Abstract: The present invention relates to a steel sheet for enameling which is not prone to the occurrence of surface defects such as fish scale defects and which has good formability. The steel sheet of the present invention comprises in wt %: more than 0 but no more than 0.005% of C; 0.1 to 0.5% of Mn; more than 0 but no more than 0.03% of Si; 0.05 0.3% of Cr; more than 0 but no more than 0.03% of Al; 0.03 0.1% of O; more than 0 but no more than 0.03% of P; more than 0 but no more than 0.02% of S; more than 0 but no more than 0.015% of Cu; more than 0% but no more than 0.005% of N; wherein the remainder is Fe and unavoidable impurities.
WHAT IS CALIMED IS
1. A steel sheet for enamel having no surface defects, comprising:
more than 0 wt% and 0.005 wt% or less of C, 0.1 to 0.5 wt% of Mn, more than 0 wt% and 0.03 wt% or less of Si, 0.05 to 0.3 wt% of Cr, more than 0 wt% and 0.03 wt% or less of Al, 0.03 to 0.1 wt% of O, more than 0 wt% and 0.03 wt% or less of P, more than 0 wt% and 0.02 wt% or less of S, more than 0 wt% and 0.015 wt% or less of Cu, more than 0 wt% and 0.005 wt% or less of N, Fe in a remaining content, and other inevitable impurities.
2. The steel sheet for enamel having no surface defects of claim 1, wherein: a Cr-Mn complex oxide is formed in the steel sheet for enamel.
3. The steel sheet for enamel having no surface defects of claim 2, wherein: an atomic ratio of Cr/Mn in the Cr-Mn complex oxide is in the range of
0.01 to 2.
6. A method of manufacturing a steel sheet for enamel having no surface
defects, comprising:
manufacturing a slab formed of more than 0 wt% and 0.005 wt% or less of C, 0.1 to 0.5 wt% of Mn, more than 0 wt% and 0.03 wt% or less of Si, 0.05 to 0.3 wt% of Cr, more than 0 wt% and 0.03 wt% or less of Al, 0.03 to 0.1 wt% of O, more than 0 wt% and 0.03 wt% or less of P, more than 0 wt% and 0.02 wt% or
less of S, more than 0 wt% and 0.015 wt% or less of Cu, more than 0 wt% and 0.005 wt% or less of N, Fe in a remaining content, and other inevitable impurities;
manufacturing a hot rolled steel sheet by hot rolling after the slab is re¬heated to 1,200°C or more; and
winding the hot rolled steel sheet at 550°C or more.
7. The method of manufacturing a steel sheet for enamel having no surface
defects of claim 6, further comprising:
performing cold rolling at a reduction ratio of 50 to 90% after the winding.
8. The method of manufacturing a steel sheet for enamel having no surface
defects of claim 7, further comprising:
performing continuous annealing of the cold rolled steel sheet at 700°C or more for 20 sec or more after the cold rolling.
9. The method of manufacturing a steel sheet for enamel having no surface
defects of any one of claim 6 to claim 8, wherein:
in the steel sheet for enamel manufactured by the method of manufacturing the steel sheet for enamel, a Cr-Mn complex oxide is formed and an atomic ratio of Cr/Mn in the Cr-Mn complex oxide is 0.01 to 2.
10. The method of manufacturing a steel sheet for enamel having no surface
defects of claim 9, wherein:
in the steel sheet for enamel manufactured by the method of manufacturing the steel sheet for enamel, a size of the Cr-Mn complex oxide is 1 to 25 µm.
11. The method of manufacturing a steel sheet for enamel having no surface
defects of claim 10, wherein:
in the steel sheet for enamel manufactured by the method of manufacturing the steel sheet for enamel, the number of the Cr-Mn complex oxides is 1.5X102 or more per 1 mm2 of an observation view.
12. The method of manufacturing a steel sheet for enamel having no surface
defects of claim 11, wherein:
in the steel sheet for enamel manufactured by the method of manufacturing the steel sheet for enamel, micro-voids are formed in the Cr-Mn complex oxide itself or a periphery thereof.
| # | Name | Date |
|---|---|---|
| 1 | Specification.pdf | 2013-03-25 |
| 2 | Form 5.pdf | 2013-03-25 |
| 3 | Form 3.pdf | 2013-03-25 |
| 4 | Drawings.pdf | 2013-03-25 |
| 5 | 2283-CHENP-2013 CORRESPONDENCE OTHERS 11-9-2013.pdf | 2013-10-29 |
| 6 | 2283-CHENP-2013 FORM-3 11-9-2013.pdf | 2013-10-29 |
| 7 | 2283-CHENP-2013.pdf | 2014-06-02 |
| 8 | 2283-CHENP-2013 FORM-1 06-08-2014.pdf | 2014-08-06 |
| 9 | 2283-CHENP-2013 CORRESPONDENCE OTHERS 06-08-2014.pdf | 2014-08-06 |
| 10 | Form-18(Online).pdf | 2014-12-17 |
| 11 | 2283-CHENP-2013 FORM-13 27-02-2015.pdf | 2015-02-27 |
| 12 | FORM 13.pdf ONLINE | 2015-03-03 |
| 13 | FORM 1.pdf ONLINE | 2015-03-03 |
| 14 | FORM 13.pdf | 2015-03-13 |
| 15 | FORM 1.pdf | 2015-03-13 |
| 16 | 2283-CHENP-2013 CORRESSPONDENCE 1812016.pdf | 2016-06-21 |
| 17 | 2283-CHENP-2013-FER.pdf | 2018-12-28 |
| 18 | 2283-CHENP-2013-FORM 3 [11-03-2019(online)].pdf | 2019-03-11 |
| 19 | 2283-CHENP-2013-certified copy of translation (MANDATORY) [11-03-2019(online)].pdf | 2019-03-11 |
| 20 | Correspondence by Agent_Verification Certificate_21-03-2019.pdf | 2019-03-21 |
| 21 | 2283-CHENP-2013-OTHERS [27-06-2019(online)].pdf | 2019-06-27 |
| 22 | 2283-CHENP-2013-FER_SER_REPLY [27-06-2019(online)].pdf | 2019-06-27 |
| 23 | 2283-CHENP-2013-CLAIMS [27-06-2019(online)].pdf | 2019-06-27 |
| 24 | 2283-CHENP-2013-PatentCertificate28-01-2021.pdf | 2021-01-28 |
| 25 | 2283-CHENP-2013-IntimationOfGrant28-01-2021.pdf | 2021-01-28 |
| 26 | 2283-CHENP-2013-RELEVANT DOCUMENTS [24-09-2022(online)].pdf | 2022-09-24 |
| 1 | strategy_25-09-2018.pdf |