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Sns@Carbon As Alternate Anode For High Capacity Lithium Ion Battry

Abstract: ABSTRACT High capacity lithium-ion battery using SnS@Carbon as an alternate anode are disclosed. Alternate anode materials such as Tin or tin sulfide-decorated nitrogen-doped carbon leaves (Sn-NCL or SnS-NCL) were prepared by a simple pyrolysis of [Sn(Salen)] complex followed by hydrothermal treatment. Fabrication processes for manufacturing such high capacity lithium-ion batteries are disclosed.

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
20 August 2019
Publication Number
09/2021
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
Parent Application
Patent Number
Legal Status
Grant Date
2025-10-28
Renewal Date

Applicants

Pondicherry University
R.V.Nagar, Kalapet, Puducherry 605014, India.

Inventors

1. Dr.P.Elumalai
Department of Green Energy Technology, Madanjeet School of Green Energy Technologies, Pondicherry University, Pondicherry-605014,India.
2. Mr. E. Duraisamy
Department of Green Energy Technology, Madanjeet School of Green Energy Technologies, Pondicherry University, Pondicherry - 605 014, India.
3. Mr. A. Prasath
Department of Green Energy Technology, Madanjeet School of Green Energy Technologies,Pondicherry University, Pondicherry - 605 014, India.
4. Ms. Archana Suresh
Department of Green Energy Technology, Madanjeet School of Green Energy Technologies, Pondicherry University, Pondicherry - 605 014, India.

Specification

CLAIMS
1. A high capacity and high energy density Lithium-ion battery comprising lithium transition metal oxide, a negative electrode, a separator between the positive electrode and the negative electrodes, binders, electrolyte wherein the negative electrode comprises a metal-carbon composite material and the battery having a storage discharge capacity of at least 300 mAh g"1 and an energy density of at least 1000 W h kgv
2. The lithium ion battery of claim 1, wherein the cathode materials are selected from the group of Lithiated transition metal-oxides (LTMO, LiCoCh), NMC622 (LiNio.gMno.2Coo.2O2) orNMC71515 (LiNio.7Mnp.15Coo.15O2).
3. The lithium ion battery of claim 1, wherein the anode materials, metal-carbon composite material selected from the group of Sn, Si, Ge, Zn and Ni @carbon.
4. A high capacity and high energy density Lithium-ion battery of claim 1 comprising:

a) Lithiated transition metal-oxides (LTMO, LiCo02) as cathode, the cathode comprising a binder such as polyvinylidene difluoride (PVDF), Polytetrafluoroethylene (PTFE), poly sodium aery late (PAA); and a conductive additive such as super P carbon, acetylene black, activated carbon
b) slurry was prepared by adding a solvent such as NMP, ethanol and coated on a current collector such as carbon cloth, nickel foam, stainless steel, copper foil and the slurry-pasted substrates are used as electrodes
c) SnS@Carbon used as anode, commercial LTMO (ex. LiCo02) used as cathode and a separator between the anode and the cathode
d) LiPF4 in EC/DEC as the electrolyte

5. The high capacity Lithium-ion battery of claim 1, wherein the processing of
SnS@Carbon used as anode comprising:
a) Synthesis of (H2-salen) ligand by reacting salicylaldehyde and phenylenediamine
b) Synthesis of [Sn(salen)] complex by reacting the (l-h-salen) ligand and tin chloride in a distilled ethanol and acetonitrile (2:3 volume) using a stoichiometric amount
c) Subjecting the [Sn(salen)] complex to pyrolysis at 600 - 800 °C in Ar atmosphere to get Sn-decorated nitrogen-doped carbon leaf (Sn-NCL)
d) Dispersing Sn-NCL sample (0.5 g) in about 40 ml of distilled water by means of ultrasonication
e) Adding 1.5 g thiourea as a sulphide source to this dispersed solution and stirring for about 1-4 hours.
f) Transferring the solution into a Teflon-lined autoclave and kept in a muffle furnace for hydrothermal treatment at about 150 - 240 °C for about 12-24 hours.
g) After the heat treatment, the obtained SnS-decorated nitrogen-doped carbon leaf (SnS-NCL) sample was subjected to centrifugation, washed several times with ethanol and dried at about 100 °C in air.

6. The Lithium-ion battery of claim 1, having high storage discharge capacity in the range of about 300 mAh g"1 to about 500 mAh g'1.
7. The Lithium-ion battery of claim 1, having high energy density in the range of about 1000 W h kg"1 to about 2000 W h kg1.

Documents

Application Documents

# Name Date
1 201941033432-FER.pdf 2025-01-08
1 201941033432-FORM-8 [27-04-2024(online)].pdf 2024-04-27
1 Form2 Title Page_Complete_20-08-2019.pdf 2019-08-20
2 201941033432-FORM-8 [27-04-2024(online)].pdf 2024-04-27
2 201941033432-EVIDENCE OF ELIGIBILTY RULE 24C1f [12-02-2024(online)].pdf 2024-02-12
2 Form 5_As Filed_20-08-2019.pdf 2019-08-20
3 201941033432-EVIDENCE OF ELIGIBILTY RULE 24C1f [12-02-2024(online)].pdf 2024-02-12
3 201941033432-FORM 18A [12-02-2024(online)].pdf 2024-02-12
3 Form 3_As Filed_20-08-2019.pdf 2019-08-20
4 Form 1_As Filed_20-08-2019.pdf 2019-08-20
4 201941033432-FORM 18A [12-02-2024(online)].pdf 2024-02-12
4 201941033432-FORM 18 [29-07-2023(online)].pdf 2023-07-29
5 Drawing_As Filed_20-08-2019.pdf 2019-08-20
5 201941033432-FORM-26 [29-07-2023(online)].pdf 2023-07-29
5 201941033432-FORM 18 [29-07-2023(online)].pdf 2023-07-29
6 Description Complete_As Filed_20-08-2019.pdf 2019-08-20
6 Abstract_As Filed_20-08-2019.pdf 2019-08-20
6 201941033432-FORM-26 [29-07-2023(online)].pdf 2023-07-29
7 Correspondence by Applicant_As Filed_20-08-2019.pdf 2019-08-20
7 Claims_As Filed_20-08-2019.pdf 2019-08-20
7 Abstract_As Filed_20-08-2019.pdf 2019-08-20
8 Claims_As Filed_20-08-2019.pdf 2019-08-20
8 Correspondence by Applicant_As Filed_20-08-2019.pdf 2019-08-20
9 Abstract_As Filed_20-08-2019.pdf 2019-08-20
9 Correspondence by Applicant_As Filed_20-08-2019.pdf 2019-08-20
9 Description Complete_As Filed_20-08-2019.pdf 2019-08-20
10 201941033432-FORM-26 [29-07-2023(online)].pdf 2023-07-29
10 Description Complete_As Filed_20-08-2019.pdf 2019-08-20
10 Drawing_As Filed_20-08-2019.pdf 2019-08-20
11 201941033432-FORM 18 [29-07-2023(online)].pdf 2023-07-29
11 Drawing_As Filed_20-08-2019.pdf 2019-08-20
11 Form 1_As Filed_20-08-2019.pdf 2019-08-20
12 201941033432-FORM 18A [12-02-2024(online)].pdf 2024-02-12
12 Form 1_As Filed_20-08-2019.pdf 2019-08-20
12 Form 3_As Filed_20-08-2019.pdf 2019-08-20
13 201941033432-EVIDENCE OF ELIGIBILTY RULE 24C1f [12-02-2024(online)].pdf 2024-02-12
13 Form 3_As Filed_20-08-2019.pdf 2019-08-20
13 Form 5_As Filed_20-08-2019.pdf 2019-08-20
14 201941033432-FORM-8 [27-04-2024(online)].pdf 2024-04-27
14 Form 5_As Filed_20-08-2019.pdf 2019-08-20
14 Form2 Title Page_Complete_20-08-2019.pdf 2019-08-20
15 201941033432-FER.pdf 2025-01-08
15 Form2 Title Page_Complete_20-08-2019.pdf 2019-08-20
16 201941033432-OTHERS [07-07-2025(online)].pdf 2025-07-07
17 201941033432-FER_SER_REPLY [07-07-2025(online)].pdf 2025-07-07
18 201941033432-DRAWING [07-07-2025(online)].pdf 2025-07-07
19 201941033432-COMPLETE SPECIFICATION [07-07-2025(online)].pdf 2025-07-07
20 201941033432-CLAIMS [07-07-2025(online)].pdf 2025-07-07
21 201941033432-ABSTRACT [07-07-2025(online)].pdf 2025-07-07
22 201941033432-Proof of Right [15-07-2025(online)].pdf 2025-07-15
23 201941033432-US(14)-HearingNotice-(HearingDate-13-10-2025).pdf 2025-09-11
24 201941033432-Correspondence to notify the Controller [19-09-2025(online)].pdf 2025-09-19
25 201941033432-Written submissions and relevant documents [18-10-2025(online)].pdf 2025-10-18
26 201941033432-FORM 13 [27-10-2025(online)].pdf 2025-10-27
27 201941033432-PatentCertificate28-10-2025.pdf 2025-10-28
28 201941033432-IntimationOfGrant28-10-2025.pdf 2025-10-28

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