DESC:FIELD OF THE INVENTION:
The present invention relates to synergistic pesticidal agrochemical composition comprising of bioactive amounts of (A) Broflanilide and; (B) at least one insecticide selected from diamide group of insecticides; (C) at least one more compound selected from insecticides, fungicides, plant health additives or combination thereof.. The present invention further relates to process of preparing the said composition for foliar spray and seed treatment along with at least one inactive excipients and formulations thereof.

BACKGROUND OF THE INVENTION:
Combination of insecticides, insecticides and fungicides, insecticides and plant health additives are used to provide complete protections to the crop plants against insects, mites, nematodes, fungal and bacterial diseases, to reduce dosage, to decrease chances of development of resistance, to increases the tolerance against biotic and abiotic stress. The combination of insecticides, insecticides and fungicides, insecticides and plant health additives at times demonstrate an additive or synergistic effect that results in an improved control on the pests.
Insecticide or pesticides are used widely and very frequently in commercial agriculture
and have enabled an enormous increase in crop yields and product quality which
ultimately increased the ease to farmers in term of economic advantage as well as ease of farming activities.
Plant health additives (PHA) are typically any substance or mixture of substances intended to accelerate or slow down the rate of growth or ripening, or otherwise change the development of plants, or to produce plants. Some plant health additives protect plants from biotic and abiotic stress. They give tolerance to extreme temperatures, both high and low, to drought, to high salt content, which are some examples of abiotic stresses that plants can undergo. PHA allows plants to withstand biotic and abiotic stresses by manipulating many physiological processes in the plant.
The insects, mites, fungal and bacterial diseases damages above ground plant parts such as leaves, flowers, fruits, twigs, stems, branches etc., whereas few insects, fungal and bacterial diseases and nematodes damages below ground plant parts, seeds and plant propagating materials which causes considerable yield loss. Treating the crop and plants with insecticides, insecticide and fungicide, insecticide and plant health additives combinations as foliar application, soil applications and seed treatments helps to reduce damage from insects, mites, nematodes, fungal and bacterial diseases. The advantage of treating seeds or other plant propagation material is the improvement in germination rates, increased yield and improved plant health.
WO2016128261A2 patent relates to a Pesticidal mixture comprising a pyrazole compound, an insecticide and a fungicide. The use of a pesticidal mixture PM comprising at least one compound of formula I as defined in the specification, an insecticide II and a fungicide III for protecting plants selected from wheat, maize, barley, oat, rye, rice, soybean, cotton, sugarbeet, rapeseed, and potato, the plant propagation material thereof, or soil or water, in which the plants are growing, against the attack or infestation by invertebrate pests and/or phytopathogenic harmful fungi. Furthermore, the present invention relates to a seed treatment composition comprising the pesticidal mixture PM and to seeds comprising the pesticidal mixture PM or the seed treatment composition thereof. Moreover, the present invention relates to a method for controlling invertebrate pests and/or phytopathogenic harmful fungi on plants selected from wheat, maize, barley, oat, rye, rice, soybean, cotton, sugarbeet, rapeseed, and potato comprising contacting the plant or the plant propagation material; the pest or its food supply, habitat or breeding ground; and/or the fungi or their habitat, with an effective amount of the pesticidal mixture PM or the seed treatment composition thereof. In a further aspect, the present invention relates to binary mixtures of a compound of formula I and tioxazafen, tetraniliprole, broflanilide, cyhalodiamide, fluazaindolizine, and fluxametamide, resp.
US20210127680A1 patent relates to a pesticidal composition combination comprising: a) at least one insecticidal diamide compound selected from the group consisting of broflanilide, chlorantraniliprole, cyantraniliprole, cyclaniliprole, cyhalodiamide, flubendiamide, tetrachlorantraniliprole, tyclopyrazoflor, and tetraniliprole; b) at least one benzoylphenyl urea compound; and c) at least a third insecticidal compound.
WO2017091627A1 patent relates to a Fungicidal compositions containing derivatives of 2,4-dioxo-1,4-dihydrothieno[2,3-d]pyrimidine. Provided herein are compounds that exhibit activity as fungicides and are useful, for example, in methods for the control of fungal pathogens in plants and can be applied to said plants in a variety of ways.
US11154058B2 Patent relates to a fungicidal composition comprising a mixture of a N-phenylamidine defined as component (A) and a further pesticide as component (B) as defined in claim, as well as the use of the composition in agriculture or horticulture for controlling or preventing infestation of plants by phytopathogenic microorganisms, preferably fungi.
There is however a need for improvement of these combinations. Single active combinations used over a long period of time has resulted in resistance. With the onset of resistance to certain pests, there is a need in the art for a combination of actives that decreases chances of resistance and improves the spectrum of disease and pest control.
Therefore there is a need for pesticidal agrochemical composition comprises Broflanilide; at least one insecticide selected from diamide group of insecticides; at least one more compound selected from insecticides, fungicides, plant health additives which overcomes some of the existing problems and can be prepared easily without much complex manufacturing process.
In general use, the pesticide actives are used in the form of a dilute aqueous composition because it can attain a good interaction with the target organism, such as plants, fungi and insects. However, most active pesticide compounds that are used as pesticides are only sparingly or even insoluble in water. The low solubility of such compounds present the challenges and difficulties to formulator in formulating pesticide compounds in stable formulations that can be easily stored for a long time and which still have a high stability and effective activity until end use. This problem especially occurs and may get worsen if more than one active compound is present in the composition.
Therefore, one object of the present invention is to provide improved Combination of insecticides, insecticides and fungicides, insecticides and plant health additives for the control of soil borne pests. Another object of the present invention is to provide a method and a composition for controlling insect pests and fungal diseases around plant propagation material.
Yet another object of the present invention is to provide improved combinations of insecticides and fungicides that promote plant health and increasing plant stand in the field.
Most pesticides are applied at low rate which makes it difficult for the user to apply uniformly in the field conditions. Many pesticides are unstable in terms of their active ingredients. There are formulations unable to put together more than one active ingredients in a stable form which is helpful to the growers to apply them uniformly in the field conditions.
Yet another object of the present invention is to provide improved combinations of insecticides, insecticides and fungicides, insecticides and plant health additives that promote plant health.
Inventors of the present invention have surprisingly found that the present pesticidal synergistic
agrochemical composition comprising of Broflanilide; at least one insecticide selected from diamide group of insecticides; at least one more compound selected from insecticides, fungicides, plant health additives having various mode of action as described herein provides solution to the above mentioned problems. Further the present pesticidal composition is found to be effective against insect-pests and diseases control and also produces more fruits, flowers and grains, increases spectrum of control, reduces number of pesticidal applications under field conditions.

SUMMARY OF THE INVENTION:
Therefore an aspect of the present invention provides a synergistic pesticidal agrochemical composition comprising of (A) Broflanilide and; (B) at least one insecticide selected from diamide group of insecticides; (C) at least one more compound selected from insecticides, fungicides, plant health additives and plant health addditives selected from bio-stimulants, plant growth promoter/regulators and micronutrients or mixture thereof.
More particularly an aspect of the present invention provides a synergistic pesticidal agrochemical composition comprising possible combinations of Broflanilide+Diamide group of insecticide+Insecticide or Broflanilide+Diamide group of Insecticide+ Fungicide or Broflanilide+ Diamide group of Insecticide+Plant health additives or combination thereof.
In a further aspect of the present invention, an insecticides for present synergistic pesticidal agrochemical composition may be selected from Carbamates; Organophosphate; Phenylpyrazole; Pyrethroids; Nicotinic insecticides; Spinosyns; Mectins; Mimics; Multisite inhibitors; Chordotonal organs modulators; Mite growth inhibitors; Microbial disruptors of insect midgut membrane; Inhibitors of mitochondrial ATP synthase; Uncouplers of oxidative phosphorylation; Nereis toxin; Chitin biosynthesis inhibitors; Inhibitors of the chitin biosynthesis type 1; Moulting disruptors; Ecdyson receptor agonists; Octopamin receptor agonists; Mitochondrial complex III (METI-mitochondrial electrom transport inhibitors) inhibitors; Mitochondrial complex I (METI) inhibitors; Voltage-dependent sodium channel blockers; Inhibitors of the lipid synthesis, Inhibitors of acetyl CoA carboxylase; Mitochondrial complex IV (METI) inhibitors; Mitochondrial complex II (METI) inhibitors; Chordotonal organ modulators-undefined target; Metadiamides; Isoxazolines; Baculoviruses; Calcium activated potassium channel (KCa2) modulators; Compounds of unknown or uncertain mode of action.
In a further aspect of the present invention, a fungicide synergistic pesticidal agrochemical composition may be selected from Nucleic acid synthesis inhibitors; Cytoskeleton and motor proteins/cell division inhibitors; Respiration inhibitors; Amino acids and protein synthesis inhibitors; Signal transduction inhibitors; Lipid or transport and membrane synthesis inhibitors; Sterol biosynthesis Inhibitors; Cell wall biosynthesis Inhibitors; Melanin synthesis in cell wall Inhibitors; Plant defence inducers; Unknow mode of action; Not classified (N); Chemicals with multisite activities (M)-multisite contact activities; Biologicals with multiple modes of action (BM); Others fungicides-Ipflufenoquin, Pyridachlometyl, Quinofumelin, Dichlobentiazox, Aminopyrifen, Dipymetitrone.
In an another aspect of the present invention the plant health additives synergistic pesticidal agrochemical composition selected from bio-stimulants, plant growth promoter/regulators and micronutrients or mixture thereof.
Accordingly, in a further aspect of the present synergistic pesticidal agrochemical composition comprises (A) Broflanilide is in range of 0.01% to 20% w/w of the composition; (B) at least one insecticide selected from diamide group of insecticides is in range of 0.01% to 30% w/w of the composition; (C) at least one more compound selected from insecticides, fungicides, plant health additives are in range of 0.001% to 50% w/w of the composition.
Accordingly, in a further aspect, the present invention provides a method of protecting a plant propagation material, a plant, parts of a plant and/or plant organs that grow at a later point in time against pathogenic damage or pest damage by applying to the plant propagation material comprising an agrochemical composition defined in the first aspect.
Accordingly, in a yet another aspect the agrochemical composition comprising (A) Broflanilide and; (B) at least one insecticide selected from diamide group of insecticides; (C) at least one more compound selected from insecticides, fungicides, plant health additives and plant health additives selected from bio-stimulants, plant growth promoter/regulators and micronutrients or mixture thereof wherein the formulations selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR), Water dispersible powder for slurry treatment (WS), solution for seed treatment (LS), emulsions for seed treatment (ES), Flowable suspension/concentrate for seed treatment (FS), aqueous capsule suspension (CS), powder for dry seed treatment (DS).
The remainder of the aqueous formulation is preferably wholly water but may comprise other materials, such as inorganic salts. The formulation is preferably, completely free from organic solvents.
Accordingly, in a first aspect, the present invention provides a synergistic pesticidal agrochemical composition comprising (A) Broflanilide and; (B) at least one insecticide selected from diamide group of insecticides; (C) at least one more compound selected from insecticides, fungicides, plant health additives or combination thereof.

DETAILED DESCRIPTION OF THE INVENTION:
The term "synergistic", as used herein, refers the combined action of two or more active
agents blended together and administered conjointly that is greater than the sum of their
individual effects.
"Bioactive amounts” as mentioned herein means that amount which, when applied treatment of crops, is sufficient to effect such treatment.
Therefore an aspect of the present invention provides a synergistic pesticidal composition for foliar spray comprising (A) Broflanilide and; (B) at least one insecticide selected from diamide group of insecticides; (C) at least one more compound selected from insecticides, fungicides, plant health additives or combination thereof.
In an embodiment of the present invention the insecticide from the class of diamide insecticides may be selected from chlorantraniliprole, cyantraniliprole, cyclaniliprole, tetraniliprole, tetrachlorantraniliprole, tyclopyrazoflor, cyhalodiamide, flubendiamide, fluchlordiniliprole.
In an embodiment of the present invention, an insecticide may be selected from Carbamates; Organophosphate; Phenylpyrazole; Pyrethroids; Nicotinic insecticides; Spinosyns; Mectins; Mimics; Multisite inhibitors; Chordotonal organs modulators; Mite growth inhibitors; Microbial disruptors of insect midgut membrane; Inhibitors of mitochondrial ATP synthase; Uncouplers of oxidative phosphorylation; Nereis toxin; Chitin biosynthesis inhibitors; Inhibitors of the chitin biosynthesis type 1; Moulting disruptors; Ecdyson receptor agonists; Octopamin receptor agonists; Mitochondrial complex III (METI-mitochondrial electrom transport inhibitors) inhibitors; Mitochondrial complex I (METI) inhibitors; Voltage-dependent sodium channel blockers; Inhibitors of the lipid synthesis, Inhibitors of acetyl CoA carboxylase; Mitochondrial complex IV (METI) inhibitors; Mitochondrial complex II (METI) inhibitors; Chordotonal organ modulators-undefined target; Metadiamides; Isoxazolines; Baculoviruses; Calcium activated potassium channel (KCa2) modulators; Compounds of unknown or uncertain mode of action.
In an embodiment of the present invention the insecticide from the class of Carbamates insecticides may be selected from carbaryl, carbofuran, carbosulfan, methomyl, oxamyl, pirimicarb, thiodicarb.
In an embodiment of the present invention the insecticide from the class of organophosphates insecticides may be selected from acephate, cadusafos, chlorpyrifos, chlorpyrifos-methyl, demeton-S-methyl, dimethoate, ethion, fenamiphos, fenitrothion, fenthion, fosthiazate, methamidophos, monocrotophos, oxydemeton-methyl, parathion, parathion-methyl, phenthoate, phorate, phosalone, phosphamidon, profenofos, quinalphos, triazophos.
In an embodiment of the present invention the insecticide from the class of phenylpyrazole insecticides may be selected from ethiprole, fipronil, flufiprole, nicofluprole, pyrafluprole, pyriprole.
In an embodiment of the present invention the insecticide from the class of pyrethroids insecticides may be selected from bifenthrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, fenpropathrin, fenvalerate, tau-fluvalinate, permethrin, phenothrin, prallethrin, profluthrin, pyrethrin (pyrethrum).
In an embodiment of the present invention the insecticide from the class of nicotinic insecticides may be selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam, flupyrimin, cycloxaprid, paichongding, guadipyr, cycloxylidin; sulfoximines-sulfoxaflor; butenolides- flupyradifurone; mesoionics- triflumezopyrim, dichloromezotiaz, fenmezoditiaz.
In an embodiment of the present invention the insecticide from the class of spinosyns insecticides may be selected from spinosad, spinetoram.
In an embodiment of the present invention the insecticide from the class of mectins insecticide may be selected from Avermectins-abamectin, emamectin benzoate, ivermectin, lepimectin; milbemycins- milbemectin.
In an embodiment of the present invention the insecticide from the class of mimics insecticides may be selected from hydroprene, kinoprene, methoprene, fenoxycarb, Pyriproxyfen.
In an embodiment of the present invention the insecticide from the class of multisite inhibitors insecticides may be selected from chloropicrin, dazomet, metam.
In an embodiment of the present invention the insecticide from the class of chordotonal organs modulators insecticides may be selected from selective homopteran feeding blockers: pyridine azomethine-pymetrozine, pyrifluquinazon; pyropenes- afidopyropen, others-flonicamid.
In an embodiment of the present invention the insecticide from the class of mite growth inhibitors insecticides may be selected from clofentezine, hexythiazox, diflovidazin or etoxazole.
In an embodiment of the present invention the insecticide from the class of microbial disruptors of insect midgut membrane insecticides may be selected from Bacillus thuringiensis and insecticidal proteins they product.
In an embodiment of the present invention the insecticide from the class of inhibitors of mitochondrial ATP synthase insecticides may be selected from diafenthiuron, azocyclotin, cyhexatin, fenbutatin oxide, propargite, or tetradifon.
In an embodiment of the present invention the insecticide from the class of uncouplers of oxidative phosphorylation insecticides may be selected from chlorfenapyr, DNOC, or sulfluramid.
In an embodiment of the present invention the insecticide from the class of nereis toxin insecticides may be selected from bensultap, monosultap, cartap hydrochloride, thiocyclam, thiocyclam hydrogen oxalate, thiocyclam hydrochloride, thiosultap sodium.
In an embodiment of the present invention the insecticide from the class of chitin biosynthesis inhibitors insecticides may be selected from benzoylureas-bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron, triflumuron.
In an embodiment of the present invention the insecticide from the class of chitin biosynthesis type 1 insecticides may be selected from buprofezin.
In an embodiment of the present invention the insecticide from the class of moulting disruptors insecticides may be selected from cyromazine.
In an embodiment of the present invention the insecticide from the class of ecdyson receptor agonists insecticides may be selected from diacylhydrazines- methoxyfenozide, tebufenozide, halofenozide, fufenozide or chromafenozide.
In an embodiment of the present invention the insecticide from the class of octopamin receptor insecticide may be selected from amitraz.
In an embodiment of the present invention the insecticide from the class of mitochondrial complex III (METI-mitochondrial electron transport inhibitors) Inhibitors insecticide may be selected from hydramethylnon, acequinocyl, fluacrypyrim, bifenazate, flometoquin.
In an embodiment of the present invention the insecticide from the class of mitochondrial complex I (METI) inhibitors insecticide may be selected from fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, tolfenpyrad, flufenerim, rotenone, fluacrypyrim, pyriminostrobin.
In an embodiment of the present invention the insecticide from the class of voltage-dependent sodium channel blockers insecticide may be selected from oxadiazines-indoxacarb, semicarbazones- metaflumizone.
In an embodiment of the present invention the insecticide from the class of inhibitors of the lipid synthesis, inhibitors of acetyl CoA carboxylase insecticide may be selected from Tetronic and tetramic acid derivatives-spirodiclofen, spiromesifen, spirotetramat, spidoxamat or spiropidion.
In an embodiment of the present invention the insecticide from the class of mitochondrial complex IV (METI) inhibitors insecticide may be selected from phosphides and cyanides.
In an embodiment of the present invention the insecticide from the class of mitochondrial complex II (METI) inhibitors insecticide may be selected from beta ketonitrile derivative-cyenopyrafen, cyflumetofen; carboxanilides-pyflubumide.
In an embodiment of the present invention the insecticide from the class of chordotonal organ modulators-undefined target insecticide may be selected from flonicamid.
In an embodiment of the present invention the insecticide from the class of metadiamides insecticide may be selected from cyproflanilide.
In an embodiment of the present invention the insecticide from the class of Isoxazolines insecticide may be selected from fluxametamide, Isocycloseram, afoxolaner, esafoxolaner, fluralaner, lotilaner, sarolaner.
In an embodiment of the present invention the insecticide from the class of Baculoviruses insecticide may be selected from granuloviruses and nucleopolyhedrosis viruses.
In an embodiment of the present invention the insecticide from the class of activated potassium channel (KCa2) modulators insecticide may be selected from acynonapyr.
In an embodiment of the present invention the insecticide from the Compounds of unknown or uncertain mode of action insecticide may be selected from azadirachtin, benzoximate, bromopropylate, benzpyrimoxan, chinomethionat, dicofol, pyridalyl, oxazosulfyl, dimpropyridaz, indazapyroxamet, acaricidal compounds-fluhexafon, cyetpyrafen, flupentiofenox, acyonapyr, trifluenfuronate; nematicidal compounds-cyclobutrifluram, fluazaindolizine, tioxazafen.
In an embodiment of the present invention, a fungicide may be selected from Nucleic acid synthesis inhibitors; Cytoskeleton and motor proteins/cell division inhibitors; Respiration inhibitors; Amino acids and protein synthesis inhibitors; Signal transduction inhibitors; Lipid or transport and membrane synthesis inhibitors; Sterol biosynthesis Inhibitors; Cell wall biosynthesis Inhibitors; Melanin synthesis in cell wall Inhibitors; Plant defence inducers; Unknow mode of action; Not classified (N); Chemicals with multisite activities (M)-multisite contact activities; Biologicals with multiple modes of action (BM); Others fungicides-Ipflufenoquin, Pyridachlometyl, Quinofumelin, Dichlobentiazox, Aminopyrifen, Dipymetitrone.
In an embodiment of the present invention the fungicide from the group of nucleic acid synthesis inhibitors fungicides may be selected from PhenylAmides group(A1)-Acylalanines-benalaxyl, benalaxyl-M (=kiralaxyl), furalaxyl, metalasxyl, metalaxyl-M (=mefenoxam)), butyrolactones(ofurace),oxazolidinones (oxadixyl),hydroxy-(2-amino-) pyrimidines; A2. bupirimate, dimethirimol, ethirimol, heteroaromatics; (A3)-isothiazolones-octhilinone, isoxazoles-hymexazole; carboxylic acids(A4)-oxolinic acid; Other-5-fluorocytosine, 5- fluoro-2-(p-tolylmethoxy)pyrimidin-4-amine, 5-fluoro-2-(4-fluorophenylmethoxy)pyrimidin-4-amine.
In an embodiment of the present invention the fungicide from the group of cytoskeleton and motor proteins/cell division inhibitors fungicides may be selected from benzimidazoles(B1)-benomyl, carbendazim, fuberidazole, thiabendazole; thiophanates(B1)-thiophanate, thiophanate-methyl; N-phenyl carbamates (B2)-diethofencarb; toluamides(B3)-zoxamide; ethylamino-thiazole-carboxamide (B3)-ethaboxam; phenylureas (B4)-pencycuron; pyridinylmethyl benzamides (B5)-fluopicolide, flufenoxadiazam, fluopimomide; aminocyanoacrylates (B6)-phenamacril; benzophenone(B6)-metrafenone; benzoylpyridine (B6)-pyriofenone.
In an embodiment of the present invention the fungicide from the group of respiration inhibitors fungicides may be selected from Pyrimidinamines(C1)-diflumetorim; pyrazole-5-carboxamide(C1)-tolfenpyrad; quinazoline(C1)-fenazaquin; SDHI (Succinate dehydrogenase inhibitors) (C2)-phenyl-benzamides(C2)-benodanil, flutolanil, mepronil; phenyl-oxo-ethyl thiophene amid(C2)-isofetamid; pyridinyl-ethyl-benzamides(C2)-fluopyram; furan-carboxamides(C2)-fenfuran; oxathin-carboxamides(C2)-carboxin, oxycarboxin, thiazole-carboxamides(C2)-thifluzamide; pyrazole-4-carboxamides(C2)-benzovindiflupyr, bixafen, fluindapyr, fluxapyroxad, furametpyr, isopyrazam, penflufen, penthiopyrad, sedaxane, flubeneteram, pyrapropoyne, inpyrfluxam, isoflucypram, pydiflumetofen; pyridine carboxamides(C2)-boscalid, pyraziflumid; QoI-fungicides (Quinone outside Inhibitors) (C3)-benzyl carbamates-pyribencarb; dihydro dioxazines-fluoxastrobin; imidazolinones-fenamidone; methoxy acetamide; mandestrobin; methoxy acrylates-azoxystrobin, coumoxystrobin, enoxastrobin, flufenoxystrobin, picoxystrobin, pyraoxystrobin; methoxy carbamates-pyraclostrobin, pyrametostrobin, triclopyricarb; oxazolidine diones-famoxadone; oximino acetamides-dimoxystrobin, fenamistrobin, metominostrobin, orysastrobin; oximino acetates-kresoxim methyl, trifloxystrobin; QiI-fungicides (Quinone inside Inhibitors) (C4)-cyano imidazole-cyazofamid; sulfamoyl triazole-amisulbrom; picolinamides-fenpicoxamid, florylpicoxamid, metarylpicoxamid; tetrazolinones-metyltetraprole; uncouplers of oxidative phosphorylation (C5)-dinitophenyl crotonates (C5)-binapacryl, meptyldinocap, dinocap, 2,6-dinitro anilines (C5)-fluazinam, inhibitors of oxidative phosphorylation,ATP synthase (C6)-tri phenyl tin compounds (C6)-fentin acetate, fentin chloride, fentin hydroxide, ATP transport(C7)-thiophene (C7)-silthiofam, Quinone outside Inhibitors,stigmatellin binding type (QoSI-C8) triazolo pyrimidylamine (C8)-ametoctradin.
In an embodiment of the present invention the fungicide from the group Amino acids and protein synthesis inhibitors fungicides may be selected from anilino-pyrimidines (D1)-cyprodinil, mepanipyrim, pyrimethanil, enopyranuronic acid antibiotic (D2)-blasticidin-S, hexopyranosyl antibiotic (D3)-kasugamycin, glucopyranosyl antibiotic (D4)-streptomycin, tetracycline antibiotic (D5)-oxytetracycline.
In an embodiment of the present invention the fungicide from the group Signal transduction inhibitors fungicides may be selected from aryloxyquinoline (E1)-quinoxyfen, quinazolinone (E1)-proquinazid, phenylpyrroles (E2)-fenpiclonil, fludioxonil, dicarboximides (E3)-chlozolinate, dimethachlone, iprodione, procymidone, vinclozolin;
In an embodiment of the present invention the fungicide from the group Lipid or transport and membrane synthesis inhibitors fungicides may be selected from dithiolanes (F2)-isoprothiolane, phosphorthiolates(F2)-edifenphos, iprobenfos (IBP), pyrazophos, aromatic hydrocarbons (F3)-biphenyl, chloroneb, dicloran, quintozene, tecnazene, tolcofos methyl, etridiazole, carbamates (F4)-iodocarb, propamocarb, prothiocarb, terpene hydrocarbons (F7)-extract from Melaleuca arternifolia (tea tree), plant oils (mixtures); eugenol, geraniol, thymol, amphoteric macrolide antifungal (F8)-natamycin (pimaricin), piperidinyl thiazole isoxazolines (F9)-oxathiapipronil, fluoxapipronil, Fluoxapiprolin-s.
In an embodiment of the present invention the fungicide from the group Sterol biosynthesis Inhibitors fungicides may be selected from imidazoles(G1)-imazalil, imidazoles(G1)-oxpoconazole, pefurazoate, procloraz, triflumizole, piperazines-triforine, pyridines-pyrifenox, pyrisoxazole, pyrimidines-fenarimo, naurimol, triazoles-azaconazole, bitertanol, bromuconazole, cyproconazole, difenoconazole, diniconazole, epoxiconazole, etaconazole, fenbuconazole, fluquinconazole, flusilazole, frutriafol, hexaconazole, imibenconazole, ipconazole, mefentrifluconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, simconazole, tebuconazole, tetraconazole, tiradimefon, tiradimenol, triticonazole, fluoxytioconazole, morpholines (G2)-aldimoprh, dedomorph, tridemorph, fenpropimorph, piperidines (G2)-fenpropidin, piperalin, spiroketal amines (G2)-spiroxamine, amino pyrazolinone (G3)-fenpyrazamine, hydroxyanilides (G3)-fenhexamid, allaylamines (G4)-naftifine, terbinafine, pyributicarb.
In an embodiment of the present invention the fungicide from the group Cell wall biosynthesis Inhibitors fungicides may be selected from peptidpyl pyrimidine (H4)-polyoxin, cinnamic acid amides (H5)-dimethomorph, flumorph, pyrimorph, mandelic acid amides (H5)-mandipropamid, valinamide carbamates (H5)-benthiavalicard, iprovalicarb, alifenalate.
In an embodiment of the present invention the fungicide from the group Melanin synthesis in cell wall Inhibitors fungicides may be selected from isobenzo furanone (I1)-fthalide, pyrrolo quinolinone-pyroquilon, triazolobenzothiazole-tricyclazole, carboxamide (I2)-diclycymet, cyclopropane carboxamide (I2)-carpropamid, propionamide(I2)-fenoxanil, trifluoroethyl carbamate (I3)-tolprocarb.
In an embodiment of the present invention the fungicide from the group Plant defence inducers fungicides may be selected from benzothiadiazole (P1)-acibenzolar-S-methyl, probenazole, thiadiazole (P3)-tiadinil, isotianil, polysaccharides (P4)-laminarin, complex mixture thanol extract (P5)- extract from Reynoutria sachalinensis (giant knowweed), bacterial Bacillus (P6)-Bacillus mycoides isolate J, cell awall of Saccharomyces erevisiae strain LAS117, phosphonates(P7)-fosetyl-AL, phosphoric acid and salts.
In an embodiment of the present invention the fungicide from the group Unknow mode of action fungicides may be selected from cyanoacetamide oxime-cymoxanil, phthalamic acid-teclofthalam, benzotirazines-triazoxide, benzene-sulfonamides-fluslfamide, pyridazinones-diclomezine, phenyl acetamide-cyflufenamid, guanindines-dodine, cyano methylene thiazolidines-flutianil, pyrimidinone hydrazones-ferimzone, flumetylsulforim, 4-quinolyl acetates-tebufloquin, tetrazolyloximes-picarbutrazox, glucopyranosyl antibiotics-validamycin.
In an embodiment of the present invention the fungicide from the group Not classified (N) fungicides may be selected from mineral oils, inorganic oils, organic oils, potassium bicarbonates, materials of biological origin.
In an embodiment of the present invention the fungicide from the group Chemicals with multisite activities (M)-multisite contact activities fungicides may be selected from - inorganic-copper (copper hydroxide, copper oxychloride, copper (II) sulphate, Bordeaux mixture, copper salicylate, cuprous oxide), sulphur, dithiocarbamates and relatives-ferbam, mancozeb, maneb, metiram, propineb, thiram, zinc thiazole, zineb, ziram, phthalimides-captan, captafol, folpet, chloronitriles (phthalonitriles)-chlorothalonil, sulfamides-dichlofluanid, tolylfluanid, bis guanidines-guazatine, iminoctadine, triazines-anilazine, quinones (anthraquinones)-dithianon, quinoxalines-chinomethionat / quinomethionate, maleimide-fluoroimide, thiocarbamate-methasulfocarb.
In an embodiment of the present invention the fungicide from the group Biologicals with multiple modes of action (BM) fungicides may be selected from polypeptide (lectin)-extract from the cotyledons of lupine plantlets (“BLAD”), Plant extract-Phenols, Sesquiterpenes, Triterpenoids, Coumarins, microbial (living microbes or extract metabilites-Trichoderma atroviride strain SC1, Trichoderma atroviride strain I-1237, Trichoderma atroviride strain LU132, Trichoderma asperellum strain T34, Gliocladium catenulatum strain J1446 , Clonostachys rosea strain CR-7 , Bacillus amyloliquefaciens strain QST713, strain FZB24, strain MBI600, strain D747, strain F727, Bacillus subtilis strain AFS032321, Pseudomonas chlororaphis strain AFS009, Streptomyces griseovirides strain K61, Streptomyces lydicus strain WYEC108, Polyoxin D zinc salt.
In an embodiment of the present invention the fungicide from the others group fungicides may be selected from Ipflufenoquin-quinoline fungicide, Pyridachlometyl-pyridazine fungicide, quinofumelin, dichlobentiazox, aminopyrifen, dipymetitrone, seboctylamine (bactericide), chloroinconazide (virucide).
In an embodiment of the present invention the plant health addditives selected from bio-stimulants, plant growth promoter/regulators and micronutrients or mixture thereof.
In an embodiment of the present invention the plant health additives from the group bio-simulants may be selected from Humic acid & salt, fulvic acid & salt, amino acid (alanine, arginine, aspartic acid, cysteine, glutamic acid, glycine, histidine, isoleucine, leucine, lysine, methionine, phenylalanine, proline, serine, threonine, tryptophan, tyrosine, valine or mixture thereof), protein hydrolysates, carboxylic acid, jasmonic acid, methyl jasmonate, chitosan, chitin, alginate, cyclodextrin, probenazole, acibenzolar-s-methyl, laminarin, seaweed extract (Ascophyllum nodosum), polyamines, silicic acid & salt-orthosilicic acid (H4Si04), salicylic acid, lactic acid, phenyl lactic acid, fumaric acid, nitrobenzene, stigmasterol, campesterol, brassinolide (homo), forchlorfenuron, triacontanol, nitrophenolate (sodium para-nitrophenolate, ortho-nitrophenolate, sodium-5-nitroguaiacolate or mixture thereof.
In an embodiment of the present invention the plant health additives from the group Plant growth promotor/regulators may be selected from Indole acetic acid, Indole butyric acid, alpha-naphthyl acetic acid, kinetin, zeatin, 6-benzylaminopurine, 6-benzyladenine, dipheylurea, thidiazuron, anisiflupurin, aviglycine, prohexadione, prohexadione calcium, trinexapac, trinexapac-ethyl, aminoethoxyvinylglycine (AVG), gibberelline, gibberellic acid, GA3, abscisic acid, chlorpropham, flumetralin, maleic hydrazide, mepiquat, mepiquat chloride, mepiquat pentaborate, chlormequat, chlormequat chloride, paclobutrazol, uniconazole-P; or mixture thereof.
In an embodiment of the present invention the plant health additives from the group Micronutrients may be selected from : zinc (zinc sulphate heptahydrate, zinc sulphate mono hydrate, Zn-EDTA, zinc oxide, zinc lactate gluconate, zinc polyflavonoid), ferrous sulphate, copper sulphate, Manganese sulphate, boron (borax-sodium tetraborate, boric acid (H3BO3), di-sodium octa borate tetra hydrate (Na2B8O13.4H2O), di-sodium tetra borate penta hydrate, anhydrous borax, ) and sulphur (elemental sulphur, bentonite sulphur, boronated sulphur or a sulphate and thiosulphate salt) or mixture thereof.
In an embodiment of the present invention the present synergistic agrochemical pesticidalc composition may be applicable bu not limited for the foliar spray and for the seed treatment.
Broflanilide is an insecticide. Broflanilide IUPAC name is 3-[ benzoyl (methyl)amino]-N-[2-bromo-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-6-(trifluoromethyl)phenyl]-2-fluorobenzamide. Broflanilide is a complex, polycyclic, organohalogen, insecticide which provides a novel mode of action. Broflanilide is not systemic in the plant and stays in the root zone where you need protection from soil insect-pests, if applied as seed treatment. Broad Spectrum Broflanilide insecticide can be applied for crop and non-crop uses to control chewing insect pests, certain thrips, plus non-crop pests like termites, ants, flies and cockroaches.
The synergistic agrochemical composition are used to protect the crops and plants from insect and fungus pests. The lists of the major crops includes genetically modified varieties or hybrid varieties or conventional varieties of GMO (Genetically Modified Organism) and Non GMO traits, hybrids and conventional varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticum aestavum), Barley (Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Oat (Avena sativa), Pearl millet (Pennisetum glaucum), Sugarcane (Saccharum officinarum), Sugarbeet (Beta vulgaris), Soybean (Glycin max), Groundnut/Peanut (Arachis hypogaea), Sunflower (Helianthus annuus), Mustard (Brassica juncea), Rape seed (Brassica napus), Sesame (Sesamum indicum), Green gram (Vigna radiata), Black gram (Vigna mungo), Chickpea (Cicer aritinum), Cowpea (Vigna unguiculata), Red gram (Cajanus cajan), French bean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotyloma uniflorum), Field pea (Pisum sativum), Cluster bean (Cyamopsis tetragonoloba), Lentils (Lens culinaris), Brinjal (Solanum melongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschus esculentus), Onion (Allium cepa L.), Tomato (Solanum lycopersicun), Potato (Solanum tuberosum), Sweet potato (Ipomoea batatas), Chilly (Capsicum annum), Bell pepper (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumis sativus), Muskmelons (Cucumis melo), Watermelon (Citrullus lanatus), Bottle gourd (Lagenaria siceraria), Bitter gourd (Momordica charantia), Radish (Raphanus sativus), Carrot (Dacus carota subsp. sativus), Turnip (Brassica rapa rapa), Apple (Melus domestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitis vinifera), Guava (Psidium guajava), Mango (Mangifera indica), Papaya (Carica papaya), Pineapple (Ananas comosus), Pomegranate (Punica granatum), Sapota (Manilkara zapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiber officinale), Cumin (Cuminum cyminum), Black Pepper (Piper nigrum), Mentha ( Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold ( Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera ( Gerbera jamesonii), Carnation (Dianthus caryophyllus).
Crops are to be understood as also including those crops which have been rendered tolerant to herbicides or classes of herbicides (e.g. ALS-, GS-, EPSPS-, PPO-, ACCase- and HPPD-inhibitors) by conventional methods of breeding or by genetic engineering. An example of a crop that has been rendered tolerant to imidazolinones, e.g. imazamox, by conventional methods of breeding is Clearfield® summer rape (canola). Examples of crops that have been rendered tolerant to herbicides by genetic engineering methods include e.g. glyphosate- and glufosinate-resistant maize varieties commercially available under the trade names RoundupReady® and LibertyLink®.
Crops are also to be understood as being those which have been rendered resistant to harmful insects by genetic engineering methods, for example Bt maize (resistant to European corn borer), Bt cotton (resistant to cotton boll weevil) and also Bt potatoes (resistant to Colorado beetle). Examples of Bt maize are the Bt 176 maize hybrids of NK® (Syngenta Seeds). The Bt toxin is a protein that is formed naturally by Bacillus thuringiensis soil bacteria. Examples of toxins, or transgenic plants able to synthesise such toxins, are described in EP-A-451 878, EP-A-374 753, WO 93/07278, WO 95/34656, WO 03/052073 and EP-A-427 529. Examples of transgenic plants comprising one or more genes that code for an insecticidal resistance and express one or more toxins are KnockOut® (maize), Yield Gard® (maize), NuCOTIN33B® (cotton), Bollgard® (cotton), NewLeaf® (potatoes), NatureGard® and Protexcta®. Plant crops or seed material thereof can be both resistant to herbicides and, at the same time, resistant to insect feeding (“stacked” transgenic events). For example, seed can have the ability to express an insecticidal Cry3 protein while at the same time being tolerant to glyphosate.
Crops are also to be understood to include those which are obtained by conventional methods of breeding or genetic engineering and contain so-called output traits (e.g. improved storage stability, higher nutritional value and improved flavour).
Other useful plants include turf grass for example in golf-courses, lawns, parks and roadsides, or grown commercially for sod, and ornamental plants such as flowers or bushes.
The synergistic combination of the present invention used to control the The major insects pests are belongs to the order Hemiptera, for example, rice leafhopper/green leaf hopper (GLH) Nephotettix nigropictus, rice brown plant hopper (BPH) Nilaparvata lugen, rice backed plant hopper (WBPH) Sogatella furcifera , Apple Mealy bug Phenococcus aceris, bean aphid Aphis fabae, black citrus aphid Toxoptera aurantii, citrus black scale Saissetia oleae, cabbage aphid Brevicoryne brassicae, Lipaphis erysimi, citrus red scale Aonidiella aurantii, yellow scale Aonidiella citrine, citrus mealybug Planococcus citri, corn leaf aphid Rhopalosiphum maidis, aphid Aphis gossypii, jassid Amrasca biguttula biguttla, mealy bug Planococcus spp. And Pseudococcus spp., cotton stainer Dysdercus suturellus, whitefly Bemisia tabaci, cowpea aphid Aphis crassivora, grain aphid Sitobion avenae, golden glow aphid Uroleucon spp., grape mealybug Pseudococcus maritimus, green peach aphid Myzus persicae, greenhouse whitefly Trialeurodes vaporariorum, papaya mealy bug Pracoccus marginatus, pea aphid Acyrthosiphon pisum, sugarcane mealybug Saccharicoccus sacchari, potato aphid Myzus persicae, potato leaf hopper Empoasca fabae, cotton whitefly Bemisia tabaci, tarnished plant bug Lygus lineolaris, wooly apple aphid Eriosoma lanigerum, mango hopper Amritodus atkinsoni, Idioscopus spp. ; order Lepidoptera, army worm Mythimna unipuncta, asiatic rice borer Chilo suppressalis, bean pod borer Maruca vitrata, beet armyworm Spodoptera exigua, black cutworm Agrotis ipsilon, bollworm Helicoverpa armigera , cabbage looper Trichoplusia ni, codling moth Cydia pomonella, croton caterpillar Achea janata, diamond backmoth Plutella xylostella, cabbage worm Pieris rapae, pink bollworm Pectinophora gossypiella, sugarcane borer Diatraea saccharalis, sugarcane early shoot borer Chilo infuscatellus tobacco budworm Heliothis virescens, tomato fruitworm Helicoverpa zea, velvet bean caterpillar Anticarsia gemmatalis, yellow stem borer Scirpophaga incertulas, spotted bollworm Earias vittella, rice leaffolder Cnaphalocrocis medinalis, pink stem borer Sesamia spp., tobacco leafeating caterpillar Spodoptera litura; brinjal fruit and shoot borer Leucinodes orbonalis, bean pod borer Maruca vitrata, Maruca testulalis, armyworm Mythimna separata, cotton pinkbollworm Pectinophora gossypiella, citrus leafminer Phyllocnistis citrella, cabbage butterfly Pieris bras-sicae, diamond backmoth Plutella xylostella, paddy stem borer Scirpophaga excerptallis, Scirpophaga incertulas, Scirpophaga innotata, wheat stem borer Sesamia inferens, Sitotroga cerealella, Spilosoma obliqua, fall armyworm Spodoptera frugiperda, Spodoptera littoralis, Spodoptera litura, Trichoplusia ni, Tryporyza nivella, Tryporyza incertulas, Tuta absoluta.
The synergistic combination of the present invention used to control the insects-pests from the the order Coleoptera, for example, apple twig borer Amphicerus spp., corn root worm Diabrotica virgifera, cucumber beetle diabrotica balteata, boll weevil Anthonomus grandis, grape flea beetle Altica chalybea, grape root worm Fidia viticola, grape trunk borer Clytoleptus albofasciatus, radish flea beetle Phyllotreta armoraciae, maize weevil Sitophilus zeamais, northern corn rootworm Diabrotica barberi, rice water weevil Lissorhoptrus oryzophilus, Anthonomus grandis, Bruchus lentis, Diabrotica semipunctata, Diabrotica virgifera, Dicladispa armigera, Epila-chna varivestis, various species of white grubs are Holotrichia bicolor, Holotrichia consanguinea, Holotrichia serrata, Leptinotarsa decemlineata, Phyllotreta chrysocephala, Popillia japonica etc; from the order Orthoptera, for example, Gryllotalpa spp., Locusta spp., and Schistocerca is spp.; from the order Thysanoptera, for example, Frankliniella spp., Thrips palmi, Thrips tabaci and Scirtothrips dorsalis; termites (Isoptera), e.g. Calotermes flavicollis, Coptotermes formosanus, Heterotermes aureus, Leucotermes flavipes, Microtermes obesi, Odontotermes obesus, Reticulitermes flavipes, Termes natalensis; from the order Heteroptera, for example, Dysdercus spp., Leptocorisa spp., from the order Hymenoptera, for example, Solenopsis spp. ; from the order Diptera, for example, Antherigona soccata, Dacus spp., Liriomyza spp., Melanagromyza spp., from the order Acarina, for example, Aceria mangiferae, Brevipalpus spp., Eriophyes spp., Oligonychus mangiferus, Oligonychus punicae, Panonychus citri, Panonychus ulmi, Polyphagotarsonemus latus, Tarsonemus spp., Tetranychus urticae, Tetranychus cinnabarinus; plant parasitic nematodes such as root-knot nematodes, Meloidogyne incognita, Meloidogyne javanica and other Meloidogyne species; cyst nematodes, Globodera rostochiensis, Globodera pallida, Globodera tabacum and other Globodera species, Heterodera avenae, Heterodera glycines, Heterodera schachtii, Heterodera trifolii, and other Heterodera species; seed gall nematodes, Anguina funesta, Anguina tritici and other Anguina species; stem and foliar nematodes, Aphelenchoides besseyi, Aphelen-choides fragariae, Aphelenchoides ritzemabosi and other Aphelenchoides species; sting nematodes, Belonolaimus longicaudatus and other Belonolaimus species; pine nematodes, Bursaphelenchus xylophilus and other Bursaphelenchus species; ring ne-matodes, Criconema species, Criconemella species, Criconemoides species, and Me-socriconema species; stem and bulb nematodes, Ditylenchus destructor, Ditylenchus dipsaci, Ditylenchus myceliophagus and other Ditylenchus species; awl nematodes, Dolichodorus species; spiral nematodes, Helicotylenchus dihystera, Helicotylenchus multicinctus and other Helicotylenchus species, Rotylenchus robustus and other Roty-lenchus species; sheath nematodes, Hemicycliophora species and Hemicriconemoides species; Hirshmanniella species; lance nematodes, Hoplolaimus columbus, Hoplolai-mus galeatus and other Hoplolaimus species; false root-knot nematodes, Nacobbus aberrans and other Nacobbus species; needle nematodes, Longidorus elongates and other Longidorus species; pin nematodes, Paratylenchus species; lesion nematodes, Pratylenchus brachyurus, Pratylenchus coffeae, Pratylenchus curvitatus, Pratylenchus goodeyi, Pratylencus neglectus, Pratylenchus penetrans, Pratylenchus scribneri, Pratylenchus vulnus, Pratylenchus zeae and other Pratylenchus species; Radinaphelenchus cocophilus and other Radinaphelenchus species; burrowing nematodes, Radopholus similis and other Radopholus species; reniform nematodes, Rotylenchulus reniformis and other Rotylenchulus species; Scutellonema species; stubby root nematodes, Tri-chodorus primitivus and other Trichodorus species; Paratrichodorus minor and other Paratrichodorus species; stunt nematodes, Tylenchorhynchus claytoni, Tylenchorhyn-chus dubius and other Tylenchorhynchus species and Merlinius species; citrus nematodes, Tylenchulus semipenetrans and other Tylenchulus species; dagger nematodes, Xiphinema americanum, Xiphinema index, Xiphinema diversicaudatum and other Xi-phinema species; and other plant parasitic nematode species.
The compositions according to the invention have very good fungicidal properties and can be employed for controlling phytopathogenic fungi such as Ascomycetes, Basidiomycetes, Chytridiomycetes, Deuteromycetes, Oomycetes, Plasmodiophoromycetes, Zygomycetes, and the like.
Examples which may be mentioned, but not by limitation, are some pathogens of fungal diseases which come under the above generic terms: Diseases caused by pathogens causing powdery mildew such as, for example, Blumeria species such as, for example, Blumeria graminis; Podosphaera species such as, for example, Podosphaera leucotricha; Oidium species such as, for example Oidium mangiferae, Sphaerotheca species such as, for example, Sphaerotheca fuliginea; Uncinula species such as, for example, Uncinula necator; Leveillula species such as, for example Leveillula taurica, Erysiphe species such as for example Erysiphe polygoni.
Diseases caused by pathogens of rust diseases such as, for example, Gymnosporangium species such as, for example, Gymnosporangium sabinae, Hemileia species such as, for example, Hemileia vastatrix; Phakopsora species such as, for example, Phakopsora pachyrhizi and Phakopsora meibomiae; Puccinia species such as, for example, Puccinia graminis, Puccinia recondita or Puccinia triticina, Puccinia striiformis; Uromyces species such as, for example, Uromyces phaseoli;
Diseases caused by pathogens of smut diseases such as, for example, Sporisorium species such as , for example, Sporisorium scitamineum; Ustilago species such as, for example Ustilago maydis, Tilletia species such as for example Tilletia tritici, Ustilaginoidea species such as , for example Ustilaginoidea virens.
Diseases caused by pathogens of ergot diseases such as, for example Claviceps species, Claviceps purpurea; diseases caused by pathogens from the group of the Oomycetes such as, for example, Bremia species such as, for example, Bremia lactucae; Peronospora species such as, for example, Peronospora pisi or P. brassicae; Phytophthora species such as, for example, Phytophthora infestans; Plasmopara species such as, for example, Plasmopara viticola; Pseudoperonospora species such as, for example, Pseudoperonospora humuli or Pseudoperonospora cubensis; Pythium species such as, for example, Pythium ultimum; leaf spot diseases and leaf wilt caused by, for example, Alternaria species such as, for example, Alternaria solani, Alternaria alternata, Alternaria porii; Cercospora species such as, for example, Cercospora arachidicola; Cladiosporum species such as, for example, Cladiosporium cucumerinum; Cochliobolus species such as, for example, Cochliobolus sativus (conidial form: Drechslera, syn: Helminthosporium);
Colletotrichum species such as, for example, Colletotrichum capsici; Cycloconium species such as, for example, Cycloconium oleaginum; Diaporthe species such as, for example, Diaporthe citri;
Elsinoe species such as, for example, Elsinoe fawcettii; Gloeosporium species such as, for example, Gloeosporium laeticolor; Glomerella species such as, for example, Glomerella cingulata; Guignardia species such as, for example, Guignardia bidwelli;
Leptosphaeria species such as, for example, Leptosphaeria maculans; Magnaporthe species such as, for example, Magnaporthe grisea;
Mycosphaerella species such as, for example, Mycosphaerella graminicola; Phaeosphaeria species such as, for example, Phaeosphaeria nodorum; Pyrenophora species such as, for example, Pyrenophora teres;
Ramularia species such as, for example, Ramularia collo-cygni; Rhynchosporium species such as, for example, Rhynchosporium secalis; Septoria species such as, for example, Septoria apii;
Typhula species such as, for example, Typhula incarnata; Venturia species such as, for example, Venturia inaequalis; root and stalk diseases, caused by, for example, Corticium species such as, for example, Corticium graminearum; Fusarium species such as, for example, Fusarium oxysporum;
Gaeumannomyces species such as, for example, Gaeumannomyces graminis; Rhizoctonia species such as, for example, Rhizoctonia solani; Tapesia species such as, for example, Tapesia acuformis;
Thielaviopsis species such as, for example, Thielaviopsis basicola; ear and panicle diseases (including maize cobs), caused by, for example, Alternaria species such as, for example, Alternaria spp.;
Aspergillus species such as, for example, Aspergillus flavus; Cladosporium species such as, for example, Cladosporium spp.; Claviceps species such as, for example, Claviceps purpurea;
Fusarium species such as, for example, Fusarium culmorum; Gibberella species such as, for example, Gibberella zeae; Monographella species such as, for example, Monographella nivalis;
diseases caused by smuts such as, for example, Sphacelotheca species such as, for example, Sphacelotheca reiliana; Tilletia species such as, for example, Tilletia caries; Urocystis species such as, for example, Urocystis occulta; Ustilago species such as, for example, Ustilago nuda; fruit rot caused by, for example, Aspergillus species such as, for example, Aspergillus flavus;
Botrytis species such as, for example, Botrytis cinerea; Penicillium species such as, for example, Penicillium expansum; Sclerotinia species such as, for example, Sclerotinia sclerotiorum;
Verticilium species such as, for example, Verticilium alboatrum; seed- and soil-borne rots and wilts, and seedling diseases, caused by, for example, Fusarium species such as, for example, Fusarium culmorum; Phytophthora species such as, for example, Phytophthora cactorum; Pythium species such as, for example, Pythium ultimum; Rhizoctonia species such as, for example, Rhizoctonia solani;
Sclerotium species such as, for example, Sclerotium rolfsii; cankers, galls and witches' broom diseases, caused by, for example, Nectria species such as, for example, Nectria galligena; wilts caused by, for example, Monilinia species such as, for example, Monilinia laxa; deformations of leaves, flowers and fruits, caused by, for example, Taphrina species such as, for example, Taphrina deformans; degenerative diseases of woody species, caused by, for example, Esca species such as, for example, Phaemoniella clamydospora; flower and seed diseases, caused by, for example, Botrytis species such as, for example, Botrytis cinerea; diseases of plant tubers caused by, for example, Rhizoctonia species such as, for example, Rhizoctonia solani; diseases caused by bacterial pathogens such as, for example, Xanthomonas species such as, for example, Xanthomonas campestris pv. oryzae; Pseudomonas species such as, for example, Pseudomonas syringae pv. lachrymans; Erwinia species such as, for example, Erwinia amylovora.
Formulation of the present invention can be in any of the formulations selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR), Water dispersible powder for slurry treatment (WS), solution for seed treatment (LS), emulsions for seed treatment (ES), Flowable suspension/concentrate for seed treatment (FS), aqueous capsule suspension (CS), powder for dry seed treatment (DS).
The present invention relates to synergistic agrochemical composition comprising of bioactive amounts of (A) Broflanilide is in range of 0.01% to 20% w/w of the composition; (B) at least one insecticide selected from diamide group of insecticides is in range of 0.01% to 30% w/w of the composition; (C) at least one more compound selected from insecticides, fungicides, plant health additives are in range of 0.001% to 50% w/w of the composition.
The composition of the present invention in addition to bioactive amounts of active ingredients further comprises inactive excipients including but not limited to Super Wetting-spreading-penetrating agent, solvents, dispersant or dispersing agent, anti-freezing agent, emulsifying agent, anti-foam agent, preservatives and buffering agent.
A wetting agent is a substance that when added to a liquid increases the spreading or penetration power of the liquid by reducing the interfacial tension between the liquid and the surface on which it is spreading. Wetting agents are used for two main functions in agrochemical formulations: during processing and manufacture to increase the rate of wetting of powders in water to make concentrates for soluble liquids or suspension concentrates; and during mixing of a product with water in a spray tank or other vessel to reduce the wetting time of wettable powders and to improve the penetration of water into water-dispersible granules.
Examples wetting-spreading-penetrating agent used herein for OD (Oil Dispersion) formulation include but not limited to Organosilicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof etc.
Examples wetting agent used herein for OD (Oil Dispersion) formulation include but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate.
Examples of dispersants or dispersing agent used herein for Oil dispersion (OD) formulation includes but not limited to alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Emulsifying agent used herein for the Oil dispersion (OD) formulation includes but not limited to castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkyl ammonium salts of alkylbenzene sulphonate, alkyl sulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylenesorbitan monolaurate, Polyoxyethylene sorbitol hexaoleate.
Examples of Antifoaming agent used herein for Oil dispersion (OD) formulation include but not limited to silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethylsiloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane.
Examples of Anti-freezing agent used herein for Oil dispersion (OD) formulation include but not limited to ethylene glycol, propane diols, glycerine or the urea, glycol (Monoethylene glycol, Diethylene glycol, Polypropylene glycol, Polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride etc.
Preservative used herein for the Oil dispersion (OD) formulation include but not limited to 1,2-benzisothiazolin-3(2H)-one, sodium salt, sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, formaldehyde, sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one.
Example of solvents used herein for the Oil dispersion (OD) formulation includes but not limited to vegetable oil (plant, seed or tree) or its alkylated or ethoxylated or esterified. The alkylated vegetable oil may be methylated vegetable oil or ethylated vegetable oil. The vegetable oils include olive oil, kapok oil, castor oil, papaya oil, camellia oil, sesame oil, corn oil, rice bran oil, cotton seed oil, soybean oil, groundnut oil, rapeseed-mustard oil, linseed oil, tung oil, sunflower oil, safflower oil, coconut oil. The alkyl ester of vegetable oils includes methyl ester, ethyl ester, propyl ester or butyl ester of vegetable oils. Some of the examples are methylated seed oil, polyalkyleneoxide modified polydimethylsiloxane alkylphenol ethoxylate, rapeseed oil methyl ester, rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, soybean oil methyl ester, soybean oil ethyl ester, soybean oil propyl ester, soybean oil butyl ester, castor oil methyl ester, castor oil ethyl ester, castor oil propyl ester, castor oil butyl ester, cotton seed oil methyl ester, cotton seed oil ethyl ester, cotton seed oil butyl ester, cotton seed oil propyl ester, tall oil fatty acids esters-tallow methyl ester, tallow ethyl ester, tallow propyl ester, bio-diesel, mineral oil (aromatic solvents, isoparaffin, base solvent), fatty acid amides (e.g. C1 -C3 amines, alkylamines or alkanolamines with C6–C18 carboxylic acids), fatty acids, alkyl esters of fatty acids, methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols. The above oil based carrier/diluting agents may be used as solo or mixture of two or more if desired.
Cosolvent used herein for the Oil dispersion (OD) formulation includes but not limited to Cyclohexanone, Acetophenone, NMP, Dimethyl sulfoxide, Benzyl alcohol, Butanol, N-octanol, N-Propanol, 2-ethyl hexanol, Tetrahydro furfuryl alcohol, Isophorone, Fatty acid dimethyl amide, 2-hexylethyl lactate, Propylene carbonate.
Examples of Wetting agent used herein for Suspension Concentrate (SC) formulation include but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, polyalkoxylated butyl ether, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate, organosilicons surfactants (as a wetting-spreading-penetrating agent) includes trisiloxane ethoxylate, Methylated seed oil, polyalkyleneoxide modified trisiloxane, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, modified form includes polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, polyalkyleneoxide modified trisiloxane, polyalkyleneoxide modified polydimethylsiloxane, trisiloxane ethoxylate, polyoxyethylene methyl polysiloxane, polyether polymethyl siloxane copolymer, polyether modified polysiloxane; may or may not be in modified form, may be liquid or powder form or mixture thereof etc.;
Examples of Dispersing agent used herein for Suspension Concentrate (SC) formulation include but not limited to Naphthalene sulfonic acid, sodium salt condensated with formaldehyde, alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium polycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethylene oxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycol ether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonylphenol polyglycol ether with 9-10 moles ethylene oxide;
Examples of Suspending agent used herein for Suspension Concentrate (SC) formulation include but not limited to aluminum magnesium silicate, bentonite clay, silica, attapulgite clay;
Examples of Antifoaming agent used herein for Suspension Concentrate (SC) formulation include but not limited to silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane etc;
Examples of Anti-freezing agent used herein for Suspension Concentrate (SC) formulation include but not limited to ethylene glycol, propane diols, glycerin or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerin, urea, magnesium sulfate heptahydrate, sodium chloride etc;
Examples of Preservatives used herein for Suspension Concentrate (SC) formulation include but not limited to 1,2-benzisothiazolin-3(2H)-one, sodium salt, sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, formaldehyde, sodium o-phenyl phenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one
Examples of Thickeners used herein for Suspension Concentrate (SC) formulation include but not limited to xanthan gum, PVK, carboxymethyl celluloses, polyvinyl alcohols, gelatin, sodium carboxymethylcellulose, hydroxyethyl cellulose, sodium polyacrylate, modified starch, acacia gum;
Examples of Humectant used herein for Suspension Concentrate (SC) formulation include but not limited to urea, humic acid, glycerol, lactose.
Examples of Solvent used herein for Suspo-Emulsion (SE) formulation include but not limited to water, water soluble alcohols and dihydroxy alcohol ethers. Water soluble alcohol or lower alcohol (1-4 carbon atoms) includes-methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol. Macromolecular alcohol includes polyethylene glycol, sorbitol, glucitol etc., dihydroxy alcohol ethers includes dihydroxy alcohol alkyl ether or dihydroxy alcohol aryl ethers. The examples of dihydroxy alcohol alkyl ether include ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether, etc. The examples of dihydroxy alcohol aryl ethers include ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl ether, and the like. Any of the mentioned solvent can be used either alone or in combinations thereof. Hyrdocarbons includes n-pentane, hexane(s), cyclohexane, methylcyclohexane, heptane, isooctane, benzene, toluene, xylene(s), isophorone and ester solvents such as methyloleate, dimethylamide and morpholineamide derivatives of C6-C16 fatty acids, and mono-alkylene carbonates such as ethylene carbonate, propylene carbonate and butylene carbonates, dimethylsulfoxide (DMSO), 2-ethylhexanol and n-butanol, n-alkylpyrrolidones, fatty acid dimethyl esters, fatty acid esters, dibasic esters, aromatic hydrocarbons and/or aliphatic hydrocarbons, one or more dimethylamides, such as C8-dimethylamide, C10-dimethylamide, C12-dimethylamide, ethylene glycol, propylene glycol, polyalkylene glycols, aromatic hydrocarbons, methylpyrrolidinone (NMP); dimethylformamide (DMF); dimethylisosorbide (DMI); isophorone; acetophenone; 1,3-dimethyl-2-imidazolidonone; lactate esters; dimethyl and diethylcarbonates; alcohols including methanol; ethanol; iso-propanol; n-propanol; n-butanol; iso-butanol; and tert-butanol; Methyl L-lactate, 2-Ethylhexyl L-lactate, Ethyl L-lactate, n-Butyl L-lactate, Octyl phenol ethoxylates.
Examples of Emulsifier used herein for Suspo-Emulsion (SE) formulation include but not limited to salts of dodecylbenzene sulphonate, e.g. Ca-salts or amine salts, and sulphonates of other C11-C16 alkylbenzenes, alkylether sulphates, alkylphenoletherphosphates and ester phosphates; non-ionic surfactants such as alkoxylated alcohols and alkylphenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid esters, e.g. of sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; and catanionic emulsifiers such as a cationic amine, optionally in combination with an alkylsulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkylphenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol (tristyrlphenol with 16 moles EO), tristyrylphenol-polyglycolether-phosphate, fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkylbenzenes in the range C11-C16 and salts thereof; alkylether sulphates; alkyletherphosphates; alkylphenoletherphosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenol; or a catanionic system, wherein a cationic amine is present in combination with an alkylsulphonate, an alkylethersulphonate, an ether sulphate, or an ether phosphate such as an alkyletherphosphate, nonylphenol polyethoxy ethanols, castor oil polyglycol ethers, polyadducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol.
Examples of Stabilizer used herein for Suspo-Emulsion (SE) formulation include but not limited to butylated hydroxytoluene (BHT) and epoxidized soybean oil (ESBO), Epichlorhydrin.
Examples of Anti-freezing agent used herein for Suspo-Emulsion (SE) formulation include but not limited to ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride etc;
Examples of Antifoaming agent used herein for Suspo-Emulsion (SE) formulation include but not limited to silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethylsiloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane etc.
Examples of Suspending agent used herein for Suspo-Emulsion (SE) formulation include but not limited to aluminum magnesium silicate, bentonite clay, silica, silicone dioxide, attapulgite clay.
Examples of Wetting agent used herein for Suspo-Emulsion (SE) formulation include but not limited to Ethylene oxide/propylene oxide block copolymer, Polyarylphenyl ether phosphate, Ethoxylated Fatty Alcohol, Sodium dioctyl sulfosuccinate, sodium lauryl sulphate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, Alkyl naphthalene sulfonate, Octyl phenol ethoxylate, alkyl phenol ethoxylate;
Examples of Wetting-spreading-penetrating agent used herein for Suspo-Emulsion (SE) formulation include but not limited to Organosilicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, heptamethyl trisiloxane ethoxylate, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof etc;
Examples of Preservatives used herein for Suspo-Emulsion (SE) formulation include but not limited to propionic acid and its sodium salt, sorbic acid and its sodium or potassium salt, benzoic acid and its sodium salt, p-hydroxy benzoic acid sodium salt; methyl p-hydroxy benzoate; and biocide such as sodium benzoate, 1,2-benzisothiazoline-3-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2- methyl-4-isothiazolin-3-one, potassium sorbate, para hydroxy benzoates or mixtures thereof.
Examples of Thickeners used herein for Suspo-Emulsion (SE) formulation include but not limited to: Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers. It is possible to produce suspension concentrate formulations using clays and silicas. Examples of these types of materials, include, but are limited to, montmorillonite, e.g. bentonite; magnesium aluminium silicate; and attapulgite. Water-soluble polysaccharides have been used as thickening-gelling agents for many years. The types of polysaccharides most commonly used are natural extracts of seeds and 15 seaweeds are synthetic derivatives of cellulose or mixtures thereof. Examples of these types of materials include, but are not limited to, guar gum; locust bean gum; carrageenam; xanthan gum; alginates; methyl cellulose; sodium carboxymethyl cellulose (SCMC); hydroxyethyl cellulose (HEC) or mixtures thereof. Other types of anti-settling agents are based on modified starches, polyacrylates, polyvinyl 20 alcohol and polyethylene oxide or mixtures.
Examples of Dispersing agent used herein for Suspo-Emulsion (SE) formulation include but not limited to Sodium salt of polycarboxylate, Acrylic graft copolymer, polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylic polymers, acrylic graft copolymer, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol, vinylacetate and vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins and define copolymers and mixtures thereof. Examples of preferred polymers are acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these. Polymers that are biodegradable are also useful in the present invention. As used herein, a polymer is biodegradable if is not water soluble, but is degraded over a period of several weeks when placed in an application environment. Examples of biodegradable polymers that are useful in the present invention include biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof. The examples of dispersing agents are alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium salt of alkyl naphthalene sulfonate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Examples of Buffering agent used herein for Suspo-Emulsion (SE) formulation include but not limited to as used herein is selected from group consisting of calcium hydroxyapatite, Potassium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.
Examples of Humectant used herein for Suspo-Emulsion (SE) formulation include but not limited to urea, humic acid, glycerol, lactose.
Examples of Dispersing agents used herein for WG (Wettable Granule) formulation include but not limited to sodium polycarboxylate (sodium polyacrylate), naphthalene sulfonic acid, sodium salt condensates with formaldehyde, polyalcoxylated alkylphenol, naphthalene sulfonic acid formaldehyde condensate, methyl naphthalene-formaldehyde-condensate sodium salt, naphthalene condensates, lignosulfonates, calcium lignosulfonate, lignin sulfonate sodium salt, alkyl naphthalene sulfonate, sodium salt. The preferred dispersing agent is alkyl naphthalene sulfonate. It provides an excellent wetting, dispersing, hydrotroping and medium to low foaming. It offers acid and base stability, hard water tolerance and high temperature stability.
Examples of Wetting agents used herein for WG (Wettable Granule) formulation include but not limited to sodium N-methyl-N-oleoyl taurate, alkylated naphthalene sulfonate, sodium salt, mixture of isomers of dibutyl naphthalene sulphonic acid sodium salt, sodium di-isopropyl naphthalene sulphonate, sodium Lauryl sulfate, dioctyl sulfate, alkyl naphthalene sulfonates, phosphate esters, sulphosuccinates and non-ionic such as tridecyl alcohol ethoxylate, alkyl or alkaryl sulfonates such as alkylbenzene sulfonates, alpha olefin sulfonate and alkyl naphthalene sulfonates, ethoxylated or non-ethoxylated alkyl or alkaryl carboxylates, alkyl or alkaryl phosphate esters, alkyl polysaccharide, di or mono alkyl sulfosuccinate derivatives, alpha olefin sulfonates, alkyl naphthalene sulfonates, dialkyl sulphosuccinates, butyl, dibutyl, isopropyl and di-isopropyl naphthalene sulfonate salts, C12 alkyl benzene sulfonate or C10-C16 alkyl benzene sulfonate, organosilicons surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, trisiloxane heptamethyl, Polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof etc.
Examples of Antifoaming agent used herein for WG (Wettable Granule) formulation include but not limited to polydimethylsiloxane.
Examples of Carrier used herein for WG (Wettable Granule) formulation include but not limited to china clay, silica, lactose anhydrous, ammonium sulfate, sodium sulfate anhydrous, corn starch, urea, EDTA, urea formaldehyde resin, diatomaceous earth, kaolin, bentonite, kieselguhr, fuller's earth, attapulgite clay, bole, loess, talc, chalk, dolomite, limestone, lime, calcium carbonate, powdered magnesia, magnesium oxide, magnesium sulphate, sodium chloride, gypsum, calcium sulphate, pyrophyllite, silicates and silica gels; fertilizers such as, for example, ammonium sulphate, ammonium phosphate, ammonium nitrate and urea; natural products of vegetable origin such as, for example, grain meals and flours, bark meals, wood meals, nutshell meals and cellulosic powders; and synthetic polymeric materials such as, for example, ground or powdered plastics and resins, bentonites, zeolites, titanium dioxide, iron oxides and hydroxides, aluminium oxides and hydroxides, or organic materials such as bagasse, charcoal, or synthetic organic polymers.
Examples of Humectant used herein for WG (Wettable Granule) formulation include but not limited to humic acid, glycerol, lactose, Sodium sulphate anhydrous.
While the foregoing written description of the invention enables one of ordinary skill to make and use what is considered presently to be the best mode thereof, those of ordinary skill will understand and appreciate the existence of variations, combinations, and equivalents of the specific embodiment, method, and examples herein. The invention should therefore not be limited by the above described embodiment, method, and examples, but by all embodiments and methods within the scope and spirit of the invention. The invention shall now be described with reference to the following specific examples. It should be noted that the example(s) appended below illustrate rather than limit the invention, and that those skilled in the art will be able to design many alternative embodiments without departing from the scope of the present invention.
These and other aspects of the invention may become more apparent from the examples set forth herein below. These examples are provided merely as illustrations of the invention and are not intended to be construed as a limitation thereof.
EXAMPLE 1:
Broflanilide 1.2%+Chlorantraniliprole 1.8%+Tolfenpyrad 10% SC
Chemical composition Percent (w/w)
Broflanilide a.i. 1.20
Chlorantraniliprole a.i. 1.80
Tolfenpyrad a.i. 10.00
Methylated seed oil, polyalkyleneoxide modified trisiloxane (super wetting-spreading-penetrating agent) 5.00
Tristyryl phenol ethoxylate phosphate esters (dispersing agent I) 3.50
Sodium salt of polycarboxylate (dispersing agent II) 1.50
Aluminum magnesium silicate (suspending agent) 0.50
Polydimethylsiloxane (anti foaming agent) 0.30
sodium benzoate (preservative) 0.15
Polypropylene glycol (anti freezing agent) 5.00
Xanthan gum (thickner) 0.15
Diluent water 57.35
Total 100.00
Active ingredients on the basis of 100% purity.
Storage stability- Broflanilide 1.2%+Chlorantraniliprole 1.8%+Tolfenpyrad 10% SC
Laboratory storage stability for 14 days
Parameters Specification (in house) Initial Stability at 54±2 0C Stability at 0±2 0C
Broflanilide a.i. 1.14 to 1.32 1.30 1.25 1.3
Chlorantraniliprole a.i. 1.71 to 1.98 1.85 1.81 1.85
Tolfenpyrad a.i. 9.50 to 10.50 10.25 10.18 10.24
Broflanilide suspensibility (%) 80 98.75 98.30 98.50
Chlorantraniliprole suspensibility (%) 80 98.95 98.50 98.60
Tolfenpyrad suspensibility (%) 80 98.70 98.10 98.65
pH range (1% aq. Suspension) 5.0 to 7.0 6.50 6.50 6.50
Pourability (%) 95 98.20 98.00 97.60
Specific gravity 1.00-1.10 1.05 1.05 1.05
Viscosity at spindle no.62,20 rpm 350-800 cps 540 555 550
Particle size (micron) D50<3, D90<10 2.1,8.4 2.2,8.5 2.2,8.5
Persistent foam ml (after 1 minute) max. 60 nil nil nil
Room temperature storage stability up to 12 months
Parameters Specification (in house) Initial 1 month 6 month 12 month
Broflanilide a.i. 1.14 to 1.32 1.30 1.30 1.3 1.3
Chlorantraniliprole a.i. 1.71 to 1.98 1.85 1.85 1.85 1.85
Tolfenpyrad a.i. 9.50 to 10.50 10.25 10.25 10.25 10.24
Broflanilide suspensibility (%) 80 98.75 98.75 98.50 98.30
Chlorantraniliprole suspensibility (%) 80 98.95 98.95 98.60 98.50
Tolfenpyrad suspensibility (%) 80 98.70 98.70 98.65 98.10
pH range (1% aq. Suspension) 5.0 to 7.0 6.50 6.50 6.50 6.50
Pourability (%) 95 98.20 98.20 97.60 98.00
Specific gravity 1.00-1.10 1.05 1.05 1.05 1.05
Viscosity at spindle no. 62, 20 rpm 350-800 cps 540 540 540 550
Particle size (micron) D50<3, D90<10 2.1,8.4 2.1,8.4 2.2,8.5 2.2,8.5
Persistent foam in ml (after 1 minute) max. 60 nil nil nil nil

The composition of Broflanilide 1.2%+Chlorantraniliprole 1.8%+Tolfenpyrad 10% SC meets the all in-house specifications for storage stability studies in laboratory (at 54±2 C & At 0±2 C for 14 days) and room temperature (for 12 months).
Manufacturing process for 100 kg batch of Broflanilide 1.2%+Chlorantraniliprole 1.8%+Tolfenpyrad 10% SC
Step 1: 2% Gum Solution: Charge Xanthan gum (2.0 kg) and sodium benzoate (2.0 kg) into 96.0 kg water and homogenize. It should be made 12-18 hour prior to use
Step 2: Charge DM water (49.85 kg) and 1,2-propylene glycol (5 kg) into designated vessel and ix thoroughly.
Step 3: Add Sodium salt of polycarboxylate (1.5 kg), Tristyryl phenol ethoxylate phosphate esters (3.5 kg) and Aluminum magnesium silicate (0.5 kg) into the vessel having water and homogenise the contents for 45 – 60 minutes using high shear homogeniser.
Step 4: Then add Broflanilida technical (1.2 kg), Chlorantraniliprole technical (1.80 kg) and Tolfenpyrad technical (10.0 kg) to this premix slowly and homogenised to get uniform slurry ready for grinding.
Step 5: Before grinding half the quantity of Polydimethylsiloxane (0.15 kg) was added and then material was subjected to grinding in Dyno mill till desired particle size is achieved.
Step 6: Add remaining Polydimethyl siloxane (0.15 kg) antifoam was added after grinding process completes and before sampling for in process analysis.
Step 7: Finally add 7.5 kg of 2% Xanthum gum solution and 5.0 kg of Methylated seed oil, polyalkyleneoxide modified trisiloxaneto this formulation and homogenized for 30 minutes.
Step 8: Now send this final formulation to QC for quality check.

EXAMPLE 2:
Composition of Broflanilide 2%+Cyantraniliprole 8%+Abamectin 1.4% SC
Chemical composition Percent (w/w)
Broflanilide a.i. 2.00
Cyantraniliprole a.i. 8.00
Abamectin a.i. 1.40
Methylated seed oil, polyalkyleneoxide modified trisiloxane (super wetting-spreading-penetrating agent) 5.00
Ethylene-propylene oxide block copolymer (dispersing agent I) 4.75
Sodium naphthalene sulphonate formaldehyde condensates (dispersing agent II) 1.25
Aluminum magnesium silicate (suspending agent) 0.50
Polydimethylsiloxane (anti foaming agent) 0.30
sodium benzoate (preservative) 0.20
Polypropylene glycol (anti freezing agent) 5.00
Xanthan gum (thickner) 0.20
Diluent water 65.07
Total 100.00
Active ingredients on the basis of 100% purity.
Storage stability- Broflanilide 2%+Cyantraniliprole 8%+Abamectin 1.4% SC
Laboratory storage stability for 14 days
Parameters Specification (in house) Initial Stability at 54±2 0C Stability at 0±2 0C
Broflanilide a.i. 1.90 to 2.20 2.25 2.20 2.25
Cyantraniliprole a.i. 7.60 to 8.80 8.50 8.35 8.49
Abamectin a.i. 1.33 to 1.54 1.50 1.41 1.5
Broflanilide suspensibility (%) 80 98.60 98.10 98.50
Cyantraniliprole suspensibility (%) 80 98.50 98.30 98.50
Abamectin suspensibility (%) 80 98.70 98.20 98.45
pH range (1% aq. Suspension) 4.0 to 6.0 5.00 5.00 5.00
Pourability (%) 95 98.20 98.00 98.10
Specific gravity 1.00 -1.10 1.05 1.05 1.05
Viscosity at spindle no.62,20 rpm 350-800 cps 530 550 550
Particle size (micron) D50<3, D90<10 2.1,8.5 2.1,8.7 2.1,8.7
Persistent foam ml (after 1 minute) max. 60 nil nil nil

Room temperature storage stability up to 12 months
Parameters Specification (in house) Initial 1 month 6 month 12 month
Broflanilide a.i. 1.90 to 2.20 2.25 2.25 2.25 2.24
Cyantraniliprole a.i. 7.60 to 8.80 8.50 8.50 8.50 8.49
Abamectin a.i. 1.33 to 1.54 1.50 1.50 1.5 1.5
Broflanilide suspensibility (%) 80 98.60 98.60 98.50 98.50
Cyantraniliprole suspensibility (%) 80 98.50 98.50 98.50 98.50
Abamectin suspensibility (%) 80 98.70 98.70 98.45 98.45
pH range (1% aq. Suspension) 4.0 to 6.0 5.00 5.00 5.00 5.00
Pourability (%) 95 98.20 98.20 98.10 98.10
Specific gravity 1.00 -1.10 1.05 1.05 1.05 1.05
Viscosity at spindle no.62,20 rpm 350-800 cps 530 530 530 540
Particle size (micron) D50<3, D90<10 2.1,8.5 2.1,8.5 2.1,8.7 2.1,8.7
Persistent foam ml (after 1 minute) max. 60 nil nil nil nil

The composition of Broflanilide 2%+Cyantraniliprole 8%+Abamectin 1.4% SC meets the all in-house specifications for storage stability studies in laboratory (at 54±2 C & at 0±2 C for 14 days) and room temperature (for 12 months).
Manufacturing process for 100 kg batch of Broflanilide 2%+Cyantraniliprole 8%+Abamectin 1.4% SC:
Step 1: 2% Gum Solution: Charge Xanthan gum (2.0 kg) and 1,2-benzisothiazoline-3-one (2.0 kg) into 96.0 kg water and homogenize. It should be made 12-18 hour prior to use.
Step 2: Charge DM water (55.07 kg) and 1,2-propylene glycol (5 kg) into designated vessel and ix thoroughly.
Step 3: Add Sodium naphthalene sulphonate formaldehyde condensates (1.25 kg), Ethylene-propylene oxide block copolymer (4.75 kg) and Aluminum magnesium silicate (0.5 kg) into the vessel having water and homogenise the contents for 45 – 60 minutes using high shear homogeniser.
Step 4: Then add Broflanilide technical (2.0 kg), Cyantraniliprole technical (8.0 kg) and Abamectin technical (1.40 kg) to this premix slowly and homogenised to get uniform slurry ready for grinding.
Step 5: Before grinding half the quantity of Polydimethylsiloxane (0.15 kg) was added and then material was subjected to grinding in Dyno mill till desired particle size is achieved.
Step 6: Add remaining Polydimethyl siloxane (0.15 kg) antifoam was added after grinding process completes and before sampling for in process analysis.
Step 7: Finally add 10.0 kg of 2% Xanthum gum solution and 5.0 kg of Methylated seed oil, polyalkyleneoxide modified trisiloxane to this formulation and homogenized for 30 minutes.
Step 8: Now send this final formulation to QC for quality check.

EXAMPLE 3:
Broflanilide 1.33%+Cyantraniliprole 5.33%+Fluxametamide 4% OD
Chemical composition Percent (w/w)
Broflanilide a.i. 1.33
Cyantraniliprole a.i. 5.33
Fluxametamide a.i. 4.00
Polyoxyethylene sorbitol hexaoleate (Oil Emulsifier) 10.00
Salts of polyolefin condensates (Non-Aqueous dispersant ) 2.50
Silicon antifoam (Antifoam) 0.30
Ethoxylated sorbitan ester (Co-Emulsifier) 8.50
Bentonite clay (Rheology modifier/ stabilizer) 1.50
Styrene acrylic polymer (Aqueous dispersant) 1.50
Methylated seed oil (Oil continuous phase, solvent) 65.04
Total 100.00
Active ingredients on the basis of 100% purity.
Storage stability: Broflanilide 1.33%+Cyantraniliprole 5.33%+Fluxametamide 4% OD
Laboratory storage stability for 14 days
Parameters Specification (in house) Initial Stability at 54±2 0C Stability at 0±2 0C
Broflanilide a.i. 1.263 to 1.463 1.40 1.36 1.40
Cyantraniliprole a.i. 5.063 to 5.863 5.50 5.35 5.4
Fluxametamide a.i. 3.80 to 4.40 4.20 4.15 4.20
Broflanilide suspensibility (%) 80 98.90 98.10 98.80
Cyantraniliprole suspensibility (%) 80 99.00 98.50 98.90
Fluxametamide suspensibility (%) 80 98.80 98.10 98.80
pH range (1% aq. Suspension) 4.0 to 6.0 5.25 5.25 5.25
Pourability (%) 95 98.20 98.10 98.20
Specific gravity 1.00-1.10 1.03 1.03 1.03
Viscosity at spindle no.62,20 rpm 350-800 cps 510 520 510
Particle size (micron) D50<3, D90<10 2.1,8.0 2.1,8.2 2.1,8.1
Persistent foam ml (after 1 minute) max. 60 nil nil nil
Room temperature storage stability up to 12 months
Parameters Specification (in house) Initial 1 month 6 month 12 month
Broflanilide a.i. 1.263 to 1.463 1.40 1.40 1.40 4.18
Cyantraniliprole a.i. 5.063 to 5.863 5.50 5.50 5.4 5.20
Fluxametamide a.i. 3.80 to 4.40 4.20 4.20 4.20 4.19
Broflanilide suspensibility (%) 80 98.90 98.90 98.80 98.80
Cyantraniliprole suspensibility (%) 80 99.00 99.00 98.90 98.80
Fluxametamide suspensibility (%) 80 98.80 98.80 98.80 98.70
pH range (1% aq. Suspension) 4.0 to 6.0 5.25 5.25 5.25 6.95
Pourability (%) 95 98.20 98.20 98.20 98.20
Specific gravity 1.00-1.10 1.03 1.03 1.03 1.03
Viscosity at spindle no.62,20 rpm 350-800 cps 510 510 510 515
Particle size (micron) D50<3, D90<10 2.1,8.0 2.1,8.0 2.1,8.1 2.1,8.1

The composition of Broflanilide 1.33%+Cyantraniliprole 5.33%+Fluxametamide 4% OD meets the all in-house specifications for storage stability studies in laboratory (at 54±2 C & At 0±2 C for 14 days) and room temperature (for 12 months).
Manufacturing Process for 100 kg batch of Broflanilide 1.33%+Cyantraniliprole 5.33%+Fluxametamide 4% OD
Step 1: 15% Bentonite clay Solution Preparation:
Add 15 kg of Bentonite clay in to 85 kg of Methylated seed oil and also and homogenized till it gets completely dissolved. It must be kept for 12-18 hour prior to use.
Step 2: OD Premix:
Charge 55.04 kg of Methylated seed oil into a designated vessel for OD production.
Step 3: Now add 10.0 kg of Polyoxyethylene sorbitol hexaoleate, 1.50 kg of Styrene acrylic polymer,8.50 kg of Ethoxylated sorbitan ester,2.50 kg of Salts of polyolefin condensates and 0.15 kg of Polydimethyl siloxane homogenise the contents for 45 – 60 minutes using high shear homogeniser .
Step 4: Add 4.0 kg of Fluxametamide technical, 5.33 kg of Cyantraniliprole technical and 1.33 kg of Broflanilide technical, into this premix and homogenized for 30-45 minutes.
Step 5: Add remaining 0.15 kg of Silicon antifoam and 10 kg of 15% Bentonite caly solution after milling to avoid foaming.
Step 6: Send this final formulation to QC for quality check

EXAMPLE 4:
Broflanilide 5%+Chlorantraniliprole 10%+Prothioconazole 25% WG
Chemical composition Percent (w/w)
Broflanilide a.i. 5.00
Chlorantraniliprole a.i. 10.00
Prothioconazole a.i. 25.00
Modified Sodium lignosulphonate (dispersing agent I) 7.00
Modified polyacrylate copolymer (dispersing agent II) 3.00
Sodium isopropyl naphthalene sulfonate (wetting agent) 5.00
Polydimethylsiloxane (Antifoaming Agent) 1.00
Corn Starch 15.00
China clay 29.00
Total 100.00
Active ingredients on the basis of 100% purity.
Storage stability- Broflanilide 5%+Chlorantraniliprole 10%+Prothioconazole 25% WG
Laboratory storage stability for 14 days
Parameters Specification (in house) Initial Stability at 54±2 0C Stability at 0±2 0C
Broflanilide a.i. 4.75 to 5.50 5.30 5.15 5.3
Chlorantraniliprole a.i. 9.50 to 10.50 10.40 10.30 10.40
Prothioconazole a.i. 23.75 to 26.25 25.50 25.35 25.5
Broflanilide suspensibility (%) 70 98.40 97.30 98.20
Chlorantraniliprole suspensibility (%) 70 98.20 97.50 98.20
Prothioconazole suspensibility (%) 70 98.80 97.40 98.60
pH range (1% aq. Suspension) 5 to 9 7.50 7.60 7.50
Wettability Max 30 s 10 12 10
Wet Sieve(45 micron) Mini 98.5% 99.5 99.4 99.5
Bulk Density 0.45-0.85 0.55 0.55 0.55
Moisture Content Max 3.0% 1.4 1.2 1.4
Persistent foam ml (after 1 minute) max. 60 nil nil nil
Room temperature storage stability up to 12 months
Parameters Specification (in house) Initial 1 month 6 month 12 month
Broflanilide a.i. 4.75 to 5.50 5.30 5.30 5.3 5.28
Chlorantraniliprole a.i. 9.50 to 10.50 10.40 10.40 10.40 10.40
Prothioconazole a.i. 23.75 to 26.25 25.50 25.50 25.5 25.48
Broflanilide suspensibility (%) 70 98.40 98.40 98.20 98.15
Chlorantraniliprole suspensibility (%) 70 98.20 98.20 98.20 98.20
Prothioconazole suspensibility (%) 70 98.80 98.80 98.60 98.55
pH range (1% aq. Suspension) 5 to 9 7.50 7.50 7.50 7.51
Wettability Max 30 s 10 10 10 11
Wet Sieve(45 micron) Mini 98.5% 99.5 99.5 99.5 99.5
Bulk Density 0.45-0.85 0.55 0.55 0.55 0.55
Moisture Content Max 3.0% 1.4 1.4 1.4 1.4
Persistent foam ml (after 1 minute)max. 60 nil nil nil nil

The composition of Broflanilide 5%+Chlorantraniliprole 10%+Prothioconazole 25% WG meets the all in-house specifications for storage stability studies in laboratory (at 54±2 C & At 0±2 C for 14 days) and room temperature (for 12 months).
Manufacturing process for 100 kg batch of Broflanilide 5%+Chlorantraniliprole 10%+Prothioconazole 25% WG
Step 1: Charge the 29.0 kg China clay, 15.0 kg Corn starch, 0.5 kg silicone antifoam, 5 kg of Sodium isopropyl naphthalene sulfonate, 3 kg Modified polyacrylate copolymer and 7.0 kg of Modified Sodium lingo sulphonate blend into a ribbon or premix blender and homogenization for 30 minutes.
Step 2: Now charge 5.0 kg Broflanilide technical, 10 kg Chlorantraniliprole technical and 25.0 kg Prothioconazole technical and again homogenize for 30 minutes and now this Pre-blended material is then grinded through Jet mill/ air classifier mills. Finely grinded material is blended in post blender till it becomes homogeneous. (for approx 1.5 hr).
Step 3: Finely grinded powder is mixed with 10 kg of water having 0.5 kg silicone antifoam to form extrudable dough.
Step 4: Dough is passed through extruder to get granules of required size.
Step 5: Wet granules are passed through Fluidized bed drier to remove 10 kg extra water added and further graded using vibrating screens.
Step 6: Final product is sent for QC approval.
Step 7: After approval material is packed in required pack sizes.

EXAMPLE 5:
Broflanilide 5%+Chlorantraniliprole 12%+Zinc oxide 12.5% SC
Chemical composition Percent (w/w)
Broflanilide a.i. 5.00
Chlorantraniliprole a.i. 12.00
Zinc oxide a.i. 12.50
Dioctyl sulfosuccinate (wetting agent) 2.00
Ethylene-propylene oxide block copolymer (dispersing agent I) 4.50
Sodium salt of polycarboxylate (dispersing agent II) 1.50
Aluminum magnesium silicate (suspending agent) 1.00
Polydimethylsiloxane (antifoaming agent) 0.30
1,2-benzisothiazolin-3(2H)-one (preservative) 0.15
Polypropylene glycol (antifreezing agent) 5.00
Xanthan gum (thickner) 0.15
Water (diluent) 55.90
Total 100.00
Active ingredients on the basis of 100% purity.
Storage stability- Broflanilide 5%+Chlorantraniliprole 12%+Zinc oxide 12.5% SC
Laboratory storage stability for 14 days
Parameters Specification (in house) Initial Stability at 54±2 0C Stability at 0±2 0C
Broflanilide a.i. 4.75 to 5.50 5.30 5.20 5.30
Chlorantraniliprole a.i. 11.40 to 12.60 12.25 12.15 12.24
Zinc oxide a.i. 11.875 to 13.125 12.65 12.51 12.64
Broflanilide suspensibility (%) 80 98.50 98.50 98.30
Chlorantraniliprole suspensibility (%) 80 98.60 98.50 98.40
Zinc oxide suspensibility (%) 80 98.00 98.00 97.60
pH range (1% aq. Suspension) 5.5 to 8.5 7.15 7.20 7.15
Pourability (%) 95 98.20 98.20 97.80
Specific gravity 1.00-1.10 1.08 1.08 1.08
Viscosity at spindle no.62,20 rpm 350-800 cps 550 550 560
Particle size (micron) D50<3, D90<10 2.1,8.6 2.1,8.6 2.1,8.7
Persistent foam ml (after 1 minute) max. 60 nil nil nil
Room temperature storage stability up to 12 months
Parameters Specification (in house) Initial 1 month 6 months 12 months
Broflanilide a.i. 4.75 to 5.50 5.30 5.30 5.30 5.28
Chlorantraniliprole a.i. 11.40 to 12.60 12.25 12.25 12.25 12.25
Zinc oxide a.i. 11.875 to 13.125 12.65 12.65 12.65 12.62
Broflanilide suspensibility (%) 80 98.50 98.50 98.30 98.50
Chlorantraniliprole suspensibility (%) 80 98.60 98.60 98.40 98.60
Zinc oxide suspensibility (%) 80 98.00 98.00 97.60 98.00
pH range (1% aq. Suspension) 5.5 to 8.5 7.15 7.15 7.15 7.15
Pourability (%) 95 98.20 98.20 97.80 98.20
Specific gravity 1.00-1.10 1.08 1.08 1.08 1.08
Viscosity at spindle no.62,20 rpm 350-800 cps 550 550 560 550
Particle size (micron) D50<3, D90<10 2.1,8.6 2.1,8.6 2.1,8.7 2.1,8.6
Persistent foam ml (after 1 minute) max. 60 nil nil nil nil
The composition of Broflanilide 5%+Chlorantraniliprole 12%+Zinc oxide 12.5% SC meets all the criteria for storage stability studies in laboratory (at 54±2 C & At 0±2 C for 14 days) and room temperature (for 12 months).
Manufacturing process for 100 kg batch of Broflanilide 5%+Chlorantraniliprole 12%+Zinc oxide 12.5% SC:
Step 1: 2% Gum Solution: Charge Xanthan gum (2.0 kg) and 1,2-benzisothiazoline-3-one (2.0 kg) into 96.0 kg water and homogenize. It should be made 12-18 hour prior to use.
Step 2: Charge DM water (48.40 kg) and 1,2-propylene glycol (5 kg) into designated vessel and ix thoroughly.
Step 3: Add Sodium salt of polycarboxylate (1.5 kg), Ethylene-propylene oxide block copolymer (4.5 kg),Dioctyl sulfosuccinate (2.0 kg) and Aluminum magnesium silicate (1.0 kg) into the vessel having water and homogenise the contents for 45 – 60 minutes using high shear homogeniser.
Step 4: Then add Broflanilide technical (5.0 kg), Chlorantraniliprole technical (12.0 kg) and Zinc oxide technical (12.5 kg) to this premix slowly and homogenised to get uniform slurry ready for grinding.
Step 5: Before grinding half the quantity of Polydimethylsiloxane (0.15 kg) was added and then material was subjected to grinding in Dyno mill till desired particle size is achieved.
Step 6: Add remaining Polydimethyl siloxane (0.15 kg) antifoam was added after grinding process completes and before sampling for in process analysis.
Step 7: Finally add 7.5 kg of 2% Xanthum gum solution to this formulation and homogenized for 30 minutes.
Step 8: Now send this final formulation to QC for quality check.

EXAMPLE 6:
Broflanilide 4%+Cyantraniliprole 22.5%+Fulvic acid 5% WG
Chemical composition Percent (w/w)
Broflanilide a.i.(100%) 4.00
Cyantraniliprole a.i.(100%) 22.50
Fulvic acid a.i.(100%) 5.00
Sodium naphthalene sulphonate formaldehyde condensate (dispersing agent I) 6.00
Sodium Polycarboxylate (dispersing agent II) 5.00
Sodium lauryl sulfate (wetting Agent) 5.00
Polydimethylsiloxane (antifoaming Agent) 1.00
Corn Starch 20.00
China Clay (Carrier) 31.50
Total 100.00
Active ingredients on the basis of 100% purity.
Storage stability- Broflanilide 4%+Cyantraniliprole 22.5%+Fulvic acid 5% WG
Laboratory storage stability for 14 days
Parameters Specification (in house) Initial Stability at 54±2 0C Stability at 0±2 0C
Broflanilide a.i. 3.80 to 4.20 4.25 4.15 4.25
Cyantraniliprole a.i. 21.375 to 23.625 22.80 22.60 22.80
Fulvic acid a.i. 4.75 to 5.25 5.30 5.23 5.30
Broflanilide suspensibility (%) 70 98.30 97.50 98.10
Cyantraniliprole suspensibility (%) 70 98.20 97.40 98.20
Fulvic acid suspensibility (%) 70 99.00 98.10 99.00
pH range (1% aq. Suspension) 5 to 8.5 7.15 7.20 7.10
Wettability Max 30 s 10 13 12
Wet Sieve(45 micron) Mini 98.5% 99.6 99.2 99.5
Bulk Density 0.45-0.85 0.5 0.5 0.5
Moisture Content Max 3.0% 1.5 1.2 1.2
Persistent foam ml (after 1 minute) max. 60 nil 2 ml nil
Room temperature storage stability up to 12 months
Parameters Specification (in house) Initial 1 month 6 month 12 month
Broflanilide a.i. 3.80 to 4.20 4.25 4.25 4.25 4.25
Cyantraniliprole a.i. 21.375 to 23.625 22.80 22.80 22.80 22.80
Fulvic acid a.i. 4.75 to 5.25 5.30 5.30 5.30 5.30
Broflanilide suspensibility (%) 70 98.30 98.30 98.10 98.00
Cyantraniliprole suspensibility (%) 70 98.20 98.20 98.20 98.20
Fulvic acid suspensibility (%) 70 99.00 99.00 99.00 99.20
pH range (1% aq. Suspension) 5 to 8.5 7.15 7.15 7.15 7.15
Wettability Max 30 s 10 10 12 12
Wet Sieve(45 micron) Mini 98.5% 99.6 99.6 99.5 99.5
Bulk Density 0.45-0.85 0.5 0.5 0.5 0.5
Moisture Content Max 3.0% 1.5 1.5 1.2 1.2
Persistent foam ml (after 1 minute) max. 60 nil nil nil nil

The composition of Broflanilide 4%+Cyantraniliprole 22.5%+Fulvic acid 5% WG meets the all in-house specifications for storage stability studies in laboratory (at 54±2 C & At 0±2 C for 14 days) and room temperature (for 12 months).
Manufacturing process for 100 kg batch of Broflanilide 4%+Cyantraniliprole 22.5%+Fulvic acid 5% WG
Step 1: Charge the 31.5 kg China clay, 20.0 kg Corn starch, 0.5 kg silicone antifoam, 6 kg Sodium naphthalene sulphonate formaldehyde condensate, 5 kg Sodium Polycarboxylate and 5.0 kg of Sodium lauryl sulfate blend into a ribbon or premix blender and homogenization for 30 minutes.
Step 2: Now charge 4.0 kg Broflanilide technical, 22.5 kg Cyantraniliprole technical and 5.0 kg Fulvic acid technical and again homogenize for 30 minutes and now this Pre-blended material is then grinded through Jet mill/ air classifier mills. Finely grinded material is blended in post blender till it becomes homogeneous. (for approx 1.5 hr).
Step 3: Finely grinded powder is mixed with 10 kg of water having 0.5 kg silicone antifoam to form extrudable dough.
Step 4: Dough is passed through extruder to get granules of required size.
Step 5: Wet granules are passed through Fluidized bed drier to remove 10 kg extra water added and further graded using vibrating screens.
Step 6: Final product is sent for QC approval.
Step 7: After approval material is packed in required pack sizes.

EXAMPLE 7:
Broflanilide 6%+Cyclaniliprole 10%+Gibberellic acid 0.8% SE
Chemical composition Percent (w/w)
Broflanilide a.i. 6.00
Cyclaniliprole a.i. 10.00
Gibberellic acid a.i. 0.80
Polyarylphenyl anionic ether sulfate, ammonium salt (Emulsifier) 1.50
Aromatic solvent C-9 15.00
Acrylic graft copolymer (dispersing agent I) 3.00
Sodium salt of polycarboxylate (dispersing agent II) 4.50
Aluminum magnesium silicate (suspending agent) 0.50
Polydimethylsiloxane (anti foaming agent) 0.20
1,2-benzisothiazolin-3(2H)-one (preservative) 0.15
Polypropylene glycol (anti freezing agent) 5.00
Xanthan gum (thickner) 0.15
Diluent water 54.00
Total 100.00
Active ingredients on the basis of 100% purity.
Storage stability- Broflanilide 6%+Cyclaniliprole 10%+Gibberellic acid 0.8% SE
Laboratory storage stability for 14 days
Parameters Specification (in house) Initial Stability at 54±2 0C Stability at 0±2 0C
Broflanilide a.i. 5.70 to 6.60 6.25 6.18 6.24
Cyclaniliprole a.i. 9.50 to 10.50 10.30 10.2 10.30
Gibberellic acid a.i. 0.76 to 0.88 0.85 0.84 0.85
Broflanilide suspensibility (%) 80 98.90 97.50 98.50
Cyclaniliprole suspensibility (%) 80 99.00 97.90 98.60
Gibberellic acid suspensibility (%) 80 98.50 97.60 98.30
pH range (1% aq. Suspension) 5.5 to 8.5 7.50 7.50 7.55
Pourability (%) 95 98.20 98.20 97.80
Specific gravity 1.00-1.10 1.05 1.05 1.05
Viscosity at spindle no.62,20 rpm 350-800 cps 550 560 560
Particle size (micron) D50<3, D90<10 2.1,8.2 2.2,8.5 2.1,8.2
Persistent foam ml (after 1 minute) max. 60 nil nil nil
Room temperature storage stability up to 12 months
Parameters Specification (in house) Initial 1 month 6 month 12 month
Broflanilide a.i. 5.70 to 6.60 6.25 6.25 6.25 6.24
Cyclaniliprole a.i. 9.50 to 10.50 10.30 10.30 10.30 10.2
Gibberellic acid a.i. 0.76 to 0.88 0.85 0.85 0.85 0.84
Broflanilide suspensibility (%) 80 98.90 98.50 98.50 97.50
Cyclaniliprole suspensibility (%) 80 99.00 98.60 98.60 97.90
Gibberellic acid suspensibility (%) 80 98.50 98.30 98.30 97.60
pH range (1% aq. Suspension) 5.5 to 8.5 7.50 7.55 7.55 7.50
Pourability (%) 95 98.20 97.80 97.80 98.20
Specific gravity 1.00-1.10 1.05 1.05 1.05 1.05
Viscosity at spindle no.62,20 rpm 350-800 cps 550 560 560 560
Particle size (micron) D50<3, D90<10 2.1,8.2 2.1,8.2 2.1,8.2 2.2,8.5
Persistent foam ml (after 1 minute) max. 60 nil nil nil nil

The composition of Broflanilide 6%+Cyclaniliprole 10%+Gibberellic acid 0.8% SE meets the all inhouse specifications for storage stability studies in laboratory (at 54±2 C & At 0±2 C for 14 days) and room temperature (for 12 months).
Manufacturing process for 100 kg batch of Broflanilide 6%+Cyclaniliprole 10%+Gibberellic acid 0.8% SE
Step 1: 2% Gum Solution: Charge 2 kg Xanthan gum and 2 kg 1,2-benzisothiazoline-3-one into 96 kg water and homogenizeand should be made 12-18 hour prior to use.
Step 2: EC premix-Add 15.0 kg of Aromatic solvent into other vessel having slow stirring.Now add 0.8 kg of Gibberelic acid technical and 1.5 kg of Polyarylphenyl anionic ether sulfate, ammonium salt and mix properly for 30-45 minutes.
Step 3: Charge 46.5 kg of DM water and 5 kg of 1,2-propylene glycol into designated vessel and mix thoroughly.
Step 4: Add 0.5 kg of Aluminum magnesium silicate, 3.0 kg of Acrylic graft copolymer, 4.50 kg of Sodium salt of polycarboxylate and 0.10 kg of Polydimethylsiloxane into the vessel having water and homogenise the contents for 45 – 60 minutes using high shear homogeniser.
Step 5: Then add 6.0 kg of Broflanilide technical and 10.0 kg of Cyclaniliprole technical to this premix slowly and homogenised to get uniform slurry ready for grinding.
Step 6: Before grinding half the quantity of antifoam was added and then material was subjected to grinding in Dyno mill till desired particle size is achieved.
Step 7: Add remaining 0.10 kg of Polydimethyl siloxane antifoam was added after grinding process completes and before sampling for in process analysis.
Step 8: Now mix EC premix to this milled slurry under slow stirring and homogenize for 30-45 minutes
Step 9: Finally add 7.5 kg of 2% gum solution to this formulation and send to QC for quality check.

EXAMPLE 9:
The preferred compositions for present invention are:
Broflanilide 2.4%+Chlorantraniliprole 3.6%+Fipronil 8% SC
Broflanilide 3%+Chlorantraniliprole 4.5%+Abamectin 1.8% SC
Broflanilide 1.2%+Chlorantraniliprole 1.8%+Tolfenpyrad 10% SC
Broflanilide 2.4%+Chlorantraniliprole 3.6%+Fluxametamide 6% SC
Broflanilide 3.6%+Chlorantraniliprole 8%+Fenpyroximate 8% SC
Broflanilide 3.6%+Chlorantraniliprole 8%+Etoxazole 10% SC
Broflanilide 3.6%+Chlorantraniliprole 8%+Cyenopyrafen 20% SC
Broflanilide 1.8%+Chlorantraniliprole 4%+Cyflumetofen 20% SC
Broflanilide 0.9%+Chlorantraniliprole 1.8%+Diafenthiuron 20% SC
Broflanilide 1.8%+Chlorantraniliprole 3.6%+Flonicamid 10% SC
Broflanilide 1.8%+Chlorantraniliprole 3.6%+Spiromesifen 18% SC
Broflanilide 3.6%+Chlorantraniliprole 8%+Acetamiprid 8% SC
Broflanilide 3.6%+Chlorantraniliprole 8%+Dinotefuran 8% SC
Broflanilide 3.6%+Chlorantraniliprole 8%+Thiamethoxam 16% SC
Broflanilide 3.6%+Chlorantraniliprole 8%+Clothianidin 16% SC
Broflanilide 1.8%+Chlorantraniliprole 3.6%+Methoxyfenozide 18% SC
Broflanilide 2.4%+Chlorantraniliprole 4.8%+Indoxacarb 12%SC
Broflanilide 2%+Chlorantraniliprole 4%+Spiropidion 6% SC
Broflanilide 2%+Chlorantraniliprole 4%+Isocycloseram 6% SC
Broflanilide 2%+Chlorantraniliprole 4%+Oxazasulfyl 6% SC
Broflanilide 2%+Chlorantraniliprole 4%+Dimpropyridaz 6% SC
Broflanilide 2%+Chlorantraniliprole 4%+Chlorfenapyr 8% SC
Broflanilide 2%+Cyantraniliprole 8%+Abamectin 1.4% SC
Broflanilide 2%+Cyantraniliprole 8%+Emamectin benzoate 1.4% SC
Broflanilide 1.33%+Cyantraniliprole 5.33%+Tolfenpyrad 13.33% SC
Broflanilide 1.33%+Cyantraniliprole 5.33%+Fluxametamide 4% OD
Broflanilide 1.75%+Cyantraniliprole 9%+Isocycloseram 6.25% OD
Broflanilide 1.33%+Cyantraniliprole 5.33%+Fipronil 5% SC
Broflanilide 4%+Cyantraniliprole 16%+Fenpyroximate 8% SC
Broflanilide 4%+Cyantraniliprole 16%+Etoxazole 10% SC
Broflanilide 1.67%+Cyantraniliprole 6.67%+Diafenthiuron 33.33 SC
Broflanilide 1.67%+Cyantraniliprole 6.67%+Chlorfenapyr 10% SC
Broflanilide 0.9%+Cyantraniliprole 4%+Diafenthiuron 20% SC
Broflanilide 1.8%+Cyantraniliprole 8%+Flonicamid 10% SC
Broflanilide 1.8%+Cyantraniliprole 8%+Spiromesifen 18% SC

Broflanilide 2.4%+Cyantraniliprole 10%+Acetamiprid 8% SC
Broflanilide 2.4%+Cyantraniliprole 8%+Clothianidin 16% SC
Broflanilide 1%+Tetraniliprole 3%+Tolfenpyrad 13.33% SC
Broflanilide 1%+Flubendiamide 3%+Tolfenpyrad 13.33% SC
Broflanilide 3%+Chlorantraniliprole 4%+Pyraclostrobin 15% SC
Broflanilide 3%+Cyantraniliprole 9%+Pyraclostrobin 15% SC
Broflanilide 3%+Tetraniliprole 5%+Pyraclostrobin 15% SC
Broflanilide 3%+Cyclaniliprole 5%+Pyraclostrobin 15% SC
Broflanilide 3%+Flubendiamide 5%+Pyraclostrobin 15% SC
Broflanilide 3%+Chlorantraniliprole 4%+Azoxystrobin 20% SC
Broflanilide 2.5%+Cyantraniliprole 7.5%+Azoxystrobin 16.67% SC
Broflanilide 3%+Tetraniliprole 5%+Azoxystrobin 20% SC
Broflanilide 3%+Flubendiamide 5%+Azoxystrobin 20% SC
Broflanilide 5%+Chlorantraniliprole 8%+Fluxapyroxad 25% SC
Broflanilide 5%+Cyantraniliprole 16%+Fluxapyroxad 25% SC
Broflanilide 5%+Tetraniliprole 10%+Fluxapyroxad 25% SC
Broflanilide 5%+Flubendiamide 8%+Fluxapyroxad 25%SC
Broflanilide 5%+Chlorantraniliprole 12%+Zinc oxide 12.5% SC
Broflanilide 5%+Cyantraniliprole 22.5%+Zinc oxide 12.5% SC
Broflanilide 5%+Tetraniliprole 12%+Zinc oxide 12.5% SC
Broflanilide 5%+Cyclaniliprole 12%+Zinc oxide 12.5% SC
Broflanilide 5%+Flubendiamide 8%+Zinc oxide 12.5% SC
Broflanilide 2.2%+Chlorantraniliprole 4%+Ascophyllum nodosum extract 20% SC
Broflanilide 2.2%+Cyantraniliprole 10%+Ascophyllum nodosum extract 20% SC
Broflanilide 2.2%+Tetraniliprole 5%+Ascophyllum nodosum extract 20% SC
Broflanilide 2.2%+Flubendiamide 6%+Ascophyllum nodosum extract 20% SC
Broflanilide 6%+Chlorantraniliprole 8%+Gibberellic acid 0.8% SC
Broflanilide 6%+Cyantraniliprole 16%+Gibberellic acid 0.8% SC
Broflanilide 6%+Tetraniliprole 10%+Gibberellic acid 0.8% SC
Broflanilide 1%+Cyhalodiamide 3%+Tolfenpyrad 13.33% SC
Broflanilide 1.4%+Tetraniliprole 5%+Isocycloseram 5% SC
Broflanilide 1.4%+Flubendiamide 4%+Isocycloseram 5% SC
Broflanilide 6%+Cyclaniliprole 10%+Gibberellic acid 0.8% SE
Broflanilide 3.2%+Cyclaniliprole 12%+Fulvic acid 4% SE
Broflanilide 2.8%+Chlorantraniliprole 7.2%+Isocycloseram 10% SE
Broflanilide 4%+Cyantraniliprole 16%+Hexythiazox 8% SE
Broflanilide 3.6%+Chlorantraniliprole 8%+Hexythiazox 8% SE
Broflanilide 1%+Cyclaniliprole 3%+Tolfenpyrad 13.33% SE
Broflanilide 6%+Chlorantraniliprole 9%+Deltamethrin 5% SE
Broflanilide 0.9%+Cyantraniliprole 4%+Pyriproxyfen 7% SE
Broflanilide 2.8%+Chlorantraniliprole 7.2%+Isocycloseram 10% SE
Broflanilide 2.4%+Chlorantraniliprole 4.8%+Novaluron 12% SE
Broflanilide 7.2%+Chlorantraniliprole 14.4%+Pyrifluquinazon 14% WG
Broflanilide 2.4%+Chlorantraniliprole 4.8%+Tebufenozide 12% WG
Broflanilide 2.4%+Chlorantraniliprole 4.8%+Chlorfluazuron 12% WG
Broflanilide 2.25%+Cyantraniliprole 10%+Pyrifluquinazon 17.5% WG
Broflanilide 3%+Cyantraniliprole 12.4%+Dinotefuran 4% WG
Broflanilide 5%+Chlorantraniliprole 10%+Prothioconazole 25% WG
Broflanilide 5%+Cyantraniliprole 20%+Prothioconazole 25% WG
Broflanilide 5%+Tetraniliprole 10%+Prothioconazole 25% WG
Broflanilide 5%+Cyclaniliprole 10%+Prothioconazole 25% WG
Broflanilide 5%+Flubendiamide 8%+Prothioconazole 25% WG
Broflanilide 8%+Chlorantraniliprole 22.5%+Fulvic acid 10% WG
Broflanilide 4%+Cyantraniliprole 22.5%+Fulvic acid 5% WG
Broflanilide 8%+Tetraniliprole 22.5%+Fulvic acid 10% WG
Broflanilide 8%+Flubendiamide 22.5%+Fulvic acid 10% WG
Active ingredients on the basis of 100% purity.
Biological Examples:
The synergistic pesticide action of the inventive mixtures can be demonstrated by the experiments below. A synergistic effect exists wherever the action of a combination (ready-mix) or tank mix of active ingredient is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticide activity than the sum of the pesticide activities of the individual components.
In the field of agriculture, it is often understood that the term “synergy” is as defined by Colby S.R. in an article entitled “Calculation of the synergistic and antagonistic responses of herbicide combinations” published in the journal Weeds, 1967, 15, p.20-22, incorporated herein by reference in its entirety. The action expected for a given combination of two or three active components can be calculated as follows:

The objective of the present studies was to study the synergism and benefits. The various formulations of broflanilide+ at least diamide insecticide+ at least one more compound selected from the group of insecticide, fungicide or plant health additives.
Broflanilide+ at least one diamide insecticide+ one more insecticide,
Broflanilide+ at least one diamide insecticide+ at least one fungicide,
Broflanilide+ at least one diamide insecticide+ at least one plant health additive.
Bio-efficacy of Broflanilide+ at least one diamide insecticide+ at least one insecticide:
Example 1: Bio efficacy against Chilli thrips, fruit borer and effect on yield.
Crop : Chilli
Location : Umreth, Gujarat
Number of Treatments: 19
Plot size : 40 sq.m. (square meter)
Crop stage : 72 days after transplanting.
Method of application: foliar spray with battery operated backpack sprayer
Water volume : 450 liter per hectare
Observation Methods:
Thrips (Scirtothrips dorsalis & Thrips parvispinus): Count the number of live thrips by shaking the twigs on black piece of paper. Record the observations from 3 twigs per plant and 10 plants per plot on 5 and 10 DAA (days after application). Calculate thrips control (%) as observed control and apply Colby’s formula to calculate synergism.

Fruit borer (mixed infestation of Helicoverpa armigera and Spodoptera exigua) larval control (%): Count the number of live larvae per plant. Record observations from 10 plants per plot on 5th and 10th days after application. Calculate larval control (%) as,

Fruit borer larval control (%) data were used to check the synergism by applying Colby’s formula given above.
Healthy Fruit count: Count the number of healthy fruits per plant. Record the observations from 10 plants per plot and calculate increase (%) in healthy fruits over UTC (untreated check).
Table 1: Treatment details
Sr.no. Treatment compositions gram actives per hectare
T1 Broflanilide 2.4%+Chlorantraniliprole 3.6%+Fipronil 8% SC 12+18+40
T2 Broflanilide 6%+Chlorantraniliprole 9%+Deltamethrin 5% SE 12+18+10
T3 Broflanilide 3%+Chlorantraniliprole 4.5%+Abamectin 1.8% SC 12+18+7.2
T4 Broflanilide 1.2%+Chlorantraniliprole 1.8%+Tolfenpyrad 10% SC 12+18+100
T5 Broflanilide 2.4%+Chlorantraniliprole 3.6%+Fluxametamide 6% SC 12+18+30
T6 Chlorantraniliprole 5%+Fipronil 10% SC 25+50
T7 Chlorantraniliprole 9%+Deltamethrin 5% SE 18+10
T8 Chlorantraniliprole 4.5%+Abamectin 1.8% SC 28.15+11.25
T9 Chlorantraniliprole 3%+Tolfenpyrad 12% SC 30+120
T10 Chlorantraniliprole 5%+Fluxametamide 6% SC 25+30
T11 Broflanilide 6%+Chlorantraniliprole 12% SC 12+24
T12 Broflanilide 30% SC 12
T13 Chlorantraniliprole 20% SC 18
T14 Fipronil 5% SC 40
T15 Deltamethrin 5% EC 10
T16 Abamectin 1.9% EC 7.2
T17 Tolfenpyrad 15% EC 100
T18 Fluxametamide 10% EC 30
T19 Untreated Check (UTC) -
Sr.no. - serial number, SC suspension concentrate, SE suspo emulsion, EC emulsifiable concentrate, T1 to T5 are innovative compositions, T6 to T11 are known compositions, T12 to T18 are market products. Chlorantraniliprole 20% w/v (18.5% w/w) SC.

,CLAIMS:CLAIMS
We claim;

[CLAIM 1]. A synergistic pesticidal agrochemical composition comprising:
a. Broflanilide is present in amount of 0.01% to 20% w/w;
b. a diamide group of insecticide selected from chlorantraniliprole, cyantraniliprole, cyclaniliprole, tetraniliprole, tetrachlorantraniliprole, tyclopyrazoflor, cyhalodiamide, flubendiamide, fluchlordiniliprole present in amount of 0.01% to 30% w/w;
c. a compound selected from Fipronil, Deltamethrin, Abamectin, Tolfenpyrad, Fluxametamide, Emamectin benzoate, Fenpyroximate, Hexythiazox, Etoxazole, Cyenopyrafen, Cyflumetofen, Diafenthiuron, Chlorfenapyr, Flonicamid, Pyrifluquinazon, Pyriproxyfen, Spiromesifen, Isocycloseram, Methoxyfenozide, Tebufenozide, Chlorfluazuron, Novaluron, Indoxacarb, Pyraclostrobin, Prothioconazole, Azoxystrobin, Zinc oxide, Ascophyllum nodosum extract, Fulvic acid, Gibberellic acid present in amount of 0.001% to 50% w/w;
d. inactive formulation excipients.

[CLAIM 2]. The synergistic pesticidal agrochemical composition as claimed in claim 1, wherein the formulation for the said composition is selected from Suspension concentrate (SC), Suspo-emulsion (SE), Wettable Granule (WG) and Oil dispersion (OD).

[CLAIM 3]. The synergistic pesticidal agrochemical composition as claimed in claim 1, wherein the preferred combinations of active ingredients in the composition for the Suspension concentrate (SC) formulation comprises:
i. Broflanilide 2.4%+Chlorantraniliprole 3.6%+Fipronil 8%;
ii. Broflanilide 3%+Chlorantraniliprole 4.5%+Abamectin 1.8%;
iii. Broflanilide 1.2%+Chlorantraniliprole 1.8%+Tolfenpyrad 10%;
iv. Broflanilide 2.4%+Chlorantraniliprole 3.6%+Fluxametamide 6%;
v. Broflanilide 3.6%+Chlorantraniliprole 8%+Fenpyroximate 8%;
vi. Broflanilide 3.6%+Chlorantraniliprole 8%+Etoxazole 10%;
vii. Broflanilide 3.6%+Chlorantraniliprole 8%+Cyenopyrafen 20%;
viii. Broflanilide 1.8%+Chlorantraniliprole 4%+Cyflumetofen 20%;
ix. Broflanilide 2%+Cyantraniliprole 8%+Abamectin 1.4%;
x. Broflanilide 2%+Cyantraniliprole 8%+Emamectin benzoate 1.4%;
xi. Broflanilide 1.33%+Cyantraniliprole 5.33%+Tolfenpyrad 13.33%;
xii. Broflanilide 1.33%+Cyantraniliprole 5.33%+Fipronil 5%;
xiii. Broflanilide 4%+Cyantraniliprole 16%+Fenpyroximate 8%;
xiv. Broflanilide 4%+Cyantraniliprole 16%+Etoxazole 10%;
xv. Broflanilide 1.67%+Cyantraniliprole 6.67%+Diafenthiuron 33.33;
xvi. Broflanilide 1.67%+Cyantraniliprole 6.67%+Chlorfenapyr 10%;
xvii. Broflanilide 0.9%+Cyantraniliprole 4%+Diafenthiuron 20%;
xviii. Broflanilide 1.8%+Cyantraniliprole 8%+Flonicamid 10%;
xix. Broflanilide 1.8%+Cyantraniliprole 8%+Spiromesifen 18%;
xx. Broflanilide 3%+Chlorantraniliprole 4%+Pyraclostrobin 15%;
xxi. Broflanilide 3%+Cyantraniliprole 9%+Pyraclostrobin 15%;
xxii. Broflanilide 3%+Tetraniliprole 5%+Pyraclostrobin 15%;
xxiii. Broflanilide 3%+Cyclaniliprole 5%+Pyraclostrobin 15%;
xxiv. Broflanilide 3%+Flubendiamide 5%+Pyraclostrobin 15%;
xxv. Broflanilide 1%+Tetraniliprole 3%+Tolfenpyrad 13.33%;
xxvi. Broflanilide 1%+Flubendiamide 3%+Tolfenpyrad 13.33%;
xxvii. Broflanilide 1%+Cyhalodiamide 3%+Tolfenpyrad 13.33%;
xxviii. Broflanilide 1.4%+Tetraniliprole 5%+Isocycloseram 5%;
xxix. Broflanilide 1.4%+Flubendiamide 4%+Isocycloseram 5%;
xxx. Broflanilide1.8%+Chlorantraniliprole3.6%+Methoxyfenozide18%;
xxxi. Broflanilide 2.4%+Chlorantraniliprole 4.8%+Indoxacarb 12%;
xxxii. Broflanilide 5%+Chlorantraniliprole 12%+Zinc oxide 12.5%;
xxxiii. Broflanilide 5%+Cyantraniliprole 22.5%+Zinc oxide 12.5%;
xxxiv. Broflanilide 5%+Tetraniliprole 12%+Zinc oxide 12.5%;
xxxv. Broflanilide 5%+Cyclaniliprole 12%+Zinc oxide 12.5%;
xxxvi. Broflanilide 5%+Flubendiamide 8%+Zinc oxide 12.5%;
xxxvii. Broflanilide 6%+Chlorantraniliprole 8%+Gibberellic acid 0.8%;
xxxviii. Broflanilide 6%+Cyantraniliprole 16%+Gibberellic acid 0.8%;
xxxix. Broflanilide 6%+Tetraniliprole 10%+Gibberellic acid 0.8%;
xl. Broflanilide 6%+Flubendiamide 8%+Gibberellic acid 0.8%.

[CLAIM 4]. The synergistic pesticidal agrochemical composition as claimed in claim 3, wherein, the Suspension concentrate (SC) comprises:
i. Broflanilide is present in amount of 1% to 20% w/w;
ii. a diamide group of insecticide selected from chlorantraniliprole, cyantraniliprole, tetraniliprole, tetrachlorantraniliprole, Cyclaniliprole, cyhalodiamide, flubendiamide present in amount of 0.01% to 30% w/w;
iii. a compound selected from Fipronil, Abamectin, Tolfenpyrad, Fluxametamide, Fenpyroximate, Etoxazole, Cyenopyrafen, Cyflumetofen, Emamectin benzoate, Diafenthiuron, Chlorfenapyr, Flonicamid, Spiromesifen, Pyraclostrobin, Isocycloseram, Methoxyfenozide, Indoxacarb, Zinc oxide, Gibberellic acid present in amount of 0.001% to 50% w/w;
iv. super wetting-spreading-penetrating agent in an amount of 2 to 6 % by weight;
v. dispersing agent I in an amount of 1 to 6 % by weight;
vi. dispersing agent II in an amount of 1 to 3 % by weight;
vii. suspending agent in an amount of 0.2 to 4.0 % by weight;
viii. antifoaming agent in an amount of 0.1 to 1.5 % by weight;
ix. preservative in an amount of 0.1 to 0.5 % by weight;
x. anti-freezing agent in an amount of 2 to 6 % by weight;
xi. thickner in an amount of 0.1 to 1.0 % by weight;
xii. diluent water in an amount of 40 to 70 % by weight.

[CLAIM 5]. The synergistic pesticidal agrochemical composition as claimed in claim 4, wherein wetting-spreading-penetrating agent is selected from ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, polyalkoxylated butyl ether, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate, organosilicons surfactants (as a wetting-spreading-penetrating agent) includes trisiloxane ethoxylate, Methylated seed oil, polyalkyleneoxide modified trisiloxane, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, modified form includes polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, polyalkyleneoxide modified trisiloxane, polyalkyleneoxide modified polydimethylsiloxane, trisiloxane ethoxylate, polyoxyethylene methyl polysiloxane, polyether polymethyl siloxane copolymer, polyether modified polysiloxane; may or may not be in modified form, may be liquid or powder form or mixture thereof.

[CLAIM 6]. The synergistic pesticidal agrochemical composition as claimed in claim 4, wherein dispersing agent is selected from Naphthalenesulfonic acid, sodium salt condensated with formaldehyde, alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium polycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethylene oxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycol ether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonylphenol polyglycol ether with 9-10 moles ethylene oxide.

[CLAIM 7]. The synergistic pesticidal agrochemical composition as claimed in claim 4, wherein suspending agent is selected from aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.

[CLAIM 8]. The synergistic pesticidal composition as claimed in claim 4, wherein antifoaming agent is selected from silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane.

[CLAIM 9]. The synergistic pesticidal agrochemical composition as claimed in claim 4, wherein anti-freezing agent is selected from ethylene glycol, propane diols, glycerin or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerin, urea, magnesium sulfate heptahydrate, sodium chloride.

[CLAIM 10]. The synergistic pesticidal agrochemical composition as claimed in claim 4, wherein preservative is selected from 1,2-benzisothiazolin-3(2H)-one, sodium salt, sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, formaldehyde, sodium o-phenyl phenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one.

[CLAIM 11]. The synergistic pesticidal agrochemical composition as claimed in claim 1, wherein preferred combinations of active ingredients in the composition for the suspo-emulsion (SE) formulation comprises:
i. Broflanilide 1%+Cyclaniliprole 3%+Tolfenpyrad 13.33%;
ii. Broflanilide 3.2%+Cyclaniliprole 12%+Fulvic acid 4%;
iii. Broflanilide 6%+Cyclaniliprole 10%+Gibberellic acid 0.8%;
iv. Broflanilide 3.6%+Chlorantraniliprole 8%+Hexythiazox 8%;
v. Broflanilide 4%+Cyantraniliprole 16%+Hexythiazox 8%;
vi. Broflanilide 2.8%+Chlorantraniliprole 7.2%+Isocycloseram 10%;
vii. Broflanilide 2.4%+Chlorantraniliprole 4.8%+Novaluron 12%.

[CLAIM 12]. The synergistic pesticidal agrochemical composition as claimed in claim 11, wherein the Suspo-emulsion (SE) formulation comprises:
i. Broflanilide is present in amount of 1% to 20% w/w;
ii. a diamide group of insecticide selected from chlorantraniliprole, Cyclaniliprole, Cyantraniliprole present in amount of 10.01% to 30% w/w;
iii. a compound selected from Tolfenpyrad, Isocycloseram, Gibberellic acid, Fulvic acid, Novaluron, Hexythiazox present in amount of 0.001% to 50% w/w;
iv. solvent in an amount of 10 to 20 % w/w;
v. Emulsifier agent in an amount of 2 to 6 % % w/w;
vi. dispersing agent 1 in an amount of 2 to 8 % w/w;
vii. dispersing agent 2 in an amount of 2 to 8 % w/w;
viii. suspending agent in an amount of 0.2 to 4.0 % w/w;
ix. antifoaming agent in an amount of 0.1 to 1.5 % w/w;
x. preservative in an amount of 0.1 to 0.5 % w/w;
xi. anti-freezing agent in an amount of 2 to 6 % w/w;
xii. thickener in an amount of 0.1 to 1.0 % w/w;
xiii. diluent water in an amount of 40 to 70 % w/w.

[CLAIM 13]. The synergistic pesticidal agrochemical composition as claimed in claim 12, wherein Emulsifier is selected from Ca-salts or amine salts, and sulphonates of other C11-C16 alkylbenzenes, alkylether sulphates, alkyl phenol ether phosphates and ester phosphates, Polyarylphenyl anionic ether sulfate, ammonium salt; alkoxylated alcohols and alkylphenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid estersof sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; cationic amine, optionally in combination with an alkylsulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkylphenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol (tristyrlphenol with 16 moles EO), tristyrylphenol-polyglycolether-phosphate, fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkylbenzenes in the range C11-C16 and salts thereof; alkyl ether sulphates; alkyl ether phosphates; alkyl phenol ether phosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenole.

[CLAIM 14]. The synergistic pesticidal agrochemical composition as claimed in claim 12, wherein dispersing agent is selected from Sodium salt of polycarboxylate, Acrylic graft copolymer, polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylic polymers, acrylic graft copolymer, styrene copolymers, butadiene copolymers, poly(methacrylate), poly(ethyl methacrylate), poly(methyl methacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium salt of alkyl naphthalene sulfonate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.

[CLAIM 15]. The synergistic pesticidal agrochemical composition as claimed in claim 12, wherein suspending agent is selected from aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.

[CLAIM 16]. The synergistic pesticidal agrochemical composition as claimed in claim 12, wherein solvent is selected from methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol. Macromolecular alcohol includes polyethylene glycol, sorbitol, glucitol etc., dihydroxy alcohol ethers includes dihydroxy alcohol alkyl ether or dihydroxy alcohol aryl ethers, ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether, ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl ether, n-pentane, hexane(s), cyclohexane, methylcyclohexane, heptane, isooctane, benzene, toluene, xylene(s), isophorone and ester solvents such as methyloleate, dimethylamide and morpholineamide derivatives of C6-C16 fatty acids, and mono-alkylene carbonates such as ethylene carbonate, propylene carbonate and butylene carbonates, dimethylsulfoxide (DMSO), 2-ethylhexanol and n-butanol, n-alkylpyrrolidones, fatty acid dimethyl esters, fatty acid esters, dibasic esters, aromatic hydrocarbons and/or aliphatic hydrocarbons, one or more dimethylamides, such as C8-dimethylamide, C10-dimethylamide, C12-dimethylamide, ethylene glycol, propylene glycol, polyalkylene glycols, aromatic hydrocarbons, methylpyrrolidinone (NMP); dimethylformamide (DMF); dimethylisosorbide (DMI); isophorone; acetophenone; 1,3-dimethyl-2-imidazolidonone; lactate esters; dimethyl and diethylcarbonates; alcohols including methanol; ethanol; iso-propanol; n-propanol; n-butanol; iso-butanol; and tert-butanol; Methyl L-lactate, 2-Ethylhexyl L-lactate, Ethyl L-lactate, n-Butyl L-lactate, Octyl phenol ethoxylates.

[CLAIM 17]. The synergistic pesticidal agrochemical composition as claimed in claim 1, wherein preferred combinations of active ingredients in the composition of the Wettable Granule formulation comprises
i. Broflanilide 2.25%+Cyantraniliprole 10%+Pyrifluquinazon 17.5%;
ii. Broflanilide 2.4%+Chlorantraniliprole 4.8%+Tebufenozide 12%;
iii. Broflanilide 2.4%+Chlorantraniliprole 4.8%+Chlorfluazuron 12%;
iv. Broflanilide 5%+Chlorantraniliprole 10%+Prothioconazole 25%;
v. Broflanilide 5%+Cyantraniliprole 20%+Prothioconazole 25%;
vi. Broflanilide 5%+Tetraniliprole 10%+Prothioconazole 25%;
vii. Broflanilide 5%+Cyclaniliprole 10%+Prothioconazole 25%;
viii. Broflanilide 5%+Flubendiamide 8%+Prothioconazole 25%;
ix. Broflanilide 8%+Chlorantraniliprole 22.5%+Fulvic acid 10%;
x. Broflanilide 4%+Cyantraniliprole 22.5%+Fulvic acid 5%;
xi. Broflanilide 8%+Tetraniliprole 22.5%+Fulvic acid 10%;
xii. Broflanilide 8%+Flubendiamide 22.5%+Fulvic acid 10%.

[CLAIM 18]. The synergistic pesticidal agrochemical composition as claimed in claim 17, wherein, the Wettable Granule formulation comprises
i. Broflanilide is present in amount of 1% to 20% w/w;
ii. a diamide group of insecticide selected from chlorantraniliprole, cyantraniliprole, Cyclaniliprole, tetraniliprole, flubendiamide present in amount of 0.01% to 30% w/w;
iii. a compound selected from Fulvic acid, Prothioconazole, Tebufenozide, Chlorfluazuron, Pyrifluquinazon, Fulvic acid present in amount of 0.001% to 50% w/w;
iv. wetting agent in an amount of 2 to 6 % % by weight;
v. dispersing agent 1 in an amount of 2 to 8 % by weight;
vi. dispersing agent 2 in an amount of 2 to 6 % by weight;
vii. antifoaming agent in an amount of 0.1 to 2.0 % by weight;
viii. carrier in an amount of 20 to 40 % by weight.

[CLAIM 19]. The synergistic pesticidal agrochemical composition as claimed in claim 18, wherein dispersing agent is selected from sodium polycarboxylate (sodium polyacrylate), naphthalene sulfonic acid, sodium salt condensates with formaldehyde, polyalcoxylated alkylphenol, naphthalene sulfonic acid formaldehyde condensate, methyl naphthalene-formaldehyde-condensate sodium salt, naphthalene condensates, lignosulfonates, calcium lignosulfonate, lignin sulfonate sodium salt, alkyl naphthalene sulfonate, sodium salt.

[CLAIM 20]. The synergistic pesticidal agrochemical composition as claimed in claim 18, wherein wetting agent is selected from sodium N-methyl-N-oleoyl taurate, alkylated naphthalene sulfonate, sodium salt, mixture of isomers of dibutyl naphthalene sulphonic acid sodium salt, sodium di-isopropyl naphthalene sulphonate, sodium Lauryl sulfate, dioctyl sulfate, alkyl naphthalene sulfonates, phosphate esters, sulphosuccinates and non-ionic such as tridecyl alcohol ethoxylate, alkyl or alkaryl sulfonates such as alkylbenzene sulfonates, alpha olefin sulfonate and alkyl naphthalene sulfonates, ethoxylated or non-ethoxylated alkyl or alkaryl carboxylates, alkyl or alkaryl phosphate esters, alkyl polysaccharide, di or mono alkyl sulfosuccinate derivatives, alpha olefin sulfonates, alkyl naphthalene sulfonates, dialkyl sulphosuccinates, butyl, dibutyl, isopropyl and di-isopropyl naphthalene sulfonate salts, C12 alkyl benzene sulfonate or C10-C16 alkyl benzene sulfonate, organosilicons surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, trisiloxane heptamethyl, Polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane.

[CLAIM 21]. The synergistic pesticidal agrochemical composition as claimed in claim 18, wherein antifoaming agent is polydimethylsiloxane.

[CLAIM 22]. The synergistic agrochemical pesticidal composition as claimed in claim 18, wherein carrier is selected from china clay, silica, lactose anhydrous, ammonium sulfate, sodium sulfate anhydrous, corn starch, urea, EDTA, urea formaldehyde resin, diatomaceous earth, kaolin, bentonite, kieselguhr, fuller's earth, attapulgite clay, bole, loess, talc, chalk, dolomite, limestone, lime, calcium carbonate, powdered magnesia, magnesium oxide, magnesium sulphate, sodium chloride, gypsum, calcium sulphate, pyrophyllite, silicates and silica gels.

[CLAIM 23]. The synergistic pesticidal agrochemical composition as claimed in claim 1, wherein preferred combinations of active ingredients in the composition of Oil dispersion (OD) formulation comprises
i. Broflanilide 1.33%+Cyantraniliprole 5.33%+Fluxametamide 4%;
ii. Broflanilide 1.75%+Cyantraniliprole 9%+Isocycloseram 6.25%.

[CLAIM 24]. The synergistic pesticidal agrochemical composition as claimed in claim 1, wherein, Oil dispersion (OD) formulation comprises:
i. Broflanilide is present in amount of 1% to 20% w/w;
ii. a diamide group of insecticide cyantraniliprole present in amount of 0.01% to 30% w/w;
iii. a compound selected from Fluxametamide, Isocycloseram present in amount of 0.001% to 50% w/w;
iv. solvent in an amount of 40 to 70 % w/w;
v. dispersing agent in an amount of 8 to 12 % w/w;
vi. emulsifying agent in an amount of 2 to 8 % w/w;
vii. antifoaming agent in an amount of 0.1 to 1.5% w/w;
viii. stabilizer in an amount of 0.5 to 3.0 % w/w;
ix. co-solvent in an amount of 0.1 to 1.0 % w/w.

[CLAIM 25]. The synergistic pesticidal agrochemical composition as claimed in claim 24, wherein dispersing agent is selected from alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.

[CLAIM 26]. The synergistic pesticidal agrochemical composition as claimed in claim 24, wherein solvent is selected from vegetable oil in its alkylated or ethoxylated or esterified form selected from olive oil, kapok oil, castor oil, papaya oil, camellia oil, sesame oil, corn oil, rice bran oil, cotton seed oil, soybean oil, groundnut oil, rapeseed-mustard oil, linseed oil, tung oil, sunflower oil, safflower oil, coconut oil. The alkyl ester of vegetable oils includes methyl ester, ethyl ester, propyl ester or butyl ester of vegetable oils. Some of the examples are methylated seed oil, polyalkyleneoxide modified polydimethylsiloxane alkylphenol ethoxylate, rapeseed oil methyl ester, rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, soybean oil methyl ester, soybean oil ethyl ester, soybean oil propyl ester, soybean oil butyl ester, castor oil methyl ester, castor oil ethyl ester, castor oil propyl ester, castor oil butyl ester, cotton seed oil methyl ester, cotton seed oil ethyl ester, cotton seed oil butyl ester, cotton seed oil propyl ester, tall oil fatty acids esters-tallow methyl ester, tallow ethyl ester, tallow propyl ester, bio-diesel, mineral oil (aromatic solvents, isoparaffin, base solvent), fatty acid amides (e.g. C1 -C3 amines, alkylamines or alkanolamines with C6–C18 carboxylic acids), fatty acids, alkyl esters of fatty acids, methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols.

[CLAIM 27]. The synergistic pesticidal agrochemical composition as claimed in claim 24, wherein stabilizer is selected from hectorite clay, aluminium magnesium silicate, bentonite clay, silica, attapulgite clay.

[CLAIM 28]. The synergistic pesticidal agrochemical composition as claimed in claim 24, wherein emulsifying agent is selected from Polyoxyethylene sorbitol hexaoleate castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkylammonium salts of alkylbenzene sulphonate, alkylsulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylene sorbitan monolaurate.

Dated this 06th day of March 2023