25.5-0.0137 × V), and if V> 1000, the tension S is 1.96 ≦ S ≦ 11. It is 8.8.
[2] The grain-oriented electrical steel sheet according to another aspect of the present invention has a
　silicon steel sheet, a
　forsterite film arranged on the silicon steel sheet, and
　an insulating film arranged on the forsterite film. , The
　silicon steel sheet has a component composition of mass%,
Si: 2.5% or more and 4.5% or less,
Mn: 0.01% or more and 0.15% or less,
and total of S and Se: 0% or more and 0. It contains .005% or less,
acid-soluble Al: 0% or more and 0.01% or less, and
N: 0% or more and 0.005% or less,
and the balance is
　composed of Fe and impurities, and the secondary recrystallization of the silicon steel sheet. The grain-
　oriented electrical steel sheet has an average grain size of 10 mm or more and 50 mm or less .
　　The plate thickness is 0.15 mm or more and 0.23 mm or less, the
　　iron loss Wp is W 17/50 , 0.800 W / kg or less, and
　　the abundance ratio of wrinkles with a steepness of 0.01 or more is 0 in the plate width direction. The number / m or more and 10 pieces / m or less, and the
　　magnetic flux density B8 value is 1.930T or more.
Effect of the invention
[0010]
　According to the above aspect according to the present invention, when a rapid temperature rise is performed at a rate of temperature rise faster than that of the prior art by primary recrystallization annealing, the surface shape is better and the magnetic domain control treatment is performed. It is possible to provide a grain-oriented electrical steel sheet having a reduced iron loss value and a method for manufacturing the same.
A brief description of the drawing
[0011]
FIG. 1 is a diagram showing a specific example of a heat pattern in the heating process of primary recrystallization annealing.
FIG. 2 is a diagram showing another specific example of a heat pattern in the heating process of primary recrystallization annealing.
FIG. 3 is a diagram showing another specific example of a heat pattern in the heating process of primary recrystallization annealing.
FIG. 4 is a diagram showing another specific example of a heat pattern in the heating process of primary recrystallization annealing.
[Fig. 5] Fig. 5 is a diagram showing a cross-sectional curve of a grain-oriented electrical steel sheet for explaining how to obtain steepness.
FIG. 6 is a diagram plotting the results shown in Table 1 with the temperature rising rate V on the horizontal axis and the steel plate tension S on the vertical axis.
FIG. 7 is a diagram plotting the results shown in Table 1 with the ratio T / L on the horizontal axis and the steel plate tension S on the vertical axis.
Mode for carrying out the invention
[0012]
　Preferred embodiments of the present invention will be described in detail below with reference to the accompanying drawings. However, the present invention is not limited to the configuration disclosed in the present embodiment, and various modifications can be made without departing from the spirit of the present invention. Further, in the present specification and the drawings, the components having substantially the same functional configuration are designated by the same reference numerals to omit duplicate description.
[0013]
　The present inventors have obtained the following findings as a result of diligent studies on a grain-oriented electrical steel sheet and a method for manufacturing the grain-oriented electrical steel sheet in order to improve the magnetic properties of the grain-oriented electrical steel sheet.
[0014]
　Specifically, in the directional electromagnetic steel plate, the present inventors rapidly raise the temperature in the temperature range of 550 ° C. to 700 ° C. at an average temperature rise rate of 400 ° C./s or more in the temperature raising process of primary recrystallization annealing. As a result, it was found that after the primary recrystallization annealing, the number of Goss-oriented crystal grains having good magnetic properties (also referred to as Goss-oriented grains) increases. Further, the present inventors have found that the faster the average temperature rise rate in the rapid temperature rise of the primary recrystallization annealing, the more the Goss orientation grains after the primary recrystallization, and the iron loss value of the grain-oriented electrical steel sheet finally obtained. Was found to be reduced. If the average rate of temperature rise in the rapid temperature rise of the primary recrystallization annealing is increased, the degree of accumulation of crystal grains in the ideal Goss orientation after the secondary recrystallization can be improved, and the diameter of the secondary recrystallized grains is reduced. Therefore, it is possible to reduce the iron loss value of the grain-oriented electrical steel sheet without performing the magnetic domain control process.
[0015]
　On the other hand, as a result of the study by the present inventors, it has been clarified that the shape of the steel sheet changes significantly depending on the conditions of rapid temperature rise in the temperature raising process of the primary recrystallization annealing. Specifically, it is clear that unevenness (wrinkles) may occur on the surface of the steel sheet depending on the magnitude of the tension applied in the steel sheet passing direction (hereinafter, also referred to as steel sheet tension) at the time of rapid temperature rise. It became. In such a case, in the manufacture of a transformer, when the grain-oriented electrical steel sheets are stacked, a gap is generated between the steel sheets, so that the space factor of the iron core material decreases and the iron loss of the transformer increases. Resulting in.
[0016]
　The reason why the shape of the steel sheet fluctuates due to the rapid temperature rise in the primary recrystallization annealing is that, for example, the thermal expansion due to the rapid temperature rise causes a rapid rise with respect to the width of the steel sheet on the low temperature side before the rapid temperature rise. It is conceivable that the width of the steel plate on the high temperature side after warming will change. In such a case, if the steel plate tension is excessively increased, the steel plate on the high temperature side stretched by thermal expansion contracts greatly in the plate width direction, so that there is a steep shape difference between the steel plate on the low temperature side and the steel plate on the high temperature side. Is considered to occur and wrinkles are formed. Therefore, in order to suppress the occurrence of wrinkles in the heating process of primary recrystallization annealing, it is important to prevent the steel sheet tension from becoming excessively large.
[0017]
　Further, the present inventors have found that the upper limit of the steel sheet tension that does not cause wrinkles in the grain-oriented electrical steel sheet depends on the rate of rapid temperature rise in the primary recrystallization annealing. Specifically, the present inventors have found that the upper limit of the steel sheet tension becomes smaller as the rate of rapid temperature rise increases. This is because the higher the rate of temperature rise of the rapid temperature rise, the larger the temperature difference between the steel sheet on the low temperature side before the rapid temperature rise and the steel plate on the high temperature side after the rapid temperature rise, which is a reaction of thermal expansion. It is considered that this is because the contraction of the
[0018]
　Further, the present inventors, in the temperature raising process including rapid temperature rise in the temperature range of 550 ° C. to 700 ° C., the temperature rising amount T (the temperature at the start of the temperature rising process and the temperature at the end of the temperature rising process). It was found that the relationship between the heating length L (the length of the steel sheet from the start position of the temperature rise process to the end position of the temperature rise process) has a great influence on the shape of the steel sheet.
[0019]
　Specifically, the present inventors have found that the smaller the temperature rise amount T and the longer the heating length L, the less wrinkled the grain-oriented electrical steel sheet can be obtained. That is, the present inventors have found that the smaller the T / L, which is the value obtained by dividing the heating amount T by the heating amount L, the better the shape of the grain-oriented electrical steel sheet can be obtained. This is because T / L represents the temperature change rate of the steel sheet in the through plate direction, so that the larger the T / L, the larger the temperature difference between the low temperature side steel sheet and the high temperature side steel sheet, resulting in thermal expansion. It is considered that wrinkles are likely to occur on the surface of the steel sheet due to the influence of.
[0020]
　The present inventors have come up with the present invention by considering the above findings. One embodiment of the present invention has the following configurations.
[0021]
　A method for producing a directional electromagnetic steel sheet, in which the component composition is mass%,
C: 0.02% or more and 0.10% or less,
Si: 2.5% or more and 4.5% or less,
Mn: 0.01. % Or more and 0.15% or less,
total of S and Se: 0.001% or more and 0.050% or less,
acid-soluble Al: 0.01% or more and 0.05% or less,
N: 0.002% or more and 0.015 A
step of obtaining a hot-rolled steel sheet by heating a slab containing % or less and the balance of Fe and impurities to 1280 ° C. to 1450 ° C. and performing hot rolling,
　and hot-rolling the hot-rolled steel sheet. A step of obtaining a cold-rolled steel sheet by performing one cold-rolling or two or more cold-rolling sandwiching an intermediate quenching, a
　step of performing a primary recrystallizing quenching on the cold-rolled steel sheet, and a
　primary A step of applying a quenching separator containing MgO to the surface of the cold-rolled steel sheet after recrystallizing and then performing finish annealing to obtain a
　finished annealed sheet, and applying an insulating film to the finished annealed sheet and then flattening it. In the 　heating process of the primary recrystallizing annealing
including the step of
performing the rolling, the average heating rate V (° C./s) in the temperature range of 550 ° C to 700 ° C is 400 ° C / s or more, and the temperature is 550 ° C. T / L (° C.), which is the ratio of the amount of temperature rise T (° C.) in a series of temperature rise processes including temperature rise in the temperature range of about 700 ° C. to the heating length L (mm) in the series of temperature rise processes. / Mm) is 0.1 ≦ T / L ≦ 4.0, and the tension S (N / mm 2) applied in the passing direction of the cold-rolled steel sheet. ) Is 1.96 ≦ S ≦ (19.6-1.96 × T / L) and V ≦ 1000, the tension S is 1.96 ≦ S ≦ (25.5-0.0137 ×). V), and when V> 1000, the tension S is 1.96 ≦ S ≦ 11.8.
[0022]
　In the grain- oriented electrical steel sheet manufactured by the above manufacturing method, the iron loss Wp when the magnetic domain control treatment is not applied is W 17/50 , which is 0.800 W / kg or less. In the manufacturing method according to the present embodiment, the grain-oriented electrical steel sheet can be efficiently reduced in iron loss by rapidly raising the temperature during the primary recrystallization annealing.
[0023]
　Further, in the manufacturing method according to the present embodiment, as described above, the influence of thermal expansion of the steel sheet is reduced by controlling the steel sheet tension S, the average temperature rising rate V and T / L in a complex and indivisible manner. Can be done. Therefore, the abundance ratio of wrinkles having a steepness of 0.01 or more in the plate width direction can be set to 0 / m or more and 10 / m or less.
[0024]
　Hereinafter, a method for manufacturing a grain-oriented electrical steel sheet according to the present embodiment having the above-mentioned characteristics will be described more specifically.
[0025]
　First, the component composition of the slab used in the method for producing grain-oriented electrical steel sheets according to the present embodiment will be described. In the following, unless otherwise specified, the notation "%" indicates "mass%". The numerical limitation range described below includes the lower limit value and the upper limit value. Numerical values ​​indicated as "super" and "less than" do not include the value in the numerical range.
[0026]
　The content of C (carbon) is 0.02% or more and 0.10% or less. C has various roles, but when the C content is less than 0.02%, the crystal grain size becomes excessively large when the slab is heated, which increases the iron loss value of the grain-oriented electrical steel sheet. Let me. When the C content is more than 0.10%, the decarburization time becomes long during decarburization after cold rolling, and the manufacturing cost increases. Further, when the C content is more than 0.10%, decarburization tends to be incomplete, and magnetic aging may occur in the grain-oriented electrical steel sheet. Therefore, the content of C is 0.02% or more and 0.10% or less. Preferably, it is 0.05% or more, or 0.09% or less.
[0027]
　The content of Si (silicon) is 2.5% or more and 4.5% or less. Si increases the electrical resistance of the steel sheet to reduce the eddy current loss of the grain-oriented electrical steel sheet and reduce the iron loss. When the Si content is less than 2.5%, it becomes difficult to sufficiently suppress the eddy current loss in the grain-oriented electrical steel sheet. When the Si content is more than 4.5%, the workability of the grain-oriented electrical steel sheet is lowered. Therefore, the Si content is 2.5% or more and 4.5% or less. Preferably, it is 2.7% or more, or 4.0% or less.
[0028]
　The content of Mn (manganese) is 0.01% or more and 0.15% or less. Mn forms MnS, MnSe, and the like, which are inhibitors that influence secondary recrystallization. When the Mn content is less than 0.01%, the absolute amounts of MnS and MnSe that cause secondary recrystallization are insufficient, and the orientation cannot be preferably controlled. If the Mn content is more than 0.15%, it becomes difficult to dissolve Mn during slab heating, which is not preferable. Further, when the Mn content is more than 0.15%, the precipitation sizes of the inhibitors MnS and MnSe tend to be coarse, the optimum size distribution as the inhibitor is impaired, and the inhibitor cannot be preferably controlled. Therefore, the Mn content is 0.01% or more and 0.15% or less. Preferably, it is 0.03% or more, or 0.13% or less.
[0029]
　The total content of S (sulfur) and Se (selenium) is 0.001% or more and 0.050% or less. S and Se form an inhibitor together with Mn described above. Both S and Se may be contained in the slab, but at least one of them may be contained in the slab. When the total content of S and Se is out of the above range, a sufficient inhibitory effect cannot be obtained and the orientation cannot be preferably controlled. Therefore, the total contents of S and Se are 0.001% or more and 0.050% or less. Preferably, it is 0.005% or more, or 0.040% or less.
[0030]
　The content of acid-soluble Al (acid-soluble aluminum) is 0.01% or more and 0.05% or less. Acid-soluble Al forms the inhibitors required to produce grain-oriented electrical steel sheets with high magnetic flux density. When the content of the acid-soluble Al is less than 0.01%, the inhibitor strength is insufficient and the orientation cannot be preferably controlled. When the content of the acid-soluble Al is more than 0.05%, AlN precipitated as an inhibitor becomes coarse, the inhibitor strength decreases, and the orientation cannot be preferably controlled. Therefore, the content of acid-soluble Al is 0.01% or more and 0.05% or less. Preferably, it is 0.02% or more, or 0.04% or less.
[0031]
　The content of N (nitrogen) is 0.002% or more and 0.015% or less. N forms the inhibitor AlN together with the acid-soluble Al described above. When the content of N is out of the above range, a sufficient inhibitory effect cannot be obtained and the orientation cannot be preferably controlled. Therefore, the content of N is 0.002% or more and 0.015% or less. Preferably, it is 0.005% or more, or 0.012% or less.
[0032]
　The rest of the slab used in the production of grain-oriented electrical steel sheets according to this embodiment is Fe and impurities. However, in addition to the above-mentioned elements, the slab used for producing the grain-oriented electrical steel sheet according to the present embodiment is Cu as an element for stabilizing secondary recrystallization in place of a part of Fe which is the remainder. , Sn, Ni, Cr and Sb may be contained in any one or more. It is not necessary to limit the lower limit of these selective elements, and the lower limit may be 0%. The content of each of these selective elements may be 0.01% or more and 0.30% or less. When the content of even one of these selected elements is 0.01% or more, the effect of stabilizing secondary recrystallization can be sufficiently obtained, and the iron loss value of the grain-oriented electrical steel sheet is further reduced. be able to. If the content of even one of these selected elements exceeds 0.30%, the effect of stabilizing secondary recrystallization is saturated and the production cost increases, which is not preferable.
[0033]
　A slab is formed by casting molten steel adjusted to the composition of the components described above. The slab casting method is not particularly limited. For example, the slab may be cast by a casting method such as a normal continuous casting method, an ingot method, or a thin slab casting method. In the case of continuous casting, the steel may be once cooled to a low temperature (for example, room temperature), reheated, and then hot-rolled, or the steel immediately after casting (casting slab) may be used. It may be continuously hot rolled. Further, in research and development, even when a steel ingot is formed in a vacuum melting furnace or the like, the same effect as that when a slab is formed has been confirmed with respect to the above-mentioned component composition.
[0034]
　Subsequently, the slab is heated to 1280 ° C. or higher to dissolve the inhibitor component in the slab. When the heating temperature of the slab is less than 1280 ° C., it becomes difficult to sufficiently dissolve inhibitor components such as MnS, MnSe, and AlN, and preferable orientation control cannot be performed. The upper limit of the heating temperature of the slab at this time may be 1450 ° C. or lower from the viewpoint of equipment protection.
[0035]
　The heated slab is hot-rolled to obtain a hot-rolled steel sheet. The thickness of the hot-rolled steel sheet may be, for example, 1.8 mm or more and 3.5 mm or less. When the thickness of the hot-rolled steel sheet is less than 1.8 mm, the temperature of the steel sheet after hot rolling becomes low, and the amount of AlN precipitated in the steel sheet increases, which destabilizes secondary recrystallization and finally becomes unstable. The magnetic characteristics of the obtained directional electromagnetic steel sheet having a thickness of 0.23 mm or less may deteriorate. When the thickness of the hot-rolled steel sheet exceeds 3.5 mm, the rolling load in the cold rolling process may be large.
[0036]
　A cold-rolled steel sheet is obtained by subjecting the hot-rolled steel sheet to hot-rolled sheet annealing and then performing one cold-rolling or a plurality of cold-rolling sandwiching an intermediate annealing. When the hot-rolled steel sheet is rolled by a plurality of cold rollings sandwiching the intermediate annealing, it is possible to omit the hot-rolled sheet annealing in the previous stage. However, since the shape of the steel sheet can be improved by performing hot-rolled sheet annealing, the possibility of the steel sheet breaking during cold rolling can be reduced. Therefore, even when the hot-rolled steel sheet is cold-rolled a plurality of times with intermediate annealing sandwiched between them, it is preferable to perform hot-rolled sheet annealing in the preceding stage. The conditions for hot-rolled sheet annealing are not particularly limited, but general conditions may be used, and in the case of continuous annealing, the hot-rolled steel sheet after hot rolling is uniformly heated at 750 to 1200 ° C. for 10 seconds to 10 minutes. In the case of box annealing, soaking may be performed at 650 to 950 ° C. for 30 minutes to 24 hours.
[0037]
　The steel sheet may be heat-treated at about 300 ° C. or lower between cold rolling passes, between rolling roll stands, or during rolling. By performing the heat treatment, the magnetic properties of the finally obtained grain-oriented electrical steel sheet can be further improved. The hot-rolled steel sheet may be rolled by cold rolling three or more times, but since cold rolling a large number of times increases the manufacturing cost, the hot-rolled steel sheet is cold-rolled once or twice. It is preferably rolled by rolling.
[0038]
　The cold-rolled steel sheet is rapidly heated and then decarburized and annealed. These processes (rapid heating and decarburization annealing) are also referred to as primary recrystallization annealing and are preferably carried out continuously. By the primary recrystallization annealing, in the cold-rolled steel sheet, the Goss orientation grains before the secondary recrystallization can be increased and the diameter of the secondary recrystallized grains after the secondary recrystallization can be reduced.
[0039]
　In the production method according to the present embodiment, the average temperature rise rate V in the temperature range of 550 ° C. to 700 ° C. is set to 400 ° C./s or more in the temperature rise process in the primary recrystallization annealing. By performing the above-mentioned rapid temperature rise in the temperature raising process in the primary recrystallization annealing, the Goss orientation grains before the secondary recrystallization of the cold-rolled steel sheet are further increased, and the secondary recrystallization after the secondary recrystallization is performed. The diameter of the crystal grains can be reduced.
[0040]
　When the average heating rate V in the temperature range of 550 ° C to 700 ° C is 700 ° C / s or more, the Goss directional grains before the secondary recrystallization can be further increased, so that the finally obtained directional electromagnetic steel is obtained. The iron loss of the steel sheet can be further reduced. On the other hand, when the average heating rate V is less than 400 ° C./s, it becomes difficult to form sufficient Goss directional grains to reduce the crystal grains after secondary recrystallization, and the direction finally obtained. The iron loss of the grain-oriented electrical steel sheet increases. The upper limit of the average heating rate V is not particularly limited, but may be, for example, 3000 ° C./s from the viewpoint of equipment and manufacturing cost.
[0041]
　Here, the heat pattern in the heating process of the primary recrystallization annealing will be described with reference to FIGS. 1 to 4. 1 to 4 are diagrams showing specific examples of heat patterns in the heating process of primary recrystallization annealing.
[0042]
　As shown in FIG. 1, there may be only one heating device 10 that raises the temperature of the steel sheet 1 from 550 ° C to 700 ° C. In such a case, the average temperature rise rate V rises from the point where the temperature rise is started (the temperature rise start point A) in the temperature rise process (heating device 10) including the temperature rise from 550 ° C to 700 ° C. Let it be the average value of the temperature rise rate up to the point where the temperature ends (the temperature rise end point B).
[0043]
　As shown in FIG. 2, there may be a plurality of heating devices 21 and 22 for raising the temperature of the steel sheet 1 from 550 ° C to 700 ° C. In such a case, the average temperature rise rate V is increased in the temperature rise process including 550 ° C. (including the temperature rise from a temperature range of less than 550 ° C. to a temperature range of more than 550 ° C.) in the temperature riser 21. From the starting point (heating start point A), the temperature is raised in the temperature raising process of the temperature raising device 22 including 700 ° C. (including the temperature rise from a temperature range below 700 ° C to a temperature range above 700 ° C). Is the average value of the temperature rise rate up to the point where the temperature rise is completed (the temperature rise end point B).
[0044]
　That is, the temperature rise start point A is a point (that is, a heat pattern) in which the temperature of the steel sheet 1 changes from a state in which the temperature of the steel sheet 1 decreases to a state in which the temperature of the steel sheet 1 increases on the low temperature side of the temperature rise process including 550 ° C. The point where the minimum value is taken in the graph). Further, the temperature rising end point B is a point (that is, a heat pattern) in which the temperature of the steel sheet 1 changes from a state in which the temperature of the steel sheet 1 rises to a state in which the temperature of the steel sheet 1 decreases on the high temperature side of the temperature rising process including 700 ° C. The point that takes the maximum value in the graph).
[0045]
　However, as shown in FIG. 3, when the temperature of the steel sheet 1 continues to rise even on the lower temperature side than the temperature raising process including 550 ° C. due to the arrangement of the plurality of temperature raising devices 31 and 32, the temperature rising start point A May be a point (point A in FIG. 3) where the rate of change of the temperature rising rate is the maximum with a positive value at 550 ° C. or lower. Further, as shown in FIG. 4, when the temperature of the steel sheet 1 continues to rise even on the higher temperature side than the temperature raising process including 700 ° C. due to the arrangement of the plurality of temperature raising devices 41 and 42, the temperature rising end point B May be a point (point B in FIG. 4) where the rate of change of the temperature rising rate becomes the minimum with a negative value in the temperature range of 700 ° C. or higher.
　That is, the temperature rise start point A and the temperature rise end point B may not coincide with the inlet and outlet of the temperature riser depending on the heater configuration, heating capacity, arrangement, and the like of the temperature riser.
[0046]
　In the heating process of the primary recrystallization annealing, the heat pattern in the temperature range of 550 ° C. to 700 ° C. is not particularly limited, and the heat pattern between the heating devices when there are a plurality of heating devices is not particularly limited. The heating method or the heating device in the heating process is also not particularly limited, and for example, an energization heating method or an induction heating method may be used. In the temperature raising process of the primary recrystallization annealing, the heat pattern in the temperature range other than the temperature range of 550 ° C. to 700 ° C. is not particularly limited, but before the temperature rising process including the temperature range of 550 ° C. to 700 ° C. It is not preferable that the temperature is 550 ° C. or higher because the effect of rapid temperature rise in the primary recrystallization annealing is reduced.
[0047]
　Here, the method for discriminating between the temperature rise start point A and the temperature rise end point B is not particularly limited, but for example, by measuring the temperature of the steel plate outside the temperature riser and inside the temperature riser using a radiation thermometer or the like. It is possible to discriminate. The method for measuring the temperature of the steel sheet is not particularly limited.
[0048]
　When it is difficult to measure the temperature of the steel plate and it is difficult to distinguish between the temperature rise start point A and the temperature rise end point B, the thickness of the steel plate through which each heat pattern of the temperature rise process and the cooling process is passed is passed. The temperature rise start point A and the temperature rise end point B may be estimated by analogy with the above. Further, the temperature on the inlet side of the temperature riser and the temperature on the exit side of the temperature riser in the temperature rise process may be set as the temperature rise start point A and the temperature rise end point B.
[0049]
　In the present embodiment, T / L (° C./mm) which is a ratio of the amount of temperature rise T (° C.) in the temperature rise process including rapid temperature rise in the temperature range of 550 ° C. to 700 ° C. and the heating length L (mm). ) Is controlled to 0.1 ≦ T / L ≦ 4.0. Here, the temperature rise amount T represents the amount of temperature rise from the above-mentioned temperature rise start point A to the temperature rise end point B, and the heating length L means the temperature rise end from the above-mentioned temperature rise start point A. It represents the length of the steel plate passing through the heating device up to the point B. Therefore, when there are a plurality of heating devices, the heating length L also includes the length between the heating devices.
[0050]
　T / L, which is the ratio of the amount of temperature rise T to the length L of heating, represents the rate of temperature change in the longitudinal direction of the steel sheet in the primary recrystallization annealing. Therefore, the larger the T / L, the larger the difference in plate thickness due to thermal expansion between the steel plate on the low temperature side and the steel plate on the high temperature side. When the T / L is large, the shrinkage of the plate width of the steel plate on the high temperature side becomes larger than that of the steel plate on the low temperature side, so that it is considered that wrinkles are likely to occur on the surface of the steel plate. Therefore, it is considered that the larger the T / L, the more the shape of the grain-oriented electrical steel sheet changes and the wrinkles on the surface of the grain-oriented electrical steel sheet increase.
[0051]
　The upper limit of T / L capable of suppressing the proportion of wrinkles existing on the surface of the grain-oriented electrical steel sheet is 4.0 ° C./mm as can be seen from Examples described later. Preferably, T / L is 2.7 ° C./mm or less.
[0052]
　The smaller the temperature rise amount T and the longer the heating length L, the smaller the T / L, so that it is possible to obtain a grain-oriented electrical steel sheet having less wrinkles and a good surface shape. However, T / L has a lower limit from the viewpoint of equipment restrictions. This is because it is important to rapidly raise the temperature at least from 550 ° C to 700 ° C in order to improve the magnetic properties of the grain-oriented electrical steel sheet by the rapid temperature rise in the primary recrystallization annealing, and the amount of temperature rise T is reduced. This is because there is a limit to this. Further, the longer the heating length L, the larger the installation space for the temperature raising device, and the more difficult it becomes to increase the speed of passing the steel sheet. Therefore, the lower limit of T / L is 0.1 ° C./mm from the viewpoint of equipment restrictions. Preferably, T / L is 0.2 ° C./mm or higher.
[0053]
　The directional electromagnetic steel sheet also depends on the magnitude of the tension S (N / mm 2 ) (that is, the steel sheet tension S (N / mm 2 )) applied in the sheet passing direction of the steel sheet in the process of raising the temperature of the primary recrystallization annealing. The shape of is changed. This is because when the steel sheet tension S is excessively large, the heat-expanded steel sheet tends to shrink in the width direction during the rapid temperature rise of the primary recrystallization annealing, so that wrinkles are formed on the surface of the grain-oriented electrical steel sheet. It is thought that this is because it is stored. Therefore, the upper limit of the steel sheet tension S that does not cause wrinkles in the grain-oriented electrical steel sheet depends on the average heating rate V (° C./s) in the rapid temperature rise. Further, the magnitude of the effect of increasing the Goss directional grains by the rapid temperature rise also varies depending on the magnitude of the steel plate tension S applied to the steel sheet during the rapid temperature rise of the primary recrystallization annealing. Therefore, the magnitude of the steel sheet tension S during the rapid temperature rise of the primary recrystallization annealing is affected by the average temperature rise rate V (° C./s) during the rapid temperature rise.
[0054]
　Specifically, the steel sheet tension S (N / mm 2 ) is 1.96 ≦ S ≦ (19.6-1.96 × T ) with respect to the average temperature rising rate V (° C./s) in the temperature rising process. / L) and the steel plate tension S is 1.96 ≦ S ≦ (25.5-0.0137 × V) when V ≦ 1000, and 1.96 ≦ S ≦ when V> 1000. It is 11.8. The steel plate tension S is an average value of the steel plate tension in the temperature raising process including the rapid temperature rise in the temperature range of 550 ° C. to 700 ° C.
[0055]
　When the steel sheet tension S exceeds the upper limit value depending on the average heating rate V, the tension applied in the sheet-passing direction deteriorates the shape of the finally obtained grain-oriented electrical steel sheet and increases the wrinkles on the surface. Further, the tension applied in the sheet-passing direction of the steel sheet disturbs the texture of the crystal grains generated by the primary recrystallization, and the orientation cannot be preferably controlled. On the other hand, when the steel plate tension S is less than 1.96 N / mm 2 , the steel plate in the through plate meanders, which may cause breakage of the steel plate and damage to the equipment.
[0056]
　The rapidly heated steel sheet is decarburized and annealed at a temperature of 900 ° C. or lower for 30 seconds to 10 minutes in a moist atmosphere containing hydrogen and nitrogen. In the primary recrystallization annealing consisting of rapid temperature rise and decarburization annealing, the cold-rolled steel sheet may be subjected to reduction annealing following decarburization annealing for the purpose of improving magnetic properties and coating properties. The rapid heating step and the decarburization annealing step may be separate steps, but may be performed continuously from the viewpoint of omitting the manufacturing process line. When rapid temperature rise and decarburization annealing are continuously performed, the rapid temperature rise step and decarburization annealing step may be connected by a throat or the like.
[0057]
　An annealing separator containing MgO as a main component is applied to the cold-rolled steel sheet after primary recrystallization annealing, and then finish annealing is performed to obtain a finish annealing sheet. In finish annealing, secondary recrystallization occurs. Further, after the annealing separating agent is applied, the finish annealing is performed to form a forsterite film on the surface of the silicon steel sheet (cold-rolled steel sheet).
　Finish annealing may be performed by holding a coiled cold-rolled steel sheet to which an annealing separator has been applied for 20 hours or more at a temperature of 800 ° C. to 1000 ° C. using, for example, a batch type heating furnace or the like. Good. Further, in order to further reduce the iron loss value of the finally obtained grain-oriented electrical steel sheet, a purification treatment may be performed in which the coiled finish annealed plate is heated to a temperature of about 1200 ° C. and then held. ..
[0058]
　The average heating rate in the process of raising the temperature of the finish annealing is not particularly limited, and general finish annealing conditions may be used. For example, the average heating rate in the temperature raising process of finish annealing may be 5 ° C./h to 100 ° C./h from the viewpoint of productivity and general equipment restrictions. Further, the temperature raising process of the finish annealing may be performed by another known heat pattern. The atmospheric gas composition in the finish annealing is not particularly limited. In the secondary recrystallization process, it may be a mixed gas of nitrogen and hydrogen. It may be a dry atmosphere or a moist atmosphere. The atmosphere gas composition of the purification treatment may be dry hydrogen gas.
[0059]
　After the finish annealing, an insulating film containing, for example, aluminum phosphate and colloidal silica as main components is applied to the surface of the finish annealed plate for the purpose of imparting insulation and tension to the finish annealed plate. After that, flattening annealing is performed for the purpose of baking the insulating film and flattening the shape of the steel sheet deformed by finish annealing. The flattening annealing may be performed under known conditions, and may be performed, for example, by holding the finished annealing plate in a temperature range of 800 ° C. to 950 ° C. for 10 seconds or longer. The components of the insulating coating are not particularly limited as long as the finished annealed plate is provided with insulating properties and tension.
[0060]
　The grain-oriented electrical steel sheet according to the present embodiment can be manufactured by the manufacturing method described above. The grain-oriented electrical steel sheets according to the present embodiment manufactured by such a manufacturing method are as follows.
[0061]
　A
　grain-
　oriented electrical steel sheet having a silicon steel sheet, a forsterite film arranged on the silicon steel sheet, and an insulating film arranged on the forsterite film, the
　silicon steel sheet has a component composition of mass%.
in, Si: 2.5% to 4.5% or
less, Mn: 0.01% or more and 0.15% or less,
the total of S and Se: 0% or more than 0.005%,
acid-soluble Al: 0% or more It contains 0.01% or less and
N: 0% or more and 0.005% or less,
the balance is
　composed of Fe and impurities, and the average particle size of the secondary recrystallized grains of the silicon steel sheet is 10 mm or more and 50 mm or less. The grain-
　oriented electrical steel sheet has a
　　thickness of 0.15 mm or more and 0.23 mm or less, an
　　iron loss Wp of W 17/50 , 0.800 W / kg or less, and a
　　steepness of 0.01 or more. The abundance ratio of is 0 pieces / m or more and 10 pieces / m or less in the plate width direction, and the
　　magnetic flux density B8 value is 1.930T or more.
[0062]
　In order to reduce the iron loss in the grain-oriented electrical steel sheet according to the present embodiment without performing the magnetic domain control treatment, the Si and Mn contents in the component composition contained in the silicon steel sheet of the grain-oriented electrical steel sheet should be adjusted. It is important to control.
[0063]
　Si reduces the eddy current loss that forms part of the iron loss by increasing the electrical resistance of the steel sheet. It is desirable that Si is contained in the silicon steel sheet in the range of 2.5% or more and 4.5% or less in mass%. Preferably, it is 2.7% or more, or 4.0% or less. When the Si content is less than 2.5%, it becomes difficult to suppress the eddy current loss in the grain-oriented electrical steel sheet. When the Si content is more than 4.5%, the workability of the grain-oriented electrical steel sheet is lowered.
[0064]
　Mn forms MnS and MnSe, which are inhibitors that influence secondary recrystallization. It is desirable that Mn is contained in the silicon steel sheet in the range of 0.01% or more and 0.15% or less in mass%. Preferably, it is 0.03% or more, or 0.13% or less. When the Mn content is less than 0.01%, the absolute amounts of MnS and MnSe that cause secondary recrystallization are insufficient, and the orientation cannot be preferably controlled. When the Mn content is more than 0.15%, it becomes difficult to dissolve Mn during slab heating, and the precipitation size of the inhibitor becomes coarse, so that the optimum size distribution of the inhibitor is impaired, and the inhibitor is preferably used. I can't control it.
[0065]
　The rest of the silicon steel plate according to this embodiment is Fe and impurities. However, instead of a part of Fe which is the balance, C, S, Se, acid-soluble Al and N, and any of Cu, Sn, Ni, Cr and Sb as an element for stabilizing secondary recrystallization. Or may contain one or more. It is not necessary to limit the lower limit of these selective elements, and the lower limit may be 0%.
[0066]
　The C content is preferably low, but may be 0.0050% or less. If the C content is more than 0.0050% even after decarburization annealing, magnetic aging may occur and the magnetic properties of grain-oriented electrical steel sheets may deteriorate.
　The contents of S and Se are preferably low, but the total content may be 0.005% or less. If the total content of S and Se is more than 0.005%, magnetic aging may occur and the magnetic properties may deteriorate.
　The N content is preferably low, but may be 0.010% or less. If the N content is more than 0.010%, magnetic aging may occur and the magnetic properties may deteriorate. More preferably, it may be 0.005% or less.
　The acid-soluble Al content is preferably low, but may be 0.01% or less. If the acid-soluble Al content is more than 0.01%, magnetic aging may occur and the magnetic properties may deteriorate.
[0067]
　The content of each of Cu, Sn, Ni, Cr and Sb may be 0.01% or more and 0.30% or less. When the content of even one of these elements is 0.01% or more, the effect of stabilizing secondary recrystallization can be sufficiently obtained, the iron loss value can be further reduced, and it is better. Magnetic properties can be obtained. When the content of even one of these elements exceeds 0.30%, the effect of stabilizing secondary recrystallization is saturated, which is preferable from the viewpoint of suppressing an increase in the manufacturing cost of grain-oriented electrical steel sheets. Absent.
[0068]
　The composition of the silicon steel sheet may be measured by using ICP-AES (Inductively Coupled Plasma-Atomic Measurement Spectrum) for the obtained silicon steel sheet after removing the insulating film and the forsterite film of the grain-oriented electrical steel sheet. In addition, C and S may be measured by using the combustion-infrared absorption method, and N may be measured by using the inert gas melting-thermal conductivity method.
　Specifically, the method for removing the insulating coating and the forsterite coating on the grain-oriented electrical steel sheet is as follows. The insulating coating and the forsterite coating of the grain-oriented electrical steel sheet are removed to obtain a silicon steel sheet. Specifically, NaOH: 20% by mass + H 2 O: 80 wt% aqueous sodium hydroxide, 20 minutes at 80 ° C., after soaking the grain-oriented electrical steel sheet, followed by drying and washing with water, oriented electrical Remove the insulating coating on the steel plate. Subsequently, HCl: 20% by mass + H 2 O: 80 wt% aqueous hydrochloric acid solution, 2 minutes at 50 ° C., after soaking the grain-oriented electrical steel sheet, followed by drying and washing with water, forsterite oriented electrical steel sheet The coating is removed to obtain a silicon steel sheet. The time of immersion in the above-mentioned sodium hydroxide aqueous solution or hydrochloric acid aqueous solution may be changed according to the thickness of the coating film.
[0069]
　In the silicon steel plate according to the present embodiment, the average particle size of the secondary recrystallized grains is controlled. In the silicon steel plate according to the present embodiment, the average particle size of the secondary recrystallized grains is 10 mm or more and 50 mm or less. It is preferably 40 mm or less.
[0070]
　When the average particle size of the secondary recrystallized grains exceeds 50 mm, the iron loss value (particularly, eddy current loss) of the grain-oriented electrical steel sheet becomes large. The lower limit of the average particle size of the secondary recrystallized grains may be, for example, 10 mm in order to satisfy the magnetic characteristics of the grain-oriented electrical steel sheet according to the present embodiment.
[0071]
　The average particle size of the secondary recrystallized grains of the silicon steel sheet can be measured by, for example, the following method.
　The insulating coating and forsterite coating of the grain-oriented electrical steel sheet are removed by the same method as described above. Since the obtained silicon steel plate has a pit pattern formed on the surface of the steel plate according to the crystal orientation during immersion in the hydrochloric acid aqueous solution, the steel structure of the silicon steel plate can be observed. A test piece is cut out so that the observation surface has at least a width of 60 mm and a length of 300 mm, the steel structure of the silicon steel plate is observed, and the grain boundaries of the crystal grains that can be visually recognized are traced with an oil-based pen. At least five images of the surface of the grain-oriented electrical steel sheet are acquired using a commercially available image scanner device, and the acquired images are analyzed using commercially available image analysis software. After measuring the equivalent circle diameter of the crystal grains of the directional electromagnetic steel plate in all images by image analysis, the average value of the measured equivalent circle diameters is calculated to average the secondary recrystallized grains of the directional electromagnetic steel plate. Obtain the particle size.
　For example, small crystal grains having a particle size of less than 2 mm, which are difficult to identify visually, are excluded from the measurement of the particle size of the secondary recrystallized grains.
[0072]
　The forsterite film arranged on the silicon steel plate is mainly composed of Mg 2 SiO 4 , and contains a small amount of impurities and additives contained in the silicon steel plate and the annealing separator and their reaction products.
　The insulating film arranged on the forsterite film is mainly composed of phosphate and colloidal silica, and contains a small amount of elements and impurities diffused from the silicon steel sheet during purification annealing and their reaction products. It should be noted that components other than the above may be used as long as the insulating property and the tension on the steel plate can be obtained.
[0073]
　The thickness of the grain-oriented electrical steel sheet according to this embodiment is 0.15 mm or more and 0.23 mm or less. When the thickness of the grain-oriented electrical steel sheet is less than 0.15 mm, the load of cold rolling increases remarkably. When the thickness of the grain-oriented electrical steel sheet exceeds 0.23 mm, the iron loss of the grain-oriented electrical steel sheet deteriorates.
[0074]
　The thickness of the grain-oriented electrical steel sheet may be determined by measuring with radiation or the like. For simplicity, a sample of a predetermined size may be taken from a grain-oriented electrical steel sheet by shearing, and calculated by converting from the weight of the steel sheet using the iron density. Further, it may be obtained by converting from the coil diameter and the number of steel plate turns. The iron density is preferably selected according to the amount of Si contained.
[0075]
　The magnetic flux density B8 value of the grain-oriented electrical steel sheet shall be 1.930T or more. Here, the magnetic flux density B8 value is an average value of the magnetic flux density when a magnetic field of 800 A / m is applied.
　When the magnetic flux density B8 value is less than 1.930 T, the iron loss value (particularly, hysteresis loss) of the grain-oriented electrical steel sheet becomes large. The upper limit of the magnetic flux density B8 value is not particularly limited, but in reality, it may be 2.000T, for example. The magnetic properties of the grain-oriented electrical steel sheet, such as the magnetic flux density, can be measured by a known method. For example, the magnetic properties of grain-oriented electrical steel sheets are determined by a method based on the Epstein test specified in JIS C 2550: 2011, or a single plate magnetic property test method (Single Sheet Tester: SST) specified in JIS C 2556: 2015. However, in the present embodiment, it is determined by a method based on the Epstein test specified in JIS C 2550: 2011. In the measurement of the magnetic flux density B8 value, a set of samples is taken from both ends of the coil of the directional electromagnetic steel plate in the longitudinal direction after the final process, and the average value of the magnetic flux density B8 values ​​obtained by using those samples is taken. Ask. After the coil is divided in the longitudinal direction, a set of samples may be collected from both ends of the divided coil in the longitudinal direction. Further, when a sample is taken, if a sufficient length cannot be obtained in the longitudinal direction of the coil and only one set of samples can be taken, the measured value of one set of samples may be used.
[0076]
　In the grain-oriented electrical steel sheet according to the present embodiment, the abundance ratio of wrinkles having a steepness of 0.01 or more is 0 / m or more and 10 / m or less in the plate width direction. Since the grain-oriented electrical steel sheets manufactured by the manufacturing method according to the present embodiment have a good surface shape, the steepness of 0.01 or more, which reduces the space factor of the core material when the grain-oriented electrical steel sheets are stacked, is 0.01 or more. The abundance ratio of wrinkles can be reduced.
[0077]
　How to obtain the steepness will be described with reference to FIG. FIG. 5 is a diagram showing a cross-sectional curve (waviness curve) of the grain-oriented electrical steel sheet obtained by measuring the surface of the grain-oriented electrical steel sheet with a laser displacement meter.
　The steepness is calculated by measuring the shape of the convex portion existing on the surface of the grain-oriented electrical steel sheet. First, the shape of the steel sheet in the plate width direction is measured with a laser displacement meter to obtain a cross-sectional curve in the plate width direction of the grain-oriented electrical steel sheet as shown in FIG. When the noise of the cross-sectional curve is large, the noise may be removed within a range that does not deviate significantly from the measured cross-sectional curve. A convex portion having a peak height h of 0.1 mm or more is extracted from this cross-sectional curve. The peak height h extracted as the convex portion is more preferably 0.05 mm or more. The peak height h is the distance between the straight line connecting the two lowest points (points a and b in FIG. 5) near the convex portion and the highest point (point c in FIG. 5) of the convex portion. Extraction is performed by dividing the peak height h of the extracted convex portion by 1/2 of the length L of the straight line connecting the two lowest points (point a and point b in FIG. 5) in the vicinity of the extracted convex portion. The steepness of the convex portion is obtained (that is, the steepness = 2h / L). In the present embodiment, the convex portion having a steepness of 0.01 or more obtained by the above method is regarded as a wrinkle, and the wrinkle having a steepness of 0.01 or more existing per 1 m in the plate width direction of the grain-oriented electrical steel sheet is regarded as a wrinkle. Get the number. A cross-sectional curve is obtained from at least four locations of the grain-oriented electrical steel sheet so as to have a total of 4 m in the plate width direction, and the number of wrinkles is obtained by the above method.
[0078]
　As described above, the grain-oriented electrical steel sheet according to the present embodiment can reduce the iron loss value without performing magnetic domain control. Specifically, in the grain- oriented electrical steel sheet according to the present embodiment, the iron loss Wp when the magnetic domain control treatment is not performed is W 17/50 , which is 0.800 W / kg or less. It is preferably 0.790 W / kg or less, and more preferably 0.785 W / kg or less. The lower limit is not particularly limited, but may be 0.600 W / kg from the viewpoint of industrial stable manufacturability. Here, as the iron loss Wp when the magnetic domain control process is not performed, the value measured on the grain-oriented electrical steel sheet after strain annealing is used. W 17/50 is the average value of iron loss when the grain-oriented electrical steel sheet is excited to 1.7 T at 50 Hz. In the measurement of iron loss Wp, a set of samples is taken from both ends in the longitudinal direction of the coil of the grain-oriented electrical steel sheet after the final process, and the average value of the iron loss obtained by using those samples is obtained. After the coil is divided in the longitudinal direction, a set of samples may be collected from both ends of the divided coil in the longitudinal direction. Further, when a sample is taken, if a sufficient length cannot be obtained in the longitudinal direction of the coil and only one set of samples can be taken, the measured value of one set of samples may be used.
[0079]
　As described above, the grain-oriented electrical steel sheet according to the present embodiment can sufficiently reduce the iron loss even if the magnetic domain control treatment is not performed. Although the magnetic domain control process can reduce the iron loss value of the grain-oriented electrical steel sheet, it increases the noise of the transformer using the grain-oriented electrical steel sheet as the iron core material. Therefore, the grain-oriented electrical steel sheet according to the present embodiment can have both the magnetic characteristics of the transformer and the noise characteristics.
[0080]
　According to the method for manufacturing grain-oriented electrical steel sheets according to the present embodiment, it is possible to manufacture grain-oriented electrical steel sheets having a sufficiently reduced iron loss and a good surface shape without performing magnetic domain control treatment. Since the grain-oriented electrical steel sheet according to the present embodiment manufactured by the manufacturing method has a good surface shape, the space factor can be improved when it is used as an iron core material of a transformer. Needless to say, in the present embodiment, the magnetic domain control treatment may be applied to the grain-oriented electrical steel sheet depending on the purpose of the customer.
Example
[0081]
　Hereinafter, the method for manufacturing the grain-oriented electrical steel sheet and the grain-oriented electrical steel sheet according to the present embodiment will be described more specifically while showing examples. It should be noted that the examples shown below are merely examples of the grain-oriented electrical steel sheets according to the present embodiment, and the grain-oriented electrical steel sheets according to the present embodiment are not limited to the examples shown below.
[0082]
　(Example 1) In
　mass%, C: 0.08%, Si: 3.3%, Mn: 0.08%, S: 0.024%, acid-soluble Al: 0.03%, N: 0. A slab containing 008% and having the balance of Fe and impurities was prepared. The slab was heated at 1350 ° C. for 1 hour and then hot-rolled to obtain a hot-rolled steel sheet having a thickness of 2.3 mm. The obtained hot-rolled steel sheet is annealed at a maximum temperature of 1100 ° C. for 140 seconds, pickled, and then cold-rolled to obtain a cold-rolled steel sheet having a thickness of 0.23 mm. Obtained.
[0083]
　Subsequently, the obtained cold-rolled steel sheet was rapidly subjected to the average temperature rise rate V (° C./s) shown in Tables 1 and 2 while applying the steel sheet tension S (N / mm 2 ) shown in Tables 1 and 2. The temperature was raised. At this time, the average temperature rise rate V (° C./s) is the average value of the temperature rise rate in the temperature range of 550 ° C. to 700 ° C. By exchanging the heating device and the like, the temperature rise amount T (° C.) and the heating length L (mm) were changed as shown in Tables 1 and 2. Here, the temperature rise start point A is the temperature on the entrance side of the temperature riser in the temperature rise process including 550 ° C., and the temperature rise end point B is the temperature on the exit side of the temperature riser in the temperature rise process including 700 ° C. The average from the temperature start point A to the temperature rise end point B was defined as the average temperature rise rate V (° C./s). Then, decarburization annealing was performed in a moist hydrogen atmosphere at 850 ° C. for 180 seconds.
[0084]
　Next, an annealing separator containing MgO was applied to the surface of the cold-rolled steel sheet after primary recrystallization annealing, and then finish annealing was performed to obtain finish annealing, and the finish annealing plate was washed with water. Then, after applying an insulating film containing aluminum phosphate and colloidal silica as main components to the surface of the finished annealed sheet, the sheet thickness is obtained by baking the insulating film and performing flattening annealing for the purpose of flattening the steel sheet. A grain-oriented electrical steel sheet having a thickness of 0.15 mm or more and 0.23 mm or less was obtained.
[0085]
　Samples of the Epstein method were collected one by one by shearing from both ends of the coil of the grain-oriented electrical steel sheet obtained by the above method in the plate width direction, and these samples were subjected to strain-removal annealing. The iron loss Wp and the magnetic flux density B8 value were measured according to the Epstein method specified in 2011. The iron loss Wp was measured at W 17/50 and used as the average value of the iron loss obtained by exciting to 1.7 T at 50 Hz. The magnetic flux density B8 value was taken as the average value of the magnetic flux densities obtained by applying a magnetic field of 800 A / m at 50 Hz.
[0086]
　In addition, two samples were taken by shearing from both ends of the coil of the directional electromagnetic steel plate in the plate width direction, and the surface shape in the plate width direction was measured with a laser displacement meter to obtain a cross-sectional curve. Using the obtained cross-sectional curve, the number of wrinkles having a steepness of 0.01 or more existing per 1 m in the plate width direction of the grain-oriented electrical steel sheet was obtained by the above-mentioned method.
[0087]
　Further, after removing the insulating coating and the forsterite coating of the obtained grain-oriented electrical steel sheet by the above method, the component composition of the silicon steel sheet was measured using ICP-AES. Further, the average particle size of the secondary recrystallized grains of the silicon steel sheet was measured by the above method.
[0088]
　When the iron loss Wp was 0.800 or less and the wrinkle presence ratio was 0 / m or more and 10 / m or less, it was judged to be acceptable. If any one of these conditions was not met, it was judged to be rejected, and "C" was entered in the evaluation column in the table. The iron loss Wp of the example judged to be acceptable was evaluated based on the following criteria.
S (extremely good): 0.785 W / kg or less
A (better): Wp more than 0.785 W / kg 0.790 W / kg or less
B (good): Wp more than 0.790 W / kg 0.800 W / kg Less than
[0089]
　Tables 1 and 2 show the manufacturing conditions, measurement results, and evaluation results of grain-oriented electrical steel sheets. In the example of the present invention, in the composition of the silicon steel sheet, the total content of S and Se is 0.005% or less, the acid-soluble Al content is 0.01% or less, and the N content is 0. It was less than .005%, and the balance was Fe and impurities.
[0090]
[table 1]

[0091]
[Table 2]

[0092]
　With reference to the results in Tables 1 and 2, it was found that the grain-oriented electrical steel sheets (examples of the present invention) satisfying the conditions of the present embodiment had an evaluation of B or higher (good or higher). Further, in the example of the present invention in which the average heating rate V in the temperature range of 550 ° C. to 700 ° C. in the primary recrystallization annealing was 700 ° C./s or more, the iron loss Wp was 0.790 W / kg or less, and the evaluation was A. It turned out to be above (better or better). Further, in the example of the present invention in which the average heating rate V in the temperature range of 550 ° C. to 700 ° C. in the primary recrystallization annealing was 1000 ° C./s or more, the iron loss Wp was 0.785 W / kg or less, and the evaluation was S. It turned out to be (extremely good).
[0093]
　FIG. 6 shows a graph in which the results shown in Tables 1 and 2 are plotted with the temperature rise rate V on the horizontal axis and the steel plate tension S on the vertical axis. Further, FIG. 7 shows a graph in which the results shown in Tables 1 and 2 are plotted with T / L on the horizontal axis and steel plate tension S on the vertical axis. In addition, in FIG. 6 and FIG. 7, the example of the present invention was plotted with round dots, and the comparative example was plotted at intersections.
[0094]
　As shown in FIG. 6, between the temperature rising rate V (° C./s) in the temperature raising process of the primary recrystallization annealing and the steel sheet tension S (N / mm 2 ), the manufacturing method according to the present embodiment is applied. It can be seen that the following relations of Equation 1 and Equation 2 must be satisfied as specified in. Therefore, according to the manufacturing method according to the present embodiment, it is possible to manufacture grain-oriented electrical steel sheets having a reduced iron loss value.
[0095]
　1.96 ≦ S ≦ (25.5-0.0137 × V) (V ≦ 1000) ・ ・ ・ Equation 1
　1.96 ≦ S ≦ 11.8 (V> 1000) ・ ・ ・ Equation 2
[0096]
　Further, as shown in FIG. 7, as defined by the manufacturing method according to the present embodiment, the steel plate tension S (N / mm 2 ) and T / L (° C./mm) in the temperature raising process of the primary recrystallization annealing. It can be seen that the number of wrinkles in the directional electromagnetic steel sheet can be reduced by defining) and as in the following equations 3 and 4.
[0097]
　0.1 ≤ T / L ≤ 4.0 ... Equation 3
　1.96 ≤ S ≤ (19.6-1.96 x T / L) ... Equation 4
[0098]
　(Example 2)
　C: 0.08%, S: 0.023%, acid-soluble Al: 0.03%, N: 0.008% in mass%, and the balance is shown in Tables 3 and 4. A slab composed of Si and Mn having the indicated contents, Fe and impurities was prepared. The slab was heated at 1350 ° C. for 1 hour and then hot-rolled to obtain a hot-rolled steel sheet having a thickness of 2.3 mm. The obtained hot-rolled steel sheet was annealed at a maximum temperature of 1100 ° C. for 140 seconds, and then pickled and then cold-rolled to obtain a cold-rolled steel sheet having a thickness of 0.23 mm. ..
[0099]
　Subsequently, the obtained cold-rolled steel sheet was rapidly heated at the heating rate V (° C./s) shown in Tables 3 and 4 below, and then decarburized and annealed in a moist hydrogen atmosphere at 850 ° C. for 180 seconds. Was given. The average temperature rise rate V (° C./s) is the average value of the temperature rise rate in the temperature range of 550 ° C. to 700 ° C. , 7.84 N / mm 2 steel plate tension S was applied. The temperature rise amount T was 400 ° C., and the heating length L was 400 mm. The average heating rate V was calculated by the same method as in Example 1.
[0100]
　An annealing separating agent containing MgO was applied to the surface of the cold-rolled steel sheet after primary recrystallization annealing, and then finish annealing was performed to obtain finish annealing, and the finish annealing plate was washed with water. Then, after applying an insulating film containing aluminum phosphate and colloidal silica as main components to the surface of the finished annealed sheet, the sheet thickness is obtained by baking the insulating film and performing flattening annealing for the purpose of flattening the steel sheet. A grain-oriented electrical steel sheet having a thickness of 0.15 mm or more and 0.23 mm or less was obtained.
[0101]
　With respect to the grain-oriented electrical steel sheet obtained by the above method, the iron loss Wp, the magnetic flux density B8 value, the number of wrinkles having a steepness of 0.01 or more existing per 1 m in the plate width direction, and The composition of the silicon steel sheet and the average particle size of the secondary recrystallized grains were measured.
[0102]
　When the iron loss Wp was 0.800 or less and the wrinkle presence ratio was 0 / m or more and 10 / m or less, it was judged to be acceptable. If any one of these conditions was not met, it was judged to be unacceptable, and "C" was entered in the evaluation column in the table. Further, the iron loss Wp of the example judged to be acceptable was evaluated as S (extremely good), A (better), and B (good) based on the same criteria as in Example 1.
[0103]
　Tables 3 and 4 show the manufacturing conditions, measurement results, and evaluation results of grain-oriented electrical steel sheets. In the example of the present invention, in the composition of the silicon steel sheet, the total content of S and Se is 0.005% or less, the acid-soluble Al content is 0.01% or less, and the N content is 0. It was less than .005%, and the balance was Fe and impurities.
[0104]
[Table 3]

[0105]
[Table 4]

[0106]
　With reference to the results in Tables 3 and 4, the grain-oriented electrical steel sheets containing Si: 2.5% or more and 4.5% or less and Mn: 0.01% or more and 0.15% or less in mass% were evaluated. Was found to be B or higher (good or higher). Further, in the example of the present invention in which the average heating rate V in the temperature range of 550 ° C. to 700 ° C. in the primary recrystallization annealing was 700 ° C./s or more, the iron loss Wp was 0.790 W / kg or less, and the evaluation was A. It turned out to be above (better or better). Further, in the example of the present invention in which the average heating rate V in the temperature range of 550 ° C. to 700 ° C. in the primary recrystallization annealing was 1000 ° C./s or more, the iron loss Wp was 0.785 W / kg or less, and the evaluation was S. It turned out to be (extremely good). Condition B5 was judged to be unacceptable because the Si content was too high to perform hot rolling and the grain-oriented electrical steel sheet could not be manufactured, and "C (rolling not possible)" was entered in the evaluation column. ) ”.
[0107]
　(Example 3) In
　mass%, C: 0.08%, Si: 3.3%, Mn: 0.08%, S: 0.024%, acid-soluble Al: 0.03%, N: 0. A slab containing 008% and having the balance of Fe and impurities was prepared. The slab was heated at 1350 ° C. for 1 hour and then hot-rolled to obtain a hot-rolled steel sheet having a thickness of 2.3 mm. The obtained hot-rolled steel sheet was annealed at a maximum temperature of 1100 ° C. for 140 seconds, and then pickled and then cold-rolled to obtain a cold-rolled steel sheet having a thickness of 0.23 mm. ..
[0108]
　Subsequently, the obtained cold-rolled steel sheet was rapidly heated at the average heating rate V (° C./s) shown in Tables 5 and 6 below, and then decarburized in a moist hydrogen atmosphere at 850 ° C. for 180 seconds. Annealed. The temperature rising rate V (° C./s) was taken as the average value of the temperature rising rates in the temperature range of 550 ° C to 700 ° C. Further, in the heating process of the primary recrystallization annealing, the steel plate tension S (N / mm 2 ), the heating amount T (° C.), and the heating length L (mm) were changed as shown in Tables 5 and 6. The average heating rate V was calculated by the same method as in Example 1.
[0109]
　An annealing separator containing MgO was applied to the surface of the cold-rolled steel sheet after primary recrystallization annealing, and then finish annealing was performed to obtain a finish annealing plate, and the finish annealing plate was washed with water. Then, after applying an insulating film containing aluminum phosphate and colloidal silica as main components to the surface of the finished annealed sheet, the sheet thickness is obtained by baking the insulating film and performing flattening annealing for the purpose of flattening the steel sheet. A grain-oriented electrical steel sheet having a thickness of 0.15 mm or more and 0.23 mm or less was obtained.
[0110]
　Regarding the grain-oriented electrical steel sheet obtained by the above method, the iron loss Wp, the magnetic flux density B8 value, the number of wrinkles having a steepness of 0.01 or more existing per 1 m in the plate width direction, and silicon by the same method as in Example 1. The composition of the steel sheet and the average particle size of the secondary recrystallized grains were measured.
[0111]
　When the iron loss Wp was 0.800 or less and the wrinkle presence ratio was 0 / m or more and 10 / m or less, it was judged to be acceptable. If any one of these conditions was not met, it was judged to be unacceptable, and "C" was entered in the evaluation column in the table. Further, the iron loss Wp of the example judged to be acceptable was evaluated as S (extremely good), A (better), and B (good) based on the same criteria as in Example 1.
[0112]
　Tables 5 and 6 show the manufacturing conditions, measurement results, and evaluation results of grain-oriented electrical steel sheets. In the example of the present invention, in the composition of the silicon steel sheet, the total content of S and Se is 0.005% or less, the acid-soluble Al content is 0.01% or less, and the N content is 0. It was less than .005%, and the balance was Fe and impurities.
[0113]
[Table 5]

[0114]
[Table 6]

[0115]
　With reference to Tables 5 and 6, grain-oriented electrical steel sheets having an average grain size of 10 mm or more and 50 mm or less and a magnetic flux density B8 of 1.930 T or more are evaluated as B or more (good or better). ). Further, in the example of the present invention in which the average heating rate V in the temperature range of 550 ° C. to 700 ° C. in the primary recrystallization annealing was 700 ° C./s or more, the iron loss Wp was 0.790 W / kg or less, and the evaluation was A. It turned out to be above (better or better). Further, in the example of the present invention in which the average heating rate V in the temperature range of 550 ° C. to 700 ° C. in the primary recrystallization annealing was 1000 ° C./s or more, the iron loss Wp was 0.785 W / kg or less, and the evaluation was S. It turned out to be (extremely good).
[0116]
　(Example 4) In
　mass%, C: 0.08%, Si: 3.3%, Mn: 0.08%, S: 0.005%, Se: 0.019%, acid-soluble Al: 0. A slab containing 03% and N: 0.008% and having the balance of Fe and impurities was prepared. The slab was heated at 1350 ° C. for 1 hour and then hot-rolled to obtain a hot-rolled steel sheet having a plate thickness of 2.1 mm. The obtained hot-rolled steel sheet was annealed at a maximum temperature of 1100 ° C. for 140 seconds, and then pickled and then cold-rolled to obtain a cold-rolled steel sheet. In cold rolling, the cumulative rolling ratio was controlled so that the finally obtained grain-oriented electrical steel sheet had the sheet thickness shown in Table 7.
[0117]
　The obtained cold-rolled steel sheet was rapidly heated so that the average temperature rise rate V in the temperature range of 550 ° C to 700 ° C was 1000 ° C / s, and then decarburized in a moist hydrogen atmosphere at 850 ° C for 180 seconds. Annealed. In the temperature raising process of the primary recrystallization annealing, the steel plate tension S was 7.84 N / mm 2 , the temperature rise amount T was 400 ° C., and the heating length L was 400 mm. The average heating rate V was calculated by the same method as in Example 1.
[0118]
　An annealing separator containing MgO was applied to the surface of the cold-rolled steel sheet after primary recrystallization annealing, and then finish annealing was performed to obtain a finish annealing plate, and the finish annealing plate was washed with water. Then, after applying an insulating film containing aluminum phosphate and colloidal silica as main components to the surface of the finished annealed sheet, the sheet thickness is obtained by baking the insulating film and performing flattening annealing for the purpose of flattening the steel sheet. A grain-oriented electrical steel sheet having a thickness of 0.15 mm or more and 0.23 mm or less was obtained.
[0119]
　With respect to the grain-oriented electrical steel sheet obtained by the above method, the iron loss Wp, the magnetic flux density B8 value, the number of wrinkles having a steepness of 0.01 or more existing per 1 m in the plate width direction, and The composition of the silicon steel sheet and the average particle size of the secondary recrystallized grains were measured.
[0120]
　When the iron loss Wp was 0.800 or less and the wrinkle presence ratio was 0 / m or more and 10 / m or less, it was judged to be acceptable. If any one of these conditions was not met, it was judged to be unacceptable, and "C" was entered in the evaluation column in the table. Further, the iron loss Wp of the example judged to be acceptable was evaluated as S (extremely good), A (better), and B (good) based on the same criteria as in Example 1.
[0121]
　Table 7 shows the manufacturing conditions, measurement results, and evaluation results of grain-oriented electrical steel sheets. In the example of the present invention, in the composition of the silicon steel sheet, the total content of S and Se is 0.005% or less, the acid-soluble Al content is 0.01% or less, and the N content is 0. It was less than .005%, and the balance was Fe and impurities.
[0122]
[Table 7]

[0123]
　With reference to Table 7, it was found that the grain-oriented electrical steel sheet having a plate thickness of 0.15 mm or more and 0.23 mm or less was evaluated as B or more (good or more).
[0124]
　(Example 5) In
　mass%, C: 0.08%, Si: 3.3%, Mn: 0.08%, S: 0.023%, acid-soluble Al: 0.03%, N: 0. A slab containing 008% and having the balance of Fe and impurities was prepared. The slab was heated at 1350 ° C. for 1 hour and then hot-rolled to obtain a hot-rolled steel sheet having a thickness of 2.3 mm. The obtained hot-rolled steel sheet was annealed at a maximum temperature of 1100 ° C. for 140 seconds, and then pickled and then cold-rolled to obtain a cold-rolled steel sheet having a thickness of 0.23 mm. ..
[0125]
　Subsequently, the obtained cold-rolled steel sheet was rapidly heated at the average heating rate V (° C./s) shown in Table 8 below, and then decarburized and annealed in a moist hydrogen atmosphere at 850 ° C. for 180 seconds. did. The average temperature rise rate V (° C./s) is the average value of the temperature rise rate in the temperature range of 550 ° C. to 700, and is set in the passing direction of the cold-rolled steel sheet during the rapid temperature rise of the primary recrystallization annealing. , 7.84 N / mm 2 steel plate tension was applied. In addition, Table 8 below shows the number of heating devices, the amount of temperature rise T (° C.), and the heating length L (mm) during primary recrystallization annealing, including the process of raising the temperature in the temperature range of 550 ° C to 700 ° C. Changed as shown in. The average heating rate V was calculated by the same method as in Example 1.
[0126]
　An annealing separator containing MgO was applied to the surface of the cold-rolled steel sheet after primary recrystallization annealing, and then finish annealing was performed to obtain a finish annealing plate, and the finish annealing plate was washed with water. Then, after applying an insulating film containing aluminum phosphate and colloidal silica as main components to the surface of the finished annealed sheet, the sheet thickness is obtained by baking the insulating film and performing flattening annealing for the purpose of flattening the steel sheet. A grain-oriented electrical steel sheet having a thickness of 0.15 mm or more and 0.23 mm or less was obtained.
[0127]
　With respect to the grain-oriented electrical steel sheet obtained by the above method, the iron loss Wp, the magnetic flux density B8 value, the number of wrinkles having a steepness of 0.01 or more existing per 1 m in the plate width direction, and The composition of the silicon steel sheet and the average particle size of the secondary recrystallized grains were measured.
[0128]
　When the iron loss Wp was 0.800 or less and the wrinkle presence ratio was 0 / m or more and 10 / m or less, it was judged to be acceptable. If any one of these conditions was not met, it was judged to be unacceptable, and "C" was entered in the evaluation column in the table. Further, the iron loss Wp of the example judged to be acceptable was evaluated as S (extremely good), A (better), and B (good) based on the same criteria as in Example 1.
[0129]
　Table 8 shows the manufacturing conditions, measurement results, and evaluation results of grain-oriented electrical steel sheets. In the example of the present invention, in the composition of the silicon steel sheet, the total content of S and Se is 0.005% or less, the acid-soluble Al content is 0.01% or less, and the N content is 0. It was less than .005%, and the balance was Fe and impurities.
[0130]
[Table 8]

[0131]
　With reference to Table 8, it was found that the grain-oriented electrical steel sheet (example of the present invention) satisfying the conditions specified in the present invention was evaluated as B or higher (good or higher). Further, in the example of the present invention in which the average heating rate V in the temperature range of 550 ° C. to 700 ° C. in the primary recrystallization annealing was 700 ° C./s or more, the iron loss Wp was 0.790 W / kg or less, and the evaluation was A. It turned out to be above (better or better). Further, in the example of the present invention in which the average heating rate V in the temperature range of 550 ° C. to 700 ° C. in the primary recrystallization annealing was 1000 ° C./s or more, the iron loss Wp was 0.785 W / kg or less, and the evaluation was S. It turned out to be (extremely good).
[0132]
　Further, in the example of the present invention in Table 8, it was found that the condition of the present embodiment is satisfied under any condition regardless of the number of temperature raising devices.
[0133]
　Although the preferred embodiments of the present invention have been described in detail with reference to the accompanying drawings, the present invention is not limited to such examples. It is clear that a person having ordinary knowledge in the field of technology to which the present invention belongs can come up with various modifications or modifications within the scope of the technical ideas described in the claims. , These are also naturally understood to belong to the technical scope of the present invention.
Industrial applicability
[0134]
　According to the above aspect according to the present invention, when the temperature is raised more rapidly than in the prior art by primary recrystallization annealing, the surface shape is better and the iron loss value is not subjected to the magnetic domain control treatment. It is possible to provide a grain-oriented electrical steel sheet in which
Description of the sign
[0135]
　1
　Steel plate 10, 21, 22, 31, 32, 41, 42 Heat raising device
The scope of the claims
[Claim 1]
　A method for producing a directional electromagnetic steel sheet, in which the component composition is mass%,
C: 0.02% or more and 0.10% or less,
Si: 2.5% or more and 4.5% or less,
Mn: 0.01. % Or more and 0.15% or less,
total of S and Se: 0.001% or more and 0.050% or less,
acid-soluble Al: 0.01% or more and 0.05% or less,
N: 0.002% or more and 0.015 A
step of obtaining a hot-rolled steel sheet by heating a slab containing % or less and the balance of Fe and impurities to 1280 ° C. to 1450 ° C. and performing hot rolling,
　and hot-rolling the hot-rolled steel sheet. was subjected to a step of obtaining a cold rolled steel sheet by performing twice or more cold rolling sandwiching the rolling or intermediate annealing between single cold,
　a step of performing primary recrystallization annealing to the cold-rolled steel sheet,
　the primary A step of applying a quenching separator containing MgO to the surface of the cold-rolled steel sheet after recrystallizing and then performing finish annealing to obtain a
　finished annealed sheet, and applying an insulating film to the finished annealed sheet and then flattening it. In the
　heating process of the primary recrystallizing annealing including the step of performing the rolling, the average heating rate V (° C./s) in the temperature range of 550 ° C to 700 ° C is 400 ° C / s or more, and the temperature is 550 ° C. T / L (° C.), which is the ratio of the amount of temperature rise T (° C.) in the series of temperature rise processes including the temperature rise in the temperature range of about 700 ° C. to the heating length L (mm) in the series of temperature rise processes. / Mm) is 0.1 ≦ T / L ≦ 4.0, and the tension S (N / mm 2) applied in the passing direction of the cold-rolled steel sheet. ) Is 1.96 ≦ S ≦ (19.6-1.96 × T / L) and V ≦ 1000, the tension S is 1.96 ≦ S ≦ (25.5-0.0137 ×). V), and when V> 1000, the
method for manufacturing a grain-oriented electrical steel sheet , wherein the tension S is 1.96 ≦ S ≦ 11.8 .
[Claim 2]
　A
　grain-
　oriented electrical steel sheet having a silicon steel sheet, a forsterite film arranged on the silicon steel sheet, and an insulating film arranged on the forsterite film, and the
　silicon steel sheet has a composition of mass. %,
Si: 2.5% or more and 4.5% or less,
Mn: 0.01% or more and 0.15% or less,
total of S and Se: 0% or more and 0.005% or less,
acid-soluble Al: 0% When 0.01% or more and
N: 0% or more and 0.005% or less
are contained, the balance is
　composed of Fe and impurities, and the average particle size of the secondary recrystallized grains of the silicon steel sheet is 10 mm or more and 50 mm or less. The grain-
　oriented electrical steel sheet has a
　　thickness of 0.15 mm or more and 0.23 mm or less, an
　　iron loss Wp of W 17/50 , 0.800 W / kg or less, and a
　　steepness of 0.01 or more. A
　　grain-
oriented electrical steel sheet having an abundance ratio of 0 pieces / m or more and 10 pieces / m or less in the plate width direction and a magnetic flux density B8 value of 1.930 T or more .