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Steel Material And Shock Absorbent Member

Abstract: Provided i s a steel material serving as a material for a shock-absorbent member having high impact energy absorption and reduced fracture under impact load, having the chemical composition, expressed in percentage by mass, of C : 0.05-0. 18%, Mn:1-3%, Si+Al: at least 0.5% but less than 2.5%, and N : 0.001-0.015%, and in some cases, Cr: <0.5%, Mo: <0.2%, Ti: <0.05%, N b <0.05%, V <0.2%, and B : <0.002%, with the remainder being Fe and impurities, the material having a steel texture i n which the area ratio oibainite constituted of lath morphology having average spacing of 1 p or smaller i s 70% or above and the area ratio of martensite i s 5-30%, and which satisfies the following formulas (1) and (2): (1) 1.2 < H M o/H o 1.6, (2) 0.90 < {( Mio/HMo)/(HBIO/HBO) Provided i s a steel material serving as a material for a shock-absorbent member having high impact energy absorption and reduced fracture under impact load, having the chemical composition, expressed in percentage by mass, of C : 0.05-0. 18%, Mn: 1-3%, Si+Al: at least 0.5% but less than 2.5%, and N : 0.001-0.015%, and in some cases, Cr: <0.5%, Mo: <0.2%, Ti: <0.05%, N b <0.05%, V <0.2%, and B : <0.002%, with the remainder being Fe and impurities, the material having a steel texture i n which the area ratio oi bainite constituted of lath morphology having average spacing of 1 p or smaller i s 70% or above and the area ratio of martensite i s 5-30%, and which satisfies the following formulas (1) and (2): (1) 1.2 < HMo/HBo≤ 1.6, (2) 0.90 ≤ {(HMio/HMo)/ (HBIO/HBO) £ 1.3, wherein HMo and H M i o represent average nano -hardness, in an initial state and after 10% tensile deformation, of the martensite, and HBO and HBO represent that of the bainite, respectively.

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Patent Information

Application #
Filing Date
15 June 2015
Publication Number
01/2016
Publication Type
INA
Invention Field
METALLURGY
Status
Email
Parent Application
Patent Number
Legal Status
Grant Date
2022-12-15
Renewal Date

Applicants

NIPPON STEEL & SUMITOMO METAL CORPORATION
6- 1, Marunouchi 2- chome Chiyoda- ku, Tokyo 100-8071

Inventors

1. KAWANO, Kaori
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6- 1, Marunouchi 2- chome Chiyoda -ku ,Tokyo 100-8071
2. TASAKA, Masahito
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6- 1 ,Marunouchi 2- chome Chiyoda- ku ,Tokyo 100-8071
3. NAKAZAWA ,Yoshiaki
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6- 1 ,Marunouchi 2- chome Chiyoda -ku, Tokyo 100-8071
4. TANAKA ,Yasuaki
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6- 1 Marunouchi 2- chome Chiyoda- ku ,Tokyo 100-8071
5. TOMIDA ,Toshiro
c/o NIPPON STEEL & SUMITOMO METAL CORPORATION 6- 1, Marunouchi 2- chome Chiyoda -ku ,Tokyo 100-8071

Specification

STEEL MATERIAL AND IMPACT ABSORBING MEMBER 5 Technical Field The present inventi'Sn relates to a steel material and an impact absorbing member. Specifically, the present invention relates to an impact absorbing member in which occurrence of cracking when subjected to an impact load is suppressed and which has a high effective flow stress, and a steel material suitable as a starting 10 material for the impact absorbing member. Background Art In recent years, in order to protect global environment, weight reduction of automobile bodies is demanded as a measure to decrease the amount of CO2 15 discharged from automobiles, and increases in the strength of steel materials for automobiles are required. This is because increase in the strength of steel material will allow decrease of the thickness of steel material for automobiles. On the other hand, there are increased demands for safety bf automobiles in collisions. Accordingly, there is need for not only simply increasing the strength of steel 20 material, but also developing a steel material havmg improved impact resistance upon collision during driving. In such cases, since each portion of a steel material for an automobile is subjected to deformation at a high strain rate of at least several tens of seconds"^ in collision, a high strength steel material having improved dynamic strength properties 25 is required. As such a high strength steel material, there are known a low alloy TRIP steel having a high static-dynamic difference (difference between static strength and dynamic strength), and a high-strength multi-phase structure steel material such as a multi-phase structure steel having a second phase primarily including martensite. RegardiQg the low-alloy TRIP steel, for example. Patent Document 1 discloses 30 a strain induced transformation-type high-strength steel sheet (TRIP steel sheet) having improved dynamic deformation properties and for absorbing automobile collision energy. 2- On the other hand, regarding the multi-phase structure steel sheet having a second phase primarily including martensite, the foUowings are proposed. Patent Document 2 discloses a high-strength steel sheet having improved balance of strength and ductility and a static-dynamic difference of at least 170 MPa, 5 wherein the steel sheet is made up of fine ferrite grains, and the average grain diameter ds of nano crystal grains having a grain diameter of at most 1.2 |im and an average grain diameter dL of micro crystal grains having a grain diameter of more than 1.2 jxm satisfy a relationship of dL/ds > 3. Patent Document 3 discloses a steel sheet having a high static-dynamic ratio, 10 wherein the steel sheet has a dual-phase structure of martensite having an average grain diameter of at most 3 \iva and ferrite having an average grain diameter of at most 5 |im. Patent Document 4 discloses a cold-rolled steel sheet having improved impact absorption properties, wherein the steel sheet contains at least 75% of ferrite phase 15 having an average grain diameter of at most 3.5 \xm, the remainder being tempered martensite. Patent Document 5 discloses a cold-rolled steel sheet having a static-dynamic difference of at least 60 MPa at a strain rate of 5 x 10 to 5 x 10 /s, wherein the steel sheet is made to have a dual-phase structure of ferrite and martensite by pre-straining. 20 Patent Document 6 discloses a high-strength hot-rolled steel sheet having improved impact resistant properties, wherein the steel sheet is made up only of at least 85% of bainite and a hard phase such as martensite. Citation List 25 Patent Document Patent Document 1: Japanese Patent Laid-Open No. 11-80879 Patent Document 2: Japanese Patent Laid-Open No.2006-161077 Patent Document 3: Japanese Patent Laid-Open No.2004-84074 Patent Document 4: Japanese Patent Laid-Open No.2004-277858 30 Patent Document 5: Japanese Patent Laid-Open No.2000-17385 Patent Document 6: Japanese Patent Laid-Open No. 11-269606 Summary of Invention However, a steel material which is a starting material for a conventional impact absorbing member has the following problem. That is, to improve impact absorbing properties of an impact absorbing member (hereafter, also referred to simply as a 5 "member"), it is necessary to increase the strength of the steel material which is a starting material for the impact absorbing member (hereafter, also referred to simply as a "steel material"). As understood from the disclosure in Journal of Japan Society for Technology of Plasticity, vol. 46, No.534, p.641-645, which shows that an average load (Fave) that 10 determines the absorption of the impact energy of steel material is given as: Fave«: (aY-t^)/4, where aY is effective flow stress, and t is sheet thickness, the impact energy greatly depends on the thickness of steel material. Therefore, 15 both a decreased thickness and a high impact absorbing capability for an impact absorbing member only by increasing the strength of steel sheet can be achieved only to some extent. Further, as disclosed in, for example. International Publication Nos. 2005/010396, 2005/010397, and 2005/010398, the absorption of impact energy of an 20 impact absorbing member also greatly depends on its shape. Therefore, there is possibility to rapidly increase the absorption of impact energy of the impact absorbing member to a level which cannot be achieved simply by increasing the strength of steel material, by optimizing the shape of the impact absorbing member so as to increase the plastic deformation work. 25 However, even if the shape of an impact absorbing member is optimized so as to increase the amount of plastic deformation work, crack would have occurred in the impact absorbing member in an early period before the desired plastic deformation is completed, unless the steel material has a deformation capability to be able to endure the amount of plastic deformation work. In such a case, it is not possible to increase 30 the amount of plastic deformation work and therefore is not possible to rapidly increase the absorption of absorption of impact energy thereof. Moreover, if a crack occurs in the impact absorbing member in an early period, an unexpected situation h may be brought in which another member disposed adjacent to this impact absorbing member is damaged. Conventionally, the dynamic strength of steel material has been increased based on the technical concept that the absorption of impact energy of the impact 5 absorbingmember depends on the dynamic strength of steel material. However, simply increasing the dynamic strength of steel material may significantly deteriorate deformation properties. For that reason, even if the shape of the impact absorbing member is optimized so as to increase the amount of plastic deformation work, it is not necessarily possible to dramatically increase the impact energy absorbed by the 10 impact absorbing member. Further, since conventionally the shape of an impact absorbing member has been studied on the assumption that the steel material produced based on the above described technical concept is used, the optimization of the shape of the impact absorbing member has been studied from the beginning on the assumption of 15 deformation capability of conventional steel sheets. For that reason, sufficient study has not been done from the perspective of improving the deformation capability of steel material so as to improve the amount of plastic deformation work as well as optimizing the shape of an impact absorbing member made of the obtained steel material. 20 As described above, to improve the absorption of impact energy of an impact absorbing member, it is important to optimize the shape of the impact absorbing member, in addition to increasing the strength of the steel material which is a starting material for the impact absorbing member so as to increase the amount of plastic deformation work. 25 Regarding the steel material of which is a starting material for an impact absorbing member, in order to optimize the shape of the impact absorbing member so as to increase the amount of plastic deformation work, it is important to increase an effective flow stress of the steel material while suppressing the occurrence of cracking when subjected to an impact load. Further, there is need for improving the 30 robustness of the impact absorbing member such that even when the buckling direction of the impact absorbing member upon collision is different from the T buckling direction assumed at the time of design thereof, cracking is suppressed and high absorption of impact energy is obtained. In order to realize an impact absorbing member having high absorption of impact energy and excellent robustness, the present inventors have studied on steel 5 materials which is a starting material for the impact absorbing member, regarding the means of suppressing the occurrence of cracking, increasing the robustness, and increasing effective flow stress when subjected to an impact load when the steel materials are formed into impact absorbing members, and thus have obtained new findings listed below. 10 (A) To improve the absorption of impact energy of an impact absorbing member, it is effective to increase an effective flow stress when a true strain of 5% is applied (hereafter, referred to as "5% flow stress") to the steel material. (B) To suppress the occurrence of cracking in a member when subject to an impact load, it is effective to improve uniform elongation and local ductility of the 15 steel material. (C) To increase the robustness of a member relating to the suppression of cracking when subject to an impact load, it is effective to improve the local ductility of the steel material. (D) To increase 5% flow stress of a steel material, it is effective to increase 20 yield strength thereof and a work hardening coefficient (n value) in a low strain region. (E) To increase the yield strength and the work hardening coefficient in a low strain region of a steel material, it is necessary that the steel structure of the steel material has a multi-phase structure containing bainite as the main phase, and 25 martensite which is harder than bainite, in a second phase. (F) The yield strength and local ductility of a multi-phase structure steel material having bainite as the main phase depend on the area fraction of bainite and the average interval of a lath structure (hereafter, also referred to as an "average lath interval") of bainite. Therefore, to obtain a high yield strength and a high local 30 ductility in a multi-phase structure steel material having bainite as the main phase, it is necessary to specify a lower limit for the area fraction of bainite, in which an upper limit of the average lath interval is specified. (G) Martensite contained in the second phase contributes to an increase of the work hardening coefficient in a low strain region and an increase in the uniform elongation. Therefore, it is necessary to specify a lower limit of the area fraction of martensite. 5 (H) On the other, excessive large area fraction of martensite will lead, to decrease of local ductility. Therefore, it is necessary to specify an upper limit for the area fraction of martensite. (I) When a hardness ratio between bainite which is the main phase and martensite contained in the second phase is excessively large, mobile dislocations are 10 more likely to be formed by plastic deformation, thereby decreasing the yield strength of the steel material. Therefore, it is necessary to specify an upper limit for the hardness ratio between bainite which is the main phase and martensite. (J) On the other, excessive small hardness ratio between bainite which is the main phase and martensite contained in the second phase will make it difficult to 15 increase the work hardening coefficient in a low strain region, which is obtained by including martensite, and increase the uniform elongation. Therefore, it is necessary to specify a lower limit of the hardness ratio between bainite which is the main phase and martensite. (K) In a multi-phase structure steel material having bainite as the main phase, 20 strain concentrates and work hardening occurs only in bainite by deformation it becomes likely that cracking occurs along a shear band and a grain boundary in bainite, thereby decreasing local ductility. On the other, when the second phase is excessively hardened by plastic deformation, since the hardness difference between the main phase and the second phase increases, it becomes more likely that cracking 25 occurs from an interface therebetween, thereby decreasing local ductility as well. Therefore, to achieve high local ductility in a multi-phase structure steel material containing bainite as the main phase, it is necessary to cause strain to be appropriately distributed between bainite which is the main phase and the second phase. That is, it is necessary that bainite, which is the main phase, and the second phase are subject 30 to a same level of work hardening when plastically deformed. As an index for this, it is preferable to use a proportion of work hardening rates after 10% tensile deformation. That is, in a multi-phase structure steel material containing bainite as > the main phase and martensite in a second phase, it is necessary to specify lower and upper limits for the ratio between the work hardening rate of bainite after 10% tensile deformation and the work hardening rate of martensite after 10% tensile deformation. The present invention, which is based on the above described new findings, is 5 a steel material, comprising a chemical composition containing: by mass%, C: at least 0.05% and at most 0.18%, Mn: at least 1% and at most 3%, Si + Al: at least 0.5% and less than 2.5%, and N: at least 0.001% and at most 0.015%, and fiirther, in some cases, one or two selected fi-om Cr: at most 0.5% and Mo: at most 0.2%, one or more selected from Ti: at most 0.05%, Nb: at most 0.05%, and V: at most 0.2%, and B: at 10 most 0.002%, the remainder being Fe and impurities; and a steel structure containing: by area%, bainite made up of a lath structure having an average interval of at most 1 |im: at least 70%, and martensite: at least 5% and at most 30%, the steel structure satisfying the following Formulas (1) and (2): 1.2 -r- it becomes possible to dramatically improve the absorption of impact energy of the above described impact absorbing member. Figure 1 is an explanatory diagram to show an example of portion to which an impact absorbing member is applied in an automobile body 1. An impact absorbing 5 member having an impact absorbing portion, which absorbs impact energy by being axially crashed and buckled when subjected to an impact from front, rear, or side, can be exemplified by, for example in automobile members, those members as shown by shadowing in Figure 1, specifically, a front crash box 2, a rear crash box 3, a front side member (front frame) 4, a rear side member (rear frame) 5, a front upper rail 6, a 10 side sill (rocker) 7, and members constituting various cross members 8 and the like. Figures 2 and 3 are both two-view diagrams to show an example of the shape of impact absorbing portions 9 and 10. The shape of the impact absorbing portion, for which a tubular body having a closed section is suitable, can be exemplified by tubular bodies having a closed section of a rectangular shape as shown in Figure 2 15 and a closed section of an octagonal shape as shown in Figure 3. Although an example in which the sectional shape is constant in the axial direction is shown in each of Figures 2 and 3, the sectional shape is not limited thereto. The sectional shape may be continuously changed in axial direction. Moreover, although examples in which sectional shapes are a rectangular shape and 20 an octagonal shape are shown in Figures 2 and 3, the sectional shape is not limited thereto. The sectional shape may be any polygonal shape. Further, it may be any shape having a closed section such as a star shape. Moreover, the comers thereof may be rounded. Since an impact absorbing member made of the steel material according to the 25 present invention has excellent robustness, it also has excellent impact absorption capability against impact other than in axial direction. Therefore, the steel material according to the present invention is also suitably applied to an impact absorbing portion in an impact absorbing member, in which the impact absorbing portion absorbs impact energy by being crashed in bending and plastically deformed. The 30 impact absorbing member having the impact absorbing portion for absorbing impact energy by being crashed in bending and plastically deformed can be exemplified by the front crash box 2, the rear crash box 3, the front side member (front frame) 4, the \ - ir- rear side member (rear frame) 5, the front upper rail 6, the side sill (rocker) 7, various cross members 8, a bumper reinforcement 11, and members constituting various pillars such as a center pillar (B post) 12. As well known to a person skilled in the art, some impact absorbing members 5 absorb impact energy through either one of, or both of axial crash and bending. 4. Plating layer The steel material according to the present invention may be made a surface-treated steel material having a plating layer on at least one surface thereof (for example, one or both surfaces thereof when the steel material is a steel sheet) for the 10 purpose of improving corrosion resistance, and so on. The plating layer may be an elecfroplating layer or a hot-dip plating layer. The electroplating layer is exemplified by those by electro-galvanizing, Zn-Ni alloy electroplating, and the like. The hot-dip plating layer is exemplified by those by hot-dip galvanizing, alloyed hot-dip galvanizing, hot-dip Al plating, hot-dip Zn-Al 15 alloy plating, hot-dip Zn-Al-Mg alloy plating, hot-dip Zn-Al-Mg-Si alloy plating, and the like. The mass of deposit of plating is not particularly limited, and may be the same as prior art. Moreover, an appropriate chemical treatment (for example, application and drying of silicate-base chromium-free liquid for chemical conversion) can be 20 applied after plating to fiirther improve corrosion resistance. 5. Manufacturing method The above described steel material according to the present invention is preferably manufactured by the manufacturing method described below. (1) Hot rolling condition 25 It is preferable to obtain hot-rolled steel sheet by performing hot rolling in such a way that a slab having the above described chemical composition is subjected to hot rolling at a total rolling reduction of at least 50% in a temperature range of at least 800°C and at most 950°C, and thereafter the obtained steel sheet is cooled to a temperature range of at least 400°C and at most 500°C starting within 0.4 second 30 after completion of hot rolling and at an average cooling rate of at least 600°C/sec, and is fiirther cooled to a temperature range of at most 350°C at an average cooling rate of at least 20°C/sec and less than 100°C/sec to be coiled. (8- -r- First, applying hot rolling at a total rolling reduction of at least 50% in a temperature range of at least 800°C and at most 950°C to accumulate a large amount of work strain in austenite, and then starting the cooling within 0.4 seconds after completion of hot rolling, and at an average cooling rate of at least 600°C/sec to a 5 temperature range of at least 400°C and at most 500°C makes it possible to obtain bainite structure made up of a fine lath. This cooling is hereafter also referred to as primary cooling. After performing this primary cooling, cooling the steel sheet to a temperature range of at most 350 °C at an average cooling rate of at least 20°C/sec and less than 10 100°C/sec, and thereafter coiling the same makes it possible to cause the retained austenite which has not transformed to bainite to transform into martensite so that the second phase contains martensite. The cooling at this time is hereafter also referred to as secondary cooling. The steel material according to the present invention may be a hot-rolled steel 15 sheet manufactured as described above, or may be a cold-rolled steel sheet which is obtained by subjecting the hot-rolled steel sheet to cold rolling and continuous annealing as described below. Moreover, it may also be a plated steel sheet obtained by plating a hot-rolled steel sheet or cold-rolled steel sheet. (2) Cold rolling, annealing, hot-dip galvanizing 20 When a cold-rolled steel sheet is obtained by subjecting the above described hot-rolled steel sheet to cold rolling and continuous annealing, it is preferable that the cold rolling is performed at a rolling reduction of at least 40% and at most 90%, and the continuous annealing is performed by holding the cold-rolled steel sheet in a temperature range of at least 750°C and at most 900°C for at least 10 seconds and at 25 most 150 seconds, and then cooling the obtained steel sheet to a temperature range of at most 500°C at an average cooling rate of at least 8°C/sec. It is fiirther preferable that the cooling in the continuous annealing is performed by cooling the steel sheet to a temperature range of at most 450°C at an average cooling rate of at least 15°C/sec. After this cooling, a low-temperature heat treatment for holding the steel sheet at a 30 temperature near the cooling temperature may be performed. Performing the cold rolling at a rolling reduction of at least 40% thereby accumulating work strain, and holding the cold-rolled steel sheet in a temperature l°l f' range of at least 750°C and at most 900°C for at least 10 seconds and at most 150 seconds and thereafter cooling it to a temperature range of at most 500°C at an average cooling rate of at least 8°C/sec makes it possible to promote the bainite transformation, and cause the retained austenite which has not transformed to be 5 transformed into martensite, so that the second phase contains martensite. Thus obtained steel sheet may be fiirther subjected to hot-dip galvanizing by immersing it in a hot-dip galvanizing bath to manufacture a hot-dip galvanized steel sheet. After being subjected to the hot-dip galvanizing, the steel sheet may be fiirther subjected to alloying treatment to manufacture an alloyed hot-dip galvanized 10 steel sheet. The alloying treatment is preferably at the temperature of at most 550°C. When hot-dip galvanizing and alloying treatment are applied, it is preferable in view of productivity that a continuous hot-dip galvanizing facility is used to perform continuous annealing and hot-dip galvanizing, and in some cases, alloying treatment in one process step. 15 Examples Experiments were carried out by using slabs (thickness: 35 mm, width: 160 to 250 mm, iand length: 70 to 90 mm) having chemical compositions shown in Table 1. Each of the slabs was obtained by vacuum melting and casting 150 kg of molten steel, 20 thereafter heating the obtained cast sample at an in-fiimace temperature of 1250°C, and hot-forging the same at a temperature of at least 950°C. [Table 1] Steel Type Chemical Composition (Unit mass%, the Renainder Fe and Impurities) Remarks 0 Si Al Mn P S N Or, Mo Other Elements A 0.12 0.51 0.034 2.01 0.001 0.002 0.0024 Or 0.25 Ti: 0.01 Inventive Example B 0.08 0.50 0.033 1.49 0.001 0.005 0.0025 Or 0.25 Mo: 0.13 Ti: 0.02 Nb: 0.020 Inventive Example 0 0.10 1.25 0.033 2.18 0.005 0.002 0.0028 Or 0.15 — Inventive Example D 0.12 0.55 0.032 2.21 0.003 0.002 0.0025 Cr 0.15 Ti: 0.005; V: 0.005; B: 0.001 Inventive Example E 0.15 1.25 0.050 2.48 0.008 0.002 O.0030 — Nb: 0.010 Inventive Example F 0.16 0.51 0.017 2.01 0.013 0.002 0.0046 Or 0.51 Ti: 0.057: Nb: 0.008 Comparative Example G 0.15 0.01 0.033 0.75 0.015 0.001 0.0035 — — Comparative Example H 0.15 0.50 0.033 2.11 0.005 0.002 0.0025 Cr 0.25 Ti: 0.01 ;Nb: 0.005 Inventive Example 2-0 After being subjected to reheating at 1250°C for within 1 hour, each of the above described slabs was subjected to rough hot-rolling of four passes and further to finish hot-rolling of three passes by using a hot-rolling test machine, and a hot-rolled steel sheet was obtained by performing primary cooling and secondary cooling. The hot rolling conditions and cooling conditions are shown in Table 2. [Table 2] Test No. Steel Type Hot Rolling Primary Cooling Secondary Cooling Hotrrolled Steel Sheet Thickness (mm) Rough Hot-rolling Rnish Hot-rolling Average cooling rate (°C/s) Cooling completi on temperat ure (°C) Rolling completion to Cooling start Time (s) Average cooling rate CC/s) Coiling temperat ure (X) Number of passes Total rolling reduction (%) Number of passes Rolling reduction of each pass Rnish rolling temperat ure (°C) 1 A 4 83 3 30«-30%-30X 850 >1000 450 0.1 70 <350 1.63 2 A 4 83 3 30«-30%-30S 850 >1000 650 0.1 80 <350 1.67 3 A 4 83 3 30i6-30%-30» 850 500 700 1.2 80 350 1.62 4 B 4 83 3 30S-30S-30X 850 >1000 450 0.1 80 350 3.02 5 C 4 83 3 30X-30«-30S 850 >1000 450 0.1 80 350 1.65 6 D 4 83 3 30«-30«-30X 850 >1000 450 0.1 80 350 2.99 7 E 4 83 3 30%-30«-30X 900 >1000 450 0.1 80 350 3.01 8 E 4 83 3 30S-30K-30S 850 >1000 500 0.1 80 350 2.89 a G 4 83 3 30X-30K-30S 850 >1000 550 0.1 80 350 1.62 10 H 4 83 3 30«-30»-30X 850 >1000 660 0.1 80 <350 1.65 11 H 4 83 3 30K-30%-30X 850 >1000 450 0.1 80 350 1.66 Some of the hot-rolled steel sheets were subjected to cold rolling, and 10 thereafter to heat treatments under the conditions shown in Table 3 by using a continuous aimealing simulator. Table 3 shows Test Nos. of hot-rolled steel sheets used, and conditions of cold rolling and heat treatment. In Table 3, the cooling rate means a cooling rate after annealing, and the reaching temperature in that cooling is the temperature shown in the column of low temperature heat treatment. 15 [Table 3] Test No. Hot-rolled Steel Sheet (Test No. in Table 3) Steel Type Cold Rolling Reduction (%) Annealing Temperature <°C) Annealing Time (sec) Cooling Rate (°C/sec) Low Temper Heat Treatr ature nent Steel Sheet Thickness (mm) Temperature CO Time (sec) 12 4 B 47 800 120 20 400-450 120 1.65 13 6 D 47 800 120 20 380~400 120 1.62 14 7 E 47 850 120 20 400~450 120 1.66 15 8 F 48 850 120 20 400~450 120 1.58 2^1 r- Each of hot-rolled steel sheets and cold-rolled steel sheets thus obtained was subjected to the following investigations. The test results are summarized in Table 4. In the above described Tables, underlined numerals or symbols indicate that they are out of the range specified in the present invention. 5 Tension Test Tension test was carried out by sampling a JIS 5 tensile test sample from steel sheet to determine yield strength (YS: 0.2% proof stress), tensile strength (TS), 5% flow stress, and uniform elongation (u-El). Hole Expanding Test: 10 To eliminate the effect of end surface damage, reamer processing was performed for a machined hole, and a hole expanding test was carried out otherwise according to Japan Iron and Steel Federation Standard JFS T 1001-1996 to determine a hole expansion ratio. Steel structure: 15 EBSD analysis was carried out on a portion at a depth of 1/4 sheet thickness of a section in parallel with the rolling direction of the steel sheet to obtain a grain boundary face orientation difference map and an image quality map. These maps were used to determine the area fraction of bainite made up of a lath structure having an average interval of at most 1 jim, and the area fraction of martensite. 20 Nano hardness Nano hardness of bainite and martensite was determined by a nanoindentation method. A portion at a depth of 1/4 sheet thickness in a cross section of steel sheet in parallel with the rolling direction was polished with emery paper, and thereafter mechanochemically polished with colloidal silica, and fiorther the affected layer was 25 removed by electrolytic polishing to be subjected to testing. The nanoindentation method was carried out by using a Berkovich type indenter at an indentation load of 500 jiN. The size of indentation in this method was at most 0.1 [xm in diameter. Measurements were made at randomly selected 20 points for each phase of bainite and martensite to determine an average nano hardness for each. Moreover, average 30 nano hardness of bainite and martensite for steel sheets after 10% tensile deformation was determined by the above described method. Impact absorption performance 2-2- 22^- (1) Axial Crash Test Steel sheets to be tested were used to fabricate a rectangular tubular member, and an axial crash test in which the collision speed in the axial direction was 64 km/h was carried out to evaluate collision absorbing performance. The section of the 5 rectangular tubular member perpendicular to the axial direction was a regular octagonal shape, and the axial direction length of the rectangular tubular member was 200 mm. On the above described rectangular tubular members, a relationship between a sectional shape factor (Wp/t), which was defined by using the length (Wp) of one 10 side (the length of a straight portion excepting the curved portions of comer portions) of the above described regular octagon and the sheet thickness (t) of steel sheet, and a impact absorption energy index (Epa) and a crack occurrence rate. Here, the impact absorption energy index (Epa) is a parameter, which is obtained by determining an average stress applied to the above described rectangular 15 tubular member upon buckling and normalizing it by the tensile strength of steel sheet, and is defined by the following Formula (3). [Expression 1] E p, = [Load F,,, /(L • t)] / VTS" (S) 20 Where, Load Fave is the average load applied to the member, L is the circumference of the above described regular polygon, and t is the thickness of steel sheet. A stable buckling ratio is a proportion of the number of test samples in which no cracking occurred in the axial crash test with respect to the total number of 25 samples. In general, as the sectional shape factor (Wp/t) decreases, the absorption of impact energy improves. However, as the sectional shape factor (Wp/t) decreases, the amount of plastic deformation work per unit crash amount increases. For that reason, cracking becomes more likely to occur in the course of crash, and there may 30 be a case in which consequently the amount of work by plastic deformation cannot be increased^ and therefore the absorption of impact energy cannot be improved. ^ (2) Bending crash test Using some of the steel sheets, a hat-type member was fabricated by arc-welding steel sheet formed into a hat shape with a flat steel sheet. This member was subjected to a bending crash test, in which the collision speed was 64 km/h in a direction perpendicular to the axial direction of the member, to evaluate the collision absorbing performance. The results are shown by the absorbed energy and the occurrence or non-occurrence of cracking at the time of bending crash. 25 - Figure 4 is a graph showing the relationship between the average crash load and the 5% flow stress in two deferent sectional shape factors (Wp/t = 20, 16) for Test Nos. 1 to 15. Moreover, Figure 5 is graphs showing the relationship among stable buckling ratio, 5% flow sti'ess, uniform elongation, and hole expansion ratio 5 for each sectional shape factor. Figure 6 is a graph showing the relationship between the absorption of impact energy and the 5% flow stress in the bending crash test. As seen from Table 4, the steel materials according to the present invention exhibited a 5% flow stress of as high as at least 900 MPa, and an average load of as 10 high as at least 0.34 kN/mm^ during axial crash in the axial crash test when a sectional shape factor Wp/t = 20. Moreover, they showed excellent impact absorbing performance in axial crash in that the stable buckling ratio was at least 80% when a sectional shape factor Wp/t = 20, and at least 30% when a sectional shape factor Wp/t = 16. 15 In Comparative Examples, the axial crash load and the stable buckling ratio are not satisfied concurrently, and the axial crash load and/or the stable buckling ratio was low. Further, it can be concluded that the steel materials according to the present invention were excellent in robustness in that they exhibited good impact absorbing 20 performance not only in axial crash but also in bending crash. It can be seen from Figure 4 that as the 5% flow stress increases, the average crash load (impact absorbing performance) in the axial crash test increases. It can be seen from Figure 5 that there is a correlation between the stable buckling ratio, and the 5% flow stress, the uniform elongation, and the hole expansion ratio in the axial 25 crash test, and that as the value of [(uniform elongation x hole expansion ratio)/5% flow stress] increases, the stable buckling ratio increases. Further, it can be seen from Figure 6 that as the 5% flow stress increases, the bending crash absorbing energy increases, and thereby the impact absorbing performance is improved. %Jc. We Claim: 1. A steel material, comprising: a chemical composition containing: by mass%, C: at least 0.05% and at most 5 0.18%, Mn: at least 1% to at most 3%, Si+Al: at least 0.5% and less than 2.5%, and N: at least 0.001% and at most 0.015%, Cr: 0 to 0.5%, Mo: 0 to 0.2%, Ti: 0 to 0.05%, Nb: 0 to 0.05%, V: 0 to 0.2%, and B: 0 to 0.002%, the remainder being Fe and impurities; and a steel structure containing: by area % bainite made up of a lath structure 10 having an average interval of at most 1 |am: at least 70%, and martensite: 5% to 30%, the steel structure satisfying the following Formulas (1) and (2): 1.2

Documents

Application Documents

# Name Date
1 5171-DELNP-2015.pdf 2015-06-16
2 Form 5.pdf 2015-06-24
3 Form 3.pdf 2015-06-24
3 5171-DELNP-2015-Correspondence-240919.pdf 2019-09-26
4 Cover Letter, Form 1, Form 2 along with specification and Abstract.pdf 2015-06-24
5 5171-delnp-2015-GPA-(30-06-2015).pdf 2015-06-30
6 5171-delnp-2015-Correspondence Others-(30-06-2015).pdf 2015-06-30
7 5171-delnp-2015-Form-3-(10-07-2015).pdf 2015-07-10
8 5171-delnp-2015-Form-1-(10-07-2015).pdf 2015-07-10
9 5171-delnp-2015-Correspondence Others-(10-07-2015).pdf 2015-07-10
10 5171-DELNP-2015-FORM 3 [31-08-2017(online)].pdf 2017-08-31
11 5171-DELNP-2015-MARKED COPIES OF AMENDEMENTS [09-10-2017(online)].pdf 2017-10-09
12 5171-DELNP-2015-AMMENDED DOCUMENTS [09-10-2017(online)].pdf 2017-10-09
13 5171-DELNP-2015-Amendment Of Application Before Grant - Form 13 [09-10-2017(online)].pdf 2017-10-09
14 5171-DELNP-2015-FORM 3 [10-07-2018(online)].pdf 2018-07-10
15 5171-DELNP-2015-FER.pdf 2019-03-22
16 5171-DELNP-2015-FORM 3 [20-05-2019(online)].pdf 2019-05-20
17 5171-DELNP-2015-RELEVANT DOCUMENTS [27-06-2019(online)].pdf 2019-06-27
18 5171-DELNP-2015-FORM 13 [27-06-2019(online)].pdf 2019-06-27
19 5171-DELNP-2015-AMENDED DOCUMENTS [27-06-2019(online)].pdf 2019-06-27
20 5171-DELNP-2015-OTHERS-280619.pdf 2019-07-05
21 5171-DELNP-2015-Correspondence-280619.pdf 2019-07-05
22 5171-DELNP-2015-FORM 3 [09-09-2019(online)].pdf 2019-09-09
23 5171-DELNP-2015-PETITION UNDER RULE 137 [12-09-2019(online)].pdf 2019-09-12
24 5171-DELNP-2015-Information under section 8(2) (MANDATORY) [13-09-2019(online)].pdf 2019-09-13
25 5171-DELNP-2015-FORM 3 [13-09-2019(online)].pdf 2019-09-13
26 5171-DELNP-2015-FER_SER_REPLY [13-09-2019(online)].pdf 2019-09-13
27 5171-DELNP-2015-CLAIMS [13-09-2019(online)].pdf 2019-09-13
28 5171-DELNP-2015-Power of Attorney-240919.pdf 2019-09-26
29 5171-DELNP-2015-Correspondence-240919.pdf 2019-09-26
30 5171-DELNP-2015-PatentCertificate15-12-2022.pdf 2022-12-15
31 5171-DELNP-2015-IntimationOfGrant15-12-2022.pdf 2022-12-15

Search Strategy

1 5171delnp2015_20-12-2018.pdf

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