“Plant treatment” refers to the application of insecticide, plant growth regulator and another insecticide to the plant so as to disinfect them from parasitic insects and pest. It also refers to subjecting plants to solar energy exposure, spraying conditioned water etc.
The term “synergistic”, as used herein, refers the combined action of two or more active agents blended together and administered conjointly that is greater than the sum of their individual effects.
“Bioactive amounts” as mentioned herein means that amount which, when applied to the treatment of crops is sufficient to effect such treatment.
The term "health of a plant" or "plant health" is defined as a condition of the plant and/or its products. As a result of the improved health, yield, plant vigor, quality and tolerance to abiotic or biotic stress are increased. Noteworthy, the health of a plant when applying the method according to the invention, is increased independently of the pesticidal properties of the active ingredients used because the increase in health is not based upon the reduced pest pressure but instead on complex physiological and metabolic reactions which result for example in an activation of the plant's own natural defense system. As a result, the health of a plant is increased even in the absence of pest pressure. Accordingly, in an especially preferred embodiment of the method according to the invention, the health of a plant is increased both in the presence and absence of biotic or abiotic stress factors. The above identified indicators for the health condition of a plant may be interdependent or they may result from each other. An increase in plant vigor may for example result in an increased yield and/or tolerance to abiotic or biotic stress. One indicator for the condition of the plant is the yield. "Yield" is to be understood as any plant product of economic value that is produced by the plant such as grains, fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants) or even flowers (e.g. in the case of gardening plants, ornamentals). The plant products may in addition be further utilized and/or processed after harvesting.
In an especially preferred embodiment of the invention, the yield of the treated plant is increased. In another preferred embodiment of the invention, the yield of the plants treated according to the method of the invention, is increased synergistically.
According to the present invention, "increased yield" of a plant, in particular of an agricultural, silvicultural and/or horticultural plant means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the mixture according to the invention.
Increased yield can be characterized, among others, by the following improved proper-ties of the plant: increased plant, weight, increased plant height, increased biomass such as higher overall fresh weight (FW), increased number of flowers per plant, higher grain yield, more tillers or side shoots (branches), larger leaves, increased shoot growth, increased protein content, increased oil content, increased starch content, increased pigment content, increased leaf are index.
A further indicator for the condition of the plant is the plant vigor. The plant vigor becomes manifest in several aspects such as the general visual appearance. In another especially preferred embodiment of the invention, the plant vigor of the treated plant is increased. In another preferred embodiment of the invention, the plant vigor of the plants treated according to the method of the invention is increased synergistically. Improved plant vigor can be characterized, among others, by the following improved properties of the plant: improved vitality of the plant, improved plant growth, improved plant development, improved visual appearance, improved plant stand (less plant verse/lodging), improved emergence, enhanced root growth and/or more developed root system, enhanced nodulation, in particular rhizobial nodulation, bigger leaf blade, bigger size, increased plant weight, increased plant height, increased tiller number, increased number of side shoots, increased number of flowers per plant, increased shoot growth, increased root growth (extensive root system), increased yield when grown on poor soils or unfavorable climate, enhanced photosynthetic activity (e.g. based on increased stomatal conductance and/or increased C02 assimilation rate), increased stomatal conductance, increased C02 assimilation rate, enhanced pigment content (e.g. chlorophyll content), earlier flowering, earlier fruiting, earlier and improved germination, earlier grain maturity, improved self-defense mechanisms, improved stress tolerance and resistance of the plants against biotic and abiotic stress factors such as fungi, bacteria, viruses, insects, heat stress, cold stress, drought stress, UV stress and/or salt stress, less non-productive tillers, less dead basal leaves, less input needed (such as fertilizers or water), greener leaves, complete maturation under shortened vegetation periods, less fertilizers needed, less seeds needed, easier harvesting, faster and more uniform ripening, longer shelf-life, longer panicles, delay of senescence, stronger and/or more productive tillers, better extractability of ingredients, improved quality of seeds (for being seeded in the following seasons for seed production), better nitrogen uptake, improved reproduction, reduced production of ethylene and/or the inhibition of its reception by the plant.
The improvement of the plant vigor according to the present invention particularly means that the improvement of any one or several or all of the above mentioned plant characteristics are improved independently of the pesticidal action of the mixture or active ingredients (components).
Another indicator for the condition of the plant is the "quality" of a plant and/or its products. In an especially preferred embodiment of the invention, the quality of the treated plant is increased.
In another preferred embodiment of the invention, the quality of the plants treated according to the method of the invention, is increased synergistically.
According to the present invention, enhanced quality means that certain plant characteristics such as the content or composition of certain ingredients are increased or improved by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the mixtures of the present invention. Enhanced quality can be characterized, among others, by following improved properties of the plant or its product: increased nutrient content, increased protein content, increased content of fatty acids, increased metabolite content, increased carotenoid content, increased sugar content, increased amount of essential amino acids, improved nutrient composition, improved protein composition, improved composition of fatty acids, improved metabolite composition, improved carotenoid composition, improved sugar composition, improved amino acids composition, improved or optimal fruit color, improved leaf color, higher storage capacity, higher process ability of the harvested products.
Another indicator for the condition of the plant is the plant's tolerance or resistance to biotic and/or abiotic stress factors. Biotic and abiotic stress, especially over longer terms, can have harmful effects on plants. Biotic stress is caused by living organisms while abiotic stress is caused for example by environmental extremes. According to the present invention, "enhanced tolerance or resistance to biotic and/or abiotic stress factors" means (1.) that certain negative factors caused by biotic and/or abiotic stress are diminished in a measurable or noticeable amount as compared to plants exposed to the same conditions, but without being treated with a mixture according to the invention and (2.) that the negative effects are not diminished by a direct action of the mixture according to the invention on the stress factors, e.g. by its fungicidal or insecticidal action which directly destroys the microorganisms or pests, but rather by a stimulation of the plants' own defensive reactions against said stress factors.
The present invention provides a novel synergistic agrochemical composition for plant treatment comprising (A) an insecticide from the group Selective feeding blocker; (B) a plant growth regulator; (C) one or more insecticides.
In another embodiment of the present invention, (B) Plant Growth Regulators may be used from the class of Antiauxins such as clofibric acid, 2,3,5-tri-iodobenzoic acid.
In an embodiment of the present invention, the plant growth regulator from the class of Auxin may be selected from 4-CPA, 2,4-D, 2,4-DB, 2,4-DEP, dichlorprop, fenoprop, IAA, IBA, naphthaleneacetamide, a-naphthaleneacetic acid, 1-naphthol, naphthoxyacetic acid, potassium naphthenate, sodium naphthenate, 2,4,5-T.
In an embodiment of the present invention, plant growth regulator may be used from the class of Cytokinins such as adenine, adenine hemisulfate di-hydrate, 2iP, 6-benzylaminopurine, N-Oxide-2,6-lutidine, 2,6-dimethylpyridine, kinetin, zeatin.
In yet another embodiment of the present invention, plant growth regulator may be used from the class of Defoliants such as calcium cyanamide, dimethipin, endothal, merphos, metoxuron, pentachlorophenol, thidiazuron, tribufos, tributyl phosphorro trithioate.
In a further embodiment of the present invention, plant growth regulator may be used from the class of Ethylene modulators such as aviglycine, 1-MCP, prohexadione, prohexadione calcium, trinexapac, trinexapac-ethyl, amino ethoxy vinyl glycine (AVG).
In another embodiment of the present invention, plant growth regulator may be used from the class of Ethylene releasers such as ACC, etacelasil, ethephon, glyoxime.
In an embodiment of the present invention, plant growth regulator may be used from the class of Gibberellins such as gibberelline, gibberellic acid, GA3.
In a further embodiment of the present invention, plant growth regulator may be used from the class of Growth Inhibitors such as abscisic acid, ancymidol, butralin, carbaryl, chlorphonium, chlorpropham, dikegulac, flumetralin, fluoridamid, fosamine, glyphosine, isopyrimol, jasmonic acid, maleic hydrazide, mepiquat, mepiquat chloride, mepiquatpentaborate, piproctanyl, prohydrojasmon, propham, 2,3,5-tri-iodobenzoic acid.
In yet another embodiment of the present invention, plant growth regulator may be used from the class of Morphactins such as chlorfluren, chlorflurenol, dichlorflurenol, flurenol.
In another embodiment of the present invention, plant growth regulator may be used from the class of Growth retardants such as chlormequat, chlormequat chloride, daminozide, flurprimidol, mefluidide, paclobutrazol, tetcyclacis, uniconazole, metconazole.
Moreover in another embodiment of the present invention, plant growth regulator may be used from the class of Growth stimulants such as brassinolide, forchlor fenuron, hymexazol.
In yet another embodiment of the present invention, plant growth regulator may be used from the class of Unclassified plant growth regulators such as amidochlor, benzofluor, buminafos, carvone, choline chloride, ciobutide, clofencet, cloxyfonac, cyanamide, cyclanilide, cycloheximide, cyprosulfamide, epocholeone, ethychlozate, ethylene, fenridazon, fluprimidol, fluthiacet, heptopargil, holosulf, inabenfide, karetazan, lead arsenate, methasulfocarb, pydanon, sintofen, triapenthenol, Nitrophenolate (sodium para-nitrophenolate, ortho-nitrophenoate, sodium-5-nitroguaiacolate), triacontanol, alpha naphthyl acetic acid, 6-benzyladenine.
In an embodiment of the present invention, (C) One or more insecticides may be used from a group of Acetylcholine Esterase Inhibitors from the class of Carbamates such as aldicarb, alanycarb, bendiocarb, benfuracarb, butocarboxim, butoxycarboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, trimethacarb, XMC, xylylcarb, and triazamate.
In yet another embodiment of the present invention, one or more insecticides may be used from the group of Acetylcholine Esterase Inhibitors from the class of Organophosphates such as acephate, azamethiphos, azinphos-ethyl, azinphos-methyl, cadusafos, chlorethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton-S-methyl, diazinon, dichlorvos/ DDVP, dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, famphur, fenamiphos, fenitrothion, fenthion, fosthiazate, heptenophos, imicyafos, isofenphos, isopropyl O-(methoxyaminothio-phosphoryl) salicylate, isoxathion, malathion, mecarbam, methamidophos, methidathion, mevinphos, monocrotophos, naled, omethoate, oxydemeton-methyl, parathion, parathion-methyl, phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, pirimiphos- methyl, profenofos, propetamphos, prothiofos, pyraclofos, pyridaphenthion, quinalphos, sulfotep, tebupirimfos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon, vamidothion.
In a further embodiment of the present invention, one or more insecticides may be used from the class of GABA-gated chloride channel antagonists such as Cyclodiene organo chlorine compounds like endosulfan; or Phenyl pyrazole like ethiprole, fipronil, flufiprole, nicofluprole, pyrafluprole, or pyriprole.
In a further embodiment of the present invention, one or more insecticides may be used from the group of Sodium Channel Modulators from the class of Pyrethroids such as acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cylclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, meperfluthrin, metofluthrin, momfluorothrin, permethrin, phenothrin, prallethrin, profluthrin, pyrethrin (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethylfluthrin, tetramethrin, tralomethrin, transfluthrin.
In a further embodiment of the present invention, one or more insecticides may be used from a group of nicotinic Acetylcholine receptor (nAChR) competitive modulators such as Neonicotinoids like acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam; or Sulfoximines such as sulfoxaflor; or Butenolides like flupyradifurone; or Mesoionics like triflumezopyrim and flupyrimin.
In a further embodiment of the present invention, one or more insecticides may be used from a group of Nicotinic Acteylcholine receptor (nAChR) allosteric modulators-Site I-from the class of spinosyns such as spinosad, spinetoram.
In yet another embodiment of the present invention, one or more insecticides may be used from a class of Glutamate-gated Chloride channel (GluCl) allosteric modulators of Avermectins such as abamectin, emamectin benzoate, ivermectin, lepimectin; Milbemycins-milbemectin.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Juvenile Hormone Mimics such as hydroprene, kinoprene, methoprene, fenoxycarb, pyriproxyfen.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Non-specific multi-site inhibitors such as methyl bromide and other alkyl halides, chloropicrin, sulfuryl fluoride, borax or tartar emetic, dazomet, metam.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Mite growth inhibitors affecting CHS1such asclofentezine, hexythiazox, diflovidazin or etoxazole.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Microbial Disruptors of insect midgut membrane such as Bacillus thuringiensis and insecticidal proteins they produce.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Inhibitors of mitochondrial ATP synthase such as diafenthiuron, azocyclotin, cyhexatin, fenbutatin oxide, propargite, or tetradifon.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Uncouplers of oxidative phosphorylation such as chlorfenapyr, DNOC, or sulfluramid.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Nicotinic acetylcholine receptor channel blockers such as bensultap, cartap hydrochloride, thiocyclam, thiosultap sodium.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Inhibitors of the chitin biosynthesis affecting CHS1 such as Benzoylureas-bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron, and triflumuron.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Inhibitors of the chitin biosynthesis type 1 such as buprofezin.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Moulting disruptors such as cyromazine.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Ecdyson receptor agonists such as diacylhydrazines- methoxyfenozide, tebufenozide, halofenozide, fufenozide or chromafenozide.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Octopamin receptor agonists such as amitraz.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Mitochondrial complex III electron transport inhibitors such as hydramethylnon, acequinocyl, flometoquin, fluacrypyrim, pyriminostrobin or bifenazate.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Mitochondrial complex I electron transport inhibitors such as fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, tolfenpyrad, flufenerim, or rotenone.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Voltage-dependent sodium channel blockers such as oxadiazines-indoxacarb, semicarbazones-metaflumizone or 1 -[(E)-[2-(4-cyanophenyl)-1-[3-(trifluoromethyl) phenyl] ethylidene]amino]-3-[4-(difluoro methoxy)phenyl]urea.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Inhibitors of the lipid synthesis, inhibitors of acetyl CoA carboxylase such as Tetronic and tetramic acid derivatives-spirodiclofen, spiromesifen, spirotetramat or spiropidion.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Mitochondrial complex II electron transport inhibitors such as cyenopyrafen, cyflumetofen or pyflubumide.
In a further embodiment of the present invention, one or more insecticides may be used from the class of Baculoviruses such as Granuloviruses and Nucleopolyhedrosis viruses.
In a further embodiment of the present invention, one or more insecticides may be used from the class of UN-Compounds of unknown or uncertain mode of action such as azadirechtin, benzoximate, benzpyrimoxan, pyridalyl and oxazosulfyl (ethyl 2-{5-[(trifluoromethyl)sulfonyl]-1,3-benzoxazol-2-yl}-3-pyridyl sulfone); dimpropyridaz (1-[(1RS)-1,2-dimethylpropyl]-N-ethyl-5-methyl-N-pyridazin-4-yl-1H-pyrazole-4-carboxamide), tyclopyrazoflor (N-[3-chloro-1-(3-pyridyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoro propyl) thio] propenamide); dichloromezotiaz, fluhexafon,
Acaricidal compound-cyetpyrafen(Z)-2-(4-tert-butylphenyl)-2-cyano-1-(1-ethyl-3-methyl-1H-pyrazol-5-yl)vinyl 2,2-dimethylpropanoate), flupentiofenox (4-chloro-2-fluoro-5-[(RS)-(2,2,2-trifluoroethyl)sulfinyl]phenyl 5-[(trifluoro methyl)thio]pentyl ether), acynonapyr (3-endo-[2-propoxy-4-(trifluoro methyl)phenoxy]-9-{[5-(trifluoromethyl)-2-pyridyl]oxy}-9-azabi cyclo [3.3.1] nonane);
Compound with nematicidal action-cyclobutrifluram (N-[2-(2,4-dichlo rophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3-carboxamide, containing 80–100% of the (1S,2S)-enantiomer and 20–0% of the (1R,2R)-enantiomer), fluazaindolizine (8-chloro-N-[(2-chloro-5-methoxyphenyl)sulfonyl]-6-(trifluo romethyl)imidazo[1,2-a]pyridine-2-carboxamide), tioxazafen.
More preferably the present invention provides a synergistic agrochemical composition for foliar treatment comprising (A) a selective feeding blocker group of insecticide selected from afidopyropen, flonicamid, pyrifluquinazon or pymetrozine; (B) a plant growth regulator selected from auxin, anti-auxin, cytokinin, Defoliants, Ethylene modulators, Ethylene releasers, Growth inhibitors, Gibberellins, Morphactins, Growth retardants, Growth stimulators and unclassified growth regulators with uncertain mode of action; (C) one more insecticide or more insecticides selected from the groups consisting Acetylcholine esterase inhibitors from the class of carbamates or from the class of organophosphates, GABA-gated chloride channel antagonists, Sodium channel modulators from the class of pyrethroids, Nicotinic acteylcholine receptor (nAChR) competitive modulators, Nicotinic acteylcholine receptor (nAChR) allosteric modulators, Glutamate-gated chloride channel (GluCl) allosteric modulators, Juvenile hormone mimics, Non-specific multi-site inhibitors, Mite growth inhibitors affecting CHS1, Microbial disruptors of insect midgut membrane, Inhibitors of mitochondrial ATP synthase, Uncouplers of oxidative phosphorylation, Nicotinic acetylcholine receptor channel blockers, Inhibitors of the chitin biosynthesis affecting CHS1, Ecdyson receptor agonists, Octopamin receptor agonists, Mitochondrial complex III electron transport inhibitors, Mitochondrial complex I electron transport inhibitors, Voltage-dependent sodium channel blockers, Inhibitors of the lipid synthesis, inhibitors of acetyl CoA carboxylase, Mitochondrial complex II electron transport inhibitors, Baculoviruses, UN-Compounds of unknown or uncertain mode of action;
Selective Feeding Blocker:
In general, selective feeding blockers (or inhibitors) are a group of insecticides that have a broad or physical mode of action that prevents insects from feeding by interfering with neural regulation of plant fluid intake in the mouthparts. These insecticides may modify behavior by inhibiting or disrupting stylet penetration into plant vascular fluids (phloem sieve tubes), which prevents insects from obtaining nutrients. This results in starvation.
Selective feeding blockers are active on certain phloem-feeding insects that are problematic in greenhouse production systems; these include aphids and whiteflies. Selective feeding blockers have activity against the young and adult stages, and they rapidly inhibit feeding. For example, aphids will stop feeding within hours, although they will remain alive for two to four days. In addition, selective feeding blockers may inhibit transmission of viruses that are vectored by aphids. These insecticides have no activity on flies (Diptera), beetles (Coleoptera), or caterpillars (Lepidoptera). Selective feeding blockers have both systemic and translaminar activity (penetrate leaf tissues and form a reservoir of active ingredient in the leaf), and can provide up to three weeks of residual activity. Selective feeding blocker insecticides are less directly and indirectly toxic to bees and natural enemies.
Plant Growth Regulators
Plant Growth Regulators are defined as small, simple chemicals produced naturally by plants to regulate their growth and development.
Plant Growth Regulators can be of a diverse chemical composition such as gases (ethylene), terpenes (gibberellic acid) or carotenoid derivatives (abscisic acid). They are also referred to as plant growth substances, phytohormones or plant hormones.
Plant growth hormones are organic compounds which are either produced naturally within the plants or are synthesized in laboratories. They profoundly control and modify the physiological processes like the growth, development, and movement of plants.
Gibberellic acid is a simple gibberellin, a pentacyclic diterpene acid promoting growth and elongation of cells. It affects decomposition of plants and helps plants grow if used in small amounts, but eventually plants develop tolerance to it. Gibberellic acid is a very potent hormone whose natural occurrence in plants controls their development. Since GA regulates growth, applications of very low concentrations can have a profound effect while too much will have the opposite effect. Gibberellins have a number of effects on plant development. They can stimulate rapid stem and root growth, induce mitotic division in the leaves of some plants, and increase seed germination rates.
Moreover oral toxicity of Gibberellic acid (GA3) has been evaluated in S. littoralis and L.migratoriainsect species. Researchers observed that GA3 caused significant reduction in food consumption in both insect species which led to larval weight loss. GA3 toxicity was also demonstrated by larval mortality due to exuviation difficulties.
Paclobutrazol (PBZ) is a plant growth retardant and triazole fungicide. It is a known antagonist of the plant hormone gibberellin. It acts by inhibiting gibberellin biosynthesis, reducing internodal growth to give stouter stems, increasing root growth, causing early fruitset and increasing seedset in plants such as tomato and pepper. PBZ has also been shown to reduce frost sensitivity in plants. Moreover, paclobutrazol can be used as a chemical approach for reducing the risk of lodging in cereal crops. PBZ is used by arborists to reduce shoot growth and has been shown to have additional positive effects on trees and shrubs. Among those are improved resistance to drought stress, darker green leaves, higher resistance against fungi and bacteria, and enhanced development of roots. Cambial growth, as well as shoot growth, has been shown to be reduced in some tree species.
Triacontanol is a fatty alcohol of the general formula C30H62O, also known as melissyl alcohol or myricyl alcohol. It is found in plant cuticle waxes and in beeswax. Triacontanol has been reported to increase the growth of plants by enhancing the rates of photosynthesis, protein biosynthesis, the transport of nutrients in a plant and enzyme activity, reducing complex carbohydrates among many other purposes. The fatty alcohol appears to increase the physiological efficiency of plant cells and boost the potential of the cells responsible for the growth and maturity of a plant.
Brassinolide is a plant hormone. The first isolated brassinosteroid, it was discovered when it was shown that pollen from rapeseed (Brassica napus) could promote stem elongation and cell division. The biologically active component was isolated and named brassinolide.
The present inventors believe that the combination of the present invention surprisingly results in a synergistic action. The combinations of the present invention allow for a broad spectrum of pest control and have surprisingly improved plant vigour and yield. The broad spectrum of the present combination also provides a solution for preventing the development of resistance.
The synergistic composition has very advantageous preventive and systemic insecticidal properties for protecting cultivated plants. As has been mentioned, said active ingredient composition can be used to inhibit or destroy the insect pest and mites that occur on plants or parts of plants of different crops. The synergistic agrochemical composition of specific active ingredient has the special advantage of being highly active against parasitic pest that feed on plant fluids (in phloem).
The synergistic agrochemical of the present invention is used to protect the crops and plants from insect pest and mites. Examples of the crops on which the present compositions may be used include but are not limited to GMO (Genetically Modified Organism) and Non GMO varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticumaestavum), Barley (Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Oat (Avena sativa), Pearl millet (Pennisetumglaucum), Sugarcane (Saccharum officinarum) , Sugarbeet (Beta vulgaris), Soybean (Glycin max), Peanut (Arachishypogaea), Sunflower (Helianthus annuus) , Mustard (Brassica juncea), Rape seed (Brassica napus), Linseed (Linumusitatissimum), Sesame (Sesamumindicum), Green gram (Vignaradiata), Black gram (Vigna mungo), Chickpea (Ciceraritinum), Cowpea (Vignaunguiculata), Redgram (Cajanuscajan), Frenchbean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotylomauniflorum), Field pea (Pisumsativum), Cluster bean (Cyamopsistetragonoloba), Lentils (Lens culinaris), Brinjal (Solanum melongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschusesculentus) , Onion (Allium cepa L.), Tomato (Solanum lycopersicun) , Potato (Solanum tuberosum) , Sweet potato (Ipomoea batatas), Chilly (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumissativus), Muskmelons (Cucumismelo), Watermelon (Citrulluslanatus), Bottle gourd (Lagenariasiceraria), Bitter gourd (Momordicacharantia), Radish (Raphanussativus), Carrot (Dacuscarota subsp. sativus), Turnip (Brassica rapasubsprapa), Apple (Melusdomestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitisvinifera), Guava (Psidiumguajava), Litchi (Litchi chinensis), Mango (Mangiferaindica), Papaya (Carica papaya), Pineapple (Ananascomosus), Pomegranate (Punicagranatum), Sapota (Manilkarazapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiberofficinale), Cumin (Cuminumcyminum), Fenugreek (Trigonellafoenum-graecum), Fennel (Foeniculum vulgare), Coriander (Coriandrumsativum), Ajwain (Trachyspermumammi), Psyllium (Plantago ovate), Black Pepper (Piper nigrum), Stevia (Stevia rebaudiana), Safed musli (Chlorophytumtuberosum), Drum stick (Moringa oleifera), Coconut (Coco nucifera), Mentha ( Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold ( Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera ( Gerbera jamesonii), Carnation (Dianthus caryophyllus).
Further the said composition can be applied to but are not limited to vegetables: solanaceous vegetables such as eggplant, tomato, pimento, pepper, potato, etc., cucurbit vegetables such as cucumber, pumpkin, zucchini, water melon, melon, squash, etc., cruciferous vegetables such as radish, white turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, leaf mustard, broccoli, cauliflower, etc., asteraceous vegetables such as burdock, crown daisy, artichoke, lettuce, etc, liliaceous vegetables such as green onion, onion, garlic, and asparagus, ammiaceous vegetables such as carrot, parsley, celery, parsnip, etc., chenopodiaceous vegetables such as spinach, Swiss chard, etc., lamiaceous vegetables such as Perillafrutescens, mint, basil, etc, strawberry, sweet potato, Dioscorea japonica, colocasia, etc.
Furthermore the said synergistic composition of the present invention can also be applied to flowers, foliage plants, turf grasses, fruits: pome fruits such apple, pear, quince, etc, stone fleshy fruits such as peach, plum, nectarine, Prunusmume, cherry fruit, apricot, prune, etc., citrus fruits such as orange, lemon, rime, grapefruit, etc., nuts such as chestnuts, walnuts, hazelnuts, almond, pistachio, cashew nuts, macadamia nuts, etc. berries such as blueberry, cranberry, blackberry, raspberry, etc., grape, kaki fruit, olive, plum, banana, coffee, date palm, coconuts, etc. , trees other than fruit trees; tea, mulberry, flowering plant, trees such as ash, birch, dogwood, Eucalyptus, Ginkgo biloba, lilac, maple, Quercus, poplar, Judas tree, Liquidambar formosana, plane tree, zelkova, Japanese arborvitae, fir wood, hemlock, juniper, Pinus, Picea, and Taxus cuspidate, etc.
The mixtures according to the invention can be applied to any and all developmental stages of pests, such as egg, larva, pupa, and adult. The pests may be controlled by contacting the target pest, its food supply, habitat, breeding ground or its locus with a pesticidally effective amount of the inventive mixtures or of compositions comprising the mixtures.
The synergistic agrochemical composition of the present invention is active against a broad spectrum of insects and mites. The major insects pests belong to the order Hemiptera, for example, rice leafhopper Nephotettixnigropictus, rice brown plant hopper Nilaparvatalugen, rice white backed plant hopper, Apple Mealy bug Phenococcusaceris, bean aphid Aphis fabae, black citrus aphid Toxopteraaurantii, citrus black scale Saissetiaoleae, cabbage aphid Brevicorynebrassicae, Lipaphiserysimi, citrus red scale Aonidiellaaurantii, yellow scale Aonidiella citrine, citrus mealybug Planococcuscitri, corn leaf aphid Rhopalo siphummaidis, cotton aphid Aphis gossypii, cotton jassid Amrasca biguttulabiguttla, cotton mealy bug Planococcus spp. And Pseudococcus spp., cotton stainer Dysdercussuturellus, cotton whitefly Bemisiatabaci, cowpea aphid Aphis crassivora, grain aphid Sitobionavenae, golden glow aphid Uroleucon spp., grape mealybug Pseudo coccusmaritimus, green peach aphid Myzuspersicae, greenhouse whitefly Trialeuro desvaporariorum, papaya mealy bug Pracoccusmarginatus, pea aphid Acyrthosiphonpisum, sugarcane mealybug Saccharico ccussacchari, potato aphid Myzuspersicae, potato leaf hopper Empoascafabae, cotton whitefly Bemisiatabaci, tarnished plant bug Lyguslineolaris, wooly apple aphid Eriosomalanigerum, mango hopper Amritodusatkinsoni, Idioscopus spp.
Moreover the said combination of the present invention is also advantageous against insects of the order Lepidoptera, army worm Mythimnaunipuncta, asiatic rice borer Chilosuppressalis, bean pod borer Marucavitrata, beet armyworm Spodopteraexigua, black cutworm Agrotisipsilon, bollworm Helicoverpaarmigera , cabbage looperTrichoplusiani, codling moth Cydiapomonella, croton caterpillar Acheajanata, diamond backmoth Plutellaxylostella, cabbage worm Pierisrapae, pink bollworm Pectinophoragossypiella, sugarcane borer Diatraeasaccharalis, tobacco budworm Heliothisvirescens, tomato fruitworm Helicoverpazea, velvet bean caterpillar Anticarsiagemmatalis, yellow stem borer Scirpophagain certulas, spotted bollworm Eariasvittella, rice leaffolder Cnaphalocrocismedinalis, pink stem borer Sesamia spp., tobacco leafeating caterpillar Spodopteralitura; brinjal fruit and shoot borer Leucinodesorbonalis, bean pod borer Marucavitrata, Marucatestulalis, armyworm Mythimnaseparata, cotton pinkbollworm Pectinophoragossypiella, citrus leafminer Phyllocnistiscitrella, cabbage butterfly Pieris bras-sicae, diamond backmoth Plutellaxylostella, paddy stem borer Scirpophagaexcerptallis, Scirpophagain certulas, Scirpophagainnotata, wheat stem borer Sesamiain ferens, Sitotrogacerealella, Spilosomaobliqua, Spodopterafrugiperda, Spodopteralittoralis, Spodopteralitura, Trichoplusiani, Tryporyza novella, Tutaabsoluta.
Furthermore the present invention is also active against insect species of the order Coleoptera, for example, apple twig borer Amphicerus spp., corn root worm Diabroticavirgifera, cucumber beetle diabroticabalteata, boll weevil Anthonomusgrandis, grape flea beetle Alticachalybea, grape root worm Fidiaviticola, grape trunk borer Clytoleptus albofasciatus, radish flea beetle Phyllotretaarmoraciae, maize weevil Sitophilus zeamais, northern corn rootworm Diabroticabarberi, rice water weevil Lissorhoptrusoryzophilus, Anthonomusgrandis, Bruchuslentis, Diabroticasemipunctata, Diabroticavirgifera, Dicladispaarmigera, Epila-chnavarivestis, various species of white grubs are Holotrichia bicolor, Holotrichiacon sanguinea, Holotrichiaserrata, Leptinotarsa decemlineata, Phyllotretachrysocephala, Popillia japonica etc.
The present invention is also advantageous against pests of the order Orthoptera, for example, Gryllotalpa spp., Locusta spp., and Schistocerca is spp. As well as against the order Thysanoptera, for example, Frankliniella spp., Thripspalmi, Thripstabaci and Scirtothrips dorsalis.
The synergistic agrochemical composition is active against termites (Isoptera), e.g. Calotermesflavicollis, Coptotermes formosanus, Heterotermes aureus, Leucotermesflavipes, Microtermesobesi, Odontotermesobesus, Reticulitermesflavipes, Termesnatalensis; from the order Heteroptera, for example, Dysdercus spp., Leptocorisa spp., from the order Hymenoptera, for example, Solenopsis spp. ; from the order Diptera, for example, Antherigonasoccata, Dacus spp., Liriomyza spp., Melanagromyza spp., from the order Acarina, for example, Aceriamangiferae, Brevipalpus spp., Eriophyesspp.,Oligonychusmangiferus, Oligonychuspunicae, Panonychuscitri, Panonychusulmi, Polyphagotarsonemus latus, Tarsonemus spp., Tetranychusurticae, Tetranychus cinnabarinus.
Formulation of the present invention can be in any of the formulations selected from Capsule suspension (CS), Dispersible concentrate (DC), Powder for dry seed treatment (DS), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion for foliar spray (ES), Emulsion, oil in water (EW), Flowable suspension/concentrate for foliar spray (FS), Granule/ soil applied (GR), Controlled (Slow or Fast) release granules (CR), Jambo balls or bags (bags in water soluble pouch), Solution for foliar spray (LS), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (= flowable concentrate) (SC), Suspo-emulsion (SE), Water soluble granule (SG), Soluble concentrate (SL), Water soluble powder (SP), Water dispersible granule (WG or WDG), Wettable powder (WP), Water dispersible powder for slurry treatment (WS), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW).
Further present insecticidal composition comprising bioactive amounts of (A) Selective feeding blocker; (B) Plant growth regulator; and (C) One or more insecticides; which are bioactive ingredients for the present composition are present in specific fixed ratio.
In further aspect the present invention relates to the present synergistic composition comprises bioactive amount of 0.1% to 40% w/w of Homopteran Selective Feeding Blocker; 0.001% to 20% w/w of Plant Growth Regulator; and insecticides with various mode of action in an amount of 0.1% to 40% w/w of the composition.
Active Ingredients Compound
A Compound
B Compound
C
Examples Selective Feeding Blocker Plant Growth Regulator Insecticides
% of Active Ingredient
0.1% to 40%w/w
0.001% to
20% w/w
0.1% to 40% w/w
The composition of the present invention in addition to bioactive amounts of active ingredients further comprises inactive excipients including but not limited to dispersant or dispersing agent, anti-freezing agent, anti-foam agent, wetting agent, suspension aid, disintegrating agent, thickener, slow releasing agents and buffering agent.

A wetting agent is a substance that when added to a liquid increases the spreading or penetration power of the liquid by reducing the interfacial tension between the liquid and the surface on which it is spreading. Wetting agents are used for two main functions in agrochemical formulations: during processing and manufacture to increase the rate of wetting of powders in water to make concentrates for soluble liquids or suspension concentrates; and during mixing of a product with water in a spray tank or other vessel to reduce the wetting time of wettable powders and to improve the penetration of water into water-dispersible granules.
Examples of wetting agent used herein for SC (Suspension concentrate) formulation include but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyldiphenylsulfonates, sodium isopropyl naphthalene sulfonate,alkylnaphthalene sulfonate.
Examples of wetting agent used herein for Oil dispersion (OD) formulation includes but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyldiphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkylnaphthalene sulfonate.
Examples of wetting agent used herein for SE (Suspo Emulsion) formulation includes but not limited to Ethylene oxide/propylene oxide block copolymer, Polyarylphenyl ether phosphate, Ethoxylated Fatty Alcohol, Sodium dioctyl sulfosuccinate, sodium lauryl sulphate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, Alkyl naphthalene sulfonate, Octyl phenol ethoxylate, alkyl phenol ethoxylate and aliphatic alcohol ethoxylate or mixture thereof.
Examples of wetting agent used herein for WG (Wettable Granule), WDG (Water Dispersible Granule) formulation includes but not limited to sodium N-methyl-N-oleoyl taurate, alkylated naphtalene sulfonate, sodium salt, mixture of isomers of dibutylnaphthalene sulphonic acid sodium salt, sodium diisopropylnaphthalenesulphonate, sodium Lauryl sulfate, dioctyl sulfate, alkyl naphthalene sulfonates, phosphate esters, sulphosuccinates and nonionics such as tridexyl alcohol ethoxylate, alkyl or alkaryl sulfonates such as alkylbenzene sulfonates, alpha olefin sulfonate and alkyl naphthalene sulfonates, ethoxylated or non-ethoxylated alkyl or alkyaryl carboxylates, alkyl or alkyaryl phosphate esters, alkylpolysaccharide, di or mono alkyl sulfosuccinate derivatives, alpha olefin sulfonates, alkyl naphthalene sulfonates, dialkyl sulphosuccinates, butyl, dibutyl, isopropyl and diisopropyl naphthalene sulfonate salts, C12 alkyl benzene sulfonate or C10-C16 alkyl benzene sulfonate.
Examples of wetting agent used herein for Controlled Release granule (CR) formulation includes but not limited to mono C2-6alkyl ether of a polyC2-4alkylene oxide block copolymer,condensation product of castor oil and polyC2-4alkylene oxide, alkoxylated castor oil, exthoxylated castor oil, a mono- or di-ester of a C12-24fatty acid and polyC2-4alkylene oxide, carboxylates, sulphates, sulphonates, alcohol ethoxylates, alkyl phenol ethoxylates, fatty acid ethoxylates, sorbitan esters, ethoxylated fats or oils, amine ethoxylates, phosphate esters, ethylene oxide - propylene oxide copolymers, fluorocarbons,alkyd-polyethylene glycol resin, polyalkylene glycol ether, apolyalkoxylated nonyl phenyl, alkoxylated primary alcohol, ethoxylated distyrylphenol, ethoxylated distyrylphenol sulphate, ethoxylated tristyrylphenol phosphate, tristyrylphenol phosphate ester, hydroxylated stearic acid polyalkylene glycol polymerand their corresponding salts,alkyd-polyethylene glycol resin, polyalkylene glycol ether, ethoxylated distyrylphenol, ethoxylated distyrylphenol sulphate, ethoxylated tristyrylphenol phosphate, tristyrylphenol phosphate ester, tristyrylphenol phosphate potassium salt, dodecysulfate sodium salt;
Examples of Wetting and spreading agent used herein for SC (Suspension concentrate) formulation, SE (Suspo Emulsion) formulation, CS (Capsule Suspension) and Oil dispersion (OD) formulation include but not limited to trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyether polymethyl siloxane copolymer, modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof etc; The addition of organic silicone type surfactant works as super wetting agent, speading agent, penetrating agent which improves the bioefficacy. It reduces the wash off/run off from foliage during rainy season, enhance the penetration of active ingredeints into the foliage, improve the availability of active ingredients on lower surface of leaves (i.e. translaminar action), and improve the spray coverage which is very much essential for contact action insecticides. Overall, addition of organic silicone type surfactants increases the bioefficacy and residual control period of the products which helps in reducing the number of pesticidal applications into the crop ecosystem.

A dispersant or a dispersing agent is a substance which adsorbs onto the surface of particles and helps to preserve the state of dispersion of the particles and prevents them from re-aggregating. Dispersants are added to agrochemical formulations to facilitate dispersion and suspension during manufacture, and to ensure the particles re-disperse into water in a spray tank. They are widely used in wettable powders, suspension concentrates and water-dispersible granules. Surfactants that are used as dispersants have the ability to adsorb strongly onto a particle surface and provide a charged or steric barrier to re-aggregation of particles. The most commonly used surfactants are anionic, non-ionic, or mixtures of the two types. For wettable powder formulations, the most common dispersants are sodium lingo sulphonates. In recent years, new types of very high molecular weight polymeric surfactants have been developed as dispersants. These have very long hydrophobic ‘backbones’ and a large number of ethylene oxide chains forming the ‘teeth’ of a ‘comb’ surfactant. These high molecular weight polymers can give very good long-term stability to suspension concentrates because the hydrophobic backbones have many anchoring points onto the particle surfaces.
Examples of dispersants or dispersing agent used herein for SC (Suspension concentrate) formulation include but not limited to alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Examples of dispersants or dispersing agent used herein for Oil dispersion (OD) formulation includes but not limited to alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Examples of dispersants or dispersing agent used herein for SE (Suspo Emulsion) formulation includes but not limited to alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide, polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylic polymers and copolymers, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol, vinylacetate and vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins and define copolymers and mixtures thereof. Examples of preferred polymers are acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these. Polymers that are biodegradable are also useful in the present invention. As used herein, a polymer is biodegradable if is not water soluble, but is degraded over a period of several weeks when placed in an application environment. Examples of biodegradable polymers that are useful in the present invention include biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof.
Examples of dispersants or dispersing agent used herein for WG (Wettable Granule), WDG (Water Dispersible Granule) formulation include but not limited to naphthalene sulfonic acid, sodium salt condensated with formaldehyde, polyalcoxylated alkylphenol, naphthalenesulfonic acid formaldehyde condensate, methylnaphtaline-formaldehyde-condensate sodium salt, napthalene condensates, lignosulfonates, polyacrylates and phosphate esters, calcium lignosulfonate,lignin sulfonate sodium salt;
Examples of dispersants or dispersing agent used herein for Controlled Release granule (CR) formulation includes but not limited to copolymer of propylene oxide (PO) and ethylene oxide (EO) and/or an ethoxylated tristyrene phenol, copolymer of PO and EO is alpha-butyl-omega-hydroxypoly(oxypropylene) block polymer with poly(oxyethylene), ethoxylated tristyrene phenol is alpha-[2,4,6-tris[1-(phenyl)ethyl] phenyl]-omega-hydroxy poly(oxyethylene, poly(oxy-1,2-ethanediyl)-alpha-C10-15alkyl-omega-hydroxy phosphate or sulphate and/or a C10-13alkylbenzenesulfonic acid, tristyrylphenols, nonylphenols, dinonylphenol and octylphenols, styrylphenolpolyethoxyester phosphate, alkoxylated C14-20 fatty amines;
Antifoaming agent for the present formulation is selected from various compounds and selectively used according to the formulation. Generally, there are two types of antifoam agents, namely silicones and non-silicones. Silicones are usually aqueous emulsions of dimethyl poly siloxane while the non-silicone anti-foam agents are water- insoluble oils, such as octanol and nonanol, or silica. In both cases, the function of the anti-foam agent is to displace the surfactant from the air-water interface.
Examples of Antifoaming agent used herein for SC (Suspension concentrate), Oil dispersion (OD) formulation and SE (Suspo Emulsion) formulation include but not limited to silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethylsiloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane.
Examples of Antifoaming agent used herein for WG (Wettable Granule), WDG (Water Dispersible Granule) formulation includes but not limited to polydimethylsiolxane.
Anti-freezing agent for the present formulation is selected from various compounds and selectively used according to the formulation.
Examples of Anti-freezing agent used herein for SC (Suspension concentrate) and Oil dispersion (OD) formulation and SE (Suspo Emulsion) formulation formulation include but not limited to ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.
Disintegrating agent used herein for the WG (Wettable Granule), WDG (Water Dispersible Granule) formulation is selected from citric acid, succinic acid or the sodium bicarbonate.
Preservative used herein for the SC (Suspension concentrate) formulation and Oil dispersion (OD) formulation include but not limited to 1,2-benzisothiazolin-3(2H)-one, sodium salt, Sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, Formaldehyde, Sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one.
Preservative used herein for the SE (Suspo Emulsion) formulation include but not limited to propionic acid and its sodium salt, sorbic acid and its sodium or potassium salt, benzoic acid and its sodium salt, p-hydroxy benzoic acid sodium salt; methyl p-hydroxy benzoate; and biocide such as sodium benzoate, 1,2-benzisothiazoline-3-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2- methyl-4-isothiazolin-3-one, potassium sorbate, para hydroxy benzoates or mixtures thereof.
Thickeners or gelling agents are used mainly in the formulation of suspension concentrates, emulsions and suspoemulsions to modify the rheology or flow properties of the liquid and to prevent separation and settling of the dispersed particles or droplets. Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers.
Examples of thickeners used herein for SC (Suspension concentrate) formulation include but not limited to xanthan gum, PVK, carboxymethylcelluloses, polyvinyl alcohols,gelatin, sodium carboxymethylcellulose, hydroxyethylcellulose, sodium polyacrylate, modified starch;
Examples of thickeners used herein for SE (Suspo Emulsion) formulation include various compound depending upon the nature of the composition. Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers. It is possible to produce suspension concentrate formulations using clays and silicas. Examples of these types of materials, include, but are limited to, montmorillonite, e.g. bentonite; magnesium aluminum silicate; and attapulgite. Water-soluble polysaccharides have been used as thickening-gelling agents for many years. The types of polysaccharides most commonly used are natural extracts of seeds and 15 seaweeds are synthetic derivatives of cellulose or mixtures thereof. Examples of these types of materials include, but are not limited to, guar gum; locust bean gum; carrageenam; xanthan gum; alginates; methyl cellulose; sodium carboxymethyl cellulose (SCMC); hydroxyethyl cellulose (HEC) or mixtures thereof. Other types of anti-settling agents are based on modified starches, polyacrylates, polyvinyl 20 alcohol and polyethylene oxide or mixtures.
Suspension aid or the suspending agent in the present description denotes a natural or synthetic, organic or inorganic material with which the active substance is combined in order to facilitate its application to the plant, to the seeds or to the soil. This carrier is hence generally inert, and it must be agriculturally acceptable, in particular to the plant being treated. The carrier may be solid (clays, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, and the like or mixtures thereof) or liquid (water, alcohols, ketones, petroleum fractions, aromatic or paraffinic hydrocarbons, chlorinated hydrocarbons, liquefied gases, and the like or mixtures thereof).
Examples of suspending agent used herein for SC (Suspension concentrate) formulation, SE (Suspo Emulsion) formulation include but not limited to Aluminum Magnesium Silicate, Bentonite clay, Silica, Attapulgite clay.
Slow releasing agent used herein for Controlled Release granule (CR) formulation includes but not limited to xanthan gum, PVK, carboxymethyl celluloses, polyvinyl alcohols,gelatin, sodium carboxymethylcellulose, hydroxyethylcellulose, Sodium Polyacrylate, modified starch, parafin wax, polyvinyl acetate,montan wax and vinyl acetate, polyethylene glycol 6000, cationic hydrosoluble polymer, C4 alkylated polyvinyl pyrrolidone.
Carrier for the present formulation is selected from selected from various compounds and selectively used according to the formulation.
Examples of Carrier used herein for Oil dispersion (OD) formulation include but not limited to olive oil, kapok oil, castor oil, papaya oil, camellia oil, palm oil, sesame oil, corn oil, rice bran oil, peanut oil, cotton seed oil, soybean oil, rapeseed oil, linseed oil, tung oil, sunflower oil, safflower oil, palm (Elaeis guineensis) oil, neem (azadirecha indica) oil, eucalyptus oil, karanja (Milletia pinnata/Pongamia pinnata) oil, coconut oil, alkyl ester of vegetable oils, (e.g. rapeseed oil methyl ester or rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, neem oil, tall oil fatty acids esters etc.), diesel, mineral oil, fatty acid amides (e.g. C1 -C3 amines, alkylamines or alkanolamines with C6 - Ci8 carboxylic acids), fatty acids, tall oil fatty acids, alkyl esters of fatty acids (e.g. Ci, Methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols. The above oil based carrier/diluting agents may be used as solo or mixture of two or more if desired.
Certain vegetables/plant/seed oils as a carrier, increases the bioefficacy and residual control of products through increase in penetration of active ingredients into leaf surface, improves the retention of active ingredietns on leaf surface especially on waxy leaf surface, improves the spreading properties and thereby improves the spray coverage.
Examples of Carrier used herein for WG (Wettable Granule), WDG (Water Dispersible Granule) formulation includes but not limited to china clay, silica, lactose anhydrous, ammonium sulfate, sodium sulfate anhydrous, corn starch, urea, EDTA, urea formaldehyde resin, diatomaceous earth, kaolin, bentonite, kieselguhr, fuller's earth, attapulgite clay,bole, loess, talc, chalk, dolomite, limestone, lime, calcium carbonate, powdered magnesia, magnesium oxide, magnesium sulfate, sodium chloride, gypsum, calcium sulfate, pyrophyllite, silicates and silica gels; fertilizers such as, for example, ammonium sulfate, ammonium phosphate, ammonium nitrate and urea; natural products of vegetable origin such as, for example, grain meals and flours, bark meals, wood meals, nutshell meals and cellulosic powders; and synthetic polymeric materials such as, for example, ground or powdered plastics and resins, bentonites, zeolites, titanium dioxide, iron oxides and hydroxides, aluminium oxides and hydroxides, or organic materials such as bagasse, charcoal, or synthetic organic polymers.
Examples of Carrier used herein for Controlled Release granule (CR) formulation includes but not limited to diatomaceous earth, attapulgite or zeolites, dolomite, limestone, silica, fly ash, hydrated lime, wheat flour, wood flour, ground wheat straw, cellulose and soy flour, bentonite, kaolin, attapulgite, diatomaceous earth, calcium carbonate, talc, muscovite mica, fused sodium potassium, aluminum silicate , perlite, talc and muscovite mica, urea, sulfur-coated urea, isobutylidenediurea, ammonium nitrate, ammonium sulfate, ammonium phosphate, triple super phosphate, phosphoric acid, potassium sulfate, potassium nitrate, potassium metaphosphate, potassium chloride, dipotassium carbonate, potassium oxide and a combination of these. calcium, magnesium, sulfur, iron, manganese, copper, zinc; oxides, humic acid, wood floor, calcium silicate, cellulose granules, magnesium stearate.
Solvents used herein for the Controlled Release granule (CR) formulation includes but not limited to fatty acid methyl ester, cyclohexane, xylene, mineral oil or kerosene, mixtures or substituted naphthalenes, mixtures of mono- and polyalkylated aromatics, dibutyl phthalate or dioctyl phthalate, ethylene glycol monomethyl or monoethyl ether, butyrolactone, octanol, castor oil, soybean oil, cottonseed oil , epoxidised coconut oil or soybean oil, neem (azadirechtin base) oil, aromatic hydrocarbons, dipropyleneglycolmonomethylether, polypropylene glycol [M.W. 2000-4000], polyoxyethylenepolyoxypropylene glycols, polyoxypropylenepolyoxyethylene glycols, diethyleneglycol, polyethylene glycol [M.W. 200-4000 amu], methoxy polyethylene glycols 350, 550, 750, 2000, 5000; glycerol, methyl oleate, n-octanol, alkyl phosphates such as tri-n-butyl phosphate, propylene carbonate and isoparaffinic, tetrahydrofurfuryl alcohol, gamma-butyrolactone, N-methyl-2-pyrrolidone, tetramethylurea, dimethylsulfoxide, N,N-dimethylacetamide , Diacetone alcohol, Polybutene, Propylene carbonate, Dipropylene glycol isomer mixture.

Example of solvens used herein for the SE (Suspo Emulsion) formulation includes but not limited to water, water soluble alcohols and dihydroxy alcohol ethers. Water soluble alcohol or lower alcohol (1-4 carbon atoms) includes-methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol. Macromolecular alcohol includes polyethylene glycol, sorbitol, glucitol etc., dihydroxy alcohol ethers includes dihydroxy alcohol alkyl ether or dihydroxy alcohol aryl ethers. The examples of dihydroxy alcohol alkyl ether include ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether, etc. The examples of dihydroxy alcohol aryl ethers include ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl ether, and the like. Any of the mentioned solvent can be used either alone or in combinations thereof. Paraffinic hydrocarbons, cyclohexanone, isophorone and ester solvents such as methyloleate, dimethylamide and morpholineamide derivatives of C6-C16 fatty acids, and mono-alkylene carbonates such as ethylene carbonate, propylene carbonate and butylene carbonates, dimethylsulfoxide (DMSO), 2-ethylhexanol and n-butanol, n-alkylpyrrolidones, fatty acid dimethyl esters, fatty acid esters, dibasic esters, aromatic hydrocarbons and/or aliphatic hydrocarbons, one or more dimethylamides, such as C8-dimethylamide, C10-dimethylamide, C12-dimethylamide, ethylene glycol, propylene glycol, polyalkylene glycols, aromatic hydrocarbons, methylpyrrolidinone (NMP); dimethylformamide (DMF); dimethylisosorbide (DMI); isophorone; acetophenone; 1,3-dimethyl-2-imidazolidonone; lactate esters; dimethyl and diethylcarbonates; alcohols including methanol; ethanol; iso-propanol; n-propanol; n-butanol; iso-butanol; and tert-butanol; Methyl L-lactate, 2-Ethylhexyl L-lactate, Ethyl L-lactate, n-Butyl L-lactate, Octyl phenyl ethoxylates.
Colorant used herein for the Controlled Release granule (CR) formulation includes but not limited to crystal violet, thalocyano dye chlorinated, aerosol green FFB dye, rodamine, azo compound.
Emulsifying agent used herein for the Oil dispersion (OD) formulation includes but not limited to castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkylammonium salts of alkylbenzene sulphonate, alkylsulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylenesorbitan monolaurate.
Example of emulsifier used herein for the Suspo-emulsion (SE) formulation includes but not limited to salts of dodecylbenzene sulphonate, e.g. Ca-salts or amine salts, and sulphonates of other C11-C16 alkylbenzenes, alkylether sulphates, alkylphenoletherphosphates and ester phosphates; non-ionic surfactants such as alkoxylated alcohols and alkylphenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid esters, e.g. of sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; and catanionic emulsifiers such as a cationic amine, optionally in combination with an alkylsulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkylphenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol; fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkylbenzenes in the range C11-C16 and salts thereof; alkylether sulphates; alkyletherphosphates; alkylphenoletherphosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenol; or a catanionic system, wherein a cationic amine is present in combination with an alkylsulphonate, an alkylethersulphonate, an ether sulphate, or an ether phosphate such as an alkyletherphosphate, nonylphenol polyethoxy ethanols, castor oil polyglycol ethers, polyadducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol.
Stabilizers or stabilizing agent used herein for the Oil dispersion (OD) formulation includes but not limited to hectorite clay, aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.
Examples of Stabilizers or stabilizing agent used herein for the Suspo-emulsion (SE) formulation includes but not limited to butylated hydroxytoluene (BHT) and epoxidized soybean oil (ESBO), Epichlorhydrin.
Buffering agent used herein for the SE (Suspo Emulsion) formulation includes but not limited to calcium hydroxyapatite, Potassium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.
The process for preparing the present novel synergistic composition can be modified accordingly by any person skilled in the art based on the knowledge of the manufacturing the formulation. However all such variation and modification is still covered by the scope of present invention.
The present invention highlights the synergistic effect of the combination of the at least one homopteran selective feeding blocker insecticide or mixture thereof; one of plant growth regulator; and one more insecticide or mixture thereof.
Following the right use of the invented technology and the synergistic insecticidal composition of the invention with a formulations having a multi-pesticide components i.e. pesticide mixture, formulation prepared with an extra care of physical compatibility by purposefully specially selected solvents, dispersing agents, carriers and the surfactants, thickeners, stabilizers etc. exhibits better insect-pest and mites management and boost plant health.
While the foregoing written description of the invention enables one of ordinary skill to make and use what is considered presently to be the best mode thereof, those of ordinary skill will understand and appreciate the existence of variations, combinations, and equivalents of the specific embodiment, method, and examples herein. The invention should therefore not be limited by the above described embodiment, method, and examples, but by all embodiments and methods within the scope and spirit of the invention. The invention shall now be described with reference to the following specific examples. It should be noted that the example(s) appended below illustrate rather than limit the invention, and that those skilled in the art will be able to design many alternative embodiments without departing from the scope of the present invention.
These and other aspects of the invention may become more apparent from the examples set forth herein below. These examples are provided merely as illustrations of the invention and are not intended to be construed as a limitation thereof.
EXAMPLE 1:
Pyrifluquinazon 4%+Brassinolide 0.025%+Diafenthiuron 20% OD (Oil Dispersion)
Chemical composition % (w/w)
Pyrifluquinazon a.i. 4.00
Brassinolide a.i. 0.025
Diafenthiuron a.i. 20.00
Wetting and spreading agent 5.00
Dispersing agent 4.50
Emulsifying agent 8.00
Stabilizer 1.50
Antifoaming agent 0.30
Preservative 0.20
Antifreezing agent 5.00
Carrier as solvent 51.48
Total 100.00

Stability Study:
Storage stability-Pyrifluquinazon 4%+Brassinolide 0.025%+Diafenthiuron 20% OD
Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Pyrifluquinazon content percent by mass 3.80 to 4.40 4.25 4.15 2.22
Brassinolide content percent by mass 0.02375 to 0.0275 0.025 0.025 0.025
Diafenthiuron content percent by mass 19 to 21 20.50 20.10 20.40
Pyrifluquinazon suspensibility percent min. 80 96.30 95.10 96.20
Brassinolide suspensibility percent min. 80 96.20 95.30 96.10
Diafenthiuron suspesnibility precent min. 80 97.10 96.40 97.00
pH range (1% aq. Suspension) 5.5 to 8.5 6.60 6.50 6.50
Pourability 95% min. 97.50 97.10 97.40
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 640 650 680
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 Nil 3 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Pyrifluquinazon content percent by mass 3.80 to 4.40 4.25 4.22 4.10
Brassinolide content percent by mass 0.02375 to 0.0275 0.025 0.025 0.025
Diafenthiuron content percent by mass 19 to 21 20.50 20.30 20.10
Pyrifluquinazon suspensibility percent min. 80 96.30 96.10 95.40
Brassinolide suspensibility percent min. 80 96.20 96.00 95.50
Diafenthiuron suspesnibility precent min. 80 97.10 96.80 96.10
pH range (1% aq. Suspension) 5.5 to 8.5 6.50 6.50 6.50
Pourability 95% min. 97.40 97.20 97.50
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 650 660 675
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 Nil 3 nil

Procedure: Manufacturing process for OD (Oil Dispersion) formulation:
Preparation of Oil dispersion (OD) formulation:
Part A Preparation of the liquid premix
Step 1 Charge Vegetable oil or solvent or both into a vessel with anchor stirrer.
Step 2 Under stirring, add the emulsifier and dispersing agent and stir until all ingredients are dissolved completely.
Part B Preparation of the slurry
Step 1 Now, charge the liquid premix into a second vessel, equipped with a cooling and heating device and a high shear stirrer.
Step 2 Add the active ingredient and homogenize thoroughly. Pre-mill this mixture and finally mill it using a bead mill to achieve a particle size distribution as required by the specification.
Part C Preparation of the Thickener gel
Step 1 Charge the vegetable/plant/seed oil or solvent to the vessel, equipped with a high shear stirrer.
Step 2 Add gradually the thickener which is organophilic clay, maintaining high-shear mixing throughout. Stirring is continued until thoroughly mixed.
Step 3 Under stirring, the thickener activating agent propylene carbonate is added. Allow the gel to swell whilst maintaining mixing.
Part D Preparation of the final formulation
Step 1 Now add the thickener gel or silica and disperse the mixture by using a high shear stirrer.
Step 2 Finally add the recommended wetting and spreading agent or adjuvants (silicone or non-silicone based) to this formulation and disperse by using high shear stirrer.
Step 3 Check the finished formulation to specification.
Step 4 After approval, material is packed in required pack sizes.

EXAMPLE 2:
Pyrifluquinazon 4%+Brassinolide 0.025%+Tolfenpyrad 10% OD (Oil Dispersion)
Chemical composition % (w/w)
Pyrifluquinazon a.i. 4.00
Brassinolide a.i. 0.025
Tolfenpyrad a.i. 10.00
Wetting and spreading agent 5.00
Dispersing agent 4.50
Emulsifying agent 8.00
Stabilizer 1.50
Antifoaming agent 0.30
Preservative 0.20
Antifreezing agent 5.00
Carrier as solvent 61.48
Total 100.00

Stability Study:
Storage stability-Pyrifluquinazon 4%+Brassinolide 0.025%+Tolfenpyrad 10% OD
Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Pyrifluquinazon content percent by mass 3.80 to 4.40 4.40 4.10 4.30
Brassinolide content percent by mass 0.02375 to 0.0275 0.025 0.025 0.025
Tolfenpyrad content percent by mass 9.50 to 10.50 10.40 10.20 10.30
Pyrifluquinazon suspensibility percent min. 80 96.30 95.10 96.20
Brassinolide suspensibility percent min. 80 96.20 95.30 96.10
Tolfenpyrad suspesnibility precent min. 80 97.10 96.40 97.00
pH range (1% aq. Suspension) 5.5 to 8.5 6.60 6.50 6.50
Pourability 95% min. 97.50 97.10 97.40
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 640 650 680
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 Nil 3 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Pyrifluquinazon content percent by mass 3.80 to 4.40 4.40 4.20 4.10
Brassinolide content percent by mass 0.02375 to 0.0275 0.025 0.025 0.025
Tolfenpyrad content percent by mass 9.50 to 10.50 10.40 10.30 10.20
Pyrifluquinazon suspensibility percent min. 80 97.20 96.80 96.20
Brassinolide suspensibility percent min. 80 98.20 98.20 98.00
Tolfenpyrad suspesnibility precent min. 80 96.60 96.00 95.60
pH range (1% aq. Suspension) 5.5 to 8.5 6.60 6.50 6.40
Pourability 95% min. 97.40 97.30 97.20
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 630 640 640
Particle size (micron) D50<3, D90<10 2.1,8.5 2.2,8.6 2.3,8.7
Persistent foam ml (after 1 minute) max. 60 Nil 3 nil

Procedure: Manufacturing process for OD (Oil Dispersion) formulation as per Example 1.

EXAMPLE 3:
Pyrifluquinazon 5%+Gibberellic acid 0.1%+Diafenthiuron 20% SC (Suspension Concentrate)
Chemical composition % (w/w)
Pyrifluquinazon a.i. 5.00
Gibberellic acid a.i. 0.10
Diafenthiuron a.i. 20.00
Wetting and spreading agent 3.50
Dispersing agent 1 4.50
Dispersing agent 2 1.00
Suspending agent 2.00
Antifoaming agent 0.30
Preservative 0.20
Antifreezing agent 5.00
Thickner 0.15
Diluent Water 58.25
Total 100.00
Stability Study:
Storage stability-Pyrifluquinazon 5%+Gibberellic acid 0.1%+Diafenthiuron 20% SC (Suspension Concentrate)
Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Pyrifluquinazon content percent by mass 4.75 to 5.50 5.30 5.10 5.30
Gibberellic acid content percent by mass 0.095 to 0.11 0.10 0.10 0.10
Diafenthiuron content percent by mass 19 to 21 20.50 20.10 20.40
Pyrifluquinazon suspensibility percent min. 80 96.10 95.00 96.20
Gibberellic acid suspensibility percent min. 80 97.20 96.80 96.40
Diafenthiuron suspesnibility precent min. 80 97.30 96.60 96.20
pH range (1% aq. Suspension) 5.5 to 8.5 6.60 6.50 6.60
Pourability 95% min. 97.40 97.20 97.50
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 650 660 675
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 Nil 3 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Pyrifluquinazon content percent by mass 4.75 to 5.50 5.30 5.20 5.10
Gibberellic acid content percent by mass 0.095 to 0.11 0.10 0.10 0.10
Diafenthiuron content percent by mass 19 to 21 20.50 20.30 20.10
Pyrifluquinazon suspensibility percent min. 80 96.10 95.80 95.40
Gibberellic acid suspensibility percent min. 80 97.20 96.80 96.20
Diafenthiuron suspesnibility precent min. 80 97.30 96.60 96.10
pH range (1% aq. Suspension) 5.5 to 8.5 6.60 6.60 6.50
Pourability 95% min. 97.40 97.20 97.50
Specific gravity 1.02-1.08 1.04 1.04 1.04
Viscosity at spindle no. 62, 20 rpm 350-800 cps 660 670 680
Particle size (micron) D50<3, D90<10 2.2,8.7 2.3,8.9 2.4,9.0
Persistent foam ml (after 1 minute) max. 60 Nil 3 nil

Procedure: Manufacturing process for SC (Suspension Concentrate) formulation.
Step 1 2% Gel Preparation: Charge the required quantity of water to a vessel, equipped with a high shear stirrer and start the agitation. Add the required amount of preservative. Mix until homogenous. Add the required amount of thickener and mix vigorously until it is fully wetted.
Step 2 Charge the required quantity of water to a vessel, equipped with bulk agitator and a high shear homogenizer and start agitation. Add the required amount of ant freezing agent and mix until uniform. Add the antifoaming agent and ensure that it is well dispersed. Add the wetting and dispersing agent and mix until uniform. Ensure that the dispersing agent is fully dispersed.
Step 3 Now add the active ingredient and continue agitating the vessel contents until all components get dissolved. Mill this pre-mix through a Colloid mill and subsequently through a Dyno mill to meet the specified particle size.
Step 4 Now add remaining antifoaming agent to this SC mill base to a vessel, equipped with bulk agitator. Mix until uniform. Add the required amount of 2% aqueous pre-gel and suspending agent and continue agitation until the formulation is homogeneous and has the target viscosity is reached.
Step 5 Final product is sent for QC approval.
Step 6 After approval, material is packed in required pack sizes.

EXAMPLE 4:
Flonicamid 5 %+Brassinolide 0.025%+Tolfenpyrad 5% SE (Suspo Emulsion)
Chemical composition % (w/w)
Flonicamid a.i. 5.00
Brassinolide a.i. 0.025
Tolfenpyrad a.i. 10.00
Solvent 10.00
Wetting and spreading agent 3.50
Dispersing agent 1 4.50
Dispersing agent 2 1.00
Suspending agent 2.00
Antifoaming agent 0.30
Preservative 0.20
Antifreezing agent 5.00
Thickner 0.15
Diluent Water 58.33
Total 100.00

Stability Study:
Storage stability-Flonicamid 5%+Brassinolide 0.025%+Tolfenpyrad 10% SE (Suspo Emulsion)
Laboratory storage for 14 days
Parameters Specification
(in house) Initial At 54±2 0C At 0±2 0C
Flonicamid content percent by mass 4.75 to 5.50 5.30 5.10 5.20
Brassinolide content percent by mass 0.024 to 0.028 0.0260 0.0260 0.0260
Tolfenpyrad content percent by mass 9.50 to 10.50 10.40 10.10 10.30
Flonicamid suspensibility percent min. 80 96.14 95.15 96.03
Brassinolide suspensibility percent min. 80 97.16 97.10 96.80
Tolfenpyrad suspesnibility precent min. 80 97.15 97.12 96.80
pH range (1% aq. Suspension) 5.5 to 8.5 6.30 6.50 6.35
Pourability 95% min. 97.40 97.20 97.50
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 650 660 675
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 3 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Flonicamid content percent by mass 4.75 to 5.50 5.30 5.20 5.10
Brassinolide content percent by mass 0.024 to 0.028 0.0260 0.0260 0.0260
Tolfenpyrad content percent by mass 9.50 to 10.50 10.40 10.30 10.20
Flonicamid suspensibility percent min. 80 95.20 94.80 94.20
Brassinolide suspensibility percent min. 80 96.70 96.70 96.60
Tolfenpyrad suspesnibility precent min. 80 97.20 96.40 95.20
pH range (1% aq. Suspension) 5.5 to 8.5 6.60 6.50 6.40
Pourability 95% min. 97.70 97.40 97.10
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 630 650 670
Particle size (micron) D50<3, D90<10 2.0,8.5 2.1,8.6 2.2,8.7
Persistent foam ml (after 1 minute) max. 60 Nil 3 nil

Procedure: Manufacturing process of Suspo Emulsion (SE) formulation
Manufacturing process of Suspo Emulsion (SE) formulation:
Step 1 2% Gel Preparation: Charge the required quantity of water to a vessel, equipped with a high shear stirrer and start the agitation. Add the required amount of preservative. Mix until homogenous. Add the required amount of thickener and mix vigorously until it is fully wetted.
Step 2 Oil Phase: Charge solvent into the vessel and then add active technical slowly and if required, heat it for 500C so that technical can be dissolved in solvent and then add emulsifier.
Step 3 Charge the required quantity of water to a vessel, equipped with bulk agitator and a high shear homogenizer and start agitation. Add the required amount of ant freezing agent and mix until uniform. Add the antifoaming agent and ensure that it is well dispersed. Add the wetting and spreading agent and dispersing agent and mix until uniform. Ensure that the dispersing agent is fully dispersed.
Step 4 Now add the active ingredient and continue agitating the vessel contents until all components get dissolved. Mill this pre-mix through a Colloid mill and subsequently through a Dyno mill to meet the specified particle size.
Step 5 Now add remaining antifoaming agent to this mill base to a vessel, equipped with bulk agitator. Mix until uniform.
Step 6 Now add oil phase in aqueous phase and stir for 30 minutes using homogenizer.

Step 7
Add the required amount of 2% aqueous pre-gel and also suspending agent and continue agitation until the formulation is homogeneous and has the target viscosity. Mix well.
Step 8 Step 8-Final product is sent for QC approval.
Step 9 Step 9-After approval, material is packed in required pack sizes.

EXAMPLE 5:
Pymetrozine 15%+ Mepiquat chloride 4% +Triflumezopyrim 3% WG (Water dispersible granule/Wettable Granule)
Chemical composition % (w/w)
Pymetrozine a.i. 15.00
Mepiquat chloride a.i. 4.00
Triflumezopyrim a.i. 3.00
Wetting agent 3.00
Dispersing agent I 6.00
Dispersing agent II 2.00
Disintegrating agent 0.50
Antifoaming agent 1.00
Carrier 65.50
Total 100.00

Stability Study:
Storage stability-Pymetrozine 15%+ Mepiquat chloride 4% +Triflumezopyrim 3% WG
Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Pymetrozine content percent by mass 14.25 to 15.75 15.50 15.20 15.40
Mepiquat chloride content percent by mass 3.80 to 4.20 4.15 4.08 4.12
Triflumezopyrim content percent by mass 2.85 to 3.15 3.10 3.02 3.08
Pymetrozine suspensibility percent min. 70 97.20 96.80 97.10
Mepiquat chloride suspensibility percent min. 70 96.80 96.40 96.70
Triflumezopyrim suspensibility percent min. 70 97.60 97.20 97.50
pH range (1% aq. Suspension) 6.0 to 9.0 7.30 7.30 7.30
Wettability sec. max. 60 8 9 9
Wet sieve (45 micron) percent by mass min. 98.5 99.5 99.2 99.3
Bulk density (g/ml) 0.45 to 0.65 0.48 0.48 0.48
Moisture content percent by mass max. max. 2% 2 2 2
Room temperature storage stability up to 12 months
Parameters specification (in house) 1 month 6 months 12 months
Pymetrozine content percent by mass 14.25 to 15.75 15.50 15.30 15.20
Mepiquat chloride content percent by mass 3.80 to 4.20 4.15 4.10 4.05
Triflumezopyrim content percent by mass 2.85 to 3.15 3.10 3.08 3.04
Pymetrozine suspensibility percent min. 70 97.80 97.20 96.80
Mepiquat chloride suspensibility percent min. 70 96.80 96.40 95.90
Triflumezopyrim suspensibility percent min. 70 97.50 97.10 96.50
pH range (1% aq. Suspension) 6.0 to 9.0 7.50 7.50 7.50
Wettability sec. max. 60 8 9 9
Wet sieve (45 micron) percent by mass min. 98.5 99.5 99.5 99.5
Bulk density (g/ml) 0.45 to 0.65 0.48 0.48 0.48
Moisture content percent by mass max. max. 2% 2 2 2

Procedure: Manufacturing process of Water Dispersible Granules (WG) by extrusion method

Step 1 Charge the required quantity of filler, wetting agent, dispersing agent, and suspending agent, & technical in premixing blender for homogenization for 30 minutes.
Step 2 Pre-blended material is then grinded through Jet mill/ air classifier mills. Finely grinded material is blended in post blender till it becomes homogeneous. (Forapprox. 1.5 hr.)
Step 3 Finely grinded powder is mixed with required quantity of water to form extrudable dough.
Step 4 Dough is passed through extruder to get granules of required size.
Step 5 Wet granules are passed through Fluidized bed drier and further graded using vibrating screens.
Step 6 Final product is sent for QC approval.
Step 7 After approval material is packed in required pack sizes.

Procedure: Manufacturing process of Water Dispersible Granules (WG) by spray dried method

Step 1 Charge required quantity of DM water need to be taken in designated vessel for production.
Step 2 Add required quantity of Wetting agent, dispersing agent, antifoam & suspending agents and homogenize the contents for 45 – 60 minutes using high shear homogenizer.
Step 3 Add required quantity technical and homogenized to get uniform slurry ready for grinding.
Step 4 Now material is subjected to grinding in Bead mill till desired particle size is achieved.
Step 5 After grinding process completes the material is sprayed at required temperature.
Step 6 After completion of spray drying process material is collected and sent for QC department approval.
Step 7 After approval material is packed in required pack sizes.

EXAMPLE 6:
Pymetrozine 2%+Paclobutrazol 0.5%+Triflumezopyrim 0.5% GR (Controlled Release)
Chemical composition % (w/w)
Pymetrozine a.i. 2.00
Paclobutrazol a.i. 0.50
Triflumezopyrim a.i. 0.50
Wetting agent 3.00
Dispersing agent 1.00
Slow release agent (all) 20.00
Colourant 0.50
Solvent 4.00
Carrier 68.50
Total 100.00

Stability Study:
Storage stability of Granule (GR) formulation of Pymetrozine 2%+ Paclobutrazol 0.125%+Triflumezopyrim 1%
Laboratory storage stability for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Pymetrozine content percent by mass 1.90 to 2.20 2.15 2.05 2.10
Paclobutrazol content percent by mass 0.475 to 0.55 0.520 0.510 0.518
Triflumezopyrim content percent by mass 0.475 to 0.55 0.52 0.51 0.52
pH range (1% aq. Suspension) 4.0 to 8.5 7.20 7.20 7.20
Dustiness < 20 mg 10 10 10
Dry sieve (300 micron) percent by mass min. > 90% 99.5 99.2 99.3
Attrition Resistance (<100 micron) < 5% 2.1 2.1 2.1
Bulk density (g/ml) 1.25 to 1.50 1.3 1.3 1.3
Moisture content percent by mass max. max. 2% 1 1 1
Room temperature storage stability
Parameters specification (in house) 1 month 6 months 12 months
Pymetrozine content percent by mass 1.90 to 2.20 2.15 2.10 2.05
Paclobutrazol content percent by mass 0.475 to 0.55 0.520 0.515 0.510
Triflumezopyrim content percent by mass 0.475 to 0.55 0.52 0.51 0.50
pH range (1% aq. Suspension) 4.0 to 8.5 7.50 7.50 7.50
Dustiness < 20 mg 12 11 12
Dry sieve (300 micron) percent by mass min. > 90% 99.5 99.4 99.3
Attrition Resistance (<100 micron) < 5% 2.1 2.1 2.1
Bulk density (g/ml) 1.25 to 1.50 1.3 1.3 1.3
Moisture content percent by mass max. max. 2% 0.9 1 1.1

Procedure: Manufacturing process for GR (Controlled Release) formulation.
Preparation of GR (Controlled/slow release) formulation:
Part A Preparation of active ingredient A slurry for Bentonite Granules
Step 1 Load the Bentonite Granule carrier into an appropriate blender equipped with a heating jacket.
Step 2 Charge water to a vessel, equipped with a high shear stirrer. Under stirring, add Dispersing and wetting agent. Continue stirring until the mixture gets homogenized. Then, again under the stirring add the active ingredient A technical to the vessel.
Step 3 Pass the whole mixed mass through a bead-mill until specified particle size is achieved. Homogenize the milled suspension thoroughly.
Step 4 Under gentle stirring, add Slow releasing agent 1 to milled slurry. Continue to stir until the suspension is thoroughly mixed.
Step 5 Spray this slurry on Blank Bentonite granules by means of suitable spray nozzle and mix until uniform.
Part B Preparation of active ingredient B slurry for Bentonite Granules
Step 1 Mix the active ingredient B technical and solvent along with suitable Emulsifiers and wetting agent and make a solution.
Step 2 Now add Slow releasing agent 2 to this slurry and mix until uniform.
Step 3 Spray this slurry on active ingredient A treated Bentonite granules by means of suitable spray nozzle and mix until uniform.
Part C Preparation of active ingredient C slurry for Bentonite Granules
Step 1 Charge Water, colorant and the active ingredient C to the vessel, equipped with a high shear stirrer. Under stirring, add the thickener gradually. Now add Paraffin wax and continue to stir after the addition is completed and until the mixture is thoroughly mixed.
Step 2 Now charge active ingredient C gel solution onto these granules by means of suitable spray nozzle and mix until uniform.
Step 3 Now add China clay and Silica on these coated Bentonite granules to make them free-flowing and mix until uniform.
Step 4 Dry the granules in the blender to about 40 – 450C. The final product should be a free flowing, non-sticky granule
Step 5 Final product is sent for QC approval.
Step 6 After approval, material is packed in required pack sizes.

EXAMPLE 7:
Most Preferred formulations:
Compound A-Selective feeding blocker Compound B-Plant health regulator Compound C-Insecticide(s) Active ingredients (%) Formulation Strength (%) Formulation Type
A B C
Pyrifluquinazon Brassinolide Diafenthiuron 4 0.025 20 24.03 OD
Flonicamid Brassinolide Diafenthiuron 4 0.025 20 24.03 SC
Afidopyropen Brassinolide Diafenthiuron 4 0.025 20 24.03 SE
Pyrifluquinazon Brassinolide Tolfenpyrad 4 0.025 10 14.03 OD
Flonicamid Brassinolide Tolfenpyrad 5 0.025 10 15.03 SC
Pymetrozine Brassinolide Tolfenpyrad 10 0.025 10 20.03 SE
Pyrifluquinazon Gibberellic acid Diafenthiuron 5 0.1 20 25.10 SC
Pyrifluquinazon Gibberellic acid Pyriproxyfen 5 0.1 5 10.10 SE
Pyrifluquinazon Gibberellic acid Spiromesifen 10 0.2 20 30.20 OD
Pyrifluquinazon Gibberellic acid Spirotetramat 10 0.2 10 20.20 OD
Pyrifluquinazon Gibberellic acid Spiropidion 10 0.2 10 20.20 SC
Pyrifluquinazon Gibberellic acid Dimpropyridaz 8 0.2 10 18.20 SC
Pyrifluquinazon Gibberellic acid Lambda cyhalothrin 8 0.2 4 12.20 ZC
Pyrifluquinazon Gibberellic acid Tolfenpyrad 8 0.2 15 23.20 SE
Pyrifluquinazon Gibberellic acid Dinotefuran 8 0.2 4 12.20 SC
Flonicamid Gibberellic acid Diafenthiuron 5 0.1 20 25.10 SC
Flonicamid Gibberellic acid Pyriproxyfen 5 0.1 5 10.10 SE
Flonicamid Gibberellic acid Spiropidion 5 0.1 5 10.10 SC
Flonicamid Brassinolide Fipronil 15 0.1 15 30.10 WG
Flonicamid Brassinolide Emamectin benzoate 15 0.1 2.5 17.60 WG
Flonicamid Brassinolide Lambda cyhalothrin 9 0.06 4 13.06 ZC
Pyrifluquinazon Brassinolide Diafenthiuron 6 0.033 30 36.03 SC
Pyrifluquinazon Gibberellic acid Diafenthiuron 5 0.1 25 30.10 SC
Pyrifluquinazon Triacontanol Diafenthiuron 5 0.025 25 30.03 SC
Pyrifluquinazon Paclobutrazol Diafenthiuron 5 4 25 34.00 SC
Pyrifluquinazon Mepiquat chloride Diafenthiuron 5 4 25 34.00 SC
Pyrifluquinazon Brassinolide Pyriproxyfen 5 0.025 5 10.03 SE
Pyrifluquinazon Triacontanol Pyriproxyfen 5 0.025 5 10.03 SE
Pyrifluquinazon Paclobutrazol Pyriproxyfen 5 4 5 14.00 SE
Pyrifluquinazon Mepiquat chloride Pyriproxyfen 5 3 5 13.00 SE
Pyrifluquinazon Brassinolide Spiromesifen 10 0.05 20 30.05 SC
Pyrifluquinazon Gibberellic acid Spiromesifen 10 0.2 20 30.20 OD
Pyrifluquinazon Triacontanol Spiromesifen 10 0.05 20 30.05 SC
Pyrifluquinazon Paclobutrazol Spiromesifen 6.67 5.33 13.33 25.33 SC
Pyrifluquinazon Brassinolide Spirotetramat 10 0.05 10 20.05 SC
Pyrifluquinazon Gibberellic acid Spirotetramat 10 0.2 10 20.20 OD
Pyrifluquinazon Triacontanol Spirotetramat 10 0.05 10 20.05 SC
Pyrifluquinazon Paclobutrazol Spirotetramat 10 8 10 28.00 SC
Pyrifluquinazon Mepiquat chloride Spirotetramat 6.67 4 6.67 17.34 SC
Pyrifluquinazon Brassinolide Dinotefuran 10 0.05 4 14.05 WG
Pyrifluquinazon Gibberellic acid Dinotefuran 8 0.2 4 12.20 SC
Pyrifluquinazon Triacontanol Dinotefuran 10 0.05 4 14.05 WG
Pyrifluquinazon Paclobutrazol Dinotefuran 10 8 4 22.00 WG
Pyrifluquinazon Mepiquat chloride Dinotefuran 10 6 4 20.00 WG
Pyrifluquinazon Brassinolide Emamectin benzoate 10 0.05 4 14.05 SC
Pyrifluquinazon Gibberellic Acid Emamectin benzoate 10 0.2 4 14.20 SC
Pyrifluquinazon Triacontanol Emamectin benzoate 10 0.05 4 14.05 SC
Pyrifluquinazon Paclobutrazol Emamectin benzoate 10 8 4 22.00 SC
Pyrifluquinazon Brassinolide Acephate 5 0.025 50 55.03 WG
Pyrifluquinazon Gibberellic Acid Acephate 5 0.1 50 55.10 WG
Pyrifluquinazon Triacontanol Acephate 5 0.025 50 55.03 WG
Pyrifluquinazon Brassinolide Lambda cyhalothrin 8 0.05 4 12.05 ZC
Pyrifluquinazon Gibberellic acid Lambda cyhalothrin 8 0.2 4 12.20 ZC
Pyrifluquinazon Triacontanol Lambda cyhalothrin 8 0.05 4 12.05 ZC
Pyrifluquinazon Paclobutrazol Lambda cyhalothrin 8 8 4 20.00 ZC
Flonicamid Gibberellic acid Dimpropyridaz 5 0.1 5 10.10 SC
Flonicamid Brassinolide Diafenthiuron 5 0.025 22.5 27.53 SC
Flonicamid Gibberellic Acid Diafenthiuron 5 0.1 25 30.10 SC
Flonicamid Triacontanol Diafenthiuron 5 0.025 25 30.03 SC
Flonicamid Paclobutrazol Diafenthiuron 5 4 25 34.00 SC
Flonicamid Mepiquat chloride Diafenthiuron 5 3 25 33.00 SC
Flonicamid Brassinolide Pyriproxyfen 5 0.025 5 10.03 SE
Flonicamid Gibberellic Acid Pyriproxyfen 5 0.1 5 10.10 SE
Flonicamid Triacontanol Pyriproxyfen 5 0.025 5 10.03 SE
Flonicamid Paclobutrazol Pyriproxyfen 5 4 5 14.00 SE
Flonicamid Mepiquat chloride Pyriproxyfen 5 3 5 13.00 SE
Flonicamid Brassinolide Spirotetramat 10 0.05 10 20.05 SC
Flonicamid Gibberellic Acid Spirotetramat 10 0.2 10 20.20 SC
Flonicamid Triacontanol Spirotetramat 10 0.05 10 20.05 SC
Flonicamid Paclobutrazol Spirotetramat 10 8 10 28.00 SC
Flonicamid Mepiquat chloride Spirotetramat 6.67 4 6.67 17.34 SC
Flonicamid Brassinolide Dinotefuran 10 0.05 5 15.05 WG
Flonicamid Gibberellic Acid Dinotefuran 10 0.2 5 15.20 WG
Flonicamid Triacontanol Dinotefuran 10 0.05 5 15.05 WG
Flonicamid Paclobutrazol Dinotefuran 10 8 5 23.00 WG
Flonicamid Mepiquat chloride Dinotefuran 10 6 5 21.00 WG
Flonicamid Brassinolide Emamectin benzoate 10 0.05 4 14.05 SC
Flonicamid Gibberellic Acid Emamectin benzoate 10 0.2 4 14.20 SC
Flonicamid Triacontanol Emamectin benzoate 10 0.05 4 14.05 SC
Flonicamid Paclobutrazol Emamectin benzoate 10 8 4 22.00 SC
Flonicamid Mepiquat chloride Emamectin benzoate 10 6 4 20.00 SC
Flonicamid Gibberellic Acid Profenofos 5 0.1 25 30.10 EC
Flonicamid Triacontanol Profenofos 5 0.025 25 30.03 EC
Flonicamid Mepiquat chloride Profenofos 5 3 25 33.00 EC
Flonicamid Brassinolide Acephate 5 0.025 50 55.03 WG
Flonicamid Gibberellic Acid Acephate 5 0.1 50 55.10 WG
Flonicamid Triacontanol Acephate 5 0.025 50 55.03 WG
Flonicamid Paclobutrazol Acephate 5 4 50 59.00 WG
Flonicamid Mepiquat chloride Acephate 5 3 50 58.00 WG
Flonicamid Brassinolide Lambda cyhalothrin 8 0.05 5 13.05 ZC
Flonicamid Gibberellic Acid Lambda cyhalothrin 8 0.2 8 16.20 ZC
Flonicamid Triacontanol Lambda cyhalothrin 8 0.05 8 16.05 ZC
Flonicamid Paclobutrazol Lambda cyhalothrin 8 8 4 20.00 ZC
Flonicamid Mepiquat chloride Lambda cyhalothrin 8 6 4 18.00 ZC
Afidopyropen Brassinolide Diafenthiuron 4 0.025 22.5 26.53 SE
Afidopyropen Gibberellic Acid Diafenthiuron 4 0.1 22.5 26.60 SE
Afidopyropen Triacontanol Diafenthiuron 4 0.025 22.5 26.53 SE
Afidopyropen Paclobutrazol Diafenthiuron 4 4 22.5 30.50 SE
Afidopyropen Mepiquat chloride Diafenthiuron 4 3 22.5 29.50 SE
Afidopyropen Brassinolide Pyriproxyfen 4 0.025 7.5 11.53 SC
Afidopyropen Gibberellic Acid Pyriproxyfen 4 0.1 7.5 11.60 SC
Afidopyropen Triacontanol Pyriproxyfen 4 0.025 7.5 11.53 SC
Afidopyropen Paclobutrazol Pyriproxyfen 4 4 7.5 15.50 SC
Afidopyropen Mepiquat chloride Pyriproxyfen 4 3 7.5 14.50 SC
Afidopyropen Brassinolide Spiromesifen 5 0.05 20 25.05 OD
Afidopyropen Gibberellic Acid Spiromesifen 5 0.2 20 25.20 OD
Afidopyropen Triacontanol Spiromesifen 5 0.05 20 25.05 OD
Afidopyropen Paclobutrazol Spiromesifen 5 8 20 33.00 OD
Afidopyropen Mepiquat chloride Spiromesifen 5 5 20 30.00 OD
Afidopyropen Brassinolide Spirotetramat 5 0.05 10 15.05 SC
Afidopyropen Gibberellic Acid Spirotetramat 5 0.2 10 15.20 SC
Afidopyropen Triacontanol Spirotetramat 5 0.05 10 15.05 SC
Afidopyropen Paclobutrazol Spirotetramat 5 8 10 23.00 SC
Afidopyropen Mepiquat chloride Spirotetramat 5 5 10 20.00 SC
Afidopyropen Brassinolide Dinotefuran 5 0.05 5 10.05 WG
Afidopyropen Gibberellic Acid Dinotefuran 5 0.2 5 10.20 WG
Afidopyropen Triacontanol Dinotefuran 5 0.05 5 10.05 WG
Afidopyropen Paclobutrazol Dinotefuran 5 8 5 18.00 WG
Afidopyropen Mepiquat chloride Dinotefuran 5 6 5 16.00 WG
Afidopyropen Brassinolide Emamectin benzoate 5 0.05 2 7.05 SC
Afidopyropen Gibberellic Acid Emamectin benzoate 5 0.2 2 7.20 SC
Afidopyropen Triacontanol Emamectin benzoate 5 0.05 2 7.05 SC
Afidopyropen Paclobutrazol Emamectin benzoate 5 8 2 15.00 SC
Afidopyropen Brassinolide Profenofos 2.5 0.025 25 27.53 EC
Afidopyropen Gibberellic Acid Profenofos 2.5 0.1 25 27.60 EC
Afidopyropen Triacontanol Profenofos 2.5 0.025 25 27.53 EC
Afidopyropen Paclobutrazol Profenofos 2.5 4 25 31.50 EC
Afidopyropen Mepiquat chloride Profenofos 2.5 3 25 30.50 EC
Afidopyropen Brassinolide Acephate 2.5 0.025 25 27.53 WG
Afidopyropen Gibberellic Acid Acephate 2.5 0.1 25 27.60 WG
Afidopyropen Triacontanol Acephate 2.5 0.025 25 27.53 WG
Afidopyropen Paclobutrazol Acephate 2.5 4 25 31.50 WG
Afidopyropen Mepiquat chloride Acephate 2.5 3 25 30.50 WG
Afidopyropen Brassinolide Lambda cyhalothrin 5 0.05 5 10.05 ZC
Afidopyropen Gibberellic Acid Lambda cyhalothrin 5 0.2 5 10.20 ZC
Afidopyropen Triacontanol Lambda cyhalothrin 5 0.05 5 10.05 ZC
Afidopyropen Paclobutrazol Lambda cyhalothrin 5 8 5 18.00 ZC
Afidopyropen Mepiquat chloride Lambda cyhalothrin 5 6 5 16.00 ZC
Pymetrozine Brassinolide Clothianidin 25 0.05 25 50.05 WG
Pymetrozine Gibberellic Acid Thiamethoxam 25 0.2 25 50.20 WG
Pymetrozine Triacontanol Thiamethoxam 25 0.05 25 50.05 WG
Pymetrozine Paclobutrazol Thiamethoxam 25 5 25 55.00 WG
Pymetrozine Brassinolide Dinotefuran 15 0.05 5 20.05 WG
Pymetrozine Gibberellic Acid Dinotefuran 15 0.2 5 20.20 WG
Pymetrozine Triacontanol Dinotefuran 15 0.05 5 20.05 WG
Pymetrozine Paclobutrazol Dinotefuran 15 5 5 25.00 WG
Pymetrozine Mepiquat chloride Dinotefuran 15 4 5 24.00 WG
Pymetrozine Brassinolide Triflumezopyrim 15 0.05 3 18.05 WG
Pymetrozine Gibberellic Acid Triflumezopyrim 15 0.2 3 18.20 WG
Pymetrozine Triacontanol Triflumezopyrim 15 0.05 3 18.05 WG
Pymetrozine Paclobutrazol Triflumezopyrim 15 5 3 23.00 WG
Pymetrozine Mepiquat chloride Triflumezopyrim 15 4 3 22.00 WG
Pymetrozine Brassinolide Triflumezopyrim 2 0.003 0.5 2.50 GR
Pymetrozine Triacontanol Triflumezopyrim 2 0.125 0.5 2.63 GR
Pymetrozine Paclobutrazol Triflumezopyrim 2 0.5 0.5 3.00 GR-CR
Pymetrozine Mepiquat chloride Triflumezopyrim 2 0.5 0.5 3.00 GR
Pymetrozine Brassinolide Clothianidin 2 0.003 1 3.00 GR
Pymetrozine Triacontanol Clothianidin 2 0.125 1 3.13 GR
Pymetrozine Paclobutrazol Clothianidin 2 0.5 1 3.50 GR-CR
Pymetrozine Mepiquat chloride Clothianidin 2 0.5 1 3.50 GR
Pymetrozine Brassinolide Thiamethoxam 2 0.003 1.2 3.20 GR
Pymetrozine Triacontanol Thiamethoxam 2 0.125 1.2 3.33 GR
Pymetrozine Paclobutrazol Thiamethoxam 2 0.5 1.2 3.70 GR-CR
Pymetrozine Mepiquat chloride Thiamethoxam 2 0.5 1.2 3.70 GR
Pymetrozine Trinexapac ethyl Triflumezopyrim 20 5 3 28.00 OD
Pymetrozine Trinexapac ethyl Clothianidin 20 5 3 28.00 OD
Pymetrozine Trinexapac ethyl Thiamethoxam 20 5 3 28.00 OD
Pymetrozine Trinexapac ethyl Dinotefuran 20 5 3 28.00 OD

The composition of the present invention in addition to bioactive amounts of active ingredients further comprises inactive excipients including but not limited to dispersant, anti-freezing agent, anti-foam agent, wetting agent, suspension aid, disintegrating agent, antimicrobial agent, thickener, quick coating agent or sticking agents, emulsifying agent, filler, binders, anti-caking agents, absorbents and buffering agent.

The process for preparing the present synergistic composition can be modified accordingly by any person skilled in the art based on the knowledge of the manufacturing the formulation. However all such variation and modification is still covered by the scope of present invention.
BIOLOGICAL EXAMPLES:
A synergistic effect exists wherever the action of a combination of active ingredient is greater than the sum of the action of each of the components alone. Therefore a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticidal activity than the sum of the pesticidal activities of the individual components.
In the field of agriculture, it is often understood that the term “synergy” is as defined by Colby S.R. in an article entitled “ Calculation of the synergistic and antagonistic responses of herbicide combinations” published in the journal Weeds, 1967, 15, p.20-22, incorporated herein by reference in its entirety. The action expected for a given combination of two or three active components can be calculated as follows:

FIELD BIO-EFFICACY STUDIES:
The field trials has been carried out on different crops to judge the synergism and benefits of invention in comparison to prior arts.

EXAMPLE 8:
Experiment 1: Control of sucking pests of cotton
Crop : Cotton,
Location : Idar, Gujarat
Treatments : 16
Plot size : 40 sq.m
Spacing : 120 cm x 60 cm
Time of Application : As soon as sucking pests reached 5-10 insects per leaf. Two continuous spray applied at 15 days interval.
Method of Application: Foliar spray with knapsack sprayer
Water volume : 400 liter/hectare
Agronomic Practices : All agronomic practices followed as per the crop requirement.
Observation Methods:
Sucking pests (Whitefly Bemisiatabaci) control (%): Count the number of insects per leaf. Observed 3 leaves per plant and 5 plants per plot.
Record the observations on 3, 7, 10 and 15 days after spray. Calculate % insect control by given formula.

% Insect control data used to check the synergism by applying Colby’s formula given above.
Fruiting bodies count:
Count the number of fruiting bodies (square, flowers and balls) per plant. Record the
observations from 5 plants per plot at 15 days after second spray.
Table 1: Treatment details for bio-efficacy against sucking pests in cotton

Treatment number Treatment details with application Rate (ml or g per Hectare)
T1 (Pyrifluquinazon 4%+Brassinolide 0.025%+Diafenthiuron 20%) OD-1000 ml (ready-mix)
T2 (Flonicamid 4%+Brassinolide 0.025%+Diafenthiuron 20%) SC-1000 ml (ready-mix)
T3 (Afidopyropen 4%+Brassinolide 0.025%+Diafenthiuron 20%) SC-1000 ml (ready-mix)
T4 Brassinolide 0.04% L-625 ml+Pyrifluquinazon 20% SC-200 ml (prior art)
T5 Brassinolide 0.04% L-625 ml+Flonicamid 50% WG-80 g (prior art)
T6 Brassinolide 0.04% L-625 ml+Afidopyropen 5% DC-800 ml (prior art)
T7 Diafenthiuron 50% WP-400 g+Pyrifluquinazon 20% SC-200 ml (prior art)
T8 Diafenthiuron 50% WP-400 g+Flonicamid 50% WG-80 g (prior art)
T9 Diafenthiuron 50% WP-400 g+Afidopyropen 5% DC-800 ml (prior art)
T10 Diafenthiuron 50% WP-400 g+Brassinolide 0.04% L-625 ml (prior art)
T11 Pyrifluquinazon 20% SC-200 ml
T12 Flonicamid 50% WG-80 g
T13 Afidopyropen 5% DC-800 ml
T14 Brassinolide 0.04% L-625 ml
T15 Diafenthiuron 50% WP-400 g
T16 UTC (Untreated Check)

Table 2: Control of sucking pests of cotton
Treatment number % Whitefly control at 3 DAA Synergism (Y/N) % Whitefly control Average number of fruiting bodies/plants
Obs. Value Cal. Value Colby's ratio 7 DAA 10 DAA 15 DAA
T1 99.6 89.06 1.12 Y 93.4 85.40 73.20 154.2
T2 96.8 87.23 1.11 Y 89.6 80.40 70.40 156.8
T3 97.2 88.51 1.10 Y 88.8 79.40 68.80 152.4
T4 66.6 67.64 0.98 N 57.2 51.40 42.60 128.7
T5 61.8 62.21 0.99 N 50.8 40.20 26.40 124.9
T6 65.6 66.01 0.99 N 53.8 39.20 14.80 122.3
T7 86.8 87.90 0.99 N 81.4 70.40 56.80 131.4
T8 85.2 85.87 0.99 N 78.6 68.20 53.40 130.6
T9 86.6 87.29 0.99 N 79.2 65.40 48.60 132.2
T10 67.8 69.44 0.98 N 59.4 29.60 5.20 118.6
T11 64.2 56.4 45.4 37.4 118.3
T12 58.2 49.6 34.8 18.8 109.7
T13 62.4 52.6 30.4 15.2 105.6
T14 9.6 4.2 2.6 0.8 100.5
T15 66.2 59.4 33.4 10.6 102.8
T16 0.0 0.0 0 0 95.2

All innovative ready mix formulations (T1,T2 and T3) shows synergism in terms of efficacy against cotton whitefly and provides better residual control in comparison to all prior art treatments. The readymix formulations (T1, T2 and T3) also produces higher number of fruiting bodies (square, flowers, bolls) which are directly contributing to the yield.

EXAMPLE 9:
Experiment 2: Bioefficacy against insect pests infesting brinjal crop
Crop & Variety : Brinjal, Dolly
Location : Anand, Gujarat
Treatments : 29
Plot size : 25sq.m
Spacing : 90cm x 45 cm
Time of Application : As soon as moderate infestation (>10 insect/leaf) sucking pests observed.
Method of Application:Foliar spray with knap sack sprayer.
Water volume : 500 liter per hectare
Agronomic Practices : All agronomic practices followed as per the crop requirement.
Observation Methods:
Sucking pests (Whitefly Bemisiatabaci&JassidAmrascabiguttulabiguttula)
control (%): same as given in experiment 1.
Fruit and Flower count: same as given in experiment 1.

Table 3: Treatment details for bioefficacy evaluation of ready mix formulations in brinjal crop

Treatment number Treatment details with application Rate (ml or g per Hectare)
T1 Pyrifluquinazon 5%+Gibberellic acid 0.1%+Diafenthiuron 20% SC-1000 ml (ready-mix)
T2 Pyrifluquinazon 10%+Gibberellic acid 0.2%+Spiropidion 10% SC-500 ml (ready-mix)
T3 Pyrifluquinazon 8%+Gibberellic acid 0.2%+Dimpropyridaz 10% SC-500 ml (ready-mix)
T4 Pyrifluquinazon 8%+Gibberellic acid 0.2%+Lambda cyhalothrin 4% ZC-500 ml (ready-mix)
T5 Pyrifluquinazon 8%+Gibberellic acid 0.2%+Tolfenpyrad 15% SE-500 ml (ready-mix)
T6 Pyrifluquinazon 8%+Gibberellic acid 0.2%+Dinotefuran 4% SC-500 ml (ready-mix)
T7 Gibberellic acid 40% WSG-2.5 g+Diafenthiuron 50% WP-400 g (prior art)
T8 Gibberellic acid 40% WSG-2.5 g+Spiropidion 10% SC-500 ml (prior art)
T9 Gibberellic acid 40% WSG-2.5 g+Dimpropyridaz 12% SC-416.67 ml (prior art)
T10 Gibberellic acid 40% WSG-2.5 g+Lambda cyhalothrin 5% EC-400 ml (prior art)
T11 Gibberellic acid 40% WSG-2.5 g+Tolfenpyrad 15% EC-500 ml (prior art)
T12 Gibberellic acid 40% WSG-2.5 g+Dinotefurn 20% SG-100 g (prior art)
T13 Pyrifluquinazon 20% SC-250 ml+Diafenthiuron 50% WP-400 g (prior art)
T14 Pyrifluquinazon 20% SC-250 ml+Spiropidion 10% SC-500 ml (prior art)
T15 Pyrifluquinazon 20% SC-200 ml+Dimpropyridaz 12% SC-416.67 ml (prior art)
T16 Pyrifluquinazon 20% SC-200 ml+Lambda cyhalothrin 5% EC-400 ml (prior art)
T17 Pyrifluquinazon 20% SC-200 ml+Tolfenpyrad 15% EC-500 ml (prior art)
T18 Pyrifluquinazon 20% SC-200 ml+Dinotefurn 20% SG-100 g (prior art)
T19 Pyrifluquinazon 20% SC-200 ml+Gibberellic acid 40% WSG-2.5 g (prior art)
T20 Diafenthiuron 50% WP-400 g
T21 Spiropidion 10% SC-500 ml
T22 Dimpropyridaz 12% SC-416.67 ml
T23 Lambda cyhalothrin 5% EC-400 ml
T24 Tolfenpyrad 15% EC-500 ml
T25 Dinotefurn 20% SG-100 g
T26 Gibberellic acid 40% WSG-2.5 g
T27 Pyrifluquinazon 20% SC-250 ml
T28 Pyrifluquinazon 20% SC-200 ml
T29 UTC (Untreated Check)

Table 4: Efficacy against sucking pests in brinjal crop.
Treatment number % Whitefly control % Jassid control Synergism (Y/N) fruits/ plant flowers/ plant
Obs. Value Cal. Value Colby's ratio Obs. Value Cal. Value Colby's ratio
T1 93.4 84.08 1.11 82.4 74.34 1.11 Y 16.8 32.4
T2 92.6 82.22 1.13 90.4 72.44 1.25 Y 17.4 33.7
T3 90.2 81.31 1.11 92.6 77.63 1.19 Y 16.6 31.4
T4 84.2 75.16 1.12 82.4 73.14 1.13 Y 17.8 34.2
T5 86.2 78.45 1.10 90.4 79.13 1.14 Y 18.2 32.8
T6 85.4 74.30 1.15 88.6 74.34 1.19 Y 17.0 31.3
T7 61.2 61.74 0.99 52 52.30 0.99 N 11.2 27.6
T8 56.8 57.27 0.99 47.8 48.77 0.98 N 13.0 25.8
T9 60.8 61.38 0.99 57.2 58.43 0.98 N 12.3 26.4
T10 47.6 48.68 0.98 49.2 50.07 0.98 N 11.4 25.7
T11 55.2 55.48 0.99 60.4 61.21 0.99 N 12.1 28.3
T12 46.6 46.90 0.99 50.6 52.30 0.97 N 11.9 27.5
T13 82.2 82.20 1.00 70.4 72.35 0.97 N 12.8 23.5
T14 80 80.12 1.00 70.2 70.30 1.00 N 12.3 24.8
T15 78.4 79.09 0.99 75.8 75.90 1.00 N 11.4 23.7
T16 71.2 72.22 0.99 68.4 71.06 0.96 N 10.4 22.9
T17 74.4 75.90 0.98 77.2 77.51 1.00 N 12.3 24.3
T18 70.8 71.25 0.99 71.8 72.35 0.99 N 13.1 21.8
T19 62.4 62.81 0.99 48.6 50.07 0.97 N 11.1 25.2
T20 57.2 48.6 8.9 19.8
T21 52.2 44.8 9.3 21.3
T22 56.8 55.2 9.5 21.0
T23 42.6 46.2 8.4 18.6
T24 50.2 58.2 9.8 21.8
T25 40.6 48.6 8.6 17.5
T26 10.6 7.2 8.0 22.4
T27 58.4 46.2 9.1 20.6
T28 51.6 40.4 8.7 19.7
T29 0.0 0.0 7.2 12.4

All innovative ready mix formulations (T1 to T6) shows synergism in terms of efficacy against whitefly and jassid. The ready mix formulations (T1 to T6) also produces more number of fruits and flowers in comparison to all prior art treatments. Other visual observations shows excellent crop vigor, greenery, branches were observed in innovative ready mix formulations (T1 to T6).

EXAMPLE 10:
Experiment 3: Bioefficacy against insect pests infesting okra crop
Crop & Variety : Brinjal, Dolly
Location : Anand, Gujarat
Treatments : 16
Plot size : 20 sq.m
Spacing : 90 cm x 20-25 cm
Time of Application : As soon as moderate infestation (>10 insect/leaf) sucking pests observed.
Method of Application: Foliar spray with knap sack sprayer.
Water volume : 450 liter per hectare
Agronomic Practices : All agronomic practices followed as per the crop requirement.
Observation Methods:
Sucking pests (JassidAmrascabiguttulabiguttula and Thrips Thripstabaci)
control (%): same as given in experiment 1.
Fruit and Flower count: same as given in Experiment 1.

Table 5: Treatment details for bioefficacy evaluation of ready mix formulations in okra crop
Treatment number Treatment details with application Rate (ml or g per Hectare)
T1 (Flonicamid 5%+Gibberellic acid 0.1%+Diafenthiuron 20%) SC-1000 ml
T2 (Flonicamid 5%+Gibberellic acid 0.1%+Pyriproxyfen 5%) SE-1000 ml
T3 (Flonicamid 5%+Gibberellic acid 0.1%+Spiropidion 5%) SC-1000 ml
T4 Gibberellic acid 40% WSG-2.5 g+Diafenthiuron 50% WP-400 g (prior art)
T5 Gibberellic acid 40% WSG-2.5 g+Pyriproxyfen 10% EC-500 ml (prior art)
T6 Gibberellic acid 40% WSG-2.5 g+Spiropidion 10% SC-500 ml (prior art)
T7 Flonicamid 50% WG-100 g+Diafenthiuron 50% WP- 400 g (prior art)
T8 Flonicamid 50% WG-100 g+Pyriproxyfen 10% EC-500 ml (prior art)
T9 Flonicamid 50% WG-100 g+Spiropidion 10% SC-500 ml (prior art)
T10 Flonicamid 50% WG-100 g+Gibberellic acid 0.04% L-750 ml (prior art)
T11 Diafenthiuron 50% WP-400 g
T12 Pyriproxyfen 10% EC-500 ml
T13 Spiropidion 10% SC-500 ml
T14 Gibberellic acid 40% WSG-2.5 g
T15 Flonicamid 50% WG-100 g
T16 UTC (Untreated Check)

Table 6: Efficacy against sucking pest infesting okra crop
Treatment number % Jassid control % Thrips control Synergism (Y/N) fruits/5 plant flowers/ 5 plant
Obs. Value Cal. Value Colby's ratio Obs. Value Cal. Value Colby's ratio
T1 92.4 77.29 1.20 88.4 75.87 1.17 Y 41.8 32.6
T2 88.2 76.76 1.15 77.2 59.08 1.31 Y 43.6 33.2
T3 96.8 84.96 1.14 90.6 74.09 1.22 Y 42.8 34.2
T4 40.6 42.95 0.95 58.2 59.38 0.98 N 36.8 26.8
T5 38.8 41.62 0.93 30.2 31.11 0.97 N 37.4 25.8
T6 60.2 62.22 0.97 54.4 56.38 0.96 N 38.6 24.6
T7 75.6 76.20 0.99 72.4 74.22 0.98 N 34.8 26.4
T8 74.4 75.64 0.98 53.8 56.28 0.96 N 35.6 27.2
T9 83.4 84.24 0.99 70.6 72.32 0.98 N 36.6 25.8
T10 60.8 62.03 0.98 42.2 44.40 0.95 N 35.2 24.3
T11 40.2 56.6 26.2 16.4
T12 38.8 26.4 25.6 17.2
T13 60.4 53.4 28.6 18.2
T14 4.6 6.4 24.2 20.6
T15 60.2 40.6 27.4 16.4
T16 0.0 0.0 19.8 10.2

All innovative ready mix formulations (T1 to T3) shows synergism in terms of efficacy against jassid and thrips. The ready mix formulations (T1 to T3) also produces more number of fruits and flowers in comparison to all prior art treatments.

EXAMPLE 11:
Experiment 4: Bioefficacy against insect pests infesting chilli crop
Crop & Variety : Chilli, Nisha
Location : Umreth, Gujarat
Treatments : 16
Plot size : 20 sq.m
Spacing : 90 cm x 15-20 cm
Time of Application : As soon as moderate infestation of sucking pests observed.
Method of Application: Foliar spray with knap sack sprayer.
Water volume : 520 liter per hectare
Agronomic Practices : All agronomic practices followed as per the crop requirement.
Observation Methods:
Sucking pests (Thrips Scirtothrips dorsalis) control (%): Count the number of insects per twig by shaking the twigs on black color piece of paper on 5th day after spray. Record the count from 3 twigs per plant and 5 plants per plot.
Fruit and Flower count: count the number of fruits and flower per plant and 5 plants per plot on 15th day after spray.
Table 7: Treatment details for bio-efficacy against sucking pest infesting chillicrop
Treatment number
Treatment details with application Rate (ml or g per Hectare)

T1 (Pyrifluquinazon 4%+Brassinolide 0.025%+Tolfenpyrad 10%) OD-1000 ml
T2 (Flonicamid 5%+Brassinolide 0.025%+Tolfenpyrad 10%) SC-1000 ml
T3 (Pymetrozine 10%+Brassinolide 0.025%+Tolfenpyrad 10%) SE-1000 ml
T4 Pyrifluquinazon 20% SC-200 ml+Brassinolide 0.04% L-625 ml (prior art)
T5 Flonicamid 50% WG-100 g+Brassinolide 0.04% L-625 ml (prior art)
T6 Pymetrozine 50% WG-100 g+Brassinolide 0.04% L-625 ml (prior art)
T7 Pyrifluquinazon 20% SC-200 ml+Tolfenpyrad 15% EC-666.7 ml (prior art)
T8 Flonicamid 50% WG-100 g+Tolfenpyrad 15% EC-666.7 ml (prior art)
T9 Pymetrozine 50% WG-100 g+Tolfenpyrad 15% EC-666.7 ml (prior art)
T10 Brassinolide 0.04% L-625 ml+Tolfenpyrad 15% EC-666.7 ml (prior art)
T11 Pyrifluquinazon 20% SC-200 ml
T12 Flonicamid 50% WG-100 g
T13 Pymetrozine 50% WG-100 g
T14 Brassinolide 0.04% L-625 ml
T15 Tolfenpyrad 15% EC-666.7 ml
T16 UTC (Untreated Check)

Table 8: Bio-efficacy against sucking pest (Thrips Scirtothrips dorsalis) infesting chilli crop

Treatment number % Thrips control Synergism (Y/N) fruits/ plant flowers/ plant
Obs. Value Cal. Value Colby's ratio
T1 92.6 78.84 1.17 Y 82.6 112.6
T2 88.4 77.14 1.15 Y 83.6 108.6
T3 85.6 77.70 1.10 Y 81.6 113.2
T4 45.2 46.84 0.97 N 74.6 96.2
T5 40.8 42.56 0.96 N 72.8 89.2
T6 40.2 43.98 0.91 N 70.2 95.6
T7 73.4 76.28 0.96 N 73.6 90.4
T8 71.2 74.37 0.96 N 75.4 88.6
T9 72.8 75.01 0.97 N 71.2 83.4
T10 62.4 64.50 0.97 N 77.2 95.2
T11 40.4 56.8 77.4
T12 35.6 46.6 72.2
T13 37.2 43.6 75.4
T14 10.8 42.2 70.2
T15 60.2 60.8 81.2
T16 0.0 33.8 60.2

Thrips is the most destructive pests of chilli crop and its difficult to control. The field trials results shows ready mix formulations (T1, T2 and T3) show synergistic control of thrips and also produces higher number of green chilli fruits and flower per plant in comparison to prior art treatments. The visual observation shows excellent recovery on leaf curling symptoms (due to Thrips damage), reduction in flower bud dropping, big and dark green leaves, more number of branches with excellent crop canopy and crop growth and vigor.
EXAMPLE 12:
Experiment 5: Control of brown plant hopperinfesting paddy/rice crop
Crop : Paddy
Location : Kurud, Dhamtari, Chattishgarh
Plot size : 30sq. mt. (6m x 5m)
Number of Treatments: 12
Application Time : When moderate infestation of Brown plant hopper (BPH, Nilaparvatalugens) observed.
Method of Application: Foliar spray with knap sack sprayer.
Agronomic Practices : All agronomic practices followed as per the crop requirement.
Observation Methods:
% Brwon Plant Hopper(BPH), Nilaparvatalugens control:
Count the number of hoppers (BPH) per hill, observe 10 hills per plot. Record the observations
On 5, 10 and 15 days after spray to check the residual control.
Calculate the % Hoppers (BPH) control (observed value) as below formula.

The calculated value of % control was used to worked out the Colby’s formula to judge the
synergism.
Tiller count : Count the number of productive tillers per hill. Record observations from 10 hills per plot at the time of harvesting.
Plant lodging (%): Record the plant lodging on entire plot basis by visual observation at the time of harvesting.

Table 9: Treatment details for field bio-efficacy against BPH (Nilaparvatalugens) infesting paddy crop
Treatment number Treatment details with application Rate (ml or g per Hectare)
T1 (Pymetrozine 15%+Mepiquat chloride 4%+Triflumezopyrim 3%) WG-600 g
T2 (Pymetrozine 15%+Mepiquat chloride 4%+Dinotefuran 5%) WG-600 g
T3 Pymetrozine 50% WG-180 g+Mepiquat chloride 5% AS-480 ml (prior art)
T4 Pymetrozine 50% WG-180 g+Triflumezopyrim 10% SC-180 ml (prior art)
T5 Pymetrozine 50% WG-180 g+Dinotefuran 20% SG-150 g (prior art)
T6 Mepiquat chloride 5% AS-480 ml+Triflumezopyrim 10% SC-180 ml (prior art)
T7 Mepiquat chloride 5% AS-480 ml+Dinotefuran 20% SG-150 g (prior art)
T8 Pymetrozine 50% WG-180 g
T9 Mepiquat chloride 5% AS-480 ml
T10 Triflumezopyrim 10% SC-180 ml
T11 Dinotefuran 20% SG-150 g
T12 UTC (Untreated Check)

Table 10: Bioefficacy against brown plant hopper

Treatment number % BPH control on 5th day Synergism (Y/N) productive tillers/hill at harvest % Plant lodging at harvest
Obs. Value Cal. Value Colby's ratio
T1 98.4 86.91 1.13 Y 36.2 0
T2 92.6 83.67 1.11 Y 34.6 0
T3 57.6 58.57 0.98 N 30.4 5
T4 84.8 86.16 0.98 N 28.8 20
T5 81.6 82.74 0.99 N 26.6 25
T6 69.6 70.11 0.99 N 25.4 5
T7 62.2 62.73 0.99 N 24.6 5
T8 56.2 21.6 30
T9 5.4 23.4 5
T10 68.4 22.8 25
T11 60.6 21.2 30
T12 0.0 17.6 40

Brown plant hopper is the key constraint in rice productions. Both the innovative ready-mix formulations (T1& T2) provides synergistic control of brown plant hopper and also gave longer residual control in comparison to all prior art treatments. Both the innovative ready-mix formulations (T1 & T2) shows no plant lodging and produces higher number of productive tillers which are directly contributing to the grain yield. The anti lodging is mainly due to excellent control of BPH and reduction in plant height due to shortening of internodal distance. Both the treatment increases plant girth due to increase in lignification, making the base of plant hard and thus prevent the plant lodging and also reduces the infestation of BPH.

EXAMPLE 13:
Experiment 6: Control of brown plant hopper infesting paddy/rice crop
Crop : Paddy
Location : Kurud, Dhamtari, Chattishgarh
Plot size : 40sq. mt. (8m x 5m)
Number of Treatments: 16
Application Time : Manual broadcasting at 50 days after transplanting.
Observation Methods:
% Brwon Plant Hopper (BPH), Nilaparvatalugens control:
Count the number of hoppers (BPH) per hill, observe 10 hills per plot. Record the observations
On 60, 75 and 90 DATP.
Tiller count : same as given in experiment 5.
Plant lodging (%): same as given in experiment 5.

Table 11: Treatment details for field bio-efficacy against brown plant hopper BPH (Nilaparvatalugens)

Treatment number Treatment details with application Rate (ml or g per Hectare)
T1 (Pymetrozine 2%+Paclobutrazol 0.5%+Triflumezopyrim 0.5%) GR-SL-7.5 kg
T2 (Pymetrozine 2%+Paclobutrazol 0.5%+Clothianidin 1%) GR-SL-7.5 kg
T3 (Pymetrozine 2%+Paclobutrazol 0.5%+Thiamethoxam 1.2%) GR-SL-7.5 kg
T4 Pymetrozine 50% WG-300 g+Paclobutrazol 25% AS-150 ml (prior art)
T5 Pymetrozine 50% WG-300 g+Triflumezopyrim 10% SC-375 ml (prior art)
T6 Pymetrozine 50% WG-300 g+Clothianidin 20% SG-150 g (prior art)
T7 Pymetrozine 50% WG-300 g+Thiamethoxam 75% SG-120 g (prior art)
T8 Paclobutrazol 5% AS-150 ml+Triflumezopyrim 10% SC-375 ml (prior art)
T9 Paclobutrazol 5% AS-150 ml+Clothianidin 50% WDG-150 g (prior art)
T10 Paclobutrazol 5% AS-150 ml+Thiamethoxam 75% SG-120 g (prior art)
T11 Pymetrozine 50% WG-300 g
T12 Paclobutrazol 25% SC-150 ml
T13 Triflumezopyrim 10% SC-375 ml
T14 Clothianidin 50% WDG-150 g
T15 Thiamethoxam 75% SG-120 g
T16 UTC (Untreated Check)

Table 12: Bioefficacy against brown plant hopper BPH (Nilaparvatalugens)

Treatment number % BPH control productive tillers/hill at harvest % Plant lodging at harvest
60 DATP 75 DATP 90 DATP
Obs. Value Cal. Value Colby's ratio Synergism (Y/N)
T1 100 93.96 1.06 Y 98.8 88.2 44.2 0
T2 99.2 92.13 1.08 Y 92.6 84.6 42.6 0
T3 98.8 91.14 1.08 Y 91.2 81.6 41.2 0
T4 73.8 75.24 0.98 N 62.4 46.6 33.2 10
T5 91.4 92.88 0.98 N 84.4 62.4 36.8 15
T6 88.8 90.71 0.98 N 81.4 58.8 35.2 20
T7 87.6 89.55 0.98 N 79.6 54.2 34.4 20
T8 78.0 79.31 0.98 N 66.8 48.8 32.6 10
T9 71.8 73.03 0.98 N 59.4 38.2 31.2 10
T10 68.4 69.64 0.98 N 54.6 32.6 30.8 10
T11 70.8 62.4 45.6 26.8 25
T12 15.2 7.8 1.2 21.8 15
T13 75.6 66.4 47.8 28.8 20
T14 68.2 58.2 37.4 25.6 25
T15 64.2 52.6 31.4 23.4 25
T16 0.0 0 0 18.8 45

The innovative ready-mix formulations (T1, T2 and T3) provides synergistic control of brown plant hopper, provides longer residual control, produces higher number of productive tillers and prevents plant lodging in comparison to all prior art treatments.
The single granular application of ready mix formulations provides season long control of brown plant hopper in paddy.
For the biological examples: cm-centimetre, m- meter, g-gram, kg-kilogram, ml-millilitre, sq.mt. square meter (m2), DAS-Days after sowing, DAP-Days after planting, DATP-Days after transplanting, DAA -Days after application, spp-species, sr.no. -series number, Ob. Value-observed value, Cal.Value-calculated value.
GR/Gr- Granule/soil applied granule, GR-SL Granule Slow release, SC Suspension concentrate, SE Suspo emulsion, OD Oil dispersion, SL Soluble liquid, WG/WDG-Water dispersible granule, WP Wettable powder, SG Soluble granule, L Liquid, SL Soluble liquid, EC Emulsifiable concentrate.
Visual observations of the field trials:
The field trials results show many benefits/advantages of ready mix formulations of feeding blockers with plant growth regulators and insecticides. All synergistic ready mixtures of the present invention shows excellent field trial results, shows synergistic control of plant diseases, provides higher level of insect control (increase % control), provides effective control of more number of insect-pests species at a time and over a period of time, provides longer duration of control (residual control), increases plant growth, vigor, height, produces more number of tillers, shoots, branches, flowers, fruits, pods, square, bolls, seeds, grains etc. and overall biomass of the crop, which directly increases the yield of the crop, regulates the plant growth and thereby prevent plant lodging due to biotic and abiotic factors.
The increase in bio efficacy, residual control and plant growth were also observed due to novelty and innovation in the recipe of formulations (OD, ZC, SE, SC, WG, GR, GR-SL).

We claim;

[CLAIM 1].A synergistic agrochemical composition for arthropod control comprising:
a. an insecticide from the group selective feeding blocker in an amount of 0.1 to 40% by weight of the composition;
b. a plant growth regulator in an amount of 0.001 to 20% by weight of the composition or mixture thereof;
c. at least an insecticides from various group in an amount of 0.1 to 40% by weight or mixture thereof;
d. an inactive formulation excipients.

[CLAIM 2]. The synergistic agrochemical composition for arthropod control as claimed in claim 1, wherein an insecticide from class of selective feeding blocker group of insecticide selected from afidopyropen, flonicamid, pyrifluquinazon or pymetrozine.

[CLAIM 3]. The synergistic agrochemical composition as claimed in claim 1, wherein plant growth regulators
from the class of Antiauxins is selected from clofibric acid, 2,3,5-tri-iodobenzoic acid;
from the class of Auxin is selected from 4-CPA, 2,4-D, 2,4-DB, 2,4-DEP, dichlorprop, fenoprop, IAA, IBA, naphthalene acetamide, a-naphthaleneacetic acid, 1-naphthol, naphthoxy acetic acid, potassium naphthenate, sodium naphthenate, 2,4,5-T;
from the class of Cytokinins is selected from adenine, adenine hemisulfate di-hydrate, 2iP, 6-benzylaminopurine, N-Oxide-2,6-lutidine, 2,6-dimethylpyridine, kinetin, zeatin;
from the class of Defoliants is selected from calcium cyanamide, dimethipin, endothal, merphos, metoxuron, pentachlorophenol, thidiazuron, tribufos, tributyl phosphorotrithioate;
from the class of Ethylene modulators is selected from aviglycine, 1-MCP, prohexadione, prohexadione calcium, trinexapac, trinexapac-ethyl, aminoethoxyvinylglycine (AVG);
from the class of Ethylene releasers is selected from ACC, etacelasil, ethephon, glyoxime;
from the class of Gibberellins is selected from gibberelline, gibberellic acid, GA3;
from the class of Growth Inhibitors is selected from abscisic acid, ancymidol, butralin, carbaryl, chlorphonium, chlorpropham, dikegulac, flumetralin, fluoridamid, fosamine, glyphosine, isopyrimol, jasmonic acid, maleic hydrazide, mepiquat, mepiquat chloride, mepiquatpentaborate, piproctanyl, prohydrojasmon, propham, 2,3,5-tri-iodobenzoic acid;
from the class of Morphactins is selected from chlorfluren, chlorflurenol, dichlorflurenol, flurenol;
from the class of Growth retardants is selected from chlormequat, chlormequat chloride, daminozide, flurprimidol, mefluidide, paclobutrazol, tetcyclacis, uniconazole, metconazole;
from the class of Growth stimulants is selected from brassinolide, forchlorfenuron, hymexazol;
from the class of Unclassified plant growth regulators is selected from amidochlor, benzofluor, buminafos, carvone, choline chloride, ciobutide, clofencet, cloxyfonac, cyanamide, cyclanilide, cycloheximide, cyprosulfamide, epocholeone, ethychlozate, ethylene, fenridazon, fluprimidol, fluthiacet, heptopargil, holosulf, inabenfide, karetazan, lead arsenate, methasulfocarb, pydanon, sintofen, triapenthenol, Nitrophenolate (sodium para-nitrophenolate, ortho-nitrophenoate, sodium-5-nitroguaiacolate), triacontanol, alpha naphthyl acetic acid, 6-benzyladenine.

[CLAIM 4]. The synergistic agrochemical composition as claimed in claim 1, wherein an insecticide
from a group of Acetylcholine Esterase Inhibitors from the class of Carbamates is selected from aldicarb, alanycarb, bendiocarb, benfuracarb, butocarboxim, butoxycarboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetanate, furathiocarb, isoprocarb, methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, trimethacarb, XMC, xylylcarb, and triazamate;
from the group of Acetylcholine Esterase Inhibitors from the class of Organophosphates is selected from acephate, azamethiphos, azinphos-ethyl, azinphos-methyl, cadusafos, chlorethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton-S-methyl, diazinon, dichlorvos/ DDVP, dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, famphur, fenamiphos, fenitrothion, fenthion, fosthiazate, heptenophos, imicyafos, isofenphos, isopropyl O-(methoxyaminothio-phosphoryl) salicylate, isoxathion, malathion, mecarbam, methamidophos, methidathion, mevinphos, monocrotophos, naled, omethoate, oxydemeton-methyl, parathion, parathion-methyl, phenthoate, phorate, phosalone, phosmet, phosphamidon, phoxim, pirimiphos- methyl, profenofos, propetamphos, prothiofos, pyraclofos, pyridaphenthion, quinalphos, sulfotep, tebupirimfos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon, vamidothion;
from the class of GABA-gated chloride channel antagonists is selected from Cyclodiene organochlorine compounds like endosulfan; or Phenylpyrazole like ethiprole, fipronil, flufiprole, nicofluprole, pyrafluprole, or pyriprole;
from the group of Sodium Channel Modulators from the class of Pyrethroids is selected from acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cylclopentenyl, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, empenthrin, esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate, halfenprox, imiprothrin, meperfluthrin, metofluthrin, momfluorothrin, permethrin, phenothrin, prallethrin, profluthrin, pyrethrin (pyrethrum), resmethrin, silafluofen, tefluthrin, tetramethylfluthrin, tetramethrin, tralomethrin, transfluthrin;
from a group of nicotinic Acetylcholine receptor (nAChR) competitive modulator is selected from Neonicotinoids like acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam; or Sulfoximines such as sulfoxaflor; or Butenolides like flupyradifurone; or Mesoionics like triflumezopyrim and flupyrimin;
from a group of Nicotinic Acteylcholine receptor (nAChR) allosteric modulators-Site I-from the class of spinosyns selected from spinosad, spinetoram;
from a class of Glutamate-gated Chloride channel (GluCl) allosteric modulators of Avermectins selected from abamectin, emamectin benzoate, ivermectin, lepimectin; Milbemycins-milbemectin;
from the class of Juvenile Hormone Mimics is selected from hydroprene, kinoprene, methoprene, fenoxycarb, pyriproxyfen;
from the class of Non-specific multi-site inhibitors is selected from methyl bromide and other alkyl halides, chloropicrin, sulfuryl fluoride, borax or tartar emetic, dazomet, metam;
from the class of Mite growth inhibitors affecting CHS1 is selected from asclofentezine, hexythiazox, diflovidazin or etoxazole;
from the class of Microbial Disruptors of insect midgut membrane is selected from Bacillus thuringiensis and insecticidal proteins they produce;
from the class of Inhibitors of mitochondrial ATP synthase is selected from diafenthiuron, azocyclotin, cyhexatin, fenbutatin oxide, propargite, or tetradifon;
from the class of Uncouplers of oxidative phosphorylation is selected from chlorfenapyr, DNOC, or sulfluramid;
from the class of Nicotinic acetylcholine receptor channel blockers is selected from bensultap, cartap hydrochloride, thiocyclam, thiosultap sodium;
from the class of Inhibitors of the chitin biosynthesis affecting CHS1 is selected from Benzoylureas-bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron, and triflumuron;
from the class of Inhibitors of the chitin biosynthesis type 1 is buprofezin;
from the class of Moulting disruptors is cyromazine;
from the class of Ecdyson receptor agonists selected from diacylhydrazines- methoxyfenozide, tebufenozide, halofenozide, fufenozide or chromafenozide;
from the class of Octopamin receptor agonists such as amitraz;
from the class of Mitochondrial complex III electron transport inhibitors selected from hydramethylnon, acequinocyl, flometoquin, fluacrypyrim, pyriminostrobin or bifenazate;
from the class of Mitochondrial complex I electron transport inhibitors selected from fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, tolfenpyrad, flufenerim, or rotenone;
from the class of Voltage-dependent sodium channel blockers selected from oxadiazines-indoxacarb, semicarbazones-metaflumizone or 1 -[(E)-[2-(4-cyanophenyl)-1-[3-(trifluoromethyl) phenyl] ethylidene] amino]-3-[4-(difluoromethoxy)phenyl]urea;
from the class of Inhibitors of the lipid synthesis, inhibitors of acetyl CoA carboxylase selected from Tetronic and tetramic acid derivatives-spirodiclofen, spiromesifen, spirotetramat or spiropidion;
from the class of Mitochondrial complex II electron transport inhibitors selected from cyenopyrafen, cyflumetofen or pyflubumide;
from the class of Baculoviruses such as Granuloviruses and Nucleopolyhedrosis viruses;
from the class of unknown or uncertain mode of action such as azadirechtin, benzoximate, benzpyrimoxan, pyridalyl and oxazosulfyl (ethyl 2-{5-[(trifluoromethyl)sulfonyl]-1,3-benzoxazol-2-yl}-3-pyridyl sulfone); dimpropyridaz (1-[(1RS)-1,2-dimethylpropyl]-N-ethyl-5-methyl-N-pyridazin-4-yl-1H-pyrazole-4-carboxamide), tyclopyrazoflor (N-[3-chloro-1-(3-pyridyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoro propyl) thio] propenamide); dichloromezotiaz, fluhexafon;
from Acaricidal compound selected from cyetpyrafen(Z)-2-(4-tert-butylphenyl)-2-cyano-1-(1-ethyl-3-methyl-1H-pyrazol-5-yl)vinyl 2,2-dimethylpropanoate), flupentiofenox (4-chloro-2-fluoro-5-[(RS)-(2,2,2-trifluoroethyl)sulfinyl]phenyl 5-[(trifluoro methyl)thio]pentyl ether), acynonapyr (3-endo-[2-propoxy-4-(trifluoro methyl)phenoxy]-9-{[5-(trifluoromethyl)-2-pyridyl]oxy}-9-azabi cyclo [3.3.1] nonane);
from the compound with nematicidal action selected from cyclobutrifluram (N-[2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)pyridine-3carboxamide, containing 80–100% of the (1S,2S)-enantiomer and 20–0% of the (1R,2R)-enantiomer),fluazaindolizine(8-chloro-N-[(2-chloro-5 methoxy phenyl) sulfo-nyl]-6-(trifluoromethyl)imidazo[1,2-a]pyridine-2-carboxamide), tioxazafen.

[CLAIM 5]. The synergistic agrochemical composition as claimed in claim 1 wherein, the formulation for the said composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Powder for dry seed treatment (DS), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion for foliar spray (ES), Emulsion, oil in water (EW), Flowable suspension/concentrate for foliar spray (FS), Granule/ soil applied (GR), Controlled (Slow or Fast) release granules (CR), Jambo balls or bags (bags in water soluble pouch), Solution for foliar spray (LS), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (= flowable concentrate) (SC), Suspo-emulsion (SE), Water soluble granule (SG), Soluble concentrate (SL), Water soluble powder (SP), Water dispersible granule (WG or WDG), Wettable powder (WP), Water dispersible powder for slurry treatment (WS), a mixed formulation of CS and SC (ZC), a mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW).

[CLAIM 6]. The synergistic agrochemical composition as claimed in claim 1- claim 5, wherein preferred compositions for the Oil Dispersion (OD) formulation comprises:
i. Oil Dispersion (OD) formulation of Pyrifluquinazon 4% + Brassinolide 0.025% + Diafenthiuron 20%
ii. Oil Dispersion (OD) formulation of Pyrifluquinazon 4% + Brassinolide 0.025% + Tolfenpyrad 10%
iii. Oil Dispersion (OD) formulation of Pyrifluquinazon 10% + Gibberellic acid 0.2% +Spiromesifen 20%
iv. Oil Dispersion (OD) formulation of Pyrifluquinazon 10% + Gibberellic acid 0.2% + Spirotetramat 10%
v. Oil Dispersion (OD) formulation of Afidopyropen 5%+Brassinolide 0.05%+Spiromesifen 20%
vi. Oil Dispersion (OD) formulation of Afidopyropen 5%+Gibberellic Acid 0.2%+ Spiromesifen 20%
vii. Oil Dispersion (OD) formulation of Afidopyropen
5%+Triacontanol 0.05% +Spiromesifen 20%
viii. Oil Dispersion (OD) formulation of Pymetrozine 20%+ Trinexapac ethyl 5%+ Triflumezopyrim 3%
ix. Oil Dispersion (OD) formulation of Pymetrozine 20%+ Trinexapac ethyl 5%+ Clothianidin 3%

[CLAIM 7]. The synergistic agrochemical composition as claimed in claim 1- claim 5, wherein the Oil Dispersion (OD) formulation comprises:
i. an insecticide from the group Selective feeding blocker in an amount of 0.1 to 40% by weight of the composition is Pyrifluquinazon, Afidopyropen, Pymetrozine;
ii. a plant growth regulator in an amount of 0.001 to 20% by weight of the composition selected is Brassinolide, Gibberellic acid, Triacontanol, Trinexapac ethyl;
iii. an insecticides from various group in an amount of 0.1 to 40% by weight is selected form Diafenthiuron, Tolfenpyrad, Spiromesifen, Spirotetramat, Triflumezopyrim, Clothianidin;
iv. Wetting and spreading agent in an amount of 2 to 6 % by weight;
v. Dispersing agent in an amount of 2 to 8 % by weight;
vi. Emulsifying agent in an amount of 6 to 10 % by weight;
vii. Stabilizer in an amount of 0.5 to 4% by weight;
viii. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
ix. Preservative in an amount of 0.1 to 0.5 % by weight;
x. Antifreezing agent in an amount of 2 to 6 % by weight;
xi. Carrier as solvent in an amount of 40 to 70% by weight.

[CLAIM 8]. The synergistic agrochemical composition as claimed in claim 7, wherein wetting agent is selected from ethylene oxide/propylene oxide block copolymer, polyaryl phenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate.
[CLAIM 9]. The synergistic agrochemical composition as claimed in claim 7, wherein emulsifying agent is selected from castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecyl benzene sulphonate, alkyl ammonium salts of alkyl benzene sulphonate, alkyl sulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylene sorbitan monolaurate.

[CLAIM 10]. The synergistic agrochemical composition as claimed in claim 7, wherein dispersing agent is selected from alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkyl phenol alkoxylates, tristyryl phenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploy carboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethylene oxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyryl phenol-poly glycol ether-phosphate, tristyryl phenole with 16 moles EO, tristyryl phenol-poly glycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonyl phenol poly glycol ether with 9-10 moles ethylene oxide.

[CLAIM 11]. The agrochemical composition as claimed in claim 7, wherein Carrier as solvent or diluting agent is selected from vegetable or plant or seed oil or its alkylated oil or alkylated oil of vegetable oil, alkylated oil (alkylated vegetable oil) may be methylated or ethylated oil of the vegetable oil, wherein vegetable oil are olive oil, kapok oil, castor oil, papaya oil, camellia oil, palm oil, sesame oil, corn oil, rice bran oil, peanut oil, cotton seed oil, soybean oil, groundnut oil, rapeseed oil, linseed oil, tung oil, sunflower oil, safflower oil, palm (Elaeis guineensis) oil, neem (azadirecha indica) oil, eucalyptus oil, karanja (Milletia pinnata/Pongamia pinnata) oil, coconut oil, alkyl ester of vegetable oils, (e.g. rapeseed oil methyl ester or rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, neem oil, tall oil fatty acids esters etc.), diesel, mineral oil, fatty acid amides (e.g. C1 -C3 amines, alkylamines or alkanolamines with C6 - Ci8 carboxylic acids), fatty acids, tall oil fatty acids, alkyl esters of fatty acids (e.g. Ci, Methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols or mixture thereof.

[CLAIM 12]. The synergistic agrochemical composition as claimed in claim 7, wherein antifoaming agent is selected from silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, poly dimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, poly alkylene oxide modified polydimethylsiloxane.

[CLAIM 13]. The synergistic agrochemical composition as claimed in claim 1- claim 5, wherein preferred compositions for the Suspension Concentrate (SC) formulation comprises:
i. Suspension concentrate (SC) formulation of Pyrifluquinazon 5% + Gibberellic acid 0.1% + Diafenthiuron 20%
ii. Suspension concentrate (SC) formulation of Pyrifluquinazon 10% + Gibberellic acid 0.2% + Spiropidion 10%
iii. Suspension concentrate (SC) formulation of Pyrifluquinazon 8% + Gibberellic acid 0.2% + Dimpropyridaz 10%
iv. Suspension concentrate(SC) formulation of Pyrifluquinazon 8% + Gibberellic acid 0.2% + Dinotefuran 4%
v. Suspension concentrate(SC) formulation of Pyrifluquinazon 5% + Gibberellic acid 0.1%+Diafenthiuron 25%
vi. Suspension concentrate (SC) formulation of Flonicamid 5% + Gibberellic acid 0.1% + Diafenthiuron 20%
vii. Suspension concentrate (SC) formulation of Flonicamid 5% + Gibberellic acid 0.1% + Spiropidion 5%
viii. Suspension concentrate (SC) formulation of Flonicamid 4% + Brassinolide 0.025% + Diafenthiuron 20%
ix. Suspension concentrate (SC) formulation of Flonicamid 5% +Brassinolide 0.025% + Tolfenpyrad 10%
x. Suspension concentrate(SC) formulation of Pyrifluquinazon 6% + Brassinolide 0.033%+ Diafenthiuron 30%
xi. Suspension concentrate(SC) formulation of Pyrifluquinazon 5% + Triacontanol 0.025%+ Diafenthiuron 25%
xii. Suspension concentrate(SC) formulation of Pyrifluquinazon 5% + Paclobutrazol 4%+ Diafenthiuron 25%
xiii. Suspension concentrate(SC) formulation of Pyrifluquinazon 5%+ Mepiquat chloride 4%+ Diafenthiuron 25%
xiv. Suspension concentrate(SC) formulation of Pyrifluquinazon 10%+ Brassinolide 0.05%+ Spiromesifen 20%
xv. Suspension concentrate(SC) formulation of Pyrifluquinazon 10%+ Triacontanol 0.05%+ Spiromesifen 20%
xvi. Suspension concentrate(SC) formulation of Pyrifluquinazon 6.67%+ Paclobutrazol 5.33%+ Spiromesifen 13.33
xvii. Suspension concentrate(SC) formulation of Pyrifluquinazon 10%+ Brassinolide 0.05%+ Emamectin benzoate 4%
xviii. Suspension concentrate(SC) formulation of Flonicamid 5%+ Gibberellic acid 0.1%+ Dimpropyridaz 5%
xix. Suspension concentrate(SC) formulation of Flonicamid 5%+ Brassinolide 0.025%+ Diafenthiuron 22.50%
xx. Suspension concentrate(SC) formulation of Flonicamid 5%+Gibberellic Acid 0.1%+ Diafenthiuron 25%
xxi. Suspension concentrate(SC) formulation of Flonicamid 5%+ Triacontanol 0.025%+ Diafenthiuron 25%
xxii. Suspension concentrate(SC) formulation of Flonicamid 10%+ Brassinolide 0.05%+ Spirotetramat 10%
xxiii. Suspension concentrate(SC) formulation of Flonicamid 10%+ Gibberellic Acid 0.2%+ Spirotetramat 10%
xxiv. Suspension concentrate(SC) formulation of Flonicamid 10%+ Triacontanol 0.05%+ Spirotetramat 10%
xxv. Suspension concentrate(SC) formulation of Flonicamid 10%+ Brassinolide 0.05%+ Emamectin benzoate 4%
xxvi. Suspension concentrate(SC) formulation of Flonicamid 10%+ Gibberellic Acid 0.2%+Emamectin benzoate 4%
xxvii. Suspension concentrate(SC) formulation of Flonicamid 10%+ Triacontanol 0.05%+ Emamectin benzoate 4%
xxviii. Suspension concentrate(SC) formulation of Afidopyropen 4%+ Brassinolide 0.025%+ Pyriproxyfen 7.5%
xxix. Suspension concentrate(SC) formulation of Afidopyropen 4%+ Gibberellic Acid 0.1%+ Pyriproxyfen 7.5%
xxx. Suspension concentrate(SC) formulation of Afidopyropen 4%+Triacontanol 0.025%+Pyriproxyfen 7.5%
xxxi. Suspension concentrate(SC) formulation of Afidopyropen 4%+Paclobutrazol 4%+ Pyriproxyfen 7.5%
xxxii. Suspension concentrate(SC) formulation of Afidopyropen 4%+ Mepiquat chloride 3%+ Pyriproxyfen 7.5%
xxxiii. Suspension concentrate(SC) formulation of Afidopyropen 5%+ Brassinolide 0.05%+ Spirotetramat 10%
xxxiv. Suspension concentrate(SC) formulation of Afidopyropen 5%+Gibberellic Acid 0.2%+ Spirotetramat 10%
xxxv. Suspension concentrate(SC) formulation of Afidopyropen 5%+Triacontanol 0.05%+ Spirotetramat 10%
xxxvi. Suspension concentrate(SC) formulation of Afidopyropen 5%+Brassinolide 0.05%+Emamectin benzoate 2%
xxxvii. Suspension concentrate(SC) formulation of Afidopyropen 5%+ Gibberellic Acid 0.2%+ Emamectin benzoate 2%
xxxviii. Suspension concentrate (SC) formulation of Afidopyropen 5%+Triacontanol 0.05%+ Emamectin benzoate 2%.

[CLAIM 14]. The synergistic agrochemical composition as claimed in claim 1- claim 5, wherein the Suspension Concentrate (SC) formulation comprises:
i. an insecticide from the group Selective feeding blocker in an amount of 0.1 to 40% by weight of the composition is Pyrifluquinazon, Flonicamid, Afidopyropen;
ii. a plant growth regulator in an amount of 0.001 to 20% by weight of the composition is Gibberellic acid, Brassinolide, Triacontanol, Paclobutrazol, Mepiquat chloride;
iii. an insecticides from various group in an amount of 0.1 to 40% by weight selected is Diafenthiuron, Spiromesifen, Emamectin benzoate, Dimpropyridaz, Spirotetramat, Emamectin benzoate, Pyriproxyfen;
iv. Wetting and spreading agent in an amount of 2 to 6 % by weight;
v. Dispersing agent 1 in an amount of 2 to 8 % by weight;
vi. Dispersing agent 2 in an amount of 1to 3 % by weight;
vii. Suspending agent in an amount of 0.2 to 4.0 % by weight;
viii. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
ix. Preservative in an amount of 0.1 to 0.5 % by weight;
x. Antifreezing agent in an amount of 2 to 6 % by weight;
xi. Thickner in an amount of 0.1 to 1.0 % by weight;
xii. Diluent Water in an amount of 40 to 70 % by weight.

[CLAIM 15]. The synergistic agrochemical composition as claimed in claim 14, wherein Wetting agent is selected from ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate.

[CLAIM 16]. The synergistic agrochemical composition as claimed in claim 14, wherein dispersing agent is selected from alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethylene oxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyryl phenol-polyglycol ether-phosphate, tristyryl phenole with 16 moles EO, tristyryl phenol-polyglycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonylphenol polyglycol ether with 9-10 moles ethylene oxide.

[CLAIM 17]. The synergistic agrochemical composition as claimed in claim 14, wherein suspending agent is selected from aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.

[CLAIM 18]. The synergistic agrochemical composition as claimed in claim 14, wherein anti-freezing agent is selected from ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.

[CLAIM 19]. The synergistic agrochemical composition as claimed in claim 1- claim 5, wherein preferred compositions for the Wettable dispersible Granules (WG) formulation comprises:
i. Wettable dispersible Granules (WG) formuation of Pymetrozine 15% + Mepiquat chloride 4% +Dinotefuran 5%
ii. Wettable dispersible Granules (WG) formuation of Pymetrozine 15% + Mepiquat chloride 4% + Triflumezopyrim 3%
iii. Wettable dispersible Granules (WG) formuation of Flonicamid 15%+ Brassinolide 0.1%+ Fipronil 15%
iv. Wettable dispersible Granules (WG) formuation of Flonicamid 15%+ Brassinolide 0.1%+ Emamectin benzoate 2.50%
v. Wettable dispersible Granules (WG) formuation of Pyrifluquinazon 5%+ Brassinolide 0.025% + Acephate 50%
vi. Wettable dispersible Granules (WG) formuation of Flonicamid 10%+ Brassinolide 0.05%+ Dinotefuran 5%
vii. Wettable dispersible Granules (WG) formuation of Flonicamid 10%+Gibberellic Acid 0.2%+ Dinotefuran 5%
viii. Wettable dispersible Granules (WG) formuation of Flonicamid 10%+ Triacontanol 0.05%+ Dinotefuran 5%
ix. Wettable dispersible Granules (WG) formuation of Flonicamid 5%+ Brassinolide 0.025%+ Acephate 50%
x. Wettable dispersible Granules (WG) formuation of Afidopyropen 5%+Brassinolide 0.05%+ Dinotefuran
xi. Wettable dispersible Granules (WG) formuation of Afidopyropen 2.5%+ Brassinolide 0.025%+ Acephate 25%
xii. Wettable dispersible Granules (WG) formuation of Afidopyropen 2.5%+ Gibberellic Acid 0.1%+Acephate 25%
xiii. Wettable dispersible Granules (WG) formuation of Afidopyropen 2.5%+ Triacontanol 0.025%+ Acephate 25%
xiv. Wettable dispersible Granules (WG) formuation of Pymetrozine 25%+ Brassinolide 0.05%+ Clothianidin 25%
xv. Wettable dispersible Granules (WG) formuation of Pymetrozine 25%+Gibberellic Acid 0.2%+ Thiamethoxam 25%
xvi. Wettable dispersible Granules (WG) formuation of Pymetrozine 25%+Triacontanol 0.05%+Thiamethoxam 25%
xvii. Wettable dispersible Granules (WG) formuation of Pymetrozine 25%+Paclobutrazol 5%+ Thiamethoxam 25%
xviii. Wettable dispersible Granules (WG) formuation of Pymetrozine 15%+ Brassinolide 0.05%+Dinotefuran 5%
xix. Wettable dispersible Granules (WG) formuation of Pymetrozine 15%+Gibberellic Acid 0.2%+ Dinotefuran 5%
xx. Wettable dispersible Granules (WG) formuation of Pymetrozine 15%+ Triacontanol 0.05%+Dinotefuran 5%
xxi. Wettable dispersible Granules (WG) formuation of Pymetrozine 15%+Paclobutrazol 5%+Dinotefuran 5%
xxii. Wettable dispersible Granules (WG) formuation of Pymetrozine 15% + Brassinolide 0.05% + Triflumezopyrim 3%
xxiii. Wettable dispersible Granules (WG) formuation of Pymetrozine 15% + Gibberellic Acid 0.2% + Triflumezopyrim 3%
xxiv. Wettable dispersible Granules (WG) formuation of Pymetrozine 15%+Triacontanol0.05%+Triflumezopyrim 3%
xxv. Wettable dispersible Granules (WG) formuation of Pymetrozine 15%+Paclobutrazol 5%+ Triflumezopyrim 3%.

[CLAIM 20]. The synergistic agrochemical composition as claimed in claim 1- claim 5 wherein, the Water Dispersible Granule (WG) formulation comprises:
i. an insecticide from the group Selective feeding blocker in an amount of 0.1 to 40% by weight of the composition is Pymetrozine, Flonicamid, Pyrifluquinazon, Afidopyropen;
ii. a plant growth regulator in an amount of 0.001 to 20% by weight of the composition is Mepiquat chloride, Brassinolide, Gibberellic Acid, Paclobutrazol, Triacontanol;
iii. an insecticides from various group in an amount of 0.1 to 40% by weight is Triflumezopyrim, Dinotefuran, Fipronil, Emamectin benzoate, Acephate, Clothianidin Thiamethoxam;
iv. Wetting and spreading agent in an amount of 2 to 6 % by weight;
v. Dispersing agent I in an amount of 2 to 8 % by weight;
vi. Dispersing agent II in an amount of 1to 3 % by weight;
vii. Disintegrating agent in an amount of 0.2 to 0.8 % by weight;
viii. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
ix. Carrier in an amount of 50 to 80 % by weight.

[CLAIM 21]. The synergistic agrochemical composition as claimed in claim 20, wherein dispersing agent is selected from naphthalene sulfonic acid, sodium salt condensated with formaldehyde, poly alcoxylated alkyl phenol, naphthalene sulfonic acid formaldehyde condensate, methyl naphtaline-formaldehyde-condensate sodium salt, naphthalene condensates, lingo sulfonates, poly acrylates and phosphate esters, calcium lingo sulfonate, lignin sulfonate sodium salt.

[CLAIM 22]. The synergistic agrochemical composition as claimed in claim 20, wherein wetting agents is selected from sodium N-methyl-N-oleoyl taurate, alkylated naphthalene sulfonate, sodium salt, mixture of isomers of dibutyl naphthalene sulphonic acid sodium salt, sodium di-isopropyl naphthalene sulphonate, sodium Lauryl sulfate, dioctyl sulfate, alkyl naphthalene sulfonates, phosphate esters, sulphosuccinates and non-ionic such as tridexyl alcohol ethoxylate, alkyl or alkaryl sulfonates such as alkyl benzene sulfonates, alpha olefin sulfonate and alkyl naphthalene sulfonates, ethoxylated or non-ethoxylated alkyl or alkaryl carboxylates, alkyl or alkyaryl phosphate esters, alkyl polysaccharide, di or mono alkyl sulfosuccinate derivatives, alpha olefin sulfonates, alkyl naphthalene sulfonates, dialkyl sulphosuccinates, butyl, dibutyl, isopropyl and diisopropyl naphthalene sulfonate salts, C12 alkyl benzene sulfonate or C10-C16 alkyl benzene sulfonate;

[CLAIM 23]. The synergistic agrochemical composition as claimed in claim 20, wherein disintegrating agent is selected from citric acid, succinic acid or the sodium bicarbonate.

[CLAIM 24]. The synergistic agrochemical composition as claimed in claim 20, wherein antifoaming agent is polydimethylsiloxane.

[CLAIM 25]. The synergistic agrochemical composition as claimed in claim 1- claim 5, wherein preferred compositions for the GR (Controlled Release Granules) formulation comprises:
i. Controlled Release granule (CR) formuation of Pymetrozine 2% + Paclobutrazol 0.5% + Triflumezopyrim 0.5%
ii. Controlled Release granule (CR) formuation of Pymetrozine 2% + Paclobutrazol 0.5% + Clothianidin 1%
iii. Controlled Release granule (CR) formuation of Pymetrozine 2% + Paclobutrazol 0.5% + Thiamethoxam 1.2%.

[CLAIM 26]. The synergistic agrochemical composition as claimed in claim 1- claim 5 wherein, the GR (Controlled/slow Release Granules) formulation comprises:
i. an insecticide from the group Selective feeding blocker in an amount of 0.1 to 40% by weight of the composition is Pymetrozine;
ii. a plant growth regulator in an amount of 0.001 to 20% by weight of the composition is Paclobutrazol;
iii. at least an insecticides from various group in an amount of 0.1 to 40% by weight is Triflumezopyrim, Clothianidin, Thiamethoxam;
iv. Wetting agent in an amount of 2 to 6 % by weight;
v. Dispersing agent in an amount of 1to 3 % by weight;
vi. Slow release agent in an amount of 15 to 30% by weight;
vii. Colourant in an amount of 0.2 to 1.0 % by weight;
viii. Solvent in an amount of 2 to 8 % by weight;
ix. Carrier in an amount of 50 to 80% by weight.

[CLAIM 27]. The synergistic agrochemical composition as claimed in claim 26, wherein wetting agent is selected from mono C2-6 alkyl ether of a poly C2-4 alkylene oxide block copolymer, condensation product of castor oil and poly C2-4 alkylene oxide, alkoxylated castor oil, ethoxylated castor oil, a mono- or di-ester of a C12-24 fatty acid and poly C2-4 alkylene oxide, carboxylates, sulphates, sulphonates, alcohol ethoxylates, alkyl phenol ethoxylates, fatty acid ethoxylates, sorbitan esters, ethoxylated fats or oils, amine ethoxylates, phosphate esters, ethylene oxide - propylene oxide copolymers, fluorocarbons, alkyd-polyethylene glycol resin, polyalkylene glycol ether, apoly alkoxylated nonyl phenyl, alkoxylated primary alcohol, ethoxylated distyryl phenol, ethoxylated distyryl phenol sulphate, ethoxylated tristyrylphenol phosphate, tristyrylphenol phosphate ester, hydroxylated stearic acid polyalkylene glycol polymer and their corresponding salts, alkyd-polyethylene glycol resin, polyalkylene glycol ether, ethoxylated distyryl phenol, ethoxylated distyryl phenol sulphate, ethoxylated tristyrylphenol phosphate, tristyrylphenol phosphate ester, tristyrylphenol phosphate potassium salt, dodecyl sulfate sodium salt.

[CLAIM 28]. The synergistic agrochemical composition as claimed in claim 26, wherein Dispersing agent is selected from copolymer of propylene oxide (PO) and ethylene oxide (EO) and/or an ethoxylated tristyrene phenol, copolymer of PO and EO is alpha-butyl-omega-hydroxypoly (oxypropylene) block polymer with poly(oxyethylene), ethoxylated tristyrene phenol is alpha-[2,4,6-tris[1-(phenyl)ethyl] phenyl]-omega-hydroxy poly(oxyethylene, poly(oxy-1,2-ethanediyl)-alpha-C10-15alkyl-omega-hydroxy phosphate or sulphate and/or a C10-13 alkylbenzene sulfonic acid, tristyrylphenols, nonylphenols, dinonylphenol and octyl phenols, styryl phenol polyethoxyester phosphate, alkoxylated C14-20 fatty amines.

[CLAIM 29]. The synergistic agrochemical composition as claimed in claim 26, wherein Slow releasing agent is selected from xanthan gum, PVK, carboxymethyl celluloses, polyvinyl alcohols, gelatine, sodium carboxymethylcellulose, hydroxyethyl cellulose, Sodium Polyacrylate, modified starch, paraffin wax, polyvinyl acetate, montane wax and vinyl acetate, polyethylene glycol 6000, cationic hydro soluble polymer, C4 alkylated polyvinyl pyrrolidone.

[CLAIM 30]. The synergistic agrochemical composition as claimed in claim 1- claim 5, wherein preferred compositions for the Suspo-emulsion (SE) formulation comprises:
i. Suspoemulsion (SE) formulation of Afidopyropen 4% + Brassinolide 0.025% + Diafenthiuron 20%
ii. Suspoemulsion (SE) formulation of Pyrifluquinazon 5% + Gibberellic acid 0.1% + Pyriproxyfen 5%
iii. Suspoemulsion (SE) formulation of Pymetrozine 10% + Brassinolide 0.025% + Tolfenpyrad 10%
iv. Suspoemulsion (SE) formulation of Pyrifluquinazon 8% + Gibberellic acid 0.2% + Tolfenpyrad 15%
v. Suspoemulsion (SE) formulation of Flonicamid 5% + Brassinolide 0.025% + Tolfenpyrad 10%.
vi. Suspoemulsion (SE) formulation of Flonicamid 5% + Gibberellic acid 0.1% + Pyriproxyfen 5%
vii. Suspoemulsion (SE) formulation of Pyrifluquinazon 5%+ Brassinolide 0.025%+ Pyriproxyfen 5%
viii. Suspoemulsion (SE) formulation of Pyrifluquinazon 5%+ Triacontanol 0.025%+ Pyriproxyfen 5%
ix. Suspoemulsion (SE) formulation of Pyrifluquinazon 5%+ Paclobutrazol 4%+ Pyriproxyfen 5%
x. Suspoemulsion (SE) formulation of Pyrifluquinazon 5%+ Mepiquat chloride 3%+ Pyriproxyfen 5%
xi. Suspoemulsion (SE) formulation of Flonicamid 5%+ Brassinolide 0.025+ Pyriproxyfen 5%
xii. Suspoemulsion (SE) formulation of Flonicamid 5%+ Gibberellic Acid 0.1+Pyriproxyfen 5%
xiii. Suspoemulsion (SE) formulation of Flonicamid 5%+ Triacontanol 0.025+ Pyriproxyfen 5%
xiv. Suspoemulsion (SE) formulation of Afidopyropen 4%+ Brassinolide 0.025%+ Diafenthiuron 22.5%
xv. Suspoemulsion (SE) formulation of Afidopyropen 4%+ Gibberellic Acid 0.1%+ Diafenthiuron 22.5%
xvi. Suspoemulsion (SE) formulation of Afidopyropen 4%+ Triacontanol 0.025% + Diafenthiuron 22.5%
xvii. Suspoemulsion (SE) formulation of Afidopyropen 4%+ Paclobutrazol 4%+ Diafenthiuron 22.5%
xviii. Suspoemulsion (SE) formulation of Afidopyropen 4%+ Mepiquat chloride 3%+ Diafenthiuron 22.5%.

[CLAIM 31]. The synergistic agrochemical composition as claimed in claim 1- claim 5 wherein, the Suspo-emulsion (SE) formulation comprises:
i. an insecticide from the group Selective feeding blocker in an amount of 0.1 to 40% by weight of the composition is Flonicamid, Afidopyropen, Pyrifluquinazon, Pymetrozine;
ii. a plant growth regulator in an amount of 0.001 to 20% by weight of the composition is Brassinolide, Gibberellic acid, Triacontanol, Paclobutrazol, Mepiquat chloride;
iii. at least an insecticides from various group in an amount of 0.1 to 40% by weight is Diafenthiuron, Pyriproxyfen, Tolfenpyrad, Diafenthiuron;
iv. Solvent in an amount of 8 to 12 % by weight;
v. Wetting and spreading agent in an amount of 2 to 6 % % by weight;
vi. Dispersing agent 1 in an amount of 2 to 8 % by weight;
vii. Dispersing agent 2 in an amount of 1to 3 % by weight;
viii. Suspending agent in an amount of 0.2 to 4.0 % by weight;
ix. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
x. Preservative in an amount of 0.1 to 0.5 % by weight;
xi. Antifreezing agent in an amount of 2 to 6 % by weight;
xii. Thickner in an amount of 0.1 to 1.0 % by weight;
xiii. Diluent Water in an amount of 40 to 70 % by weight.

[CLAIM 32]. The synergistic agrochemical composition as claimed in claim 31, wherein Emulsifier is selected from salts of dodecyl benzene sulphonate, e.g. Ca-salts or amine salts, and sulphonates of other C11-C16 alkyl benzenes, alkyl ether sulphates, alkyl phenol ether phosphates and ester phosphates; non-ionic surfactants such as alkoxylated alcohols and alkyl phenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid esters, e.g. of sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; and catanionic emulsifiers such as a cationic amine, optionally in combination with an alkyl sulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkyl phenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol; fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkyl benzenes in the range C11-C16 and salts thereof; alkyl ether sulphates; alkyl ether phosphates; alkyl phenol ether phosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenol; or a catanionic system, wherein a cationic amine is present in combination with an alkyl sulphonate, an alkyl ether sulphonate, an ether sulphate, or an ether phosphate such as an alkyl ether phosphate, nonyl phenol poly ethoxy ethanols, castor oil polyglycol ethers, poly adducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol;

[CLAIM 33]. The synergistic agrochemical composition as claimed in claim 31, wherein Stabilizer is selected from butylated hydroxy toluene (BHT) and epoxidized soybean oil (ESBO), Epichlorhydrin.

[CLAIM 34]. The synergistic agrochemical composition as claimed in claim 31, wherein dispersing agent is selected from alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycol ether-phosphate, tristyryl phenole with 16 moles EO, tristyrylphenol-polyglycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonyl phenol poly glycol ether with 9-10 moles ethylene oxide, polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methyl methacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetate butyrate, acetylated mono, di, and triglycerides, poly(vinyl pyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these; biodegradable polymers include biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, poly dioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, poly caprolactone, poly(namyl methacrylate), wood rosin, poly anhydrides, poly vinyl alcohol, poly hydroxy butyrate valerate, biodegradable aliphatic polyesters, and poly hydroxy butyrate or mixtures thereof.

[CLAIM 35]. The synergistic agrochemical composition as claimed in claim 31, wherein buffering agent is selected from as used herein is selected from group consisting of calcium hydroxyapatite, Potassium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.

[CLAIM 36]. The synergistic agrochemical composition as claimed in claim 31, wherein wetting agent is selected from Ethylene oxide/propylene oxide block copolymer, Polyarylphenyl ether phosphate, Ethoxylated Fatty Alcohol, Sodium dioctyl sulfosuccinate, sodium lauryl sulphate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, Alkyl naphthalene sulfonate, Octyl phenol ethoxylate, alkyl phenol ethoxylate, trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane and aliphatic alcohol ethoxylate or mixture thereof etc;

[CLAIM 37]. The synergistic agrochemical composition as claimed in claim 31, wherein suspending agent is selected from aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.

[CLAIM 38]. The synergistic insecticidal composition as claimed in claim 1 and claim 5, wherein SC (Suspension concentrate) formulation, SE (Suspo Emulsion) formulation, and Oil dispersion (OD) formulation further comprises of Wetting and spreading agent and is selected from trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof, organic silicone as super wetting agent - speading agent and penetrating agent to improves the bioefficacy of the products.