Abstract: The present invention addresses the problem of providing a separating membrane mainly comprising a thermoplastic resin having high permeability. The present invention relates to a separating membrane including a thermoplastic resin wherein the width of voids in the separating membrane is at least equal to 1 nm and at most equal to 1000 nm and the curvature rate of the voids is at least equal to 1.0 and at most equal to 6.0.
WE CLAIM:
[Claim 1]
A separation membrane comprising a thermoplastic resin, wherein
the separation membrane has voids therein which have a width of 1 nm -1,000 nm,
and
the voids have a tortuosity of 1.0-6.0.
[Claim 2]
The separation membrane according to claim 1 comprising a co-continuous structure that comprises a phase comprising the thermoplastic resin, and the voids.
[Claim 3]
The separation membrane according to claim 1or 2, wherein, in a graph with horizontal axis for wavenumber and vertical axis for intensity, which is obtained by Fourier transformation of a microscopic image photographed in a square visual field with each side having a length 10 times to 100 times the width of the voids of the separation membrane, when a peak half width is set as (a) and a peak maximum wavenumber is set as (b) in the graph, a region of 0 < (a)/(b) <1.5 is included therein.
[Claim 4]
The separation membrane according to any one of claims 1 to 3, which has a membrane permeation flux at 50 kPa and 25℃ of 0.05 m3/m2/h -20 m3/m2/h.
[Claim 5]
The separation membrane according to any one of claims 1 to 4, which has a thickness of 1μm -1,000 μm.
[Claim 6]
The separation membrane according to any one of claims 1 to 5, which has a shape of a hollow fiber.
[Claim 7]
The separation membrane according to claim 6, wherein the shape of a hollow fiber has an outer diameter of 100 μm -5,000 μm.
[Claim 8]
The separation membrane according to any one of claims 1 to 7, wherein the thermoplastic resin comprises at least one compound selected from the group consisting of cellulose esters, polyamides, and polyesters.
[Claim 9]
The separation membrane according to claim 8, wherein the cellulose esters are cellulose acetate propionate and/or cellulose acetate butyrate.
[Claim 10]
The separation membrane according to claim 8, wherein the polyamides are nylon-6 and/or nylon-66.
[Claim 11]
The separation membrane according to claim 8, wherein the polyesters are poly(lactic acid)-based polymers and/or polyethylene terephthalate.
[Claim 12]
A method for producing a separation membrane, comprising:
a resin melting step of melting and kneading 20 wt% to 90 wt% of a thermoplastic resin and 10 wt% to 60 wt% of a structure-forming agent to prepare a molten resin;
a molding step of discharging the molten resin from a discharge spinneret to obtain a membrane-shaped molded product;
a co-continuous structure forming step of subjecting the molten resin or molded product to heat-induced phase separation in a liquid having a temperature of 40-220℃ to form a co-continuous structure, which includes a first phase comprising the thermoplastic resin and a second phase partially compatible with the first phase; and
an eluting step of eluting the second phase from the molded product to form voids, after the co-continuous structure forming step and the molding step.
[Claim 13]
The method for producing a separation membrane according to claim 12, wherein the thermoplastic resin is a cellulose ester.
[Claim 14]
The method for producing a separation membrane according to claim 12 or claim 13, wherein a spinning spinneret is used as the discharge spinneret in the molding step to form a hollow fiber.
| # | Name | Date |
|---|---|---|
| 1 | 201947039098.pdf | 2019-09-27 |
| 2 | 201947039098-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [27-09-2019(online)].pdf | 2019-09-27 |
| 3 | 201947039098-STATEMENT OF UNDERTAKING (FORM 3) [27-09-2019(online)].pdf | 2019-09-27 |
| 4 | 201947039098-PROOF OF RIGHT [27-09-2019(online)].pdf | 2019-09-27 |
| 5 | 201947039098-PRIORITY DOCUMENTS [27-09-2019(online)].pdf | 2019-09-27 |
| 6 | 201947039098-FORM 1 [27-09-2019(online)].pdf | 2019-09-27 |
| 7 | 201947039098-DRAWINGS [27-09-2019(online)].pdf | 2019-09-27 |
| 8 | 201947039098-DECLARATION OF INVENTORSHIP (FORM 5) [27-09-2019(online)].pdf | 2019-09-27 |
| 9 | 201947039098-COMPLETE SPECIFICATION [27-09-2019(online)].pdf | 2019-09-27 |
| 10 | 201947039098-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [27-09-2019(online)].pdf | 2019-09-27 |
| 11 | 201947039098-RELEVANT DOCUMENTS [30-09-2019(online)].pdf | 2019-09-30 |
| 12 | 201947039098-MARKED COPIES OF AMENDEMENTS [30-09-2019(online)].pdf | 2019-09-30 |
| 13 | 201947039098-FORM 13 [30-09-2019(online)].pdf | 2019-09-30 |
| 14 | 201947039098-AMMENDED DOCUMENTS [30-09-2019(online)].pdf | 2019-09-30 |
| 15 | abstract_201947039098.jpg | 2019-10-01 |
| 16 | 201947039098-FORM-26 [01-10-2019(online)].pdf | 2019-10-01 |
| 17 | Correspondence by Agent_Form-1 And POA_03-10-2019.pdf | 2019-10-03 |
| 18 | 201947039098-RELEVANT DOCUMENTS [23-01-2020(online)].pdf | 2020-01-23 |
| 19 | 201947039098-MARKED COPIES OF AMENDEMENTS [23-01-2020(online)].pdf | 2020-01-23 |
| 20 | 201947039098-FORM 13 [23-01-2020(online)].pdf | 2020-01-23 |
| 21 | 201947039098-AMMENDED DOCUMENTS [23-01-2020(online)].pdf | 2020-01-23 |
| 22 | 201947039098-FORM 3 [20-02-2020(online)].pdf | 2020-02-20 |
| 23 | 201947039098-FORM 18 [02-04-2020(online)].pdf | 2020-04-02 |
| 24 | 201947039098-FORM 3 [09-04-2020(online)].pdf | 2020-04-09 |
| 25 | 201947039098-FER.pdf | 2020-08-13 |
| 26 | 201947039098-certified copy of translation [28-10-2020(online)].pdf | 2020-10-28 |
| 27 | 201947039098-OTHERS [05-02-2021(online)].pdf | 2021-02-05 |
| 28 | 201947039098-Information under section 8(2) [05-02-2021(online)].pdf | 2021-02-05 |
| 29 | 201947039098-FORM 3 [05-02-2021(online)].pdf | 2021-02-05 |
| 30 | 201947039098-FER_SER_REPLY [05-02-2021(online)].pdf | 2021-02-05 |
| 31 | 201947039098-CLAIMS [05-02-2021(online)].pdf | 2021-02-05 |
| 32 | 201947039098-PatentCertificate10-03-2021.pdf | 2021-03-10 |
| 33 | 201947039098-IntimationOfGrant10-03-2021.pdf | 2021-03-10 |
| 34 | 201947039098-RELEVANT DOCUMENTS [24-09-2022(online)].pdf | 2022-09-24 |
| 35 | 201947039098-RELEVANT DOCUMENTS [30-09-2023(online)].pdf | 2023-09-30 |
| 1 | 2020-08-0515-39-10E_07-08-2020.pdf |