Title of invention : Steel plate and its manufacturing method
Technical field
[0001]
The present invention relates to a steel plate and a manufacturing method thereof.
This application claims priority based on Japanese Patent Application No. 2020-001530 filed in Japan on January 8, 2020, the content of which is incorporated herein.
Background technology
[0002]
In recent years, high-strength steel has been used in automobiles to reduce the weight of the vehicle body, improve fuel efficiency, and reduce carbon dioxide emissions, as well as to absorb collision energy during a collision to ensure the protection and safety of passengers. Steel plates are often used. However, in general, increasing the strength of a steel sheet lowers its deformability (ductility, bendability, etc.), making it easier for the steel sheet to fracture in a localized large strain region caused by impact deformation. Therefore, steel sheets used in automobiles are required to have excellent impact fracture resistance, that is, the property that fracture is unlikely to occur in a localized large strain region caused by impact deformation.
[0003]
For example, Patent Document 1 discloses a high-strength steel sheet with a tensile strength of 900 MPa or more that can achieve both high strength and excellent formability. In Patent Document 1, in the steel structure, in terms of area ratio, ferrite is 5% or more and 80% or less, autotempered martensite is 15% or more, bainite is 10% or less, and retained austenite is 5% or less, as quenched. of the martensite is 40% or less, the average hardness of the autotempered martensite is HV ≤ 700, and the average number of precipitated iron-based carbides of 5 nm or more and 0.5 µm or less in the autotempered martensite is 5 per 1 mm 2 ×10 4 or more.
[0004]
Patent Document 2 discloses a thin steel sheet that has a tensile strength of 900 MPa or more, good weldability, and good elongation. In the steel sheet of Patent Document 2, the area ratio of ferrite is 25% or more and 65% or less, the area ratio of martensite in which iron-based carbides are precipitated in martensite grains is 35% or more and 75% or less, and the remaining structure is the ferrite and The total area ratio is 20% or less (including 0%) other than the martensite, the average grain size of the ferrite and the martensite is 5 μm or less, and Si on the interface between the ferrite and the martensite and Mn having a steel structure with an atomic concentration of 5% or more.
[0005]
In Patent Document 3, a total of 60 area % or more of ferrite and bainite and 3 area % or more and 20 area % or less of retained austenite are contained, and the average grain size of the ferrite and bainite is 0.5 μm or more and 6.0 μm. Hereinafter, a Mn-enriched portion extending in the rolling direction at a depth of 50 μm from the steel plate surface and having a steel structure in which the C concentration in the retained austenite is 0.5% by mass or more and 1.2% by mass or less, and It has an element concentration distribution in which the average spacing of the Si-enriched parts in the direction perpendicular to the rolling direction is 1000 μm or less, the maximum depth of cracks on the steel sheet surface is 4.5 μm or less, and the width is 6 μm or less and the depth is 2 μm or more. The work hardening index (n 3-8 ) is 0.10 or more and bendability satisfies the formula (R/t≦1.5).
[0006]
However, as a result of investigation by the present inventors, it was found that in Patent Documents 1 to 3, there are cases where the impact fracture resistance is not sufficient.
prior art documents
patent literature
[0007]
Patent Document 1: International Publication No. 2009/096596
Patent Document 2: International Publication No. 2018/030503
Patent Document 3: Japanese Patent No. 5659929
SUMMARY OF THE INVENTION
Problems to be Solved by the Invention
[0008]
As described above, the present invention has been made in view of the demand for improved formability and strength as well as improved impact fracture resistance in high-strength steel sheets. The present invention provides high-strength steel sheets (including galvanized steel sheets, zinc alloy-coated steel sheets, alloyed zinc-coated steel sheets, and alloyed zinc alloy-coated steel sheets) that are excellent in formability, strength, and impact fracture resistance, and a method for producing the same. intended to provide
Means to solve problems
[0009]
As a result of investigations to solve the above problems, the inventors obtained the following knowledge.
(a) Fine voids generated in the steel by forming serve as propagation paths for brittle and ductile fractures that occur during impact. Lowering it is effective for improving the impact fracture resistance.
(b) Voids generated in the vicinity of hard cementite due to cold rolling, and voids generated by cold rolling when the hot-rolled steel sheet has a high hardness due to solute carbon, appear to have disappeared by heat treatment (annealing). Since fine voids that open during molding remain in the product, controlling the distribution of cementite and solute carbon before cold rolling is effective in improving impact fracture resistance.
[0010]
The gist of the present invention based on the above findings is as follows.
[1] A steel sheet according to an aspect of the present invention has a chemical composition, in mass%,
C: 0.010 to 0.200%,
Si: 0.005 to 1.500%,
Mn: 0.05-3.00%,
Al: 0.005 to 1.000%,
P: 0.100% or less,
S: 0.0200% or less,
N: 0.0150% or less,
O: 0.0100% or less,
Nb: 0 to 0.060%,
Ti: 0 to 0.100%,
V: 0 to 0.500%,
Cr: 0 to 1.00%,
Ni: 0 to 1.00%,
Cu: 0 to 1.00%,
Mo: 0 to 1.00%,
W: 0 to 1.000%,
B: 0 to 0.0100%,
Sn: 0 to 1.00%,
Sb: 0 to 0.20%, and
one or more of Ca, Ce, Mg, Zr, La and REM: 0 to 0.0100%,
containing, the balance being Fe and impurities,
　The microstructure at the 1/4 position of the plate thickness in the plate thickness direction from the surface is
By volume %, it contains ferrite: 80% or more, martensite: 2% or less, retained austenite: 2% or less,
The ratio of non-recrystallized ferrite in the ferrite is 5% or less,
After 10% tension, the number density of voids with a maximum diameter of 1.0 μm or more in the microstructure at the position of 1/4 of the plate thickness in the plate thickness direction from the surface is 1.0 × 10 9 /m 2 or less. be.
[2] In the steel sheet according to [1] above, the chemical composition is, in mass%,
Nb: 0.005 to 0.060%,
Ti: 0.015 to 0.100%,
V: 0.010 to 0.500%,
Cr: 0.05 to 1.00%,
Ni: 0.05 to 1.00%,
Cu: 0.05 to 1.00%,
Mo: 0.03 to 1.00%,
W: 0.030 to 1.000%,
B: 0.0005 to 0.0100%,
Sn: 0.01 to 1.00%,
Sb: 0.005 to 0.20%, and
Total of one or more of Ca, Ce, Mg, Zr, La and REM: 0.0001 to 0.0100%
It may contain one or more selected from the group consisting of.
[3] In the steel sheet described in [1] or [2] above, the ferrite contained in the microstructure may have an average grain size of 6.0 to 15.0 μm.
[4] The steel sheet according to any one of [1] to [3] above may have a galvanized layer on the surface.
[5] The steel sheet according to any one of [1] to [3] above may have a zinc alloy plating layer on the surface.
[6] In the steel sheet according to [4] or [5] above, the Fe content in the zinc plating layer or the zinc alloy plating layer is 7.0 to 13.0% by mass. good.
[7] A steel plate according to another aspect of the present invention is a method for producing the steel plate according to any one of [1] to [3] above,
A steel slab having the chemical composition described in [1] above is heated to 1150 to 1320 ° C., hot rolling is completed so that the hot rolling completion temperature is 850 to 930 ° C., and after 1.5 seconds or more A hot rolling step of starting cooling and cooling to a temperature range of 500 ° C. or less so that the average cooling rate in the temperature range from the cooling start temperature to 500 ° C. is 20 ° C./s or more to form a hot rolled steel sheet;
a reheating step of heating the hot-rolled steel sheet to a temperature range of 500 to 700°C;
a cooling step of cooling the hot-rolled steel sheet to room temperature;
A cold-rolling step of cold-rolling the hot-rolled steel sheet so that the total rolling reduction is 30-90% and the cold-rolling completion temperature is 120-250°C to obtain a cold-rolled steel sheet;
An annealing step of heating the cold-rolled steel sheet to an annealing temperature of 720 to 850°C and cooling it to a temperature range of 500°C or less,
　In the hot rolling process,
In the temperature range of 1000°C or less, the following formula (1) is satisfied,
　In the reheating process,
　In the temperature range of 500 to 700°C, the following formula (2) is satisfied,
　In the annealing process,
In the heating process to the annealing temperature,
In the temperature range from 720°C to the annealing temperature, a tension of 20 MPa or more is applied, and the following formula (3) is satisfied,
In the cooling process from the annealing temperature,
The following formula (4) is satisfied in the temperature range of 720 to 500°C.
[Number 1]

In the above formula (1), Dn is an index that indicates the progress of precipitation of fine carbides in the temperature range of 1000°C or less in the hot rolling process. Each code|symbol in said Formula (1) represents the following, respectively.
　n: the number of rolling passes performed in a temperature range of 1000°C or less
　Ti: Rolling temperature of i-th pass [°C]
t i: Elapsed time [seconds] from i-th rolling to i+1-th rolling, or elapsed time [seconds] from i-th rolling until the steel plate temperature decreases and reaches 850 ° C.
h i-1: Plate thickness [mm] before i-th pass rolling in a temperature range of 1000 ° C or less
h i: Sheet thickness after i-pass rolling in a temperature range of 1000°C or less [mm]
a 1 to 11: constants (a 1 = 2.54 × 10 -6, a 2 = -3.62 × 10 -4, a 3 = -6.38 × 10 -1, a 4 = -3.00 × 10-1, a5=8.50×10-1, a6=-8.50×10-4, a7=2.40×100, a8=7.83×10-13, a9 = 2.80 × 10 5, a 10 = 6.00 × 10 -12, a 11 = 2.80 × 10 5)
[Number 2]

In the above formula (2), K 20 is the degree of progress of precipitation of the fine carbides in the 20th section when the temperature history in the temperature range of 500 to 700 ° C in the reheating process is equally divided into 20 with respect to time. is an indicator of Each code|symbol in said Formula (2) represents the following, respectively.
　T n: The temperature history in the temperature range of 500 to 700 ° C is divided into 20 equal parts with respect to time, and the average temperature [° C] in the n-th interval
　Δt K: the time obtained by dividing the total staying time in the temperature range of 500 to 700°C by 20 [hr. ], where t 1 =Δt K.
　Si: Content of Si [% by mass]
[Number 3]

Each symbol in the above formula (3) represents the following.
　K 20: the value obtained by the above formula (2)
　d1 and d2: constants (d1=9.67×10 10, d2=1.25×10 4)
T i: Average heat treatment temperature [°C] in the i-th interval obtained by dividing the temperature history in the temperature range from 720°C to the annealing temperature by 10 with respect to time
t': 1/10 second of the residence time in the temperature range from 720°C to the annealing temperature
[Number 4]

In the above formula (4), each code represents the following.
　Δi: 750-18 x Si-17 x Mn-10 x Cr-8 x Ni + 15 x Al-Ti
However, each element shows the content in mass%, and 0 is substituted when the element is not contained. Also, if the calculated value of Δi is a negative value, Δi is set to zero.
g 1 to 6: constants (g 1 = 1.00 × 10 -1, g 2 = 1.46 × 10 -1, g 3 = 1.14 × 10 -1, g 4 = 2.24 × 10 0, g5=4.53×10 0, g6=4.83×10 3)
　Nb, Mo, Si, Mn, Cr, Ni and Al: Content of each element [% by mass], but 0 is substituted if the element is not contained do.
　Ti*: Effective Ti amount represented by Ti−42/14×N, Ti and N indicate the content [mass %] of the element concerned. However, 0 is substituted when the element is not contained. The minimum value is 0.
　T i: Average heat treatment temperature [°C] in the i-th interval obtained by dividing the temperature history in the temperature range of 720 to 500°C by 10 with respect to time
　Ac 1 and Ac 3: Transformation start temperature and transformation completion temperature during heating [°C]
　T max: Maximum heating temperature [°C] in the heat treatment process
　t': 1/10 second of the residence time in the temperature range of 720 to 500 ° C
[8] In the method for manufacturing a steel sheet according to [7] above, the cold-rolled steel sheet may be hot-dip galvanized in the cooling process of the annealing process.
[9] In the method for manufacturing a steel sheet according to [7] above, the cold-rolled steel sheet may be subjected to a hot-dip zinc alloy plating treatment in the cooling process of the annealing process.
[10] The steel sheet according to [8] or [9] may be subjected to an alloying treatment in the cooling process of the annealing process after the hot dip galvanizing treatment or after the hot dip galvanizing treatment.
Effect of the invention
[0011]
According to the above aspect of the present invention, it is possible to provide a steel sheet that is excellent in formability, strength and impact fracture resistance, and a method for producing the same.
MODE FOR CARRYING OUT THE INVENTION
[0012]
The steel sheet and manufacturing conditions thereof according to the present embodiment will be sequentially described below. First, reasons for limiting the chemical composition (chemical composition) of the steel sheet according to the present embodiment will be described. In the numerical limits described below between "-", the lower limit and the upper limit are included in the range. Numerical values ​​indicated as "less than" and "greater than" do not include the value within the numerical range. All % about component composition shows the mass %.
[0013]
The steel sheet according to the present embodiment has a chemical composition in mass% of C: 0.010 to 0.200%, Si: 0.005 to 1.500%, Mn: 0.05 to 3.00%, Al : 0.005 to 1.000%, P: 0.100% or less, S: 0.0200% or less, N: 0.0150% or less, O: 0.0100% or less, Nb: 0 to 0.060% , Ti: 0-0.100%, V: 0-0.500%, Cr: 0-1.00%, Ni: 0-1.00%, Cu: 0-1.00%, Mo: 0- 1.00%, W: 0-1.000%, B: 0-0.0100%, Sn: 0-1.00%, Sb: 0-0.20%, and Ca, Ce, Mg, Zr , La and REM: 0 to 0.0100%, the balance being Fe and impurities. Each element will be described below.
[0014]
C: 0.010-0.200%
C is an element that greatly increases the strength of the steel sheet. If the C content is 0.010% or more, sufficient tensile strength (maximum tensile strength) can be obtained, so the C content is made 0.010% or more. In order to further increase the tensile strength of the steel sheet, the C content is preferably 0.020% or more, more preferably 0.030% or more.
On the other hand, if the C content is 0.200% or less, the amount of ferrite after heat treatment can be controlled to a desired amount, so impact fracture resistance can be ensured. Therefore, the C content is made 0.200% or less. In order to further improve the impact fracture resistance, the C content is preferably 0.180% or less, more preferably 0.150% or less.
[0015]
Si: 0.005-1.500%
Si is an element that refines iron-based carbides and contributes to improving the strength-formability balance. In order to improve the strength-formability balance, the Si content should be 0.005% or more. Preferably, the Si content is 0.025% or more. In particular, from the viewpoint of increasing the strength, it is more preferable to set the Si content to 0.100% or more.
In addition, when the Si content is 1.500% or less, coarse Si oxides that act as starting points for fracture are less likely to be formed, cracks are less likely to occur, embrittlement of steel can be suppressed, and impact fracture resistance can be ensured. Therefore, the Si content is set to 1.500% or less. The Si content is preferably 1.300% or less, more preferably 1.000% or less.
[0016]
　Mn: 0.05 to 3.00%
　Mn is an element that enhances the hardenability of steel and contributes to the improvement of strength. In order to obtain the desired strength, the Mn content should be 0.05% or more. Preferably, it is 0.15% or more.
In addition, when the Mn content is 3.00% or less, it is possible to suppress the deterioration of the macro homogeneity in the steel sheet due to the uneven distribution of Mn during casting, and the desired amount of ferrite can be obtained. It is possible to ensure the moldability of. Therefore, the Mn content is set to 3.00% or less. In order to obtain better moldability, the Mn content is preferably 2.80% or less, more preferably 2.60% or less.
[0017]
Al: 0.005-1.000%
Al is an element that functions as a deoxidizer. If the Al content is 0.005% or more, a sufficient deoxidizing effect can be obtained, so the Al content is made 0.005% or more. It is preferably 0.010% or more, more preferably 0.020% or more.
In addition, Al is an element that forms coarse oxides that serve as starting points for fracture and embrittles steel. When the Al content is 1.000% or less, it is possible to suppress the generation of coarse oxides that act as starting points of fracture, and to suppress the slab from becoming easily cracked. Therefore, the Al content is set to 1.000% or less. The Al content is preferably 0.800% or less, more preferably 0.600% or less.
[0018]
P: 0.100% or less
P is an element that embrittles the steel and embrittles the molten part generated by spot welding. When the P content is 0.100% or less, it is possible to prevent the steel sheet from becoming brittle and easily cracked during the production process. Therefore, the P content is set to 0.100% or less. From the viewpoint of productivity, the P content is preferably 0.050% or less, more preferably 0.030% or less.
Although the lower limit of the P content includes 0%, the lower limit may be 0.001% because the production cost can be further suppressed by setting the P content to 0.001% or more.
[0019]
S: 0.0200% or less
S is an element that forms Mn sulfide and deteriorates formability such as ductility, hole expandability, stretch flangeability and bendability. If the S content is 0.0200% or less, the formability of the steel sheet can be suppressed from significantly deteriorating, so the S content is made 0.0200% or less. The S content is preferably 0.0100% or less, more preferably 0.0080% or less.
Although the lower limit of the S content includes 0%, the lower limit may be 0.0001% because the manufacturing cost can be further suppressed by setting the S content to 0.0001% or more.
[0020]
N: 0.0150% or less
N is an element that forms nitrides and deteriorates formability such as ductility, hole expandability, stretch flangeability and bendability. If the N content is 0.0150% or less, it is possible to suppress deterioration in the formability of the steel sheet, so the N content is made 0.0150% or less. In addition, N is also an element that causes welding defects during welding and hinders productivity. Therefore, the N content is preferably 0.0120% or less, more preferably 0.0100% or less.
The lower limit of the N content includes 0%, but the production cost can be further suppressed by setting the N content to 0.0005% or more, so 0.0005% may be the lower limit.
[0021]
O: 0.0100% or less
O is an element that forms oxides and impairs formability such as ductility, hole expansibility, stretch flangeability and bendability. If the O content is 0.0100% or less, the formability of the steel sheet can be suppressed from significantly deteriorating, so the O content is made 0.0100% or less. It is preferably 0.0080% or less, more preferably 0.0050% or less.
The lower limit of the O content includes 0%, but by setting the O content to 0.0001% or more, the manufacturing cost can be further suppressed, so 0.0001% may be set as the lower limit.
[0022]
The balance of the chemical composition of the steel sheet according to the present embodiment may be Fe and impurities. Examples of impurities include elements that are inevitably mixed from steel raw materials or scraps and/or during the steelmaking process and that are permissible within a range that does not impair the properties of the steel sheet according to the present embodiment. As impurities, H, Na, Cl, Co, Zn, Ga, Ge, As, Se, Tc, Ru, Rh, Pd, Ag, Cd, In, Te, Cs, Ta, Re, Os, Ir, Pt, Au , Pb, Bi, and Po. The total amount of impurities may be 0.100% or less.
[0023]
The steel sheet according to the present embodiment may contain the following elements as optional elements instead of part of Fe. The content is 0% when the following optional elements are not contained.
[0024]
Nb: 0-0.060%
Nb is an element that contributes to the improvement of steel sheet strength through strengthening by precipitates, grain refinement strengthening by suppressing the growth of ferrite grains, and dislocation strengthening by suppressing recrystallization. Since Nb does not necessarily have to be contained, the lower limit of the Nb content includes 0%. The Nb content is preferably 0.005% or more, more preferably 0.015% or more, in order to sufficiently obtain the strength improvement effect of Nb.
In addition, when the Nb content is 0.060% or less, recrystallization can be promoted and the remaining non-recrystallized ferrite can be suppressed, and the formability of the steel sheet can be secured. Therefore, the Nb content is set to 0.060% or less. The Nb content is preferably 0.050% or less, more preferably 0.040% or less.
[0025]
Ti: 0-0.100%
Ti is an element that has the effect of reducing S, N, and O that generate coarse inclusions that act as starting points for fracture. In addition, Ti has the effect of refining the structure and improving the strength-formability balance. Nb is an element that contributes to the improvement of steel sheet strength through strengthening by precipitates, grain refinement strengthening by suppressing the growth of ferrite grains, and dislocation strengthening by suppressing recrystallization. Since Ti does not necessarily have to be contained, the lower limit of the Ti content includes 0%. In order to sufficiently obtain the above effect of Ti, the Ti content is preferably 0.015% or more, more preferably 0.025% or more.
Also, when the Ti content is 0.100% or less, the formation of coarse Ti sulfides, Ti nitrides, and Ti oxides can be suppressed, and the formability of the steel sheet can be ensured. Therefore, the Ti content is set to 0.100% or less. The Ti content is preferably 0.075% or less, more preferably 0.060% or less.
[0026]
　V: 0 to 0.500%
V is an element that contributes to the improvement of steel sheet strength through strengthening by precipitates, grain refinement strengthening by suppressing the growth of ferrite grains, and dislocation strengthening by suppressing recrystallization. Since V does not necessarily have to be contained, the lower limit of the V content includes 0%. The V content is preferably 0.010% or more, more preferably 0.030% or more, in order to sufficiently obtain the strength improvement effect of V.
In addition, when the V content is 0.500% or less, it is possible to suppress the deterioration of the formability of the steel sheet due to the precipitation of a large amount of carbonitrides. Therefore, the V content is set to 0.500% or less.
[0027]
Cr: 0-1.00%
Cr is an element that increases the hardenability of steel and contributes to the improvement of steel sheet strength, and is an element that can partially replace Mn. Since Cr does not necessarily have to be contained, the lower limit of the Cr content includes 0%. The Cr content is preferably 0.05% or more, more preferably 0.20% or more, in order to sufficiently obtain the strength improvement effect of Cr.
In addition, when the Cr content is 1.00% or less, it is possible to suppress the formation of coarse Cr carbides that can serve as starting points for fracture. Therefore, the Cr content is set to 1.00% or less.
[0028]
Ni: 0-1.00%
Ni is an element that suppresses phase transformation at high temperatures and contributes to the improvement of steel sheet strength, and is an element that can partially replace Mn. Since Ni does not necessarily have to be contained, the lower limit of the Ni content includes 0%. The Ni content is preferably 0.05% or more, more preferably 0.20% or more, in order to sufficiently obtain the strength improvement effect of Ni.
In addition, Ni-containing If the amount is 1.00% or less, deterioration of the weldability of the steel sheet can be suppressed, so the Ni content is made 1.00% or less.
[0029]
Cu: 0-1.00%
Cu is an element that exists in steel as fine particles and contributes to improving the strength of the steel sheet, and is an element that can partially replace C and/or Mn. Since Cu does not necessarily have to be contained, the lower limit of the Cu content includes 0%. The Cu content is preferably 0.05% or more, more preferably 0.15% or more, in order to sufficiently obtain the strength improvement effect of Cu.
Also, if the Cu content is 1.00% or less, it is possible to suppress deterioration of the weldability of the steel sheet, so the Cu content is made 1.00% or less.
[0030]
Mo: 0-1.00%
Mo is an element that suppresses phase transformation at high temperatures and contributes to the improvement of steel sheet strength, or is an element that can partially replace Mn. Since Mo does not necessarily have to be contained, the lower limit of the Mo content includes 0%. In order to sufficiently obtain the strength improvement effect of Mo, the Mo content is preferably 0.03% or more, more preferably 0.06% or more.
In addition, when the Mo content is 1.00% or less, it is possible to suppress the decrease in hot workability and productivity. Therefore, Mo content shall be 1.00% or less.
[0031]
W: 0-1.000%
W is an element that suppresses phase transformation at high temperatures and contributes to improvement of steel sheet strength, and is an element that can partially replace C and/or Mn. Since W does not necessarily have to be contained, the lower limit of the W content includes 0%. The W content is preferably 0.030% or more, more preferably 0.100% or more, in order to sufficiently obtain the strength improvement effect of W.
Also, if the W content is 1.000% or less, it is possible to suppress the deterioration of hot workability and productivity, so the W content is made 1.000% or less.
[0032]
B: 0-0.0100%
B is an element that suppresses phase transformation at high temperatures and contributes to the improvement of steel sheet strength, and is an element that can partially replace Mn. Since B does not necessarily have to be contained, the lower limit of the B content includes 0%. The B content is preferably 0.0005% or more, more preferably 0.0010% or more, in order to sufficiently obtain the strength improvement effect of B.
In addition, if the B content is 0.0100% or less, it is possible to suppress the formation of B precipitates and the decrease in strength of the steel sheet, so the B content is made 0.0100% or less.
[0033]
Sn: 0-1.00%
Sn is an element that suppresses the coarsening of crystal grains and contributes to the improvement of steel sheet strength. Since Sn does not necessarily have to be contained, the lower limit of the Sn content includes 0%. In order to sufficiently obtain the effect of Sn, the Sn content is more preferably 0.01% or more.
Also, if the Sn content is 1.00% or less, the steel sheet can be prevented from embrittlement and breakage during rolling, so the Sn content is made 1.00% or less.
[0034]
Sb: 0-0.20%
Sb is an element that suppresses the coarsening of crystal grains and contributes to the improvement of steel sheet strength. Since Sb does not necessarily have to be contained, the lower limit of the Sb content includes 0%. In order to sufficiently obtain the above effects, the Sb content is preferably 0.005% or more.
Also, if the Sb content is 0.20% or less, the steel sheet can be prevented from embrittlement and breakage during rolling, so the Sb content is made 0.20% or less.
[0035]
　One or more of Ca, Ce, Mg, Zr, La and REM: 0 to 0.0100% in total
The chemical composition of the steel sheet according to the present embodiment may contain one or more of Ca, Ce, Mg, Zr, La and REM, if necessary.
　Ca, Ce, Mg, Zr, La and REM are elements that contribute to improving the formability of steel sheets. The lower limit of the sum of one or more of Ca, Ce, Mg, Zr, La and REM includes 0%, but the total is preferably 0.0001% or more in order to sufficiently obtain the effect of improving moldability, 0.0010% or more is more preferable.
Also, when the total content of one or more of Ca, Ce, Mg, Zr, La, and REM is 0.0100% or less, it is possible to suppress a decrease in ductility of the steel sheet. Therefore, the total content of the above elements is set to 0.0100% or less. Preferably, it is 0.0050% or less.
[0036]
REM (Rare Earth Metal) means a group of elements belonging to the lanthanide series, excluding individually specified La and Ce. These are often added in the form of misch metals, but may inevitably contain elements of the lanthanide series in addition to La and Ce.
[0037]
Next, the microstructure of the steel sheet according to this embodiment will be described.
The steel sheet according to the present embodiment has a microstructure at a quarter position of the plate thickness in the plate thickness direction from the surface, in terms of volume%, ferrite: 80% or more, martensite: 2% or less, retained austenite: 2% or less. The ratio of non-recrystallized ferrite to the ferrite is 5% or less.
In the present embodiment, the reason why the microstructure at the 1/4 position of the plate thickness is defined from the surface in the plate thickness direction is that the microstructure at this position indicates a typical microstructure of the steel plate and has a correlation with the mechanical properties of the steel plate. is strong. In addition, all ratios of the following structures in the microstructure are volume ratios (volume %).
[0038]
　Ferrite: 80% or more
Ferrite is a structure with excellent formability. Desired formability can be obtained as the volume fraction of ferrite is 80% or more. Therefore, the volume fraction of ferrite is set to 80% or more. The volume fraction of ferrite is preferably 85% or more, more preferably 90% or more. Since more ferrite is preferable, the volume fraction of ferrite may be 100%.
The ferrite referred to here also includes non-recrystallized ferrite.
[0039]
　Proportion of non-recrystallized ferrite in ferrite: 5% or less
Non-recrystallized ferrite is ferrite in which the strain introduced by cold rolling or the like remains inside. Compared to ordinary ferrite, it has higher strength but lower ductility. Therefore, in the steel sheet according to the present embodiment, the ratio of non-recrystallized ferrite to ferrite is limited to 5% or less. The proportion of non-recrystallized ferrite in ferrite is preferably 3% or less, more preferably 1% or less. In order to improve the formability of the steel sheet, it is more preferable not to contain unrecrystallized ferrite, so the ratio of unrecrystallized ferrite to ferrite may be 0%.
[0040]
　Martensite: 2% or less
Martensite is a structure that increases strength, but it becomes the starting point for the generation of fine voids during molding. If fine voids are generated during molding, desired impact resistance to fracture cannot be obtained. In order to suppress the generation of fine voids during molding, the volume fraction of martensite is set to 2% or less. The volume fraction of martensite is preferably 1% or less, more preferably 0%. In the present embodiment, the volume ratio of "martensite contained in MA (a region composed of both martensite and retained austenite)" is also included in the "martensite volume ratio".
[0041]
　Retained austenite: 2% or less
Retained austenite is a structure that improves the strength-ductility balance of steel sheets, but it also becomes the starting point for the generation of fine voids during forming. In order to suppress the generation of fine voids during molding, the volume fraction of retained austenite is set to 2% or less. The volume fraction of retained austenite is preferably 1% or less, more preferably 0%.
[0042]
Remaining organization: 20% or less
Perlite and bainite are examples of residual structures in the microstructure. By setting the volume fraction of the residual structure to 20% or less, desired impact fracture resistance can be obtained. Therefore, the total volume fraction of these tissues may be 20% or less. The smaller the residual tissue, the better, and it may be 10% or less, 5% or less, or 0%.
[0043]
The method for measuring the volume fraction of the microstructure will be described below.
A test piece is taken from a steel plate, with a cross section parallel to the rolling direction of the steel plate and perpendicular to the steel plate surface as the observation surface. After polishing the observation surface of the test piece, nital etching is performed, and t / 8 to 3 t / 8 (t is the thickness) from the surface so that the 1/4 position of the plate thickness in the plate thickness direction from the surface is the center. In the area of ​​​​1 or more fields of view, a total area of ​​2.0 × 10 -9 m 2 or more is observed with a field emission scanning electron microscope (FE-SEM: Field Emission Scanning Electron Microscope), and the morphology of the tissue Each structure is identified based on (shape of crystal grain, subgrain boundary in crystal grain, state of formation of carbide, etc.), and its area ratio (area %) is measured. The obtained area ratio of each structure is regarded as the volume ratio. This gives the volume fractions of ferrite, non-recrystallized ferrite, martensite and MA (the region consisting of both martensite and retained austenite).
[0044]
When observing multiple fields of view, the area to be analyzed in each field of view shall be 4.0×10 −10 m 2 or more. In addition, in the measurement of the area ratio, in each field of view, the point counting method was used to draw 15 lines parallel to the rolling direction and 15 lines perpendicular to the rolling direction. do. Specifically, a massive region containing no cementite and subgrain boundaries inside is determined as ferrite, and a massive region containing no cementite and having subgrain boundaries inside is determined as non-recrystallized ferrite. In addition, martensite and MA, which contain a large amount of solute carbon, are brighter than other tissues and appear white, and can be distinguished from other tissues. By the above method, the sum of the volume fraction of ferrite, the volume fraction of non-recrystallized ferrite, and the volume fraction of "martensite and MA" is obtained. The volume fraction of ferrite is obtained by calculating the sum of the volume fraction of ferrite and the volume fraction of non-recrystallized ferrite. Further, by dividing the obtained volume ratio of non-recrystallized ferrite by the volume ratio of ferrite, the ratio of non-recrystallized ferrite to ferrite is obtained.
[0045]
The volume fraction of retained austenite is analyzed by the X-ray diffraction method. In the region of t/8 to 3t/8 (t is the plate thickness) from the surface of the test piece, the surface parallel to the steel plate surface is mirror-finished, and the volume fraction of FCC iron is analyzed by X-ray diffraction. Further, the volume fraction of martensite can be obtained by subtracting the obtained volume fraction of retained austenite from the sum of the volume fractions of "martensite and MA" determined by the above observation with FE-SEM.
By subtracting the volume fraction of ferrite, the volume fraction of martensite, and the volume fraction of retained austenite from 100%, the volume fraction of the residual structure is obtained.
[0046]
After 10% tension, the number density of voids with a maximum diameter of 1.0 μm or more is 1.0×10 9 /m 2 in the microstructure at the position of 1/4 of the plate thickness in the plate thickness direction from the surface of the steel plate. is below
In the steel sheet according to the present embodiment, the number density of voids having a maximum diameter of 1.0 μm or more is 1.0× 10 9 pieces/m 2 or less. The voids present in the microstructure of the steel sheet are crushed and cannot be observed at the stage before forming, but the voids are opened and can be observed at the stage after forming. Since the steel sheet according to the present embodiment has a reduced number of voids, the number density of voids is low even before forming. However, as described above, the voids are crushed and cannot be observed at the stage before molding, so in this embodiment, the number density of voids after opening the voids by performing 10% tension is specified.
[0047]
When the number density of voids with a maximum diameter of 1.0 μm or more is 1.0×10 9 /m 2 or less, desired impact fracture resistance can be obtained. The number density of voids is preferably 0.7×10 9 /m 2 or less, more preferably 0.5×10 9 /m 2 or less. The maximum diameter is the maximum diameter of the void, and when the void has a flattened shape, the maximum diameter is the length of the major axis.
[0048]
When the maximum diameter is 1.0 μm or more It is thought that if a large amount of certain voids exist, the voids will combine with each other to form cracks during molding, making it easier to break. If the maximum diameter of the voids is less than 1.0 μm, the voids are difficult to bond with each other, so it is considered that the impact fracture resistance is not affected. Therefore, in the present embodiment, the number density of voids having a maximum diameter of 1.0 μm or more is specified.
[0049]
The number density of voids with a maximum diameter of 1.0 μm or more in the microstructure at the 1/4 position in the plate thickness direction from the surface after 10% tension is measured by the following method.
A No. 5 test piece is prepared according to JIS Z 2241:2011, a tensile test is performed with the tensile axis as the rolling direction of the steel plate, and 10% plastic strain is applied and then unloaded. A small piece is cut out from the center of the parallel portion of the test piece, and a test piece for observation is obtained with a cross section parallel to the rolling direction and perpendicular to the steel sheet surface as an observation surface. After polishing the observation surface of the observation test piece, nital etching is performed. In the area of ​​t/8 to 3t/8 (t is the thickness) from the surface so that the 1/4 position of the plate thickness in the plate thickness direction from the surface is the center, in a field of view of 1 or more, a total of 2. An area of ​​0×10 −9 m 2 or more is observed with a field emission scanning electron microscope (FE-SEM), and the number of voids having a maximum diameter of 1.0 μm or more is counted. By dividing the obtained number of voids by the observed area, the number density of voids having a maximum diameter of 1.0 μm or more is obtained.
[0050]
Average grain size of ferrite: 6.0 to 15.0 μm
The average grain size of ferrite is preferably 6.0 to 15.0 μm in the microstructure at the 1/4 position in the plate thickness direction from the surface of the steel plate according to the present embodiment. By setting the average crystal grain size of ferrite to 6.0 to 15.0 μm, the strength-ductility balance can be further improved, that is, both high strength and excellent ductility can be obtained.
[0051]
The method for measuring the average grain size of ferrite will be described below.
The average grain size of ferrite is obtained by the line segment method. In the field of view for which the volume fractions of ferrite, non-recrystallized ferrite, martensite, and MA were determined, one or more straight lines were drawn in the rolling direction so that the total was 200 μm or more, and the number of intersections between the straight lines and ferrite grain boundaries was The value obtained by dividing the length of the straight line by the number obtained by adding 1 is defined as the average particle size.
[0052]
The steel sheet according to this embodiment may have a zinc plating layer or a zinc alloy plating layer on one or both sides of the steel sheet. Further, the steel sheet according to the present embodiment may have a zinc-alloyed layer or a zinc-alloyed layer obtained by subjecting a zinc-plated layer or a zinc-alloy-plated layer to an alloying treatment.
[0053]
The plating layer formed on one or both sides of the steel sheet according to the present embodiment is preferably a zinc plating layer or a zinc alloy plating layer containing zinc as a main component. The zinc alloy plating layer preferably contains Ni as an alloy component.
[0054]
The zinc plating layer and zinc alloy plating layer are formed by hot dip plating, electroplating, or vapor deposition. If the Al content of the galvanized layer is 0.5% by mass or less, the adhesion between the steel sheet surface and the galvanized layer can be ensured, so the Al content of the galvanized layer should be 0.5% by mass or less. preferable. When the galvanized layer is a hot-dip galvanized layer, the amount of Fe in the hot-dip galvanized layer is preferably 3.0% by mass or less in order to increase the adhesion between the steel sheet surface and the galvanized layer.
When the galvanized layer is an electrogalvanized layer, the Fe content of the galvanized layer is preferably 0.5% by mass or less from the viewpoint of improving corrosion resistance.
[0055]
The zinc plating layer and the zinc alloy plating layer include Al, Ag, B, Be, Bi, Ca, Cd, Co, Cr, Cs, Cu, Ge, Hf, Zr, I, K, La, Li, Mg, Mn, One or more of Mo, Na, Nb, Ni, Pb, Rb, Sb, Si, Sn, Sr, Ta, Ti, V, W, Zr, and REM are added to a range that does not impair the corrosion resistance and formability of the steel sheet. may be contained in In particular, Ni, Al, and Mg are effective in improving corrosion resistance.
[0056]
The zinc coating layer or zinc alloy coating layer on the surface of the steel sheet according to the present embodiment may be a zinc alloy coating layer or zinc alloy coating layer that has undergone alloying treatment. When alloying the hot-dip galvanized layer or the hot-dip galvanized layer, the hot-dip galvanized layer after the alloying treatment (alloyed galvanized layer) is used from the viewpoint of improving the adhesion between the steel sheet surface and the alloyed coating layer. Alternatively, the Fe content of the hot-dip zinc alloy plating layer (alloyed zinc alloy plating layer) is preferably 7.0 to 13.0% by mass. By subjecting a steel sheet having a hot-dip galvanized layer or a hot-dip galvanized layer to an alloying treatment, Fe is incorporated into the galvanized layer and the Fe content is increased. Thereby, the Fe content can be made 7.0% by mass or more. That is, the zinc plating layer having an Fe content of 7.0% by mass or more is an alloyed zinc plating layer or an alloyed zinc alloy plating layer.
[0057]
The Fe content of the hot-dip galvanized layer (alloyed zinc-plated layer) or the hot-dip zinc alloy-plated layer (alloyed zinc-alloyed layer) after the alloying treatment can be obtained by the following method. Only the plated layer is dissolved and removed using a 5% by volume HCl aqueous solution containing an inhibitor. By measuring the Fe content in the obtained solution using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometry), the Fe content (% by mass) in the galvanized layer is obtained.
[0058]
The plate thickness of the steel plate according to the present embodiment is not limited to a specific range, but considering versatility and manufacturability, it is preferably 0.2 to 5.0 mm. When the plate thickness is 0.2 mm or more, it becomes easy to keep the shape of the steel plate flat, and dimensional accuracy and shape accuracy can be improved. Therefore, the plate thickness is preferably 0.2 mm or more. More preferably, it is 0.4 mm or more.
On the other hand, when the plate thickness is 5.0 mm or less, it becomes easier to apply appropriate strain and control temperature during the manufacturing process, and a homogeneous structure can be obtained. Therefore, the plate thickness is preferably 5.0 mm or less. More preferably, it is 4.5 mm or less.
[0059]
The steel plate according to this embodiment preferably has a tensile strength of 340 MPa or more. More preferably, it is 400 MPa or more. Although the upper limit is not particularly limited, it may be, for example, 700 MPa or less, or 500 MPa or less.
The tensile strength is measured by preparing a No. 5 test piece according to JIS Z 2241:2011 and performing a tensile test with the tensile axis in the rolling direction of the steel plate.
[0060]
Next, a method for manufacturing a steel plate according to this embodiment will be described.
The steel sheet according to the present embodiment can obtain the above effects regardless of the manufacturing method. However, the manufacturing method including the following steps is preferable because it can be stably manufactured. In the manufacturing method described below, a steel sheet having desired characteristics can be manufactured by comprehensively and inseparably controlling each step.
(I) A steel slab having a predetermined chemical composition is heated to 1150 to 1320° C., hot rolling is completed so that the hot rolling completion temperature is 850 to 930° C., and after 1.5 seconds or more, cooling is performed. A hot rolling step in which a hot-rolled steel sheet is obtained by starting and cooling to a temperature range of 500 ° C. or less so that the average cooling rate in the temperature range from the cooling start temperature to 500 ° C. is 20 ° C./s or more,
(II) a reheating step of heating the hot-rolled steel sheet to a temperature range of 500 to 700 ° C.;
(III) a cooling step of cooling the hot-rolled steel sheet to room temperature;
(IV) A cold-rolling step of cold-rolling the hot-rolled steel sheet so that the total rolling reduction is 30 to 90% and the cold-rolling completion temperature is 120 to 250 ° C. to obtain a cold-rolled steel sheet;
(V) An annealing step of heating the cold-rolled steel sheet to an annealing temperature of 720 to 850° C. and cooling it to a temperature range of 500° C. or less.
Preferred conditions for each step are described below.
[0061]

First, a steel slab having the chemical composition of the steel sheet according to the present embodiment described above is heated to 1150 to 1320°C. If the heating temperature is 1150° C. or higher, the carbides can be sufficiently dissolved, so that coarse carbides can be suppressed from remaining on the steel sheet after hot rolling. Further, when the heating temperature of the steel slab is 1320° C. or lower, coarsening of crystal grains can be suppressed, and sufficient homogenization can be achieved by performing hot rolling. The steel slabs to be heated are preferably produced by continuous casting from the viewpoint of production cost, but may be produced by other casting methods (for example, ingot casting method).
[0062]
After heating the billet, it is hot rolled so that the hot rolling completion temperature is 850-930°C. When the hot rolling completion temperature is 850° C. or higher, the rolling is performed in the single phase region, so that the anisotropy of the metal structure can be suppressed. Therefore, the hot rolling completion temperature is set to 850° C. or higher. Moreover, when the hot rolling completion temperature is 930° C. or less, excessive coarsening of the structure of the matrix austenite can be suppressed, and the structure can be made homogeneous. Therefore, the hot rolling completion temperature is set to 930° C. or lower.
[0063]
In the hot rolling process, the following formula (1) must be satisfied in the temperature range of 1000°C or less. By controlling the pass schedule so as to satisfy the following formula (1) in a temperature range of 1000° C. or less, recrystallization proceeds uniformly, and carbides are precipitated finely and homogeneously in the steel. By satisfying the following formula (1) in the temperature range of 1000° C. or less, the segregation of carbides becomes difficult, and the formation of voids in the region where the carbides segregate can be suppressed.
[0064]
[Number 5]

[0065]
Dn is an index that indicates the progress of precipitation of fine carbides in the temperature range of 1000°C or less in the hot rolling process. Each code|symbol in said Formula (1) represents the following, respectively.
　n: the number of rolling passes performed in a temperature range of 1000°C or less
　Ti: Rolling temperature of i-th pass [°C]
t i: Elapsed time [seconds] from i-th rolling to i+1-th rolling, or elapsed time [seconds] from i-th rolling until the steel plate temperature decreases and reaches 850 ° C.
However, i is a natural number from 1 to n.
h i-1: Plate thickness [mm] before i-th pass rolling in a temperature range of 1000 ° C or less
h i: Sheet thickness after i-pass rolling in a temperature range of 1000°C or less [mm]
a 1 to 11: constants (a 1 = 2.54 × 10 -6, a 2 = -3.62 × 10 -4, a 3 = -6.38 × 10 -1, a 4 = -3.00 × 10-1, a5=8.50×10-1, a6=-8.50×10-4, a7=2.40×100, a8=7.83×10-13, a9 = 2.80 × 10 5, a 10 = 6.00 × 10 -12, a 11 = 2.80 × 10 5)
[0066]
After hot rolling is completed, cooling is started after 1.5 seconds or more have passed, and the average cooling rate in the temperature range from the cooling start temperature to 500 ° C. is 20 ° C./s or more. do. A hot-rolled steel sheet is thus obtained.
After the completion of hot rolling, by securing a time of 1.5 seconds or more until the start of cooling, recrystallization occurs and a homogeneous structure is obtained. By setting the time until the start of cooling to 5.0 seconds or less, it is possible to suppress the abnormal growth of crystal grains and suppress the occurrence of grain size deviation in the steel sheet, which is preferable.
[0067]
By setting the average cooling rate in the temperature range from the cooling start temperature to 500°C to 20°C/s or more, carbides such as cementite are finely precipitated in the steel. When the average cooling rate in the above temperature range is 20° C./s or higher, formation of coarse carbides can be suppressed, and a desired microstructure can be obtained in the finally obtained steel sheet.
Although the upper limit of the average cooling rate is not particularly set, since a special refrigerant is required to obtain a cooling rate exceeding 200 ° C./s, the average cooling rate is preferably 200 ° C./s or less from the viewpoint of production costs. .
[0068]
Note that the average cooling rate in this embodiment is a value obtained by dividing the temperature difference between the start point and the end point of the set range by the elapsed time from the start point to the end point.
[0069]

In the reheating step, the obtained hot-rolled steel sheet is heated to a temperature range of 500-700°C. In the reheating process, the maximum reheating temperature By setting the temperature (maximum heating temperature in the reheating step) to 500 to 700° C., a desired microstructure can be obtained and impact fracture resistance can be secured.
[0070]
Also, in the reheating process, the temperature history in the temperature range of 500 to 700°C must satisfy the following formula (2). This heating causes fine carbides to precipitate uniformly in the steel. By satisfying the following formula (2) in the temperature range of 500 to 700° C., fine carbides can be precipitated in the steel. As a result, the amount of dissolved carbon can be reduced, and the strength of the hot-rolled steel sheet can be reduced.
[0071]
[Number 6]

[0072]
In the above formula (2), K 20 is the degree of progress of precipitation of the fine carbides in the 20th section when the temperature history in the temperature range of 500 to 700 ° C in the reheating process is equally divided into 20 with respect to time. is an indicator of Each code|symbol in said Formula (2) represents the following, respectively.
　T n: The temperature history in the temperature range of 500 to 700 ° C is divided into 20 equal parts with respect to time, and the average temperature [° C] in the n-th interval
　Δt K: the time obtained by dividing the total staying time in the temperature range of 500 to 700°C by 20 [hr. ], where t 1 =Δt K.
　Si: Content of Si [% by mass]
However, log10 is a common logarithm with a base of 10.
[0073]

After the reheating process, the hot-rolled steel sheet is cooled to room temperature. The cooling rate at this time is not particularly limited, and cooling methods include air cooling and the like. For example, room temperature is 25° C., and the average cooling rate during air cooling to room temperature after reheating is 10° C./s or less.
[0074]

Next, the hot-rolled steel sheet after cooling is cold-rolled so that the total rolling reduction is 30-90% and the cold-rolling completion temperature is 120-250°C. A cold-rolled steel sheet is thus obtained. When the total rolling reduction is 30% or more, the recrystallization in the subsequent heat treatment can be sufficiently advanced, the remaining non-recrystallized ferrite can be suppressed, and finally the desired microstructure can be obtained. . Therefore, the total rolling reduction during cold rolling is set to 30% or more. The total rolling reduction is preferably 45% or more, more preferably 60% or more. Further, when the total rolling reduction in cold rolling is 90% or less, it is possible to suppress an increase in the anisotropy of the steel sheet, reduce the number density of voids, and ensure formability. Therefore, the total rolling reduction during cold rolling is set to 90% or less. In order to further improve formability, the total rolling reduction is preferably 85% or less.
[0075]
When the cold rolling completion temperature is 120°C or higher, the number density of voids can be reduced, and finally the desired microstructure can be obtained. Therefore, the cold rolling completion temperature is set to 120° C. or higher. It is preferably 150° C. or higher, more preferably 170° C. or higher. Moreover, when the cold rolling completion temperature is 250° C. or less, recrystallization can be sufficiently advanced, and formability can be ensured. In order to promote recrystallization efficiently and ensure formability, the cold rolling completion temperature is set to 250° C. or less. Preferably, it is 230° C. or lower and 200° C. or lower.
[0076]

[Heating process]
Subsequently, the cold-rolled steel sheet (cold-rolled steel sheet) is heat-treated (annealed). First, a cold-rolled steel sheet is heated to an annealing temperature of 720-850°C. During this heating, in the temperature range of 720° C. to the annealing temperature (720 to 850° C.), a tension of 20 MPa or more must be applied and the temperature history must satisfy the following formula (3). By applying a tension of 20 MPa or more in the temperature range from 720 ° C. to the annealing temperature, the voids generated during cold rolling are sufficiently closed, and the regions where the voids existed are prevented from opening after forming. If the tension is less than 20 MPa, opening of voids generated during cold rolling cannot be sufficiently suppressed. From this point of view, the applied tension is preferably 25 MPa or more. In the temperature range from 720° C. to the annealing temperature, the temperature history satisfies the following formula (3) to promote recrystallization and dissolution of cementite. Thereby, a desired microstructure can be finally obtained.
[0077]
[Number 7]

[0078]
Each symbol in the above formula (3) represents the following.
　K 20: the value obtained by the above formula (2)
　d1 and d2: constants (d1=9.67×10 10, d2=1.25×10 4)
T i: Average heat treatment temperature [°C] in the i-th interval obtained by dividing the temperature history in the temperature range from 720°C to the annealing temperature by 10 with respect to time
t': 1/10 second of the residence time in the temperature range from 720°C to the annealing temperature
[0079]
The annealing temperature in the annealing process should be 720°C or higher. When the annealing temperature is 720° C. or higher, it is possible to prevent coarse cementite from being left undissolved, to allow recrystallization to proceed sufficiently, and to obtain a desired microstructure. The annealing temperature is preferably 750°C or higher, more preferably 780°C or higher. Further, when the annealing temperature is 850° C. or lower, excessive decrease in the volume fraction of ferrite can be suppressed. Therefore, the annealing temperature is set to 850° C. or lower. When the volume fraction of ferrite is increased to further improve formability, the annealing temperature is preferably 830° C. or lower, more preferably 810° C. or lower.
[0080]
[Holding process]
The holding time at the annealing temperature, that is, the time from reaching the annealing temperature of 720° C. or higher in the heating process to reaching 720° C. again after holding the annealing temperature of 720 to 850° C. shall be 3 seconds or longer. is preferred. By setting the holding time to 3 seconds or longer, the cementite can be sufficiently melted, and formability can be secured. The holding time is preferably 10 seconds or longer, more preferably 25 seconds or longer. Although the upper limit of the holding time is not particularly set, it is preferable to set the holding time to 200 seconds or less in view of the production cost because even if the holding time exceeds 200 seconds, the properties of the steel sheet are not affected.
[0081]
[Cooling process]
After heating to the annealing temperature and securing the holding time, cool it.
In the cooling process of cooling to a temperature range of 500°C or less, the temperature history must satisfy the following formula (4) in the temperature range of 720-500°C. By performing cooling in which the temperature history in the temperature range of 720 to 500° C. satisfies the following formula (4), formation of hard phases (martensite and retained austenite) is suppressed. Thereby, a desired microstructure can be finally obtained.
[0082]
[Number 8]

[0083]
In the above formula (4), each code represents the following.
　Δi: 750-18 x Si-17 x Mn-10 x Cr-8 x Ni + 15 x Al-Ti
However, each element shows the content in mass%, and 0 is substituted when the element is not contained. Also, if the calculated value of Δi is a negative value, Δi is set to zero.
g 1 to 6: constants (g 1 = 1.00 × 10 -1, g 2 = 1.46 × 10 -1, g 3 = 1.14 × 10 -1, g 4 = 2.24 × 10 0, g5=4.53×10 0, g6=4.83×10 3)
Nb, Mo, Si, Mn, Cr, Ni and Al: content of each element [% by mass], but 0 is substituted if the element is not contained.
　Ti*: Effective Ti amount represented by Ti−42/14×N, Ti and N indicate the content [mass %] of the element concerned. However, 0 is substituted when the element is not contained. The minimum value is 0.
　T i: Average heat treatment temperature [°C] in the i-th interval obtained by dividing the temperature history in the temperature range of 720 to 500°C by 10 with respect to time
　Ac 1 and Ac 3: Transformation start temperature and transformation completion temperature during heating [°C]
　T max: Maximum heating temperature [°C] in the heat treatment process
　t': 1/10 second of the residence time in the temperature range of 720 to 500 ° C
[0084]
After the annealing process, the steel sheet may be subjected to hot-dip galvanizing treatment or hot-dip galvanizing treatment in a temperature range of 500°C or lower. At this time, the steel sheet may be reheated before being immersed in the plating bath. Alternatively, the plated steel sheet may be heated to alloy the plated layer.
In this embodiment, Ac 1 and Ac 3 are obtained by heating a small piece cut out from the cold-rolled steel sheet to be subjected to the annealing process and from the change in thermal expansion of the small piece during heating.
[0085]
A galvanized steel sheet having a galvanized layer may be produced by subjecting the steel sheet after the annealing process to electroplating or vapor deposition to form a galvanized layer on one or both sides of the steel sheet.
The atmosphere in the annealing process may be controlled to modify the surface of the steel sheet. For example, by heat-treating in a decarburizing atmosphere, a steel sheet having excellent bendability in which the surface layer of the steel sheet is moderately decarburized can be obtained.
[0086]

After the annealing process, temper rolling may be applied so that the total rolling reduction is 0.05 to 2.00%. By performing such temper rolling, it is possible to flatten the surface shape and adjust the surface roughness.
Example
[0087]
Next, examples of the present invention will be described, but the conditions in the examples are examples of conditions adopted to confirm the feasibility and effect of the present invention. The present invention is not limited to this one conditional example. Various conditions can be adopted in the present invention as long as the object of the present invention is achieved without departing from the gist of the present invention.
[0088]
Next, examples of the present invention will be described, but the conditions in the examples are examples of conditions adopted to explain the feasibility and effect of the present invention. The present invention is not limited to this one conditional example. Various conditions can be adopted in the present invention as long as the object of the present invention is achieved without departing from the gist of the present invention.
[0089]
A steel slab was produced by casting molten steel having the chemical composition shown in Table 1. Next, the steel slabs were hot rolled under the conditions shown in Table 2 to obtain hot rolled steel sheets. Table 2 shows Dn obtained from the above equation (1) and the hot rolling conditions in the temperature range of 1000°C or lower in the hot rolling process.
Next, it was reheated under the conditions shown in Table 2. Table 2 shows K 20 obtained from the temperature history in the temperature range of 500 to 700° C. in the reheating process and the above equation (2). After reheating, it was cooled to room temperature (25° C.) at an average cooling rate of 10° C./s or less.
[0090]
After that, the hot-rolled steel sheets were subjected to cold rolling, heat treatment (annealing), and temper rolling under the conditions shown in Tables 3-1 and 3-2 to obtain steel sheets. Annealing was performed by heating to the annealing temperature shown in Tables 3-1 and 3-2 and holding for 3 to 200 seconds (that is, after reaching an annealing temperature of 720 ° C. or higher during the heating process, annealing at 720 to 850 ° C. After holding the temperature and reaching 720° C. again (the time was set to 3 to 200 seconds), it was cooled.
[0091]
Tables 3-1 and 3-2 show the temperature history in the heating process of the annealing process from 720°C to the annealing temperature and the value of the middle side of the formula (3) obtained from the above formula (3). In addition, Tables 3-1 and 3-2 show the temperature history in the temperature range of 720 to 500 ° C. in the cooling process of the annealing process and the value of the left side of formula (4) obtained from the above formula (4). show.
[0092]
The plating treatments in Tables 3-1 and 3-2 are as follows.
Zn alloy: After cooling the steel sheet to a temperature range of 500°C or less in the annealing process, it is immersed in a molten zinc alloy bath and cooled to room temperature to obtain a zinc alloy plated steel sheet.
Alloyed Zn alloy: In the annealing process, the steel sheet is cooled to a temperature range of 500 ° C. or less, immersed in a molten zinc alloy bath, subjected to alloying treatment by reheating to 580 ° C., and then cooled to room temperature to alloy. This is a process to obtain a zinc alloy plated steel sheet.
GA: In the annealing process, the steel sheet is cooled to a temperature range of 500°C or less, immersed in a molten zinc bath, subjected to alloying treatment by reheating to 560°C, and then cooled to room temperature to form an alloyed hot-dip galvanized steel sheet. (GA) is obtained.
GI: After cooling the steel sheet to a temperature range of 500°C or less in the annealing process, it is immersed in a molten zinc bath and cooled to room temperature to obtain a hot-dip galvanized steel sheet (GI).
　Evaporation: After the annealing process, the It is a process to obtain a galvanized steel sheet by plating.
EG: After the annealing process, electrogalvanizing is applied to obtain an electrogalvanized steel sheet (EG).
[0093]
Tables 4-1 and 4-2 show the characteristics of steel sheets obtained under the manufacturing conditions listed in Tables 1 to 3-2. Tables 4-1 and 4-2 show the results of microstructural observation performed by the above-described method, the volume percentage of ferrite, the percentage of unrecrystallized ferrite in ferrite, the volume percentage of martensite, the volume percentage of retained austenite, and ferrite. shows the average grain size of The ratio of non-recrystallized ferrite to ferrite was measured using OIM Data Collection and OIM Data Analysis manufactured by TSL. Also, the number density of voids having a maximum diameter of 1.0 μm or more measured by the above-described method is shown. The thickness of the steel plate was the same value as the thickness after rolling in Tables 3-1 and 3-2.
[0094]
For alloyed steel sheets, measure the Fe content of the hot-dip galvanized layer (alloyed zinc-coated layer) or hot-dip zinc alloy-coated layer (alloyed zinc-alloyed layer) by the method described above. did.
[0095]
The plating layers in Tables 4-1 and 4-2 are as follows.
　Zn alloy: Zinc alloy plating layer
Alloyed Zn alloy: Alloyed zinc alloy plating layer
GA: An alloyed hot-dip galvanized layer formed by alloying after being immersed in a hot-dip zinc bath
　GI: Hot-dip galvanized layer formed by immersion in a hot-dip zinc bath
　Vapor deposition: Zinc plating layer formed by vapor deposition plating
　EG: Galvanized layer formed by electrogalvanizing
[0096]
Tables 5-1 and 5-2 show the properties of steel sheets obtained under the manufacturing conditions in Tables 1 to 3-2. Yield strength (YS) and maximum tensile strength were obtained by performing a tensile test. A No. 5 test piece was prepared according to JIS Z 2241:2011, and a tensile test was performed with the tensile axis being the rolling direction of the steel plate. Steel sheets with a maximum tensile strength (TS) of 340 MPa or more in a tensile test were judged as having excellent strength and passed. On the other hand, steel sheets with a maximum tensile strength of less than 340 MPa were judged to be unacceptable because they did not have excellent strength. In addition, steel sheets with a uniform elongation (uEl) of 15% or more obtained by a tensile test were judged as having excellent formability and passed. On the other hand, steel sheets with a uniform elongation of less than 15% were judged to be unacceptable because they did not have excellent formability.
[0097]
A tensile test was performed under the same conditions as the above tensile test, and the load was removed after applying a strain of 15%. A semicircular notch with a radius of 1.0 mm was provided at both ends of the center of the parallel portion of the test piece, and the tensile test was performed again at -40°C until it broke. This gave the breaking stress σ 2 at −40° C. and the maximum stress σ 1 before unloading.
[0098]
Next, a Charpy impact test was conducted. When the plate thickness of the steel plate is less than 2.5 mm, as a test piece, steel plates are laminated until the total plate thickness exceeds 5.0 mm, fastened with bolts, and laminated with a V notch of 2 mm depth. A Charpy test piece was used. Other conditions were performed according to JIS Z 2242:2018. As a result, a ductile-brittle transition temperature at which the brittle fracture surface ratio becomes 50% or more was obtained.
[0099]
The value (σ2/σ1) obtained by dividing the breaking stress σ2 at −40° C. obtained by the above method by the maximum stress σ1 before unloading is 0.70 or less, and the brittle fracture surface rate is 50% or more. A steel sheet having a ductile-brittle transition temperature of −40° C. or less was judged to pass the test because it had sufficiently high deformability during impact deformation after forming (has excellent impact resistance).
On the other hand, a steel sheet with a ductility-brittle transition temperature exceeding -40 ° C. where σ2 / σ1 exceeds 0.70 and / or a brittle fracture surface ratio is 50% or more is rejected as not having excellent impact resistance. I judged.
[0100]
[table 1]

[0101]
[Table 2]

[0102]
[Table 3-1]

[0103]
[Table 3-2]

[0104]
[Table 4-1]

[0105]
[Table 4-2]

[0106]
[Table 5-1]

[0107]
[Table 5-2]

[0108]
Of the steels A to AD shown in Table 1, the steels AA to AD are comparative examples that deviate from the range of composition specified in the present invention.
[0109]
The AA steel had a lower C content than the range of the present invention. The steel plate of Experimental Example 54 obtained using this steel had a low maximum tensile strength.
[0110]
AB steel had a higher C content than the range of the present invention. The steel sheet of Experimental Example 55 obtained by using the present steel had a small amount of ferrite and a high number density of voids, so that the uniform elongation was low and σ2/σ1 was high.
[0111]
The AC steel had a higher Si content than the range of the present invention. The steel plate of Experimental Example 56 obtained using this steel had a large amount of retained austenite, and therefore had a high ductile-brittle transition temperature.
[0112]
The AD steel had a higher Mn content than the range of the present invention. The steel plate of Experimental Example 57 obtained using this steel had a small amount of ferrite, a large amount of martensite and retained austenite, and a high number density of voids. temperature was high.
[0113]
Experimental Examples 7, 15, 21, 29, 39, 49 and 50 are comparative examples in which the conditions of the hot rolling process deviate from the scope of the present invention.
[0114]
Experimental example 7 is a comparative example in which Dn was high and the formula (1) was not satisfied in the temperature range of 1000°C or lower, so the number density of voids increased and σ2/σ1 increased.
[0115]
Experimental example 15 is a comparative example in which the slab heating temperature was low, so the number density of voids increased and σ2/σ1 increased.
[0116]
Experimental example 21 is a comparative example in which the average cooling rate in the temperature range from the cooling start temperature to 500°C was low, so the number density of voids increased and σ2/σ1 increased.
[0117]
Experimental Example 29 is a comparative example in which the number density of voids increased and σ2/σ1 increased because the hot rolling completion temperature was low.
[0118]
Experimental example 39 is a comparative example in which the number density of voids increased and σ2/σ1 increased because the time from the completion of hot rolling to the start of cooling was short.
[0119]
Experimental Example 49 is a comparative example in which the hot rolling completion temperature was high, so the number density of voids was high and σ2/σ1 was high.
[0120]
Experimental example 50 is a comparative example in which the slab heating temperature was high, so the number density of voids increased and σ2/σ1 increased.
[0121]
Experimental Examples 8, 10, and 38 are comparative examples in which the conditions of the reheating process deviate from the scope of the present invention.
[0122]
Experimental Example 8 is a comparative example in which the maximum reheating temperature in the reheating process was low, so the number density of voids increased and σ2/σ1 increased.
[0123]
Experimental example 10 is a comparative example in which the maximum reheating temperature in the reheating process was high, so the number density of voids increased and σ2/σ1 increased.
[0124]
Experimental example 38 is a comparative example in which K20 is low and formula (2) is not satisfied in the temperature range of 500 to 700°C, so the number density of voids increases and σ2/σ1 increases.
[0125]
Experimental Examples 6, 37, 58 and 59 are comparative examples in which the conditions of the cold rolling process are outside the scope of the present invention.
[0126]
Experimental example 6 is a comparative example in which the total rolling reduction in the cold rolling process was high, so the number density of voids was high and σ2/σ1 was high.
[0127]
Experimental Example 37 is a comparative example in which unrecrystallized ferrite remained excessively due to the low total rolling reduction in the cold rolling process, resulting in low uniform elongation.
[0128]
Experimental example 58 is a comparative example in which the rolling completion temperature in the cold rolling process was low, so the number density of voids increased and σ2/σ1 increased.
[0129]
Experimental Example 59 is a comparative example in which unrecrystallized ferrite remained excessively due to the high rolling completion temperature in the cold rolling process, resulting in low uniform elongation.
[0130]
Experimental Examples 3, 4, 13, 27, 35 and 47 are comparative examples in which the conditions of the annealing process are outside the scope of the present invention.
[0131]
Experimental example 3 is a comparative example in which the annealing temperature was high, so the amount of ferrite was small and the uniform elongation was low.
[0132]
Experimental example 27 is a comparative example in which since the annealing temperature was low, the number density of voids increased and σ2/σ1 increased.
[0133]
Experimental example 4 is a comparative example in which the value of the middle side of formula (3) was high, so the amount of retained austenite increased and the ductile-brittle transition temperature increased.
[0134]
Experimental example 13 is a comparative example in which the value of the left side of formula (4) was low, so the amount of martensite was increased and the ductile-brittle transition temperature was increased.
[0135]
Experimental example 35 is a comparative example in which the value of the middle side of formula (3) was low, so that unrecrystallized ferrite remained excessively and the uniform elongation was low.
[0136]
Experimental example 47 is a comparative example in which the tension applied in the temperature range from 720°C to the annealing temperature was low, so the number density of voids increased and σ2/σ1 increased.
[0137]
Experimental examples excluding the above comparative examples are examples of the present invention. It can be seen that the steel sheets described as examples have excellent formability, strength, and impact fracture resistance by being manufactured by a manufacturing method that satisfies the manufacturing conditions of the present invention.
[0138]
In Experimental Examples 2, 9, 12, 16, 18, 22, 24, 26, 30, 32, 33, 34, 40, 42, 44, 46 and 52, the plated steel sheets of the present invention were obtained by plating. This is an example.
[0139]
Experimental Examples 9, 26, 32 and 42 are examples in which the steel sheets were cooled to 500°C in the annealing step, then immersed in a molten zinc bath and cooled to room temperature to obtain hot-dip galvanized steel sheets (GI). .
[0140]
In Experimental Examples 2, 18, 30 and 46, the steel sheet was cooled to 500°C in the annealing step, then immersed in a molten zinc bath, subjected to an alloying treatment of reheating to 560°C, and then cooled to room temperature to form an alloy. This is an example in which a hot dip galvanized steel sheet (GA) was obtained.
[0141]
Experimental Examples 33 and 52 are examples in which a steel sheet was cooled to 500°C in the annealing process, then immersed in a molten zinc alloy bath, and cooled to room temperature to obtain a zinc alloy plated steel sheet.
[0142]
In Experimental Examples 34 and 40, the steel sheet was cooled to 500°C in the annealing step, then immersed in a molten zinc alloy bath, subjected to alloying treatment by reheating to 580°C, and then cooled to room temperature to alloy. It is an example in which a zinc alloy plated steel sheet was obtained.
[0143]
Experimental Examples 16 and 22 are examples in which galvanized steel sheets were obtained by subjecting them to vapor deposition plating before temper rolling in the annealing process.
[0144]
Experimental Examples 12, 24, and 44 are examples in which an electrogalvanized steel sheet (EG) was obtained by performing an electrogalvanizing treatment after the annealing process.
Industrial applicability
[0145]
As described above, according to the present invention, it is possible to provide a high-strength steel sheet with excellent formability, impact fracture resistance, and toughness. Since the steel sheet of the present invention is a steel sheet suitable for significantly reducing the weight of automobiles and ensuring the protection and safety of passengers, the present invention has high applicability in the steel sheet manufacturing industry and the automobile industry.
The scope of the claims
[Claim 1]
The component composition is mass %,
C: 0.010 to 0.200%,
Si: 0.005 to 1.500%,
Mn: 0.05-3.00%,
Al: 0.005 to 1.000%,
P: 0.100% or less,
S: 0.0200% or less,
N: 0.0150% or less,
O: 0.0100% or less,
Nb: 0 to 0.060%,
Ti: 0 to 0.100%,
V: 0 to 0.500%,
Cr: 0 to 1.00%,
Ni: 0 to 1.00%,
Cu: 0 to 1.00%,
Mo: 0 to 1.00%,
W: 0 to 1.000%,
B: 0 to 0.0100%,
Sn: 0-1. 00%,
Sb: 0 to 0.20%, and
one or more of Ca, Ce, Mg, Zr, La and REM: 0 to 0.0100%,
containing, the balance being Fe and impurities,
　The microstructure at the 1/4 position of the plate thickness in the plate thickness direction from the surface is
By volume %, it contains ferrite: 80% or more, martensite: 2% or less, retained austenite: 2% or less,
The ratio of non-recrystallized ferrite in the ferrite is 5% or less,
After 10% tension, the number density of voids with a maximum diameter of 1.0 μm or more in the microstructure at the position of 1/4 of the plate thickness in the plate thickness direction from the surface is 1.0 × 10 9 /m 2 or less. be
A steel plate characterized by:
[Claim 2]
　The above component composition is in mass %,
Nb: 0.005 to 0.060%,
Ti: 0.015 to 0.100%,
V: 0.010 to 0.500%,
Cr: 0.05 to 1.00%,
Ni: 0.05 to 1.00%,
Cu: 0.05 to 1.00%,
Mo: 0.03 to 1.00%,
W: 0.030 to 1.000%,
B: 0.0005 to 0.0100%,
Sn: 0.01 to 1.00%,
Sb: 0.005 to 0.20%, and
Total of one or more of Ca, Ce, Mg, Zr, La and REM: 0.0001 to 0.0100%
The steel sheet according to claim 1, characterized by containing one or more selected from the group consisting of:
[Claim 3]
The steel sheet according to claim 1 or claim 2, wherein the ferrite contained in the microstructure has an average grain size of 6.0 to 15.0 µm.
[Claim 4]
The steel sheet according to any one of claims 1 to 3, characterized by having a galvanized layer on the surface.
[Claim 5]
The steel sheet according to any one of claims 1 to 3, characterized by having a zinc alloy plating layer on the surface.
[Claim 6]
The steel sheet according to claim 4 or 5, wherein the Fe content in the zinc plating layer or the zinc alloy plating layer is 7.0 to 13.0% by mass.
[Claim 7]
A method for manufacturing the steel sheet according to any one of claims 1 to 3,
A steel slab having the chemical composition according to claim 1 is heated to 1150 to 1320 ° C., hot rolling is completed so that the hot rolling completion temperature is 850 to 930 ° C., and after 1.5 seconds or more, cooling A hot rolling step of cooling to a temperature range of 500 ° C. or less so that the average cooling rate in the temperature range from the cooling start temperature to 500 ° C. is 20 ° C./s or more to form a hot rolled steel sheet;
a reheating step of heating the hot-rolled steel sheet to a temperature range of 500 to 700°C;
a cooling step of cooling the hot-rolled steel sheet to room temperature;
A cold-rolling step of cold-rolling the hot-rolled steel sheet so that the total rolling reduction is 30-90% and the cold-rolling completion temperature is 120-250°C to obtain a cold-rolled steel sheet;
An annealing step of heating the cold-rolled steel sheet to an annealing temperature of 720 to 850°C and cooling it to a temperature range of 500°C or less,
　In the hot rolling process,
In the temperature range of 1000°C or less, the following formula (1) is satisfied,
　In the reheating process,
　In the temperature range of 500 to 700°C, the following formula (2) is satisfied,
　In the annealing process,
In the heating process to the annealing temperature,
In the temperature range from 720°C to the annealing temperature, a tension of 20 MPa or more is applied, and the following formula (3) is satisfied,
In the cooling process from the annealing temperature,
Satisfies the following formula (4) in the temperature range of 720-500°C
A steel plate manufacturing method characterized by:
[Number 1]

In the above formula (1), Dn is an index that indicates the progress of precipitation of fine carbides in the temperature range of 1000°C or less in the hot rolling process. Each code|symbol in said Formula (1) represents the following, respectively.
　n: the number of rolling passes performed in a temperature range of 1000°C or less
　Ti: Rolling temperature of i-th pass [°C]
t i: Elapsed time [seconds] from i-th rolling to i+1-th rolling, or elapsed time [seconds] from i-th rolling until the steel plate temperature decreases and reaches 850 ° C.
h i-1: Plate thickness [mm] before i-th pass rolling in a temperature range of 1000 ° C or less
h i: Sheet thickness after i-pass rolling in a temperature range of 1000°C or less [mm]
a 1 to 11: constants (a 1 = 2.54 × 10 -6, a 2 = -3.62 × 10 -4, a 3 = -6.38 × 10 -1, a 4 = -3.00 × 10-1, a5=8.50×10-1, a6=-8.50×10-4, a7=2.40×100, a8=7.83×10-13, a9 = 2.80 × 10 5, a 10 = 6.00 × 10 -12, a 11 = 2.80 × 10 5)
[Number 2]

In the above formula (2), K 20 is the degree of progress of precipitation of the fine carbides in the 20th section when the temperature history in the temperature range of 500 to 700 ° C in the reheating process is equally divided into 20 with respect to time. is an indicator of Each code|symbol in said Formula (2) represents the following, respectively.
　T n: The temperature history in the temperature range of 500 to 700 ° C is divided into 20 equal parts with respect to time, and the average temperature [° C] in the n-th interval
　Δt K: the time obtained by dividing the total staying time in the temperature range of 500 to 700°C by 20 [hr. ], where t 1 =Δt K.
　Si: Content of Si [% by mass]
[Number 3]

Each symbol in the above formula (3) represents the following.
　K 20: the value obtained by the above formula (2)
　d1 and d2: constants (d1=9.67×10 10, d2=1.25×10 4)
T i: Average heat treatment temperature [°C] in the i-th interval obtained by dividing the temperature history in the temperature range from 720°C to the annealing temperature by 10 with respect to time
t': 1/10 second of the residence time in the temperature range from 720°C to the annealing temperature
[Number 4]

In the above formula (4), each code represents the following.
　Δi: 750-18 x Si-17 x Mn-10 x Cr-8 x Ni + 15 x Al-Ti
However, each element shows the content in mass%, and 0 is substituted when the element is not contained. Also, if the calculated value of Δi is a negative value, Δi is set to zero.
g 1 to 6: constants (g 1 = 1.00 × 10 -1, g 2 = 1.46 × 10 -1, g 3 = 1.14 × 10 -1, g 4 = 2.24 × 10 0, g5=4.53×10 0, g6=4.83×10 3)
Nb, Mo, Si, Mn, Cr, Ni and Al: content of each element [% by mass], but 0 is substituted if the element is not contained.
　Ti*: Effective Ti amount represented by Ti−42/14×N, Ti and N indicate the content [mass %] of the element concerned. However, 0 is substituted when the element is not contained. The minimum value is 0.
　T i: Average heat treatment temperature [°C] in the i-th interval obtained by dividing the temperature history in the temperature range of 720 to 500°C by 10 with respect to time
　Ac 1 and Ac 3: Transformation start temperature and transformation completion temperature during heating [°C]
　T max: Maximum heating temperature [°C] in the heat treatment process
　t': 1/10 second of the residence time in the temperature range of 720 to 500 ° C
[Claim 8]
The steel sheet manufacturing method according to claim 7, wherein the cold-rolled steel sheet is subjected to a hot-dip galvanizing treatment in the cooling process of the annealing process.
[Claim 9]
The steel sheet manufacturing method according to claim 7, wherein the cold-rolled steel sheet is subjected to a hot-dip zinc alloy plating treatment in the cooling process of the annealing process.
[Claim 10]
10. The method for manufacturing the steel sheet according to claim 8 or 9, characterized in that in the cooling process of the annealing step, alloying treatment is performed after the hot dip galvanizing treatment or after the hot dip galvanizing treatment.