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Storage Stable Liquid Composition Containing Lambda Cyhalothrin

Abstract: The present invention relates generally to a storage stable composition comprising (a) an insecticidally effective amount of lambda cyhalothrin; and (b) an isomer stabilizing amount of phosphate ester of a compound selected from the group comprising: (i) alkyl or aryl alkoxylate; (ii) alkoxylates of fatty alcohol; (iii) alkoxylate of fatty acids; (iv) block co-polymers of ethylene oxide and propylene oxide; (v) polyaryl substituted aliphatic or aromatic alkoxylate; and (vi) alkoxylated polyaryl substituted phenol; and derivatives and mixtures thereof. wherein said phosphate ester is selected such that it has a degree of esterification from about 10 to about 90% and a pH in range of about 1 to 6.9. The present invention also provides a process for the preparation of said agrochemical composition.

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
05 July 2008
Publication Number
46/2009
Publication Type
INA
Invention Field
CHEMICAL
Status
Email
Parent Application
Patent Number
Legal Status
Grant Date
2014-02-20
Renewal Date

Applicants

UNITED PHOSPHORUS LIMITED
UNIPHOS HOUSE, MADHU PARK, 11TH ROAD, KHAR (W), MUMBAI

Inventors

1. SHROFF RAJANIKANT DEVIDAS
UNIPHOS HOUSE, MADHU PARK, 11TH ROAD, KHAR (W), MUMBAI 400052

Specification

FORM 2 THE PATENTS ACT, 1970 (39 of 1970) PROVISIONAL SPECIFICATION (See Section 10) "A NOVEL AND IMPROVED SYNERGISTIC COMPOSITION" We , UNITED PHOSPHORUS LIMITED, a company incorporated under the Companies Act, 1956 and having its registered office at 3-11, GIDC, Vapi-396 195, State of Gujarat, India, INDIAN. The following specification describes the invention: 1 Field of the Invention The present invention relates generally to a storage stable composition of Lambda Cyhalothrin. More particularly it relates to a composition in the form of emulsifiable concentrate by using a dispersant system as a stabilizer for the impurities causing turbidity to the formulation. Background of the Invention Lambda Cyhalothrin is a reaction product comprising equal quantities of (R)-a-cyano-3- phenoxybenzyl0(lS,3S)-3-[(Z)-2-chloro-3,3,3-trifluoropropenyl]-2,2-dimethylcy clopropanecarboxylate and (S)-a-cyano-3-phenoxybenzyl (lR,3R)-3-[(Z)-2-chloro-3,3,3- trifluoropropenyl]-2,2-dimethylcyclopropanecarboxylate, CAS name is (7?)-cyano(3- phenoxyphenyl)methyl (15,,35)-re/-3-[(lZ)-2-chloro-3,3,3-trifluoro-1 -propenyl]-2,2-dimethylcyclopropanecarboxylate. It is used as an insecticide (pyrethroid ester insecticides) and has the chemical structure, "• Lambda Cyhalothrin is a pyrethroid insecticide registered by the U.S. Envionmental protection Agency (EPA) in 1988. Pyrethroids are synthetic chemicals that are structurally 2 similar to the natural insecticides pyrethrins. Scientists developed pyrethroid insecticides to have enhanced biological activity and desired physical and chemical properties relative to pyrethrins. Lambda Cyhalothrin is similar to the pyrethroid Cyhalothrin. Pyrethroids affect the nervous system of an organism or insects. They act by disrupting the gating mechanism of sodium channels that are involved in the generation and conduction of nerve impulses. Pyrethroid disrupt the sodium channel activation gate by keeping it in open position. Delayed closing of the gate results in prolonged excitation of nerve fibers, thus causes paralysis and death of the insects. Cyhalothrin is a mixture of four isomers, and two of these isomers compose Lambda Cyhalothrin. Due to their similarity, researchers sometimes use toxicity tests conducted with Cyhalothrin to evaluate the toxicity of Lambda Cyhalothrin. Lambda Cyhalothrin is a colorless to beige solid that has a mild odor. It has a low water solubility and is nonvolatile. Technical Cyhalothrin is a mixture of 4 isomers. 1) A pair of enantiomers: (Z(l R) cis(R)alpha-CN and Z(l S) cis(S)alpha-CN) 2)B pair of enantiomers: (Z(l R) cis (S)alpha- CN and Z(l S) cis(R)alpha-CN. The enantiomers are present in equal amounts within each pair. Lambda -Cyhalothrin consists entirely of the B pair of enantiomers. F r c=c. P (s)-alcohol (Z)-(1R)-c/s-acid C—O, / H D o - MX H> u u n CK \__y LAMBDA H (R)-alcohol (Z)-(1S)-e/'s-acid ^N -, MX C—C C-—C' -^

Documents

Application Documents

# Name Date
1 969-MUM-2008-CORRESPONDENCE(04-05-2009).pdf 2009-05-04
1 969-MUM-2008-RELEVANT DOCUMENTS [25-09-2023(online)].pdf 2023-09-25
2 969-MUM-2008-GENERAL POWER OF ATTORNEY(10-10-2011).pdf 2011-10-10
2 969-MUM-2008-RELEVANT DOCUMENTS [28-03-2020(online)].pdf 2020-03-28
3 969-MUM-2008-FORM 13(10-10-2011).pdf 2011-10-10
3 969-MUM-2008-ABSTRACT(3-7-2009).pdf 2018-08-10
4 969-MUM-2008-CORRESPONDENCE(10-10-2011).pdf 2011-10-10
4 969-MUM-2008-ANNEXURE A & B(12-9-2012).pdf 2018-08-10
5 969-MUM-2008-Request For Certified Copy-Online(17-03-2015).pdf 2015-03-17
5 969-MUM-2008-CLAIMS(3-7-2009).pdf 2018-08-10
6 Letter to PO-020914.pdf 2018-08-10
6 969-MUM-2008-CLAIMS(AMENDED)-(12-9-2012).pdf 2018-08-10
7 Certified copy request _granted patents_16.03.2015.pdf 2018-08-10
7 969-MUM-2008-CLAIMS(AMENDED)-(7-10-2013).pdf 2018-08-10
8 AlterationInregister94(1).pdf_1.pdf 2018-08-10
8 969-MUM-2008-CLAIMS(GRANTED)-(20-2-2014).pdf 2018-08-10
9 969-mum-2008-claims(provisional)-(5-5-2008).pdf 2018-08-10
9 AlterationInregister94(1).pdf 2018-08-10
10 969-mum-2008-claims.pdf 2018-08-10
10 abstract1.jpg 2018-08-10
11 969-MUM-2008-CORRESPONDENCE(25-4-2013).pdf 2018-08-10
11 969-MUM-2008_EXAMREPORT.pdf 2018-08-10
12 969-MUM-2008-CORRESPONDENCE(3-7-2009).pdf 2018-08-10
12 969-MUM-2008-SPECIFICATION(MARKED COPY)-(12-9-2012).pdf 2018-08-10
13 969-MUM-2008-CORRESPONDENCE(IPO)-(1-7-2009).pdf 2018-08-10
13 969-MUM-2008-SPECIFICATION(AMENDED)-(7-10-2013).pdf 2018-08-10
14 969-MUM-2008-CORRESPONDENCE(IPO)-(21-2-2014).pdf 2018-08-10
14 969-MUM-2008-SPECIFICATION(AMENDED)-(12-9-2012).pdf 2018-08-10
15 969-mum-2008-correspondence-received.pdf 2018-08-10
15 969-MUM-2008-REPLY TO HEARING(7-10-2013).pdf 2018-08-10
16 969-mum-2008-description (provisional).pdf 2018-08-10
16 969-MUM-2008-REPLY TO EXAMINATION REPORT(12-9-2012).pdf 2018-08-10
17 969-MUM-2008-POWER OF ATTORNEY(7-10-2013).pdf 2018-08-10
17 969-MUM-2008-DESCRIPTION(COMPLETE)-(3-7-2009).pdf 2018-08-10
18 969-MUM-2008-DESCRIPTION(GRANTED)-(20-2-2014).pdf 2018-08-10
18 969-MUM-2008-OTHER DOCUMENT(7-10-2013).pdf 2018-08-10
19 969-mum-2008-description(provisional)-(5-5-2008).pdf 2018-08-10
19 969-MUM-2008-MARKED COPY(7-10-2013).pdf 2018-08-10
20 969-mum-2008-form-3.pdf 2018-08-10
21 969-mum-2008-form 1(29-5-2008).pdf 2018-08-10
21 969-mum-2008-form-2.pdf 2018-08-10
22 969-MUM-2008-FORM 18(3-7-2009).pdf 2018-08-10
23 969-mum-2008-form 2(3-7-2009).pdf 2018-08-10
23 969-mum-2008-form-1.pdf 2018-08-10
24 969-MUM-2008-FORM 2(GRANTED)-(20-2-2014).pdf 2018-08-10
24 969-MUM-2008-FORM 5(3-7-2009).pdf 2018-08-10
25 969-mum-2008-form 3(5-5-2008).pdf 2018-08-10
25 969-mum-2008-form 2(provisional)-(5-5-2008).pdf 2018-08-10
26 969-MUM-2008-FORM 2(TITLE PAGE)-(3-7-2009).pdf 2018-08-10
26 969-MUM-2008-FORM 3(3-7-2009).pdf 2018-08-10
27 969-MUM-2008-FORM 2(TITLE PAGE)-(GRANTED)-(20-2-2014).pdf 2018-08-10
27 969-mum-2008-form 2(title page)-(provisional)-(5-5-2008).pdf 2018-08-10
28 969-MUM-2008-FORM 2(TITLE PAGE)-(GRANTED)-(20-2-2014).pdf 2018-08-10
28 969-mum-2008-form 2(title page)-(provisional)-(5-5-2008).pdf 2018-08-10
29 969-MUM-2008-FORM 2(TITLE PAGE)-(3-7-2009).pdf 2018-08-10
29 969-MUM-2008-FORM 3(3-7-2009).pdf 2018-08-10
30 969-mum-2008-form 2(provisional)-(5-5-2008).pdf 2018-08-10
30 969-mum-2008-form 3(5-5-2008).pdf 2018-08-10
31 969-MUM-2008-FORM 2(GRANTED)-(20-2-2014).pdf 2018-08-10
31 969-MUM-2008-FORM 5(3-7-2009).pdf 2018-08-10
32 969-mum-2008-form 2(3-7-2009).pdf 2018-08-10
32 969-mum-2008-form-1.pdf 2018-08-10
33 969-MUM-2008-FORM 18(3-7-2009).pdf 2018-08-10
34 969-mum-2008-form 1(29-5-2008).pdf 2018-08-10
34 969-mum-2008-form-2.pdf 2018-08-10
35 969-mum-2008-form-3.pdf 2018-08-10
36 969-mum-2008-description(provisional)-(5-5-2008).pdf 2018-08-10
36 969-MUM-2008-MARKED COPY(7-10-2013).pdf 2018-08-10
37 969-MUM-2008-DESCRIPTION(GRANTED)-(20-2-2014).pdf 2018-08-10
37 969-MUM-2008-OTHER DOCUMENT(7-10-2013).pdf 2018-08-10
38 969-MUM-2008-POWER OF ATTORNEY(7-10-2013).pdf 2018-08-10
38 969-MUM-2008-DESCRIPTION(COMPLETE)-(3-7-2009).pdf 2018-08-10
39 969-mum-2008-description (provisional).pdf 2018-08-10
39 969-MUM-2008-REPLY TO EXAMINATION REPORT(12-9-2012).pdf 2018-08-10
40 969-mum-2008-correspondence-received.pdf 2018-08-10
40 969-MUM-2008-REPLY TO HEARING(7-10-2013).pdf 2018-08-10
41 969-MUM-2008-CORRESPONDENCE(IPO)-(21-2-2014).pdf 2018-08-10
41 969-MUM-2008-SPECIFICATION(AMENDED)-(12-9-2012).pdf 2018-08-10
42 969-MUM-2008-CORRESPONDENCE(IPO)-(1-7-2009).pdf 2018-08-10
42 969-MUM-2008-SPECIFICATION(AMENDED)-(7-10-2013).pdf 2018-08-10
43 969-MUM-2008-CORRESPONDENCE(3-7-2009).pdf 2018-08-10
43 969-MUM-2008-SPECIFICATION(MARKED COPY)-(12-9-2012).pdf 2018-08-10
44 969-MUM-2008-CORRESPONDENCE(25-4-2013).pdf 2018-08-10
44 969-MUM-2008_EXAMREPORT.pdf 2018-08-10
45 969-mum-2008-claims.pdf 2018-08-10
45 abstract1.jpg 2018-08-10
46 969-mum-2008-claims(provisional)-(5-5-2008).pdf 2018-08-10
46 AlterationInregister94(1).pdf 2018-08-10
47 969-MUM-2008-CLAIMS(GRANTED)-(20-2-2014).pdf 2018-08-10
47 AlterationInregister94(1).pdf_1.pdf 2018-08-10
48 Certified copy request _granted patents_16.03.2015.pdf 2018-08-10
48 969-MUM-2008-CLAIMS(AMENDED)-(7-10-2013).pdf 2018-08-10
49 Letter to PO-020914.pdf 2018-08-10
49 969-MUM-2008-CLAIMS(AMENDED)-(12-9-2012).pdf 2018-08-10
50 969-MUM-2008-Request For Certified Copy-Online(17-03-2015).pdf 2015-03-17
50 969-MUM-2008-CLAIMS(3-7-2009).pdf 2018-08-10
51 969-MUM-2008-CORRESPONDENCE(10-10-2011).pdf 2011-10-10
51 969-MUM-2008-ANNEXURE A & B(12-9-2012).pdf 2018-08-10
52 969-MUM-2008-FORM 13(10-10-2011).pdf 2011-10-10
52 969-MUM-2008-ABSTRACT(3-7-2009).pdf 2018-08-10
53 969-MUM-2008-GENERAL POWER OF ATTORNEY(10-10-2011).pdf 2011-10-10
53 969-MUM-2008-RELEVANT DOCUMENTS [28-03-2020(online)].pdf 2020-03-28
54 969-MUM-2008-CORRESPONDENCE(04-05-2009).pdf 2009-05-04
54 969-MUM-2008-RELEVANT DOCUMENTS [25-09-2023(online)].pdf 2023-09-25

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