【TECHNICAL FIELD】
Cross Citation with Related Application(s)
This application claims the benefit of Korean Patent Application No. 10-2021-0067468
filed on May 26, 2021 with the Korean Intellectual Property Office, the content of which is
10 incorporated herein by reference in its entirety.
The present disclosure relates to an electrode assembly for secondary battery including a
separator with a notch groove formed therein and a secondary battery including the same
【BACKGROUND】
Due to the rapid increase in the use of fossil fuels, the demand for the use of alternative
15 energy or clean energy is increasing, and as part thereof, the fields that are being studied most
actively are the fields of power generation and power storage using electrochemistry.
At present, a secondary battery is a representative example of an electrochemical device
that utilizes such electrochemical energy, and the range of use thereof tends to be gradually
expanding.
20 In recent years, as mobile devices, such as portable computers, portable phones, and
cameras, have been increasingly developed, the demand for secondary batteries has also sharply
increased as an energy source for the mobile devices. Among such secondary batteries is a lithium
secondary battery exhibiting high charge/discharge characteristics and lifetime characteristics and
being environmentally friendly, in which much research has been carried out and which is now
25 commercialized and widely used.
Generally, the secondary battery has a structure in which a non-aqueous electrolyte is
impregnated into electrode assembly comprising a positive electrode, a negative electrode, and a
porous separator.
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At this time, the electrodes such as the positive electrode and the negative electrode must be
completely separated, but there is a problem that they contact each other and a short circuit occurs
due to contraction of the separator, protrusion of the electrode active material, and the like.
Generally, when a positive electrode active material and a negative electrode active material
5 are short-circuited, the cell voltage drops along with small heat and the reaction is terminated. In
case of a hard short circuit in which the positive electrode foil and the negative electrode active
material are directly short-circuited, heat generation in mechanical, electrical or thermal abuse
conditions leads to a thermal runaway, which greatly threatens safety.
In particular, such a hard short circuit occurs in the order of short circuit between electrodes,
10 ignition and the like while deformation of the separator and the electrode occurs mainly due to the
contraction of the separator occurring at a high temperature.
Fig. 1 schematically shows a conventional electrode assembly, and Fig. 2 schematically
shows a phenomenon in which the electrode assembly is deformed at a high temperature to occur
a hard short circuit.
15 Referring to Figs. 1 and 2, a stacked body 10 includes a positive electrode 11, a negative
electrode 12, and a separator 13 interposed between the positive electrode 11 and the negative
electrode 12, with the separator 13 being also located at the outermost surface on both sides, and
the stacked body is fixed by at least three pairs of fixing members 14 attached in the stacking
direction for fixing between the separators 13 located at the outermost surface on both sides of the
20 stacked body 10.
When such a stacked body 10 is subsequently used after being manufactured as a secondary
battery, contraction of the separator 13 occurs at a high temperature. Specifically, as the
temperature increases, the contraction of the separator 13 is accelerated, and there is a
predetermined difference depending on the material. However, the contraction in the MD/TD
25 direction at 150°C is about 10% to 20%, and the contraction in the MD/TD direction at 180°C
exceeds 40%, respectively. At this time, the contraction of the separator 13 occurs in a narrow
space between the fixing members 14, whereby the positive electrode 11 is deformed together in
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the stacking direction as in A, and a hard short circuit between the positive electrode 11 and the
negative electrode 12 occurs, which leads to ignition.
Therefore, there is an urgent need to develop a technology that can solve such problems and
delay or prevent hard short circuits between electrodes due to contraction of the separator at high
5 temperatures and thus enhance safety at high temperature.
【DETAILED DESCRIPTION OF THE INVENTION】
【Technical Problem】
The present disclosure has been made to solve the above-mentioned problems and other
technical problems that have yet to be resolved.
10 Specifically, an object of the present disclosure is to provide an electrode assembly for
secondary battery that can prevent hard short circuits between electrodes and improve high
temperature safety by forming a notch groove in the separator of the stacked body and thus
inducing a high-temperature contraction direction and path, and a secondary battery including the
same.
15 【Technical Solution】
According to one aspect of the present disclosure, there is provided an electrode assembly
for secondary battery comprising:
a stacked body that includes a positive electrode, a negative electrode, and a separator
interposed between the positive electrode and the negative electrode, with the separator being
20 located at the outermost surface on both sides; and
at least two pairs of fixing members attached in the stacking direction for fixing between
the separators located at the outermost surface on both sides of the stacked body,
wherein the separator includes at least one pair of notch grooves, and
wherein the pair of notch grooves are formed one by one on one surface perpendicular to
25 a protruding direction of an electrode tab and the other surface located in a diagonal direction
thereof.
At this time, the notch groove is formed in at least two pairs, and the notch grooves may
be formed in a diagonal direction and a linear direction of each surface perpendicular to the
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protruding direction of the electrode tab.
Further, the notch groove may be formed at a position that does not interfere with the
electrode tab.
A planar shape of the notch groove may be a slit-like shape, a polygonal shape, a circular
5 shape, or an elliptical shape.
Meanwhile, the planar shape of the notch groove may be a slit-like shape or a triangular shape.
The fixing member may include polyimide.
The fixing member may be configured such that a pair of fixing members are attached at
positions facing each other on both sides parallel to the protruding direction of the electrode tab,
10 and the other at least one pair of fixing members are attached at a position facing each other on
both sides parallel to the protruding direction of the electrode tab at a position spaced apart from
the pair of fixing members.
Meanwhile, the electrode assembly may be a lamination and stack type electrode assembly or
a stack and folding type electrode assembly.
15 According to another aspect of the present disclosure, there is provided a secondary battery in
which the electrode assembly according to the present disclosure is built in a secondary battery
case together with an electrolyte.
【BRIEF DESCRIPTION OF THE DRAWINGS】
Fig. 1 schematically shows a conventional electrode assembly;
20 Fig. 2 is a schematic view of a form in which a conventional electrode assembly for secondary
battery is deformed at a high temperature so that the separator is contracted;
Fig. 3 is a schematic diagram of an electrode assembly for secondary battery according to an
embodiment of the present disclosure;
Fig. 4 is a schematic view of a form in which the electrode assembly of Fig. 3 is deformed at
25 a high temperature so that the separator is contracted;
Fig. 5 is a schematic diagram of an electrode assembly of a secondary battery according to
another embodiment of the present disclosure;
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Fig. 6 is a schematic view of a form in which the electrode assembly of Fig. 5 is deformed at
a high temperature so that the separator is contracted; and
Fig. 7 is a schematic view which shows the planar shape of the notch groove.
【DETAILED DESCRIPTION OF THE EMBODIMENTS】
5 Hereinafter, the present disclosure will be described in more detail for a better understanding
of the present disclosure.
Terms or words used in the present specification and claims should not be construed as limited
to ordinary or dictionary terms, and the present disclosure should be construed with meanings and
concepts that are consistent with the technical idea of the present disclosure based on the principle
10 that the inventors may appropriately define concepts of the terms to appropriately describe their
own disclosure in the best way.
The technical terms provided herein is merely used for the purpose of describing particular
embodiments only, and is not intended to be limiting of the present disclosure. The singular forms
“a”, “an”, and “the” are intended to include the plural forms as well, unless the context clearly
15 indicates otherwise.
It should be understood that the terms “comprise”, “include”, “have”, etc. are used
herein to specify the presence of stated features, integers, steps, components or combinations
thereof, but do not preclude the presence or addition of one or more other features, integers,
steps, components, or combinations thereof.
20 According to one embodiment of the present disclosure, there is provided an electrode
assembly for secondary battery comprising:
a stacked body that includes a positive electrode, a negative electrode, and a separator
interposed between the positive electrode and the negative electrode, with the separator being
located at the outermost surface on both sides; and
25 at least two pairs of fixing members attached in the stacking direction for fixing between the
separators located at the outermost surface on both sides of the stacked body,
wherein the separator includes at least one pair of notch grooves, and
wherein the pair of notch grooves are formed one by one on one surface perpendicular to a
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protruding direction of an electrode tab and the other surface located in a diagonal direction
thereof.
Fig. 3 schematically shows an electrode assembly 100 for secondary battery according to an
embodiment of the present disclosure.
5 Referring to Fig. 3, the electrode assembly 100 according to the present disclosure includes a
stacked body 110 that includes a positive electrode 111, a negative electrode 112, and a separator
113 interposed between the positive electrode 111 and the negative electrode 112, and present at
the outermost surface on both sides; and at least three pairs of fixing members 114 attached in the
stacking direction for fixing between the separators 113 located at the outermost surface on both
10 sides of the stacked body 110.
The fixing member 114 is provided for fixing the stacked body 110, and may include at least
two pairs of fixing members for firmly fixing the stacked body 110.
At this time, the fixing member 114 is configured such that a pair of fixing members 114a are
attached at positions facing each other on both sides parallel to the protruding direction of the
15 electrode tabs 111a and 112a, and the other at least one pair of fixing members 114b and 114c are
attached at a position facing each other on both sides parallel to the protruding direction of the
electrode tabs 111a and 112a at a position spaced apart from the pair of fixing members 114a.
As the material constituting such a fixing member 114, various materials used for the battery
can be selected, but specifically, a material that has both heat resistance and insulating property
20 and thus does not have a short circuit problem is preferable, and for example, it may include
polyimide.
Further, according to the present disclosure, the separator 113 includes a pair of notch grooves
115 that are formed one by one on one surface perpendicular to the protruding direction of the
electrode tabs 111a and 112a and the other surface located in a diagonal direction thereof, and the
25 notch groove 115 may be formed at a position that does not interfere with the electrode tabs 111a
and 112a, so as to prevent the electrode tab having a first polarity and the electrode active material
layer having a second polarity from contacting with each other and causing a short circuit.
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That is, for example, when the notch groove 114 is formed at a position where it overlaps
with the electrode tabs 111a and 112b, there is a possibility that the positive electrode tab 111a
and the negative electrode active material layer of the negative electrode 112 comes into contact
with each other at the notch groove 115 portion to cause a short circuit. Therefore, in order to
5 prevent these problems, the tabs 111a and 112a are formed at positions that do not interfere with
each other.
Additionally, a pair of notch grooves 115 are specifically formed at horizontally and vertically
symmetrical positions with respect to each other.
Fig. 4 schematically shows a phenomenon in which the separator contracts and deforms when
10 the electrode assembly 100 is exposed to a high temperature.
Referring to Fig. 4, if a pair of notch grooves 115 are formed in the separator 113 as in the
present disclosure, the separator contracts as well when the electrode assembly 100 is exposed to
a high temperature. However, the pair of previously formed notch grooves 115 causes tearing of
the separator in the form of connecting a pair of notch grooves 115, whereby contraction does not
15 occur between the fixing members 114, and the positive electrode 111 and the separator 114 are
not deformed in the stacking direction, thereby capable of preventing a hard short circuit, reducing
the possibility of ignition and thus improving battery safety.
That is, the pair of notch grooves 115 causes tearing of the separator 113 while inducing a
path in which the separator 113 is contracted, thereby preventing deformation of the positive
20 electrode 111 or the negative electrode 112 in the stacking direction.
Meanwhile, a pair of notch grooves may be formed as shown in Figs. 3 to 4, but at least two
pairs may be formed.
Fig. 5 schematically shows an electrode assembly 200 in which two pairs of notch grooves
are formed according to another embodiment of the present disclosure, and Fig. 6 schematically
25 shows a phenomenon in which the separator contracts and deforms when the electrode assembly
is exposed to a high temperature.
First, referring to Fig. 5, the electrode assembly 200 includes a stacked body 210, and three
pairs of fixing members 214 attached in the stacking direction for fixing between the separators
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213 located at the outermost surface on both sides of the stacked body 210, similarly to those
shown in Fig. 3. However, the separator 213 includes two pairs of notch grooves 215 formed in a
diagonal direction and a linear direction on each surface perpendicular to the protruding direction
of the electrode tabs 211a and 212a, and the two pairs of notch grooves 215 are formed at positions
5 that do not interfere with the electrode tabs 211a and 212a. Further, the two pairs of notch grooves
215 are specifically formed in horizontally and vertically symmetrical shapes with respect to each
other.
Referring to Fig. 6, when the electrode assembly 200 in which the two pairs of notch grooves
215 are formed in this way is also exposed to a high temperature, the separator 213 is contracted,
10 and the separator 213 is torn and contracted in a vertical direction or a diagonal direction by the
two pairs of notch grooves 215. Therefore, similarly to the electrode assembly 100 in which a pair
of notch grooves are formed, no contraction occurs between the fixing members 214, and thus, the
positive electrode or the negative electrode and the separator 214 are not deformed in the stacking
direction, thereby capable of preventing a hard short circuit, reducing the possibility of ignition
15 and thus improving battery safety.
If at least two pairs of notch grooves are formed in this way, it is possible to more reliably
induce the path of contraction and tearing of the separator.
Meanwhile, the planar shape of the notch grooves is not limited, and can be formed in various
ways. For example, it may be a slit-like shape, a polygonal shape, a circular shape, or an elliptical
20 shape.
Fig. 7 schematically shows the planar shape of the notch groove 315.
Referring to Fig. 7, the notch groove 315 forms the planar shape into a triangular shape, so
that the contraction and tearing directions of the separator 313 can be induced in a diagonal
direction (Fig 7(a)), or it forms the planar shape into a slit-like shape, so that the contraction and
25 tearing direction of the separator 113 can be induced in a direction in which a slit is formed, that
is, in a linear direction (Fig. 7(b)), or it forms the planar shape into a square shape, so that the
contraction and tearing direction of the separator 113 can be induced in a direction extending from
the lower corners on both sides (Fig 7(c)), or it forms the planar shape into a circular or elliptical
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shape, so that the contraction and tearing direction of the separator 313 can be induced in various
directions.
However, specifically, the planar shape of the notch groove 315 may be a slit-like shape or a
triangular shape so that the direction of contraction and tearing of the separator is constant and
5 thus can minimize influence on the fixing member.
Further, the size of the notch groove is preferably formed into a size in which a short circuit
between the positive electrode and the negative electrode does not occur due to the formation of
the notch groove, that is, a size in which the positive electrode active material layer and the
negative electrode active material layer are not exposed. Within this range, the size is not limited.
10 Meanwhile, the electrode assembly is not limited as long as it has a shape including a stacked
body, and may be a stack type electrode assembly, a lamination and stack type electrode assembly,
or a stack and folding type electrode assembly. Specifically, it may be a lamination and stack type
electrode assembly or a stack and folding type electrode assembly.
Since the detailed manufacturing method and configuration of such an electrode assembly are
15 known in the art, a detailed description thereof will be omitted herein.
Meanwhile, according to another embodiment of the present disclosure, there is provided a
secondary battery in which the electrode assembly is built in a secondary battery case together
with an electrolyte.
At this time, the electrolyte may be a lithium salt non-aqueous electrolyte, and the secondary
20 battery may be a lithium secondary battery.
Since the above configuration is well known in the art, a detailed description thereof will be
omitted herein.
Based on the above disclosure, various applications and modifications can be carried out by
those of ordinary skill in the art without deviating from the spirit and scope of the present
25 disclosure.
【Industrial Applicability】
As described above, the electrode assembly for secondary battery according to an
embodiment of the present disclosure forms a notch groove in the separator and gives an artificial
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defect to the separator, which thus induces the contraction direction and path during contraction
of the separator at a high temperature, thereby exhibiting the effects of delaying and preventing
hard short circuits between electrodes that may occur at high temperature, and thus, preventing
ignition at high temperatures and enhancing the safety of secondary batteries.
5
10
15
20
25
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【CLAIMS】
【Claim 1】
An electrode assembly for secondary battery comprising:
a stacked body that includes a positive electrode, a negative electrode, and a separator
5 interposed between the positive electrode and the negative electrode, with the separator being
located at the outermost surface on both sides; and
at least two pairs of fixing members attached in the stacking direction for fixing between the
separators located at the outermost surface on both sides of the stacked body,
wherein the separator includes at least one pair of notch grooves, and
10 wherein the pair of notch grooves are formed one by one on one surface perpendicular to a
protruding direction of an electrode tab and the other surface located in a diagonal direction
thereof.
【Claim 2】
The electrode assembly for secondary battery according to claim 1, wherein:
15 the notch groove is formed in at least two pairs, and the notch grooves are formed in a diagonal
direction and a linear direction of each surface perpendicular to the protruding direction of the
electrode tab.
【Claim 3】
The electrode assembly for secondary battery according to claim 1, wherein:
20 the notch groove is formed at a position that does not interfere with the electrode tab.
【Claim 4】
The electrode assembly for secondary battery according to claim 1, wherein:
a planar shape of the notch groove is a slit-like shape, a polygonal shape, a circular shape, or
an elliptical shape.
25 【Claim 5】
The electrode assembly for secondary battery according to claim 4, wherein:
the planar shape of the notch groove is a slit-like shape or a triangular shape.
【Claim 6】
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The electrode assembly for secondary battery according to claim 1, wherein:
the fixing member includes polyimide.
【Claim 7】
The electrode assembly for secondary battery according to claim 1, wherein:
5 the fixing member is configured such that a pair of fixing members are attached at positions
facing each other on both sides parallel to the protruding direction of the electrode tab, and the
other at least one pair of fixing members are attached at a position facing each other on both sides
parallel to the protruding direction of the electrode tab at a position spaced apart from the pair of
fixing members.
10 【Claim 8】
The electrode assembly for secondary battery according to claim 1, wherein:
the electrode assembly is a lamination and stack type electrode assembly or a stack and folding
type electrode assembly.
【Claim 9】
15 A secondary battery in which the electrode assembly according to claim 1 is built in a
secondary battery case together with an electrolyte.