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Separating Membrane And Method For Manufacturing Separating Membrane

Abstract: The present invention addresses the problem of providing a separating membrane mainly comprising a thermoplastic resin having high permeability. The present invention relates to a separating membrane including a thermoplastic resin wherein the width of voids in the separating membrane is at least equal to 1 nm and at most equal to 1000 nm and the curvature rate of the voids is at least equal to 1.0 and at most equal to 6.0.

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Patent Information

Application #
Filing Date
27 September 2019
Publication Number
40/2019
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
patent@depenning.com
Parent Application
Patent Number
Legal Status
Grant Date
2021-03-10
Renewal Date

Applicants

TORAY INDUSTRIES, INC.
1-1, Nihonbashi-Muromachi 2-chome, Chuo-ku, Tokyo 1038666

Inventors

1. TAKADA, Koichi
c/o Shiga Plant, Toray Industries, Inc., 1-1, Sonoyama 1-chome, Otsu-shi, Shiga 5208558
2. YAMAMURA, Gohei
c/o Shiga Plant, Toray Industries, Inc., 1-1, Sonoyama 1-chome, Otsu-shi, Shiga 5208558
3. EIMURA, Hiroki
c/o Shiga Plant, Toray Industries, Inc., 1-1, Sonoyama 1-chome, Otsu-shi, Shiga 5208558

Specification

WE CLAIM:
[Claim 1]
A separation membrane comprising a thermoplastic resin, wherein
the separation membrane has voids therein which have a width of 1 nm -1,000 nm,
and
the voids have a tortuosity of 1.0-6.0.
[Claim 2]
The separation membrane according to claim 1 comprising a co-continuous structure that comprises a phase comprising the thermoplastic resin, and the voids.
[Claim 3]
The separation membrane according to claim 1or 2, wherein, in a graph with horizontal axis for wavenumber and vertical axis for intensity, which is obtained by Fourier transformation of a microscopic image photographed in a square visual field with each side having a length 10 times to 100 times the width of the voids of the separation membrane, when a peak half width is set as (a) and a peak maximum wavenumber is set as (b) in the graph, a region of 0 < (a)/(b) <1.5 is included therein.
[Claim 4]
The separation membrane according to any one of claims 1 to 3, which has a membrane permeation flux at 50 kPa and 25℃ of 0.05 m3/m2/h -20 m3/m2/h.
[Claim 5]
The separation membrane according to any one of claims 1 to 4, which has a thickness of 1μm -1,000 μm.
[Claim 6]
The separation membrane according to any one of claims 1 to 5, which has a shape of a hollow fiber.
[Claim 7]

The separation membrane according to claim 6, wherein the shape of a hollow fiber has an outer diameter of 100 μm -5,000 μm.
[Claim 8]
The separation membrane according to any one of claims 1 to 7, wherein the thermoplastic resin comprises at least one compound selected from the group consisting of cellulose esters, polyamides, and polyesters.
[Claim 9]
The separation membrane according to claim 8, wherein the cellulose esters are cellulose acetate propionate and/or cellulose acetate butyrate.
[Claim 10]
The separation membrane according to claim 8, wherein the polyamides are nylon-6 and/or nylon-66.
[Claim 11]
The separation membrane according to claim 8, wherein the polyesters are poly(lactic acid)-based polymers and/or polyethylene terephthalate.
[Claim 12]
A method for producing a separation membrane, comprising:
a resin melting step of melting and kneading 20 wt% to 90 wt% of a thermoplastic resin and 10 wt% to 60 wt% of a structure-forming agent to prepare a molten resin;
a molding step of discharging the molten resin from a discharge spinneret to obtain a membrane-shaped molded product;
a co-continuous structure forming step of subjecting the molten resin or molded product to heat-induced phase separation in a liquid having a temperature of 40-220℃ to form a co-continuous structure, which includes a first phase comprising the thermoplastic resin and a second phase partially compatible with the first phase; and
an eluting step of eluting the second phase from the molded product to form voids, after the co-continuous structure forming step and the molding step.

[Claim 13]
The method for producing a separation membrane according to claim 12, wherein the thermoplastic resin is a cellulose ester.
[Claim 14]
The method for producing a separation membrane according to claim 12 or claim 13, wherein a spinning spinneret is used as the discharge spinneret in the molding step to form a hollow fiber.

Documents

Application Documents

# Name Date
1 201947039098.pdf 2019-09-27
2 201947039098-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [27-09-2019(online)].pdf 2019-09-27
3 201947039098-STATEMENT OF UNDERTAKING (FORM 3) [27-09-2019(online)].pdf 2019-09-27
4 201947039098-PROOF OF RIGHT [27-09-2019(online)].pdf 2019-09-27
5 201947039098-PRIORITY DOCUMENTS [27-09-2019(online)].pdf 2019-09-27
6 201947039098-FORM 1 [27-09-2019(online)].pdf 2019-09-27
7 201947039098-DRAWINGS [27-09-2019(online)].pdf 2019-09-27
8 201947039098-DECLARATION OF INVENTORSHIP (FORM 5) [27-09-2019(online)].pdf 2019-09-27
9 201947039098-COMPLETE SPECIFICATION [27-09-2019(online)].pdf 2019-09-27
10 201947039098-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [27-09-2019(online)].pdf 2019-09-27
11 201947039098-RELEVANT DOCUMENTS [30-09-2019(online)].pdf 2019-09-30
12 201947039098-MARKED COPIES OF AMENDEMENTS [30-09-2019(online)].pdf 2019-09-30
13 201947039098-FORM 13 [30-09-2019(online)].pdf 2019-09-30
14 201947039098-AMMENDED DOCUMENTS [30-09-2019(online)].pdf 2019-09-30
15 abstract_201947039098.jpg 2019-10-01
16 201947039098-FORM-26 [01-10-2019(online)].pdf 2019-10-01
17 Correspondence by Agent_Form-1 And POA_03-10-2019.pdf 2019-10-03
18 201947039098-RELEVANT DOCUMENTS [23-01-2020(online)].pdf 2020-01-23
19 201947039098-MARKED COPIES OF AMENDEMENTS [23-01-2020(online)].pdf 2020-01-23
20 201947039098-FORM 13 [23-01-2020(online)].pdf 2020-01-23
21 201947039098-AMMENDED DOCUMENTS [23-01-2020(online)].pdf 2020-01-23
22 201947039098-FORM 3 [20-02-2020(online)].pdf 2020-02-20
23 201947039098-FORM 18 [02-04-2020(online)].pdf 2020-04-02
24 201947039098-FORM 3 [09-04-2020(online)].pdf 2020-04-09
25 201947039098-FER.pdf 2020-08-13
26 201947039098-certified copy of translation [28-10-2020(online)].pdf 2020-10-28
27 201947039098-OTHERS [05-02-2021(online)].pdf 2021-02-05
28 201947039098-Information under section 8(2) [05-02-2021(online)].pdf 2021-02-05
29 201947039098-FORM 3 [05-02-2021(online)].pdf 2021-02-05
30 201947039098-FER_SER_REPLY [05-02-2021(online)].pdf 2021-02-05
31 201947039098-CLAIMS [05-02-2021(online)].pdf 2021-02-05
32 201947039098-PatentCertificate10-03-2021.pdf 2021-03-10
33 201947039098-IntimationOfGrant10-03-2021.pdf 2021-03-10
34 201947039098-RELEVANT DOCUMENTS [24-09-2022(online)].pdf 2022-09-24
35 201947039098-RELEVANT DOCUMENTS [30-09-2023(online)].pdf 2023-09-30

Search Strategy

1 2020-08-0515-39-10E_07-08-2020.pdf

ERegister / Renewals

3rd: 30 Apr 2021

From 30/03/2020 - To 30/03/2021

4th: 30 Apr 2021

From 30/03/2021 - To 30/03/2022

5th: 17 Feb 2022

From 30/03/2022 - To 30/03/2023

6th: 21 Feb 2023

From 30/03/2023 - To 30/03/2024

7th: 16 Feb 2024

From 30/03/2024 - To 30/03/2025

8th: 11 Feb 2025

From 30/03/2025 - To 30/03/2026