Abstract: ABSTRACT High capacity lithium-ion battery using SnS@Carbon as an alternate anode are disclosed. Alternate anode materials such as Tin or tin sulfide-decorated nitrogen-doped carbon leaves (Sn-NCL or SnS-NCL) were prepared by a simple pyrolysis of [Sn(Salen)] complex followed by hydrothermal treatment. Fabrication processes for manufacturing such high capacity lithium-ion batteries are disclosed.
CLAIMS
1. A high capacity and high energy density Lithium-ion battery comprising lithium transition metal oxide, a negative electrode, a separator between the positive electrode and the negative electrodes, binders, electrolyte wherein the negative electrode comprises a metal-carbon composite material and the battery having a storage discharge capacity of at least 300 mAh g"1 and an energy density of at least 1000 W h kgv
2. The lithium ion battery of claim 1, wherein the cathode materials are selected from the group of Lithiated transition metal-oxides (LTMO, LiCoCh), NMC622 (LiNio.gMno.2Coo.2O2) orNMC71515 (LiNio.7Mnp.15Coo.15O2).
3. The lithium ion battery of claim 1, wherein the anode materials, metal-carbon composite material selected from the group of Sn, Si, Ge, Zn and Ni @carbon.
4. A high capacity and high energy density Lithium-ion battery of claim 1 comprising:
a) Lithiated transition metal-oxides (LTMO, LiCo02) as cathode, the cathode comprising a binder such as polyvinylidene difluoride (PVDF), Polytetrafluoroethylene (PTFE), poly sodium aery late (PAA); and a conductive additive such as super P carbon, acetylene black, activated carbon
b) slurry was prepared by adding a solvent such as NMP, ethanol and coated on a current collector such as carbon cloth, nickel foam, stainless steel, copper foil and the slurry-pasted substrates are used as electrodes
c) SnS@Carbon used as anode, commercial LTMO (ex. LiCo02) used as cathode and a separator between the anode and the cathode
d) LiPF4 in EC/DEC as the electrolyte
5. The high capacity Lithium-ion battery of claim 1, wherein the processing of
SnS@Carbon used as anode comprising:
a) Synthesis of (H2-salen) ligand by reacting salicylaldehyde and phenylenediamine
b) Synthesis of [Sn(salen)] complex by reacting the (l-h-salen) ligand and tin chloride in a distilled ethanol and acetonitrile (2:3 volume) using a stoichiometric amount
c) Subjecting the [Sn(salen)] complex to pyrolysis at 600 - 800 °C in Ar atmosphere to get Sn-decorated nitrogen-doped carbon leaf (Sn-NCL)
d) Dispersing Sn-NCL sample (0.5 g) in about 40 ml of distilled water by means of ultrasonication
e) Adding 1.5 g thiourea as a sulphide source to this dispersed solution and stirring for about 1-4 hours.
f) Transferring the solution into a Teflon-lined autoclave and kept in a muffle furnace for hydrothermal treatment at about 150 - 240 °C for about 12-24 hours.
g) After the heat treatment, the obtained SnS-decorated nitrogen-doped carbon leaf (SnS-NCL) sample was subjected to centrifugation, washed several times with ethanol and dried at about 100 °C in air.
6. The Lithium-ion battery of claim 1, having high storage discharge capacity in the range of about 300 mAh g"1 to about 500 mAh g'1.
7. The Lithium-ion battery of claim 1, having high energy density in the range of about 1000 W h kg"1 to about 2000 W h kg1.
| # | Name | Date |
|---|---|---|
| 1 | 201941033432-FER.pdf | 2025-01-08 |
| 1 | 201941033432-FORM-8 [27-04-2024(online)].pdf | 2024-04-27 |
| 1 | Form2 Title Page_Complete_20-08-2019.pdf | 2019-08-20 |
| 2 | 201941033432-FORM-8 [27-04-2024(online)].pdf | 2024-04-27 |
| 2 | 201941033432-EVIDENCE OF ELIGIBILTY RULE 24C1f [12-02-2024(online)].pdf | 2024-02-12 |
| 2 | Form 5_As Filed_20-08-2019.pdf | 2019-08-20 |
| 3 | 201941033432-EVIDENCE OF ELIGIBILTY RULE 24C1f [12-02-2024(online)].pdf | 2024-02-12 |
| 3 | 201941033432-FORM 18A [12-02-2024(online)].pdf | 2024-02-12 |
| 3 | Form 3_As Filed_20-08-2019.pdf | 2019-08-20 |
| 4 | Form 1_As Filed_20-08-2019.pdf | 2019-08-20 |
| 4 | 201941033432-FORM 18A [12-02-2024(online)].pdf | 2024-02-12 |
| 4 | 201941033432-FORM 18 [29-07-2023(online)].pdf | 2023-07-29 |
| 5 | Drawing_As Filed_20-08-2019.pdf | 2019-08-20 |
| 5 | 201941033432-FORM-26 [29-07-2023(online)].pdf | 2023-07-29 |
| 5 | 201941033432-FORM 18 [29-07-2023(online)].pdf | 2023-07-29 |
| 6 | Description Complete_As Filed_20-08-2019.pdf | 2019-08-20 |
| 6 | Abstract_As Filed_20-08-2019.pdf | 2019-08-20 |
| 6 | 201941033432-FORM-26 [29-07-2023(online)].pdf | 2023-07-29 |
| 7 | Correspondence by Applicant_As Filed_20-08-2019.pdf | 2019-08-20 |
| 7 | Claims_As Filed_20-08-2019.pdf | 2019-08-20 |
| 7 | Abstract_As Filed_20-08-2019.pdf | 2019-08-20 |
| 8 | Claims_As Filed_20-08-2019.pdf | 2019-08-20 |
| 8 | Correspondence by Applicant_As Filed_20-08-2019.pdf | 2019-08-20 |
| 9 | Abstract_As Filed_20-08-2019.pdf | 2019-08-20 |
| 9 | Correspondence by Applicant_As Filed_20-08-2019.pdf | 2019-08-20 |
| 9 | Description Complete_As Filed_20-08-2019.pdf | 2019-08-20 |
| 10 | 201941033432-FORM-26 [29-07-2023(online)].pdf | 2023-07-29 |
| 10 | Description Complete_As Filed_20-08-2019.pdf | 2019-08-20 |
| 10 | Drawing_As Filed_20-08-2019.pdf | 2019-08-20 |
| 11 | 201941033432-FORM 18 [29-07-2023(online)].pdf | 2023-07-29 |
| 11 | Drawing_As Filed_20-08-2019.pdf | 2019-08-20 |
| 11 | Form 1_As Filed_20-08-2019.pdf | 2019-08-20 |
| 12 | 201941033432-FORM 18A [12-02-2024(online)].pdf | 2024-02-12 |
| 12 | Form 1_As Filed_20-08-2019.pdf | 2019-08-20 |
| 12 | Form 3_As Filed_20-08-2019.pdf | 2019-08-20 |
| 13 | 201941033432-EVIDENCE OF ELIGIBILTY RULE 24C1f [12-02-2024(online)].pdf | 2024-02-12 |
| 13 | Form 3_As Filed_20-08-2019.pdf | 2019-08-20 |
| 13 | Form 5_As Filed_20-08-2019.pdf | 2019-08-20 |
| 14 | 201941033432-FORM-8 [27-04-2024(online)].pdf | 2024-04-27 |
| 14 | Form 5_As Filed_20-08-2019.pdf | 2019-08-20 |
| 14 | Form2 Title Page_Complete_20-08-2019.pdf | 2019-08-20 |
| 15 | 201941033432-FER.pdf | 2025-01-08 |
| 15 | Form2 Title Page_Complete_20-08-2019.pdf | 2019-08-20 |
| 16 | 201941033432-OTHERS [07-07-2025(online)].pdf | 2025-07-07 |
| 17 | 201941033432-FER_SER_REPLY [07-07-2025(online)].pdf | 2025-07-07 |
| 18 | 201941033432-DRAWING [07-07-2025(online)].pdf | 2025-07-07 |
| 19 | 201941033432-COMPLETE SPECIFICATION [07-07-2025(online)].pdf | 2025-07-07 |
| 20 | 201941033432-CLAIMS [07-07-2025(online)].pdf | 2025-07-07 |
| 21 | 201941033432-ABSTRACT [07-07-2025(online)].pdf | 2025-07-07 |
| 22 | 201941033432-Proof of Right [15-07-2025(online)].pdf | 2025-07-15 |
| 23 | 201941033432-US(14)-HearingNotice-(HearingDate-13-10-2025).pdf | 2025-09-11 |
| 24 | 201941033432-Correspondence to notify the Controller [19-09-2025(online)].pdf | 2025-09-19 |
| 25 | 201941033432-Written submissions and relevant documents [18-10-2025(online)].pdf | 2025-10-18 |
| 26 | 201941033432-FORM 13 [27-10-2025(online)].pdf | 2025-10-27 |
| 27 | 201941033432-PatentCertificate28-10-2025.pdf | 2025-10-28 |
| 28 | 201941033432-IntimationOfGrant28-10-2025.pdf | 2025-10-28 |
| 1 | searchE_07-01-2025.pdf |