[0001]The present invention relates to a method for producing a Fugata film.
BACKGROUND
[0002]
　Plastic polarized lens can prevent transmission of reflected light. Therefore, it protects the like or eye by blocking the strong reflected light in outdoor such as ski and fishing, it is used in ensuring of safety by blocking the reflected light from an oncoming vehicle at the time of driving a car. Plastic polarized lens, and a and a polarizing film plastic lens substrate is formed by laminating. As the polarizing film, Fugata been film is used.
[0003]
　Patent Document 1, a manufacturing method of the polarizing film is pressed on one of the surfaces pressurized by introducing a gas into the interior of the member surrounding the surface, the other surface of the heated mold surface of the film of the film There has been disclosed. Furthermore, plastic products including a polarizing film obtained is disclosed.
[0004]
　Patent Document 2, by utilizing the pressure difference between the space exposed space and the other surface of the one surface is exposed polyimide film, a polyimide film is brought into close contact with the mold surfaces Fugata, the polyimide film molded article manufacturing process is disclosed.
　Patent Document 3, using a low pressure air stream, a method of thermoforming a thermoplastic sheet is pressed against the mold is disclosed.
[0005]
　Patent Document 4, using a mold, a method of biasing form the thermoplastic polyester at a predetermined temperature condition is disclosed. Furthermore, the plastic polarized lens comprising a polarizing film obtained is disclosed.
[0006]
　Patent Document 5, by contacting the wafer into a mold having a surface of predetermined shape, the method of forming the wafer in a curved shape is disclosed. Further, optical components, including wafers resulting curved shape is also disclosed.
　Patent Document 6, pressure forming mold is disclosed. Further, by using the mold, the pressure of the pressurized air, a method of Fugata the film or sheet is disclosed.
[0007]
　Patent Document 7 discloses a method of the polarizing film of planar shape is preheated, pressing the convex surface of the lens substrate while pressing a pad, adhering the film on the convex surface of the lens substrate via a pressure-sensitive adhesive layer There has been described (FIG. 2).
　Patent Document 8, push the latex by the film on the convex surface of the lens substrate, as well as Fugata the film, the film on the convex surface of the lens substrate via a latex layer formed on the convex surface how paste have been described (FIGS. 3A ~ Figure 3C).
CITATION
Patent Document
[0008]
Patent Document 1: JP-T 2003-533719 Patent Publication
Patent Document 2: JP 2004-261961 Patent Publication
Patent Document 3: JP 2005-289040 Patent Publication
Patent Document 4: WO 2009/098886 Patent
Patent Document 5: JP 2012-56315 JP
Patent Document 6: JP 2014-131858 Patent Publication
Patent Document 7: JP-T 2009-527783 Patent Publication
Patent Document 8: JP-T 2008-529077 Patent Publication
Disclosure of the Invention
Problems that the Invention is to Solve
[0009]
　However, the technology described in Patent Documents 1 to 8, there is room for improvement in the following points.
　Patent Document as described in 1-6, in the method a film on the surface of the mold pressing or close contact so it is Fugata, when a foreign substance on the mold surface are present, the shape of the foreign matter Fugata film transcribed, there are cases where desired surface shape can not be obtained. Further, foreign matter attached to Fugata film surface, there become contaminated. In this way, there is room for improvement in the yield of the product.
　Furthermore, the method, it is necessary to keep the mold surface constantly clean, are those that complicated maintenance and management of the mold, there is room for improvement in production efficiency.
　Further, as in Patent Document 7, even in a method of Fugata by pressing the film using a pad, there is room for same as described above improvements.
[0010]
　The technique described in Patent Document 8, for pushing the latex by the film on the convex surface of the lens substrate, the stress in the film itself takes, there may affect the optical properties of the film. Further, when the thickness of the latex layer is not uniform, there have been cases where Fugata film having a desired surface shape can not be obtained. In this way, there is room for improvement in the yield of the product.
Means for Solving the Problems
[0011]
　The present invention can be illustrated below.
[1] with a thermoplastic resin film, so as to partition the space into the second space of the one first space and the other surface side of the surface side of the film, placing a thermoplastic resin film,
　the thermoplastic heating the resin film,
　by utilizing the pressure difference between the second space and the first space, a step of bending said thermoplastic resin film in space,
　the curvature of the thermoplastic resin film a step of stopping in a state where at least a convex curved surface of the both surfaces of the film is exposed in the space,
　cooling the curved the films,
including the method of Fugata film.
[2] the step of bending said thermoplastic resin film,
　the first space or pressurizing at least one of the second space, curving the thermoplastic resin film in the space towards the pressure smaller comprising the step, a manufacturing method of Supplementary shaped film according to [1].
[3] the step of bending said film,
　said first space or in vacuo at least one of the second space, comprising the step of bending said thermoplastic resin film in the space towards the pressure smaller the method of Supplementary shaped film according to [1].
[4] the step of bending said film,
　said one of the first space or the second space under reduced pressure and the other in space with pressurized, to the thermoplastic resin film in a space whose pressure is reduced to comprising the step of bending, a manufacturing method of Supplementary shaped film according to [1].
[5] the step of bending said thermoplastic resin film,
　one was charged the medium of the first space or the second space, by pressurizing said one space, the thermoplastic comprising the step of bending the resin film into the other space, a manufacturing method of Supplementary shaped film according to [2] or [4].
[6] The step of bending the thermoplastic resin film,
　wherein a molding tool disposed in the first space or the second space, the thermoplastic resin film opposite to the mold medium on the surface of using the medium supply means for supplying,
　in said first space or the second space, the thermoplastic resin supplied medium from the medium supply means between said thermoplastic resin film and the mold Supplementary shaped film according to the film to press the, by utilizing the difference between the pressure in the other space comprises the step of bending said thermoplastic resin film in a state not in contact with the surface of the mold, [2] the method of production.
[7] The mold, the surface facing the thermoplastic resin film has a substantially hemispherical convex or concave, the manufacturing method of Supplementary shaped film according to [6].
[8] the made mold of a porous material, manufacturing method of Supplementary shaped film according to [6] or [7].
[9] The step of bending the thermoplastic resin film in the other space,
　by pressurizing the inside space charged with the medium heated in the first space or the second space comprising the step of bending said thermoplastic resin film in the other space at a temperature of 30 ° C. ~ 300 ° C., a manufacturing method of Supplementary shaped film according to [5].
[10] the step of bending said thermoplastic resin film,
　based on the position of the thermoplastic resin film which is detected by the position sensor, comprising the step of controlling the amount of curvature of the thermoplastic resin film, [5] manufacturing method of Supplementary shaped film according to.
[11] prior to said step of cooling the curved the films,
　including the step of heating the curved the film was re-manufacturing method of Supplementary shaped film according to any one of [10] [1].
[12] The re-heating step is performed at a heating temperature ~ the thermoplastic resin film constituting the resin Tm (melting point) below the temperature in the heating step, the manufacturing method of Supplementary shaped film according to [11].
[13] the step of placing the thermoplastic resin film, the first molding member comprises a first space which is opened to one, with placing the thermoplastic resin film so as to cover the opening, heat comprising the step of fixing the thermoplastic resin film to the open end,
　the step of bending said thermoplastic resin film comprises a first space on one surface of the thermoplastic resin film is exposed, thermoplastic resin film of utilizing the pressure difference between the second space and the other surface is exposed, including the step of bending said thermoplastic resin film in a state not in contact with the inner wall surface of the first molding member, [1] manufacturing method of Supplementary shaped film according to any one of [12] from.
[14] The thermoplastic resin film, the back surface of the surface exposed to at least the first space portion is covered with a second molding member having a second space portion opened to one, according to [13] manufacturing method of Supplementary shaped film of.
[15] The thermoplastic resin film is fixed to the open end of the first molding member, in a state where the other surface of the thermoplastic resin film is exposed to the enclosing member, the thermoplastic resin film and the and the first molding member disposed in the enclosing member,
　the step of curving the thermoplastic resin film while maintaining one of the internal or the first space portion of the enclosing member to a normal pressure, the other under reduced pressure, comprising the step of bending said thermoplastic resin film,
the manufacturing method of Supplementary shaped film according to [13].
[16] The thermoplastic resin film is fixed to the open end of the first molding member, in a state where the other surface of the thermoplastic resin film is exposed to the enclosing member, the thermoplastic resin film and the and the first molding member disposed in the enclosing member,
　the step of curving the thermoplastic resin film while maintaining one of the internal or the first space portion of the enclosing member to a normal pressure, the other by pressurizing, comprising the step of bending said thermoplastic resin film,
the manufacturing method of Supplementary shaped film according to [13].
[17] The thermoplastic resin film is fixed to the open end of the first molding member, in a state where the other surface of the thermoplastic resin film is exposed to the enclosing member, the thermoplastic resin film and the and the first molding member disposed in the enclosing member,
　the step of curving the thermoplastic resin film, an internal or one pressurized of the first space portion of the enclosing member, by reducing the pressure of the other comprising the step of bending said thermoplastic resin film,
the manufacturing method of Supplementary shaped film according to [13].
[18] The process line as a series of steps in a state where the thermoplastic resin film on the first molding member is mounted for heating the process and curved the film was curving the thermoplastic resin film again dividing method of Supplementary shaped film according to any one of [17] from [13].
[19] The in enclosing member includes
　a second heating means for heating the interior of the first heating means or enclosing member for heating the thermoplastic resin film,
　wherein the inside or the first mold member of the enclosing members first and pressure reduction means for reducing the pressure of the first space portion pressurizing means for pressurizing, or the first space portion of the interior or the first mold member of the enclosing member,
is provided, from [15] manufacturing method of Supplementary shaped film according to any one of [18].
[20] The pressurization means comprises a medium introduction means for internal or charged medium in the first space portion of the first mold member of the enclosing member, the manufacture of Supplementary shaped film according to [19] Method.
[21] further includes a third heating means for heating said medium, a manufacturing method of Supplementary shaped film according to [20].
[22] In addition, a position sensor capable of continuously measuring the position of the thermoplastic resin film to bend,
　based on the position of the thermoplastic resin film as measured by the position sensor, the pressing means and a control means for controlling, the method for producing a Supplementary shaped film according to any one of [21] from [19].
[23] is the thermoplastic resin film, polyvinyl alcohol film made, polyester film, polyamide film, polyimide film, polyolefin film is selected from polyvinyl chloride film and polycarbonate film, [1] - [ manufacturing method of Supplementary shaped film according to any one of 22.
[24] [1] - comprising the steps of any one of [23], the production method of the polarizing film.
[25] The thermoplastic resin film, so as to partition the space into the second space of the one first space and the other surface side of the surface side of the film, placing a thermoplastic resin film,
　the thermoplastic heating the resin film,
　by utilizing the pressure difference between the second space and the first space, a step of bending said thermoplastic resin film in space,
　the curvature of the thermoplastic resin film a step of stopping in a state where at least a convex curved surface of the both surfaces of the film is exposed in the space,
　obtaining a polarizing film by cooling a curved said films,
　at least one surface of the polarizing film a step of laminating the lens substrate to
comprise a method of manufacturing a polarizing lens.
Effect of the invention
[0012]
　According to the manufacturing method of Supplementary shaped film of the present invention, since the thermoplastic resin film in a state of non-contact with the mold or the like can be Fugata, hardly scratched the surface, In addition, since the foreign matter hardly adheres , it can be obtained Fugata film having a substantially spherical shape with a very smooth surface by a simple method. That is, according to the production method of the present invention, the yield of products such as optical materials are improved with Fugata film or the Fugata film.
　Furthermore, it is possible to mold maintenance and management as convenient, to improve production efficiency of the product.
BRIEF DESCRIPTION OF THE DRAWINGS
[0013]
　Above objects, and other objects, features and advantages, preferred embodiments described below, and become more apparent from the following drawings associated therewith.
[0014]
In [1] The present embodiment is a cross-sectional view schematically showing a manufacturing method of Fugata film.
In [2] The present embodiment is a cross-sectional view schematically showing a manufacturing method of Fugata film.
In [3] The present embodiment is a cross-sectional view schematically showing a manufacturing method of Fugata film.
In [4] The present embodiment is a cross-sectional view schematically showing a manufacturing method of Fugata film.
In [5] The present embodiment is a cross-sectional view schematically showing a manufacturing method of Fugata film.
In [6] The present embodiment is a cross-sectional view schematically showing a manufacturing method of Fugata film.
DESCRIPTION OF THE INVENTION
[0015]
　Manufacturing method of Supplementary shaped film of the present invention,
　a thermoplastic resin film, so as to partition the space into the second space of the one first space and the other surface side of the surface side of the film, the thermoplastic resin film placing,
　heating the thermoplastic resin film,
　by utilizing the pressure difference between the second space and the first space, a step of bending said thermoplastic resin film in space,
　the curvature of the thermoplastic resin film, a step of at least the convex curved surface of the both surfaces of the film is stopped in a state exposed to the space,
　cooling the curved the films,
including.
　Hereinafter, the embodiment of the manufacturing method of Supplementary shaped film of the present invention will be described with reference to the accompanying drawings. In all the drawings, like numerals represent like components, the explanation will be appropriately omitted.
[0016]
　Manufacturing method of Supplementary shaped film of this embodiment includes the following steps.
Step a: a thermoplastic resin film 18, so as to partition the space into the second space 22 of the one first space 16 of the surface 18a side and the other surface 18b side of the film, placing a thermoplastic resin film 18 ( Figure 1 (a)).
Step b: heating the thermoplastic resin film 18.
Step c: the first space 16 and by utilizing the pressure difference between the second space 22, to bend the thermoplastic resin film 18 in the second space 22 (Figure 1 (b)).
Step d: the curvature of the thermoplastic resin film 18, the other surface 18b of the thermoplastic resin film 18 is stopped in a state of being exposed into the second space 22.
Step e: cooling the thermoplastic resin film 18 that is curved.
　Hereinafter, the respective steps will be described.
[0017]
(Step a)
　Step a, as shown in FIG. 1 (a), the first molding member 14 comprising a first space 16 which is open at one, placing a thermoplastic resin film 18 so as to cover the opening to location. The first space 16, one surface 18a of the thermoplastic resin film 18 is exposed. Then, using the second molding member 24 comprising a second space 22 which is open at one, the other with the second molding member 24 as the other surface 18b of the thermoplastic resin film 18 is exposed in the second space 22 cover the surface 18b.
[0018]
　Open end and the opening end portion of the second molding member 24 of the first molding member 14 may be fitted, the thermoplastic resin film 18 can be fixed between these open ends.
[0019]
　The first molding member 14 and the second molding member 24 is configured such metal.
　The shape of the first space 16, the thermoplastic resin film 18 does not contact the inner wall surface of the space 16 of the first molding member 14 in Fugata step is not particularly limited as long heated thermoplastic resin film 18. The shape of the second space 22 available to the pressure difference between the first space 16 and the second space 22 in Fugata process, not further particularly limited as long heated thermoplastic resin film 18.
[0020]
　The first molding member 14, a first heating means for heating the thermoplastic resin film 18, second heating means for heating the interior first space 16,
the medium to pressurize the inner first space 16 first space 16 transfer means for charging the interior,
it may be vacuum means are provided for reducing the pressure of the third heating means or within the first space 16 to heat the medium. Heated medium may be configured to circulate within the first space 16. Furthermore, the first molding member 14 may not be a closed system.
[0021]
　The second molding member 24 includes a first heating means for heating the thermoplastic resin film 18, second heating means for heating the interior second space 22, the medium to pressurize the inner second space 22 the second space 22 transfer means for charging the interior, it may be vacuum means are provided for reducing the pressure of the third heating means or within the second space 22, to heat the medium. Heated medium may be configured to circulate the second space 22. Further, the second molding member 24 may not be a closed system.
　Media can be heated thermoplastic resin film 18, the front and back surfaces of the film is not particularly limited as long as it can provide a pressure differential, e.g., air, inert gas such as nitrogen, water vapor, such as liquid such as water it can be mentioned.
　The first heating means, infrared radiator, heat ray irradiation apparatus or a oven. The second heating means can include an oven or the like.
[0022]
　The thermoplastic resin film 18, include polyvinyl alcohol film made, polyester film made of polyethylene terephthalate and polyethylene naphthalate, polyamide films, polyimide films, polyolefin films, polyvinyl chloride film made, the polycarbonate film and the like be able to. The film thickness of the thermoplastic resin film 18 have different preferred thickness depending on the use of the resulting Fugata film, it can be appropriately selected. These thermoplastic resin films, dichroic dyes, dimming dye, a specific wavelength cut dye may comprise a dye, ultraviolet absorber and the like.
[0023]
(Step b)
　is then heated in a state where the thermoplastic resin film 18 is fixed at the open end of the open end and the second molding members 24 of the first molding member 14.
[0024]
　And the presence or absence of the reheating step described below, stretched state (presence and magnification) and the material of the thermoplastic resin film 18, although the heating temperature by the thickness varies in the case of polyester film by stretching, heating temperature is 30 ° C. ~ 300 ° C., preferably 100 ~ 200 ° C., more preferably 120 ~ 180 ° C.. The heating temperature of the thermoplastic resin film 18, in the space in which the film is exposed, can be confirmed by measuring the temperature of the ambient surrounding temperature or the film medium.
[0025]
　To heat the thermoplastic resin film 18, the first heating means provided in the first mold member 14 and / or the second molding member 24, a method of heating by light and heat rays, first molding member mention may be made of 14 and / or second heating means provided in the second molding member 24 method of heating the inner first space 16 inside and / or the second space 22. Furthermore, in step c, it can be heated thermoplastic resin film 18 by using a heated medium.
　Incidentally, the method for circulating a heated medium in the first space 16, it is possible to perform step b and step c simultaneously.
[0026]
(Step c)
　then, by utilizing the pressure difference between the first space 16 and the second space 22, to bend the thermoplastic resin film 18 in the space. Note that the process is carried out with or heated while maintaining the temperature of step b.
[0027]
　As this process, creating a pressure difference between the inside and the first space 16 second space 22 may be the following manner.
(I) while the second molding member 24 to maintain the second space 22 to the atmosphere release to atmospheric pressure, is charged with the medium in the first space 16. Note that when circulating the heated medium in the first space 16 can perform step b and step c simultaneously.
(Ii) The medium is charged into the first space 16 and the second space 22, it is larger than the other space pressure of one space. Incidentally, the heated medium when circulating in the first space and / or the second space 22 16 may perform step b and step c simultaneously.
(Iii) by vacuum means of the second molding member 24 while reducing the pressure in the second space 22, is charged with the medium in the first space 16. Note that when circulating the heated medium in the first space 16 can perform step b and step c simultaneously.
(Iv) while reducing the pressure in the second space 22 by the vacuum means of the second molding member 24 to maintain the first molding member 14 to the first space 16 to the atmosphere release to normal pressure.
(V) as well as reduce the pressure in the first space 16 by the pressure reducing means of the first molding member 14, the pressure reducing means of the second molding member 24 to reduce the pressure in the second space 22, the other the pressure of one space larger than the space.
[0028]
　The pressure in the first space 16 when pressurizing the material of the thermoplastic resin film 18, although different by temperatures and the film thickness and the desired radius of curvature, in the case of 100 ~ 200 [mu] m thick stretched polyester film, 0. 001 is about ~ 0.4MPa. When pressurizing the inside first space 16 inside and the second space 22, the material of the thermoplastic resin film 18, based on the desired curvature radius temperatures and the film thickness and can set the pressure difference needed.
　Furthermore, the curvature radius of the thermoplastic resin film 18 in the process is uniquely determined by the relationship between the pressure applied to the elastic force of the film.
[0029]
　Step c is convex or concave deformation of the curved shape is formed in the thermoplastic resin film 18, by checking the pressure, etc., can be controlled bending of the thermoplastic resin film 18.
　In this embodiment, step c can include based on the position change of the thermoplastic resin film 18 detected by the position sensor, not shown, to control the amount of curvature of the thermoplastic resin film 18 process.
[0030]
　Position sensor may be provided on or in the second space 22 the first space 16. Position sensor detects a change in position of the thermoplastic resin film 18 with a laser or the like, and is configured to sense the bending amount. Then, the control means, by controlling the output of the pressure means or reduced pressure means on the basis of the bending amount, it is possible to control the amount of curvature of the thermoplastic resin film 18. According to this configuration, the thermoplastic resin film 18 bend amount can be accurately set, it is possible to arbitrarily set the curved shape. The reference position of the thermoplastic resin film 18 (variation: 0), for example be a first molding member 14 position of the fixed thermoplastic resin film 18 between the second forming members 24 it can.
　Control means can be based on the position of the thermoplastic resin film 18 which position sensor is read, to grasp the change of the thermoplastic resin film 18 (the bending amount), and controls the output of the pressure means or reduced pressure means .
[0031]
(Step d)
　Then, the curvature of the thermoplastic resin film 18, the other surface 18b of the thermoplastic resin film 18 is stopped in a state of being exposed into the second space 22. Thus, the thermoplastic resin film 18 can be Fugata without contacting the mold or the like.
　In step d, the position sensor and the control means and the like used in step c, and a thermoplastic resin film 18 is curved to a desired shape, the thermoplastic resin in a state of non-contact with the second molding member 24 Film 18 curved in can be stopped.
[0032]
　In the present embodiment can include the step of improving the thermal stability of a curved thermoplastic resin film 18 (heat setting step).
　Temperature in heating again, can be the same temperature or higher and the heating temperature in step b, preferably to less the melting point of the resin constituting the heating temperature ~ the thermoplastic resin film in the heating step . When heating again normally, it is preferable that the predetermined time for holding or contracts with heating.
[0033]
　The reheating step, it is possible to reduce the dimensional change such as thermal shrinkage of the thermoplastic resin film 18. Further, when the thermoplastic resin film 18 is configured by a material that thermally contracts, when allowed to some extent shrinkage at the use temperature or higher temperatures, the shrinkage in the dimensional stability of the effect (assumed operating temperature smaller suppress) can be increased.
　The step c curving the present process and the thermoplastic resin film 18, the first molding member can be performed as a series of steps in a state where the thermoplastic resin film 18 is placed, Supplementary shaped by a simple method film can be obtained.
[0034]
(Step e)
　was then obtained in step d, cooling the thermoplastic resin film 18 that is curved.
　The step can also be performed by another device, and terminates the heating of the thermoplastic resin film 18, it is preferable to cool while maintaining the pressurized state. The cooling may be a method such as to return method, the normal temperature to exit the heating by the heating means to lower the temperature of the medium.
　The present embodiment includes the step as described above, it can be obtained Fugata film.
[0035]
[Applications]
　Supplementary shaped film of this embodiment, the polarization substrate or polarizing plate or polarizing film glasses or sunglasses, a specific wavelength cut film, light control films, reflective concave mirror, in a variety of applications such as light-collecting reflectors it can be used.
　Hereinafter, as an optical material using the Supplementary shaped film of the present embodiment as a polarization element, it will be described plastic polarized lens.
[0036]
[Plastic polarized lens]
　The plastic polarized lens of the present embodiment, the above-described manufacturing method Supplementary shaped film obtained by (polarizing film), a plastic lens substrate having laminated on at least one side of the polarizing film, it can be used with a. Or, only polarization substrate or polarizer made of Supplementary shaped film obtained by the above manufacturing method, can be used as a plastic polarized lens.
[0037]
　The polarizing film can be used, for example, iodine-containing polyvinyl alcohol polarizing film, dichroic dye-containing polyvinyl alcohol polarizing film, various ones such as dichroic dye-containing thermoplastic polyester polarizing film. Polyester polarizing film may include a moisture for the purpose of easily formed from a polyvinyl alcohol polarization film.
　The thickness is usually 1 ~ 500 [mu] m of the polarizing film, preferably in the range of 10 ~ 300 [mu] m.
[0038]
　Polarizing film may be a single-layer structure, polycarbonate, triacetyl cellulose, polyamide, acryl, polyethylene terephthalate, laminated formed by laminating a cyclic olefin copolymer, a sheet made of a cycloolefin polymer or the like to both sides or one side of the polarizing film It can also be a structure.
　In the case of the polarization substrate, or a polarizing plate may be a laminated structure of the lamination of the sheet on either side or both sides of the polarizing substrate or polarizer. The thickness of the polarizing substrate or polarizing plate is usually 10 ~ 2000 .mu.m, preferably in the range of 10 ~ 1000 .mu.m.
[0039]
　Polarizing film, in order to improve the adhesion between the lens substrate resin, a primer (coating) process, chemical treatment (reactive gas, acids or chemical treatment such as an alkali), a corona discharge treatment, plasma treatment, ultraviolet irradiation treatment , electron beam irradiation treatment, surface roughening treatment, flame treatment etch process, one or more preprocessing selected from such cleaning treatment may also be used after performing. Among such pretreatment, a primer coating treatment, chemical treatment, corona discharge treatment, one or two or more selected from plasma treatment is particularly preferred.
　The resin constituting the lens substrate, mention may be made of thermosetting resin or thermoplastic resin.
[0040]
　The thermosetting resins, urethane resins, thiourethane resins, acrylic resins, episulfide resin, allyl diglycol carbonate resin. Thermosetting resins, internal mold release agents, ultraviolet absorbers, antioxidants, light stabilizers, solvent dye, dimming dye, a specific wavelength cut dyes, bluing agents, chain extenders, crosslinking agents, such as fillers it may contain a.
[0041]
　As the thermoplastic resin, polycarbonate, polyamide, polymethylmethacrylate, polyester, polyolefin, polyurethane, polyether ketone, polyether sulfone, polyvinyl chloride, and the like. These may be used as a mixed alloy.
[0042]
　These thermoplastic resins may be added various function-imparting agents. The functionalization agent, for example, UV absorbers, thermal stabilizers, antioxidants, light stabilizers, flame retardants, dimming dye, a specific wavelength cut dyes, pigments, dyes, lubricants, plasticizers, antistatic agents, antifogging , antimicrobial agents, and the like.
[0043]
　In particular, in order to prevent foreign matter during melt kneading in the kneading step and production processes occurs, to add a phosphorus-based heat stabilizer and a hindered phenolic antioxidant it is preferred.
[0044]
　It can also be incorporated release agent as necessary. It is suitably used fatty acid ester as a release agent. Such as stearic acid monoglycerides, lower fatty acid esters such as stearic stearate rate, higher fatty acid esters such as sebacic acid behenate, pentaerythritol esters such as pentaerythritol tetrastearate are used.
[0045]
　Having described embodiments of the present invention, these are illustrative of the present invention, within the range not impairing the effects of the present invention, it is possible to adopt various other configurations.
[0046]
　For example, as shown in FIG. 2, the first molding member 14 comprising a first space 16 which is open at one, placing the thermoplastic resin film 18 so as to cover the opening. Then, to fix the thermoplastic resin film 18 at the open end by a fixing member 20. Thus, the first space portion 16 of one surface 18a side of the thermoplastic resin film 18, so as to partition the space of the other surface 18b side, placing a thermoplastic resin film 18.
[0047]
　Then, as shown in FIG. 2, the inside of the first space portion 16 is pressurized to bend the thermoplastic resin film 18. It is also possible to bend the thermoplastic resin film 18 by reducing the pressure in the first space 16 into the first space portion 16.
[0048]
　Heating process of the thermoplastic resin film 18, when heated by light or infrared can be directly heated from the other surface 18b side of the thermoplastic resin film 18. The step of bending the thermoplastic resin film 18 can be performed by pressurizing the inside of the first space portion 16.
[0049]
　On the other hand, the method shown in FIG. 2 may be performed in the enclosing member (not shown). The enclosing member, a heating means for heating the inner enclosing member, pressurizing means for pressurizing the inner enclosing member with gas or steam, heating means for heating the gas or vapor, pressurizing means for pressurizing the interior first space 16 , an inner first space 16 may be vacuum means are provided for reducing the pressure. Furthermore, the enclosing member, the interior and within the first space 16 of the enclosing member so that it can be kept in a normal pressure, or may be configured to allow air opening.
[0050]
　When carrying out the process shown in FIG. 2 in a surrounding member, the step of bending the thermoplastic resin film 18 can take the following aspects.
(1) while maintaining the internal encircling member to a normal pressure by pressurizing the inside of the first space portion 16, to bend the thermoplastic resin film 18.
(2) pressurizing the interior and the first space portion 16 of the enclosing member, to be greater than the pressure inside the enclosing member the pressure in the first space portion 16, to bend the thermoplastic resin film 18.
(3) reducing the pressure inside of the enclosing member, by pressurizing the inside of the first space portion 16, to bend the thermoplastic resin film 18.
(4) internal and the first space 16 and reduced pressure of the enclosing member, by the pressure in the first space portion 16 is greater than the pressure inside the enclosing member, to bend the thermoplastic resin film 18.
[0051]
　2 has been described by embodiments curving the thermoplastic resin film 18 on the other surface 18b direction, bending the thermoplastic resin film 18 on one surface 18a direction by reducing the pressure in the first space portion 16 It can also be a aspect.
　Incidentally, when it is disposed in the enclosing member, the step of bending the thermoplastic resin film 18 can take the following aspects.
(1) while maintaining the internal encircling member to a normal pressure by reducing the pressure in the first space portion 16, to bend the thermoplastic resin film 18.
(2) while maintaining the first space 16 to atmospheric pressure by pressurizing the interior of the enclosing member, to bend the thermoplastic resin film 18.
(3) internal pressurized enclosing member, by reducing the pressure in the first space portion 16, to bend the thermoplastic resin film 18.
[0052]
　Further, it is also possible to prepare Fugata film as shown in FIG. 3, comprises the following steps.
Step a: a thermoplastic resin film 18, so as to partition the space into the second space 22 of the one first space 16 of the surface 18a side and the other surface 18b side of the film, placing a thermoplastic resin film 18 ( Figure 3 (a)).
Step b: heating the thermoplastic resin film 18.
Step c: by using a pressure difference between the first space 16 and the second space 22, to bend the thermoplastic resin film 18 without using a mold in the first space 16 (FIG. 3 (b)) .
Step d: the curvature of the thermoplastic resin film 18, one surface 18a of the thermoplastic resin film 18 is stopped in a state of being exposed in the first space 16.
Step e: cooling the thermoplastic resin film 18 that is curved.
　Can adopt the same configuration as the embodiment described in FIG. 1, description thereof will be omitted for the same steps.
[0053]
　In step c, to cause a pressure difference between the inside and the first space 16 second space 22 may be the following manner.
(I) while the first molding member 14 maintains the first space 16 to the atmosphere release to atmospheric pressure, is charged with the medium in the second space 22. Note that when circulating the heated medium in the second space 22 can perform step b and step c simultaneously.
The (ii) medium were charged into the first space 16 and the second space 22, to increase towards the pressure of the second space 22. Incidentally, the heated medium when circulating in the first space and / or the second space 22 16 may perform step b and step c simultaneously.
(Iii) by vacuum means of the first molding member 14 while reducing the pressure in the first space 16 is charged with the medium in the second space 22. Note that when circulating the heated medium in the second space 22 can perform step b and step c simultaneously.
(Iv) vacuum means by while reducing the pressure in the first space 16 of the first molding member 14 to maintain the second mold member 24 and the second space 22 to the atmosphere release to normal pressure.
(V) as well as reduce the pressure in the first space 16 by the pressure reducing means of the first molding member 14, the pressure reducing means of the second molding member 24 to reduce the pressure in the second space 22, towards the pressure of the second space 22 It is increased.
[0054]
　Further, in the method for producing a Fugata film as shown in FIG. 3, it is also possible to use a first molding member 14 having, as shown in FIG. 4, the first space 16 of the hemispherical. In the prior art, in the form as shown in FIG. 4, but manufactures Fugata films by adhering the film 18 to the first mold member 14 while the film 18 pressed from the second space 22 side According to this embodiment, without contacting the film 18 to the first molding member 14 can be produced Fugata film.
[0055]
　Step of bending the thermoplastic resin film 18 in the present embodiment, for example, can be controlled by measuring the amount of change by the volume of medium that was used for bending.
　The step of bending the thermoplastic resin film 18 in the present embodiment, for example, in a space on the side of curving advance filled with liquid (such as oil), the amount of liquid pushed out by the thermoplastic resin film 18 is bent in it is also possible to control the end point of the bending.
[0056]
　Further, it is also possible to prepare Fugata film as shown in FIG. 5, comprises the following steps.
Step a: a thermoplastic resin film 18, so as to partition the space into the second space of the one first space 16 and the other surface 18b side of the surface 18a side of the film, placing a thermoplastic resin film 18 (FIG. 5 (a)).
Step b: heating the thermoplastic resin film 18.
Step c: In the first space 16, between the thermoplastic resin film 18 and the mold 32 is in a non-contact state, the thermoplastic resin medium 34 fed between the mold 32 and the thermoplastic resin film 18 Film 18 presses the, bending the thermoplastic resin film 18 by using the difference between the pressure in the second space (Figure 5 (b)).
Step d: To stop the bending of the thermoplastic resin film 18. The other surface 18b of the thermoplastic resin film 18 is exposed to the second space.
Step e: cooling the thermoplastic resin film 18 that is curved.
　Can adopt the same configuration as the embodiment described in FIG. 1, description thereof will be omitted for the same steps.
[0057]
　Step a
　As shown in Figure 5 (a), the first molding member 14 comprising a first space 16 which is open at one, placing the thermoplastic resin film 18 so as to cover the opening. Then, to fix the thermoplastic resin film 18 at the open end by a fixing member 20. Thus, the first space portion 16 of one surface 18a side of the thermoplastic resin film 18, so as to partition the space of the other surface 18b side, placing a thermoplastic resin film 18.
[0058]
　The first inner mold member 14, the mold 32 is disposed vertically movable. Surface 32a of the mold 32 is substantially hemispherical convex. Mold 32, the porous body comprises a myriad of pores; that solidified to flow the medium in one direction by bundling hollow tube, for example, a hollow body hardened bundling pipe-shaped molded body; a plurality of sheets structure using a plate, for example, laminate construction was layered as stacked spaced apart a plurality of plate-flowing media through the gap; structures that formed a plurality of plate in a lattice-like or triangular shape; fibrous body solidified those fibrous; are composed of such, it is possible to supply the medium to the surface 32a of the mold 32.
　The porous body sintered metal; those that have been gathered to those binder coated particulate inorganic (ceramic / metal); sintered ceramic foam metal; plastic granules were gathered particles; foam plastic organic polymer granulate ; cellular rubber; those hardened by bundling hollow fibers; metal, ceramic, plastic, hollow body hardened bundling pipe-like structures made of rubber or the like; metals, ceramics, plastics, plate-like structures made of rubber or the like cavity body was laminated a gap; and the like.
　Mold 32 is provided with medium supply means (not shown) can be supplied to the medium on the surface 32a from the interior of the mold 32. Media can be heated thermoplastic resin film 18, the front and back surfaces of the film is not particularly limited as long as it can provide a pressure differential, e.g., air, inert gas such as nitrogen, water vapor, such as liquid such as water it can be mentioned.
[0059]
Step c
　When the thermoplastic resin film 18 is fixed to the open end by the fixing member 20, the mold 32 is moved in the direction of the thermoplastic resin film 18, the medium from the medium supply means to the surface 32a of the mold 32 34 and supplies. Then, to further increase the mold 32, thereby bending the thermoplastic resin film 18 by the pressing force of the medium 34 (Figure 5 (b)).
[0060]
　By supplying medium 34 to the surface 32a of the mold 32, between the mold 32 and the thermoplastic resin film 18 is formed with a layer of medium 34, a thermoplastic resin film 18 which has been heated by the step b is formed it is possible to transfer the surface shape of the mold 32 without coming into contact with the mold 32.
　That is, the mold 32 is moved toward the thermoplastic film 18, the Yuku push gradually the film 18, and the ejection pressure of the medium 34 to be ejected from the surface of the mold 32, the elastic modulus at a heating temperature of the film 18 and drag on the mold direction due to, for an equilibrium state at a certain distance and pressure was applied and the mold 32 from the opposite direction is balanced, the mold 32 and the film 18 without contact, the shape of the mold 32 There is transferred to the film 18. As a result, it is possible to bend the thermoplastic resin film. This can be carried out in a conventional method similar to the method of forming the shape in contact with the mold takes place, since the molded film is not in contact with the mold, is not affected by the surface roughness of the mold.
[0061]
　As the thermoplastic resin film 18 has a desired shape, adjusting the rising speed of the mold 32, the temperature of the medium 34, the amount of feed, the feed rate and the like. In the present embodiment, the second space on the other surface 18b side of the thermoplastic resin film 18 is opened, on the other surface 18b but the atmospheric pressure is applied, as shown in FIG. 1, on one using the second molding member 24 comprising a second space 22 which is open, the other surface 18b on the second molding member 24 as the other surface 18b of the thermoplastic resin film 18 in the second space 22 is exposed It can be covered. This allows the pressure in the second space 22 is also adjusted.
[0062]
　Further, as shown in FIG. 6, the mold surface can also be used forming mold 36 is a substantially hemispherical concave.
　As for the embodiment of FIGS. 5 and 6, may be used by vertically inverting the entire device, or may be used in the horizontal direction. In either case, the thermoplastic resin film can be Fugata as described above.
[0063]
　As an optical material using the Supplementary shaped film of the present embodiment as a polarization element it can also include glass polarized lens. The glass polarized lens, with the above Supplementary shaped film obtained by the production process (polarizing film), and a glass substrate laminated on at least one surface of the polarizing film can also include those with.
Example
[0064]
　Hereinafter, a more detailed explanation of the present invention through examples, the present invention is not limited thereto.
[0065]
[Embodiment 1]
FIG. 4 Fugata production of a film as shown in
　heating the first molding member 14 to the lower center had a laser transmitting holes having a diameter of 10mm and the second molding members 24 145 degrees (first heating means ) and, after a polyethylene terephthalate polarizing film (thickness 140 microns) horizontally stacked between the members fitted and fixed, set by the laser measurement (Keyence CCD laser displacement sensor LK-G150) the film distance is zero, 120 seconds It was held.
　The second pressurized space 22 at a pressure of 0.04Mpa while maintaining the temperature, and the first space 16 side inflated polyethylene terephthalate polarizing film. Thereafter, while the film distance laser measurements under reduced pressure and pressure by manually atmosphere opening pressure of the second space 22 where it reaches the -5.6Mm, between the film distance from -5.6Mm of -5.2Mm 30 second it was held.
　Further in member of the first molding member 14 to circulate water, while the vacuum and pressure by air release the pressure in the second space 22 manually, 60 between the film distance from -5.6mm to -5.2mm after seconds hold, a first molding member 14 to open the second molding member 24 to obtain the height 5.4 mm, the curved films Fugata curvature radius 130.4Mm.
　Observation of the surface of the curved film was visually absent scratches or foreign material on the surface, it was confirmed to have a very smooth surface. Further, observation of the cross section cut in half curved film, it was confirmed that a substantially spherical.
[0066]
[Embodiment 2]
FIG. 4 Fugata production of a film as shown in
　heating the first molding member 14 to the lower center had a laser transmitting holes having a diameter of 10mm and the second molding members 24 145 degrees (first heating means ) and, after a polyethylene terephthalate polarizing film (thickness 140 microns) horizontally stacked between the members fitted and fixed, set by the laser measurement (Keyence CCD laser displacement sensor LK-G150) the film distance is zero, 120 seconds It was held. The second pressurized space 22 at a pressure of 0.04Mpa while maintaining the temperature, and the first space 16 side inflated polyethylene terephthalate polarizing film. Next, with the vacuum and pressure by manually atmosphere opening pressure of the second space 22 where the film distance laser measuring reaches -7.5Mm, between the film distance from -7.5Mm of -6.5mm 30 seconds was held. Thereafter, the pressure in the second space 22 is depressurized by the air release, where the contracted film to film distance -5.4Mm, while vacuum and pressure by air release the pressure in the second space 22 manually, the film distance was maintained for 30 seconds in between -5.6mm the -5.2Mm. Further in member of the first molding member 14 to circulate water, while the vacuum and pressure by air release the pressure in the second space 22 manually, 60 between the film distance from -5.6mm to -5.2mm after seconds hold, a first molding member 14 to open the second molding member 24 to obtain the height 5.4 mm, the curved films Fugata curvature radius 130.4Mm.
　Observation of the surface of the curved film was visually absent scratches or foreign material on the surface, it was confirmed to have a very smooth surface. Further, observation of the cross section cut in half curved film, it was confirmed that a substantially spherical.
[0067]
Example 3
Production of polarized lens using Fugata film
　m- xylylene diisocyanate 50.6 parts by weight, and 4,8-dimercaptomethyl-1,11-dimercapto-3,6,9-trithiaundecane 4,7 mixture of dimercaptomethyl-1,11-dimercapto-3,6,9-trithiaundecane and 5,7-dimercaptomethyl-1,11-dimercapto-3,6,9-trithiaundecane 49.4 parts by weight of dibutyltin dichloride 0.01 parts by weight of a curing accelerator, Zelec UN as a releasing agent (trademark, manufactured by Stepan Company) 0.1 parts by weight, and Seesorb 709 (Shipro Kasei Co. as an ultraviolet absorber after Ltd.) and 0.05 part by weight and stirred to dissolve, and defoamed under reduced pressure, and served as injection the monomer mixture immediately after preparation. Viscosity at 20 ° C. stirring dissolved after 1 hour was 30 mPa · s.
　Then, two glass mold of the lens casting mold, the two gap portions partitioned by the films Fugata in Example 1, the monomer mixture was injected through a filter after the tube through a 3μm filter. Incidentally, the distance of the narrow gap portion most gap was about 0.5 mm. After injection stoppered lenses casting mold was placed in a hot air circulating oven, heated to over 12 hours 108 ° C. from 25 ° C., 7 hours maintained thereafter 108 ° C., after slow cooling, the lens from the oven Note It was taken out of the mold for the mold. The lens from the lens casting mold was released to obtain a polarizing lens was 2.5 hours annealing at 110 ° C..
[0068]
[Example 4]
　As the porous material, the average pore size 15 [mu] m, a porosity of 15% Porous aluminum, one side machined in a concave shape, the back surface thickness carved in a convex shape was prepared substantially equal material . The porous material, into the space 16 in the mold of Figure 3, the concave surface as the mold 36 of Figure 6 is arranged so as to face the film. That is, in FIG. 6, was placed a second molding member 24 of FIG. 3, instead of the fixed member 20 surrounds. Toward the concave surface of the porous material flowing air (medium 34) at a pressure of 0.02MPa from the back side.
　After the PET uniaxially stretched film having a thickness of 140μm and the second molding member 24 fitted between the first molding member 14, it holds heat the whole at 145 ° temperature 120 seconds, the second space 22 after air was 0.06MPa applied 60 seconds, and the second molding member 24 and the first molding member 14 is cooled to 80 degrees. Thereafter, the pressure in the first space 16 and the second space 22 was stopped and removed processed film bent open fitting.
　When the obtained bending surface of the film was visually observed, there is no flaw or foreign matter on the surface, was confirmed to have a very smooth surface. It was also possible to produce similarly lens in Example 3.
[0069]
　This application claims priority based on Japanese Patent Application No. 2016-032656, filed on February 24, 2016, the entire disclosure of which is incorporated herein.
[0070]
　The present invention may also take the following embodiments.
[1] with a thermoplastic resin film, so as to partition the space into the second space of the one first space and the other surface side of the surface side of the film, placing a thermoplastic resin film,
　the thermoplastic heating the resin film,
　by utilizing the pressure difference between the first said and space the second space, the step of bending said thermoplastic resin film in the space,
　cooling the curved said films When,
including method of Fugata film.
[2] the step of bending said thermoplastic resin film,
　the first by applying one pressure to the inside space or the second space, comprising the step of bending said thermoplastic resin film in the other space, manufacturing method of Supplementary shaped film according to [1].
[3] the step of bending said film,
　comprising the step of bending said first space or one by reducing the pressure of the second space, the thermoplastic resin film depressurized space of [1 manufacturing method of Supplementary shaped film according to.
[4] the step of bending said film,
　said one of the first space or the second space under reduced pressure and the other in space with pressurized, to the thermoplastic resin film in a space whose pressure is reduced to comprising the step of bending, a manufacturing method of Supplementary shaped film according to [1].
[5] the step of bending said thermoplastic resin film,
　one was charged the medium of the first space or the second space, by pressurizing said one space, the thermoplastic comprising the step of bending the resin film into the other space, a manufacturing method of Supplementary shaped film according to [2] or [4].
[6] The step of bending the thermoplastic resin film in the other space,
　by pressurizing the inside space charged with the medium heated in the first space or the second space comprising the step of bending said thermoplastic resin film in the other space at a temperature of 30 ° C. ~ 300 ° C., a manufacturing method of Supplementary shaped film according to [5].
[7] the step of bending said thermoplastic resin film,
　based on the position of the thermoplastic resin film which is detected by the position sensor, comprising the step of controlling the amount of curvature of the thermoplastic resin film, [5] manufacturing method of Supplementary shaped film according to.
[8] prior to said step of cooling the curved the films,
　including the step of heating the curved the film was re-manufacturing method of Supplementary shaped film according to any one of [7] [1].
[9] the reheating step is carried out at a heating temperature ~ of the resin constituting the thermoplastic resin film Tm (melting point) below the temperature in the heating step, the manufacturing method of Supplementary shaped film according to [8].
[10] the step of placing the thermoplastic resin film, the first molding member comprises a first space which is opened to one, with placing the thermoplastic resin film so as to cover the opening, heat comprising the step of fixing the thermoplastic resin film to the open end,
　the step of bending said thermoplastic resin film comprises a first space on one surface of the thermoplastic resin film is exposed, thermoplastic resin film of utilizing the pressure difference between the second space and the other surface is exposed, including the step of bending said thermoplastic resin film in a state not in contact with the inner wall surface of the first molding member, [1] manufacturing method of Supplementary shaped film according to any one of [9] from.
[11] The thermoplastic resin film is at least the back surface of the surface exposed to the first space portion is covered with a second molding member having a second space portion opened to one, according to [10] manufacturing method of Supplementary shaped film of.
[12] The thermoplastic resin film is fixed to the open end of the first molding member, in a state where the other surface of the thermoplastic resin film is exposed to the enclosing member, the thermoplastic resin film and the and the first molding member disposed in the enclosing member,
　the step of curving the thermoplastic resin film while maintaining one of the internal or the first space portion of the enclosing member to a normal pressure, the other under reduced pressure, comprising the step of bending said thermoplastic resin film,
the manufacturing method of Supplementary shaped film according to [10].
[13] The thermoplastic resin film is fixed to the open end of the first molding member, in a state where the other surface of the thermoplastic resin film is exposed to the enclosing member, the thermoplastic resin film and the and the first molding member disposed in the enclosing member,
　the step of curving the thermoplastic resin film while maintaining one of the internal or the first space portion of the enclosing member to a normal pressure, the other by pressurizing, comprising the step of bending said thermoplastic resin film,
the manufacturing method of Supplementary shaped film according to [10].
[14] The thermoplastic resin film is fixed to the open end of the first molding member, in a state where the other surface of the thermoplastic resin film is exposed to the enclosing member, the thermoplastic resin film and the and the first molding member disposed in the enclosing member,
　the step of curving the thermoplastic resin film, an internal or one pressurized of the first space portion of the enclosing member, by reducing the pressure of the other comprising the step of bending said thermoplastic resin film,
the manufacturing method of Supplementary shaped film according to [10].
[15] The step of heating the process and curved the film was again bending the thermoplastic resin film, the thermoplastic resin film line as a series of steps in a state that is placed on the first molding member dividing method of Supplementary shaped film according to any one of [14] from [10].
[16] The in enclosing member includes
　a second heating means for heating the interior of the first heating means or enclosing member for heating the thermoplastic resin film,
　wherein the inside or the first mold member of the enclosing members first and pressure reduction means for reducing the pressure of the first space portion pressurizing means for pressurizing, or the first space portion of the interior or the first mold member of the enclosing member,
is provided, from [12] manufacturing method of Supplementary shaped film according to any one of [15].
[17] The pressurization means comprises a medium introduction means for internal or charged medium in the first space portion of the first mold member of the enclosing member, the manufacture of Supplementary shaped film according to [16] Method.
[18] further includes a third heating means for heating said medium, a manufacturing method of Supplementary shaped film according to [17].
[19] In addition, a position sensor capable of continuously measuring the position of the thermoplastic resin film to bend,
　based on the position of the thermoplastic resin film as measured by the position sensor, the pressing means and a control means for controlling, the method for producing a Supplementary shaped film according to [17] or [18].
[20] is the thermoplastic resin film, polyvinyl alcohol film made, polyester film, polyamide film, polyimide film, polyolefin film is selected from polyvinyl chloride film and polycarbonate film, [1] - [ manufacturing method of Supplementary shaped film according to any one of 19.
[21] [1] - comprising the steps of any one of [20], the production method of the polarizing film.
[22] The thermoplastic resin film, so as to partition the space into the second space of the one first space and the other surface side of the surface side of the film, placing a thermoplastic resin film,
　the thermoplastic heating the resin film,
　by utilizing the pressure difference between the first said and space the second space, the step of bending said thermoplastic resin film in the space,
　cooling the curved said films obtaining a polarizing film,
　a step of laminating a lens substrate at least one surface of the polarizing film
comprises a method of manufacturing a polarizing lens.

WE CLAIM

[Requested item 1]
　A thermoplastic resin film, so as to partition the space into the second space of the one first space and the other surface side of the surface side of the film, placing a thermoplastic resin film,
　the thermoplastic resin film and heating,
　by utilizing the pressure difference between the second space and the first space, a step of bending said thermoplastic resin film in space,
　the curvature of the thermoplastic resin film, the film at least a step of convex curved surface is stopped in a state of being exposed in the space, of the double-sided
　, cooling the curved the films
including method of Fugata film.
[Requested item 2]
　Said step of bending said thermoplastic resin film,
　the first space or pressurizing at least one of the second space, comprising the step of bending said thermoplastic resin film in the space towards the pressure smaller the method of Supplementary shaped film according to claim 1.
[Requested item 3]
　Said step of bending said thermoplastic resin film,
　the first space or by vacuum at least one of the second space, comprising the step of bending said thermoplastic resin film in the space towards the pressure smaller the method of Supplementary shaped film according to claim 1.
[Requested item 4]
　Said step of bending said thermoplastic resin film is
　one to reduce the pressure in the other space with pressurized in the first space or the second space, the thermoplastic resin film in a space whose pressure is reduced to comprising the step of bending, a manufacturing method of Supplementary shaped film according to claim 1.
[Requested item 5]
　It said step of bending said thermoplastic resin film,
　and charged with the medium to one of the first space or the second space, by pressurizing said one space, the thermoplastic resin film comprising the step of bending in the other space, a manufacturing method of Supplementary shaped film according to claim 2 or 4.
[Requested item 6]
　Said step of bending said thermoplastic resin film,
　supplies the medium to the the first space or the second arranged molding tool in space, the thermoplastic resin film opposite to the mold surface using the medium supply means,
　in the first space or the second space, pressing the thermoplastic resin film in medium supplied from the medium supply means between said thermoplastic resin film and the mold and, by utilizing the difference between the pressure in the other space comprises the step of bending said thermoplastic resin film in a state not in contact with the surface of the mold, a manufacturing method of Supplementary shaped film according to claim 2 .
[Requested item 7]
　The mold, the thermoplastic resin film opposite to the surface is substantially hemispherical convex or concave, the manufacturing method of Supplementary shaped film according to claim 6.
[Requested item 8]
　The mold is made of a porous material, manufacturing method of Supplementary shaped film according to claim 6 or 7.
[Requested item 9]
　Said step of bending said thermoplastic resin film in the other space,
　by pressurizing the inside space charged with the medium heated in the first space or the second space, 30 ° C. at a temperature of ~ 300 ° C. comprising the step of bending said thermoplastic resin film in the other space, a manufacturing method of Supplementary shaped film according to claim 5.
[Requested item 10]
　Said step of bending said thermoplastic resin film in the other space,
　based on the position of the thermoplastic resin film which is detected by the position sensor, comprising the step of controlling the amount of curvature of the thermoplastic resin film, wherein manufacturing method of Supplementary shaped film according to claim 5.
[Requested item 11]
　Prior to said step of cooling the curved the films,
　including the step of heating the curved the film was re-manufacturing method of Supplementary shaped film according to any one of claims 1 to 10.
[Requested item 12]
　The reheating step, the carried out at a temperature Tm (melting point) or less of the resin constituting the heating temperature ~ the thermoplastic resin film in the heating step, the manufacturing method of Supplementary shaped film according to claim 11.
[Requested item 13]
　Wherein the step of placing the thermoplastic resin film, the first molding member comprises a first space which is opened to one, with placing the thermoplastic resin film so as to cover the opening, the thermoplastic resin film the comprises the step of securing the open end,
　the step of bending said thermoplastic resin film comprises a first space on one surface of the thermoplastic resin film is exposed, the other of the thermoplastic resin film by utilizing the pressure difference between the second space plane is exposed, including the step of bending said thermoplastic resin film in a state not in contact with the inner wall surface of the first mold member, of claims 1 to 12 manufacturing method of Supplementary type film of any.
[Requested item 14]
　The thermoplastic resin film is at least the back surface of the surface exposed to the first space portion is covered with a second molding member having a second space portion opened to one, Supplementary form according to claim 13 method of producing a film.
[Requested item 15]
　It said thermoplastic resin film is fixed to the open end of the first molding member, in a state where the other surface of the thermoplastic resin film is exposed to the enclosing member, the thermoplastic resin film and the first mold use member is disposed in the enclosing member,
　the step of curving the thermoplastic resin film while maintaining one of the internal or the first space portion of the enclosing member to a normal pressure, reducing the pressure of the other by comprising the step of bending said thermoplastic resin film,
the manufacturing method of Supplementary shaped film according to claim 13.
[Requested item 16]
　It said thermoplastic resin film is fixed to the open end of the first molding member, in a state where the other surface of the thermoplastic resin film is exposed to the enclosing member, the thermoplastic resin film and the first mold use member is disposed in the enclosing member,
　the step of curving the thermoplastic resin film while maintaining one of the internal or the first space portion of the enclosing member to a normal pressure, pressurizing the other by comprising the step of bending said thermoplastic resin film,
the manufacturing method of Supplementary shaped film according to claim 13.
[Requested item 17]
　It said thermoplastic resin film is fixed to the open end of the first molding member, in a state where the other surface of the thermoplastic resin film is exposed to the enclosing member, the thermoplastic resin film and the first mold use member is disposed in the enclosing member,
　the step of curving the thermoplastic resin film, an internal or one pressurized of the first space portion of the enclosing member, by reducing the pressure of the other, the heat comprising the step of bending the thermoplastic resin film,
the manufacturing method of Supplementary shaped film according to claim 13.
[Requested item 18]
　Wherein the step of heating the film obtained by the process and bending curving the thermoplastic resin film again, the thermoplastic resin film on the first molding member is performed as a series of steps in a state of being placed, wherein manufacturing method of Supplementary shaped film according to any of claim 13 17.
[Requested item 19]
　Wherein the enclosing member is
　the thermoplastic and the second heating means for heating the interior of the first heating means or enclosing member for heating the resin film,
　the first space portion of the interior or the first mold member of the enclosing member pressurizing means for pressurizing or pressure reducing means for reducing the pressure of the first space portion of the interior or the first mold member of the enclosing member, and
is provided, one of claims 15 18, manufacturing method of Supplementary shaped film crab according.
[Requested item 20]
　The pressurizing means comprises a medium introduction means for loading the medium to the first space portion of the interior or the first mold member of the enclosing member, the manufacturing method of Supplementary shaped film according to claim 19.
[Requested item 21]
　Further comprising a third heating means for heating said medium, a manufacturing method of Supplementary shaped film according to claim 20.
[Requested item 22]
　Further, a position sensor capable of continuously measuring the position of the thermoplastic resin film to bend,
　based on the position of the thermoplastic resin film as measured by the position sensor, to control the pressurizing means control and means, a method for producing a Supplementary shaped film according to any one of claims 19-21.
[Requested item 23]
　Said thermoplastic resin film, polyvinyl alcohol film made, polyester film, polyamide film, polyimide film, polyolefin film is selected from polyvinyl chloride film and polycarbonate film, any one of claims 1 to 22 manufacturing method of Supplementary shaped film according to.
[Requested item 24]
　Comprising the steps of any of claims 1 to 23, a manufacturing method of the polarizing film.
[Requested item 25]
　A thermoplastic resin film, so as to partition the space into the second space of the one first space and the other surface side of the surface side of the film, placing a thermoplastic resin film,
　the thermoplastic resin film and heating,
　by utilizing the pressure difference between the second space and the first space, a step of bending said thermoplastic resin film in space,
　the curvature of the thermoplastic resin film, the film at least a step of convex curved surface is stopped in a state of being exposed in the space, of the double-sided
　obtaining a polarizing film by cooling a curved said films,
　lens group on at least one surface of the polarizing film laminating the wood,
it comprises a method of manufacturing a polarizing lens.