DESC:FIELD OF THE INVENTION:
The present invention relates to synergistic agrochemical combination comprising herbicide(s) and mixture thereof; and plant health additives for reducing phytotoxicity in crops on post herbicide application. More particularly, the present invention relates to a herbicidal composition for weeds control in post emergence conditions comprising bioactive amounts of (A) a herbicide selected from Acetyl CoA Carboxylase (ACCase) Inhibitor for control of grassy weeds or mixture thereof; (B) a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grassy weeds and sedges in economical crops or mixture thereof; and (C) a plant health additive(s) for reducing phytotoxicity in crops on post herbicide application or mixture thereof. The present invention further relates to process of preparing said composition along with at least one inactive excipients and formulation thereof.

BACKGROUND OF THE INVENTION:
Weeds are a nuisance in most agricultural crops, orchards, plantation crops, landscapes and sometimes the herbicides used to control the weeds end up injuring crops, useful plants, some of ornamental plants. Herbicide injury is observed after application of herbicide in terms of stunting, yellowing, scorching, epinasty, hyponasty, germination loss, poor plant population stand in field and even loss of crop or plant yield. It normally happens while not following the directions on the label as carefully as one should. Farmers tend to use more herbicide than the label instructs or can be careless and spray during windy conditions or wave the wand around so that the spray drifts onto non-target plants.
Herbicides are pesticides useful for killing or controlling unwanted plants. Generally, there are two kinds of herbicides- selective and non-selective. Selective herbicides kill certain target weeds while leaving the desired crop relatively unharmed while non-selective herbicides kill both the weeds and crops. Profitable crop production depends on effective weed control. The weeds can reduce field crop yields by competing for water, sunlight and nutrients. In today’s crop production systems, starting off with a good burn-down program is a must as it helps to achieve maximum initial crop growth and reduce weed interference during early stages of the crop cycle. Since the weed-crop competition is critical during the early stages of crop cycle, the weed interference at early stage has a direct impact on the yield of the crop.
The term for plant damage is “phytotoxicity” and it can be caused by pesticides,
nutrients, or physical and environmental damage (wind, sun, hail, etc.). Often the
identity of the herbicide can be determined by the injury symptoms on the plants.
Symptoms can be divided into 5 main categories: leaf and shoot malformations,
root and shoot stunting, leaf spotting, leaf chlorosis (yellowing), and leaf necrosis
(death).
An effective weed control can be achieved by usage of herbicides appropriately. The activity of herbicides can be enhanced in various ways to achieve the maximum benefit. One of the ways is to use combinations. However, identifying appropriate combinations, which will reduce the toxicity at the same time due to the application of herbicides on crop, their agrochemical application rates and ratio of the combinations is essential to achieve efficacious control, which is not straight forward. The selection of a particular formulation type is more cumbersome for an agrochemical combination.
The efficacy of these herbicides against harmful weeds in the crop plants depends on the application rate, the formulation ingredients, the harmful weeds to be controlled, the climatic conditions and the soil conditions.
Farmers are applying more than one active ingredients or applying high use rate to control different types of weeds at a time, to control multiple generations of weeds in fields, to control troublesome weeds and to get residual control. Such practices increases the chances of herbicidal injury or phytotoxicity to the target crops.
There are many herbicides which used in combination creates characteristic phytotoxic injuries in plants like malformed, distorted leaves and shoots, stunted shoots and roots, chlorotic, necrotic, or spotted leaves.
However, there remains a great need for improved broadleaf and grassy weed control compositions and a method of controlling such noxious vegetation in pre and post emergence without adversely affecting desirable plants and which reduces the amount of chemical herbicidal agent necessary to obtain the acceptable weed control along with reducing the undesirable post treatment toxic effect or injury of the herbicides on crops.
There are many combinations of herbicides known in the art for the control of weeds. For example, EP2836072B1 relates to an herbicidal composition comprising a uracil compound as an active ingredient. Furthermore, the invention relates to methods of applying said mixture. The patent further relates to the herbiciedes like metamifop; Pinoxaden present in the composition.
US8802597B2 relates to certain pyrimidines group of herbicides, their N-oxides, agriculturally suitable salts and compositions, and methods of their use for controlling undesirable vegetation. More precisely, the herbicidal composition comprising compounds like Propaquizafop, Bispyribac sodium, Chlorimuron ethyl along with more herbicidal compounds.
US8846571B2 relates to herbicidal compositions containing as active ingredients (a) a herbicidal benzoylpyrazole compound or its salt and (b) other herbicidal compound. The patent further relates to herbicidal mixture comprisies of herbicidal compounds like Chlorimuron ethyl, metribuzin, propargyl, pyroxasulfone.
There is however a need for improvement of these combinations. Further there is a need of a safener in the herbicidal composition which will reduce the unwanted phytotoxic effect on crops after application of herbicide. Plant health additives play a significant role in development of crop and reduces the phytotoxic effect. Single active combinations used over a long period of time has resulted in resistance. With the onset of resistance to certain weeds, there is a need in the art for a combination of actives that decreases chances of resistance and improves the spectrum of controlling grassy, broad leaf weeds and sedges with pre-emergence and post-emergence application.
However still there is a need of herbicidal composition comprises of a herbicide selected from Acetyl CoA Carboxylase (ACCase) Inhibitor for control of grasses or mixture thereof; a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grasses in crops of useful plants or mixture thereof; and a plant health additive(s) for reducing phytotoxicity in crops on post herbicide application or mixture thereof which overcomes some of the existing problems and can be prepared easily without much complex manufacturing process.
In general use, the herbicidal actives are used in the form of a dilute aqueous composition because it can attain a good interaction with the target weed. However, most active herbicidal compounds that are used as pesticides are only sparingly or even insoluble in water. The low solubility of such compounds present the challenges and difficulties to formulator in formulating herbicidal compounds in stable formulations that can be easily stored for a long time and which still have a high stability and effective activity until end use. This problem especially occurs and may get worsen if more than one active compound is present in the composition.
Therefore, one object of the present invention is to provide improved herbicidal combination for weeds control in pre and post emergence conditions along with plant health additives acting as a safener in the herbicidal composition which will reduce the unwanted phytotoxic effect on crops after application of herbicide. Another object of the present invention is to provide a method and a composition for controlling weeds in pre and post emergence conditions.
Yet another object of the present invention is to provide improved combinations of improved broadleaf and grassy weed control without adversely affecting desirable plants and reducing the unwanted effect by using plant health additives.
Embodiment of the present invention can ameliorate one or more of the above mentioned problems.
Inventors of the present invention have surprisingly found that the novel synergistic
herbicidal composition of a herbicide selected from Acetyl CoA Carboxylase (ACCase) Inhibitor for control of grasses or mixture thereof; a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grasses in crops of useful plants or mixture thereof; and a plant health additive(s) for reducing phytotoxicity in crops on post herbicide application or mixture thereof as described herein which can provide solution to the above mentioned problems.

SUMMARY OF THE INVENTION
Therefore an aspect of the present invention provides a synergistic herbicidal composition comprising plant health additive(s) for reducing phytotoxicity in crops on post herbicide application.
Another aspect of the present invention provides composition comprises with various compounds and micronutrients as a plant health additive along with herbicides for reducing phytotoxicity in crops on post herbicide application.
Therefore an aspect of the present invention provides a synergistic herbicidal composition comprising bioactive amounts of (A) a herbicide selected from Acetyl CoA Carboxylase (ACCase) Inhibitor for control of grasses or mixture thereof; (B) a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grasses in crops of useful plants or mixture thereof; and (C) a plant health additive(s) for reducing phytotoxicity in crops on post herbicide application or mixture thereof.
Further aspect of the present invention provides a synergistic herbicidal composition comprising bioactive amounts of (A) a herbicide from Acetyl CoA Carboxylase (ACCase) Inhibitor for control of grasses of Aryloxyphenoxy group is selected from propionate ('FOPs')-clodinafop-propargyl, cyhalofop-butyl, diclofop, fenoxaprop-P, fluazifop-P, haloxyfop, metamifop, propaquizafop, quizalofop-P-ethyl;of Cyclohexanedione ('DIMs') group is selected from alloxydim, butroxydim, clethodim, cycloxydim, sethoxydim, tralkoxydim, tepraloxydim; of Phenylpyrazoline ('DEN') group is selected from pinoxaden or mixture thereof; (B) a one or more herbicide(s) selected from the group of Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor, Synthetic Auxin, Inhibitor of photosynthesis at photosystem II site A, Inhibitor of photosynthesis at photosystem II site B, Inhibitor of lipid synthesis; not ACCase inhibition, Inhibitor of 5-enolypyruvyl-shikimate-3-phosphate synthase (EPSPS), Inhibitor of glutamine synthetase: Phosphonic acid, Inhibitor of phytoene desaturase (PDS), Inhibitor of 1-deoxy-D-xyulose 5-phosphate sunthatase (DOXP synthase), Inhibitor of protoporphyrinogen oxidase (Protox, PPO), Mitosis Inhibitor, Inhibitor of 7,8-dihydro-preroate synthetase (DHP), Inhibitor of indoleacetic acid transport, Inhibitor of cell wall synthesis site A, Inhibitor of cell wall synthesis site B, Inhibitor of cell wall synthesis site C, Inhibition of cellulose synthesis, Photosystem I electron diverter, Membrane disruptor (uncouplers), Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD), Tyrosine Aminotransferase, Inhibition of dihydroorotate dehydrogenase(DHODH), HTS (homogentisate solanesyltransferase)-a downstream enzyme of HPPD, VLCAFE inhibitors, Inhibition of lycopene cyclase, Inhibition of Solanesyl Diphosphate Synthase (SDS), Inhibition of serine-threonine protein phosphatase or Herbicide with unknown mode of action or mixture thereof; and (C) a plant health additive(s) for reducing phytotoxicity in crops on post herbicide application or mixture thereof.
In one aspect the invention provides a synergistic herbicidal composition comprising plant heath additives as a safener in composition for reducing phytotoxicity in crops on post herbicide application.
In further aspect the present invention provides a synergistic herbicidal composition comprising plant heath additives to promote speedy recovery of the crop or plant from herbicidal injury. Thus accordingly reduces the stress due to abiotic factors and thus promotes overall plant or crop health and there by plant or crop yield.
Accordingly, in a further aspect, the present invention provides a combination and a method of controlling pre-emergence and post-emergence weeds and provide a herbicidal combination for improved broadleaf and grassy weed control without adversely affecting desirable plants by reducing phytotoxicity in crops on post herbicide application.
Yet in another aspect, the present invention provides a herbicidal combination which reduces the amount of chemical herbicidal agent necessary to obtain the acceptable weed control.
Accordingly, the present invention relates to method which provides a broader spectrum of controlling weeds that helps in resistance management, thus preventing the weed from becoming resistant to either of the herbicides while providing a broader spectrum of control at lower use rates.
As per one embodiment formulation for the herbicidal composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR); and and one or more customary formulation adjuvants such as a) dispersant b) wetting agent c) anti-foaming agent d) biocides e) anti-freezing agent f) suspending agent g) thickener h) coating agent and i) buffering agent.
The remainder of the aqueous formulation is preferably wholly water but may comprise other materials, such as inorganic salts. The formulation is preferably, completely free from organic solvents.
Accordingly, in a first aspect, the present invention provides a synergistic herbicidal compositions comprising bioactive amounts of (A) a herbicide from Acetyl CoA Carboxylase (ACCase) Inhibitor for control of grasses of Aryloxyphenoxy group is selected from propionate ('FOPs')-clodinafop-propargyl, cyhalofop-butyl, diclofop, fenoxaprop-P, fluazifop-P, haloxyfop, metamifop, propaquizafop, quizalofop-P-ethyl;of Cyclohexanedione ('DIMs') group is selected from alloxydim, butroxydim, clethodim, cycloxydim, sethoxydim, tralkoxydim, tepraloxydim; of Phenylpyrazoline ('DEN') group is selected from pinoxaden or mixture thereof; (B) a one or more herbicide(s) selected from the group of Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor, Synthetic Auxin, Inhibitor of photosynthesis at photosystem II site A, Inhibitor of photosynthesis at photosystem II site B, Inhibitor of lipid synthesis; not ACCase inhibition, Inhibitor of 5-enolypyruvyl-shikimate-3-phosphate synthase (EPSPS), Inhibitor of glutamine synthetase: Phosphonic acid, Inhibitor of phytoene desaturase (PDS), Inhibitor of 1-deoxy-D-xyulose 5-phosphate sunthatase (DOXP synthase), Inhibitor of protoporphyrinogen oxidase (Protox, PPO), Mitosis Inhibitor, Inhibitor of 7,8-dihydro-preroate synthetase (DHP), Inhibitor of indoleacetic acid transport, Inhibitor of cell wall synthesis site A, Inhibitor of cell wall synthesis site B, Inhibitor of cell wall synthesis site C, Inhibition of cellulose synthesis, Photosystem I electron diverter, Membrane disruptor (uncouplers), Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD), Tyrosine Aminotransferase, Inhibition of dihydroorotate dehydrogenase(DHODH), HTS (homogentisate solanesyltransferase)-a downstream enzyme of HPPD, VLCAFE inhibitors, Inhibition of lycopene cyclase, Inhibition of Solanesyl Diphosphate Synthase (SDS), Inhibition of serine-threonine protein phosphatase or Herbicide with unknown mode of action or mixture thereof; and (C) a plant health additive(s) ) for reducing phytotoxicity in crops on post herbicide application or mixture thereof and one or more customary formulation adjuvants; shows synergistic activity.

DETAILED DESCRIPTION OF THE INVENTION:
The term "synergistic", as used herein, refers the combined action of two or more active
agents blended together and administered conjointly that is greater than the sum of their
individual effects.
"Bioactive amounts” as mentioned herein means that amount which, when applied treatment of crops, is sufficient to effect such treatment.
For the purposes of the present invention, plant health additive is used as ‘safener’ and the term ‘safener’ in present context is defined as substances which reduce or prevent the phytotoxic effect of crop protectants specifically herbicide, on plants treated therewith and/or on plants whose seeds and/or growth substrate have been treated or are treated therewith.
The term ‘herbicide’ is used herein to mean an active ingredient that kills, controls or otherwise adversely modifies the growth of unwanted plants. An herbicidally effective or vegetation controlling amount is an amount of active ingredient which causes an adversely modifying effect and includes deviations from natural development, killing, regulation, desiccation, retardation, and the like.
The term “seed” represents all types of plant propagation material. It comprises seeds in the actual sense, grains, fruits, tubers, the rhizome, spores, cuttings, slips, meristem tissue, individual plant cells and any form of plant tissue from which a complete plant can be grown. Preferably, it takes the form of seed in the actual sense.
The term “phytotoxicity” as used herein means unintended herbicidal effect on a plant of interest resulting in significant damage to the plant. In an embodiment the present invention relates to use of a pyrethroid insecticide for reducing phytotoxicity in crops on post herbicide application.
Therefore an aspect of the present invention provides a synergistic herbicidal composition comprising bioactive amounts of (A) a herbicide selected from Acetyl CoA Carboxylase (ACCase) Inhibitor for control of grasses or mixture thereof; (B) a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grasses in crops of useful plants or mixture thereof; and (C) a plant health additive(s) for reducing phytotoxicity in crops on post herbicide application or mixture thereof.
Further aspect of the present invention provides a synergistic herbicidal composition comprising bioactive amounts of (A) a herbicide from Acetyl CoA Carboxylase (ACCase) Inhibitor for control of grasses of Aryloxyphenoxy group is selected from propionate ('FOPs')-clodinafop-propargyl, cyhalofop-butyl, diclofop, fenoxaprop-P, fluazifop-P, haloxyfop, metamifop, propaquizafop, quizalofop-P-ethyl;of Cyclohexanedione ('DIMs') group is selected from alloxydim, butroxydim, clethodim, cycloxydim, sethoxydim, tralkoxydim, tepraloxydim; of Phenylpyrazoline ('DEN') group is selected from pinoxaden or mixture thereof; (B) a one or more herbicide(s) selected from the group of Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor, Synthetic Auxin, Inhibitor of photosynthesis at photosystem II site A, Inhibitor of photosynthesis at photosystem II site B, Inhibitor of lipid synthesis; not ACCase inhibition, Inhibitor of 5-enolypyruvyl-shikimate-3-phosphate synthase (EPSPS), Inhibitor of glutamine synthetase: Phosphonic acid, Inhibitor of phytoene desaturase (PDS), Inhibitor of 1-deoxy-D-xyulose 5-phosphate sunthatase (DOXP synthase), Inhibitor of protoporphyrinogen oxidase (Protox, PPO), Mitosis Inhibitor, Inhibitor of 7,8-dihydro-preroate synthetase (DHP), Inhibitor of indoleacetic acid transport, Inhibitor of cell wall synthesis site A, Inhibitor of cell wall synthesis site B, Inhibitor of cell wall synthesis site C, Inhibition of cellulose synthesis, Photosystem I electron diverter, Membrane disruptor (uncouplers), Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD), Tyrosine Aminotransferase, Inhibition of dihydroorotate dehydrogenase(DHODH), HTS (homogentisate solanesyltransferase)-a downstream enzyme of HPPD, VLCAFE inhibitors, Inhibition of lycopene cyclase, Inhibition of Solanesyl Diphosphate Synthase (SDS), Inhibition of serine-threonine protein phosphatase or Herbicide with unknown mode of action or mixture thereof; and (C) a plant health additive(s) for reducing phytotoxicity in crops on post herbicide application or mixture thereof.
In an embodiment of the present invention herbicide from Acetyl CoA Carboxylase (ACCase) Inhibitor is selected from Aryloxyphenoxy-propionate ('FOPs') such as clodinafop-propargyl, cyhalofop-butyl, diclofop, fenoxaprop-P, fluazifop-P, haloxyfop, metamifop, propaquizafop, quizalofop-P-ethyl; Cyclohexanedione ('DIMs') such as alloxydim, butroxydim, clethodim, cycloxydim, sethoxydim, tralkoxydim, tepraloxydim; Phenylpyrazoline ('DEN') such as pinoxaden.
In an embodiment of the present invention herbicide of Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor from Sulfonylurea group is selected from amidosulfuron, azimsulfuron, bensulfuron methyl, chlorimuron ethyl, chlorsulfuron, cinosulfuron, cloransulfuron methyl, cyclosulfamuron, ethametsulfuron methyl, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron methyl sodium, foramsulfuron, halosulfuron methyl, imazosulfuron, iodosulfuron, mesosulfuron, metazosulfuron, metsulfuron mehtyl, nicosufulfuron, primisulfuron methyl, prosulfuron, pyrazosulfuron ehtyl, rimsulfuron, rimsulfuron, sulfometuron methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron, tribenuron methyl, trifloxysulfuron, triflusulfuron methyl.
In an embodiment of the present invention herbicide from Acetoacetate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor from Pyrimidinyl(thio)benzoate group is selected from bispyribac-sodium, pyribenzoxim, pyrimisulfan, pyrithiobac sodium; from Triazolopyrimidine group selected from cloransulam-methyl, diclosulam, florasulam, flumetsulam, penoxsulam, pyroxsulam.
In an embodiment of the present invention herbicide from Acetoacetate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor of Sulfonylaminocarbonyl group is selected from triazolinone-flucarbazone-sodium, propoxycarbazone-sodium, thiencarbazone-methyl; from Imidazolinone group such as imazamethabenz methyl, imazamox, imazapic, imazapyr, imazaquin, imazethapyr; from Sulfonanilides group is triafamone.
In an embodiment of the present invention herbicide from Synthetic Auxin of Phenoxy carboxylic acid group is selected from 2,4-D, 2,4-DB, dichloroprop, MCPA, MCPB, mecoprop; of Pyrimidine carboxylic acid group is selected from aminocyclopyrachlor; of Pyridine carboxylic acid group is selected from aminopyralid, clopyralid, fluroxypyr, picloram, triclopyr; of Benzoic acid group is dicamba; of Quinoline carboxylic acid group is quinclorac; and halauxifen methyl.
In an embodiment of the present invention herbicide from Inhibitor of photosynthesis at photosystem II site A of Phenyl carbamate group is selected from desmedipham, phenmedipham; of Pyridazinone group is pyrazon; of Triazine group is selected from ametryn, atrazine, cyanazine, desmetryn, prometon, prometryn, propazine, simazine, simetryn, terbumeton, terbuthylazine, trietazine; of Triazinone group is selected from hexazione, metamitron, metribuzin; of Triazolinone group is amicarbazone; of Urea group is metoxuron; of Uracil group is group is selected from bromacil, terbacil.
In an embodiment of the present invention herbicide from Inhibitor of photosynthesis at photosystem II site B of Benzothiadiazinone group is bentazone; of Nitrile group is selected from bromoxynil, ioxynil; of Phenyl-pyridazine group is pyridate.
In an embodiment of the present invention herbicide from Inhibitor of lipid synthesis; not ACCase inhibition of Benzofuran group is ethofumesate; of Phosphorodithioate group is bensulie; of Thiocarbamate group is selected from butylate, cycloate, EPTC, esprocarb, molinate, pebulate, prosulfocarb, thiobencarb, triallate, vernolate.
In an embodiment of the present invention herbicide from Inhibitor of 5-enolypyruvyl-shikimate-3-phosphate synthase (EPSPS) of Glycine group is Glyphosate.
In an embodiment of the present invention herbicide from Inhibitor of glutamine synthetase of Phosphonic acid group is glufosinate.
In an embodiment of the present invention herbicide from Inhibitor of phytoene desaturase (PDS) of Pyridinecarboxamide group is selected from diflufenican, picolinafen; of Pyridazinone group is norflurazon; and other compounds such as beflubutamid, fluridone, flurochloridone, flurtamone.
In an embodiment of the present invention herbicide from Inhibitor of 1-deoxy-D-xyulose 5-phosphate sunthatase (DOXP synthase) of Isoxazolidinone group is clomazone.
In an embodiment of the present invention herbicide from Inhibitor of protoporphyrinogen oxidase (Protox, PPO) of Dipheylether group is selected from aclifluorfen, bifenox, fluoroglycofen, fomesafen, lactofen, oxyfluorfen; of Triazolinone group is selected from azafenidin, carfentrazone-ethyl, flufenpyr-ethyl, sulfentrazone; of Pyrimidinedione group is selected from butafenacil, saflufenacil; of N-phenylphthalimide group is selected from flumiclorac, flumioxazin; of N-Phenyl-imide group is trifludimoxazin; of Thiadiazole group is fluthiacet-methyl; of Oxadiazole group is selected from oxadiargyl, oxadiazon; of Phenylpyrazole group is pyraflufen-ethyl, of other group is pyraclonil; of Uracil group is tiafenacil; of Pyrazole group is cyclopyranil.
In an embodiment of the present invention herbicide from Mitosis Inhibitor of Chloroacetamide group is selected from acetochlor, alachlor, butachlor, dimethenamid, metazachlor, pretilachlor, propachlor, S-metolachlor, thenylchlor; of Tetrazolinone group is fentrazamide; of Oxyacetamide group is selected from flufenacet, mefenacet; of Acetamide group is napropamide; of Carbamate group is carbetamide and Other compound such as anilofos.
In an embodiment of the present invention herbicide from Inhibitor of 7,8-dihydro-preroate synthetase (DHP) of Carbamate group is asulam.
In an embodiment of the present invention herbicide from Inhibitor of indoleacetic acid transport of Phthalamate semicarbazone group is selected from diflufenzopyr, naptalam.
In an embodiment of the present invention herbicide from Inhibitor of indoleacetic acid transport of Phthalamate semicarbazone group is selected from diflufenzopyr, naptalam.
In an embodiment of the present invention herbicide from Inhibitor of cell wall synthesis site A of Nitrile group is dichlobenil.
In an embodiment of the present invention herbicide from Inhibitor of cell wall synthesis site B of Benzamide group is isoxaben.
In an embodiment of the present invention herbicide from Inhibitor of cell wall synthesis site C of Alkylazines group is selected from indaziflam, triaziflam.
In an embodiment of the present invention herbicide from Inhibitors of cellulose synthesis of Triazolocarboxamide group is flupoxam; of nitriles group is dichlobenil, chlorthiamide.
In an embodiment of the present invention herbicide from Inhibitors of cellulose synthesis of Triazolocarboxamide group is flupoxam; of nitriles group is dichlobenil, chlorthiamide.
In an embodiment of the present invention herbicide from Photosystem I electron diverter of Pyridiniums group is selected from cyperquat, diquat, morfamquat, paraquat.
In an embodiment of the present invention herbicide from Membrane disruptor (uncouplers) of Dinitrophenol group is dinoterb.
In an embodiment of the present invention herbicide from Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD) of Pyrazole group is selected from benzofenap, pyrasulfotole, pyrazolynate, pyrazoxyfen, tolpyralate; of Benzoylbicyclooctanedione group is benzobicyclon; Triketone group is selected from mesotrione, tembotrione, sulcotrione, tefuryltrione, fenquinotrione, lancotrione sodium; of Isoxazoles group is selected from isoxaflutole; bicyclo ring compound group is bicyclopyrone.
In an embodiment of the present invention herbicide from Tyrosine Aminotransferase class is selected from cinmethylin, methiozolin.
In an embodiment of the present invention herbicide from Inhibitors of dihydroorotate dehydrogenase (DHODH) is tetflupyrolimet.
In an embodiment of the present invention herbicide from HTS (homogentisate solanesyltransferase)-a downstream enzyme of HPPD is cyclopyrimorate.
In an embodiment of the present invention herbicide from VLCAFE inhibitors of Isoxazoline group is pyroxasulfone, of Triazolinone group is ipfencarbazone, of Trifluoromethansulfonanilides group is dimesulfazet, and other compounds such as fenoxasulfone.
In an embodiment of the present invention herbicide from Inhibitors of lycopene cyclase is amitrole.
In an embodiment of the present invention herbicide from Inhibitors of Solanesyl Diphosphate Synthase (SDS) is aclonifen.
In an embodiment of the present invention herbicide from Inhibitors of serine-threonine protein phosphatase is endothall.
In an embodiment of the present invention herbicide with unknown mode of action is selected from bromobutide, cacodylic acid, CAMA, cumyluron, difenzoquat, DSMA, dymron=daimuron, etobenzanid, fasamine, methyldymron, monalide, MA, oleic acid, oxaziclomefone, pelargonic acid, pyributicarb, quinoclamine, diphenamid, naproanilide, napropamide, flamprop-m, tebutam, dalapon, flupropanate, TCA, flamprop-m, tebutam, bensulide, mefluidide, perfluidone, dazomet, acrolein, AMS, benzolin, benoxacor, cacodylic acid, cloquintocet mexyl, copper chelate, copper sulfate, cyprosulfamide, dichlomid, dietholate, dimethipin, fenchlorazole-ethyl. fenclorim, fluxofenim, maleic hydrazide, mefenpyr-diethyl, mefluidide, metaborate, oxaziclomefone, sodium chlorate, epyrifenacil, bixzolone.
In an embodiment of the present invention Plant health additive is selected from humic acid (salts), fulvic acid (salts), amino acids (alanine, arginine, aspartic acid, cysteine, glutamic acid, glycine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, proline, serine, threonine, tryptophan, tyrosine, valine or mixture thereof), protein hydrolysates, peptides, organic acid, acetylthioproline, thiazolidine carboxylic acid, jasmonic acid, methyl jasmonate, chitosan, chitin, seaweed extract (Ascophyllum nodosum), polyamines, silicic acid (salts)-orthosilicic acid (H4Si04), silica nanoparticles (10-100 nm), calcium silicate, potassium silicate, sodium silicate), silicyclic acid, lactic acid, phenyllactic acid, fumaric acid, acibenzolar-s-methyl, gibberellic acid, GA3, brassinolide, forchlorfenuron, triacontanol, silicyclic acid, Nitrophenolate (sodium para-nitrophenolate, ortho-nitrophenolate, sodium-5-nitroguaiacolate), nitrobenzene or mixture thereof.
In an embodiment of the present invention plant health additive from group of micronutrients is selected from Zinc (zinc sulphate heptahydrate ZnSO47H2O, zinc sulphate mono hydrate ZnSO4.H2O, chelated zinc as Zn-EDTA, zinc oxide, Zinc Lactate Gluconate, Zinc Polyflavonoid), Boron (borax-sodium tetraborate, boric acid (H3BO3), di-sodium octa borate tetra hydrate (Na2B8O13.4H2O), di-sodium tetra borate penta hydrate, anhydrous borax, ), Manganese (manganese sulphate), Copper (copper sulphate), Iron (ferrous sulphate, chelated iron as Fe-EDTA), Molybdanum (ammonium molybdate), Magnesium (Magnesium sulphate) or Sulphur (elemental sulphur, boronated sulphur) and mixture thereof.
Acetyl CoA Carboxylase (ACCase) Inhibitor:
Clodinafop-propargyl is a carboxylic ester resulting from the formal condensation of the carboxy group of clodinafop with the hydroxy group of prop-2-yn-1-ol. It has IUPAC name as prop-2-ynyl (2R)-2-[4-(5-chloro-3-fluoropyridin-2-yl)oxyphenoxy]propanoate. It is widely used as a herbicide for the control of annual grass weeds in cereal crops. It has a role as an EC 6.4.1.2 (acetyl-CoA carboxylase) inhibitor, a herbicide and an agrochemical. It is a carboxylic ester, an aromatic ether, an organochlorine compound, an organofluorine compound, a member of pyridines and a propyzamide. It derives from a prop-2-yn-1-ol and a clodinafop.
Metamifop is a 2-{4-[(6-chloro-1,3-benzoxazol-2-yl)oxy]phenoxy}-N-(2-fluoro phenyl)-N-methylpropanamide that has R-configuration. It is an inhibitor of acetyl-coenzyme A carboxylase (ACCase) and a postemergence herbicide which exhibits high control efficacy against sensitive weeds, especially Echinochloa crus-galli in paddy fields. It has a role as an EC 6.4.1.2 (acetyl-CoA carboxylase) inhibitor and a phenoxy herbicide. It is an enantiomer of a (S)-metamifop.
Propaquizafop is a herbicide from class of Acetyl CoA Carboxylase (ACCase) Inhibitor. It ha IUPAC name as 2-(propan-2-ylideneamino) oxyethyl 2-[4-(6-chloroquinoxalin-2-yl) oxyphenoxy] propanoate. It is a herbicide of the aryloxyphenoxy propionates family. It is used for the post emergence control of a wide range of annual and perennial grasses. Propaquizafop is selective to all major broadleaf crops, during all their stages of development. Propaquizafop is a systemic herbicide, which is quickly absorbed by the leaves and translocated from the foliage to the growing points of the leaves and roots of the sprayed weeds.
Quizalofop-P-ethyl is an ethyl 2-{4-[(6-chloroquinoxalin-2-yl) oxy] phenoxy} propanoate that has R configuration. A proherbicide for quizalofop-P, it is used to control annual and perennial grass weeds in a variety of crops, including potatoes, sugar beet, peanuts, cotton and flax. It has a role as a proherbicide and an agrochemical. It is an ethyl 2-{4-[(6-chloroquinoxalin-2-yl) oxy]phenoxy}propanoate and a quinoxaline herbicide. It derives from a quizalofop-P. It is an enantiomer of a (S)-quizalofop-ethyl.
Phenylpyrazoline ('DEN'):
Pinoxaden is a pyrazolooxadiazepine that is 7-oxo-1,2,4,5-tetrahydro-7H-pyrazolo[1,2-d][1,4,5]oxadiazepin which is substituted at positions 8 and 9 by 2,6-diethyl-4-methylphenyl and pivaloyloxy groups, respectively. A pro-herbicide (by hydrolysis of the pivalate ester to give the corresponding enol), it is used for control of grass weeds in cereal crops. It has a role as a xenobiotic, an environmental contaminant, an agrochemical, an EC 6.4.1.2 (acetyl-CoA carboxylase) inhibitor and a proherbicide. It is a pivalate ester and a pyrazolooxadiazepine. It derives from a pinoxaden acid.
Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor:
Bispyribac-sodium is a herbicide from class of Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor. It has IUPAC name as sodium; 2,6-bis[(4,6-dimethoxypyrimidin-2-yl)oxy]benzoate. It has been used as a Pesticides used to destroy unwanted vegetation, especially various types of weeds, grasses (POACEAE), and woody plants.
Imazethapyr is an aromatic carboxylic acid and a member of pyridines. It has IUPAC name as 5-ethyl-2-(4-methyl-5-oxo-4-propan-2-yl-1H-imidazol-2-yl)pyridine-3-carboxylic acid. It has been absorbed by plant roots and foliage, being translocated to meristematic regions where it inhibits the biosynthesis of valine, leucine and isoleucine preventing cell division.
Inhibitor of protoporphyrinogen oxidase (Protox, PPO):
Acifluorfen is a member of the class of benzoic acids that is 2-nitrobenzoic acid in which the hydrogen at position 5 is replaced by a 2-chloro-4-(trifluoromethyl)phenoxy group. It ha IUPAC name as 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoic acid. It is a herbicide used for the post-emergence control of a variety of annual broadleaf weeds. It has a role as a herbicide, an agrochemical and an EC 1.3.3.4 (protoporphyrinogen oxidase) inhibitor. It is a member of benzoic acids, an organochlorine compound, an organofluorine compound, an aromatic ether, a monocarboxylic acid and a C-nitro compound.
Fomesafen is an N-sulfonylcarboxamide that is N-(methylsulfonyl)benzamide in which the phenyl ring is substituted by a nitro group at position 2 and a 2-chloro-4-(trifluoromethyl)phenoxy group at position 5. It has IUPAC name as 5-[2-chloro-4-(trifluoromethyl)phenoxy]-N-methylsulfonyl-2-nitrobenzamide. A protoporphyrinogen oxidase inhibitor, it was specially developed for use (generally as the corresponding sodium salt, fomesafen-sodium) for post-emergence control of broad-leaf weeds in soya. It has a role as a herbicide, an agrochemical and an EC 1.3.3.4 (protoporphyrinogen oxidase) inhibitor. It is an aromatic ether, a N-sulfonylcarboxamide, a C-nitro compound, an organofluorine compound, a member of monochlorobenzenes and a member of phenols.
Carfentrazone-ethyl is Ethyl 2-chloro-3-{2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl]-4-fluorophenyl}propanoate is an ethyl ester resulting from the formal condensation of the carboxy group of 2-chloro-3-{2-chloro-5-[4-(difluoromethyl)-3-methyl-5-oxo-4,5-dihydro-1H-1,2,4-triazol-1-yl]-4-fluorophenyl} pro panoic acid with ethanol. It has a role as a proherbicide.
Fluthiacet-methyl is a methyl ester resulting from the formal condensation of the carboxy group of fluthiacet with methanol. A proherbicide for fluthiacet, it is used for the control of broad-leaved weeds in crops such as maize and soya. It has IUPAC name as methyl 2-[2-chloro-4-fluoro-5-[(3-oxo-5,6,7,8-tetrahydro[1,3,4]thiadiazolo[3,4-a]pyridazin-1 ylidene)amino]phenyl]sulfanyacetate. It has a role as an agrochemical, an EC 1.3.3.4 (protoporphyrinogen oxidase) inhibitor and a proherbicide. It is an organic sulfide, a methyl ester, a member of monochlorobenzenes, a member of monofluorobenzenes and a thiadiazolopyridazine.
Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD):
Tolpyralate is pyrazole group of herbicide having IUPAC name as 1-[2-ethyl-4-[3-(2-methoxyethoxy)-2-methyl-4-methylsulfonylbenzoyl]pyrazol-3-yl]oxyethyl methyl carbonate. It is an aromatic ether, a benzoylpyrazole, a carbonate ester, a member of toluenes, an aromatic ketone and a sulfone. It has mode of action as an inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD)
Mesotrione is an aromatic ketone that is cyclohexa-1,3-dione in which one of the hydrogens at position 2 is substituted by a 4-(methanesulfonyl)-2-nitrobenzoyl group. It has IUPAC name as 2-(4-methylsulfonyl-2-nitrobenzoyl)cyclohexane-1,3-dione. It has a role as a herbicide, an EC 1.13.11.27 (4-hydroxyphenylpyruvate dioxygenase) inhibitor, a xenobiotic, an environmental contaminant and a carotenoid biosynthesis inhibitor. It is a sulfone, a C-nitro compound, an aromatic ketone and a beta-triketone. It derives from a benzophenone.
Tembotrione is an aromatic ketone. It has IUPAC name as 2-[2-chloro-4-methylsulfonyl-3-(2,2,2-trifluoroethoxymethyl)benzoyl]cyclohexane-1,3-dione. It is a post-emergence herbicide used (particularly in conjunction with the herbicide safener cyprosulfamide) for the control of a wide range of broad-leaved and grassy weeds in corn and other crops. It has a role as a herbicide, an agrochemical, an EC 1.13.11.27 (4-hydroxyphenylpyruvate dioxygenase) inhibitor and a carotenoid biosynthesis inhibitor. It is a sulfone, a cyclic ketone, an aromatic ketone, a member of monochlorobenzenes, an organofluorine compound, an ether and a beta-triketone. It acts by inhibiting 4-hydroxyphenylpyruvate dioxygenase (HPPD), which leads to chlorophyll destruction by photooxidation and causes bleaching of emerging foliar tissue. In mammals, HPPD is a key enzyme in the catabolism of tyrosine. It catalyzes the conversion of 4-hydroxyphenylpyruvate (HPP) to homogentisate. Inhibition of HPPD leads to a reconversion of HPP to tyrosine and a consequent increase in blood tyrosine concentrations (tyrosinemia).

Inhibition of dihydroorotate dehydrogenase (DHODH):
Tetflupyrolimet is a new aryl pyrrolidinone anilide chemical class) for grass control in rice. The target site is dihydroorotate dehydrogenase, a key enzyme in pyrimidine biosynthesis It ha IUPAC name as (3S, 4S)-2'-fluoro-1-methyl-2-oxo-4-[3-(trifluoromethyl) phenyl]pyrrolidine-3-carboxanilide. It effectively control economically important monocotyledonous and dicotyledonous weeds while safe to wheat, corn and rice.
VLCAFE inhibitors:
Dimesulfazet is a sulfonanilide herbicide having IUPAC name as 2'-[(3,3-dimethyl-2-oxoazetidin-1-yl)methyl]-1,1,1-trifluoromethanesulfonanilide. It belongs to which belongs to trifluoro methansulfonanilides, is presumed to be a VLCFAE inhibitor, since trifluoromethansulfonanilides such as mefluidide and perfluidone have been reported to inhibit a very-long-chain fatty acid (VLCFA) synthesis.
Herbicide with unknown mode of action:
Bromobutide is a monocarboxylic acid amide having a 2-phenylpropan-2-yl substituent attached to the amide nitrogen and a 1-bromo-2,2-dimethylpropyl group attached to the carbonyl carbon. It has a role as a herbicide. It is a monocarboxylic acid amide and an organobromine compound. It has a IUPAC name as 2-bromo-3,3-dimethyl-N-(2-phenylpropan-2-yl)butanamide.
The present inventors believe that the combination of the present invention surprisingly results in a synergistic action. The combination of the present invention allows for a broad spectrum of weed control and hence has surprisingly improved plant vigour and yield. The broad spectrum of the present combination of controlling weeds that also provides a solution for in resistance management, thus preventing the weed from becoming resistant to either of the herbicides while providing a broader spectrum of control at lower use rates.
The synergistic composition has very advantageous curative, preventive herbicidal properties for protecting cultivated plants. As has been mentioned, said active ingredient composition can be used to inhibit or destroy and effective management of the controlling pre-emergence and post-emergence weeds. The synergistic composition comprising herbicidal compounds for management and control of broad-leaved weeds and grasses in crops of useful plants.
The present synergistic herbicidal composition further comprises of plant health additives play very crucial role in protection of plant or crops of interest. The plant health additives in present composition reduces the phytotoxicity of herbicides and promotes speedy recovery of the crop or plant from herbicidal injury. Thus accordingly reduces the stress due to abiotic factors and thus promotes overall plant or crop health and there by plant or crop yield.
Therefor the aspect of the present invention provides the herbicidal compositions comprising bioactive amounts of (A) a herbicide selected from Acetyl CoA Carboxylase (ACCase) Inhibitor for control of grasses or mixture thereof; (B) a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grasses in crops of useful plants or mixture thereof; and (C) a plant health additive(s) for reducing phytotoxicity in crops on post herbicide application or mixture thereof; are present in most preferred composition as below:
Compound A Acetyl CoA Carboxylase (ACCase) Inhibitor Compound B Compound C Plant health additives

Clodinafop Propargyl Chlorimuron ethyl Fulvic acid
Clodinafop Propargyl Sulfosulfuron Amino acid
Clodinafop Propargyl Diclosulam Seaweed extract
Clodinafop Propargyl Imazethapyr Brassinolide
Clodinafop Propargyl Imazamox Silicic acid
Clodinafop Propargyl Halauxifen methyl Nitrobenzene
Clodinafop Propargyl Metribuzin Gibberellic acid
Clodinafop Propargyl Bentazone Triacontanol
Clodinafop Propargyl Clomazone Fulvic acid
Clodinafop Propargyl Acifluorfen Amino acid
Clodinafop Propargyl Fomesafen Seaweed extract
Clodinafop Propargyl Lactofen Brassinolide
Clodinafop Propargyl Carfentrazone ethyl Silicic acid
Clodinafop Propargyl Sulfentrazone Nitrobenzene
Clodinafop Propargyl Saflufenacil Gibberellic acid
Clodinafop Propargyl Fluthiacet methyl Triacontanol
Clodinafop Propargyl Tiafenacil Fulvic acid
Clodinafop Propargyl Cyclopyranil Amino acid
Clodinafop Propargyl Tolpyralate Seaweed extract
Clodinafop Propargyl Mesotrione Brassinolide
Clodinafop Propargyl Tembotrione Silicic acid
Clodinafop Propargyl Tetflupyrolimet Gibberellic acid
Clodinafop Propargyl Cyclopyrimorate Triacontanol
Clodinafop Propargyl Pyroxasulfone Fulvic acid
Clodinafop Propargyl Ipfencarbazone Amino acid
Clodinafop Propargyl Dimesulfazet Seaweed extract
Clodinafop Propargyl Fenoxasulfone Brassinolide
Clodinafop Propargyl Epyrifenacil Silicic acid
Clodinafop Propargyl Bixzolone Nitrobenzene
Clodinafop Propargyl Glyphosate Gibberellic acid
Clodinafop Propargyl Glufosinate Triacontanol
Quizalofop-P-Ethyl Chlorimuron ethyl Fulvic acid
Quizalofop-P-Ethyl Sulfosulfuron Amino acid
Quizalofop-P-Ethyl Diclosulam Seaweed extract
Quizalofop-P-Ethyl Imazethapyr Brassinolide
Quizalofop-P-Ethyl Imazamox Silicic acid
Quizalofop-P-Ethyl Halauxifen methyl Nitrobenzene
Quizalofop-P-Ethyl Bentazone Gibberellic acid
Quizalofop-P-Ethyl Clomazone Triacontanol
Quizalofop-P-Ethyl Acifluorfen Fulvic acid
Quizalofop-P-Ethyl Fomesafen Amino acid
Quizalofop-P-Ethyl Lactofen Seaweed extract
Quizalofop-P-Ethyl Carfentrazone ethyl Brassinolide
Quizalofop-P-Ethyl Sulfentrazone Silicic acid
Quizalofop-P-Ethyl Saflufenacil Nitrobenzene
Quizalofop-P-Ethyl Fluthiacet methyl Gibberellic acid
Quizalofop-P-Ethyl Tiafenacil Triacontanol
Quizalofop-P-Ethyl Cyclopyranil Fulvic acid
Quizalofop-P-Ethyl Cyclopyrimorate Amino acid
Quizalofop-P-Ethyl Pyroxasulfone Seaweed extract
Quizalofop-P-Ethyl Epyrifenacil Brassinolide
Propaquizafop Chlorimuron ethyl Silicic acid
Propaquizafop Diclosulam Nitrobenzene
Propaquizafop Imazethapyr Gibberellic acid
Propaquizafop Imazamox Triacontanol
Propaquizafop Halauxifen methyl Fulvic acid
Propaquizafop Bentazone Amino acid
Propaquizafop Clomazone Seaweed extract
Propaquizafop Acifluorfen Brassinolide
Propaquizafop Fomesafen Silicic acid
Propaquizafop Lactofen Nitrobenzene
Propaquizafop Carfentrazone ethyl Gibberellic acid
Propaquizafop Sulfentrazone Triacontanol
Propaquizafop Fluthiacet methyl Fulvic acid
Propaquizafop Tiafenacil Amino acid
Propaquizafop Cyclopyranil Seaweed extract
Propaquizafop Tolpyralate Brassinolide
Propaquizafop Tetflupyrolimet Silicic acid
Propaquizafop Cyclopyrimorate Nitrobenzene
Propaquizafop Pyroxasulfone Gibberellic acid
Metamifop Chlorimuron ethyl Triacontanol
Metamifop Pyrazosulfuron ethyl Fulvic acid
Metamifop Sulfosulfuron Amino acid
Metamifop Bispyribac sodium Seaweed extract
Metamifop Pyribenzoxim Brassinolide
Metamifop Penoxsulam Silicic acid
Metamifop Triafamone Nitrobenzene
Metamifop Halauxifen methyl Triacontanol
Metamifop Bentazone Fulvic acid
Metamifop Clomazone Amino acid
Metamifop Acifluorfen Seaweed extract
Metamifop Fomesafen Brassinolide
Metamifop Lactofen Silicic acid
Metamifop Carfentrazone ethyl Nitrobenzene
Metamifop Sulfentrazone Gibberellic acid
Metamifop Saflufenacil Triacontanol
Metamifop Tetflupyrolimet Fulvic acid
Metamifop Cyclopyrimorate Amino acid
Metamifop Pyroxasulfone Seaweed extract
Metamifop Ipfencarbazone Brassinolide
Metamifop Fenoxasulfone Silicic acid
Cyhalofop butyl Chlorimuron ethyl Nitrobenzene
Cyhalofop butyl Pyrazosulfuron ethyl Gibberellic acid
Cyhalofop butyl Sulfosulfuron Triacontanol
Cyhalofop butyl Bispyribac sodium Fulvic acid
Cyhalofop butyl Pyribenzoxim Amino acid
Cyhalofop butyl Penoxsulam Seaweed extract
Cyhalofop butyl Triafamone Brassinolide
Cyhalofop butyl Halauxifen methyl Nitrobenzene
Cyhalofop butyl Bentazone Gibberellic acid
Cyhalofop butyl Clomazone Triacontanol
Cyhalofop butyl Acifluorfen Fulvic acid
Cyhalofop butyl Fomesafen Amino acid
Cyhalofop butyl Lactofen Seaweed extract
Cyhalofop butyl Carfentrazone ethyl Brassinolide
Cyhalofop butyl Sulfentrazone Silicic acid
Cyhalofop butyl Saflufenacil Nitrobenzene
Cyhalofop butyl Tetflupyrolimet Gibberellic acid
Cyhalofop butyl Cyclopyrimorate Triacontanol
Cyhalofop butyl Pyroxasulfone Triacontanol
Cyhalofop butyl Ipfencarbazone Triacontanol
Cyhalofop butyl Fenoxasulfone Triacontanol
Clodinafop Propargyl Metribuzin+Pyroxasulfone Gibberellic acid
Clodinafop Propargyl Propaquizafop+Fomesafen Gibberellic acid
Clodinafop Propargyl Quizalofop-P-Ethyl+Acifluorfen Gibberellic acid
Metamifop Bispyribac sodium+Bentazon Gibberellic acid
Metamifop Bispyribac sodium+Carfentrazone ethyl Gibberellic acid
Metamifop Pyrazosulfuron ethyl+Carfentrazone ethyl Gibberellic acid
Cyhalofop butyl Bispyribac sodium+Bentazon Gibberellic acid
Cyhalofop butyl Bispyribac sodium+Carfentrazone ethyl Gibberellic acid
Cyhalofop butyl Pyrazosulfuron ethyl+Carfentrazone ethyl Gibberellic acid
Clodinafop Propargyl Metribuzin+Pyroxasulfone Triacontanol
Clodinafop Propargyl Propaquizafop+Fomesafen Triacontanol
Clodinafop Propargyl Quizalofop-P-Ethyl+Acifluorfen Triacontanol
Metamifop Bispyribac sodium+Bentazon Triacontanol
Metamifop Bispyribac sodium+Carfentrazone ethyl Triacontanol
Metamifop Pyrazosulfuron ethyl+Carfentrazone ethyl Triacontanol
Cyhalofop butyl Bispyribac sodium+Bentazon Triacontanol
Cyhalofop butyl Bispyribac sodium+Carfentrazone ethyl Triacontanol
Cyhalofop butyl Pyrazosulfuron ethyl+Carfentrazone ethyl Triacontanol
Clodinafop Propargyl Metribuzin+Pyroxasulfone Silicic acid
Clodinafop Propargyl Propaquizafop+Fomesafen Silicic acid
Clodinafop Propargyl Quizalofop-P-Ethyl+Acifluorfen Silicic acid
Metamifop Bispyribac sodium+Bentazon Silicic acid
Metamifop Bispyribac sodium+Carfentrazone ethyl Silicic acid
Metamifop Pyrazosulfuron ethyl+Carfentrazone ethyl Silicic acid
Cyhalofop butyl Bispyribac sodium+Bentazon Silicic acid
Cyhalofop butyl Bispyribac sodium+Carfentrazone ethyl Silicic acid
Cyhalofop butyl Pyrazosulfuron ethyl+Carfentrazone ethyl Silicic acid
Clodinafop Propargyl Metribuzin+Pyroxasulfone Fulvic acid
Clodinafop Propargyl Propaquizafop+Fomesafen Fulvic acid
Clodinafop Propargyl Quizalofop-P-Ethyl+Acifluorfen Fulvic acid
Metamifop Bispyribac sodium+Bentazon Fulvic acid
Metamifop Bispyribac sodium+Carfentrazone ethyl Fulvic acid
Metamifop Pyrazosulfuron ethyl+Carfentrazone ethyl Fulvic acid
Cyhalofop butyl Bispyribac sodium+Bentazon Fulvic acid
Cyhalofop butyl Bispyribac sodium+Carfentrazone ethyl Fulvic acid
Cyhalofop butyl Pyrazosulfuron ethyl+Carfentrazone ethyl Fulvic acid
Clodinafop Propargyl Metribuzin+Pyroxasulfone Gibberellic acid
Clodinafop Propargyl Propaquizafop+Fomesafen Gibberellic acid
Clodinafop Propargyl Quizalofop-P-Ethyl+Acifluorfen Gibberellic acid
Metamifop Bispyribac sodium+Bentazon Gibberellic acid
Metamifop Bispyribac sodium+Carfentrazone ethyl Gibberellic acid
Metamifop Pyrazosulfuron ethyl+Carfentrazone ethyl Gibberellic acid
Cyhalofop butyl Bispyribac sodium+Bentazon Gibberellic acid
Cyhalofop butyl Bispyribac sodium+Carfentrazone ethyl Gibberellic acid
Cyhalofop butyl Pyrazosulfuron ethyl+Carfentrazone ethyl Gibberellic acid
Clodinafop Propargyl Metribuzin+Pyroxasulfone Gibberellic acid
Clodinafop Propargyl Propaquizafop+Fomesafen Gibberellic acid
Clodinafop Propargyl Quizalofop-P-Ethyl+Acifluorfen Gibberellic acid
Metamifop Bispyribac sodium+Bentazon Gibberellic acid
Metamifop Bispyribac sodium+Carfentrazone ethyl Gibberellic acid
Metamifop Pyrazosulfuron ethyl+Carfentrazone ethyl Gibberellic acid
Cyhalofop butyl Bispyribac sodium+Bentazon Gibberellic acid
Cyhalofop butyl Bispyribac sodium+Carfentrazone ethyl Gibberellic acid
Cyhalofop butyl Pyrazosulfuron ethyl+Carfentrazone ethyl Gibberellic acid
Clodinafop Propargyl Metribuzin+Pyroxasulfone Fulvic acid
Clodinafop Propargyl Propaquizafop+Fomesafen Fulvic acid
Clodinafop Propargyl Quizalofop-P-Ethyl+Acifluorfen Fulvic acid
Metamifop Bispyribac sodium+Bentazon Fulvic acid
Metamifop Bispyribac sodium+Carfentrazone ethyl Fulvic acid
Metamifop Pyrazosulfuron ethyl+Carfentrazone ethyl Fulvic acid
Cyhalofop butyl Bispyribac sodium+Bentazon Fulvic acid
Cyhalofop butyl Bispyribac sodium+Carfentrazone ethyl Fulvic acid
Cyhalofop butyl Pyrazosulfuron ethyl+Carfentrazone ethyl Fulvic acid
Clodinafop Propargyl Metribuzin+Pyroxasulfone Fulvic acid
Clodinafop Propargyl Propaquizafop+Fomesafen Fulvic acid
Clodinafop Propargyl Quizalofop-P-Ethyl+Acifluorfen Fulvic acid
Metamifop Bispyribac sodium+Bentazon Fulvic acid
Metamifop Bispyribac sodium+Carfentrazone ethyl Fulvic acid
Metamifop Pyrazosulfuron ethyl+Carfentrazone ethyl Fulvic acid
Cyhalofop butyl Bispyribac sodium+Bentazon Fulvic acid
Cyhalofop butyl Bispyribac sodium+Carfentrazone ethyl Fulvic acid
Cyhalofop butyl Pyrazosulfuron ethyl+Carfentrazone ethyl Fulvic acid
Metamifop Bispyribac sodium+Bentazon Zinc
Metamifop Bispyribac sodium+Carfentrazone ethyl Zinc
Metamifop Pyrazosulfuron ethyl+Carfentrazone ethyl Zinc
Cyhalofop butyl Bispyribac sodium+Bentazon Zinc
Cyhalofop butyl Bispyribac sodium+Carfentrazone ethyl Zinc
Cyhalofop butyl Pyrazosulfuron ethyl+Carfentrazone ethyl Zinc
Metamifop Bispyribac sodium+Bentazon Zinc
Metamifop Bispyribac sodium+Carfentrazone ethyl Zinc
Metamifop Pyrazosulfuron ethyl+Carfentrazone ethyl Zinc
Cyhalofop butyl Bispyribac sodium+Bentazon Zinc
Cyhalofop butyl Bispyribac sodium+Carfentrazone ethyl Zinc
Cyhalofop butyl Pyrazosulfuron ethyl+Carfentrazone ethyl Zinc
The herbicidal herbicidal combination of the present invention maybe used to control the target weeds among the crops such as GMO (Genetically Modified Organism) and Non GMO varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticum aestavum), Barley (Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Oat (Avena sativa), Pearl millet (Pennisetum glaucum), Sugarcane (Saccharum officinarum), Sugarbeet (Beta vulgaris), Soybean (Glycin max), Peanut (Arachis hypogaea), Sunflower (Helianthus annuus) , Mustard (Brassica juncea), Rape seed (Brassica napus), Linseed (Linum usitatissimum), Sesame (Sesamum indicum), Green gram (Vigna radiata), Black gram (Vigna mungo), Chickpea (Cicer aritinum), Cowpea (Vigna unguiculata), Redgram (Cajanus cajan), Frenchbean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotyloma uniflorum), Field pea (Pisum sativum), Cluster bean (Cyamopsis tetragonoloba), Lentils (Lens culinaris), Brinjal (Solanum melongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschus esculentus) , Onion (Allium cepa L.), Tomato (Solanum lycopersicun) , Potato (Solanum tuberosum) , Sweet potato (Ipomoea batatas), Chilly (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumis sativus), Muskmelons (Cucumis melo), Watermelon (Citrullus lanatus), Bottle gourd (Lagenaria siceraria), Bitter gourd (Momordica charantia), Radish (Raphanus sativus), Carrot (Dacus carota subsp. sativus), Turnip (Brassica rapa subsp rapa), Apple (Melus domestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitis vinifera), Guava (Psidium guajava), Litchi (Litchi chinensis), Mango (Mangifera indica), Papaya (Carica papaya), Pineapple (Ananas comosus), Pomegranate (Punica granatum) , Sapota (Manilkara zapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiber officinale), Cumin (Cuminum cyminum), Fenugreek (Trigonella foenum-graecum), Fennel (Foeniculum vulgare), Coriander (Coriandrum sativum), Ajwain (Trachyspermum ammi), Psyllium (Plantago ovate), Black Pepper (Piper nigrum), Stevia (Stevia rebaudiana), Safed musli (Chlorophytum tuberosum), Drum stick (Moringa oleifera), Coconut (Coco nucifera), Mentha ( Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold (Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera (Gerbera jamesonii), Carnation (Dianthus caryophyllus).
The present invention of synergistic herbicidal combinations can be also used to control unwanted vegetation in plantation crops, orchards, fallow lands, water bodies, field bunds etc.
A herbicidal synergistic composition of present invention controls all kind of monocots, dicots and sedges weeds. The present synergistic herbicidal combinations also controls annual and perennial weeds. The most common weeds controlled by present inventions are Abutilon indicum, Acalypha indica, Acanthospermum hispidum, Achyranthes aspera, Aerva tomentosa, Ageratum conyzoides, Alhagi camelorum, Amaranthus hybridus, Amaranthus spinosus, Amaranthus viridis, Ammannia baccifera, Anagallis arvensis, Argemone mexicana, Artemisia nilagiricia, Asphodelus tenuifolius, Avena fatua, Avena ludoviciana, Bidens pilosa, Boerhaavia diffusa, Boerhavia repanda, Brachiaria mutica, Brassica kaber, Bromus tectorum, Calotropis gigantea, Cannabis sativa, Carthamus axyacantha, Cassia tora, Celosia argentea, Centella asiatica, Chenopodium album, Chenopodium murale, Chloris barbata, Chrozophora rottlerii, Cichorium intybus, Cirsium arvense, Clitoria ternatea, Cnicus arvensis, Commelina benghalensis, Commelina communis, Convolvulus arvensis, Conyza canadensis, Corchorus acutangulus, Coronopus didymus, Crotalaria serice, Cucumis callosus, Cuscuta campestris, Cuscuta chinensis, Cynodon dactylon, Cyanotis axillaris, Cyperus esculenthus, Cyperus iria, Cyperus rotundus, Dactyloctenium aegyptium, Datura stramonium, Daucus carota, Digera arvensis, Digitaria sanguinalis, Dinebra retroflexa, Echinochola colonum, Echinochola crusgalli, Eclipta alba, Eichhornia crassipes, Elephantopus scaber, Eleusine indica, Eragrostis major, Euphorbia geniculata, Euphorbia hirta, Fimbristylis miliacea, Fumaria indica, Gynandropsis gynandra, Heliotropium indicum, Indigofera glandulosa, Ipomea aquatica, Lantana camara, Lathyrus aphaca, Launaea asplenifolia, Launaea nudicaulis, Leucas aspera, Ludwigia parviflora, Marsilea quadrifoliata, Medicago denticulate, Mimosa pudica, Melilotus alba, Melilotus indica, Ocimum canum, Oenothera biennis, Opuntia dillenil, Orobanche ramosa, Oryza longistaminata, Oryza sativa, Oxalis corniculata, Oxalis latifolia, Parthenium hysterophorus, Paspalum sanguinale, Phalaris minor, Phyllanthus niruri, Physalis minima, Polypogon monspeliensis, Portulaca oleracea, Prosopis juliflora, Rumex dentatus, Saccharum spontaneum, Stearia glauca, Seteria viridis, Sida spinosa, Silene antirrhina, Sisymbrium irio, Solanum nigrum, Solanum surattense, Sonchus oleraceous, Sorghum halepense, Spergula arvensis, Sphenocleazeylanica Gaertn, Striga asiatica, Tagetes minuta, Trianthema monogyna, Trianthema portulacastrum, Tribulus terrestris, Trigonelia polycerata, Vernonia cinerea, Vicia sativa and Xanthium strumarium.
Formulation of the present invention can be in any of the formulations selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR).

Further formulation for the present synergistic agrochemical composition comprises ‘crop safener’ for use especially in monocotyledonous crops (wheat, paddy/rice, corn/maize, sugarcane, sorghum, pearlmillet).
In an embodiment of the present invention any one of the crop safener for the monocotyledonous crops is selected from the cyprosulfamide, dietholate, isoxadifen / isoxadifen ethyl, dicyclonon, benoxacor, mefenpyr ethyl, fenchlorazole ethyl, cloquintocet / cloquintocet mexyl, oxabetrinil, naphthalic anhydride, mephenate, mefenpyr, furilazole, fluxofenim, flurazole, fenclorim, fenchlorazole, dichlormid, cyometrinil.
One or more of the active ingredients is encapsulated for various purposes, such as to increase the residual biological activity, or to reduce the acute toxicity, or to obtain a physical or chemically stable water-based formulation. The purpose determines whether the “free” active ingredient and the “release rate” are relevant properties of a specific product.
Further herbicidal composition comprising (A) a herbicide selected from Acetyl CoA Carboxylase (ACCase) Inhibitor for control of grasses or mixture thereof; (B) a one or more herbicide(s) selected from the group of various class of compounds for control of broad-leaved weeds and grasses in crops of useful plants or mixture thereof; and (C) a plant health additive(s) for reducing phytotoxicity in crops on post herbicide application or mixture thereof are present in the said composition in specific fixed ratio.
In further aspect the present invention relates to the synergistic herbicidal composition comprising bioactive amounts of (A) is 0.1 to 60% w/w of the composition; (B) is 0.1 to 60% w/w of the composition; and (C) is 0.1 to 30% w/w of the composition.
Active Ingredients Compound A Compound
B Compound
C
Examples Acetyl CoA Carboxylase (ACCase) Inhibitor One or more herbicide(s) Plant health additives
% of Active Ingredient (w/w, w/v)
0.1 to 60%
0.1 to 60%
0.1 to 30%
The composition of the present invention in addition to bioactive amounts of active ingredients further comprises inactive excipients including but not limited to dispersant, anti-freezing agent, anti-foam agent, wetting agent, suspension aid, antimicrobial agent, thickener, quick coating agent or sticking agents (also referred to as “stickers” or “binders”) and buffering agent.
A dispersant is a substance which adsorbs onto the surface of particles and helps to preserve the state of dispersion of the particles and prevents them from re-aggregating. Dispersants are added to agrochemical formulations to facilitate dispersion and suspension during manufacture, and to ensure the particles re-disperse into water in a spray tank. Examples include but are not limited to polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylic polymers and copolymers, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol, vinylacetate and vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins and define copolymers and mixtures thereof. Examples of preferred polymers are acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these. Polymers that are biodegradable are also useful in the present invention. As used herein, a polymer is biodegradable if is not water soluble, but is degraded over a period of several weeks when placed in an application environment. Examples of biodegradable polymers that are useful in the present invention include biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof. The examples of dispersing agents are Polyarylphenyl ether sulphate ammonium salt, alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium salt of alkyl naphthalene sulfonate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Anti-freezing agent as used herein can be selected from the group consisting of ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride etc.
Water-based formulations often cause foam during mixing operations in production. In order to reduce the tendency to foam, anti-foam agents are often added either during the production stage or before filling into bottles. Examples of antifoam agent used herein include but not limited to, silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethylsiloxane, polydimethylsiloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane etc.
A wetting agent is a substance that when added to a liquid increases the spreading or penetration power of the liquid by reducing the interfacial tension between the liquid and the surface on which it is spreading. Examples of Wetting-spreading-penetrating agent used herein Suspo Emulsion (SE) formulation include but not limited to Organosilicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, heptamethyl trisiloxane ethoxylate, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof etc.
Examples of Stabilizers used herein include but are not limited to butylated hydroxytoluene (BHT) and epoxidized soybean oil (ESBO), Epichlorhydrin.
Suspension aid in the present description denotes a natural or synthetic, organic or inorganic material with which the active substance is combined in order to facilitate its application to the plant, to the seeds or to the soil. This carrier is hence generally inert, and it must be agriculturally acceptable, in particular to the plant being applied to. The carrier may be solid (clays, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, and the like or mixtures thereof) or liquid (water, alcohols, ketones, petroleum fractions, aromatic or paraffinic hydrocarbons, chlorinated hydrocarbons, liquefied gases, and the like or mixtures thereof). Examples of suspending agents used herein include but are not limited to aluminum magnesium silicate, bentonite clay, silica, silicone dioxide, attapulgite clay.
Biocides / Microorganisms cause spoilage of formulated products. Therefore antimicrobial agents are used to eliminate or reduce their effect. Examples of such agents include, but are not limited to: 2-bromo-2-nitropropane-1,3-diol, propionic acid and its sodium salt; sorbic acid and its sodium or potassium salts; benzoic acid and its sodium salt; p-hydroxy benzoic acid sodium salt; methyl p-hydroxy benzoate; and biocide such as sodium benzoate, 1,2- benzisothiazoline-3-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4- isothiazolin-3-one, potassium sorbate, para hydroxy benzoates or mixtures thereof.
Thickeners or gelling agents are used mainly in the formulation of suspension concentrates, emulsions and suspoemulsions to modify the rheology or flow properties of the liquid and to prevent separation and settling of the dispersed particles or droplets. Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers. It is possible to produce suspension concentrate formulations using clays and silicas. Examples of these types of materials, include, but are limited to, montmorillonite, e.g. bentonite; magnesium aluminum silicate; and attapulgite. Water-soluble polysaccharides have been used as thickening-gelling agents for many years. The types of polysaccharides most commonly used are natural extracts of seeds and seaweeds are synthetic derivatives of cellulose or mixtures thereof. Examples of these types of materials include, but are not limited to, guar gum; locust bean gum; carrageenam; xanthan gum; alginates; methyl cellulose; sodium carboxymethyl cellulose (SCMC); hydroxyethyl cellulose (HEC) or mixtures thereof. Other types of anti-settling agents are based on modified starches, polyacrylates, polyvinyl alcohol and polyethylene oxide or mixtures.
Buffering agent as used herein is selected from group consisting of calcium hydroxyapatite, Potassium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.
The solvent for the formulation of the present invention may include octyl phenol Ethoxylate, Solvent-C-9, water, water soluble alcohols and dihydroxy alcohol ethers. Water soluble alcohol or lower alcohol (1-4 carbon atoms) includes-methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol. Macromolecular alcohol includes polyethylene glycol, sorbitol, glucitol etc., dihydroxy alcohol ethers includes dihydroxy alcohol alkyl ether or dihydroxy alcohol aryl ethers. The examples of dihydroxy alcohol alkyl ether include ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether, etc. The examples of dihydroxy alcohol aryl ethers include ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl ether, and the like. Any of the mentioned solvent can be used either alone or in combinations thereof. Paraffinic hydrocarbons, cyclohexanone, isophorone and ester solvents such as methyloleate, dimethylamide and morpholineamide derivatives of C6-C16 fatty acids, and mono-alkylene carbonates such as ethylene carbonate, propylene carbonate and butylene carbonates, dimethylsulfoxide (DMSO), 2-ethylhexanol and n-butanol, n-alkylpyrrolidones, fatty acid dimethyl esters, fatty acid esters, dibasic esters, aromatic hydrocarbons and/or aliphatic hydrocarbons, one or more dimethylamides, such as C8-dimethylamide, C10-dimethylamide, C12-dimethylamide, ethylene glycol, propylene glycol, polyalkylene glycols, methylpyrrolidinone (NMP); dimethylformamide (DMF); dimethylisosorbide (DMI); isophorone; acetophenone; 1,3-dimethyl-2-imidazolidonone; lactate esters; dimethyl and diethylcarbonates; Methyl L-lactate, 2-Ethylhexyl L-lactate, Ethyl L-lactate, n-Butyl L-lactate.
Examples of emulsifiers used herein include but not limited to blend of Polyaryl phenol ethoxylate and calcium dodecyl benzene sulfonate, N-Methyl-2-pyrrolidone, salts of dodecylbenzene sulphonate, e.g. Ca-salts or amine salts, and sulphonates of other C11-C16 alkylbenzenes, alkylether sulphates, alkylphenoletherphosphates and ester phosphates; non-ionic surfactants such as alkoxylated alcohols and alkylphenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid esters, e.g. of sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; and catanionic emulsifiers such as a cationic amine, optionally in combination with an alkylsulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkylphenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol; fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkylbenzenes in the range C11-C16 and salts thereof; alkylether sulphates; alkyletherphosphates; alkylphenoletherphosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenol; or a catanionic system, wherein a cationic amine is present in combination with an alkylsulphonate, an alkylethersulphonate, an ether sulphate, or an ether phosphate such as an alkyletherphosphate, nonylphenol polyethoxy ethanols, castor oil polyglycol ethers, polyadducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol.
The process for preparing the present novel synergistic composition can be modified accordingly by any person skilled in the art based on the knowledge of the manufacturing the formulation. However all such variation and modification is still covered by the scope of present invention.
These and other aspects of the invention may become more apparent from the examples set forth herein below. These examples are provided merely as illustrations of the invention and are not intended to be construed as a limitation thereof.
EXAMPLE 1:
SE (Suspo emulsion) formulation of Metamifop 7.5%+Triafamone 2%+Fulvic acid 2%
Chemical composition % (w/w)
Metamifop a.i. Active ingredient 7.50
Triafamone a.i. Active ingredient 2.00
Fulvic acid a.i. Active ingredient 2.00
Octyl phenol Ethoxylate Solvent 10.00
Trisiloxane ethoxylate Wetting-spreading-penetrating agent 5.00
Tristyrylphenol-polyglycolether-phosphate Dispersing agent 1 4.50
Polyarylphenyl ether sulphate ammonium salt Dispersing agent 2 1.00
Bentonite clay Suspending agent 2.00
Polydiemthylsiloxane Antifoaming agent 0.30
2-bromo-2-nitropropane-1,3-diol Preservative 0.20
Polypropylene glycol Antifreezing agent 5.00
Xanthan gum Thickner 0.15
Water Diluent Water 60.35
Total 100.00

Storage stability-
Metamifop 7.5%+Triafamone 2%+Fulvic acid 2% SE
Storage stability study in laboratory (at 54±2 C & At 0±2 C temp. for 14 days) and at room temperature (for 12 months) shows that Metamifop 7.5%+Triafamone 2%+Fulvic acid 2% SE formulation complies all the in-house parameters like active ingredients content, suspensibility, pH range, pourability, specific gravity, viscosity, particle size and anti-foaming.
Procedure: Manufacturing process of SE (Suspo emulsion) formulation
Preparation of Suspo Emulsion (SE) formulation:
Step 1 2% Gel Preparation: Charge the required quantity of water to a vessel, equipped with a high shear stirrer and start the agitation. Add the required amount of preservative. Mix until homogenous. Add the required amount of thickener and mix vigorously until it is fully wetted.
Step 2 Oil Phase: Charge solvent into the vessel and then add active technical slowly and if required, heat it for 500C so that technical can be dissolved in solvent and then add emulsifier.
Step 3 Charge the required quantity of water to a vessel, equipped with bulk agitator and a high shear homogenizer and start agitation. Add the required amount of ant freezing agent and mix until uniform. Add the antifoaming agent and ensure that it is well dispersed. Add the wetting and dispersing agent and mix until uniform. Ensure that the dispersing agent is fully dispersed.
Step 4 Now add the active ingredient and continue agitating the vessel contents until all components get dissolved. Mill this pre-mix through a Colloid mill and subsequently through a Dyno mill to meet the specified particle size.
Step 5 Now add remaining antifoaming agent to this mill base to a vessel, equipped with bulk agitator. Mix until uniform.
Step 6 Now add oil phase in aqueous phase and stir for 30 minutes using homogenizer.
Step 7 Add the required amount of 2% aqueous pre-gel and also suspending agent and continue agitation until the formulation is homogeneous and has the target viscosity. Mix well.
Step 8 Final product is sent for QC approval.
Step 9 After approval, material is packed in required pack sizes.

EXAMPLE 2:
SE (Suspo emulsion) formulation of Cyhalofop butyl 6%+Tefuryltrione 4%+Gibberellic acid 0.2%
Chemical composition % (w/w)
Cyhalofop butyl a.i. Active ingredient 6.00
Tefuryltrione a.i. Active ingredient 4.00
Gibberellic acid a.i. Active ingredient 0.20
Octyl phenol Ethoxylate Solvent 10.00
Trisiloxane ethoxylate Wetting-spreading-penetrating agent 4.00
Tristyrylphenol-polyglycolether-phosphate Dispersing agent 1 4.50
Polyarylphenyl ether sulphate ammonium salt Dispersing agent 2 1.00
Bentonite clay Suspending agent 2.00
Polydiemthylsiloxane Antifoaming agent 0.30
2-bromo-2-nitropropane-1,3-diol Preservative 0.20
Polypropylene glycol Antifreezing agent 5.00
Xanthan gum Thickner 0.15
Water Diluent Water 62.65
Total 100.00

Storage stability-
Cyhalofop butyl 6%+Tefuryltrione 4%+Gibberellic acid 0.2% SE
Storage stability study in laboratory (at 54±2 C & At 0±2 C temp. for 14 days) and at room temperature (for 12 months) shows that Cyhalofop butyl 6%+Tefuryltrione 4%+Gibberellic acid 0.2% SE formulation complies all the in-house parameters like active ingredients content, suspensibility, pH range, pourability, specific gravity, viscosity, particle size and anti-foaming.

Procedure: Manufacturing process of SE (Suspo emulsion) formulation
The manufacturing process remains same as that in Example 1.
EXAMPLE 3:
EC (Emulsifiable Concentrate) Formulation of Haloxyfop R methyl 8%+Acifluorfen sodium 16.5%+Ortho silicic acid 0.5%
Chemical composition % (w/w)
Haloxyfop R methyl a.i. Active ingredient 8.00
Acifluorfen sodium salt a.i. Active ingredient 16.50
Ortho silicic acid a.i. Active ingredient 0.50
Blend of Polyaryl phenol ethoxylate and calcium dodecyl benzene sulfonate Emulsifying agent 1 8.00
N-Methyl-2-pyrrolidone Emulsifying agent 2 5.00
Solvent-C-9 Solvent 62.00
Total 100.00

Storage stability-
Haloxyfop R methyl 8%+Acifluorfen sodium 16.5%+Ortho silicic acid 0.5% EC
Storage stability study in laboratory (at 54±2 C & At 0±2 C temp. for 14 days) and at room temperature (for 12 months) shows that Haloxyfop R methyl 8%+Acifluorfen sodium 16.5%+Ortho silicic acid 0.5% EC formulation complies all the in-house parameters like active ingredients content, suspensibility, pH range, specific gravity, viscosity and particle size.

Procedure: Manufacturing process of EC (Emulsifiable Concentrate) formulation

Preparation of Emulsifiable Concentrate (EC) formulation
Step 1 Charge half quantity of solvent and then mix the technical into this solvent until completely soluble.
Step 2 Now add surfactants dose as per screening ration.
Step 3 Now add remaining solvent to this mixture.
Step 4 Final product is sent for QC approval.
Step 5 After approval material is packed in required pack sizes.

EXAMPLE 4:
List of preferred combinations:
Compound A Compound B Compound C Active ingredients (%) Formulation Strength (%) Formulation Type
A B C
Metamifop Triafamone Fulvic acid 7.5 2 2 11.50 SE
Metamifop Tefuryltrione Fulvic acid 7.5 4 2 13.50 SE
Metamifop Fenquinotrione Fulvic acid 7.5 10 2 19.50 SE
Metamifop Lancotrion sodium Fulvic acid 7.5 10 2 19.50 SE
Metamifop Cyclopyrimorate Fulvic acid 7.5 15 2 24.50 SE
Metamifop Tetflupyrolimet Fulvic acid 7.5 15 2 24.50 SE
Metamifop Bentazone Fulvic acid 3.75 30 1 34.75 SE
Metamifop Bispyribac sodium Fulvic acid 7.5 2 2 11.50 SE
Cyhalofop butyl Triafamone Gibberellic acid 6 2 0.2 8.20 SE
Cyhalofop butyl Tefuryltrione Gibberellic acid 6 4 0.2 10.20 SE
Cyhalofop butyl Fenquinotrione Gibberellic acid 6 10 0.2 16.20 SE
Cyhalofop butyl Lancotrion sodium Gibberellic acid 6 10 0.2 16.20 SE
Cyhalofop butyl Cyclopyrimorate Gibberellic acid 6 15 0.2 21.20 SE
Cyhalofop butyl Tetflupyrolimet Gibberellic acid 6 15 0.2 21.20 SE
Cyhalofop butyl Bentazone Gibberellic acid 3 30 0.1 33.10 SE
Haloxyfop R methyl Chlorimuron ethyl Ortho silicic acid 8 0.9 0.5 9.40 EC
Haloxyfop R methyl Imazethapyr Ortho silicic acid 8 7 0.5 15.50 EC
Haloxyfop R methyl Imazamox Ortho silicic acid 8 7 0.5 15.50 EC
Haloxyfop R methyl Acifluorfen sodium Ortho silicic acid 8 16.5 0.5 25.00 EC
Haloxyfop R methyl Fomesafen sodium Ortho silicic acid 8 18 0.5 26.50 EC
Haloxyfop R methyl Lactofen Ortho silicic acid 8 18 0.5 26.50 EC
Haloxyfop R methyl Fluthiacet methyl Ortho silicic acid 8 1.35 0.5 9.85 EC
Clodinafop Propargyl Chlorimuron ethyl Amino acid 8 0.9 2 10.90 EC
Clodinafop Propargyl Imazethapyr Amino acid 8 7 2 17.00 EC
Clodinafop Propargyl Imazamox Amino acid 8 7 2 17.00 EC
Clodinafop Propargyl Acifluorfen sodium Amino acid 8 16.5 2 26.50 EC
Clodinafop Propargyl Fomesafen sodium Amino acid 8 18 2 28.00 EC
Clodinafop Propargyl Lactofen Amino acid 8 18 2 28.00 EC
Clodinafop Propargyl Fluthiacet methyl Amino acid 8 1.35 2 11.35 EC

Biological Examples:
The field experiments were carried out to judge the impact of plant health additives on crop safety and yield when applied with herbicidal compositions (Acetyl CoA Carboxylase-ACCase Inhibitor + one or more herbicides) as inbuilt formulation and tank mixes.
Phytotoxicity: The observations on crop safety i.e. phytotoxicity or adverse effect of treatments were recorded on 7th and 14th DAA (days after application). All the visual phytotoxicity symptoms like plant yellowing, leaf scorching, bleaching, necrosis, stunting, crinkling, epinasty, hyponasty recorded by rating (0 to 10 score) the entire plot in comparison with untreated control (UTC) plot. Following rating were adopted. Score 0=No injury, Score 1=1 to 10%, Score 2=11 to 20%, Score 3=21 to 30%.......Score 10=91 to 100% Phytotoxicity.
Weed control: Species wise weed count recorded at 14 DAA (Days after Application) by using 0.25 m2 quadrant treatment wise in minimum 3 places randomly selected in the plot. The species wise weed count further grouped in to Grasses and Broad Leaf weeds (BLW) and sedges. The average of each variable was used together with the sum of all the variables per plot to calculate the percentage of control.
The % weed control data used in Colby’s formula to calculate the synergism.
A synergistic effect exists wherever the action of a combination of active ingredient is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticidal activity than the sum of the pesticidal activities of the individual components.

Example 1: Crop safety and weed control in paddy, Oryza sativa
The field experiment were conducted in paddy crop and the experimental details are as below:
Crops & Varieties: Paddy, Swarna
No. of Treatments: As per treatment details
Plot size: 24 sq. mt.
Application Time: 20 DATP (Days after transplanting)
Spray Volume: 350 liter water per hectare
Application Equipment: Manually operated knapsack sprayer fitted with flat fat nozzle
Agronomic practices: All the required agronomic practices followed except herbicidal application.
Table 1: Treatment details for crop safety study
Treatment number Treatment details Rate (gai/h)
T1 Metamifop 7.5%+Triafamone 2%+Fulvic acid 2% SE 75+20+20
T2 Metamifop 7.5%+Tefuryltrione 4%+Fulvic acid 2% SE 75+40+20
T3 Metamifop 7.5%+Fenquinotrione 10%+Fulvic acid 2% SE 75+100+20
T4 Metamifop 7.5%+Lancotrione sodium 10%+Fulvic acid 2% SE 75+100+20
T5 Metamifop 7.5%+Cyclopyrimorate 15%+Fulvic acid 2% SE 75+150+20
T6 Metamifop 7.5%+Tetflupyrolimet 15%+Fulvic acid 2% SE 75+150+20
T7 Metamifop 3.75%+Bentazone 30%+Fulvic acid 1% SE 75+600+20
T8 Metamifop 7.5%+Bispyribac sodium 2%+Fulvic acid 2% SE 75+20+20
T9 Metamifop 10% EC+Triafamone 40% WG 75+20
T10 Metamifop 10% EC+Tefuryltrione 20% SC 75+40
T11 Metamifop 10% EC+Fenquinotrione 20% SC 75+100
T12 Metamifop 10% EC+Lancotrione sodium 20% SC 75+100
T13 Metamifop 10% EC+Cyclopyrimorate 30% SC 75+150
T14 Metamifop 10% EC+Tetflupyrolimet 30% SC 75+150
T15 Metamifop 10% EC+Bentazone 48% SL 75+600
T16 Metamifop 10% EC+Bispyribac sodium 20% SC 75+20
T17 Untreated control (UTC) -

Table 2: Crop safety observations
Treatment number Phytotoxicity symptoms Number of productive tillers per hill % increase in productive tillers over
7 DAA 14 DAA
Leaf chlorosis (%) Stunting (%) Leaf chlorosis (%) Stunting (%)
T1 0.0 0.0 0.0 0.0 34.1 18.82 (over T9)
T2 5.0 0.0 0.0 0.0 35.5 21.16 (over T10)
T3 5.0 0.0 0.0 0.0 33.8 13.42 (over T11)
T4 0.0 0.0 0.0 0.0 34.3 13.95 (over T12)
T5 5.0 0.0 0.0 0.0 32.6 14.39 (over T13)
T6 5.0 0.0 0.0 0.0 33.7 17.01 (over T14)
T7 5.0 0.0 0.0 0.0 35.0 16.67 (over T15)
T8 0.0 0.0 0.0 0.0 33.3 12.12 (over T16)
T9 10.0 10.0 5.0 5.0 28.7 -
T10 20.0 10.0 10.0 5.0 29.3 -
T11 20.0 10.0 10.0 5.0 29.8 -
T12 15.0 10.0 5.0 5.0 30.1 -
T13 20.0 10.0 10.0 5.0 28.5 -
T14 15.0 10.0 5.0 5.0 28.8 -
T15 15.0 10.0 5.0 5.0 30.0 -
T16 10.0 10.0 5.0 5.0 29.7 -
T17 0.0 0.0 0.0 0.0 26.7 -

The addition of plant health additives i.e. fulvic acid in the formulation of Metamifop+Herbicide reduces the phytotoxicity symptoms i.e leaf chlorosis and plant stunting and also increases the number of productive tillers which are directly contributing to the grain yield.
Table 3: Treatment details for weed control
Treatment number Treatment details Rate (gai/h)
T1 Metamifop 7.5%+Triafamone 2%+Fulvic acid 2% SE 75+20+20
T2 Metamifop 7.5%+Tefuryltrione 4%+Fulvic acid 2% SE 75+40+20
T3 Metamifop 7.5%+Fenquinotrione 10%+Fulvic acid 2% SE 75+100+20
T4 Metamifop 7.5%+Lancotrione sodium 10%+Fulvic acid 2% SE 75+100+20
T5 Metamifop 7.5%+Cyclopyrimorate 15%+Fulvic acid 2% SE 75+150+20
T6 Metamifop 7.5%+Tetflupyrolimet 15%+Fulvic acid 2% SE 75+150+20
T7 Metamifop 3.75%+Bentazone 30%+Fulvic acid 1% SE 75+600+20
T8 Metamifop 7.5%+Bispyribac sodium 2%+Fulvic acid 2% SE 75+20+20
T9 Metamifop 10% EC+Fulvic acid 20% WP 75+20
T10 Triafamone 40% WG+Fulvic acid 20% WP 20+20
T11 Tefuryltrione 20% SC+Fulvic acid 20% WP 40+20
T12 Fenquinotrione 20% SC+Fulvic acid 20% WP 100+20
T13 Lancotrione sodium 20% SC+Fulvic acid 20% WP 100+20
T14 Cyclopyrimorate 30% SC+Fulvic acid 20% WP 150+20
T15 Tetflupyrolimet 30% SC+Fulvic acid 20% WP 150+20
T16 Bentazone 48% SL+Fulvic acid 20% WP 600+20
T17 Bispyribac sodium 20% SC+Fulvic acid 20% WP 20+20
T18 Untreated control (UTC) -

Table 4: Weed control observations
Treatment details Rate (gai/h) Weed control (%) on 14 DAA
Observed Value Calculated Value Colby's ratio Synergism (Y/N)
T1-Metamifop 7.5%+Triafamone 2%+Fulvic acid 2% SE 75+20+20 92.3 84.6 1.09 Y
T2-Metamifop 7.5%+Tefuryltrione 4%+Fulvic acid 2% SE 75+40+20 89.2 79.4 1.12 Y
T3-Metamifop 7.5%+Fenquinotrione 10%+Fulvic acid 2% SE 75+100+20 87.8 78.3 1.12 Y
T4-Metamifop 7.5%+Lancotrione sodium 10%+Fulvic acid 2% SE 75+100+20 90.7 78.7 1.15 Y
T5-Metamifop 7.5%+Cyclopyrimorate 15%+Fulvic acid 2% SE 75+150+20 91.2 81.7 1.12 Y
T6-Metamifop 7.5%+Tetflupyrolimet 15%+Fulvic acid 2% SE 75+150+20 91.2 80.8 1.13 Y
T7-Metamifop 3.75%+Bentazone 30%+Fulvic acid 1% SE 75+600+20 88.6 82.2 1.08 Y
T8-Metamifop 7.5%+Bispyribac sodium 2%+Fulvic acid 2% SE 75+20+20 87.2 83.1 1.05 Y
T9-Metamifop 10% EC+Fulvic acid 20% WP 75+20 61.2
T10-Triafamone 40% WG+Fulvic acid 20% WP 20+20 60.2
T11-Tefuryltrione 20% SC+Fulvic acid 20% WP 40+20 46.8
T12-Fenquinotrione 20% SC+Fulvic acid 20% WP 100+20 44.2
T13-Lancotrione sodium 20% SC+Fulvic acid 20% WP 100+20 45.2
T14-Cyclopyrimorate 30% SC+Fulvic acid 20% WP 150+20 52.8
T15-Tetflupyrolimet 30% SC+Fulvic acid 20% WP 150+20 50.6
T16-Bentazone 48% SL+Fulvic acid 20% WP 600+20 54.2
T17-Bispyribac sodium 20% SC+Fulvic acid 20% WP 20+20 56.4
T18-Untreated control (UTC) - 0.0

Weed flora composition in trial plot- Grassy weeds (Echinochloa spp., Leptochloa spp.) approx. 60% + Broad leaf weeds (Eclipta spp., Alternenthera spp., Monochoria spp.) approx. 30%, Sedges (Cyprus spp.) approx. 10%.

All the ready mix combination (T1 to T8) provides synergistic weed control on 14 DAA.
Example 2: Crop safety study in paddy/rice, Oryza sativa
Crops & Varieties: Paddy, Arize 6129
No. of Treatments: As per treatment details
Plot size: 30 sq. mt.
Application Time: 17 DATP (Days after transplanting)
Spray Volume: 340 liter water per hectare
Application Equipment: Manually operated knapsack sprayer fitted with flat fat nozzle
Agronomic practices: All the required agronomic practices followed except herbicidal application.
Table 5: Treatment details for crop safety and weed control
Treatment number Treatment details Rate (gai/h)
T1 Cyhalofop butyl 6%+Triafamone 2%+Gibberellic acid 0.2% SE 60+20+2
T2 Cyhalofop butyl 6%+Tefuryltrione 4%+Gibberellic acid 0.2% SE 60+40+2
T3 Cyhalofop butyl 6%+Fenquinotrione 10%+Gibberellic acid 0.2% SE 60+100+2
T4 Cyhalofop butyl 6%+Lancotrione sodium 10%+Gibberellic acid 0.2% SE 60+100+2
T5 Cyhalofop butyl 6%+Cyclopyrimorate 15%+Gibberellic acid 0.2% SE 60+150+2
T6 Cyhalofop butyl 6%+Tetflupyrolimet 15%+Gibberellic acid 0.2% SE 60+150+2
T7 Cyhalofop butyl 3%+Bentazone 30%+Gibberellic acid 0.1% SE 60+600+2
T8 Cyhalofop butyl 6%+Bispyribac sodium 2%+Gibberellic acid 0.2% SE 60+20+2
T9 Cyhalofop butyl 10% EC+Triafamone 40% WG 60+20
T10 Cyhalofop butyl 10% EC+Tefuryltrione 20% SC 60+40
T11 Cyhalofop butyl 10% EC+Fenquinotrione 20% SC 60+100
T12 Cyhalofop butyl 10% EC+Lancotrione sodium 20% SC 60+100
T13 Cyhalofop butyl 10% EC+Cyclopyrimorate 30% SC 60+150
T14 Cyhalofop butyl 10% EC+Tetflupyrolimet 30% SC 60+150
T15 Cyhalofop butyl 10% EC+Bentazone 48% SL 60+600
T16 Cyhalofop butyl 10% EC+Bispyribac sodium 20% SC 60+20
T17 Untreated control (UTC) -

Table 6: Phytotoxicity and weed control in paddy crop
Treatment number Phytotoxicity symptoms Number of productive tillers per hill increase(%) in productive tillers Weed control (%) on 14 DAA increase(%) in weed control over
7 DAA 14 DAA
Leaf chlorosis (%) Stunting (%) Leaf chlorosis (%) Stunting (%)
T1 0.0 0.0 0.0 0.0 28.4 10.51 (over T9) 90.5 3.78 (over T9)
T2 0.0 0.0 0.0 0.0 27.3 10.08 (over T10) 91.3 5.67 (over T10)
T3 0.0 0.0 0.0 0.0 29.2 15.42 (over T11) 92.3 4.65 (over T11)
T4 0.0 0.0 0.0 0.0 28.5 14.46 (over T12) 90.8 6.57 (over T12)
T5 0.0 0.0 0.0 0.0 29.0 18.37 (over T13) 92.8 7.16 (over T13)
T6 0.0 0.0 0.0 0.0 28.5 13.5 (over T14) 93.5 5.77 (over T14)
T7 0.0 0.0 0.0 0.0 27.8 12.55 (over T15) 92.6 6.93 (over T15)
T8 0.0 0.0 0.0 0.0 29.2 20.16 (over T16) 90.2 5.87 (over T16)
T9 5.0 0.0 0.0 0.0 25.7 - 87.2
T10 10.0 5.0 5.0 5.0 24.8 - 86.4
T11 10.0 5.0 5.0 5.0 25.3 - 88.2
T12 10.0 5.0 5.0 5.0 24.9 - 85.2
T13 15.0 10.0 10.0 5.0 24.5 - 86.6
T14 10.0 5.0 5.0 5.0 25.1 - 88.4
T15 10.0 5.0 5.0 5.0 24.7 - 86.6
T16 5.0 5.0 0.0 5.0 24.3 - 85.2
T17 0.0 0.0 0.0 0.0 19.7 - 0.0

All the ready mix innovative treatments (T1 to T8) found safe to the paddy crop and does not cause any injury to the crop and also produces higher number of productive tillers and provides higher weed control compared to their respective treatments without plant health additives i.e. gibberellic acid.
Example 3: Crop safety study in soybean, Glycine max
Crops: Soybean
No. of Treatments: As per treatment details
Plot size: 20 sq. mt.
Application Time: 15 DAS (Days after sowing)
Spray Volume: 375 liter water per hectare
Application Equipment: Manually operated knapsack sprayer fitted with flat fat nozzle
Agronomic practices: All the required agronomic practices followed except herbicidal application.

Table 7: Treatment details for crop safety study
Treatment number Treatment details Rate (gai/h)
T1 Haloxyfop R methyl 8%+Chlorimurone ethyl 0.9%+Ortho silicic acid 0.5% EC 80+9+5
T2 Haloxyfop R methyl 8%+Imazethapyr 7%+Ortho silicic acid 0.5% EC 80+70+5
T3 Haloxyfop R methyl 8%+Imazomox 7%+Ortho silicic acid 0.5% EC 80+70+5
T4 Haloxyfop R methyl 8%+Acifluorfen sodium 16.5%+Ortho silicic acid 0.5% EC 80+165+5
T5 Haloxyfop R methyl 8%+Fomesafen sodium 18%%+Ortho silicic acid 0.5% EC 80+180+5
T6 Haloxyfop R methyl 8%+Lactofen 18%+Ortho silicic acid 0.5% EC 80+180+5
T7 Haloxyfop R methyl 8%+Fluthiacet methyl 1.35%+Ortho silicic acid 0.5% EC 80+13.5+5
T8 Haloxyfop R methyl 8%+Chlorimurone ethyl 0.9% EC 80+9
T9 Haloxyfop R methyl 8%+Imazethapyr 7% EC 80+70
T10 Haloxyfop R methyl 8%+Imazomox 7% EC 80+70
T11 Haloxyfop R methyl 8%+Acifluorfen sodium 16.5% EC 80+165
T12 Haloxyfop R methyl 8%+Fomesafen sodium 18%% EC 80+180
T13 Haloxyfop R methyl 8%+Lactofen 18% EC 80+180
T14 Haloxyfop R methyl 8%+Fluthiacet methyl 1.35% EC 80+13.5
T15 Untreated control (UTC) -

Table 8: Crop safety and weed control in soybean
Treatment number Phytotoxicity symptoms Weed control (%) at 14 DAA % increase in weed control over Number of pods/plant % increase in pods/plant
Yellowing Leaf scorching
5 DAA 10 DAA 14 DAA 5 DAA 10 DAA 14 DAA
T1 5.0 0.0 0.0 0.0 0.0 0.0 90.7 5.22 (over T8) 21.7 16.04 (over T8)
T2 5.0 0.0 0.0 0.0 0.0 0.0 91.4 7.15 (over T9) 22.3 16.15 (over T9)
T3 5.0 0.0 0.0 0.0 0.0 0.0 92.5 6.69 (over T10) 21.4 15.68 (over T10)
T4 0.0 0.0 0.0 10.0 5.0 0.0 95.4 9.53 (over T11) 22.6 17.71 (over T11)
T5 0.0 0.0 0.0 10.0 5.0 0.0 94.8 9.34 (over T12) 23.1 17.26 (over T12)
T6 0.0 0.0 0.0 10.0 5.0 0.0 96.2 7.61 (over T13) 20.8 16.85 (over T13)
T7 0.0 0.0 0.0 10.0 5.0 0.0 95.8 8.00 (over T14) 22.4 17.89 (over T14)
T8 15.0 10.0 5.0 0.0 0.0 0.0 86.2 18.7 -
T9 20.0 15.0 5.0 5.0 0.0 0.0 85.3 19.2 -
T10 15.0 10.0 5.0 5.0 0.0 0.0 86.7 18.5 -
T11 5.0 0.0 0.0 25.0 10.0 5.0 87.1 19.2 -
T12 5.0 0.0 0.0 30.0 15.0 5.0 86.7 19.7 -
T13 5.0 0.0 0.0 25.0 15.0 5.0 89.4 17.8 -
T14 5.0 0.0 0.0 20.0 10.0 5.0 88.7 19.0 -
T15 0.0 0.0 0.0 0.0 0.0 0.0 0.0 14.5

The novel combination of Haloxyfop R methyl+Herbicide+ortho silicic acid (T1 to T7) shows better crop safety to soybean crop, increased weed control and higher number of pods per plant at harvest time as compared to combination of Haloxyfop R methyl+Herbicide (T8 to T14).

Example 4: Crop safety study in soybean, Glycine max
Crops: Soybean
No. of Treatments: As per treatment details
Plot size: 25 sq. mt.
Application Time: 21 DAS (Days after sowing)
Spray Volume: 380 liter water per hectare
Application Equipment: Manually operated knapsack sprayer fitted with flat fat nozzle
Agronomic practices: All the required agronomic practices followed except herbicidal application.

Table 9: Treatment details for crop safety and weed control in soybean
Treatment number Treatment details Rate (gai/h)
T1 Clodinafop Propargyl 10%+Chlorimurone ethyl 0.9%+Amino acid 2% EC 80+9+20
T2 Clodinafop Propargyl 10%+Imazethapyr 7%+Amino acid 2% EC 80+70+20
T3 Clodinafop Propargyl 10%+Imazomox 7%+Amino acid 2% EC 80+70+20
T4 Clodinafop Propargyl 10%+Acifluorfen sodium 16.5%+Amino acid 2% EC 80+165+20
T5 Clodinafop Propargyl 10%+Fomesafen sodium 18%%+Amino acid 2% EC 80+180+20
T6 Clodinafop Propargyl 10%+Lactofen 18%+Amino acid 2% EC 80+180+20
T7 Clodinafop Propargyl 10%+Fluthiacet methyl 1.35%+Amino acid 2% EC 80+13.5+20
T8 Clodinafop Propargyl 15% WP+Chlorimuron ethyl 25% WP (NIS-2 ml/l) 80+9
T9 Clodinafop Propargyl 15% WP+Imazethapyr 10% SL (NIS-1.5 ml+AMS-2 g/l) 80+70
T10 Clodinafop Propargyl 15% WP+Imazamox 35% WG (NIS-1.5 ml+AMS-2 g/l) 80+70
T11 Clodinafop Propargyl 15% WP+Acifluorfen sodium 20.1% SL (NIS-1.5 ml+AMS-2 g/l) 80+165
T12 Clodinafop Propargyl 15% WP+Fomesafen sodium 24% SL (NIS-1.5 ml+AMS-2 g/l) 80+180
T13 Clodinafop Propargyl 15% WP+Lactofen 24% EC (NIS-1.5 ml/l+AMS-2 g/l) 80+180
T14 Clodinafop Propargyl 15% WP+Fluthiacet methyl 10.3% EC 80+13.5
T15 Untreated control (UTC)

Table 10: Crop safety and weed control in soybean
Treatment number Phytotoxicity symptoms Weed control (%) at 14 DAA % increase in weed control over Number of pods/plant % increase in pods/plant
Yellowing Leaf scorching
5 DAA 10 DAA 14 DAA 5 DAA 10 DAA 14 DAA
T1 0.0 0.0 0.0 0.0 0.0 0.0 92.3 10.94 (over T8) 21.2 22.54 (over T8)
T2 0.0 0.0 0.0 0.0 0.0 0.0 92.8 9.56 (over T9) 21.7 19.89 (over T9)
T3 0.0 0.0 0.0 0.0 0.0 0.0 93.9 9.57 (over T10) 22.5 20.97 (over T10)
T4 0.0 0.0 0.0 10.0 5.0 0.0 96.1 9.95 (over T11) 23.7 19.70 (over T11)
T5 0.0 0.0 0.0 10.0 5.0 0.0 96.8 12.17 (over T12) 22.8 21.93 (over T12)
T6 0.0 0.0 0.0 10.0 5.0 0.0 95.7 9.12 (over T13) 21.9 24.43 (over T13)
T7 0.0 0.0 0.0 10.0 5.0 0.0 94.8 9.85 (over T14) 22.4 25.84 (over T14)
T8 10.0 5.0 0.0 5.0 0.0 0.0 83.2 17.3 -
T9 10.0 5.0 0.0 5.0 0.0 0.0 84.7 18.1 -
T10 10.0 5.0 0.0 5.0 0.0 0.0 85.7 18.6 -
T11 5.0 0.0 0.0 15.0 10.0 5.0 87.4 19.8 -
T12 5.0 0.0 0.0 15.0 10.0 5.0 86.3 18.7 -
T13 5.0 0.0 0.0 15.0 10.0 5.0 87.7 17.6 -
T14 5.0 0.0 0.0 15.0 10.0 5.0 86.3 17.8 -
T15 0.0 0.0 0.0 0.0 0.0 0.0 0.0 15.3

The field study on crop safety and weed control in soybean shows that the treatments of Clodinafop propargyl+herbicide+amino acid (T1 to T7) were safer to the soybean crop as compared to the treatments of Clodinafop propargyl+herbicide (T8 to T14). The amino acid in combination of Clodinafop propargyl+herbicide provides higher weed control and also increases number of pods per plant, which are directly contributing to the yield.
Summary of the biological experiments:
• Addition of plant health additives improves crop safety i.e. phytotoxicity symptoms if appears, are very mild and crop recovers very fast without losing potential growth parameters.
• Provides better weed control i.e. increases weed control efficiency of herbicides.
• Increases yield.
,CLAIMS:CLAIMS
We claim;
[CLAIM 1]. A synergistic agrochemical composition for reducing phytotoxicity in crops comprising:
i an herbicide selected from Acetyl CoA Carboxylase (ACCase) Inhibitor or mixture thereof in an amount of 0.1 to 60% by weight;
ii one or more herbicide(s) selected from the group of Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor, Synthetic Auxin, Inhibitor of photosynthesis at photosystem II site A, Inhibitor of photosynthesis at photosystem II site B, Inhibitor of lipid synthesis; not ACCase inhibition, Inhibitor of 5-enolypyruvyl-shikimate-3-phosphate synthase (EPSPS), Inhibitor of glutamine synthetase, Inhibitor of phytoene desaturase (PDS), Inhibitor of 1-deoxy-D-xyulose 5-phosphate sunthatase (DOXP synthase), Inhibitor of protoporphyrinogen oxidase (Protox, PPO), Mitosis Inhibitor, Inhibitor of 7,8-dihydro-preroate synthetase (DHP), Inhibitor of indoleacetic acid transport, Inhibitor of cell wall synthesis site A, Inhibitor of cell wall synthesis site B, Inhibitor of cell wall synthesis site C, Inhibition of cellulose synthesis, Photosystem I electron diverter, Membrane disruptor (uncouplers), Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD), Tyrosine Aminotransferase, Inhibition of dihydroorotate dehydrogenase(DHODH), HTS (homogentisate solanesyltransferase)-a downstream enzyme of HPPD, VLCAFE inhibitors, Inhibition of lycopene cyclase, Inhibition of Solanesyl Diphosphate Synthase (SDS), Inhibition of serine-threonine protein phosphatase or Herbicide with unknown mode of action or mixture thereof in an amount of 0.1 to 60% by weight;
iii plant health additive(s) or mixture thereof in an amount 0.1 to 30% by weight; and
iv inactive formulation excipients.

[CLAIM 2]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 1 wherein, herbicide from:
i acetyl CoA Carboxylase (ACCase) Inhibitor is selected from Aryloxyphenoxy-propionate ('FOPs') including clodinafop-propargyl, cyhalofop-butyl, diclofop, fenoxaprop-P, fluazifop-P, haloxyfop, metamifop, propaquizafop, quizalofop-P-ethyl; Cyclohexanedione ('DIMs') including alloxydim, butroxydim, clethodim, cycloxydim, sethoxydim, tralkoxydim, tepraloxydim; and Phenylpyrazoline ('DEN') including pinoxaden;
ii acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor from Sulfonylurea group is selected from amidosulfuron, azimsulfuron, bensulfuron methyl, chlorimuron ethyl, chlorsulfuron, cinosulfuron, cloransulfuron methyl, cyclosulfamuron, ethametsulfuron methyl, ethoxysulfuron, flazasulfuron, flucetosulfuron, flupyrsulfuron methyl sodium, foramsulfuron, halosulfuron methyl, imazosulfuron, iodosulfuron, mesosulfuron, metazosulfuron, metsulfuron mehtyl, nicosufulfuron, primisulfuron methyl, prosulfuron, pyrazosulfuron ehtyl, rimsulfuron, rimsulfuron, sulfometuron methyl, sulfosulfuron, thifensulfuron-methyl, triasulfuron, tribenuron methyl, trifloxysulfuron and triflusulfuron methyl;
iii acetoacetate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor from Pyrimidinyl(thio)benzoate group is selected from bispyribac-sodium, pyribenzoxim, pyrimisulfan, pyrithiobac sodium; from Triazolopyrimidine group selected from cloransulam-methyl, diclosulam, florasulam, flumetsulam, penoxsulam and pyroxsulam;
iv acetoacetate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor of Sulfonylaminocarbonyl group is selected from triazolinone-flucarbazone-sodium, propoxycarbazone-sodium, thiencarbazone-methyl; from Imidazolinone group such as imazamethabenz methyl, imazamox, imazapic, imazapyr, imazaquin, imazethapyr; from Sulfonanilides group is Triafamone;
v synthetic Auxin of Phenoxy carboxylic acid group is selected from 2,4-D, 2,4-DB, dichloroprop, MCPA, MCPB, mecoprop; of Pyrimidine carboxylic acid group is selected from aminocyclopyrachlor; of Pyridine carboxylic acid group is selected from aminopyralid, clopyralid, fluroxypyr, picloram, triclopyr; of Benzoic acid group is dicamba; of Quinoline carboxylic acid group is quinclorac; and halauxifen methyl;
vi inhibitor of photosynthesis at photosystem II site A of Phenyl carbamate group is selected from desmedipham, phenmedipham; of Pyridazinone group is pyrazon; of Triazine group is selected from ametryn, atrazine, cyanazine, desmetryn, prometon, prometryn, propazine, simazine, simetryn, terbumeton, terbuthylazine, trietazine; of Triazinone group is selected from hexazione, metamitron, metribuzin; of Triazolinone group is amicarbazone; of Urea group is metoxuron; of Uracil group is group is selected from bromacil, terbacil;
vii inhibitor of photosynthesis at photosystem II site B of Benzothiadiazinone group is bentazone; of Nitrile group is selected from bromoxynil, ioxynil; of Phenyl-pyridazine group is pyridate;
viii inhibitor of lipid synthesis; not ACCase inhibition of Benzofuran group is ethofumesate; of Phosphorodithioate group is bensulie; of Thiocarbamate group is selected from butylate, cycloate, EPTC, esprocarb, molinate, pebulate, prosulfocarb, thiobencarb, triallate, vernolate;
ix inhibitor of 5-enolypyruvyl-shikimate-3-phosphate synthase (EPSPS) of Glycine group is Glyphosate;
x inhibitor of glutamine synthetase of Phosphonic acid group is glufosinate;
xi inhibitor of phytoene desaturase (PDS) of Pyridinecarboxamide group is selected from diflufenican, picolinafen; of Pyridazinone group is norflurazon; and other compounds such as beflubutamid, fluridone, flurochloridone, flurtamone;
xii inhibitor of 1-deoxy-D-xyulose 5-phosphate sunthatase (DOXP synthase) of Isoxazolidinone group is clomazone;
xiii inhibitor of protoporphyrinogen oxidase (Protox, PPO) of Dipheylether group is selected from aclifluorfen, bifenox, fluoroglycofen, fomesafen, lactofen, oxyfluorfen; of Triazolinone group is selected from azafenidin, carfentrazone-ethyl, flufenpyr-ethyl, sulfentrazone; of Pyrimidinedione group is selected from butafenacil, saflufenacil; of N-phenylphthalimide group is selected from flumiclorac, flumioxazin; of N-Phenyl-imide group is trifludimoxazin; of Thiadiazole group is fluthiacet-methyl; of Oxadiazole group is selected from oxadiargyl, oxadiazon; of Phenylpyrazole group is pyraflufen-ethyl, of other group is pyraclonil; of Uracil group is tiafenacil; of Pyrazole group is cyclopyranil;
xiv mitosis Inhibitor of Chloroacetamide group is selected from acetochlor, alachlor, butachlor, dimethenamid, metazachlor, pretilachlor, propachlor, S-metolachlor, thenylchlor; of Tetrazolinone group is fentrazamide; of Oxyacetamide group is selected from flufenacet, mefenacet; of Acetamide group is napropamide; of Carbamate group is carbetamide and Other compound including anilofos;
xv inhibitor of 7, 8-dihydro-preroate synthetase (DHP) of Carbamate group is asulam;
xvi inhibitor of indoleacetic acid transport of Phthalamate semicarbazone group is selected from diflufenzopyr and naptalam;
xvii inhibitor of cell wall synthesis site A of Nitrile group is dichlobenil;
xviii inhibitor of cell wall synthesis site B of Benzamide group is isoxaben;
xix inhibitor of cell wall synthesis site C of Alkylazines group is selected from indaziflam and triaziflam;
xx inhibitors of cellulose synthesis of Triazolocarboxamide group is flupoxam; of nitriles group is dichlobenil, chlorthiamide;
xxi photosystem I electron diverter of Pyridiniums group is selected from cyperquat, diquat, morfamquat, paraquat;
xxii membrane disruptor (uncouplers) of Dinitrophenol group is dinoterb;
xxiii inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD) of Pyrazole group is selected from benzofenap, pyrasulfotole, pyrazolynate, pyrazoxyfen, tolpyralate; of Benzoylbicyclooctanedione group is benzobicyclon; Triketone group is selected from mesotrione, tembotrione, sulcotrione, tefuryltrione, fenquinotrione, lancotrione sodium; of Isoxazoles group is selected from isoxaflutole; bicyclo ring compound group is bicyclopyrone;
xxiv tyrosine Aminotransferase class is selected from cinmethylin and methiozolin;
xxv inhibitors of dihydroorotate dehydrogenase (DHODH) is tetflupyrolimet;
xxvi HTS (homogentisate solanesyltransferase)-a downstream enzyme of HPPD is cyclopyrimorate;
xxvii VLCAFE inhibitors of Isoxazoline group is pyroxasulfone, of Triazolinone group is ipfencarbazone, of Trifluoromethansulfonanilides group is dimesulfazet, and other compound including fenoxasulfone;
xxviii inhibitors of lycopene cyclase is amitrole;
xxix inhibitors of Solanesyl Diphosphate Synthase (SDS) is aclonifen;
xxx inhibitors of serine-threonine protein phosphatase is endothall; and
xxxi herbicide with unknown mode of action is selected from bromobutide, cacodylic acid, CAMA, cumyluron, difenzoquat, DSMA, dymron=daimuron, etobenzanid, fasamine, methyldymron, monalide, MA, oleic acid, oxaziclomefone, pelargonic acid, pyributicarb, quinoclamine, diphenamid, naproanilide, napropamide, flamprop-m, tebutam, dalapon, flupropanate, TCA, flamprop-m, tebutam, bensulide, mefluidide, perfluidone, dazomet, acrolein, AMS, benzolin, benoxacor, cacodylic acid, cloquintocet mexyl, copper chelate, copper sulfate, cyprosulfamide, dichlomid, dietholate, dimethipin, fenchlorazole-ethyl, fenclorim, fluxofenim, maleic hydrazide, mefenpyr-diethyl, mefluidide, metaborate, oxaziclomefone, sodium chlorate, epyrifenacil, bixzolone.

[CLAIM 3]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 1 wherein, Plant health additive is selected from humic acid (salts), fulvic acid (salts), amino acids (alanine, arginine, aspartic acid, cysteine, glutamic acid, glycine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, proline, serine, threonine, tryptophan, tyrosine, valine or mixture thereof), protein hydrolysates, peptides, organic acid, acetylthioproline, thiazolidine carboxylic acid, jasmonic acid, methyl jasmonate, chitosan, chitin, seaweed extract (Ascophyllum nodosum), polyamines, silicic acid (salts)-orthosilicic acid (H4Si04), silica nanoparticles (10-100 nm), calcium silicate, potassium silicate, sodium silicate), silicyclic acid, lactic acid, phenyllactic acid, fumaric acid, acibenzolar-s-methyl, gibberellic acid, GA3, brassinolide, forchlorfenuron, triacontanol, silicyclic acid, Nitrophenolate (sodium para-nitrophenolate, ortho-nitrophenolate, sodium-5-nitroguaiacolate), nitrobenzene or mixture thereof; from the group of micronutrients is selected from Zinc (zinc sulphate heptahydrate ZnSO47H2O, zinc sulphate mono hydrate ZnSO4.H2O, chelated zinc as Zn-EDTA, zinc oxide, Zinc Lactate Gluconate, Zinc Polyflavonoid), Boron (borax-sodium tetraborate, boric acid (H3BO3), di-sodium octa borate tetra hydrate (Na2B8O13.4H2O), di-sodium tetra borate penta hydrate, anhydrous borax, ), Manganese (manganese sulphate), Copper (copper sulphate), Iron (ferrous sulphate, chelated iron as Fe-EDTA), Molybdanum (ammonium molybdate), Magnesium (Magnesium sulphate) and Sulphur (elemental sulphur, boronated sulphur) and mixture thereof.

[CLAIM 4]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 1, wherein the formulation for the said composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), a mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR).

[CLAIM 5]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 1 and claim 4, wherein the preferred composition for Suspo-emulsion (SE) formulation comprises:
i Suspo-emulsion (SE) formulation of Metamifop 7.5%+ Triafamone 2%+ Fulvic acid 2%;
ii Suspo-emulsion (SE) formulation of Metamifop 7.5%+ Tefuryltrione 4%+ Fulvic acid 2%;
iii Suspo-emulsion (SE) formulation of Metamifop 7.5%+ Fenquinotrione 10%+ Fulvic acid 2%;
iv Suspo-emulsion (SE) formulation of Metamifop 7.5%+ Lancotrion sodium 10%+ Fulvic acid 2%;
v Suspo-emulsion (SE) formulation of Metamifop 7.5%+ Cyclopyrimorate 15%+ Fulvic acid 2%;
vi Suspo-emulsion (SE) formulation of Metamifop 7.5%+ Tetflupyrolimet 15%+ Fulvic acid 2%;
vii Suspo-emulsion (SE) formulation of Metamifop 3.75%+ Bentazone 30%+ Fulvic acid 1%;
viii Suspo-emulsion (SE) formulation of Metamifop 7.5%+ Bispyribac sodium 2%+ Fulvic acid 2%;
ix Suspo-emulsion (SE) formulation of Cyhalofop butyl 6%+ Triafamone 2% + Gibberellic acid 0.2%;
x Suspo-emulsion (SE) formulation of Cyhalofop butyl 6%+ Tefuryltrione 4%+ Gibberellic acid 0.2%;
xi Suspo-emulsion (SE) formulation of Cyhalofop butyl 6%+ Fenquinotrione 10%+ Gibberellic acid 0.2%;
xii Suspo-emulsion (SE) formulation of Cyhalofop butyl 6%+ Lancotrion sodium 10%+ Gibberellic acid 0.2%;
xiii Suspo-emulsion (SE) formulation of Cyhalofop butyl 6%+ Cyclopyrimorate 15%+ Gibberellic acid 0.2%;
xiv Suspo-emulsion (SE) formulation of Cyhalofop butyl 6%+ Tetflupyrolimet 15%+ Gibberellic acid 0.2%; and
xv Suspo-emulsion (SE) formulation of Cyhalofop butyl 3%+ Bentazone 30%+ Gibberellic acid 0.1%.

[CLAIM 6]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 5 wherein, the Suspo-emulsion (SE) formulation comprises:
a) an herbicide selected from Acetyl CoA Carboxylase (ACCase) Inhibitor or mixture thereof in an amount of 0.1 to 60% by weight;
b) one or more herbicide(s) selected from the group of Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor, Synthetic Auxin, Inhibitor of photosynthesis at photosystem II site A, Inhibitor of photosynthesis at photosystem II site B, Inhibitor of lipid synthesis; not ACCase inhibition, Inhibitor of 5-enolypyruvyl-shikimate-3-phosphate synthase (EPSPS), Inhibitor of glutamine synthetase: Phosphonic acid, Inhibitor of phytoene desaturase (PDS), Inhibitor of 1-deoxy-D-xyulose 5-phosphate sunthatase (DOXP synthase), Inhibitor of protoporphyrinogen oxidase (Protox, PPO), Mitosis Inhibitor, Inhibitor of 7,8-dihydro-preroate synthetase (DHP), Inhibitor of indoleacetic acid transport, Inhibitor of cell wall synthesis site A, Inhibitor of cell wall synthesis site B, Inhibitor of cell wall synthesis site C, Inhibition of cellulose synthesis, Photosystem I electron diverter, Membrane disruptor (uncouplers), Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD), Tyrosine Aminotransferase, Inhibition of dihydroorotate dehydrogenase(DHODH), HTS (homogentisate solanesyltransferase)-a downstream enzyme of HPPD, VLCAFE inhibitors, Inhibition of lycopene cyclase, Inhibition of Solanesyl Diphosphate Synthase (SDS), Inhibition of serine-threonine protein phosphatase or Herbicide with unknown mode of action or mixture thereof in an amount of 0.1 to 60% by weight;
c) plant health additive(s) or mixture thereof in an amount 0.1 to 30% by weight;
d) solvent in an amount of 8 to 12% by weight;
e) wetting-spreading-penetrating agent in an amount of 3 to 8% by weight;
f) dispersing agent in an amount of 0.5 to 7% by weight;
g) suspending agent in an amount of 1 to 4% by weight;
h) antifoaming agent in an amount of 0.1 to 0.5% by weight;
i) preservative in an amount of 0.1 to 0.3% by weight;
j) antifreezing agent in an amount of 3 to 8% by weight;
k) thickner in an amount of 0.12 to 0.17% by weight; and
l) diluent water in an amount of 50 to 70% by weight.

[CLAIM 7]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 6 wherein, solvent is selected from octyl phenol Ethoxylate, Solvent-C-9, water, methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol, polyethylene glycol, sorbitol, glucitol, ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether, ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl ether, Paraffinic hydrocarbons, cyclohexanone, isophorone, methyloleate, dimethylamide, morpholineamide derivatives of C6-C16 fatty acids, ethylene carbonate, propylene carbonate, butylene carbonates, dimethylsulfoxide (DMSO), 2-ethylhexanol, n-butanol, n-alkylpyrrolidones, fatty acid dimethyl esters, fatty acid esters, dibasic esters, aromatic hydrocarbons, aliphatic hydrocarbons, C8-dimethylamide, C10-dimethylamide, C12-dimethylamide, ethylene glycol, propylene glycol, polyalkylene glycols, methylpyrrolidinone (NMP); dimethylformamide (DMF); dimethylisosorbide (DMI); acetophenone; 1,3-dimethyl-2-imidazolidonone; lactate esters; dimethyl and diethylcarbonates; Methyl L-lactate, 2-Ethylhexyl L-lactate, Ethyl L-lactate, n-Butyl L-lactate.

[CLAIM 8]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 6 wherein, wetting-spreading-penetrating agent is selected from trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, heptamethyl trisiloxane ethoxylate, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol.

[CLAIM 9]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 6 wherein, dispersing agent is selected from polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylic polymers and copolymers, styrene copolymers, butadiene copolymers, starch, cellulose derivatives, vinylalcohol, vinylacetate, vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins, poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers, styrene-acrylic copolymers, ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, polyhydroxybutyrate, Polyarylphenyl ether sulphate ammonium salt, alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium salt of alkyl naphthalene sulfonate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.

[CLAIM 10]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 6 wherein, suspending agent is selected from aluminum magnesium silicate, bentonite clay, silica, silicone dioxide, attapulgite clay.

[CLAIM 11]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 6 wherein, antifoaming agent is selected from silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethylsiloxane, polydimethylsiloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane.

[CLAIM 12]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 6 wherein, preservative is selected from 2-bromo-2-nitropropane-1,3-diol, propionic acid and its sodium salt; sorbic acid and its sodium or potassium salts; benzoic acid and its sodium salt; p-hydroxy benzoic acid sodium salt; methyl p-hydroxy benzoate; and biocide such as sodium benzoate, 1,2- benzisothiazoline-3-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4- isothiazolin-3-one, potassium sorbate, para hydroxy benzoates or mixtures thereof.

[CLAIM 13]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 6 wherein, anti-freezing agent is selected from ethylene glycol, propane diols, glycerine, urea, monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol, magnesium sulfate heptahydrate, sodium chloride.

[CLAIM 14]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 6 wherein, thickner is selected from bentonite, magnesium aluminum silicate, attapulgite, guar gum, locust bean gum, carrageenam, xanthan gum, alginates, methyl cellulose, sodium carboxymethyl cellulose (SCMC), hydroxyethyl cellulose (HEC) or mixtures thereof.

[CLAIM 15]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 1 and claim 4, wherein the preferred composition for Emulsifiable concentrate (EC) formulation comprises:
i. Emulsifiable concentrate (EC) formulation of Haloxyfop R methyl 8%+ Chlorimuron ethyl 0.9%+ Ortho silicic acid 0.5%;
ii. Emulsifiable concentrate (EC) formulation of Haloxyfop R methyl 8%+ Imazethapyr 7%+ Ortho silicic acid 0.5%;
iii. Emulsifiable concentrate (EC) formulation of Haloxyfop R methyl 8%+ Imazamox 7%+ Ortho silicic acid 0.5%;
iv. Emulsifiable concentrate (EC) formulation of Haloxyfop R methyl 8%+ Acifluorfen sodium 16.5%+ Ortho silicic acid 0.5%;
v. Emulsifiable concentrate (EC) formulation of Haloxyfop R methyl 8%+ Fomesafen sodium 18%+ Ortho silicic acid 0.5%;
vi. Emulsifiable concentrate (EC) formulation of Haloxyfop R methyl 8%+ Lactofen 18%+ Ortho silicic acid 0.5%;
vii. Emulsifiable concentrate (EC) formulation of Haloxyfop R methyl 8%+ Fluthiacet methyl 1.35%+ Ortho silicic acid 0.5%;
viii. Emulsifiable concentrate (EC) formulation of Clodinafop Propargyl 8%+ Chlorimuron ethyl 0.9%+ Amino acid 2%;
ix. Emulsifiable concentrate (EC) formulation of Clodinafop Propargyl 8%+ Imazethapyr 7%+ Amino acid 2%;
x. Emulsifiable concentrate (EC) formulation of Clodinafop Propargyl 8%+ Imazamox 7%+ Amino acid 2%;
xi. Emulsifiable concentrate (EC) formulation of Clodinafop Propargyl 8%+ Acifluorfen sodium 16.5%+ Amino acid 2%;
xii. Emulsifiable concentrate (EC) formulation of Clodinafop Propargyl 8%+ Fomesafen sodium 18%+ Amino acid 2%;
xiii. Emulsifiable concentrate (EC) formulation of Clodinafop Propargyl 8%+ Lactofen 18%+ Amino acid 2%; and
xiv. Emulsifiable concentrate (EC) formulation of Clodinafop Propargyl 8%+ Fluthiacet methyl 1.35%+ Amino acid 2%;

[CLAIM 16]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 15 wherein, Emulsifiable concentrate (EC) formulation comprises:
i an herbicide selected from Acetyl CoA Carboxylase (ACCase) Inhibitor or mixture thereof in an amount of 0.1 to 60% by weight;
ii one or more herbicide(s) selected from the group of Acetolactate Synthase (ALS) or Acetohydroxy Acid Synthase (AHAS) inhibitor, Synthetic Auxin, Inhibitor of photosynthesis at photosystem II site A, Inhibitor of photosynthesis at photosystem II site B, Inhibitor of lipid synthesis; not ACCase inhibition, Inhibitor of 5-enolypyruvyl-shikimate-3-phosphate synthase (EPSPS), Inhibitor of glutamine synthetase: Phosphonic acid, Inhibitor of phytoene desaturase (PDS), Inhibitor of 1-deoxy-D-xyulose 5-phosphate sunthatase (DOXP synthase), Inhibitor of protoporphyrinogen oxidase (Protox, PPO), Mitosis Inhibitor, Inhibitor of 7,8-dihydro-preroate synthetase (DHP), Inhibitor of indoleacetic acid transport, Inhibitor of cell wall synthesis site A, Inhibitor of cell wall synthesis site B, Inhibitor of cell wall synthesis site C, Inhibition of cellulose synthesis, Photosystem I electron diverter, Membrane disruptor (uncouplers), Inhibitor of Hydroxyphenyl Pyruvate Dioxygenase (4-HPPD), Tyrosine Aminotransferase, Inhibition of dihydroorotate dehydrogenase(DHODH), HTS (homogentisate solanesyltransferase)-a downstream enzyme of HPPD, VLCAFE inhibitors, Inhibition of lycopene cyclase, Inhibition of Solanesyl Diphosphate Synthase (SDS), Inhibition of serine-threonine protein phosphatase or Herbicide with unknown mode of action or mixture thereof in an amount of 0.1 to 60% by weight;
iii plant health additive(s) or mixture thereof in an amount 0.1 to 30% by weight;
iv emulsifying agent in an amount of 2 to 10% by weight; and
v solvent in an amount of 50-70% by weight.

[CLAIM 17]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 16 wherein, emulsifying agent is selected from blend of Polyaryl phenol ethoxylate and calcium dodecyl benzene sulfonate, N-Methyl-2-pyrrolidone, salts of dodecylbenzene sulphonate, Ca-salts or amine salts, sulphonates of C11-C16 alkylbenzenes, alkylphenoletherphosphates and ester phosphates, alkoxylated alcohols, alkylphenols, ethoxylated fatty acids, ethoxylated castor oil, sorbitol, and their ethoxylated derivatives, ethoxylated amines, condensates of glycerolcationic amine, optionally in combination with an alkylsulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkylphenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol; fatty acid esters of sorbitol and ethoxylated derivatives, ethoxylated amines and condensates of glycerol; sulfonated alkylbenzenes in the range C11-C16 and salts thereof; alkylether sulphates; alkyletherphosphates; alkylphenoletherphosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenol; or a catanionic system, wherein a cationic amine is present in combination with an alkylsulphonate, an alkylethersulphonate, an ether sulphate, or an ether phosphate such as an alkyletherphosphate, nonylphenol polyethoxy ethanols, castor oil polyglycol ethers, polyadducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol.

[CLAIM 18]. The synergistic agrochemical composition for reducing phytotoxicity in crops as claimed in claim 16 wherein, solvent is selected from octyl phenol Ethoxylate, Solvent-C-9, water, water soluble alcohols and dihydroxy alcohol ethers. Water soluble alcohol or lower alcohol (1-4 carbon atoms) includes-methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol. Macromolecular alcohol includes polyethylene glycol, sorbitol, glucitol etc., dihydroxy alcohol ethers includes dihydroxy alcohol alkyl ether or dihydroxy alcohol aryl ethers. The examples of dihydroxy alcohol alkyl ether include ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether, etc. The examples of dihydroxy alcohol aryl ethers include ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl ether, and the like. Any of the mentioned solvent can be used either alone or in combinations thereof.