The present invention relates to synergistic formulation for pestcidal compositions comprising bioactive amounts of (A) a fungicide selected from class of SDHI (Succinate dehydrogenase inhibitor); (B) an insecticide selected from the class of neonicotinoids, chordotonal organs modulators, diamides, metadiamides, isoxazolines, insecticides with unknow mode of action or unclassified or mixture thereof. The present invention further relates to process of preparing said composition along with at least one inactive excipients and formulation thereof.
BACKGROUND OF THE INVENTION:
Combination of insecticides and fingicides are used to broaden the spectrum of control of insect and fungi, to improve the pest control with synergistc effect, reduce dosage, thereby reducing environmental impact, to broaden the spectrum of control, i.e. chewing and sucking insects at a time, decrease chances of development and management of resistance and to enhance residual control so lesser the number of sprays for crop protections and minimizing the pesticidal load in ecosystem. The combination of insecticides at times demonstrate an additive or synergistic effect that results in an improved control on the pests.
Insecticide or pesticides are used widely and very frequently in commercial agriculture
and have enabled an enormous increase in crop yields and product quality which
ultimately increased the ease to farmers in term of economic advantage as well as ease of farming activities.
There are many combinations of insecticide along with fungicides known in the art for the control of soil borne pests. For example, WO2014130409 patent relates to relates to certain pyrazole derivatives, their N-oxides and salts, and to mixtures and compositions comprising such pyrazole derivatives and methods for using such pyrazole derivatives and their mixtures and compositions as fungicides. The patent further relates to disclosing fluxapyroxad and cyclaniliprole along with other pesticidal agents.
US20190322631 patent relates to pesticidal composition agriculturally useful salts and to their use for controlling phytopathogenic fungi, or to a method for combating phytopathogenic harmful fungi, which process comprises treating the fungi, the plants, the soil or seeds to be protected against fungal attack and to mixtures comprising at least one such compound and at least one further pesticidally active substance selected from the group consisting of herbicides, safeners, fungicides, insecticides, and plant growth regulators. The patent further relates composition comprising fluxapyroxad and flupyrimin along with other pesticidal agents.
WO2015157005 patent relates to certain substituted tolyl compounds, their N-oxides and salts, and to mixtures and compositions comprising such pyrazole derivatives and methods for using such substituted tolyl compounds and their mixtures and compositions as fungicides. The patent further relates composition comprising fluxapyroxad and triflumezopyrim along with other pesticidal agents.
There is however a need for improvement of these combinations. Single active combinations used over a long period of time has resulted in resistance. With the onset of resistance to certain pests, there is a need in the art for a combination of actives that decreases chances of resistance and improves the spectrum of disease and pest control.
However still there is a need for a composition comprises of a fungicide selected from class of SDHI (Succinate dehydrogenase inhibitors); and an insecticide selected from the class of neonicotinoids, chordotonal organs modulators, diamides, metadiamides, isoxazolines, insecticides with unknow mode of action or unclassified which overcomes some of the existing problems and can be prepared easily without much complex manufacturing process.
In general use, the pesticide actives are used in the form of a dilute aqueous composition because it can attain a good interaction with the target organism, such as plants, fungi and insects. However, most active pesticide compounds that are used as pesticides are only sparingly or even insoluble in water. The low solubility of such compounds present the challenges and difficulties to formulator in formulating pesticide compounds in stable formulations that can be easily stored for a long time and which still have a high stability and effective activity until end use. This problem especially occurs and may get worsen if more than one active compound is present in the composition.

Therefore the object of the present invention is to provide novel synergistic and stable Oil Dispersion formulation, Suspension concentrate (SC) formulation comprising (A) a fungicide selected from class of SDHI (Succinate dehydrogenase inhibitor); (B) an insecticide selected from the class of neonicotinoids, chordotonal organs modulators, diamides, metadiamides, isoxazolines, insecticides with unknow mode of action or unclassified or mixture thereof.
Therefore, one object of the present invention is to provide improved combinations of insecticides and fungicides for the control of foliar feeder and soil born pests. Another object of the present invention is to provide a method and a composition for controlling insect pests.
Yet another object of the present invention is to provide improved combinations of insecticide and fungicides that promote plant health.
Embodiment of the present invention can ameliorate one or more of the above mentioned problems.

Inventors of the present invention have surprisingly found that the novel synergistic
formulation for pesticidal composition of a fungicide selected from class of SDHI (Succinate dehydrogenase inhibitors); and an insecticide selected from the class of neonicotinoids, chordotonal organs modulators, diamides, metadiamides, isoxazolines, insecticides with unknow mode of action or unclassified as described herein which can provide solution to the above mentioned problems.

SUMMARY OF THE INVENTION
Therefore an aspect of the present invention provides a synergistic formulation for pesticidal compositions comprising bioactive amounts of (A) a fungicide selected from class of SDHI (Succinate dehydrogenase inhibitors); (B) an insecticide selected from the class of neonicotinoids, chordotonal organs modulators, diamides, metadiamides, isoxazolines, insecticides with unknow mode of action or unclassified or mixture thereof.
Further aspect of the present invention provides a synergistic formulation for pesticidal compositions comprising bioactive amounts of (A) a fungicide selected from class of SDHI (Succinate dehydrogenase inhibitors) selected from benodanil, flutolanil, mepronil, isofetamid, fluopyram, fenfuran, carboxin, oxycarboxin, thifluzamide, benzovindiflupyr, bixafen, fluindapyr, fluxapyroxad, furametpyr, isopyrazam, penflufen, penthiopyrad, sedaxane, flubeneteram, pyrapropoyne, inpyrfluxam, isoflucypram, pydiflumetofen, boscalid and pyraziflumid; (B) an insecticide from the class of neonicotinoids selected from flupyrimin, triflumezopyrim, dichloromezotiaz, cycloxaprid, paichongding, guadipyr, cycloxylidin; from class of chordotonal organs modulators selected from pyrifluquinazon, afidopyropen; from class of diamides selected from cyclaniliprole, cyhalodiamide, cyproflanilide, tetraniliprole, tetrachlorantraniliprole, tyclopyrazoflor; from class of metadiamides is broflanilide; from class of isoxazolines selected from fluxametamide, isocycloseram; insecticides with unknow mode of action or unclassified selected from benzpyrimoxan (insect growth regulators), oxazosulfyl, dimpropyridaz (pyrazole carboxamide insecticide) and flometoquin or mixture thereof.
Accordingly, in a further aspect, the present invention provides a method of protecting a plant propagation material, a plant, parts of a plant and/or plant organs that grow at a later point in time against pathogenic damage or pest damage by applying to the plant propagation material a composition comprising a pesticidal composition defined in the first aspect.
Another aspect of the present invention provides synergistic formulation for pesticidal composition comprising agrochemical composition is Suspension Concentrate (SC) and Oil Dispersion (OD) formulation.
In an aspect of the present invention provides Oil Dispersion (OD) formulation comprises of vegetables oil as carrier that increases penetration into leaf surfaces, especially plant, improves retention of active ingredients on leaf surfaces, increases spreading action, so faster spray coverage on leaf surface and easily dissolve the waxy layer of the leaf surface.
Another aspect of the present invention provides the Oil Dispersion formulation of the present agrochemical composition increases the bioefficacy of targets insect-pests with reduced dose of active ingredient.
Further aspect of the present invention provides the Suspension Concentrate (SC) formulation comprises Trisiloxane Ethoxylate as a wetting spreading and penetrating agent promotes the rapid intake of the pesticide on leaf or the affected plant surface and acts as a ‘superspreader’ of pesticides over moderately hydrophobic surface to a very large area, usually in a short time period.
As per one embodiment formulation for the pesticidsal composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Powder for dry seed treatment (DS), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion for seed treatment (ES), Emulsion, oil in water (EW), Flowable suspension/concentrate for seed treatment (FS), Granule/ soil applied (GR), Controlled (Slow or Fast) release granules (CR), Solution for seed treatment (LS), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (flowable concentrate) (SC), Suspo-emulsion (SE), Water soluble granule (SG), Soluble concentrate (SL), Water soluble powder (SP), Water dispersible granule (WG or WDG), Wettable powder (WP), Water dispersible powder for slurry treatment (WS), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW); and and one or more customary formulation adjuvants such as a) dispersant b) wetting agent c) anti-foaming agent d) biocides e) anti-freezing agent f) suspending agent g) thickener h) coating agent and i) buffering agent.
The remainder of the aqueous formulation is preferably wholly water but may comprise other materials, such as inorganic salts. The formulation is preferably, completely free from organic solvents.
Accordingly, in a first aspect, the present invention provides a synergistic formulation for pesticidal compositions comprising bioactive amounts of (A) a fungicide selected from class of SDHI (Succinate dehydrogenase inhibitors); (B) an insecticide selected from the class of neonicotinoids, chordotonal organs modulators, diamides, metadiamides, isoxazolines, insecticides with unknow mode of action or unclassified; and one or more customary formulation adjuvants; shows synergistic activity.

DETAILED DESCRIPTION OF THE INVENTION:
The term "synergistic", as used herein, refers the combined action of two or more active
agents blended together and administered conjointly that is greater than the sum of their
individual effects.
"Bioactive amounts” as mentioned herein means that amount which, when applied treatment of crops, is sufficient to effect such treatment.
Therefore an aspect of the present invention provides a synergistic pesticidal compositions comprising bioactive amounts of (A) a fungicide selected from class of SDHI (Succinate dehydrogenase inhibitors); (B) an insecticide selected from the class of neonicotinoids, chordotonal organs modulators, diamides, metadiamides, isoxazolines, insecticides with unknow mode of action or unclassified.
More particularly a further aspect of the present invention provides a synergistic pesticidal compositions comprising bioactive amounts of (A) a fungicide selected from class of SDHI (Succinate dehydrogenase inhibitors) selected from benodanil, flutolanil, mepronil, isofetamid, fluopyram, fenfuran, carboxin, oxycarboxin, thifluzamide, benzovindiflupyr, bixafen, fluindapyr, fluxapyroxad, furametpyr, isopyrazam, penflufen, penthiopyrad, sedaxane, flubeneteram, pyrapropoyne, inpyrfluxam, isoflucypram, pydiflumetofen, boscalid and pyraziflumid; (B) an insecticide from the class of neonicotinoids selected from flupyrimin, triflumezopyrim, dichloromezotiaz, cycloxaprid, paichongding, guadipyr, cycloxylidin; from class of chordotonal organs modulators selected from pyrifluquinazon, afidopyropen; from class of diamides selected from cyclaniliprole, cyhalodiamide, cyproflanilide, tetraniliprole, tetrachlorantraniliprole, tyclopyrazoflor; from class of metadiamides is broflanilide; from class of isoxazolines selected from fluxametamide, isocycloseram; insecticides with unknow mode of action or unclassified selected from benzpyrimoxan (insect growth regulators), oxazosulfyl, dimpropyridaz (pyrazole carboxamide insecticide) and flometoquin or mixture thereof.
In an embodiment of the present invention an insecticides from class of SDHI (Succinate dehydrogenase inhibitors) selected from benodanil, flutolanil, mepronil, isofetamid, fluopyram, fenfuran, carboxin, oxycarboxin, thifluzamide, benzovindiflupyr, bixafen, fluindapyr, fluxapyroxad, furametpyr, isopyrazam, penflufen, penthiopyrad, sedaxane, flubeneteram, pyrapropoyne, inpyrfluxam, isoflucypram, pydiflumetofen, boscalid and pyraziflumid or mixture thereof.
In an embodiment of the present invention an insecticides from class of neonicotinoids selected from flupyrimin, triflumezopyrim, dichloromezotiaz, cycloxaprid, paichongding, guadipyr, cycloxylidin or mixture thereof.
In an embodiment of the present invention an insecticides from class of chordotonal organs modulators selected from pyrifluquinazon, afidopyropen or mixture thereof.
In an embodiment of the present invention an insecticides from class of diamides selected from cyclaniliprole, cyhalodiamide, cyproflanilide, tetraniliprole, tetrachlorantraniliprole, tyclopyrazoflor or mixture thereof.
In an embodiment of the present invention an insecticides from class of metadiamides is broflanilide;
In an embodiment of the present invention an insecticides from class of isoxazolines selected from fluxametamide, isocycloseram or mixture thereof.
In an embodiment of the present invention an insecticide with unknow mode of action or unclassified selected from benzpyrimoxan (insect growth regulators), oxazosulfyl, dimpropyridaz (pyrazole carboxamide insecticide) and flometoquin or mixture thereof.
Succinate Dehydrogenase Inhibitors Fungicides:
Succinate dehydrogenase inhibitors (SDHIs) are active substances used in fungicidal products to control certain fungi and moulds affecting crops. SDHIs prevent their development by blocking an enzyme involved in cell respiration: succinate dehydrogenase (SDH).
Fluxapyroxad is an aromatic amide class of fungicide. It has a role as a succinate dehydrogenase (quinone) inhibitor and an antifungal agrochemical. It is used to control a number of cereal fungal pathogens including those belonging to the Ascomycetes, Basidiomycetes and Zygomycetes families. It targets the succinate dehydrogenase, one of the enzymes in the respiratory chain within the mitochondria of the fungus.
Flubeneteram, belongs to the class of anilide fungicide or pyrazolecarboxamide fungicides. It has IUPAC name as 2'-[2-chloro-4-(trifluoromethyl) phenoxy]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxanilide.
Isoflucypram, the first representative of a newly installed subclass of SDHIs inside the Fungicide Resistance Action Committee (FRAC) family of complex II inhibitors, offers unparalleled long-lasting efficacy against major foliar diseases in cereals. It has IUPAC name as N-(5-Chlor-2-isopropylbenzyl)-N-cyclopropyl-3-(difluormethyl)-5-fluor-1-methyl-1H-pyrazol-4-carboxamid.
Nicotinic class of insecticides
Flupyrimin, a novel chemotype nicotinic insecticide. It has IUPAC name as N-[(E)-1-(6-chloro-3-pyridinylmethyl)pyridin-2(1H)-ylidene]-2,2,2-trifluoroacetamide. It acts as a nicotinic antagonist in American cockroach neurons, binds to the multiple high-affinity binding components in house fly nicotinic acetylcholine (ACh) receptor (nAChR) preparation
Triflumezopyrim, is an insecticide from nicotinic insecticide class. It has IUPAC name as 4-oxo-1-(pyrimidin-5-ylmethyl)-3-[3-(trifluoromethyl) phenyl] pyrido [1, 2-a] pyrimidin-1-ium-2-olate. Triflumezopyrim belongs to the class of mesoinic insecticides, binding to the orthosteric site of nicotinic acetylcholine receptor.
Dichloromezotiaz, is a pyridopyrimidine that is 9-methyl-2,4-dioxo-2H-pyrido[1,2-a]pyrimidine substituted at positions 1 and 3 by (2-chloro-1,3-thiazol-5-yl)methyl and 3,5-dichlorophenyl. A mesionic insecticide used for control of rice hoppers. It has a role as an agrochemical. It is an iminium betaine, an organochlorine insecticide, a dichlorobenzene, a member of 1,3-thiazoles and a pyridopyrimidine. It has IUPAC name as 1-[(2-chloro-1,3-thiazol-5-yl)methyl]-3-(3,5-dichlorophenyl)-9-methyl-4-oxopyrido[1,2-a]pyrimidin-1-ium-2-olate.
Diamide class of insecticides:
Cyclaniliprole is diamide group of insecticide. More particularly cyclaniliprole, is a member of cyclopropanes, a member of pyrazoles, anorganobromine compound, a chloropyridine, a secondary carboxamide, a member of monochlorobenzenes and a member of bromobenzenes. It has IUPAC name as 5-bromo-N-[2-bromo-4-chloro-6-(1-cyclopropylethylcarbamoyl) phenyl]-2-(3-chloropyridin-2-yl) pyrazole-3 carboxamide.

Metadiamide class of insecticides:
Broflanilide, is metadiamide class of insecticide that exhibits high larvicidal activity against Spodoptera litura and is effective against pests with resistance to cyclodienes and fipronil. It has IUPAC name as 3-[benzoyl(methyl)amino]-N-[2-bromo-4-(1,1,1,2,3,3,3-heptafluoropropan-2-yl)-6-(trifluoromethyl)phenyl]-2-fluorobenzamide. It has a role as an agrochemical and a GABA antagonist. It is a member of benzamides, a member of monofluorobenzenes, an organofluorine insecticide, a member of bromobenzenes and a member of (trifluoromethyl) benzenes.
Insecticides with unknown mode of action:
Dimpropyridaz is pyrazole carboxamide class of insecticide. Dimpropyridaz chemically is a pyrazole carboxamide insecticide that has a pyridin-3-yl group, as in tyclopyrazoflor. Dimpropyridaz is effective against aphids. Dimpropyridaz mechanism of action is unknown. It has IUPAC name as 1-[(1RS)-1,2-dimethylpropyl]-N-ethyl-5-methyl-N-pyridazin-4-yl-1H-pyrazole-4-carboxamide.
The present inventors believe that the combination of the present invention surprisingly results in a synergistic action. The combinations of the present invention allow for a broad spectrum of pest control and has surprisingly improved plant vigour and yield. The broad spectrum of the present combination also provides a solution for preventing the development of resistance.
The synergistic composition has very advantageous curative, preventive and systemic Insecticidal properties for protecting cultivated plants. As has been mentioned, said active ingredient composition can be used to inhibit or destroy the pathogens that occur on plants or parts of plants (fruit, blossoms, leaves, stems, tubers, roots) of different crops or useful plants, while at the same time those parts of plants which grow later are also protected from attack by such pathogens. Active ingredient composition has the special advantage of being highly active against diseases in the soil that mostly occur in the early stages of plant development.
The synergistic composition of pesticide are used to protect the crops and plants from insect and pests. The lists of the major crops includes but are not limited to GMO (Genetically Modified Organism) and Non GMO varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticum aestavum), Barley (Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Oat (Avena sativa), Pearl millet (Pennisetum glaucum), Sugarcane (Saccharum officinarum) , Sugarbeet (Beta vulgaris), Soybean (Glycin max), Peanut (Arachis hypogaea), Sunflower (Helianthus annuus) , Mustard (Brassica juncea), Rape seed (Brassica napus), Linseed (Linum usitatissimum), Sesame (Sesamum indicum), Green gram (Vigna radiata), Black gram (Vigna mungo), Chickpea (Cicer aritinum), Cowpea (Vigna unguiculata), Redgram (Cajanus cajan), Frenchbean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotyloma uniflorum), Field pea (Pisum sativum), Cluster bean (Cyamopsis tetragonoloba), Lentils (Lens culinaris), Brinjal (Solanum melongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschus esculentus) , Onion (Allium cepa L.), Tomato (Solanum lycopersicun) , Potato (Solanum tuberosum) , Sweet potato (Ipomoea batatas), Chilly (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumis sativus), Muskmelons (Cucumis melo), Watermelon (Citrullus lanatus), Bottle gourd (Lagenaria siceraria), Bitter gourd (Momordica charantia), Radish (Raphanus sativus), Carrot (Dacus carota subsp. sativus), Turnip (Brassica rapa subsp rapa), Apple (Melus domestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitis vinifera), Guava (Psidium guajava), Litchi (Litchi chinensis), Mango (Mangifera indica), Papaya (Carica papaya), Pineapple (Ananas comosus), Pomegranate (Punica granatum) , Sapota (Manilkara zapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiber officinale), Cumin (Cuminum cyminum), Fenugreek (Trigonella foenum-graecum), Fennel (Foeniculum vulgare), Coriander (Coriandrum sativum), Ajwain (Trachyspermum ammi), Psyllium (Plantago ovate), Black Pepper (Piper nigrum), Stevia (Stevia rebaudiana), Safed musli (Chlorophytum tuberosum), Drum stick (Moringa oleifera), Coconut (Coco nucifera), Mentha ( Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold ( Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera ( Gerbera jamesonii), Carnation (Dianthus caryophyllus), vegetables: solanaceous vegetables such as eggplant, tomato, pimento, pepper, potato, etc., cucurbit vegetables such as cucumber, pumpkin, zucchini, water melon, melon, squash, etc., cruciferous vegetables such as radish, white turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, leaf mustard, broccoli, cauliflower, etc., asteraceous vegetables such as burdock, crown daisy, artichoke, lettuce, etc, liliaceous vegetables such as green onion, onion, garlic, and asparagus, ammiaceous vegetables such as carrot, parsley, celery, parsnip, etc., chenopodiaceous vegetables such as spinach, Swiss chard, etc., lamiaceous vegetables such as Perilla frutescens, mint, basil, etc, strawberry, sweet potato, Dioscorea japonica, colocasia, etc., flowers, foliage plants, turf grasses, fruits: pome fruits such apple, pear, quince, etc, stone fleshy fruits such as peach, plum, nectarine, Prunus mume, cherry fruit, apricot, prune, etc., citrus fruits such as orange, lemon, rime, grapefruit, etc., nuts such as chestnuts, walnuts, hazelnuts, almond, pistachio, cashew nuts, macadamia nuts, etc. berries such as blueberry, cranberry, blackberry, raspberry, etc., grape, kaki fruit, olive, plum, banana, coffee, date palm, coconuts, etc. , trees other than fruit trees; tea, mulberry, flowering plant, trees such as ash, birch, dogwood, Eucalyptus, Ginkgo biloba, lilac, maple, Quercus, poplar, Judas tree, Liquidambar formosana, plane tree, zelkova, Japanese arborvitae, fir wood, hemlock, juniper, Pinus, Picea, and Taxus cuspidate, etc.
The synergistic composition of the present invention used to control the insects-pests. The major insects pests are belongs to the order Hemiptera, for example, rice leafhopper Nephotettix nigropictus, rice brown plant hopper Nilaparvata lugen, rice white backed plant hopper, Apple Mealy bug Phenococcus aceris, bean aphid Aphis fabae, black citrus aphid Toxoptera aurantii, citrus black scale Saissetia oleae, cabbage aphid Brevicoryne brassicae, Lipaphis erysimi, citrus red scale Aonidiella aurantii, yellow scale Aonidiella citrine, citrus mealybug Planococcus citri, corn leaf aphid Rhopalosiphum maidis, cotton aphid Aphis gossypii, cotton jassid Amrasca biguttula biguttla, cotton mealy bug Planococcus spp. And Pseudococcus spp., cotton stainer Dysdercus suturellus, cotton whitefly Bemisia tabaci, cowpea aphid Aphis crassivora, grain aphid Sitobion avenae, golden glow aphid Uroleucon spp., grape mealybug Pseudococcus maritimus, green peach aphid Myzus persicae, greenhouse whitefly Trialeurodes vaporariorum, papaya mealy bug Pracoccus marginatus, pea aphid Acyrthosiphon pisum, sugarcane mealybug Saccharicoccus sacchari, potato aphid Myzus persicae, potato leaf hopper Empoasca fabae, cotton whitefly Bemisia tabaci, tarnished plant bug Lygus lineolaris, wooly apple aphid Eriosoma lanigerum, mango hopper Amritodus atkinsoni, Idioscopus spp. ; order Lepidoptera, army worm Mythimna unipuncta, asiatic rice borer Chilo suppressalis, bean pod borer Maruca vitrata, beet armyworm Spodoptera exigua, black cutworm Agrotis ipsilon, bollworm Helicoverpa armigera , cabbage looper Trichoplusia ni, codling moth Cydia pomonella, croton caterpillar Achea janata, diamond backmoth Plutella xylostella, cabbage worm Pieris rapae, pink bollworm Pectinophora gossypiella, sugarcane borer Diatraea saccharalis, tobacco budworm Heliothis virescens, tomato fruitworm Helicoverpa zea, velvet bean caterpillar Anticarsia gemmatalis, yellow stem borer Scirpophaga incertulas, spotted bollworm Earias vittella, rice leaffolder Cnaphalocrocis medinalis, pink stem borer Sesamia spp., tobacco leafeating caterpillar Spodoptera litura; brinjal fruit and shoot borer Leucinodes orbonalis, bean pod borer Maruca vitrata, Maruca testulalis, armyworm Mythimna separata, cotton pinkbollworm Pectinophora gossypiella, citrus leafminer Phyllocnistis citrella, cabbage butterfly Pieris bras-sicae, diamond backmoth Plutella xylostella, paddy stem borer Scirpophaga excerptallis, Scirpophaga incertulas, Scirpophaga innotata, wheat stem borer Sesamia inferens, Sitotroga cerealella, Spilosoma obliqua, Spodoptera frugiperda, Spodoptera littoralis, Spodoptera litura, Trichoplusia ni, Tryporyza novella, Tuta absoluta.
from the order Coleoptera, for example, apple twig borer Amphicerus spp., corn root worm Diabrotica virgifera, cucumber beetle diabrotica balteata, boll weevil Anthonomus grandis, grape flea beetle Altica chalybea, grape root worm Fidia viticola, grape trunk borer Clytoleptus albofasciatus, radish flea beetle Phyllotreta armoraciae, maize weevil Sitophilus zeamais, northern corn rootworm Diabrotica barberi, rice water weevil Lissorhoptrus oryzophilus, Anthonomus grandis, Bruchus lentis, Diabrotica semipunctata, Diabrotica virgifera, Dicladispa armigera, Epila-chna varivestis, various species of white grubs are Holotrichia bicolor, Holotrichia consanguinea, Holotrichia serrata, Leptinotarsa decemlineata, Phyllotreta chrysocephala, Popillia japonica etc; from the order Orthoptera, for example, Gryllotalpa spp., Locusta spp., and Schistocerca is spp.; from the order Thysanoptera, for example, Frankliniella spp., Thrips palmi, Thrips tabaci and Scirtothrips dorsalis; termites (Isoptera), e.g. Calotermes flavicollis, Coptotermes formosanus, Heterotermes aureus, Leucotermes flavipes, Microtermes obesi, Odontotermes obesus, Reticulitermes flavipes, Termes natalensis; from the order Heteroptera, for example, Dysdercus spp., Leptocorisa spp., from the order Hymenoptera, for example, Solenopsis spp. ; from the order Diptera, for example, Antherigona soccata, Dacus spp., Liriomyza spp., Melanagromyza spp., from the order Acarina, for example, Aceria mangiferae, Brevipalpus spp., Eriophyes spp., Oligonychus mangiferus, Oligonychus punicae, Panonychus citri, Panonychus ulmi, Polyphagotarsonemus latus, Tarsonemus spp., Tetranychus urticae, Tetranychus cinnabarinus;
The mixtures according to the invention can be applied to any and all developmental stages of pests, such as egg, larva, pupa, and adult. The pests may be controlled by contacting the target pest, its food supply, habitat, breeding ground or its locus with a pesticidally effective amount of the inventive mixtures or of compositions comprising the mixtures.
The compositions according to the present invention is also effective for controlling the fungal and bacterial plant diseases as
Disease in rice: Blast (Magnaporthe grisea), Helminthosporium leaf spot (Cochliobolus miyabeanus), sheath blight (Rhizoctonia solani), bakanae disease (Gibberella fujikuroi) and grain discoloration (dirty panicles caused by Alternaria spp., Curvularia spp., Drechslera spp., Fusarium spp., Phoma spp. Etc.)
Diseases in wheat: powdery mildew (Erysiphe graminis) , Fusariuin head blight (Fusarium graminearum, F. avenacerum, F. culmorum, Microdochium nivale) , rust (Puccinia striiformis, P. graminis, P. recondita) , pink snow mold (Micronectriella nivale), Typhula snow blight (Typhula sp . ) , loose smut (Ustilago tritici) , bunt (Tilletia caries) , eyespot (Pseudocercosporella herpotrichoides) , leaf blotch (Mycosphaerella graminicola) , glume blotch (Stagonospora nodorum) , septoria, and yellow spot (Pyrenophora tritici-repentis) .
Diseases of barley: powdery mildew (Erysiphe graminis), Fusarium head blight (Fusarium graminearum, F. avenacerum, F. culmorum, Microdochium nivale), rust (Puccinia striiformis, P. graminis, P. hordei), loose smut (Ustilago nuda), scald (Rhynchosporium secalis), net blotch (Pyrenophora teres), spot blotch (Cochliobolus sativus), leaf stripe (Pyrenophora graminea), and Rhizoctonia damping-off (Rhizoctonia solani).
Diseases in corn: smut (Ustilago maydis), brown spot (Cochliobolus heterostrophus), copper spot (Gloeocercospora sorghi), southern rust (Puccinia polysora), gray leaf spot (Cercospora zeae-maydis), white spot (Phaeosphaeria mydis and/or Pantoea ananatis) and Rhizoctonia damping-off (Rhizoctonia solani).
Diseases of citrus: melanose (Diaporthe citri), scab (Elsinoe fawcetti), penicillium rot (Penicillium digitatum, P. italicum), and brown rot (Phytophthora parasitica, Phytophthora citrophthora).
Diseases of apple: blossom blight (Monilinia mali), canker (Valsa ceratosperma), powdery mildew (Podosphaera leucotricha), Alternaria leaf spot (Alternaria alternata apple pathotype), scab (Venturia inaequalis), powdery mildew, bitter rot (Colletotrichum acutatum), crown rot (Phytophtora cactorum), blotch (Diplocarpon mali), and ring rot (Botryosphaeria berengeriana).
Diseases of pear: scab (Venturia nashicola, V. pirina), powdery mildew, black spot (Alternaria alternata Japanese pear pathotype), rust (Gymnosporangium haraeanum), and phytophthora fruit rot (Phytophtora cactorum).
Diseases of peach: brown rot (Monilinia fructicola), powdery mildew, scab (Cladosporium carpophilum), and phomopsis rot (Phomopsis sp.).
Diseases of grape: anthracnose (Elsinoe ampelina), ripe rot (Glomerella cingulata), powdery mildew (Uncinula necator), rust (Phakopsora ampelopsidis), black rot (Guignardia bidwellii), botrytis, and downy mildew (Plasmopara viticola).
Diseases of Japanese persimmon: anthracnose (Gloeosporium kaki), and leaf spot (Cercospora kaki, Mycosphaerella nawae).
Diseases of gourd: anthracnose (Colletotrichum lagenarium), powdery mildew (Sphaerotheca fuliginea), gummy stem blight (Mycosphaerella melonis), Fusarium wilt (Fusarium oxysporum), downy mildew (Pseudoperonospora cubensis), Phytophthora rot (Phytophthora sp.) , and damping-off (Pythium sp . ).
Diseases of tomato: early blight (Alternaria solani), leaf mold (Cladosporium fulvum), and late blight (Phytophthora infestans).
Diseases of eggplant: brown spot (Phomopsis vexans), and powdery mildew (Erysiphe cichoracearum) Diseases of cruciferous vegetables: Alternaria leaf spot (Alternaria japonica), white spot (Cercosporella brassicae), clubroot (Plasmodiophora brassicae), and downy mildew (Peronospora parasitica).
Diseases of onion: rust (Puccinia allii), and downy mildew (Peronospora destructor).
Diseases of soybean: purple seed stain (Cercospora kikuchii), sphaceloma scad (Elsinoe glycines), pod and stem blight (Diaporthe phaseolorum var. sojae), septoria brown spot (Septoria glycines), frogeye leaf spot (Cercospora sojina), rust (Phakopsora pachyrhizi), Yellow rust, brown stem rot (Phytophthora sojae), and Rhizoctonia damping-off (Rhizoctonia solani).
Diseases of kidney bean: anthracnose (Colletotrichum lindemthianum). Diseases of peanut: leaf spot (Cercospora personata), brown leaf spot (Cercospora arachidicola) and southern blight (Sclerotium rolfsii).
Diseases of garden pea: powdery mildew (Erysiphe pisi), and root rot (Fusarium solani f. sp. pisi).
Diseases of potato: early blight (Alternaria solani), late blight (Phytophthora infestans), pink rot (Phytophthora erythroseptica), and powdery scab (Spongospora subterranean f. sp. subterranea).
Diseases of strawberry: powdery mildew (Sphaerotheca humuli), and anthracnose (Glomerella cingulata).
Diseases of tea: net blister blight (Exobasidium reticulatum), white scab (Elsinoe leucospila), gray blight (Pestalotiopsis sp.), and anthracnose (Colletotrichum theae-sinensis).
Diseases of tobacco: brown spot (Alternaria longipes), powdery mildew (Erysiphe cichoracearum), anthracnose (Colletotrichum tabacum), downy mildew (Peronospora tabacina) , and black shank (Phytophthora nicotianae).
Diseases of rapeseed: sclerotinia rot (Sclerotinia sclerotiorum), and Rhizoctonia damping-off (Rhizoctonia solani). Diseases of cotton: Rhizoctonia damping-off (Rhizoctonia solani).
Diseases of sugar beat: Cercospora leaf spot (Cercospora beticola), leaf blight (Thanatephorus cucumeris), Root rot (Thanatephorus cucumeris), and Aphanomyces root rot (Aphanomyces cochlioides).
Diseases of rose: black spot (Diplocarpon rosae), powdery mildew (Sphaerotheca pannosa), and downy mildew (Peronospora sparsa). Diseases of chrysanthemum and asteraceous plants: downy mildew (Bremia lactucae), leaf blight (Septoria chrysanthemi-indici), and white rust (Puccinia horiana).
Diseases of various groups: diseases caused by Pythium spp. (Pythium aphanidermatum, Pythium debarianum, Pythium graminicola, Pythium irregulare, Pythium ultimum), gray mold. (Botrytis cinerea), and Sclerotinia rot (Sclerotinia sclerotiorum).
Disease of Japanese radish: Alternaria leaf spot (Alternaria brassicicola).
Diseases of turfgrass: dollar spot (Sclerotinia homeocarpa), and brown patch and large patch (Rhizoctonia solani).
Disease of banana: Black sigatoka (Mycosphaerella fijiensis), Yellow sigatoka (Mycosphaerella musicola).
Disease of sunflower: downy mildew (Plasmopara halstedii).
Seed diseases or diseases in the early stages of the growth of various plants caused by Aspergillus spp., Penicillium spp., Fusarium spp., Gibberella spp., Tricoderma spp., Thielaviopsis spp., Rhizopus spp., Mucor spp., Corticium spp., Phoma spp., Rhizoctonia spp. and Diplodia spp.
Viral diseases of various plants mediated by Polymixa spp. or Olpidium spp. and so on.
The term "health of a plant" or "plant health" is defined as a condition of the plant and/or its products. As a result of the improved health, yield, plant vigor, quality and tolerance to abiotic or biotic stress are increased. Noteworthy, the health of a plant when applying the method according to the invention, is increased independently of the pesticidal properties of the active ingredients used because the increase in health is not based upon the reduced disease pressure but instead on complex physiological and metabolic reactions which result for example in an activation of the plant's own natural defense system. As a result, the health of a plant is increased even in the absence of diseases pressure. Accordingly, in an especially preferred embodiment of the method according to the invention, the health of a plant is increased both in the presence and absence of biotic or abiotic stress factors. The above identified indicators for the health condition of a plant may be interdependent or they may result from each other. An increase in plant vigor may for example result in an increased yield and/or tolerance to abiotic or biotic stress. One indicator for the condition of the plant is the yield. "Yield" is to be understood as any plant product of economic value that is produced by the plant such as grains, fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants) or even flowers (e.g. in the case of gardening plants, ornamentals). The plant products may in addition be further utilized and/or processed after harvesting.
In an especially preferred embodiment of the invention, the yield of the treated plant is increased.
In another preferred embodiment of the invention, the yield of the plants treated according to the method of the invention, is increased synergistically.
According to the present invention, "increased yield" of a plant, in particular of an agricultural, silvicultural and/or horticultural plant means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the mixture according to the invention.
Increased yield can be characterized, among others, by the following improved proper-ties of the plant: increased plant, weight, increased plant height, increased biomass such as higher overall fresh weight (FW), increased number of flowers per plant, higher grain yield, more tillers or side shoots (branches), larger leaves, increased shoot growth, increased protein content, increased oil content, increased starch content, increased pigment content, increased leaf are index.
According to the present invention, the yield is increased by at least 5 %, preferable by 5 to 10 %, more preferable by 10 to 20 %, or even 20 to 30 % compared to the untreated control plants or plants treated with pesticides in a way different from the method according to the present invention. In general, the yield increase may even be higher.
A further indicator for the condition of the plant is the plant vigor. The plant vigor becomes manifest in several aspects such as the general visual appearance. In another especially preferred embodiment of the invention, the plant vigor of the treated plant is increased. In another preferred embodiment of the invention, the plant vigor of the plants treated according to the method of the invention, is increased synergistically. Improved plant vigor can be characterized, among others, by the following improved properties of the plant: improved vitality of the plant, improved plant growth, improved plant development, improved visual appearance, improved plant stand (less plant verse/lodging), improved emergence, enhanced root growth and/or more developed root system, enhanced nodulation, in particular rhizobium nodulation, bigger leaf blade, bigger size, increased plant weight, increased plant height, increased tiller number, increased number of side shoots, increased number of flowers per plant, increased shoot growth, increased root growth (extensive root system), increased yield when grown on poor soils or unfavorable climate, enhanced photosynthetic activity (e.g. based on increased stomatal conductance and/or increased C02 assimilation rate), increased stomatal conductance, increased C02 assimilation rate, enhanced pigment content (e.g. chlorophyll content), earlier flowering, earlier fruiting, earlier and improved germination, earlier grain maturity, improved self-defense mechanisms, improved stress tolerance and resistance of the plants against biotic and abiotic stress factors such as fungi, bacteria, viruses, heat stress, cold stress, drought stress, UV stress and/or salt stress, less non-productive tillers, less dead basal leaves, less input needed (such as fertilizers or water), greener leaves, complete maturation under shortened vegetation periods, less fertilizers needed, less seeds needed, easier harvesting, faster and more uniform ripening, longer shelf-life, longer panicles, delay of senescence, stronger and/or more productive tillers, better extractability of ingredients, improved quality of seeds (for being seeded in the following seasons for seed production), better nitrogen uptake, improved reproduction, reduced production of ethylene and/or the inhibition of its reception by the plant.
The improvement of the plant vigor according to the present invention particularly means that the improvement of any one or several or all of the above mentioned plant characteristics are improved independently of the pesticidal action of the mixture or active ingredients (components).
Another indicator for the condition of the plant is the "quality" of a plant and/or its products.
In an especially preferred embodiment of the invention, the quality of the treated plant is increased.
In another preferred embodiment of the invention, the quality of the plants treated according to the method of the invention, is increased synergistically.
According to the present invention, enhanced quality means that certain plant characteristics such as the content or composition of certain ingredients are increased or improved by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the mixtures of the present invention. Enhanced quality can be characterized, among others, by following improved properties of the plant or its product: increased nutrient content, increased protein content, increased content of fatty acids, increased metabolite content, increased carotenoid content, increased sugar content, increased amount of essential amino acids, improved nutrient composition, improved protein composition, improved composition of fatty acids, improved metabolite composition, improved carotenoid composition, improved sugar composition, improved amino acids composition, improved or optimal fruit color, improved leaf color, higher storage capacity, higher processability of the harvested products.
Another indicator for the condition of the plant is the plant's tolerance or resistance to biotic and/or abiotic stress factors. Biotic and abiotic stress, especially over longer terms, can have harmful effects on plants. Biotic stress is caused by living organisms while abiotic stress is caused for example by environmental extremes. According to the present invention, "enhanced tolerance or resistance to biotic and/or abiotic stress factors" means (1.) that certain negative factors caused by biotic and/or abiotic stress are diminished in a measurable or noticeable amount as compared to plants exposed to the same conditions, but without being treated with a mixture according to the invention and (2.) that the negative effects are not diminished by a direct action of the mixture according to the invention on the stress factors, e.g. by its fungicidal action which directly destroys the microorganisms or diseases, but rather by a stimulation of the plants' own defensive reactions against said stress factors.
Formulation of the present invention can be in any of the formulations selected from Capsule suspension (CS), Dispersible concentrate (DC), Powder for dry seed treatment (DS), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion for seed treatment (ES), Emulsion, oil in water (EW), Flowable suspension/concentrate for seed treatment (FS), Granule/ soil applied (GR), Controlled (Slow or Fast) release granules (CR), Solution for seed treatment (LS), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (= flowable concentrate) (SC), Suspo-emulsion (SE), Water soluble granule (SG), Soluble concentrate (SL), Water soluble powder (SP), Water dispersible granule (WG or WDG), Wettable powder (WP), Water dispersible powder for slurry treatment (WS), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW).
One or more of the active ingredients is encapsulated for various purposes, such as to increase the residual biological activity, or to reduce the acute toxicity, or to obtain a physical or chemically stable water-based formulation. The purpose determines whether the “free” active ingredient and the “release rate” are relevant properties of a specific product.
Further composition comprising bioactive amounts of (A) a fungicide selected from class of SDHI (Succinate dehydrogenase inhibitors); (B) an insecticide selected from the class of neonicotinoids, chordotonal organs modulators, diamides, metadiamides, isoxazolines, insecticides with unknow mode of action or unclassified are present in the said composition in specific fixed ratio.
In further aspect the present invention relates to the synergistic pesticidal composition comprising bioactive amounts of (A) is 0.1 to 80% w/w of the composition; and (B) is 0.1 to 80% w/w of the composition
Active Ingredients Compound A Compound
B
Examples SDHI
(Succinate dehydrogenase inhibitors) Fungicide Insecticide
from class of nicotinic, chordotonal organ modulator, diamides, metadiamides, isoxazolines or unclassified group or mixture thereof
% of Active Ingredient
0.1 to 80%
0.1 to 80%

The composition of the present invention in addition to bioactive amounts of active ingredients further comprises inactive excipients including but not limited to dispersant or dispersing agent, anti-freezing agent, anti-foam agent, wetting agent, suspension aid, thickener, stabilizing agent, suspending agent, emulsifying agent and preservative.
A wetting agent is a substance that when added to a liquid increases the spreading or penetration power of the liquid by reducing the interfacial tension between the liquid and the surface on which it is spreading. Wetting agents are used for two main functions in agrochemical formulations: during processing and manufacture to increase the rate of wetting of powders in water to make concentrates for soluble liquids or suspension concentrates; and during mixing of a product with water in a spray tank or other vessel to reduce the wetting time of wettable powders and to improve the penetration of water into water-dispersible granules.
Examples of wetting agent used herein for SC (Suspension concentrate) formulation include but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate, Organosilicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof.
Examples of wetting agent used herein for Oil Dispersion (OD) includes but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyldiphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkylnaphthalene sulfonate.
More particularly wetting spreading and penetrating agent for the present agrochemical composition and Suspension Concentrate (SC) and Oil Dispersion (OD) formulation thereof is organosilicone surfactants Trisiloxane Ethoxylate.
Trisiloxane ethoxylate is a Non-ionic surfactant that improves the spray coverage and promotes spray volume reduction. In the present invention it acts as a Wetting spreading and penetrating agent for the formulation comprising present agrochemical composition. Trisiloxane Ethoxylate wetting agent/spray adjuvant is a fast spreading surfactant/ wetting agent. It lowers the surface tension of spray solutions, beyond that which is achievable with conventional adjuvants. Trisiloxane ethoxylate promotes rapid uptake of agrochemicals (rainfastness). Trisiloxane ethoxylate surfactants lower the surface tension of the water, allowing the rapid coverage and penetration of cuticular waxes on hydrophobic leaf surfaces and causes an effect known as stomatal flooding; the almost instantaneous entrance of the solution into the openings in the plant surfaces. This fast penetration results in “rainfastness” as the delivery of the pesticide into the plant has occurred and further rainfall cannot remove the residue.

Trisiloxane ethoxylate is also acts as a Superspreader for soluble liquid and emulsifiable concentrate formulations. “Superspreading”, or “superwetting”, is the process by which a small droplet of an aqueous diluted solution of certain Trisiloxane Ethoxylate spreads on a moderately hydrophobic surface to a very large area, usually in a short time period (~ tens of seconds).
Further examples of wetting-spreading-penetrating agent used herein for SC (Suspension concentrate) formulation include but not limited to organosilicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof.
Further examples of wetting-spreading-penetrating agent used herein for Oil Dispersion (OD) includes but not limited to organosilicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof.
A dispersant or a dispersing agent is a substance which adsorbs onto the surface of particles and helps to preserve the state of dispersion of the particles and prevents them from re-aggregating. Dispersants are added to agrochemical formulations to facilitate dispersion and suspension during manufacture, and to ensure the particles re-disperse into water in a spray tank. They are widely used in wettable powders, suspension concentrates and water-dispersible granules. Surfactants that are used as dispersants have the ability to adsorb strongly onto a particle surface and provide a charged or steric barrier to re-aggregation of particles. The most commonly used surfactants are anionic, non-ionic, or mixtures of the two types. For wettable powder formulations, the most common dispersants are sodium lingo sulphonates. In recent years, new types of very high molecular weight polymeric surfactants have been developed as dispersants. These have very long hydrophobic ‘backbones’ and a large number of ethylene oxide chains forming the ‘teeth’ of a ‘comb’ surfactant. These high molecular weight polymers can give very good long-term stability to suspension concentrates because the hydrophobic backbones have many anchoring points onto the particle surfaces.
Examples of dispersants or dispersing agent used herein for SC (Suspension concentrate) formulation include but not limited to alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Examples of dispersants or dispersing agent used herein for Oil Dispersion (OD) formulation include but not limited to alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Antifoaming agent for the present formulation is selected from various compounds and selectively used according to the formulation. Generally, there are two types of antifoam agents, namely silicones and non-silicones. Silicones are usually aqueous emulsions of dimethyl poly siloxane while the non-silicone anti-foam agents are water- insoluble oils, such as octanol and nonanol, or silica. In both cases, the function of the anti-foam agent is to displace the surfactant from the air-water interface.
Examples of Antifoaming agent used herein for SC (Suspension concentrate) formulation include but not limited to silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethylsiloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane.
Examples of Antifoaming agent used herein for Oil Dispersion (OD) formulation include but not limited to silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethylsiloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane.
Anti-freezing agent for the present formulation is selected from various compounds and selectively used according to the formulation.
Examples of Anti-freezing agent used herein for SC (Suspension concentrate) formulation include but not limited to ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.
Examples of Anti-freezing agent used herein for Oil Dispersion (OD) formulation include but not limited to ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.
Preservative used herein for the SC (Suspension concentrate) formulation include but not limited to 1,2-benzisothiazolin-3(2H)-one, sodium salt, Sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, Formaldehyde, Sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one.
Preservative used herein for Oil Dispersion (OD) formulation include but not limited to 1,2-benzisothiazolin-3(2H)-one, sodium salt, sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, formaldehyde, sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one.
Thickeners or gelling agents are used mainly in the formulation of suspension concentrates, emulsions and suspoemulsions to modify the rheology or flow properties of the liquid and to prevent separation and settling of the dispersed particles or droplets. Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers.
Examples of thickeners used herein for SC (Suspension concentrate) formulation include but not limited to xanthan gum, PVK, carboxymethylcelluloses, polyvinyl alcohols,gelatin, sodium carboxymethylcellulose, hydroxyethylcellulose, sodium polyacrylate, modified starch;
Suspension aid or the suspending agent in the present description denotes a natural or synthetic, organic or inorganic material with which the active substance is combined in order to facilitate its application to the plant, to the seeds or to the soil. This carrier is hence generally inert, and it must be agriculturally acceptable, in particular to the plant being treated. The carrier may be solid (clays, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, and the like or mixtures thereof) or liquid (water, alcohols, ketones, petroleum fractions, aromatic or paraffinic hydrocarbons, chlorinated hydrocarbons, liquefied gases, and the like or mixtures thereof).
Examples of suspending agent used herein for SC (Suspension concentrate) formulation include but not limited to Aluminum Magnesium Silicate, Bentonite clay, Silica, Attapulgite clay.
Examples of Emulsifying agent used herein for Oil Dispersion (OD) formulation includes but not limited to castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkylammonium salts of alkyl benzene sulphonate, alkyl sulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylene sorbitan monolaurate.
Examples of stabilizer used herein for Oil Dispersion (OD) formulation includes but not limited to hectorite clay, aluminium magnesium silicate, bentonite clay, silica, attapulgite clay.
Carrier for the present formulation is selected from selected from various compounds and selectively used according to the formulation. Certain vegetables/plant/seed oils as a carrier, increases the bioefficacy and residual control of products through increase in penetration of active ingredients into leaf surface, improves the retention of active ingredietns on leaf surface especially on waxy leaf surface, improves the spreading properties and thereby improves the spray coverage.
More particularly Carrier for the present Oil Dispersion (OD) formulation is blend of methylated seed oil, polyalkyleneoxide modified polydimethylsiloxane and alkylphenol ethoxylate.
Methylated seed oil (MSO) is a kind of fatty acid from seed oil esterified with methyl alcohol. For oil-based adjuvant, droplet spread on leaf surfaces and herbicide penetration seem to be the two predominant factors regarding the mechanism of the enhancement in pesticide efficacy. MSO decrease the surface tension and contact angle and then increase the wetted areas of droplets on both waxy and hairy leaves. Further MSO enhances the efficacy by increasing the absorption of the pesticide. Methylated seed oils (MSO) are better solvents than petroleum-based oils. They have good spreading and penetration properties. Polyalkyleneoxide modified polydimethyl siloxane (PDMS) is a surfactant and is a component of defoamers. PDMS, in a modified form, is used as a penetrant and is a critical ingredient in water-repelling coatings. A biochemical penetrant is a chemical that increases the ability of a poison to apply its toxic effect to a living organism. PDMS with its inherent chemical properties it acts as Surfactant, Emulsifier, Dispersant, Flow Control Agent, and Lubricant in formulation preparation. Alkylphenol ethoxylates are nonionic surfactants, consisting of branched-chain alkylphenols, which react with ethylene oxide, producing an ethoxylate chain. Alkylphenol ethoxylates is having inherent emulsifying activity and acts as an excellent carrier when blended with other formulation adjuvants.
Further examples of Carrier or diluting agent used herein for Oil Dispersion (OD) formulation includes but not limited to as solvent for the present formulation is selected from and not limited to vegetable oil (plant, seed or tree) or its alkylated. The alkylated vegetable oil may be methylated vegetable oil or ethylated vegetable oil. The vegetable oils include olive oil, kapok oil, castor oil, papaya oil, camellia oil, sesame oil, corn oil, rice bran oil, cotton seed oil, soybean oil, groundnut oil, rapeseed-mustard oil, linseed oil, tung oil, sunflower oil, safflower oil, coconut oil. The alkyl ester of vegetable oils includes methyl ester, ethyl ester, propyl ester or butyl ester of vegetable oils. Some of the examples are rapeseed oil methyl ester, rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, soybean oil methyl ester, soybean oil ethyl ester, soybean oil propyl ester, soybean oil butyl ester, castor oil methyl ester, castor oil ethyl ester, castor oil propyl ester, castor oil butyl ester, cotton seed oil methyl ester, cotton seed oil ethyl ester, cotton seed oil butyl ester, cotton seed oil propyl ester, tall oil fatty acids esters-tallow methyl ester, tallow ethyl ester, tallow propyl ester, diesel, mineral oil, fatty acid amides (e.g. C1 -C3 amines, alkylamines or alkanolamines with C6–C18 carboxylic acids), fatty acids, alkyl esters of fatty acids, methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols. The above oil based carrier/diluting agents may be used as solo or mixture of two or more if desired.
The process for preparing the present novel synergistic composition can be modified accordingly by any person skilled in the art based on the knowledge of the manufacturing the formulation. However all such variation and modification is still covered by the scope of present invention.
Following the right use of the invented technology and the synergistic fungicidal composition of the invention with a formulations having a multi-pesticide components i.e. pesticide mixture, formulation prepared with an extra care of physical compatibility by purposefully specially selected solvents, dispersing agents, carriers and the surfactants, thickeners, stabilizers etc. exhibits better fungal and pest management and boost plant health.
While the foregoing written description of the invention enables one of ordinary skill to make and use what is considered presently to be the best mode thereof, those of ordinary skill will understand and appreciate the existence of variations, combinations, and equivalents of the specific embodiment, method, and examples herein. The invention should therefore not be limited by the above described embodiment, method, and examples, but by all embodiments and methods within the scope and spirit of the invention. The invention shall now be described with reference to the following specific examples. It should be noted that the example(s) appended below illustrate rather than limit the invention, and that those skilled in the art will be able to design many alternative embodiments without departing from the scope of the present invention.
These and other aspects of the invention may become more apparent from the examples set forth herein below. These examples are provided merely as illustrations of the invention and are not intended to be construed as a limitation thereof.

EXAMPLE 1:
SC (Suspension Concentrate) formulation of Thifluzamide 12%+Flupyrimin 12%
Chemical composition % (w/w)
Thifluzamide Active ingredient 12.00
Flupyrimin Active ingredient 12.00
Trisiloxane ethoxylate Wetting-spreading-penetrating agent 5.00
Naphthalenesulfonic acid, sodium salt condensated with formaldehyde Dispersing agent 1 2.00
Tristyrylphenole with 16 moles EO Dispersing agent 2 3.00
Bentonite clay Suspending agent 1.50
Polydimethyl siloxane Antifoaming agent 0.50
2-bromo-2-nitropropane-1,3-diol Preservative 0.20
Polypropylene glycol Antifreezing agent 5.00
Xanthan gum Thickner 0.15
Diluent Water Water 58.65
Total 100.00

Storage stability-
Thifluzamide 12%+Flupyrimin 12% SC (Suspension Concentrate)
Laboratory storage stability
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Thifluzamide content percent by mass 11.40 to 12.60 12.50 12.30 12.40
Flupyrimin content percent by mass 11.40 to 12.60 12.50 12.30 12.40
Thifluzamide suspensibility percent min. 80 98.50 98.00 98.20
Flupyrimin suspesnibility precent min. 80 98.40 97.80 98.10
pH range (1% aq. Suspension) 4.0 to 6.5 5.80 5.60 5.70
Pourability 95% min. 97.80 97.20 97.60
Specific gravity 1.02-1.08 1.02 1.02 1.02
Viscosity at spindle no. 62, 20 rpm 350-800 cps 660 670 660
Particle size (micron) D50<3, D90<10 2.0,8.0 2.3,8.3 2.2,8.2
Persistent foam ml (after 1 minute) max. 60 nil 2 nil
Room temperature storage stability up to 12 months
Parameters Specification (in house) 1 month 6 month 12 month
Thifluzamide content percent by mass 11.40 to 12.60 12.50 12.30 12.20
Flupyrimin content percent by mass 11.40 to 12.60 12.50 12.30 12.20
Thifluzamide suspensibility percent min. 80 98.50 98.00 97.60
Flupyrimin suspesnibility precent min. 80 98.40 98.20 97.80
pH range (1% aq. Suspension) 4.0 to 6.5 5.80 5.70 5.60
Pourability 95% min. 97.80 97.50 97.00
Specific gravity 1.02-1.08 1.02 1.02 1.02
Viscosity at spindle no. 62, 20 rpm 350-800 cps 660 670 700
Particle size (micron) D50<3, D90<10 2.0,8.0 2.3,8.3 2.5,8.8
Persistent foam ml (after 1 minute) max. 60 nil 2 nil

Procedure: Manufacturing process of Suspension Concentrate (SC)
Preparation of Suspension Concentrate (SC) formulation:
Step 1 2% Gel Preparation: Charge the required quantity of water to a vessel, equipped with a high shear stirrer and start the agitation. Add the required amount of preservative. Mix until homogenous. Add the required amount of thickener and mix vigorously until it is fully wetted.
Step 2 Charge the required quantity of water to a vessel, equipped with bulk agitator and a high shear homogenizer and start agitation. Add the required amount of ant freezing agent and mix until uniform. Add the antifoaming agent and ensure that it is well dispersed. Add the wetting and dispersing agent and mix until uniform. Ensure that the dispersing agent is fully dispersed.
Step 3 Now add the active ingredient and continue agitating the vessel contents until all components get dissolved. Mill this pre-mix through a Colloid mill and subsequently through a Dyno mill to meet the specified particle size.
Step 4 Now add remaining antifoaming agent to this SC mill base to a vessel, equipped with bulk agitator. Mix until uniform. Add the required amount of 2% aqueous pre-gel and suspending agent and continue agitation until the formulation is homogeneous and has the target viscosity is reached.
Step 5 Final product is sent for QC approval.
Step 6 After approval, material is packed in required pack sizes.

EXAMPLE 2:
OD (Oil Dispersion) formulation of Fluxapyroxad 15%+Broflanilide 2%
Chemical composition % (w/w)
Fluxapyroxad Active ingredient 15.00
Broflanilide Active ingredient 2.00
Trisiloxane ethoxylate Wetting-spreading-penetrating agent 5.00
Tristyrylphenol-polyglycolether-phosphate Dispersing agent 5.00
Calcium salts of dodecylbenzene sulphonate Emulsifying agent 8.00
Bentonite clay Stabilizer 2.00
Polydimethyl siloxane Antifoaming agent 0.50
2-bromo-2-nitropropane-1,3-diol Preservative 0.10
Polypropylene glycol Antifreezing agent 5.00
Methylated seed oil, polyalkyleneoxide modified polydimethylsiloxane alkylphenol ethoxylate Carrier as solvent 57.40
Total 100.00

Storage stability- Fluxapyroxad 15%+Broflanilide 2% OD (Oil Dispersion) formulation
Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Fluxapyroxad content percent by mass 14.25 to 15.75 15.50 15.30 15.40
Broflanilide content percent by mass 1.90 to 2.20 2.15 2.10 2.12
Fluxapyroxad suspensibility percent min. 80 98.20 97.00 97.60
Broflanilide suspensibility percent min. 80 98.00 97.20 97.80
pH range (1% aq. Suspension) 5.5 to 8.5 6.60 6.50 6.60
Pourability 95% min. 97.50 97.20 97.30
Specific gravity 1.02-1.08 1.02 1.02 1.02
Viscosity at spindle no. 62, 20 rpm 350-800 cps 660 650 660
Particle size (micron) D50<3, D90<10 2.2,8.5 2.4,8.8 2.3,8.7
Persistent foam ml (after 1 minute) max. 60 nil 2 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Fluxapyroxad content percent by mass 14.25 to 15.75 15.50 15.40 15.20
Broflanilide content percent by mass 1.90 to 2.20 2.15 2.12 2.05
Fluxapyroxad suspensibility percent min. 80 98.20 97.80 97.00
Broflanilide suspensibility percent min. 80 98.00 97.50 97.20
pH range (1% aq. Suspension) 5.5 to 8.5 6.60 6.50 6.40
Pourability 95% min. 97.50 97.20 96.60
Specific gravity 1.02-1.08 1.02 1.02 1.02
Viscosity at spindle no. 62, 20 rpm 350-800 cps 660 650 640
Particle size (micron) D50<3, D90<10 2.2,8.5 2.4,8.7 2.6,8.9
Persistent foam ml (after 1 minute) max. 60 nil 2 nil

Procedure: Manufacturing process of Oil dispersion (OD) formulation:

Preparation of Oil dispersion (OD) formulation:
Part A Preparation of the liquid premix
Step 1 Charge Vegetable oil or solvent or both into a vessel with anchor stirrer.
Step 2 Under stirring, add the emulsifier and dispersing agent and stir until all ingredients are dissolved completely.
Part B Preparation of the slurry
Step 1 Now, charge the liquid premix into a second vessel, equipped with a cooling and heating device and a high shear stirrer.
Step 2 Add the active ingredient and homogenize thoroughly. Pre-mill this mixture and finally mill it using a bead mill to achieve a particle size distribution as required by the specification.
Part C Preparation of the Thickener gel
Step 1 Charge the vegetable/plant/seed oil or solvent to the vessel, equipped with a high shear stirrer.
Step 2 Add gradually the thickener which is organophilic clay, maintaining high-shear mixing throughout. Stirring is continued until thoroughly mixed.
Step 3 Under stirring, the thickener activating agent propylene carbonate is added. Allow the gel to swell whilst maintaining mixing.
Part D Preparation of the final formulation
Step 1 Now add the thickener gel or silica and disperse the mixture by using a high shear stirrer.
Step 2 Finally add the recommended wetting and spreading agent or adjuvants (silicone or non-silicone based) to this formulation and disperse by using high shear stirrer.
Step 3 Check the finished formulation to specification.
Step 4 After approval, material is packed in required pack sizes.

EXAMPLE 5:
Lists of preferred formulations:

Compound A Compound B Active ingredients (%) Formulation Strength (%) Formulation Type
Compound A Compound B
Thifluzamide Flupyrimin 12 12 24.00 SC
Thifluzamide Triflumezopyrim 12 3.33 15.33 SC
Thifluzamide Benzpyrimoxan 12 10 22.00 SC
Thifluzamide Tetraniliprole 18 10 28.00 SC
Thifluzamide Cyclaniliprole 18 10 28.00 SC
Thifluzamide Cyhalodiamide 18 10 28.00 SC
Thifluzamide Cyproflanilide 18 10 28.00 SC
Thifluzamide Dichloromezotiaz 18 10 28.00 SC
Thifluzamide Tyclopyrazoflor 18 10 28.00 SC
Thifluzamide Broflanilide 18 2 20.00 SC
Thifluzamide Fluxametamide 18 3 21.00 SC
Thifluzamide Isocycloseram 18 10 28.00 SC
Thifluzamide Oxazosulfyl 18 10 28.00 SC
Thifluzamide Dimpropyridaz 18 10 28.00 SC
Thifluzamide Pyrifluquinazon 18 10 28.00 SC
Thifluzamide Afidopyropen 18 10 28.00 SC
Thifluzamide Flupyrimin 12 12 24.00 OD
Thifluzamide Triflumezopyrim 12 3.33 15.33 OD
Thifluzamide Benzpyrimoxan 12 10 22.00 OD
Thifluzamide Tetraniliprole 18 10 28.00 OD
Thifluzamide Cyclaniliprole 18 10 28.00 OD
Thifluzamide Cyhalodiamide 18 10 28.00 OD
Thifluzamide Cyproflanilide 18 10 28.00 OD
Thifluzamide Dichloromezotiaz 18 10 28.00 OD
Thifluzamide Tyclopyrazoflor 18 10 28.00 OD
Thifluzamide Broflanilide 18 2 20.00 OD
Thifluzamide Fluxametamide 18 3 21.00 OD
Thifluzamide Isocycloseram 18 10 28.00 OD
Thifluzamide Oxazosulfyl 18 10 28.00 OD
Thifluzamide Dimpropyridaz 18 10 28.00 OD
Thifluzamide Pyrifluquinazon 18 10 28.00 OD
Thifluzamide Afidopyropen 18 10 28.00 OD
Fluxapyroxad Flupyrimin 10 12 22.00 SC
Fluxapyroxad Triflumezopyrim 10 3.33 13.33 SC
Fluxapyroxad Benzpyrimoxan 10 10 20.00 SC
Fluxapyroxad Tetraniliprole 15 10 25.00 SC
Fluxapyroxad Cyclaniliprole 15 10 25.00 SC
Fluxapyroxad Cyhalodiamide 15 10 25.00 SC
Fluxapyroxad Cyproflanilide 15 10 25.00 SC
Fluxapyroxad Dichloromezotiaz 15 10 25.00 SC
Fluxapyroxad Tyclopyrazoflor 15 10 25.00 SC
Fluxapyroxad Broflanilide 15 2 17.00 SC
Fluxapyroxad Fluxametamide 15 3 18.00 SC
Fluxapyroxad Isocycloseram 15 10 25.00 SC
Fluxapyroxad Oxazosulfyl 15 10 25.00 SC
Fluxapyroxad Dimpropyridaz 15 10 25.00 SC
Fluxapyroxad Pyrifluquinazon 15 10 25.00 SC
Fluxapyroxad Afidopyropen 15 10 25.00 SC
Fluxapyroxad Flupyrimin 10 12 22.00 OD
Fluxapyroxad Triflumezopyrim 10 3.33 13.33 OD
Fluxapyroxad Benzpyrimoxan 10 10 20.00 OD
Fluxapyroxad Tetraniliprole 15 10 25.00 OD
Fluxapyroxad Cyclaniliprole 15 10 25.00 OD
Fluxapyroxad Cyhalodiamide 15 10 25.00 OD
Fluxapyroxad Cyproflanilide 15 10 25.00 OD
Fluxapyroxad Dichloromezotiaz 15 10 25.00 OD
Fluxapyroxad Tyclopyrazoflor 15 10 25.00 OD
Fluxapyroxad Broflanilide 15 2 17.00 OD
Fluxapyroxad Fluxametamide 15 3 18.00 OD
Fluxapyroxad Isocycloseram 15 10 25.00 OD
Fluxapyroxad Oxazosulfyl 15 10 25.00 OD
Fluxapyroxad Dimpropyridaz 15 10 25.00 OD
Fluxapyroxad Pyrifluquinazon 15 10 25.00 OD
Fluxapyroxad Afidopyropen 15 10 25.00 OD
Benzovindiflupyr Dichloromezotiaz 20 6 26.00 OD
Benzovindiflupyr Cyclaniliprole 20 10 30.00 OD
Benzovindiflupyr Cyhalodiamide 20 10 30.00 OD
Benzovindiflupyr Tetraniliprole 20 10 30.00 OD
Benzovindiflupyr Tyclopyrazoflor 20 5 25.00 OD
Benzovindiflupyr Broflanilide 20 2.5 22.50 OD
Benzovindiflupyr Fluxametamide 20 5 25.00 OD
Benzovindiflupyr Isocyclaseram 20 5 25.00 OD
Benzovindiflupyr Benzpyrimoxan 20 12.5 32.50 OD
Benzovindiflupyr Oxazosulfyl 20 10 30.00 OD
Benzovindiflupyr Dimpropyridaz 20 10 30.00 OD
Bixafen Dichloromezotiaz 15 6 21.00 OD
Bixafen Cyclaniliprole 15 10 25.00 OD
Bixafen Cyhalodiamide 15 10 25.00 OD
Bixafen Tetraniliprole 15 10 25.00 OD
Bixafen Tyclopyrazoflor 15 5 20.00 OD
Bixafen Broflanilide 15 2.5 17.50 OD
Bixafen Fluxametamide 15 5 20.00 OD
Bixafen Isocyclaseram 15 5 20.00 OD
Bixafen Benzpyrimoxan 15 12.5 27.50 OD
Bixafen Oxazosulfyl 15 10 25.00 OD
Bixafen Dimpropyridaz 15 10 25.00 OD
Fluindapyr Dichloromezotiaz 15 6 21.00 OD
Fluindapyr Cyclaniliprole 15 10 25.00 OD
Fluindapyr Cyhalodiamide 15 10 25.00 OD
Fluindapyr Tetraniliprole 15 10 25.00 OD
Fluindapyr Tyclopyrazoflor 15 5 20.00 OD
Fluindapyr Broflanilide 15 2.5 17.50 OD
Fluindapyr Fluxametamide 15 5 20.00 OD
Fluindapyr Isocyclaseram 15 5 20.00 OD
Fluindapyr Benzpyrimoxan 15 12.5 27.50 OD
Fluindapyr Oxazosulfyl 15 10 25.00 OD
Fluindapyr Dimpropyridaz 15 10 25.00 OD
Isopyrazam Dichloromezotiaz 20 6 26.00 OD
Isopyrazam Cyclaniliprole 20 10 30.00 OD
Isopyrazam Cyhalodiamide 20 10 30.00 OD
Isopyrazam Tetraniliprole 20 10 30.00 OD
Isopyrazam Tyclopyrazoflor 20 5 25.00 OD
Isopyrazam Broflanilide 20 2.5 22.50 OD
Isopyrazam Fluxametamide 20 5 25.00 OD
Isopyrazam Isocyclaseram 20 5 25.00 OD
Isopyrazam Benzpyrimoxan 20 12.5 32.50 OD
Isopyrazam Oxazosulfyl 20 10 30.00 OD
Isopyrazam Dimpropyridaz 20 10 30.00 OD
Penflufen Dichloromezotiaz 20 6 26.00 OD
Penflufen Cyclaniliprole 20 10 30.00 OD
Penflufen Cyhalodiamide 20 10 30.00 OD
Penflufen Tetraniliprole 20 10 30.00 OD
Penflufen Tyclopyrazoflor 20 5 25.00 OD
Penflufen Broflanilide 20 2.5 22.50 OD
Penflufen Fluxametamide 20 5 25.00 OD
Penflufen Isocyclaseram 20 5 25.00 OD
Penflufen Benzpyrimoxan 20 12.5 32.50 OD
Penflufen Oxazosulfyl 20 10 30.00 OD
Penflufen Dimpropyridaz 20 10 30.00 OD
Penthiopyrad Dichloromezotiaz 15 6 21.00 OD
Penthiopyrad Cyclaniliprole 15 10 25.00 OD
Penthiopyrad Cyhalodiamide 15 10 25.00 OD
Penthiopyrad Tetraniliprole 15 10 25.00 OD
Penthiopyrad Tyclopyrazoflor 15 5 20.00 OD
Penthiopyrad Broflanilide 15 2.5 17.50 OD
Penthiopyrad Fluxametamide 15 5 20.00 OD
Penthiopyrad Isocyclaseram 15 5 20.00 OD
Penthiopyrad Benzpyrimoxan 15 12.5 27.50 OD
Penthiopyrad Oxazosulfyl 15 10 25.00 OD
Penthiopyrad Dimpropyridaz 15 10 25.00 OD
Sedaxane Dichloromezotiaz 20 6 26.00 OD
Sedaxane Cyclaniliprole 20 10 30.00 OD
Sedaxane Cyhalodiamide 20 10 30.00 OD
Sedaxane Tetraniliprole 20 10 30.00 OD
Sedaxane Tyclopyrazoflor 20 5 25.00 OD
Sedaxane Broflanilide 20 2.5 22.50 OD
Sedaxane Fluxametamide 20 5 25.00 OD
Sedaxane Isocyclaseram 20 5 25.00 OD
Sedaxane Benzpyrimoxan 20 12.5 32.50 OD
Sedaxane Oxazosulfyl 20 10 30.00 OD
Sedaxane Dimpropyridaz 20 10 30.00 OD
Flubeneteram Dichloromezotiaz 15 6 21.00 OD
Flubeneteram Cyclaniliprole 15 10 25.00 OD
Flubeneteram Cyhalodiamide 15 10 25.00 OD
Flubeneteram Tetraniliprole 15 10 25.00 OD
Flubeneteram Tyclopyrazoflor 15 5 20.00 OD
Flubeneteram Broflanilide 15 2.5 17.50 OD
Flubeneteram Fluxametamide 15 5 20.00 OD
Flubeneteram Isocyclaseram 15 5 20.00 OD
Flubeneteram Benzpyrimoxan 15 12.5 27.50 OD
Flubeneteram Oxazosulfyl 15 10 25.00 OD
Flubeneteram Dimpropyridaz 15 10 25.00 OD
Pyrapropoyne Dichloromezotiaz 12.5 6 18.50 OD
Pyrapropoyne Cyclaniliprole 12.5 10 22.50 OD
Pyrapropoyne Cyhalodiamide 12.5 10 22.50 OD
Pyrapropoyne Tetraniliprole 12.5 10 22.50 OD
Pyrapropoyne Tyclopyrazoflor 12.5 5 17.50 OD
Pyrapropoyne Broflanilide 12.5 2.5 15.00 OD
Pyrapropoyne Fluxametamide 12.5 5 17.50 OD
Pyrapropoyne Isocyclaseram 12.5 5 17.50 OD
Pyrapropoyne Benzpyrimoxan 12.5 12.5 25.00 OD
Pyrapropoyne Oxazosulfyl 12.5 10 22.50 OD
Pyrapropoyne Dimpropyridaz 12.5 10 22.50 OD
Isoflucypyram Dichloromezotiaz 15 6 21.00 OD
Isoflucypyram Cyclaniliprole 15 10 25.00 OD
Isoflucypyram Cyhalodiamide 15 10 25.00 OD
Isoflucypyram Tetraniliprole 15 10 25.00 OD
Isoflucypyram Tyclopyrazoflor 15 5 20.00 OD
Isoflucypyram Broflanilide 15 2.5 17.50 OD
Isoflucypyram Fluxametamide 15 5 20.00 OD
Isoflucypyram Isocyclaseram 15 5 20.00 OD
Isoflucypyram Benzpyrimoxan 15 12.5 27.50 OD
Isoflucypyram Oxazosulfyl 15 10 25.00 OD
Isoflucypyram Dimpropyridaz 15 10 25.00 OD

Biological Examples:
A synergistic effect exists wherever the action of a combination of active ingredient is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticidal activity than the sum of the pesticidal activities of the individual components.
In the field of agriculture, it is often understood that the term “synergy” is as defined by Colby S.R. in an article entitled “ Calculation of the synergistic and antagonistic responses of herbicide combinations” published in the journal Weeds, 1967, 15, p.20-22, incorporated herein by reference in its entirety. The action expected for a given combination of two or three active components can be calculated as follows:

FIELD BIO-EFFICACY STUDIES:
Various formulations of SDHI fungicides (Thifluzamide, Fluxapyroxad) and insecticide has been developed in the laboratory and evaluated under the field condition for its efficacy and synergism.
Experiment 1-Cotrol of insect-pests and diseases in paddy (Oryza sativa) crop.
Crop & Variety : Paddy, BPT 5204
Location : Kurud, Chhattisgarh
Treatments : 8
Plot size : 50 sq.m.
Crop age : 60 days after transplanting.
Spray water volume : 400 liter per hectare
Method of Application: Foliar spray with battery operated knapsack sprayer fitted with hollow cone nozzle.
Agronomic Practices : Except insecticidal and fungicidal applications, all agronomic practices followed as per the crop requirement.
Observation Methods:
Brown Plant Hopper (BPH, Nilaparvata lugens) : The observation was recorded by counting the no. of live BPH per hill. Record the observations from 10 hills per plot at 5th day after application. The percent insect control was worked out by below formula:

Sheath blight (Rhizoctonia solani) control : Observations was recorded on disease severity in each treatment before and at 14 days after spray. The observations of severity of sheath blight disease were recorded using 0-9 grade (SES,IRRI 1996). Twenty randomly selected hills were scored as per scale. The percent disease index (PDI) of plants was calculated by the following formula.


Sheath blight disease Grading (0-9 scale) :
Grade Symptoms
0 No incidence
1 Less than 1% sheath area infected
3 1-5% sheath area infected
5 6-25% sheath area infected
7 26-50% sheath area infected
9 51-100% sheath area infected

Table 1: Control of brown plant hopper in paddy
Treatments (ml per hectare) % BPH control
Obs. Value Cal. Value Colby's ratio
T1-Thifluzamide 12%+Flupyrimin 12% SC-750 ml 90.8 84.41 1.08
T2-Thifluzamide 12%+Triflumezopyrim 3.33% SC-750 ml 92.4 87.81 1.05
T3-Thifluzamide 12%+Benzpyrimoxan 10% SC-750 ml 90.6 86.92 1.04
T4-Thifluzamide 24% SC-375 ml 10.4
T5-Flupyrimin 10% SC-900 ml 82.6
T6-Triflumezopyrim 10% SC-250 ml 86.4
T7-Benzpyrimoxan 10% SC-750 ml 85.4
T8-Untreated Control 0.0

Colby’s ratio >1, means synergism

Table 2: Control of sheath blight disease in paddy
Treatment number % Sheath blight control (Reduction in disease) Productive Tillers/hill Grain Yield (kg/plot) % Yield increase over T8
Obs. Value Cal. Value Colby's ratio
T1 92.4 87.52 1.06 38.6 30.2 79.76
T2 90.8 87.27 1.04 39.2 31.2 85.71
T3 91.6 87.38 1.05 38.2 31.4 86.90
T4 86.4 30.4 24.2 44.05
T5 8.2 29.8 23.6 40.48
T6 6.4 28.4 22.8 35.71
T7 7.2 28.8 23.2 38.10
T8 0 21.6 16.8 0.00

All the ready-mix combinations of Thifluzamide and insecticides (T1,T2 and T3) shows synergism in terms of insect control (BPH) and disease (sheath blight) control and also produces higher number of productive tiller and grain yield per plot.
Experiment 2-Cotrol of insect-pests and diseases in paddy (Oryza sativa) crop.
Crop & Variety : Paddy, BPT 5204
Location : Kurud, Chhattisgarh
Treatments : 8
Plot size : 50 sq.m.
Crop age : 60 days after transplanting.
Spray water volume : 400 liter per hectare
Method of Application: Foliar spray with battery operated knapsack sprayer fitted with hollow cone nozzle.
Agronomic Practices : Except insecticidal and fungicidal applications, all agronomic practices were followed as per the crop requirement.
Observation Methods:
Stem borer (Scirpophaga incertulas) control- Count the number of healthy and damaged tillers (dead heart) per hill at 15 days after application. Record the observations from 10 hills per plot. Calculate dead heart (%) and recalculate stem borer control. Apply Colby’s formula to check synergism.


Sheath blight (Rhizoctonia solani) control: Same as given in experiment 1.
Table 3-Control of paddy stem borer
Treatments (ml per hectare) % Stem borer control
Obs. Value Cal. Value Colby's ratio
T1-Thifluzamide 18%+Tetraniliprole 10% OD-500 ml 94.6 87.54 1.08
T2-Thifluzamide 18%+Cyclaniliprole 10% OD-500 ml 93.8 86.99 1.08
T3-Thifluzamide 18%+Cyhalodiamide 10% OD-500 ml 95.2 89.19 1.07
T4-Thifluzamide 18%+Cyproflanilide 10% OD-500 ml 94.4 88.46 1.07
T5-Thifluzamide 24% EC-375 ml 8.4
T6-Tetraniliprole 20% SC-250 ml 86.4
T7-Cyclaniliprole 5% w/v SL-1000 ml 85.8
T8-Cyhalodiamide 20% SC-250 ml 88.2
T9-Cyproflanilide 20% SC-250 ml 87.4
T10-Untreated Control 0.0

Table 4-Control of Paddy sheath blight
Treatment number % Sheath blight control (Reduction in disease) Grain Yield (kg/plot) % Increase in Grain Yield over T10
Obs. Value Cal. Value Colby's ratio
T1 91.2 87.24 1.05 31.6 88.1
T2 92.4 87.19 1.06 30.8 83.3
T3 90.8 87.38 1.04 32.2 91.7
T4 91.4 87.32 1.05 31.2 85.7
T5 86.4 24.2 44.0
T6 6.2 24.6 46.4
T7 5.8 22.8 35.7
T8 7.2 23.2 38.1
T9 6.8 22.8 35.7
T10 0.0 16.8 0.0

The synergistic combination of Thifluzamide with insecticides (T1, T2, T3 and T4) provides synergistic control of paddy stem borer and sheath blight and also produces higher grain yield.

Experiment 3: Control of insect-pests and diseases in chilly (Capsicum annum)
Crop & Variety : Chilly, Rani
Location : Umreth, Dist. Anand, Gujarat
Treatments : 14
Plot size : 50 sq.m.
Crop age : 80 days after transplanting.
Spray water volume : 520 liter per hectare
Method of Application: Foliar spray with battery operated knapsack sprayer fitted with hollow cone nozzle.
Agronomic Practices : All agronomic practices followed as per the crop requirement except insecticidal and fungicidal sprays.
Observation Methods:
Fruit borer (mixed infestation of Helicoverpa armigera and Spodoptera exigua) larval control (%)- Count the number of live larvae per plant. Record observations from 10 plants per plot on 7th day after application.

Fruit rot (Colletotrichum capsici) control: Observations was recorded on disease severity in each treatment before and at 14 days after spray. The observations of severity of fruit rot disease were recorded using 0-9 grade. 100 randomly selected fruits per plot were scored as per scale. The percent disease index (PDI) was calculated by the following formula.


Fruit rot disease Grading (0-9 scale) :
Grade Symptoms
0 No incidence
1 Less than 1% fruit area infected
3 1-5% fruit area infected
5 6-25% fruit area infected
7 26-50% fruit area infected
9 51-100% fruit area infected

% Fruit borer larval control and fruit rot disease control data were used to check the synergism by applying Colby’s formula given above.
Table 5: Control of fruit borer in chilly crop
Treatments (ml per hectare) % Fruit borer control
Obs. Value Cal. Value Colby's ratio
T1-Fluxapyroxad 15%+Dichloromezotiaz 10% OD-500 ml 93.6 86.44 1.08
T2-Fluxapyroxad 15%+Tyclopyrazoflor 10% OD-500 ml 92.8 85.53 1.09
T3-Fluxapyroxad 15%+Broflanilide 2% OD-500 ml 94.2 89.56 1.05
T4-Fluxapyroxad 15%+Fluxametamide 3% OD-500 ml 93.8 85.71 1.09
T5-Fluxapyroxad 15%+Isocycloseram 10% OD-500 ml 92.4 84.98 1.09
T6-Fluxapyroxad 15%+Oxazosulfyl 10% OD-500 ml 91.2 82.96 1.10
T7-Fluxapyroxad 30% SC-250 ml 8.4
T8-Dichlormezotiaz 35% WG-142.9 g 85.2
T9-Tyclopyrazoflor 20% SC-250 ml 84.2
T10-Broflanilide 30% SC-33.33 ml 88.6
T11-Fluxametamide 10% L-150 ml 84.4
T12-Isocycloseram 10% DC-500 ml 83.6
T13-Oxazosulfyl 20% SC-250 ml 81.4
T14-Untreated control (UTC) 0.0

Table 6-Control of fruit rot disease in Chilly
Treatment number % Fruit rot control average number of healthy fruits per plant % increase in healthy fruits over T14
Obs. Value Cal. Value Colby's ratio
T1 93.4 87.14 1.07 61.6 104.0
T2 92.2 87.22 1.06 62.4 106.6
T3 93.4 87.11 1.07 63.8 111.3
T4 91.8 87.19 1.05 62.2 106.0
T5 94.4 87.08 1.08 63.6 110.6
T6 93.6 87.17 1.07 61.2 102.6
T7 86.2 41.2 36.4
T8 6.8 44.8 48.3
T9 7.4 43.8 45.0
T10 6.6 48.6 60.9
T11 7.2 47.6 57.6
T12 6.4 45.6 51.0
T13 7.0 48.2 59.6
T14 0 30.2 0.0

The synergistic combination of Fluxapyroxad with insecticides (T1, T2, T3, T4, T5 and T6) provides synergistic control of chilly fruit borer larvae and fruit rot disease and also yielded higher number of green healthy fruits per plant.

Experiment 4: Control of insect-pests and diseases in Tomato (Solanum lycoperiscum)
Crop & Variety : Tomato, Avinash
Location : Umreth, Dist. Anand, Gujarat
Treatments : 10
Plot size : 50 sq.m.
Crop age : 90 days after transplanting.
Spray water volume : 500 liter per hectare
Method of Application: Foliar spray with battery operated knapsack sprayer fitted with hollow cone nozzle.
Agronomic Practices : All agronomic practices followed as per the crop requirement except insecticidal and fungicidal sprays.
Observation Methods:
Fruit borer (Helicoverpa armigera) larval control (%)- Count the number of live larvae per plant. Record observations from 10 plants per plot on 7th day after application.

Ealy blight (Alternaria solani) control: Observations was recorded on disease severity in each treatment before and at 14 days after spray. The observations of severity of early blight disease were recorded using 0-9 grade. 100 randomly selected trifoliate leaves per plot were scored as per scale. The percent disease index (PDI) was calculated by the following formula.


Early blight disease grading (0-9 scale) :
Grade Symptoms
0 No incidence
1 Less than 1% leaf area area infected
3 1-5% leaf area infected
5 6-25% leaf area infected
7 26-50% leaf area infected
9 51-100% leaf area infected

% Fruit borer larval control and early blight disease control data were used to check the synergism by applying Colby’s formula given above.
Table 7-Control of fruit borer larvae in tomato
Treatments (ml per hectare) % Fruit borer control
Obs. Value Cal. Value Colby's ratio
T1-Fluxapyroxad 15%+Tetraniliprole 10% SC-500 ml 95.2 88.93 1.07
T2-Fluxapyroxad 15%+Cyclaniliprole 10% SC-500 ml 94.8 87.62 1.08
T3-Fluxapyroxad 15%+Cyahalodiamide 10% SC-500 ml 93.8 88.18 1.06
T4-Fluxapyroxad 15%+Cyproflanilide 10% SC-500 ml 95.6 89.12 1.07
T5-Fluxapyroxad 30% EC-250 ml 6.2
T6-Tetraniliprole 20% SC-250 ml 88.2
T7-Cyclaniliprole 5% w/v SL-1000 ml 86.8
T8-Cyhalodiamide 20% SC-250 ml 87.4
T9-Cyproflanilide 20% SC-250 ml 88.4
T10-Untreated Control 0.0

Table 8-Control of early blight disease in tomato
Treatment number % Early blight disease control average number of healthy fruits per plant % Increase in healthy fruits over T10
Obs. Value Cal. Value Colby's ratio
T1 90.6 87.98 1.03 52.6 82.6
T2 91.2 88.06 1.04 51.8 79.9
T3 90.6 88.18 1.03 50.4 75.0
T4 91.2 87.93 1.04 53.2 84.7
T5 87.4 38.6 34.0
T6 4.6 42.5 47.6
T7 5.2 43.2 50.0
T8 6.2 44.4 54.2
T9 4.2 42.8 48.6
T10 0.0 28.8 0.0

The synergistic combination of Fluxapyroxad with insecticides (T1, T2, T3 and T4) provides synergistic control of tomato fruit borer larvae and early blight disease and also yielded higher number of healthy fruits per plant.
Summery and other visual observations of field trials :
• synergism in terms of insect control, disease control
• Produces/yielded higher yield of grains and fruits
• Provides residual control as per the visual observations
• Increase in number of fruits, flowers, grain, tillers and twigs per plant.

We claim;

[CLAIM 1].A synergistic formulation for pesticidal composition comprising:
a. a fungicide selected from class of SDHI (Succinate dehydrogenase inhibitors) present in an amount of 0.1 to 80% by weight;
b. an insecticide selected from the class of nicotinic insecticides, chordotonal organs modulators, diamides, metadiamides, isoxazolines, insecticides with unknown mode of action or unclassified present in an amount of 0.1 to 80% by weight or mixture thereof;
c. formulation excipients.

[CLAIM 2]. The synergistic formulation for pesticidal composition as claimed in claim 1, wherein a fungicide from class of SDHI (Succinate dehydrogenase inhibitors) is selected from benodanil, flutolanil, mepronil, isofetamid, fluopyram, fenfuran, carboxin, oxycarboxin, thifluzamide, benzovindiflupyr, bixafen, fluindapyr, fluxapyroxad, furametpyr, isopyrazam, penflufen, penthiopyrad, sedaxane, flubeneteram, pyrapropoyne, inpyrfluxam, isoflucypram, pydiflumetofen, boscalid and pyraziflumid.

[CLAIM 3]. The synergistic formulation for pesticidal composition as claimed in claim 1, wherein an insecticide from neonicotinoids is selected from flupyrimin, triflumezopyrim, dichloromezotiaz, cycloxaprid, paichongding, guadipyr, cycloxylidin.

[CLAIM 4]. The synergistic formulation for pesticidal composition as claimed in claim 1, wherein an insecticide from chordotonal organs modulators is selected from pyrifluquinazon; and afidopyropen.

[CLAIM 5]. The synergistic formulation for pesticidal composition as claimed in claim 1, wherein an insecticide from the class of diamides is selected from cyclaniliprole, cyhalodiamide, cyproflanilide, tetraniliprole, tetrachlorantraniliprole, tyclopyrazoflor.

[CLAIM 6]. The synergistic formulation for pesticidal composition as claimed in claim 1, wherein an insecticide from metadiamide is broflanilide.

[CLAIM 7]. The synergistic formulation for pesticidal composition as claimed in claim 1, wherein an insecticide from class of isoxazolines is selected from fluxametamide, isocycloseram.

[CLAIM 8]. The synergistic formulation for pesticidal composition as claimed in claim 1, wherein an insecticide from the unclassified is selected from benzpyrimoxan, oxazosulfyl, dimpropyridaz and flometoquin.

[CLAIM 9]. The synergistic formulation for pesticidal composition as claimed in claim 1, wherein the formulation for the said composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Powder for dry seed treatment (DS), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion for seed treatment (ES), Emulsion, oil in water (EW), Flowable suspension/concentrate for seed treatment (FS), Granule/ soil applied (GR), Controlled (Slow or Fast) release granules (CR), Solution for seed treatment (LS), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (flowable concentrate) (SC), Suspo-emulsion (SE), Water soluble granule (SG), Soluble concentrate (SL), Water soluble powder (SP), Water dispersible granule (WG or WDG), Wettable powder (WP), Water dispersible powder for slurry treatment (WS), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW).

[CLAIM 10]. The synergistic formulation for pesticidal composition as claimed in claim 1-claim 9, wherein the preferred compositions of active ingrdients for the Suspension Concentrate (SC) formulation comprises:
i. Thifluzamide 12% + Flupyrimin
ii. Thifluzamide 12% + Triflumezopyrim 3.33%
iii. Thifluzamide 12% + Benzpyrimoxan 10%
iv. Fluxapyroxad 15% + Tetraniliprole 10%
v. Fluxapyroxad 15% + Cyclaniliprole 10%
vi. Fluxapyroxad 15% + Cyahalodiamide 10%
vii. Fluxapyroxad 15% + Cyproflanilide 10%

[CLAIM 11]. The synergistic formulation for pesticidal composition as claimed in claim 10, wherein the Suspension Concentrate (SC) formulation comprises:
i. A fungicide present in an amount of 0.1 to 80% by weight of the composition is Thifluzamide, Fluxapyroxad;
ii. an insecticide from the class of nicotinic insecticides, chordotonal organs modulators, diamides, metadiamides, isoxazolines, insecticides with unknown mode of action or unclassified present in an amount of 0.1 to 80% by weight is selected from Flupyrimin, Triflumezopyrim, Benzpyrimoxan, Tetraniliprole, Cyclaniliprole, Cyhalodiamide, Cyproflanilide.
iii. Wetting-spreading-penetrating agent in an amount of 2 to 6 % by weight;
iv. Dispersing agent 1 in an amount of 2 to 8 % by weight;
v. Dispersing agent 2 in an amount of 1 to 5 % by weight;
vi. Suspending agent in an amount of 0.2 to 4.0 % by weight;
vii. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
viii. Preservative in an amount of 0.1 to 0.5 % by weight;
ix. Antifreezing agent in an amount of 2 to 6 % by weight;
x. Thickner in an amount of 0.1 to 1.0 % by weight;
xi. Diluent Water in an amount of 40 to 70 % by weight.

[CLAIM 12]. The synergistic formulation for pesticidal composition as claimed in claim 11, wherein wetting-spreading-penetrating agent is trisiloxane ethoxylate.

[CLAIM 13]. The synergistic formulation for pesticidal composition as claimed in claim 11, wherein dispersing agent is selected from alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.

[CLAIM 14]. The synergistic formulation for pesticidal composition as claimed in claim 11, wherein antifoaming agent is selected from silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane.

[CLAIM 15]. The synergistic formulation for pesticidal composition as claimed in claim 11, wherein Preservative is selected from 1,2-benzisothiazolin-3(2H)-one, sodium salt, Sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, Formaldehyde, Sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one.

[CLAIM 16]. The synergistic formulation for pesticidal composition as claimed in claim 11, wherein suspending agent is selected from Aluminum Magnesium Silicate, Bentonite clay, Silica, Attapulgite clay.

[CLAIM 17]. The synergistic formulation for pesticidal composition as claimed in claim 1-claim 9, wherein the preferred composition of active ingredients for the Oil Dispersion (OD) formulation comprises:

i. Thifluzamide 18% + Tetraniliprole 10%
ii. Thifluzamide 18% + Cyclaniliprole 10%
iii. Thifluzamide 18% + Cyhalodiamide 10%
iv. Thifluzamide 18% + Cyproflanilide 10%
v. Fluxapyroxad 15% + Dichloromezotiaz 10%
vi. Fluxapyroxad 15% + Tyclopyrazoflor 10%
vii. Fluxapyroxad 15% + Broflanilide 2%
viii. Fluxapyroxad 15% + Fluxametamide 3%
ix. Fluxapyroxad 15% + Isocycloseram 10%
x. Fluxapyroxad 15% + Oxazosulfyl 10%

[CLAIM 18]. The synergistic formulation for pesticidal composition as claimed in claim 17, wherein the Oil Dispersion (OD) formulation comprises:
i. A fungicide present in an amount of 0.1 to 80% by weight of the composition is Thifluzamide, Fluxapyroxad.
ii. an insecticide from the class of nicotinic insecticides, chordotonal organs modulators, diamides, metadiamides, isoxazolines, insecticides with unknown mode of action or unclassified present in an amount of 0.1 to 80% by weight is selected from Dichloromezotiaz, Tyclopyrazoflor, Broflanilide, Fluxametamide, Isocycloseram, Oxazosulfyl, Cyclaniliprole,
Cyhalodiamide, Tetraniliprole;
iii. Wetting-spreading-penetrating agent in an amount of 2 to 6 % by weight;
xii. Dispersing agent in an amount of 2 to 8 % by weight;
xiii. Emulsifying agent in an amount of 6 to 10 % by weight;
xiv. Stabilizer in an amount of 0.5 to 4% by weight;
xv. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
xvi. Preservative in an amount of 0.1 to 0.5 % by weight;
xvii. Antifreezing agent in an amount of 2 to 6 % by weight;
xviii. Carrier as solvent in an amount of 40 to 70% by weight.

[CLAIM 19]. The synergistic formulation for pesticidal composition as claimed in claim 18, wherein carrier as a solvent is blend of Methylated seed oil, polyalkyleneoxide modified polydimethylsiloxane and alkylphenol ethoxylate.

[CLAIM 20]. The synergistic formulation for pesticidal composition as claimed in claim 18, wherein wetting-spreading-penetrating agent is selected from organosilicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, heptamethyl trisiloxane, Polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof.

[CLAIM 21]. The synergistic formulation for pesticidal composition as claimed in claim 18, wherein dispersing agent is selected from alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycol- ether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.

[CLAIM 22]. The synergistic formulation for pesticidal composition as claimed in claim 18, wherein antifoaming agent is selected from silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, polydimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkyleneoxide modified polydimethylsiloxane.

[CLAIM 23]. The synergistic formulation for pesticidal composition as claimed in claim 18, wherein Preservative is selected from 1,2-benzisothiazolin-3(2H)-one, sodium salt, Sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, Formaldehyde, Sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one.

[CLAIM 24]. The synergistic formulation for pesticidal composition as claimed in claim 18, wherein emulsifying agent is selected from castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkylammonium salts of alkyl benzene sulphonate, alkyl sulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylene sorbitan monolaurate.

[CLAIM 25]. The synergistic formulation for pesticidal composition as claimed in claim 18, wherein stabilizer is selected from hectorite clay, aluminium magnesium silicate, bentonite clay, silica, attapulgite clay.