DESC:FIELD OF INVENTION

The present invention relates to synergistic insecticidal compoistion of Dimpropyridaz, one or more Insecticides selected from class of pyrethroids, nicotinics, mectins, juvenile hormone mimics, chordotonal organ modulators, mite growth inhibitors, mitochondrial ATP Synthase inhibitors, uncouplers of oxidative phosphorylation, chitin biosysnthesis type-1 inhibitors, moulting disruptors, mitochondrial electron transport inhibitors (METI), lipid synthesis inhibitors, diamides, metadiamides, isoxazolines, compounds of unknown mechanism of action and Plant Health Additives selected from biostimulants, plant growth regulators, microbial agents and micronutrients or mixtures thereof. The present invention more particularly relates to insecticidal compositions containing Dimpropyridaz along with plant health additives and a method of preparation of the formulation for the said insecticidal composition.

BACKGROUND OF THE INVENTION

Dimpropyridaz chemically is a pyrazole carboxamide insecticide that has a pyridin-3-yl group, as in tyclopyrazoflor. It is chemically designated as 1-(1,2-dimethylpropyl)- N-ethyl-5-methyl-N-pyridazin-4-yl-pyrazole-4-carboxamide

Dimpropyridaz is effective against aphids. Dimpropyridaz mechanism of action is unknown.
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Combination of insecticides and plant health additives compounds is used to enhance the efficacy of insecticides, to increase plant vigor, to increase the plant tolerance to biotic and abiotic factors, to reduce dosage, thereby reducing environmental impact, and decrease the chances of development of resistance. The combination of an insecticide and plant health additives compound at times demonstrate an active or synergistic effect that results in an improved control on the pest and overall crop health as well as improved plant vigour in field condition.

Damage to plants from insects is a major concern for agriculturist. There are various insects such as sap suckers, caterpillars, borer, foliage feeders etc. which reduce the plant growth and vigor and decrease the overall yield of the crops. Treating plants with such an insecticide and plant health additives combination helps reduce the damage from insect pests and parasitic nematodes. Another advantage of treating the plants with the said combination is the improvement in plant growth, increased yield and overall plant health.

WO/2020/144308 discloses Crystalline Forms Of 1-(1,2-Dimethylpropyl)-N-Ethyl-5-Methyl-N-Pyridazin-4-Yl-Pyrazole-4-Carboxamide.

Agricultural biostimulants include diverse formulations of compounds, substances and micro-organisms that are applied to plants or soils to improve crop vigour, yields, quality and tolerance of abiotic stresses. Biostimulants foster plant growth and development throughout the crop life cycle from seed germination to plant maturity in a number of demonstrated ways, including but not limited to:

• Improving the efficiency of the plant’s metabolism to induce yield increases and enhanced crop quality;
• Increasing plant tolerance to and recovery from abiotic stresses;
• Facilitating nutrient assimilation, translocation and use;
• Enhancing quality attributes of produce, including sugar content, colour, fruit seeding, etc;
• Rendering water use more efficient;
• Enhancing soil fertility, particularly by fostering the development of complementary soil micro-organisms.

Biostimulants operate through different mechanisms than fertilisers, regardless of the presence of nutrients in the products.

Biostimulants differ from crop protection products because they act only on the plant’s vigour and do not have any direct actions against insect-pests. Crop biostimulation is thus complementary to crop nutrition and crop protection.

The present inventors have surprisingly developed an synergistic composition comprising Dipropyridaz, one or more Insecticides selected from class of pyrethroids, nicotinics, mectins, juvenile hormone mimics, chordotonal organ modulators, mite growth inhibitors, mitochondrial ATP Synthase inhibitors, uncouplers of oxidative phosphorylation, chitin biosysnthesis type-1 inhibitors, moulting disruptors, mitochondrial electron transport inhibitors (METI), lipid synthesis inhibitors, diamides, metadiamides, isoxazolines, compounds of unknown mechanism of action and Plant Health Additives selected from biostimulants, plant growth regulators, microbial agents and micronutrients or mixtures thereof which increase the yield and plant vigour of the treated plant.

Advantages of the present invention
• Increase in insecticidal efficacy and residual control (duration of control)
• Increase in the spectrum of insect control (to control different type of insects and mites at a time)
• To delay or prevent the resistance development to insecticides
• Increase in yield of treated plants (cereals, pulses, oilseeds, fiber crop, sugar crops, leafy vegetables, tuber crops, fruit crops, flowers, ornamentals etc.)
• Increase in yield due to protection against insect pests and diseases
• Increase in yield due to plant growth regulation, and increase in reproductive parts of plant.
• Increase in yield due to more number of tillers, more branches and sub branches, more number of flowers, more number of fruits
• Increase plant vigor
• Increase tolerance to insect-pests damage
• Increase tolerance to the weather stress, moisture stress
• Prevents lodging in susceptible plants (lodging due to biotic and abiotic factors, like heavy rains, winds, insects and diseases damage.
• Improves quality (means visual appearance, color, size, shape etc.) in grains, fruits, fiber, flowers, tuber, bulb, rhizomes, straw, leaves and other plant parts and plant products
• Improves keeping quality of produce, increase post-harvest life, storage life, protection from post-harvest diseases
• Uniform sizing in tuber, bulb, rhizome and root crops.

OBJECTS OF THE INVENTION

It is an object of the present invention to provide an synergistic composition comprising Dimpropyridaz, one or more Insecticides selected from class of pyrethroids nicotinics, mectins, juvenile hormone mimics, chordotonal organ modulators, mite growth inhibitors, mitochondrial ATP Synthase inhibitors, uncouplers of oxidative phosphorylation, chitin biosynthesis type-1 inhibitors, moulting disruptors, mitochondrial electron transport inhibitors (METI), lipid synthesis inhibitors, diamides, metadiamides, isoxazolines, compounds of unknown mechanism of action and Plant Health Additives selected from biostimulants, plant growth regulators, microbial agents and micronutrients or mixtures thereof.

It is another object of the present invention to provide an synergistic composition comprising Dimpropyridaz, one or more Insecticides selected from class of pyrethroids, nicotinics, mectins, juvenile hormone mimics, chordotonal organ modulators, mite growth inhibitors, mitochondrial ATP Synthase inhibitors, uncouplers of oxidative phosphorylation, chitin biosysnthesis type-1 inhibitors, moulting disruptors, mitochondrial electron transport inhibitors (METI), lipid synthesis inhibitors, diamides, metadiamides, isoxazolines, compounds of unknown mechanism of action and Plant Health Additives selected from biostimulants, plant growth regulators, microbial agents and micronutrients or mixtures thereof which improve the yield and plant vigour of the treated plant.

SUMMARY OF THE INVENTION

According to an aspect of the present invention there is provided a synergistic composition comprising:

I) Dimpropyridaz;
II) one or more Insecticides selected from class of pyrethroids, nicotinics, mectins, juvenile hormone mimics, chordotonal organ modulators, mite growth inhibitors, mitochondrial ATP Synthase inhibitors, uncouplers of oxidative phosphorylation, chitin biosysnthesis type-1 inhibitors, moulting disruptors, mitochondrial electron transport inhibitors (METI), lipid synthesis inhibitors, diamides, metadiamides, isoxazolines, compounds of unknown mechanism of action and
III) Plant Health Additives selected from biostimulants, plant growth regulators, microbial agents and micronutrients or mixtures thereof.

Another aspect of the present invention is to prepare suitable formulations with the composition comprising of:

I) Dimpropyridaz;
II) one or more Insecticides selected from class of pyrethroids nicotinics, mectins, juvenile hormone mimics, chordotonal organ modulators, mite growth inhibitors, mitochondrial ATP Synthase inhibitors, uncouplers of oxidative phosphorylation, chitin biosysnthesis type-1 inhibitors, moulting disruptors, mitochondrial electron transport inhibitors (METI), lipid synthesis inhibitors, diamides, metadiamides, isoxazolines, compounds of unknown mechanism of action and,
III) Plant Health Additives selected from biostimulants, plant growth regulators, microbial agents and micronutrients or mixtures thereof.

DETAILED DESCRIPTION OF THE INVENTION

The present invention relates to synergistic mixtures of Dimproipyridaz, one or more Insecticides selected from class of pyrethroids nicotinics, mectins, juvenile hormone mimics, chordotonal organ modulators, mite growth inhibitors, mitochondrial ATP Synthase inhibitors, uncouplers of oxidative phosphorylation, chitin biosysnthesis type-1 inhibitors, moulting disruptors, mitochondrial electron transport inhibitors (METI), lipid synthesis inhibitors, diamides, metadiamides, isoxazolines, compounds of unknown mechanism of action and Plant Health Additives selected from biostimulants, plant growth regulators, microbial agents and micronutrients or mixtures thereof.

In an embodiment of the present invention there is provided a synergistic composition comprising of:

I) Dimpropyridaz;
II) one or more Insecticides selected from class of pyrethroids nicotinics, mectins, juvenile hormone mimics, chordotonal organ modulators, mite growth inhibitors, mitochondrial ATP Synthase inhibitors, uncouplers of oxidative phosphorylation, chitin biosysnthesis type-1 inhibitors, moulting disruptors, mitochondrial electron transport inhibitors (METI), lipid synthesis inhibitors, diamides, metadiamides, isoxazolines, compounds of unknown mechanism of action; wherein pyrethroids are selected from bifenthrin, lambda-cyhalothrin; nicotinics selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam, flupyrimin, cycloxaprid, paichongding, guadipyr, cycloxylidin, sulfoxaflor, flupyradifurone, triflumezopyrim, dichloromezotiaz; mectins selected from abamectin, emamectin benzoate; juvenile hormone mimics is pyriproxyfen; chordotonal organ modulators selected from pymetrozine, afidopyropen, flonicamid; mite growth inhibitors selected from hexythiazox, etoxazole; mitochiondrial ATPase synthase inhibitors selected from diafenthiuron, propargite; uncouplers of oxidative phosphorylation is chlorfenapyr; inhibitors of chitin biosynthesis type-1 is buprofezin; moulting disruptors is cyromazine; mitochondrial electron transport inhibitors selected from fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, tolfenpyrad, flufenerim, rotenone, cyenopyrafen, cyflumetofen, pyflubumidemm, hydramethylnon, acequinocyl, flometoquin, fluacrypyrim, pyriminostrobin or bifenazate; inhibitors of lipid synthesis selected from Tetronic and tetramic acid derivatives-spirodiclofen, spiromesifen, spirotetramat or spiropidion; diamides selected from cyantraniliprole, tyclopyrazoflor; metadiamide is broflanilide; isoxazolines selected from fluxametamide, isocycloseram; compounds with unknown mechanism of action selected from benzpyrimoxan, pyridalyl, flometoquin, fluhexafon, acaricidal compounds-cyetpyrafen, flupentiofenox, acyonapyr and
III) Plant Health Additives selected from biostimulants, plant growth regulators, microbial agents and micronutrients or mixtures thereof wherein biostimulants are selected from humic acid, fulvic acid, amino acids, protein hydrolysates, carboxylic acid, jasmonic acid, chitosan, chitin, seaweed extract (Ascophyllum nodosum), Salicylic acid, silicic acid (Orth silicic acid (H4Si04); plant growth regulators selected from gibberellic acid (GA3), alpha-naphthyl acetic acid, mepiquat chloride, paclobutrazol, uniconazole-p, chlormequat chloride, trinexapac ethyl, aminoethoxyvinylglycine (AVG), prohexadione calcium, brassinolide, triacontanol, nitrobenzene, nitrophenolate (sodium para-nitrophenolate); micronutrients selected from zinc (zinc sulphate heptahydrate ZnSO47H2O, zinc sulphate mono hydrate ZnSO4.H2O, chelated zinc as Zn-EDTA, zinc oxide, zinc lactate gluconate, zinc polyflavonoid), boron (borax-sodium tetraborate, boric acid (H3BO3), di-sodium octa borate tetra hydrate (Na2B8O13.4H2O), di-sodium tetra borate penta hydrate, anhydrous borax, ) and sulphur (elemental sulphur, boronated sulphur) or mixture thereof.

In another embodiment of the present invention there is provided an synergistic composition comprising of Dimpropyridaz one or more Insecticides selected from class of pyrethroids, nicotinics, mectins, juvenile hormone mimics, chordotonal organ modulators, mite growth inhibitors, mitochondrial ATP Synthase inhibitors, uncouplers of oxidative phosphorylation, chitin biosysnthesis type-1 inhibitors, moulting disruptors, mitochondrial electron transport inhibitors (METI), lipid synthesis inhibitors, diamides, metadiamides, isoxazolines, compounds of unknown mechanism of action and Plant Health Additives selected from biostimulants, plant growth regulators, microbial agents and micronutrients or mixtures thereofwith the following mass percentage of the composition:

Compounds Compound A Compound B Compound C
Composition Dimpropyridaz One or more insecticides Plant health additives
% Ratio (w/w) 0.01 to 30% w/w 0.01 to 50 % w/w 0.001 to 20% w/w

The preferred combinations of the present invention may be as follows:

Compound A Compound B Compound C

Dimpropyridaz Lambda cyhalothrin Fulvic acid
Dimpropyridaz Clothianidin Fulvic acid
Dimpropyridaz Dinotefuran Fulvic acid
Dimpropyridaz Flupyradifurone Fulvic acid
Dimpropyridaz Pyriproxyfen Fulvic acid
Dimpropyridaz Pymetrozine Fulvic acid
Dimpropyridaz Afidopyropen Fulvic acid
Dimpropyridaz Flonicamid Fulvic acid
Dimpropyridaz Hexythiazox Fulvic acid
Dimpropyridaz Diafenthiuron Fulvic acid
Dimpropyridaz Fenpyroximate Fulvic acid
Dimpropyridaz Spirodiclofen Fulvic acid
Dimpropyridaz Spiromesifen Fulvic acid
Dimpropyridaz Spirotetramat Fulvic acid
Dimpropyridaz Spiropidion Fulvic acid
Dimpropyridaz Cyantraniliprole Fulvic acid
Dimpropyridaz Tyclopyrazoflor Fulvic acid
Dimpropyridaz Broflanilide Fulvic acid
Dimpropyridaz Benzpyrimoxan Fulvic acid
Dimpropyridaz Lambda cyhalothrin Amino acid
Dimpropyridaz Clothianidin Amino acid
Dimpropyridaz Dinotefuran Amino acid
Dimpropyridaz Flupyradifurone Amino acid
Dimpropyridaz Pyriproxyfen Amino acid
Dimpropyridaz Pymetrozine Amino acid
Dimpropyridaz Afidopyropen Amino acid
Dimpropyridaz Flonicamid Amino acid
Dimpropyridaz Hexythiazox Amino acid
Dimpropyridaz Diafenthiuron Amino acid
Dimpropyridaz Fenpyroximate Amino acid
Dimpropyridaz Spirodiclofen Amino acid
Dimpropyridaz Spiromesifen Amino acid
Dimpropyridaz Spirotetramat Amino acid
Dimpropyridaz Spiropidion Amino acid
Dimpropyridaz Cyantraniliprole Amino acid
Dimpropyridaz Tyclopyrazoflor Amino acid
Dimpropyridaz Broflanilide Amino acid
Dimpropyridaz Benzpyrimoxan Amino acid
Dimpropyridaz Lambda cyhalothrin Brassinolide
Dimpropyridaz Clothianidin Brassinolide
Dimpropyridaz Dinotefuran Brassinolide
Dimpropyridaz Flupyradifurone Brassinolide
Dimpropyridaz Pyriproxyfen Brassinolide
Dimpropyridaz Pymetrozine Brassinolide
Dimpropyridaz Afidopyropen Brassinolide
Dimpropyridaz Flonicamid Brassinolide
Dimpropyridaz Hexythiazox Brassinolide
Dimpropyridaz Diafenthiuron Brassinolide
Dimpropyridaz Fenpyroximate Brassinolide
Dimpropyridaz Spirodiclofen Brassinolide
Dimpropyridaz Spiromesifen Brassinolide
Dimpropyridaz Spirotetramat Brassinolide
Dimpropyridaz Spiropidion Brassinolide
Dimpropyridaz Cyantraniliprole Brassinolide
Dimpropyridaz Tyclopyrazoflor Brassinolide
Dimpropyridaz Broflanilide Brassinolide
Dimpropyridaz Benzpyrimoxan Brassinolide
Dimpropyridaz Clothianidin Ortho silicic acid
Dimpropyridaz Dinotefuran Ortho silicic acid
Dimpropyridaz Flupyradifurone Ortho silicic acid
Dimpropyridaz Pyriproxyfen Ortho silicic acid
Dimpropyridaz Pymetrozine Ortho silicic acid
Dimpropyridaz Afidopyropen Ortho silicic acid
Dimpropyridaz Flonicamid Ortho silicic acid
Dimpropyridaz Hexythiazox Ortho silicic acid
Dimpropyridaz Diafenthiuron Ortho silicic acid
Dimpropyridaz Fenpyroximate Ortho silicic acid
Dimpropyridaz Spirodiclofen Ortho silicic acid
Dimpropyridaz Spiromesifen Ortho silicic acid
Dimpropyridaz Spirotetramat Ortho silicic acid
Dimpropyridaz Spiropidion Ortho silicic acid
Dimpropyridaz Cyantraniliprole Ortho silicic acid
Dimpropyridaz Tyclopyrazoflor Ortho silicic acid
Dimpropyridaz Broflanilide Ortho silicic acid
Dimpropyridaz Benzpyrimoxan Ortho silicic acid
Dimpropyridaz Lambda cyhalothrin Gibberellic acid
Dimpropyridaz Clothianidin Gibberellic acid
Dimpropyridaz Dinotefuran Gibberellic acid
Dimpropyridaz Flupyradifurone Gibberellic acid
Dimpropyridaz Pyriproxyfen Gibberellic acid
Dimpropyridaz Pymetrozine Gibberellic acid
Dimpropyridaz Afidopyropen Gibberellic acid
Dimpropyridaz Flonicamid Gibberellic acid
Dimpropyridaz Hexythiazox Gibberellic acid
Dimpropyridaz Diafenthiuron Gibberellic acid
Dimpropyridaz Fenpyroximate Gibberellic acid
Dimpropyridaz Spirodiclofen Gibberellic acid
Dimpropyridaz Spiromesifen Gibberellic acid
Dimpropyridaz Spirotetramat Gibberellic acid
Dimpropyridaz Spiropidion Gibberellic acid
Dimpropyridaz Cyantraniliprole Gibberellic acid
Dimpropyridaz Tyclopyrazoflor Gibberellic acid
Dimpropyridaz Broflanilide Gibberellic acid
Dimpropyridaz Benzpyrimoxan Gibberellic acid
Dimpropyridaz Lambda cyhalothrin Triacontanol
Dimpropyridaz Clothianidin Triacontanol
Dimpropyridaz Dinotefuran Triacontanol
Dimpropyridaz Flupyradifurone Triacontanol
Dimpropyridaz Pyriproxyfen Triacontanol
Dimpropyridaz Pymetrozine Triacontanol
Dimpropyridaz Afidopyropen Triacontanol
Dimpropyridaz Flonicamid Triacontanol
Dimpropyridaz Hexythiazox Triacontanol
Dimpropyridaz Diafenthiuron Triacontanol
Dimpropyridaz Fenpyroximate Triacontanol
Dimpropyridaz Spirodiclofen Triacontanol
Dimpropyridaz Spiromesifen Triacontanol
Dimpropyridaz Spirotetramat Triacontanol
Dimpropyridaz Spiropidion Triacontanol
Dimpropyridaz Cyantraniliprole Triacontanol
Dimpropyridaz Tyclopyrazoflor Triacontanol
Dimpropyridaz Broflanilide Triacontanol
Dimpropyridaz Benzpyrimoxan Triacontanol

The insecticidal composition of the present invention may be formulated in the forms given below:

Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR).

In an embodiment of the present invention there is provided a method of treating a plant comprising contacting the plant or planting materials with the synergistic composition of the present invention.

In another embodiment of the present invention there is provided a method of preparing a stable, non phytotoxic formulation of the present invention.

The method of application of the insecticidal composition of the present invention includes foliar spray, Seed treatment or treatment to planting materials, soil application.

Examples of the crops on which the present compositions may be used include but are not limited to GMO (Genetically Modified Organism) and Non GMO varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticum aestavum), Barley (Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Oat (Avena sativa), Pearl millet (Pennisetum glaucum), Sugarcane (Saccharum officinarum) , Sugarbeet (Beta vulgaris), Soybean (Glycin max), Peanut (Arachis hypogaea), Sunflower (Helianthus annuus) , Mustard (Brassica juncea), Rape seed (Brassica napus), Linseed (Linum usitatissimum), Sesame (Sesamum indicum), Green gram (Vigna radiata), Black gram (Vigna mungo), Chickpea (Cicer aritinum), Cowpea (Vigna unguiculata), Redgram (Cajanus cajan), Frenchbean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotyloma uniflorum), Field pea (Pisum sativum), Cluster bean (Cyamopsis tetragonoloba), Lentils (Lens culinaris), Brinjal (Solanum melongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschus esculentus) , Onion (Allium cepa L.), Tomato (Solanum lycopersicun) , Potato (Solanum tuberosum) , Sweet potato (Ipomoea batatas), Chilly (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumis sativus), Muskmelons (Cucumis melo), Watermelon (Citrullus lanatus), Bottle gourd (Lagenaria siceraria), Bitter gourd (Momordica charantia), Radish (Raphanus sativus), Carrot (Dacus carota subsp. sativus), Turnip (Brassica rapa subsp rapa), Apple (Melus domestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitis vinifera), Guava (Psidium guajava), Litchi (Litchi chinensis), Mango (Mangifera indica), Papaya (Carica papaya), Pineapple (Ananas comosus), Pomegranate (Punica granatum) , Sapota (Manilkara zapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiber officinale), Cumin (Cuminum cyminum), Fenugreek (Trigonella foenum-graecum), Fennel (Foeniculum vulgare), Coriander (Coriandrum sativum), Ajwain (Trachyspermum ammi), Psyllium (Plantago ovate), Black Pepper (Piper nigrum), Stevia (Stevia rebaudiana), Safed musli (Chlorophytum tuberosum), Drum stick (Moringa oleifera), Coconut (Coco nucifera), Mentha ( Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold ( Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera ( Gerbera jamesonii), Carnation (Dianthus caryophyllus), vegetables: solanaceous vegetables such as eggplant, tomato, pimento, pepper, potato, etc., cucurbit vegetables such as cucumber, pumpkin, zucchini, water melon, melon, squash, etc., cruciferous vegetables such as radish, white turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, leaf mustard, broccoli, cauliflower, etc., asteraceous vegetables such as burdock, crown daisy, artichoke, lettuce, etc, liliaceous vegetables such as green onion, onion, garlic, and asparagus, ammiaceous vegetables such as carrot, parsley, celery, parsnip, etc., chenopodiaceous vegetables such as spinach, Swiss chard, etc., lamiaceous vegetables such as Perilla frutescens, mint, basil, etc, strawberry, sweet potato, Dioscorea japonica, colocasia, etc., flowers, foliage plants, turf grasses, fruits: pome fruits such apple, pear, quince, etc, stone fleshy fruits such as peach, plum, nectarine, Prunus mume, cherry fruit, apricot, prune, etc., citrus fruits such as orange, lemon, rime, grapefruit, etc., nuts such as chestnuts, walnuts, hazelnuts, almond, pistachio, cashew nuts, macadamia nuts, etc. berries such as blueberry, cranberry, blackberry, raspberry, etc., grape, kaki fruit, olive, plum, banana, coffee, date palm, coconuts, etc. , trees other than fruit trees; tea, mulberry, flowering plant, trees such as ash, birch, dogwood, Eucalyptus, Ginkgo biloba, lilac, maple, Quercus, poplar, Judas tree, Liquidambar formosana, plane tree, zelkova, Japanese arborvitae, fir wood, hemlock, juniper, Pinus, Picea, and Taxus cuspidate, etc.

The synergistic combination of the present invention used to control the insects-pests and mites.
The major insects pests are belongs to the order Hemiptera, for example, rice leafhopper Nephotettix nigropictus, rice brown plant hopper Nilaparvata lugen, rice white backed plant hopper, Apple Mealy bug Phenococcus aceris, bean aphid Aphis fabae, black citrus aphid Toxoptera aurantii, citrus black scale Saissetia oleae, cabbage aphid Brevicoryne brassicae, Lipaphis erysimi, citrus red scale Aonidiella aurantii, yellow scale Aonidiella citrine, citrus mealybug Planococcus citri, corn leaf aphid Rhopalosiphum maidis, cotton aphid Aphis gossypii, cotton jassid Amrasca biguttula biguttla, cotton mealy bug Planococcus spp. And Pseudococcus spp., cotton stainer Dysdercus suturellus, cotton whitefly Bemisia tabaci, cowpea aphid Aphis crassivora, grain aphid Sitobion avenae, golden glow aphid Uroleucon spp., grape mealybug Pseudococcus maritimus, green peach aphid Myzus persicae, greenhouse whitefly Trialeurodes vaporariorum, papaya mealy bug Pracoccus marginatus, pea aphid Acyrthosiphon pisum, sugarcane mealybug Saccharicoccus sacchari, potato aphid Myzus persicae, potato leaf hopper Empoasca fabae, cotton whitefly Bemisia tabaci, tarnished plant bug Lygus lineolaris, wooly apple aphid Eriosoma lanigerum, mango hopper Amritodus atkinsoni, Idioscopus spp. ; order Lepidoptera, army worm Mythimna unipuncta, asiatic rice borer Chilo suppressalis, bean pod borer Maruca vitrata, beet armyworm Spodoptera exigua, black cutworm Agrotis ipsilon, bollworm Helicoverpa armigera , cabbage looper Trichoplusia ni, codling moth Cydia pomonella, croton caterpillar Achea janata, diamond backmoth Plutella xylostella, cabbage worm Pieris rapae, pink bollworm Pectinophora gossypiella, sugarcane borer Diatraea saccharalis, tobacco budworm Heliothis virescens, tomato fruitworm Helicoverpa zea, velvet bean caterpillar Anticarsia gemmatalis, yellow stem borer Scirpophaga incertulas, spotted bollworm Earias vittella, rice leaffolder Cnaphalocrocis medinalis, pink stem borer Sesamia spp., tobacco leafeating caterpillar Spodoptera litura; brinjal fruit and shoot borer Leucinodes orbonalis, bean pod borer Maruca vitrata, Maruca testulalis, armyworm Mythimna separata, cotton pinkbollworm Pectinophora gossypiella, citrus leafminer Phyllocnistis citrella, cabbage butterfly Pieris bras-sicae, diamond backmoth Plutella xylostella, paddy stem borer Scirpophaga excerptallis, Scirpophaga incertulas, Scirpophaga innotata, wheat stem borer Sesamia inferens, Sitotroga cerealella, Spilosoma obliqua, Spodoptera frugiperda, Spodoptera littoralis, Spodoptera litura, Trichoplusia ni, Tryporyza novella, Tuta absoluta.
from the order Coleoptera, for example, apple twig borer Amphicerus spp., corn root worm Diabrotica virgifera, cucumber beetle diabrotica balteata, boll weevil Anthonomus grandis, grape flea beetle Altica chalybea, grape root worm Fidia viticola, grape trunk borer Clytoleptus albofasciatus, radish flea beetle Phyllotreta armoraciae, maize weevil Sitophilus zeamais, northern corn rootworm Diabrotica barberi, rice water weevil Lissorhoptrus oryzophilus, Anthonomus grandis, Bruchus lentis, Diabrotica semipunctata, Diabrotica virgifera, Dicladispa armigera, Epila-chna varivestis, various species of white grubs are Holotrichia bicolor, Holotrichia consanguinea, Holotrichia serrata, Leptinotarsa decemlineata, Phyllotreta chrysocephala, Popillia japonica etc; from the order Orthoptera, for example, Gryllotalpa spp., Locusta spp., and Schistocerca is spp.; from the order Thysanoptera, for example, Frankliniella spp., Thrips palmi, Thrips tabaci and Scirtothrips dorsalis; termites (Isoptera), e.g. Calotermes flavicollis, Coptotermes formosanus, Heterotermes aureus, Leucotermes flavipes, Microtermes obesi, Odontotermes obesus, Reticulitermes flavipes, Termes natalensis; from the order Heteroptera, for example, Dysdercus spp., Leptocorisa spp., from the order Hymenoptera, for example, Solenopsis spp. ; from the order Diptera, for example, Antherigona soccata, Dacus spp., Liriomyza spp., Melanagromyza spp., from the order Acarina, for example, Aceria mangiferae, Brevipalpus spp., Eriophyes spp., Oligonychus mangiferus, Oligonychus punicae, Panonychus citri, Panonychus ulmi, Polyphagotarsonemus latus, Tarsonemus spp., Tetranychus urticae, Tetranychus cinnabarinus.

The insecticidal composition of the present invention can be applied to any and all developmental stages of pests, such as egg, nymph, larva, pupa and adult. The pests may be controlled by contacting the target pest, its food supply, habitat, breeding ground or its locus with a pesticidally effective amount of the inventive mixtures or of compositions comprising the mixtures.

The insecticidal composition of the present invention is uses to improve the plant health.

The term “health of a plant” or “plant health” is defined as a condition of the plant and/or its products. As a result of the improved health, yield, plant vigor, quality and tolerance to abiotic or biotic stress are increased. Noteworthy, the health of a plant when applying the insecticidal composition of the present invention is increased independently of the insecticidal properties of the active ingredients used because the increase in health is not based upon the reduced pest pressure but instead on complex physiological and metabolic reactions which result for example in an activation of the plant's own natural defense system. As a result, the health of a plant is increased even in the absence of pest pressure. Accordingly, in an especially preferred embodiment of the present invention, the health of a plant is increased both in the presence and absence of biotic or abiotic stress factors. The above identified indicators for the health condition of a plant may be interdependent or they may result from each other. An increase in plant vigor may for example result in an increased yield and/or tolerance to abiotic or biotic stress. One indicator for the condition of the plant is the yield. “Yield” is to be understood as any plant product of economic value that is produced by the plant such as grains, fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants) or even flowers (e.g. in the case of gardening plants, ornamentals). The plant products may in addition be further utilized and/or processed after harvesting.

The insecticidal composition of the present invention is used to increase plant logitivity (plant life).

In an especially preferred embodiment of the present invention, the yield of the treated plant is increased.

In another preferred embodiment of the present invention, the yield of the plants treated according to the insecticidal composition of the present invention is increased synergistically.

According to the present invention, “increased yield” of a plant, in particular of an agricultural, silvicultural and/or horticultural plant means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the insecticidal composition of the present invention.

Increased yield can be characterized, among others, by the following improved properties of the plant: increased plant, weight, increased plant height, increased biomass such as higher overall fresh weight (FW), increased number of flowers per plant, higher grain yield, more tillers or side shoots (branches), larger leaves, increased shoot growth, increased protein content, increased oil content, increased starch content, increased pigment content, increased leaf are index.

According to the present invention, the yield is increased by at least 4 %, preferable by 5 to 10%, more preferable by 10 to 20%, or even 20 to 30% compared to the untreated control plants or plants treated with pesticides in a way different from the method of the present invention. In general, the yield increase may even be higher.

A further indicator for the condition of the plant is the plant vigor. The plant vigor becomes manifest in several aspects such as the general visual appearance. In another especially preferred embodiment of the present invention, the plant vigor of the treated plant is increased. In another preferred embodiment of the present invention, the plant vigor of the plants treated with insecticidal composition of the present invention is increased synergistically. Improved plant vigor can be characterized, among others, by the following improved properties of the plant: improved vitality of the plant, improved plant growth, improved plant development, improved visual appearance, improved plant stand (less plant verse/lodging), improved emergence, enhanced root growth and/or more developed root system, enhanced nodulation, in particular rhizobial nodulation, bigger leaf blade, bigger size, increased plant weight, increased plant height, increased tiller number, increased number of side shoots, increased number of flowers per plant, increased shoot growth, increased root growth (extensive root system), increased yield when grown on poor soils or unfavorable climate, enhanced photosynthetic activity (e.g. based on increased stomatal conductance and/or increased CO2 assimilation rate), increased stomatal conductance, increased CO2 assimilation rate, enhanced pigment content (e.g. chlorophyll content), earlier flowering, earlier fruiting, earlier and improved germination, earlier grain maturity, improved self-defence mechanisms, improved stress tolerance and resistance of the plants against biotic and abiotic stress factors such as fungi, bacteria, viruses, insects, heat stress, cold stress, drought stress, UV stress and/or salt stress, less non-productive tillers, less dead basal leaves, less input needed (such as fertilizers or water), greener leaves, complete maturation under shortened vegetation periods, less fertilizers needed, less seeds needed, easier harvesting, faster and more uniform ripening, longer shelf-life, longer panicles, delay of senescence, stronger and/or more productive tillers, better extractability of ingredients, improved quality of seeds (for being seeded in the following seasons for seed production), better nitrogen uptake, improved reproduction, reduced production of ethylene and/or the inhibition of its reception by the plant.

The improvement of the plant vigor according to the present invention particularly means that the improvement of any one or several or all of the above mentioned plant characteristics are improved independently of the pesticidal action of the mixture or active ingredients (components).

Another indicator for the condition of the plant is the “quality” of a plant and/or its products.

In an especially preferred embodiment of the present invention, the quality of the treated plant is increased.

In another preferred embodiment of the present invention, the quality of the plants treated with the insecticidal composition of the present invention, is increased synergistically.

According to the present invention, enhanced quality means that certain plant characteristics such as the content or composition of certain ingredients are increased or improved by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the insecticidal composition of the present invention. Enhanced quality can be characterized, among others, by following improved properties of the plant or its product: increased nutrient content, increased protein content, increased content of fatty acids, increased metabolite content, increased carotenoid content, increased sugar content, increased amount of essential amino acids, improved nutrient composition, improved protein composition, improved composition of fatty acids, improved metabolite composition, improved carotenoid composition, improved sugar composition, improved amino acids composition, improved or optimal fruit color, improved leaf color, higher storage capacity, higher processability of the harvested products.

Another indicator for the condition of the plant is the plant’s tolerance or resistance to biotic and/or abiotic stress factors. Biotic and abiotic stress, especially over longer terms, can have harmful effects on plants. Biotic stress is caused by living organisms while abiotic stress is caused for example by environmental extremes. According to the present invention, “enhanced tolerance or resistance to biotic and/or abiotic stress factors” means (1.) that certain negative factors caused by biotic and/or abiotic stress are diminished in a measurable or noticeable amount as compared to plants exposed to the same conditions, but without being treated with insecticidal composition of the present invention and (2.) that the negative effects are not diminished by a direct action of the insecticidal composition of the present invention on the stress factors, e.g. by its fungicidal or insecticidal action which directly destroys the microorganisms or pests, but rather by a stimulation of the plants' own defensive reactions against said stress factors.

The composition of the present invention in addition to bioactive amounts of active ingredients further comprises inactive excipients including but not limited to wetting agents, wetting-spreading-penetrating agent, dispersant or dispersing agent, anti-freezing agent, anti-foam agent, preservatives, solvents, carriers, suspension aid, thickener, and buffering agent.
A wetting agent is a substance that when added to a liquid increases the spreading or penetration power of the liquid by reducing the interfacial tension between the liquid and the surface on which it is spreading. Wetting agents are used for two main functions in agrochemical formulations: during processing and manufacture to increase the rate of wetting of powders in water to make concentrates for soluble liquids or suspension concentrates; and during mixing of a product with water in a spray tank or other vessel to reduce the wetting time of wettable powders and to improve the penetration of water into water-dispersible granules.
Examples of wetting agent used herein for SC (Suspension concentrate) formulation include but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, polyalkoxylated butyl ether, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate.
Examples of wetting agent used herein for Oil dispersion (OD) formulation includes but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate.
Examples of wetting agent used herein for SE (Suspo Emulsion) formulation and Capsule suspension (CS)) formulation includes but not limited to Ethylene oxide/propylene oxide block copolymer, Polyarylphenyl ether phosphate, Ethoxylated Fatty Alcohol, Sodium dioctyl sulfosuccinate, sodium lauryl sulphate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, Alkyl naphthalene sulfonate, Octyl phenol ethoxylate, alkyl phenol ethoxylate and aliphatic alcohol ethoxylate or mixture thereof.
Examples of wetting agent used herein for WDG (Water Dispersible Granule) formulation includes but not limited to sodium N-methyl-N-oleoyl taurate, alkylated naphthalene sulfonate, sodium salt, mixture of isomers of dibutyl naphthalene sulphonic acid sodium salt, sodium di-isopropyl naphthalene sulphonate, sodium Lauryl sulfate, dioctyl sulfate, alkyl naphthalene sulfonates, phosphate esters, sulphosuccinates and non-ionic such as tridecyl alcohol ethoxylate, alkyl or alkaryl sulfonates such as alkylbenzene sulfonates, alpha olefin sulfonate and alkyl naphthalene sulfonates, ethoxylated or non-ethoxylated alkyl or alkaryl carboxylates, alkyl or alkaryl phosphate esters, alkyl polysaccharide, di or mono alkyl sulfosuccinate derivatives, alpha olefin sulfonates, alkyl naphthalene sulfonates, dialkyl sulphosuccinates, butyl, dibutyl, isopropyl and di-isopropyl naphthalene sulfonate salts, C12 alkyl benzene sulfonate or C10-C16 alkyl benzene sulfonate, organosilicons surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, trisiloxane heptamethyl, Polyalkyleneoxide modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof.
Examples of Wetting-spreading-penetrating agent used herein for Suspension Concentrate (SC) formulation, Suspo-emulsion (SE) formulation and Capsule suspension (CS)) formulation include but not limited to Organo-silicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof etc;
Examples of Wetting-spreading-penetrating agent used herein for Oil dispersion (OD) formulation include but not limited to trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane.
A dispersant or a dispersing agent is a substance which adsorbs onto the surface of particles and helps to preserve the state of dispersion of the particles and prevents them from re-aggregating. Dispersants are added to agrochemical formulations to facilitate dispersion and suspension during manufacture, and to ensure the particles re-disperse into water in a spray tank. They are widely used in wettable powders, suspension concentrates and water-dispersible granules. Surfactants that are used as dispersants have the ability to adsorb strongly onto a particle surface and provide a charged or steric barrier to re-aggregation of particles. The most commonly used surfactants are anionic, non-ionic, or mixtures of the two types. For wettable powder formulations, the most common dispersants are sodium lingo sulphonates. In recent years, new types of very high molecular weight polymeric surfactants have been developed as dispersants. These have very long hydrophobic ‘backbones’ and a large number of ethylene oxide chains forming the ‘teeth’ of a ‘comb’ surfactant. These high molecular weight polymers can give very good long-term stability to suspension concentrates because the hydrophobic backbones have many anchoring points onto the particle surfaces.
Examples of dispersants or dispersing agent used herein for SC (Suspension concentrate) formulation include but not limited to alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Examples of dispersants or dispersing agent used herein for Oil dispersion (OD) formulation includes but not limited to alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Examples of dispersants or dispersing agent used herein for SE (Suspo Emulsion) formulation includes but not limited to be a conventionally available for example polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylic polymers, acrylic graft copolymer, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol, vinylacetate and vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins and define copolymers and mixtures thereof. Examples of preferred polymers are acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these. Polymers that are biodegradable are also useful in the present invention. As used herein, a polymer is biodegradable if is not water soluble, but is degraded over a period of several weeks when placed in an application environment. Examples of biodegradable polymers that are useful in the present invention include biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof. The examples of dispersing agents are alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium salt of alkyl naphthalene sulfonate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Examples of dispersants or dispersing agent used herein for Capsule suspension (CS)) formulation includes but not limited to Ethoxylated lignosulfonic acid salts, lignosulfonic acid salts, oxidized lignins, lignin salts, salts of styrenemaleic anhydride copolymers, polyvinyl alcohol, salts of partial esters of styrene-maleic anhydride copolymers, partial salts of polyacrylic acid and partial salts of polyacrylic acid terpolymers. the surfactant is lignosulfonate of calcium or sodium or mixtures thereof or a modified kraft lignin with a high sulfonic acid group , dibutylnaphthalenesulfonic acid ,fatty acids, alkyl- and alkylarylsulfonates, alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates, and salts of sulfated hexa-, hepta- and octadecanols and of fatty alcohol glycol ethers, condensates of sulfonated naphthalene and its derivatives with formaldehyde, condensates of naphthalene or of the naphthalenesulfonic acids with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctyl-, octyl- or nonylphenol, alkyl phenyl polyglycol ethers, tributyl phenyl polyglycol ethers, alkyl aryl polyether alcohols, is tridecyl alcohol, fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers or polyoxypropylene alkyl ethers, lauryl alcohol polyglycol ether acetate, sorbitol esters, lignin-sulphite waste liquors, and proteins, denatured proteins, polysaccharides , ammonium salts of sulfonates, sulfates, phosphates or carboxylates, alkylarylsulfonates, diphenyl sulfonates, alpha-olefin sulfonates, sulfonates of fatty acids and oils, sulfonates of ethoxylated alkylphenols, sulfonates of condensed naphthalene, sulfonates of dodecyl- and tridecyl benzenes, sulfonates of naphthalene and alkylnaphthalenes, sulfosuccinates or sulfosuccinates, alkoxylates, N-alkylated fatty acid amides, amine oxides, esters or sugar-based surfactants, alkylphenols, amines (e.g. tallow amine), amides, aryl phenols, fatty acids or fatty acid esters which have been alkoxylated. Ethylene oxide and/or propylene oxide may be employed for the alkoxylation, preferably ethylene oxide, polyethylene oxide and polypropylene oxide, polyacids or polybases.
Examples of dispersants or dispersing agent used herein for WDG (Water Dispersible Granule) formulation includes but not limited to alkylnaphthalene sulfonate sodium salt, sodium polycarboxylate, naphthalene sulfonic acid, sodium salt condensates with formaldehyde, polyalcoxylated alkylphenol, naphthalene sulfonic acid formaldehyde condensate, methyl naphthalene-formaldehyde-condensate sodium salt, naphthalene condensates, lignosulfonates, polyacrylates and phosphate esters, calcium lignosulfonate, lignin sulfonate sodium salt.
Examples of Wall forming material 1 used herein for Capsule suspension (CS)) formulation includes but not limited to Tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, toluene diisocyanate, diphenylmethene-4,4’-diisocyanate, polymethylene polyphenylene isocyanate, 2,4,4’-diphenyl ether tri-isocyanate, 3,3’-dimethyl-4,4’-diphenyl diisocyanate, 3,3’-dimethoxy-4,4’-diphenyl diisocyanate, 1,5-naphthylene diisocyanate and 4,4’4"-triphenylmethane tri-isocyanate, toluene diisocyanate or polymethylene polyphenylisocyanate, polyurethane comprising of polyfunctional iso cyanate and a polyamine in polarized form.
Examples of Wall forming material 2 used herein for Capsule suspension (CS)) formulation includes but not limited to Ammonia, hexamine, ethylenediamine, propylene-1,3-diamine, tetramethylenediamine, pentamethylenediamine, 1,6-hexamethylenediamine, diethylene- triamine, triethylenetetramine, tetra ethylene pentamine, pentaethylenehexamine, 4,9-dioxadodecane-1, 12-diamine, 1,3- phenylenediamine, 2,4- and 2,6-toluenediamine and 4,4’-diaminodiphenylmethane, 1,3-phenylenediamine, 2,4- and 2,6-toluenediamine, 4,4'-diaminodiphenylmethane, 1,5-diaminonaphthalene, 1,3,5-triaminobenzene, 2,4,6-triaminotoluene, 1,3,6-triaminonaphthalene, 2,4,4'-triaminodiphenyl ether, 3,4,5-triamino-1,2,4-triazole and 1,4,5,8-tetraminoanthraquinone.

Antifoaming agent for the present formulation is selected from various compounds and selectively used according to the formulation. Generally, there are two types of antifoam agents, namely silicones and non-silicones. Silicones are usually aqueous emulsions of dimethyl poly siloxane while the non-silicone anti-foam agents are water- insoluble oils, such as octanol and nonanol, or silica. In both cases, the function of the anti-foam agent is to displace the surfactant from the air-water interface.
Examples of Antifoaming agent used herein for SC (Suspension concentrate), Oil dispersion (OD) formulation, SE (Suspo Emulsion) formulation and Capsule suspension (CS)) formulation include but not limited to silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, poly dimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkylene oxide modified polydimethylsiloxane.
Examples of Antifoaming agent used herein for WDG (Water Dispersible Granule) formulation includes but not limited to polydimethylsiloxane.
Examples of Anti-freezing agent used herein for SC (Suspension concentrate) and Oil dispersion (OD) formulation, SE (Suspo Emulsion) formulation and Capsule suspension (CS)) formulation include but not limited to ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.
Preservative used herein for the SC (Suspension concentrate) formulation , Oil dispersion (OD) formulation and Capsule suspension (CS)) formulation include but not limited to 1,2-benzisothiazolin-3(2H)-one, sodium salt, Sodium benzoate, 2-bromo-2-nitropropane-1,3-diol, Formaldehyde, Sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-isothiazolin-3-one.
Preservative used herein for the SE (Suspo Emulsion) formulation include but not limited to propionic acid and its sodium salt, sorbic acid and its sodium or potassium salt, benzoic acid and its sodium salt, p-hydroxy benzoic acid sodium salt; methyl p-hydroxy benzoate; and biocide such as sodium benzoate, 1,2-benzisothiazoline-3-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2- methyl-4-isothiazolin-3-one, potassium sorbate, para hydroxy benzoates or mixtures thereof.
Thickeners or gelling agents are used mainly in the formulation of suspension concentrates, emulsions and suspo-emulsions to modify the rheology or flow properties of the liquid and to prevent separation and settling of the dispersed particles or droplets. Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers.
Examples of thickeners used herein for SC (Suspension concentrate) formulation include but not limited to xanthan gum, PVK, carboxymethylcelluloses, polyvinyl alcohols, gelatin, sodium carboxy methylcellulose, hydroxyethyl cellulose, sodium polyacrylate, modified starch.
Examples of thickeners used herein for Capsule suspension (CS)) formulation include but not limited to Xanthan gum, Carboxy methylcellulose, Attapulgite clay, Bentonite clay.
Examples of thickeners used herein for SE (Suspo Emulsion) formulation include various compound depending upon the nature of the composition. Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers. It is possible to produce suspension concentrate formulations using clays and silicas. Examples of these types of materials, include, but are limited to, montmorillonite, e.g. bentonite; magnesium aluminum silicate; and attapulgite. Water-soluble polysaccharides have been used as thickening-gelling agents for many years. The types of polysaccharides most commonly used are natural extracts of seeds and 15 seaweeds are synthetic derivatives of cellulose or mixtures thereof. Examples of these types of materials include, but are not limited to, guar gum; locust bean gum; carrageenam; xanthan gum; alginates; methyl cellulose; sodium carboxymethyl cellulose (SCMC); hydroxyethyl cellulose (HEC) or mixtures thereof. Other types of anti-settling agents are based on modified starches, polyacrylates, polyvinyl 20 alcohol and polyethylene oxide or mixtures.
Suspension aid or the suspending agent in the present description denotes a natural or synthetic, organic or inorganic material with which the active substance is combined in order to facilitate its application to the plant, to the seeds or to the soil. This carrier is hence generally inert, and it must be agriculturally acceptable, in particular to the plant being treated. The carrier may be solid (clays, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, and the like or mixtures thereof) or liquid (water, alcohols, ketones, petroleum fractions, aromatic or paraffinic hydrocarbons, chlorinated hydrocarbons, liquefied gases, and the like or mixtures thereof).
Examples of suspending agent used herein for SC (Suspension concentrate) formulation, SE (Suspo Emulsion) formulation and Capsule suspension (CS)) formulation include but not limited to Aluminium Magnesium Silicate, Bentonite clay, Silica, Attapulgite clay.
Example of solvents used herein for the Oil dispersion (OD) formulation includes but not limited to vegetable oil (plant, seed or tree) or its alkylated or ethoxylated or esterified. The alkylated vegetable oil may be methylated vegetable oil or ethylated vegetable oil. The vegetable oils include olive oil, kapok oil, castor oil, papaya oil, camellia oil, sesame oil, corn oil, rice bran oil, cotton seed oil, soybean oil, groundnut oil, rapeseed-mustard oil, linseed oil, tung oil, sunflower oil, safflower oil, coconut oil. The alkyl ester of vegetable oils includes methyl ester, ethyl ester, propyl ester or butyl ester of vegetable oils. Some of the examples are methylated seed oil, polyalkyleneoxide modified polydimethylsiloxane alkylphenol ethoxylate, rapeseed oil methyl ester, rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, soybean oil methyl ester, soybean oil ethyl ester, soybean oil propyl ester, soybean oil butyl ester, castor oil methyl ester, castor oil ethyl ester, castor oil propyl ester, castor oil butyl ester, cotton seed oil methyl ester, cotton seed oil ethyl ester, cotton seed oil butyl ester, cotton seed oil propyl ester, tall oil fatty acids esters-tallow methyl ester, tallow ethyl ester, tallow propyl ester, bio-diesel, mineral oil (aromatic solvents, isoparaffin, base solvent), fatty acid amides (e.g. C1 -C3 amines, alkylamines or alkanolamines with C6–C18 carboxylic acids), fatty acids, alkyl esters of fatty acids, methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols. The above oil based carrier/diluting agents may be used as solo or mixture of two or more if desired.
Example of co-solvents used herein for the Oil dispersion (OD) formulation includes but not limited to Cyclohexanone, Acetophenone, NMP, Dimethyl sulfoxide, Benzyl alcohol, Butanol, N-octanol, N-Propanol, 2-ethyl hexanol, Tetrahydro furfuryl alcohol, Isophorone, Fatty acid dimethyl amide, 2-hexylethyl lactate, Propylene carbonate.
Example of solvents used herein for the Capsule suspension (CS)) formulation includes but not limited to Hydrocarbon solvent such a an aliphatic, cyclic and aromatic hydrocarbons (e.g. toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalene or their derivatives, mineral oil fractions of medium to high boiling point (such as kerosene, diesel oil, coal tar oils)); a vegetable oil such as corn oil, rapeseed oil; a fatty acid ester such as C1-C10-alkylester of a C10-C22-fatty acid; or, methyl- or ethyl esters of vegetable oils such as rapeseed oil methyl ester or corn oil methyl ester, acetophenone, 2-Heptanon , 3-heptanone, 2-hexanone, 5-methyl-2-hexanone , 5-methyl-3-heptanone, 3-methyl-2-hexanone , 4-methyl-2-hexanone, 2-methyl-3-hexanone, 4-methyl-3-hexanone , 5-methyl-3-hexanone , 3-ethyl-2-pentanone , 3,3-dimethyl-2-pentanone , 3,4-dimethyl-2-pentanone, 4,4-dimethyl-2-pentanone , 2,2-dimethyl-3-pentanone , 2,4-dimethyl-3-pentanone, 2-octanone , 2,5-dimethyl-3-hexanone , 2,2-dimethyl-3-hexanone , 3,3-dimethyl-2-hexanone, 3,4-dimethyl-2-hexanone, 4,4-dimethyl-3-hexanone , 3-ethyl-4-methyl-2-pentanone , 2-methyl-3-heptanone, 2-methyl-4-heptanone, 3-methyl-2-heptanone, 3-methyl-4-heptanone, 5-methyl-3-heptanone, 6-methyl-2-heptanone , 6-methyl-3-heptanone, 3-octanone, 4-octanone, 2,2,4-trimethyl-3-pentanone , 3-ethyl-3-methyl-2-pentanone, 5-methyl-2-heptanone, isoprene.
Example of solvents used herein for the SE (Suspo Emulsion) formulation includes but not limited to water, water soluble alcohols and dihydroxy alcohol ethers. Water soluble alcohol or lower alcohol (1-4 carbon atoms) includes-methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol. Macromolecular alcohol includes polyethylene glycol, sorbitol, glucitol etc., dihydroxy alcohol ethers includes dihydroxy alcohol alkyl ether or dihydroxy alcohol aryl ethers. The examples of dihydroxy alcohol alkyl ether include ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether, etc. The examples of dihydroxy alcohol aryl ethers include ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl ether, and the like. Any of the mentioned solvent can be used either alone or in combinations thereof. Paraffinic hydrocarbons, cyclohexanone, isophorone and ester solvents such as methyloleate, dimethylamide and morpholineamide derivatives of C6-C16 fatty acids, and mono-alkylene carbonates such as ethylene carbonate, propylene carbonate and butylene carbonates, dimethylsulfoxide (DMSO), 2-ethylhexanol and n-butanol, n-alkylpyrrolidones, fatty acid dimethyl esters, fatty acid esters, dibasic esters, aromatic hydrocarbons and/or aliphatic hydrocarbons, one or more dimethylamides, such as C8-dimethylamide, C10-dimethylamide, C12-dimethylamide, ethylene glycol, propylene glycol, polyalkylene glycols, aromatic hydrocarbons, methylpyrrolidinone (NMP); dimethylformamide (DMF); dimethylisosorbide (DMI); isophorone; acetophenone; 1,3-dimethyl-2-imidazolidonone; lactate esters; dimethyl and diethylcarbonates; alcohols including methanol; ethanol; iso-propanol; n-propanol; n-butanol; iso-butanol; and tert-butanol; Methyl L-lactate, 2-Ethylhexyl L-lactate, Ethyl L-lactate, n-Butyl L-lactate, Octyl phenyl ethoxylates, N,N decanamide.
Examples of Carrier used herein for WDG (Water Dispersible Granule) formulation includes but not limited to china clay, silica, lactose anhydrous, ammonium sulfate, sodium sulfate anhydrous, corn starch, urea, EDTA, urea formaldehyde resin, diatomaceous earth, kaolin, bentonite, kieselguhr, fuller's earth, attapulgite clay, bole, loess, talc, chalk, dolomite, limestone, lime, calcium carbonate, powdered magnesia, magnesium oxide, magnesium sulphate, sodium chloride, gypsum, calcium sulphate, pyrophyllite, silicates and silica gels; fertilizers such as, for example, ammonium sulphate, ammonium phosphate, ammonium nitrate and urea; natural products of vegetable origin such as, for example, grain meals and flours, bark meals, wood meals, nutshell meals and cellulosic powders; and synthetic polymeric materials such as, for example, ground or powdered plastics and resins, bentonites, zeolites, titanium dioxide, iron oxides and hydroxides, aluminium oxides and hydroxides, or organic materials such as bagasse, charcoal, or synthetic organic polymers.
Examples of Disintegrating agent used herein for WDG (Water Dispersible Granule) formulation includes but not limited to citric acid, succinic acid or the sodium bicarbonate.
Examples of Humectant used herein for WDG (Water Dispersible Granule) formulation includes but not limited to urea, humic acid, glycerol, lactose.
Emulsifying agent used herein for the Oil dispersion (OD) formulation includes but not limited to castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkylammonium salts of alkylbenzene sulphonate, alkylsulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylenesorbitan monolaurate.
Example of emulsifier used herein for the Suspo-emulsion (SE) formulation includes but not limited to salts of dodecylbenzene sulphonate, e.g. Ca-salts or amine salts, and sulphonates of other C11-C16 alkylbenzenes, alkylether sulphates, alkylphenoletherphosphates and ester phosphates; non-ionic surfactants such as alkoxylated alcohols and alkylphenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid esters, e.g. of sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; and catanionic emulsifiers such as a cationic amine, optionally in combination with an alkylsulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkylphenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol; fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkylbenzenes in the range C11-C16 and salts thereof; alkylether sulphates; alkyletherphosphates; alkylphenoletherphosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenol; or a catanionic system, wherein a cationic amine is present in combination with an alkylsulphonate, an alkylethersulphonate, an ether sulphate, or an ether phosphate such as an alkyletherphosphate, nonylphenol polyethoxy ethanols, castor oil polyglycol ethers, polyadducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol.
Stabilizers or stabilizing agent used herein for the Oil dispersion (OD) formulation includes but not limited to hectorite clay, aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.
Examples of Stabilizers or stabilizing agent used herein for the Suspo-emulsion (SE) formulation includes but not limited to butylated hydroxytoluene (BHT) and epoxidized soybean oil (ESBO), Epichlorhydrin.
Buffering agent used herein for the SE (Suspo Emulsion) formulation includes but not limited to calcium hydroxyapatite, Potassium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.
Buffering agent used herein for Capsule suspension (CS)) formulation includes but not limited to Sodium hydroxide, potassium hydroxide, acetic acid, sulphuric acid, hydrochloric acid, ortho phosphoric acid, ammonium hydroxide.
While the foregoing written description of the invention enables one of ordinary skill to make and use what is considered presently to be the best mode thereof, those of ordinary skill will understand and appreciate the existence of variations, combinations, and equivalents of the specific embodiment, method, and examples herein. The invention should therefore not be limited by the above described embodiment, method, and examples, but by all embodiments and methods within the scope and spirit of the invention. The invention shall now be described with reference to the following specific examples. It should be noted that the example(s) appended below illustrate rather than limit the invention, and that those skilled in the art will be able to design many alternative embodiments without departing from the scope of the present invention.
These and other aspects of the invention may become more apparent from the examples set forth herein below. These examples are provided merely as illustrations of the invention and are not intended to be construed as a limitation thereof.

EXAMPLE 1:
SE (Suspo Emulsion) Dimpropyridaz 7.5%+Pyriproxyfen 7.5%+Fulvic acid 2%

Chemical composition Content % (w/w)
Dimpropyridaz a.i. 7.50
Pyriproxyfen a.i. 7.50
Fulvic acid 2.00
Solvent Octyl phenol Ethoxylate 10.00
Wetting-spreading-penetrating agent Trisiloxane ethoxylate 4.00
Dispersing agent 1 Tristyrylphenol-polyglycolether-phosphate 4.50
Dispersing agent 2 Polyarylphenyl ether sulphate ammonium salt 1.00
Suspending agent Bentonite clay 2.00
Antifoaming agent Polydiemthylsiloxane 0.30
Preservative 2-bromo-2-nitropropane-1,3-diol 0.20
Antifreezing agent Polypropylene glycol 5.00
Thickner Xanthan gum 0.15
Diluent Water Water 55.85
Total 100.00

Storage stability-
Dimpropyridaz 7.5%+Pyriproxyfen 7.5%+Fulvic acid 2% SE (Suspo Emulsion) formulation.

Laboratory storage for 14 days
Parameters Specification (in house) Initial At 54±2 0C At 0±2 0C
Dimpropyridaz content percent by mass 7.125 to 8.250 8.00 7.65 7.85
Pyriproxyfen content percent by mass 7.125 to 8.250 8.00 7.60 7.80
Fulvic acid content percent by mass 1.90 to 2.20 2.15 2.05 2.10
Dimpropyridaz suspensibility percent min. 80 98.50 97.50 98.30
Pyriproxyfen suspensibility percent min. 80 98.50 97.70 98.20
Fulvic acid suspensibility percent min. 80 98.40 98.00 97.50
pH range (1% aq. Suspension) 4.5 to 6.5 5.20 5.10 5.20
Pourability 95% min. 98.00 97.10 97.20
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 650 660 675
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 3 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Dimpropyridaz content percent by mass 7.125 to 8.250 8.00 7.85 7.65
Pyriproxyfen content percent by mass 7.125 to 8.250 8.00 7.80 7.60
Fulvic acid content percent by mass 1.90 to 2.20 2.15 2.10 2.05
Dimpropyridaz suspensibility percent min. 80 98.50 98.00 97.00
Pyriproxyfen suspensibility percent min. 80 98.50 97.80 97.20
Fulvic acid suspensibility percent min. 80 98.40 97.70 97.20
pH range (1% aq. Suspension) 4.5 to 6.5 5.20 5.20 5.20
Pourability 95% min. 98.00 97.50 97.00
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 640 670 690
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 2 nil

Procedure: Manufacturing process of Suspo Emulsion (SE) formulation:

Preparation of Suspo Emulsion (SE) formulation:
Step 1- 2% Gel Preparation: Charge the required quantity of water to a vessel, equipped with a high shear stirrer and start the agitation. Add the required amount of preservative. Mix until homogenous. Add the required amount of thickener and mix vigorously until it is fully wetted.
Step 2- Oil Phase: Charge solvent into the vessel and then add active technical slowly and if required, heat it for 500C so that technical can be dissolved in solvent and then add emulsifier.
Step 3- Charge the required quantity of water to a vessel, equipped with bulk agitator and a high shear homogenizer and start agitation. Add the required amount of ant freezing agent and mix until uniform. Add the antifoaming agent and ensure that it is well dispersed. Add the wetting and dispersing agent and mix until uniform. Ensure that the dispersing agent is fully dispersed.
Step 4- Now add the active ingredient and continue agitating the vessel contents until all components get dissolved. Mill this pre-mix through a Colloid mill and subsequently through a Dyno mill to meet the specified particle size.
Step 5- Now add remaining antifoaming agent to this mill base to a vessel, equipped with bulk agitator. Mix until uniform.
Step 6- Now add oil phase in aqueous phase and stir for 30 minutes using homogenizer.
Step 7- Add the required amount of 2% aqueous pre-gel and also suspending agent and continue agitation until the formulation is homogeneous and has the target viscosity. Mix well.
Step 8- Final product is sent for QC approval.
Step 9- After approval, material is packed in required pack sizes.

EXAMPLE 2:
OD (Oil Dispersion) formulation of Dimpropyridaz 8%+Cyantraniliprole 5%+Brassinolide 0.025%
Chemical composition Content % (w/w)
Dimpropyridaz a.i. 8.00
Cyantraniliprole a.i. 5.00
Brassinolide a.i. 0.025
Wetting-spreading-penetrating agent Trisiloxane ethoxylate 5.00
Dispersing agent Tristyrylphenol-polyglycolether-phosphate 5.00
Emulsifying agent Calcium salts of dodecylbenzene sulphonate 8.00
Stabilizer Bentonite clay 2.00
Antifoaming agent Polydimethyl siloxane 0.50
Preservative 2-bromo-2-nitropropane-1,3-diol 0.10
Antifreezing agent Polypropylene glycol 5.00
Carrier as solvent Methylated seed oil 61.38
Total 100.00

Storage stability- Dimpropyridaz 8%+Cyantraniliprole 5%+Brassinolide 0.025% OD (Oil Dispersion)
Storage stability study in laboratory (at 54±2 C & At 0±2 C temp. for 14 days) and at room temperature (for 12 months) shows that Dimpropyridaz 8%+Cyantraniliprole 5%+Brassinolide 0.025% OD (Oil Dispersion) formulation complies all the in-house parameters like active ingredients content, suspensibility, pH range, pourability, specific gravity, viscosity, particle size and anti-foaming.

Procedure: Manufacturing process of Oil dispersion (OD) formulation:

Preparation of Oil dispersion (OD) formulation:
Part A Preparation of the liquid premix
Step 1 Charge Vegetable oil or solvent or both into a vessel with anchor stirrer.
Step 2 Under stirring, add the emulsifier and dispersing agent and stir until all ingredients are dissolved completely.
Part B Preparation of the slurry
Step 1 Now, charge the liquid premix into a second vessel, equipped with a cooling and heating device and a high shear stirrer.
Step 2 Add the active ingredient and homogenize thoroughly. Pre-mill this mixture and finally mill it using a bead mill to achieve a particle size distribution as required by the specification.
Part C Preparation of the Thickener gel
Step 1 Charge the vegetable/plant/seed oil or solvent to the vessel, equipped with a high shear stirrer.
Step 2 Add gradually the thickener which is organophilic clay, maintaining high-shear mixing throughout. Stirring is continued until thoroughly mixed.
Step 3 Under stirring, the thickener activating agent propylene carbonate is added. Allow the gel to swell whilst maintaining mixing.
Part D Preparation of the final formulation
Step 1 Now add the thickener gel or silica and disperse the mixture by using a high shear stirrer.
Step 2 Finally add the recommended wetting and spreading agent or adjuvants (silicone or non-silicone based) to this formulation and disperse by using high shear stirrer.
Step 3 Check the finished formulation to specification.
Step 4 After approval, material is packed in required pack sizes.

EXAMPLE 3:
SC (Suspension Concentrate) formulation of Dimpropyridaz 7.5%+Diafenthiuron 20%+Fulvic acid 2%
Chemical composition Content
% (w/w)
Dimpropyridaz a.i. 7.50
Diafenthiuron a.i. 20.00
Fulvic acid a.i. 2.00
Wetting-spreading-penetrating agent Trisiloxane ethoxylate 5.00
Dispersing agent 1 Naphthalenesulfonic acid, sodium salt condensated with formaldehyde 2.00
Dispersing agent 2 Tristyrylphenole with 16 moles EO 3.00
Suspending agent Bentonite clay 1.50
Antifoaming agent Polydimethyl siloxane 0.50
Preservative 2-bromo-2-nitropropane-1,3-diol 0.20
Antifreezing agent Polypropylene glycol 5.00
Thickner Xanthan gum 0.15
Diluent Water Water 53.15
Total 100.00

Storage stability- Dimpropyridaz 7.5%+Diafenthiuron 20%+Fulvic acid 2% SC (Suspension Concentrate)
Storage stability study in laboratory (at 54±2 C & At 0±2 C temp. for 14 days) and at room temperature (for 12 months) shows that Dimpropyridaz 7.5%+Diafenthiuron 20%+Fulvic acid 2% SC (Suspension concentrate) formulation complies all the in-house parameters like active ingredients content, suspensibility, pH range, pourability, specific gravity, viscosity, particle size and anti-foaming.

Procedure: Manufacturing process of SC (Suspension Concentrate) formulation:
Preparation of Suspension Concentrate (SC) formulation:
Step 1 2% Gel Preparation: Charge the required quantity of water to a vessel, equipped with a high shear stirrer and start the agitation. Add the required amount of preservative. Mix until homogenous. Add the required amount of thickener and mix vigorously until it is fully wetted.
Step 2 Charge the required quantity of water to a vessel, equipped with bulk agitator and a high shear homogenizer and start agitation. Add the required amount of ant freezing agent and mix until uniform. Add the antifoaming agent and ensure that it is well dispersed. Add the wetting and dispersing agent and mix until uniform. Ensure that the dispersing agent is fully dispersed.
Step 3 Now add the active ingredient and continue agitating the vessel contents until all components get dissolved. Mill this pre-mix through a Colloid mill and subsequently through a Dyno mill to meet the specified particle size.
Step 4 Now add remaining antifoaming agent to this SC mill base to a vessel, equipped with bulk agitator. Mix until uniform. Add the required amount of 2% aqueous pre-gel and suspending agent and continue agitation until the formulation is homogeneous and has the target viscosity is reached.
Step 5 Final product is sent for QC approval.
Step 6 After approval, material is packed in required pack sizes.

EXAMPLE 4:
ZC formulation of Dimpropyridaz 7.5%+Lambda cyhalothrin 2%+Gibberellic acid 0.25%
Chemical composition Content % (w/w)
Dimpropyridaz a.i. 7.50
Lambda cyhalothrin a.i. 2.00
Gibberellic acid a.i. 0.25
Wetting-spreading-penetrating agent Trisiloxane ethoxylate 4.00
Dispersing agent 1 Naphthalenesulfonic acid, sodium salt condensated with formaldehyde 4.50
Dispersing agent 2 Tristyrylphenol-polyglycolether-phosphate 2.00
Solvent C10-13 aromatic solvent 8.00
Wall forming material 1 Toulene diisocynate 1.00
Wall forming material 2 Methylene diphenyl diisocyanate 0.50
Suspending agent Attapulgite clay 1.50
Antifoaming agent Polydimethyl siloxane 0.30
Buffering agent Sodium hydroxide 0.50
Preservative 2-bromo-2-nitropropane-1,3-diol 0.20
Antifreezing agent Polypropylene glycol 5.00
Thickner Xanthan gum 0.15
Diluent Diluent Water 62.60
Total 100.00

Storage stability- Dimpropyridaz 7.5%+Lambda cyhalothrin 2%+Gibberellic acid 0.25% ZC (Zeon Concentrate)
Storage stability study in laboratory and at room temperature shows that Dimpropyridaz 7.5%+Lambda cyhalothrin 2%+Gibberellic acid 0.25% ZC formulation complies all the in-house parameters like active ingredients content, suspensibility, pH, pourability, specific gravity, viscosity, particle size and anti-foaming.

Procedure: Manufacturing process of ZC (Zeon Concentrate) formulation:

Preparation of ZC (mixture of CS and SC) Formulation:
Part A Preparation of CS (Capsule Suspension) formulation
Step 1 Aqueous Phase-Charge water to a stainless-steel vessel equipped with a high speed stirrer. Under agitation, add the wetting agent, dispersing agent 1and dispersing agent 2 into the vessel. Now add 50% quantity of antifoam to avoid foam generation in this vessel.
Step 2 Organic Phase-Charge heavy aromatic hydrocarbons solvent into second stainless-steel reactor. Then, slowly add melted active ingredient into the reactor. Afterwards, charge wall forming material 1 material to the reactor. Continue mixing. Cool the reactor contents to room temperature.
Step 3 Start the high shear disperser of aqueous phase and charge the ‘Organic Solution’ into the ‘Aqueous Phase Solution’ under gravity in specific rate so that required particle size can be achieved and continue to shear for 30 min. Then, start heating the reactor to around 50 °C and stir the formulation under slow rpm for 3-4 hours so that Polymerization reaction gets completed.
Step 4 Now add wall forming material 2 so that residual wall forming material 1 can be consumed and stir for 1 more hour at the same temperature and if required add half quantity of antifoam to remove foam generating due to CO2 during reaction.
Step 5 After the wall polymerization reaction, increase the agitator to high speed. Add the rest half quantity of antifoam to the formulation. Under slight vacuum, allow the mixture to de-gas for approximately 30 minutes to remove CO2 from the solution. Add the linear polysaccharide, preservative and in last freezing agent and mix for some minutes. Add buffering agent for pH adjustment. Check the formulation to specifications
Part B Preparation of SC (Suspension Concentrate) formulation
Step 1 2% Gel Preparation: Charge the required quantity of water to a vessel, equipped with a high shear stirrer and start the agitation. Add the required amount of preservative. Mix until homogenous. Add the required amount of thickener and mix vigorously until it is fully wetted.
Step 2 SC Premix- Charge the required quantity of water to a vessel, equipped with bulk agitator and a high shear homogenizer and start agitation. Add the required amount of ant freezing agent and mix until uniform. Add the antifoaming agent and ensure that it is well dispersed. Add the wetting and dispersing agent and mix until uniform. Ensure that the dispersing agent is fully dispersed.
Step 3 Now add the active ingredient and continue agitating the vessel contents until all components get dissolved. Mill this pre-mix through a Colloid mill and subsequently through a Dyno mill to meet the specified particle size.
Step 4 Now add remaining antifoaming agent to this SC mill base to a vessel, equipped with bulk agitator. Mix until uniform. Add the required amount of 2% aqueous pre-gel and suspending agent and continue agitation until the formulation is homogeneous and has the target viscosity. Mix well.
Part C Preparation of ZC Formulation
Step 1 Charge the required quantity of SC formulation into a vessel, equipped with bulk agitator and start agitation. Add the CS Premix to this slurry and mix slowly until uniform. Add the required amount of 2% pre-gel and continue agitation until the formulation is homogeneous and a target viscosity of around 600-800 m cPs is reached. Mix well.
Step 2 Final product is sent for QC approval.
Step 3 After approval, material is packed in required pack sizes.

EXAMPLE 5:

WG (Water Dispersible Granule) formulation of Dimpropyridaz 15%+Flonicamid 8%+Fulvic acid 4%

Chemical composition Content % (w/w)
Dimpropyridaz a.i. 15.00
Flonicamid a.i. 8.00
Fulvic acid a.i. 4.00
Wetting-spreading-penetrating agent Trisiloxane heptamethyl 5.00
Dispersing agent I Alkylnaphthalene sulfonate sodium salt 7.00
Dispersing agent II Sodium Polycarboxylate 3.50
Disintegrating agent Sodium sulphate anhydrous 7.00
Antifoaming agent Polydimethyl siloxane 0.50
Carrier Lactose anhydrous 50.00
Total 100.00

Storage stability- Dimpropyridaz 15%+Flonicamid 8%+Fulvic acid 4% WG (Water Dispersible Granule) formulation
Storage stability study in laboratory (at 54±2 C & At 0±2 C temp. for 14 days) and at room temperature (for 12 months) shows that Dimpropyridaz 15%+Flonicamid 8%+Fulvic acid 4% WG formulation complies all the in-house parameters like active ingredients content, suspensibility, wettability, wet sieve percent by mass, pH range and mositure content.

Procedure: Manufacturing process of WG (Water Dispersible Granule) formulation:

Preparation of WG (Water Dispersible Granule) formulation:
Step 1: Before starting the process, check the cleanliness of all equipment’s in plant and get approval by QC dept.

Step 2: Check the electrical connection and standardize the weighing balance.

Step 3: Take exact weight of active ingredients (technical) in blender and then add required quantity of binder & surfactants and mix it till its complete homogenization.

Step 4: Mill this homogenized Mixture till required wet sieve and post blend again for homogeneity.

Step 5: Pass the above homogenous material through Extruder for granulation.

Step 6: Now transfer the granules through Fluid Bed Dryer to remove excess moisture.

Step 7: Transfer these granules to vibro shifter.

Step 8: Collect the final material from the vibro shifter into drum.

Step 9: Finally send the sample to QC for approval.

Step 10: After approval by QC, transfer the material into different size of drums.

EXAMPLE 6:
Lists of preferred combinations and formulations:

Compound A Compound B Compound C Active ingredients (%) Formulation Strength (%) Formulation Type
A B C
Dimpropyridaz Lambda cyhalothrin Fulvic acid 7.5 2 2 11.50 ZC
Dimpropyridaz Clothianidin Fulvic acid 7.5 2 2 11.50 SC
Dimpropyridaz Dinotefuran Fulvic acid 7.5 2 2 11.50 SC
Dimpropyridaz Abamectin Fulvic acid 7.5 0.75 2 10.25 SE
Dimpropyridaz Emamectin benzoate Fulvic acid 7.5 0.75 2 10.25 SE
Dimpropyridaz Pyriproxyfen Fulvic acid 7.5 7.5 2 17.00 SE
Dimpropyridaz Pymetrozine Fulvic acid 15 10 4 29.00 WG
Dimpropyridaz Afidopyropen Fulvic acid 7.5 3 2 12.50 OD
Dimpropyridaz Flonicamid Fulvic acid 15 8 4 27.00 WG
Dimpropyridaz Hexythiazox Fulvic acid 15 4 2 21.00 SC
Dimpropyridaz Etoxazole Fulvic acid 15 4 2 21.00 SC
Dimpropyridaz Diafenthiuron Fulvic acid 7.5 20 2 29.50 SC
Dimpropyridaz Fenpyroximate Fulvic acid 15 4 2 21.00 SC
Dimpropyridaz Spirodiclofen Fulvic acid 7.5 10 2 19.50 SC
Dimpropyridaz Spiromesifen Fulvic acid 7.5 10 2 19.50 SC
Dimpropyridaz Spirotetramat Fulvic acid 7.5 4 2 13.50 OD
Dimpropyridaz Spiropidion Fulvic acid 7.5 4 2 13.50 SC
Dimpropyridaz Chlorantraniliprole Fulvic acid 8 2.5 2 12.50 SC
Dimpropyridaz Cyantraniliprole Fulvic acid 8 5 2 15.00 OD
Dimpropyridaz Tetraniliprole Fulvic acid 8 4 2 14.00 SC
Dimpropyridaz Tyclopyrazoflor Fulvic acid 8 5 2 15.00 SC
Dimpropyridaz Broflanilide Fulvic acid 8 1 2 11.00 SC
Dimpropyridaz Benzpyrimoxan Fulvic acid 7.5 5 2 14.50 SC
Dimpropyridaz Tolfenpyrad Fulvic acid 7.5 7.5 2 17.00 SC
Dimpropyridaz Lambda cyhalothrin Amino acid 7.5 2 2 11.50 ZC
Dimpropyridaz Clothianidin Amino acid 7.5 2 2 11.50 SC
Dimpropyridaz Dinotefuran Amino acid 7.5 2 2 11.50 SC
Dimpropyridaz Abamectin Amino acid 7.5 0.75 2 10.25 SE
Dimpropyridaz Emamectin benzoate Amino acid 8 0.75 2 10.75 SE
Dimpropyridaz Pyriproxyfen Amino acid 7.5 7.5 2 17.00 SE
Dimpropyridaz Pymetrozine Amino acid 15 10 4 29.00 WG
Dimpropyridaz Afidopyropen Amino acid 7.5 3 2 12.50 OD
Dimpropyridaz Flonicamid Amino acid 15 8 4 27.00 WG
Dimpropyridaz Hexythiazox Amino acid 15 4 2 21.00 SC
Dimpropyridaz Etoxazole Amino acid 15 4 2 21.00 SC
Dimpropyridaz Diafenthiuron Amino acid 7.5 20 2 29.50 SC
Dimpropyridaz Fenpyroximate Amino acid 15 4 2 21.00 SC
Dimpropyridaz Spirodiclofen Amino acid 7.5 10 2 19.50 SC
Dimpropyridaz Spiromesifen Amino acid 7.5 10 2 19.50 SC
Dimpropyridaz Spirotetramat Amino acid 7.5 4 2 13.50 OD
Dimpropyridaz Spiropidion Amino acid 7.5 4 2 13.50 SC
Dimpropyridaz Chlorantraniliprole Amino acid 8 2.5 2 12.50 SC
Dimpropyridaz Cyantraniliprole Amino acid 8 5 2 15.00 OD
Dimpropyridaz Tetraniliprole Amino acid 8 4 2 14.00 SC
Dimpropyridaz Tyclopyrazoflor Amino acid 8 5 2 15.00 SC
Dimpropyridaz Broflanilide Amino acid 8 1 2 11.00 SC
Dimpropyridaz Benzpyrimoxan Amino acid 7.5 5 2 14.50 SC
Dimpropyridaz Tolfenpyrad Amino acid 7.5 7.5 2 17.00 SC
Dimpropyridaz Lambda cyhalothrin Brassinolide 7.5 2 0.025 9.53 ZC
Dimpropyridaz Clothianidin Brassinolide 7.5 2 0.025 9.53 SC
Dimpropyridaz Dinotefuran Brassinolide 7.5 2 0.025 9.53 SC
Dimpropyridaz Abamectin Brassinolide 7.5 0.75 0.025 8.28 SE
Dimpropyridaz Emamectin benzoate Brassinolide 8 0.75 0.025 8.78 SE
Dimpropyridaz Pyriproxyfen Brassinolide 7.5 7.5 0.025 15.03 SE
Dimpropyridaz Pymetrozine Brassinolide 15 10 0.05 25.05 WG
Dimpropyridaz Afidopyropen Brassinolide 7.5 3 0.025 10.53 OD
Dimpropyridaz Flonicamid Brassinolide 15 8 0.05 23.05 WG
Dimpropyridaz Hexythiazox Brassinolide 15 4 0.05 19.05 SC
Dimpropyridaz Etoxazole Brassinolide 15 4 0.05 19.05 SC
Dimpropyridaz Diafenthiuron Brassinolide 7.5 20 0.025 27.53 SC
Dimpropyridaz Fenpyroximate Brassinolide 15 4 0.05 19.05 SC
Dimpropyridaz Spirodiclofen Brassinolide 7.5 10 0.025 17.53 SC
Dimpropyridaz Spiromesifen Brassinolide 7.5 10 0.025 17.53 SC
Dimpropyridaz Spirotetramat Brassinolide 7.5 4 0.025 11.53 OD
Dimpropyridaz Spiropidion Brassinolide 7.5 4 0.025 11.53 SC
Dimpropyridaz Chlorantraniliprole Brassinolide 8 2.5 0.025 10.53 SC
Dimpropyridaz Cyantraniliprole Brassinolide 8 5 0.025 13.03 OD
Dimpropyridaz Tetraniliprole Brassinolide 8 4 0.025 12.03 SC
Dimpropyridaz Tyclopyrazoflor Brassinolide 8 5 0.025 13.03 SC
Dimpropyridaz Broflanilide Brassinolide 8 1 0.025 9.03 SC
Dimpropyridaz Benzpyrimoxan Brassinolide 7.5 5 0.025 12.53 SC
Dimpropyridaz Tolfenpyrad Brassinolide 7.5 7.5 0.025 15.03 SC
Dimpropyridaz Lambda cyhalothrin Triacontanol 7.5 2 0.025 9.53 ZC
Dimpropyridaz Clothianidin Triacontanol 7.5 2 0.025 9.53 SC
Dimpropyridaz Dinotefuran Triacontanol 7.5 2 0.025 9.53 SC
Dimpropyridaz Abamectin Triacontanol 7.5 0.75 0.025 8.28 SE
Dimpropyridaz Emamectin benzoate Triacontanol 7.5 0.75 0.025 8.28 SE
Dimpropyridaz Pyriproxyfen Triacontanol 7.5 7.5 0.025 15.03 SE
Dimpropyridaz Pymetrozine Triacontanol 15 10 0.05 25.05 WG
Dimpropyridaz Afidopyropen Triacontanol 7.5 3 0.025 10.53 OD
Dimpropyridaz Flonicamid Triacontanol 15 8 0.05 23.05 WG
Dimpropyridaz Hexythiazox Triacontanol 15 4 0.05 19.05 SC
Dimpropyridaz Etoxazole Triacontanol 15 4 0.05 19.05 SC
Dimpropyridaz Diafenthiuron Triacontanol 7.5 20 0.025 27.53 SC
Dimpropyridaz Fenpyroximate Triacontanol 15 4 0.05 19.05 SC
Dimpropyridaz Spirodiclofen Triacontanol 7.5 10 0.025 17.53 SC
Dimpropyridaz Spiromesifen Triacontanol 7.5 10 0.025 17.53 SC
Dimpropyridaz Spirotetramat Triacontanol 7.5 4 0.025 11.53 OD
Dimpropyridaz Spiropidion Triacontanol 7.5 4 0.025 11.53 SC
Dimpropyridaz Chlorantraniliprole Triacontanol 8 2.5 0.025 10.53 SC
Dimpropyridaz Cyantraniliprole Triacontanol 8 5 0.025 13.03 OD
Dimpropyridaz Tetraniliprole Triacontanol 8 4 0.025 12.03 SC
Dimpropyridaz Tyclopyrazoflor Triacontanol 8 5 0.025 13.03 SC
Dimpropyridaz Broflanilide Triacontanol 8 1 0.025 9.03 SC
Dimpropyridaz Benzpyrimoxan Triacontanol 7.5 5 0.025 12.53 SC
Dimpropyridaz Tolfenpyrad Triacontanol 7.5 7.5 0.025 15.03 SC
Dimpropyridaz Lambda cyhalothrin Gibberellic acid 7.5 2 0.25 9.75 ZC
Dimpropyridaz Clothianidin Gibberellic acid 7.5 2 0.25 9.75 SC
Dimpropyridaz Dinotefuran Gibberellic acid 7.5 2 0.25 9.75 SC
Dimpropyridaz Abamectin Gibberellic acid 7.5 0.75 0.25 8.50 SE
Dimpropyridaz Emamectin benzoate Gibberellic acid 7.5 0.75 0.25 8.50 SE
Dimpropyridaz Pyriproxyfen Gibberellic acid 7.5 7.5 0.25 15.25 SE
Dimpropyridaz Pymetrozine Gibberellic acid 15 10 0.5 25.50 WG
Dimpropyridaz Afidopyropen Gibberellic acid 7.5 3 0.25 10.75 OD
Dimpropyridaz Flonicamid Gibberellic acid 15 8 0.5 23.50 WG
Dimpropyridaz Hexythiazox Gibberellic acid 15 4 0.5 19.50 SC
Dimpropyridaz Etoxazole Gibberellic acid 15 4 0.5 19.50 SC
Dimpropyridaz Diafenthiuron Gibberellic acid 7.5 20 0.25 27.75 SC
Dimpropyridaz Fenpyroximate Gibberellic acid 15 4 0.5 19.50 SC
Dimpropyridaz Spirodiclofen Gibberellic acid 7.5 10 0.25 17.75 SC
Dimpropyridaz Spiromesifen Gibberellic acid 7.5 10 0.25 17.75 SC
Dimpropyridaz Spirotetramat Gibberellic acid 7.5 4 0.25 11.75 OD
Dimpropyridaz Spiropidion Gibberellic acid 7.5 4 0.25 11.75 SC
Dimpropyridaz Chlorantraniliprole Gibberellic acid 8 2.5 0.25 10.75 SC
Dimpropyridaz Cyantraniliprole Gibberellic acid 8 5 0.25 13.25 OD
Dimpropyridaz Tetraniliprole Gibberellic acid 8 4 0.25 12.25 SC
Dimpropyridaz Tyclopyrazoflor Gibberellic acid 8 5 0.25 13.25 SC
Dimpropyridaz Broflanilide Gibberellic acid 8 1 0.25 9.25 SC
Dimpropyridaz Benzpyrimoxan Gibberellic acid 7.5 5 0.25 12.75 SC
Dimpropyridaz Tolfenpyrad Gibberellic acid 7.5 7.5 0.25 15.25 SC
Dimpropyridaz Lambda cyhalothrin Paclobutrazol 7.5 2 2.5 12.00 ZC
Dimpropyridaz Clothianidin Paclobutrazol 7.5 2 2.5 12.00 SC
Dimpropyridaz Dinotefuran Paclobutrazol 7.5 2 2.5 12.00 SC
Dimpropyridaz Abamectin Paclobutrazol 7.5 0.75 2.5 10.75 SE
Dimpropyridaz Emamectin benzoate Paclobutrazol 7.5 0.75 2.5 10.75 SE
Dimpropyridaz Pyriproxyfen Paclobutrazol 7.5 7.5 2.5 17.50 SE
Dimpropyridaz Pymetrozine Paclobutrazol 15 10 5 30.00 WG
Dimpropyridaz Afidopyropen Paclobutrazol 7.5 3 2.5 13.00 OD
Dimpropyridaz Flonicamid Paclobutrazol 15 8 5 28.00 WG
Dimpropyridaz Hexythiazox Paclobutrazol 15 4 5 24.00 SC
Dimpropyridaz Etoxazole Paclobutrazol 15 4 5 24.00 SC
Dimpropyridaz Diafenthiuron Paclobutrazol 7.5 20 2.5 30.00 SC
Dimpropyridaz Fenpyroximate Paclobutrazol 15 4 5 24.00 SC
Dimpropyridaz Spirodiclofen Paclobutrazol 7.5 10 2.5 20.00 SC
Dimpropyridaz Spiromesifen Paclobutrazol 7.5 10 2.5 20.00 SC
Dimpropyridaz Spirotetramat Paclobutrazol 7.5 4 2.5 14.00 OD
Dimpropyridaz Spiropidion Paclobutrazol 7.5 4 2.5 14.00 SC
Dimpropyridaz Chlorantraniliprole Paclobutrazol 8 2.5 2.5 13.00 SC
Dimpropyridaz Cyantraniliprole Paclobutrazol 8 5 2.5 15.50 OD
Dimpropyridaz Tetraniliprole Paclobutrazol 8 4 2.5 14.50 SC
Dimpropyridaz Tyclopyrazoflor Paclobutrazol 8 5 2.5 15.50 SC
Dimpropyridaz Broflanilide Paclobutrazol 8 1 2.5 11.50 SC
Dimpropyridaz Benzpyrimoxan Paclobutrazol 7.5 5 2.5 15.00 SC
Dimpropyridaz Tolfenpyrad Paclobutrazol 7.5 7.5 2.5 17.50 SC
Dimpropyridaz Lambda cyhalothrin Mepiquat chloride 7.5 2 3 12.50 ZC
Dimpropyridaz Clothianidin Mepiquat chloride 7.5 2 3 12.50 SC
Dimpropyridaz Dinotefuran Mepiquat chloride 7.5 2 3 12.50 SC
Dimpropyridaz Abamectin Mepiquat chloride 7.5 0.75 3 11.25 SE
Dimpropyridaz Emamectin benzoate Mepiquat chloride 7.5 0.75 3 11.25 SE
Dimpropyridaz Pyriproxyfen Mepiquat chloride 7.5 7.5 3 18.00 SE
Dimpropyridaz Pymetrozine Mepiquat chloride 15 10 6 31.00 WG
Dimpropyridaz Afidopyropen Mepiquat chloride 7.5 3 3 13.50 OD
Dimpropyridaz Flonicamid Mepiquat chloride 15 8 6 29.00 WG
Dimpropyridaz Hexythiazox Mepiquat chloride 15 4 6 25.00 SC
Dimpropyridaz Etoxazole Mepiquat chloride 15 4 6 25.00 SC
Dimpropyridaz Diafenthiuron Mepiquat chloride 7.5 20 3 30.50 SC
Dimpropyridaz Fenpyroximate Mepiquat chloride 15 4 6 25.00 SC
Dimpropyridaz Spirodiclofen Mepiquat chloride 7.5 10 3 20.50 SC
Dimpropyridaz Spiromesifen Mepiquat chloride 7.5 10 3 20.50 SC
Dimpropyridaz Spirotetramat Mepiquat chloride 7.5 4 3 14.50 OD
Dimpropyridaz Spiropidion Mepiquat chloride 7.5 4 3 14.50 SC
Dimpropyridaz Chlorantraniliprole Mepiquat chloride 8 2.5 3 13.50 SC
Dimpropyridaz Cyantraniliprole Mepiquat chloride 8 5 3 16.00 OD
Dimpropyridaz Tetraniliprole Mepiquat chloride 8 4 3 15.00 SC
Dimpropyridaz Tyclopyrazoflor Mepiquat chloride 8 5 3 16.00 SC
Dimpropyridaz Broflanilide Mepiquat chloride 8 1 3 12.00 SC
Dimpropyridaz Benzpyrimoxan Mepiquat chloride 7.5 5 3 15.50 SC
Dimpropyridaz Tolfenpyrad Mepiquat chloride 7.5 7.5 3 18.00 SC
Dimpropyridaz Lambda cyhalothrin Zinc lacto gluconate 7.5 2 4 13.50 ZC
Dimpropyridaz Clothianidin Zinc lacto gluconate 7.5 2 4 13.50 SC
Dimpropyridaz Dinotefuran Zinc lacto gluconate 7.5 2 4 13.50 SC
Dimpropyridaz Abamectin Zinc lacto gluconate 7.5 0.75 4 12.25 SE
Dimpropyridaz Emamectin benzoate Zinc lacto gluconate 7.5 0.75 4 12.25 SE
Dimpropyridaz Pyriproxyfen Zinc lacto gluconate 7.5 7.5 4 19.00 SE
Dimpropyridaz Pymetrozine Zinc lacto gluconate 15 10 8 33.00 WG
Dimpropyridaz Afidopyropen Zinc lacto gluconate 7.5 3 4 14.50 OD
Dimpropyridaz Flonicamid Zinc lacto gluconate 15 8 8 31.00 WG
Dimpropyridaz Hexythiazox Zinc lacto gluconate 15 4 8 27.00 SC
Dimpropyridaz Etoxazole Zinc lacto gluconate 15 4 8 27.00 SC
Dimpropyridaz Diafenthiuron Zinc lacto gluconate 7.5 20 4 31.50 SC
Dimpropyridaz Fenpyroximate Zinc lacto gluconate 15 4 8 27.00 SC
Dimpropyridaz Spirodiclofen Zinc lacto gluconate 7.5 10 4 21.50 SC
Dimpropyridaz Spiromesifen Zinc lacto gluconate 7.5 10 4 21.50 SC
Dimpropyridaz Spirotetramat Zinc lacto gluconate 7.5 4 4 15.50 OD
Dimpropyridaz Spiropidion Zinc lacto gluconate 7.5 4 4 15.50 SC
Dimpropyridaz Chlorantraniliprole Zinc lacto gluconate 8 2.5 4 14.50 SC
Dimpropyridaz Cyantraniliprole Zinc lacto gluconate 8 5 4 17.00 OD
Dimpropyridaz Tetraniliprole Zinc lacto gluconate 8 4 4 16.00 SC
Dimpropyridaz Tyclopyrazoflor Zinc lacto gluconate 8 5 4 17.00 SC
Dimpropyridaz Broflanilide Zinc lacto gluconate 8 1 4 13.00 SC
Dimpropyridaz Benzpyrimoxan Zinc lacto gluconate 7.5 5 4 16.50 SC
Dimpropyridaz Tolfenpyrad Zinc lacto gluconate 7.5 7.5 4 19.00 SC

SE Suspo Emulsion, OD Oil Dispersion, SC Suspension Concentrate, ZC Zeon Cocncentrate, WG (Water Dispersible Granule)

Biological Examples:
A synergistic effect exists wherever the action of a combination of active ingredient is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticidal activity than the sum of the pesticidal activities of the individual components.
In the field of agriculture, it is often understood that the term “synergy” is as defined by Colby S.R. in an article entitled “ Calculation of the synergistic and antagonistic responses of herbicide combinations” published in the journal Weeds, 1967, 15, p.20-22, incorporated herein by reference in its entirety. The action expected for a given combination of two or three active components can be calculated as follows:

FIELD BIO-EFFICACY STUDIES:
The field trials have been carried out on different crops to judge the synergism and benefits of innovative ready-mix combinations in comparison to conventional treatments.
Experiment 1: Control of sucking pests in cotton crop
Crop : Cotton
Location : Rajkot, Gujarat
Plot size : 40 sq.mt.
Number of Treatments: 24
Crop Stage : 70 DAS (Days after transplanting)
Spray volume : 500 liter/h
Method of Application: Foliar spray with battery operated knap sack sprayer
Agronomic Practices : All agronomic practices followed as per the crop requirement except insect control.
Observation Methods:
Sucking Pest control : Sucking pests (Jassid Amrasca biguttulaa biguttulla, Thrips Thrips tabaci and Whitefly Bemisia tabaci). Count the number of live insects per leaf. Record the observations from 3 leaves per plant and 10 plants per plot on 3, 10 and 14 DAA (Days after application). Calculate % sucking pests (expected value) control and apply Colby’s formula to judge the synergism.

Table 1: Treatment details
Treatment Number Treatment details Rate (gai/h)
T1 Dimpropyridaz 7.5%+Pyriproxyfen 7.5%+Fulvic acid 2% SE 75+75+20
T2 Dimpropyridaz 7.5%+Spiromesifen 10%+Fulvic acid 2% SC 75+100+20
T3 Dimpropyridaz 15%+Flonicamid 8%+Fulvic acid 4% WG 75+40+20
T4 Dimpropyridaz 7.5%+Diafenthiuron 20%+Fulvic acid 2% SC 75+200+20
T5 Dimpropyridaz 7.5%+Tolfenpyrad 7.5%+Fulvic acid 2% SC 75+75+20
T6 Pyriproxyfen 10% EC+Fulvic acid 80% WP 75+20
T7 Spiromesifen 22.9% SC+Fulvic acid 80% WP 100+20
T8 Flonicamid 50% WG+Fulvic acid 80% WP 40+20
T9 Diafenthiuron 50% WP+Fulvic acid 80% WP 200+20
T10 Tolfenpyrad 15% EC+Fulvic acid 80% WP 75+20
T11 Dimpropyridaz 12% SC+Pyriproxyfen 10% EC 75+75
T12 Dimpropyridaz 12% SC+Spiromesifen 22.9% SC 75+100
T13 Dimpropyridaz 12% SC+Flonicamid 50% WG 75+40
T14 Dimpropyridaz 12% SC+Diafenthiuron 50% WP 75+200
T15 Dimpropyridaz 12% SC+Tolfenpyrad 15% EC 75+75
T16 Dimpropyridaz 12% SC+Fulvic acid 80% WP 75+20
T17 Pyriproxyfen 10% EC 75
T18 Spiromesifen 22.9% SC 100
T19 Flonicamid 50% WG 40
T20 Diafenthiuron 50% WP 200
T21 Tolfenpyrad 15% EC 75
T22 Fulvic acid 80% WP 20
T23 Dimpropyridaz 12% SC 75
T24 UTC (Untreated Check) 0

T1 to T5-Innovative ready-mix combinations, T6 to T16-conventional combinations, SC Suspension concentrate, EC Emulsifiable concentrate, SE Suspo emulsion, WG Wettable Granule, WP Wettable powder.

Table 2: Synergism, residual control of sucking pests in cotton
Treatment Number Sucking pests control (%) at 3 DAA 10 DAA 14 DAA Number of fruiting bodies/plant % increase in fruiting bodies over T24
Obs. Value Exp. Value Ratio O/E Synergism (Y/N)
T1 96.8 84.45 1.15 Y 90.2 77.2 67.5 80.0
T2 97.6 85.84 1.14 Y 91.2 80.6 68.2 81.9
T3 98.8 86.20 1.15 Y 92.4 78.4 69.2 84.5
T4 96.4 83.43 1.16 Y 94.6 78.2 68.3 82.1
T5 97.2 85.69 1.13 Y 91.8 78.8 67.8 80.8
T6 58.0 58.42 0.99 N 48.6 37.6 56.2 49.9
T7 61.8 62.13 0.99 N 50.4 44.2 57.3 52.8
T8 62.4 63.11 0.99 N 51.2 40.6 55.4 47.7
T9 55.4 55.69 0.99 N 44.4 34.2 54.2 44.5
T10 61.4 61.74 0.99 N 46.8 35.2 55.7 48.5
T11 83.4 84.07 0.99 N 70.4 60.6 52.8 40.8
T12 84.2 85.49 0.98 N 69.2 61.4 53.4 42.4
T13 85.4 85.86 0.99 N 71.4 57.8 51.8 38.1
T14 82.0 83.02 0.99 N 67.8 56.4 52.8 40.8
T15 83.6 85.34 0.98 N 72.4 60.2 51.8 38.1
T16 63.0 63.50 0.99 N 45.2 38.2 52.8 40.8
T17 57.4 50.2 40.4 44.6 18.9
T18 61.2 53.8 46.8 46.2 23.2
T19 62.2 55.4 43.4 45.9 22.4
T20 54.6 46.2 36.8 46.8 24.8
T21 60.8 52.2 40.2 47.3 26.1
T22 2.4 1.6 0.6 40.2 7.2
T23 62.6 54.4 45.2 48.7 29.9
T24 0.0 0.0 0.0 37.5 0.0
DAA- Days after application.
All the ready-mix innovative combinations (T1 to T5) provides synergistic control of sucking pests along with residual control in cotton crop and also produces higher number of fruiting bodies per plant compared to conventional combinations (T6 to T16).

Experiment 2: Control of fruit&shoot borer in brinjal, Solanum melongena
Crop : Brinjal
Location : Umreth, Gujarat
Plot size : 24 sq.mt.
Number of Treatments: 24
Crop Stage : 62 DAS (Days after transplanting)
Spray volume : 480 liter/h
Method of Application: Foliar spray with battery operated knap sack sprayer
Agronomic Practices : All agronomic practices followed as per the crop requirement except insect control.
Observation Methods:
Fruit & shoot borer (Leucinoides orbonalis) control (%): Count the number of infested and healthy shoots per plant. Record such observations from 10 plants per plot, at before application and 7 days after application. Calculate % fruit & shoot borer infestation and then recalculate percent control (observed value) by below given formula.

Fruit count: Count the number of fruits from 5 plants per plot on 14th day after application.
Table 3: Treatment details
Treatment Number Treatment details Rate (gai/h)
T1 Dimpropyridaz 8%+Chlorantraniliprole 2.5%+Brassinolide 0.025% SC 80+25+0.25
T2 Dimpropyridaz 8%+Cyantraniliprole 5%+Brassinolide 0.025% OD 80+50+0.25
T3 Dimpropyridaz 8%+Tetraniliprole 4%+Brassinolide 0.025% SC 80+40+0.25
T4 Dimpropyridaz 8%+Broflanilide 1%+Brassinolide 0.025% SC 80+10+0.25
T5 Dimpropyridaz 8%+Emamectin benzoate 0.75%+Brassinolide 0.025% SC 80+7.5+0.25
T6 Chlorantraniliprole 18.5% SC+Brassinolide 0.1% SL 25+0.25
T7 Cyantraniliprole 10.26% OD+Brassinolide 0.1% SL 50+0.25
T8 Tetraniliprole 20% SC+Brassinolide 0.1% SL 40+0.25
T9 Broflanilide 30% SC+Brassinolide 0.1% SL 10+0.25
T10 Emamectin benzoate 5% SG+Brassinolide 0.1% SL 7.5+0.25
T11 Dimpropyridaz 12% SC+Chlorantraniliprole 18.5% SC 80+25
T12 Dimpropyridaz 12% SC+Cyantraniliprole 10.26% OD 80+50
T13 Dimpropyridaz 12% SC+Tetraniliprole 20% SC 80+40
T14 Dimpropyridaz 12% SC+Broflanilide 30% SC 80+10
T15 Dimpropyridaz 12% SC+Emamectin benzoate 5% SG 80+7.5
T16 Dimpropyridaz 12% SC+Brassinolide 0.1% SL 80+0.25
T17 Chlorantraniliprole 18.5% SC 25
T18 Cyantraniliprole 10.26% OD 50
T19 Tetraniliprole 20% SC 40
T20 Broflanilide 30% SC 10
T21 Emamectin benzoate 5% SG 7.5
T22 Brassinolide 0.1% SL 0.25
T23 Dimpropyridaz 12% SC 80
T24 UTC (Untreated Check) 0

T1 to T5-innovative ready mix combinations, T6 to T16- conventional combinations
Table 4: Control of fruit & shoot borer in brinjal crop
Treatment Number Fruit borer control (%) at 7 DAA 14 DAA Number of healthy fruits/5 plants % increase in fruits over T24
Obs. Value Exp. Value Ratio O/E Synergism (Y/N)
T1 97.4 84.14 1.16 Y 84.8 45.8 106.3
T2 98.4 85.37 1.15 Y 87.4 47.4 113.5
T3 95.2 84.43 1.13 Y 85.4 45.2 103.6
T4 96.2 85.67 1.12 Y 86.8 46.8 110.8
T5 92.8 82.83 1.12 Y 85.4 45.0 102.7
T6 56.8 57.36 0.99 N 44.4 37.8 70.3
T7 59.2 60.68 0.98 N 48.6 38.6 73.9
T8 57.4 58.14 0.99 N 45.0 37.6 69.4
T9 60.4 61.47 0.98 N 49.8 38.2 72.1
T10 52.2 53.84 0.97 N 42.8 36.8 65.8
T11 83.2 83.78 0.99 N 73.8 40.8 83.8
T12 84.4 85.05 0.99 N 74.4 41.4 86.5
T13 83.2 84.08 0.99 N 73.2 40.2 81.1
T14 84.4 85.34 0.99 N 75.8 41.2 85.6
T15 81.2 82.44 0.98 N 73.4 39.8 79.3
T16 62.6 63.62 0.98 N 52.2 38.8 74.8
T17 56.4 46.2 31.2 40.5
T18 59.8 50.8 32.6 46.8
T19 57.2 47.2 31.0 39.6
T20 60.6 52.4 31.8 43.2
T21 52.8 44.6 30.4 36.9
T22 2.2 0.8 23.6 6.3
T23 62.8 55.6 30.8 38.7
T24 0.0 0.0 22.2 0.0

All the innovative combinations (T1 to T5) provides excellent control of fruit and shoot borer pests in brinjal crop and also produces higher number of fruits as compared with conventional combinations (T6 to T16).
Experiment 3: Control of sucking pests in Okra (Abelmoschus esculentus)
Crop : Okra
Location : Anand, Gujarat
Plot size : 25 sq. mt.
Number of Treatments: 24
Application Time : 54 DAS (Days after sowing)
Spray volume : 440 liter/h
Method of Application: Foliar spray with battery operated knap sack sprayer
Agronomic Practices : All agronomic practices followed as per the crop requirement except insect.
Observation Methods:
Sucking Pests control(%): As given in Experiment 1.
Fruit count: Count the number of fruits from 5 plants per plot on 10th day after application.
Table 5: Treatment details
Treatment Number Treatment details Rate (gai/h)
T1 Dimpropyridaz 7.5%+Lambda cyhalothrin 2%+Gibberellic acid 0.25% ZC 75+20+2.5
T2 Dimpropyridaz 7.5%+Dinotefuran 2%+Gibberellic acid 0.25% SC 75+20+2.5
T3 Dimpropyridaz 7.5%+Afidopyropen 3%+Gibberellic acid 0.25% OD 75+30+2.5
T4 Dimpropyridaz 15%+Fenpyroximate 4%+Gibberellic acid 0.5% SC 75+20+2.5
T5 Dimpropyridaz 7.5%+Spiropidion 4%+Gibberellic acid 0.25% SC 75+40+2.5
T6 Lambda cyhalothrin 5% EC+Gibberellic acid 40% WSG 20+2.5
T7 Dinotefuran 20% SG+Gibberellic acid 40% WSG 20+2.5
T8 Afidopyropen 5% DC+Gibberellic acid 40% WSG 30+2.5
T9 Fenpyroximate 5% EC+Gibberellic acid 40% WSG 20+2.5
T10 Spiropidion 20% SC+Gibberellic acid 40% WSG 40+2.5
T11 Dimpropyridaz 12% SC+Lambda cyhalothrin 5% EC 75+20
T12 Dimpropyridaz 12% SC+Dinotefuran 20% SG 75+20
T13 Dimpropyridaz 12% SC+Afidopyropen 5% DC 75+30
T14 Dimpropyridaz 12% SC+Fenpyroximate 5% EC 75+20
T15 Dimpropyridaz 12% SC+Spiropidion 20% SC 75+40
T16 Dimpropyridaz 12% SC+Gibberellic acid 40% WSG 75+2.5
T17 Lambda cyhalothrin 5% EC 20
T18 Dinotefuran 20% SG 20
T19 Afidopyropen 5% DC 30
T20 Fenpyroximate 5% EC 20
T21 Spiropidion 20% SC 40
T22 Gibberellic acid 40% WSG 2.5
T23 Dimpropyridaz 12% SC 75
T24 UTC (Untreated Check) 0

T1 to T5-innovative ready mix combinations, T6 to T16- conventional combinations.
Table 6: Control of sucking pests in Okra crop
Treatment Number Sucking pests control (%) at 5 DAA 10 DAA 15 DAA
Obs. Value Exp. Value Ratio O/E Synergism (Y/N)
T1 97.0 86.59 1.12 Y 87.40 73.2
T2 97.6 87.17 1.12 Y 88.20 75.2
T3 98.2 89.10 1.10 Y 90.20 80.2
T4 97.4 85.36 1.14 Y 86.60 72.4
T5 97.8 87.94 1.11 Y 88.80 76.4
T6 60.2 60.31 1.00 N 46.20 34.6
T7 61.4 62.03 0.99 N 49.40 38.6
T8 67.2 67.75 0.99 N 54.20 44.2
T9 56.2 56.69 0.99 N 45.80 35.0
T10 64.0 64.32 1.00 N 55.20 41.2
T11 85.4 85.94 0.99 N 74.20 64.8
T12 86.2 86.55 1.00 N 76.40 65.4
T13 88.0 88.58 0.99 N 77.60 67.4
T14 83.8 84.65 0.99 N 74.40 62.8
T15 86.6 87.36 0.99 N 78.20 66.4
T16 66.8 67.75 0.99 N 56.20 43.2
T17 58.4 48.6 38.2
T18 60.2 52.4 42.4
T19 66.2 58.6 46.6
T20 54.6 48.6 37.4
T21 62.6 56.2 45.2
T22 4.6 2.2 0.4
T23 66.2 58.4 46.6
T24 0.0 0 0.0

All the innovative combinations (T1 to T5) provides synergistic control with residual control control of sucking pests in okra.

Overall summery of field trials:
The field trials results shows many benefits/advantages of ready mix formulations of Dimpropyridaz+Insecticide+biostimulant
• Synergism observed in terms of insect control
• Controls of all major insects pests of crops at a time
• Provides higher level of insect control (increase in % control)
• Provides residual control (longer duration of control), so less number of spray required in a crop cycle
• Increases number of flowers, fruits, branches and overall plant growth
• Visual observations shows phytotonic/greening effect, plant looks greener with increase in overall biomass, plant growth and vigor.
• Increase in yield, may be due to combined effect of pests controls and phyto-tonic effect.
,CLAIMS:CLAIMS
We claim;
[CLAIM 1]. A synergistic insecticidal composition comprising:
a. an insecticide Dimpropyridaz present in amount of 0.01 to 30% w/w;
b. an insecticide selected from class of class of class of pyrethroids, nicotinics, mectins, juvenile hormone mimics, chordotonal organ modulators, mite growth inhibitors, mitochondrial ATP Synthase inhibitors, uncouplers of oxidative phosphorylation, chitin biosysnthesis type-1 inhibitors, moulting disruptors, mitochondrial electron transport inhibitors (METI), lipid synthesis inhibitors, diamides, metadiamides, isoxazolines, compounds of unknown mechanism of action or mixtures thereof present in amount of 0.01 to 50%,
c. a Plant Health Additives selected from biostimulants, plant growth regulators, microbial agents and micronutrients or mixtures thereof present in amount of 0.001 to 20%.
d. inactive formulation excipients.

[CLAIM 2]. The synergistic insecticidal composition as claimed in claim 1, wherein an insecticide from class of pyrethroids are selected from bifenthrin, lambda-cyhalothrin; nicotinics selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid, thiamethoxam, flupyrimin, cycloxaprid, paichongding, guadipyr, cycloxylidin, sulfoxaflor, flupyradifurone, triflumezopyrim, dichloromezotiaz; mectins selected from abamectin, emamectin benzoate; juvenile hormone mimics is pyriproxyfen; chordotonal organ modulators selected from pymetrozine, afidopyropen, flonicamid; mite growth inhibitors selected from hexythiazox, etoxazole; mitochiondrial ATPase synthase inhibitors selected from diafenthiuron, propargite; uncouplers of oxidative phosphorylation is chlorfenapyr; inhibitors of chitin biosynthesis type-1 is buprofezin; moulting disruptors is cyromazine; mitochondrial electron transport inhibitors selected from fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad, tolfenpyrad, flufenerim, rotenone, cyenopyrafen, cyflumetofen, pyflubumidemm, hydramethylnon, acequinocyl, flometoquin, fluacrypyrim, pyriminostrobin or bifenazate; inhibitors of lipid synthesis selected from Tetronic and tetramic acid derivatives-spirodiclofen, spiromesifen, spirotetramat or spiropidion; diamides selected from cyantraniliprole, tyclopyrazoflor; metadiamide is broflanilide; isoxazolines selected from fluxametamide, isocycloseram; compounds with unknown mechanism of action selected from benzpyrimoxan, pyridalyl, flometoquin, fluhexafon, acaricidal compounds-cyetpyrafen, flupentiofenox, acyonapyr

[CLAIM 3]. The synergistic insecticidal composition as claimed in claim 1, wherein plant health additives from biostimulants are selected from humic acid, fulvic acid, amino acids, protein hydrolysates, carboxylic acid, jasmonic acid, chitosan, chitin, seaweed extract (Ascophyllum nodosum), silicyclic acid, silicic acid (Orth silicic acid (H4Si04); from plant growth regulators selected from gibberellic acid (GA3), alpha-naphthyl acetic acid, mepiquat chloride, paclobutrazol, uniconazole-p, chlormequat chloride, trinexapac ethyl, aminoethoxyvinylglycine (AVG), prohexadione calcium, brassinolide, triacontanol, nitrobenzene, nitrophenolate (sodium para-nitrophenolate); from microbial agents selected from zinc (zinc sulphate heptahydrate ZnSO47H2O, zinc sulphate mono hydrate ZnSO4.H2O, chelated zinc as Zn-EDTA, zinc oxide, zinc lactate gluconate, zinc polyflavonoid), boron (borax-sodium tetraborate, boric acid (H3BO3), di-sodium octa borate tetra hydrate (Na2B8O13.4H2O), di-sodium tetra borate penta hydrate, anhydrous borax, ) and sulphur (elemental sulphur, boronated sulphur) or mixture thereof.

[CLAIM 4]. The synergistic insecticidal composition as claimed in claim 1, wherein the formulation for the said composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR).

[CLAIM 5]. The synergistic insecticidal composition as claimed in claim 1-claim 4, wherein the preferred combinations of active ingredients in the composition of the Oil Dispersion (OD) formulation comprises:
i. Dimpropyridaz 7.5% +Afidopyropen 3%+ Brassinolide0.025%;
ii. Dimpropyridaz 8% +Cyantraniliprole 5%+ Amino acid2%;
iii. Dimpropyridaz 7.5% +Afidopyropen 3%+ Amino acid2%;
iv. Dimpropyridaz 8% +Cyantraniliprole 5%+ Fulvic acid2%;
v. Dimpropyridaz 7.5% +Spirotetramat 4%+ Fulvic acid2%;
vi. Dimpropyridaz 7.5% +Spirotetramat 4%+ Brassinolide0.025%;
vii. Dimpropyridaz 8% +Cyantraniliprole 5%+ Brassinolide0.025%;
viii. Dimpropyridaz 7.5% +Afidopyropen 3%+ Triacontanol0.025%;
ix. Dimpropyridaz 7.5% +Spirotetramat 4%+ Triacontanol0.025%;
x. Dimpropyridaz 8% +Cyantraniliprole 5%+ Triacontanol0.025%;
xi. Dimpropyridaz 7.5%+Afidopyropen 3%+ Gibberellic acid 0.25%;
xii. Dimpropyridaz 7.5%+Spirotetramat 4%+ Amino acid 2%;
xiii. Dimpropyridaz 7.5%+Afidopyropen 3%+ Fulvic acid 2%;
xiv. Dimpropyridaz 7.5%+Afidopyropen 3%+ Paclobutrazol 2.5%;
xv. Dimpropyridaz 7.5%+Spirotetramat 4%+ Gibberellic acid 0.25%;
xvi. Dimpropyridaz 8%+Cyantraniliprole 5%+ Gibberellic acid 0.25%;
xvii. Dimpropyridaz 7.5%+Spirotetramat 4%+ Paclobutrazol2.5%;
xviii. Dimpropyrida 7.5%+Spirotetramat 4%+ Zinc lacto gluconate 4%;
xix. Dimpropyridaz 7.5% + Afidopyropen 3% + Mepiquat chloride 3%;
xx. Dimpropyridaz 8 % + Cyantraniliprole 5% +Zinc lacto gluconate4%;
xxi. Dimpropyridaz 7.5% +Afidopyropen3% +Zinc lacto gluconate4%;
xxii. Dimpropyridaz 7.5% +Spirotetramat4% + Mepiquat chloride3%;
xxiii. Dimpropyridaz 8% +Cyantraniliprole5% +Mepiquat chloride3%;
xxiv. Dimpropyridaz 8% +Cyantraniliprole5% +Paclobutrazol2.5%.

[CLAIM 6]. The synergistic insecticidal composition as claimed in claim 1-claim4, wherein, the Oil Dispersion (OD) formulation comprises:
i. an insecticide Dimpropyridaz present in amount of 0.01 to 30% w/w;
ii. an insecticide selected from Afidopyropen, Cyantraniliprole, Spirotetramat present in amount of 0.1 to 50%w/w;
iii. a plant health additive selected from Gibberellic acid, Paclobutrazol, Amino acid, Brassinolide, Fulvic acid, Triacontanol, Zinc lacto gluconate, Mepiquat chloride or mixture thereof present in amount of 0.001 to 20%w/w;
iv. Wetting-spreading-penetrating agent in an amount of 2 to 6 % by weight;
v. Dispersing agent in an amount of 2 to 8 % by weight;
vi. Emulsifying agent in an amount of 6 to 10 % by weight;
vii. Stabilizer in an amount of 0.5 to 4% by weight;
viii. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
ix. Preservative in an amount of 0.1 to 0.5 % by weight;
x. Anti-freezing agent in an amount of 2 to 6 % by weight;
xi. Carrier as solvent in an amount of 40 to 70% by weight.

[CLAIM 7]. The synergistic insecticidal composition as claimed in claim 6, wherein Wetting-spreading-penetrating agent is selected from trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane.

[CLAIM 8]. The synergistic insecticidal composition as claimed in claim 6, wherein emulsifying agent is selected from castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecyl benzene sulphonate, alkyl ammonium salts of alkyl benzene sulphonate, alkyl sulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylene sorbitan monolaurate.

[CLAIM 9]. The synergistic insecticidal composition as claimed in claim 6, wherein dispersing agent is selected from alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkyl phenol alkoxylates, tristyryl phenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploy carboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethylene oxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyryl phenol-poly glycol ether-phosphate, tristyryl phenole with 16 moles EO, tristyryl phenol-poly glycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonyl phenol poly glycol ether with 9-10 moles ethylene oxide.

[CLAIM 10]. The synergistic insecticidal composition as claimed in claim 6, wherein antifoaming agent is selected from silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, poly dimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, poly alkylene oxide modified polydimethylsiloxane.

[CLAIM 11]. The synergistic insecticidal composition as claimed in claim 6, wherein Carrier as solvent or diluting agent is selected from vegetable or plant or seed oil or its alkylated oil or alkylated oil of vegetable oil, alkylated oil (alkylated vegetable oil) may be methylated or ethylated oil of the vegetable oil, wherein vegetable oil are olive oil, kapok oil, castor oil, papaya oil, camellia oil, sesame oil, corn oil, rice bran oil, peanut oil, cotton seed oil, soybean oil, groundnut oil, rapeseed oil, linseed oil, tung oil, sunflower oil, safflower oil, coconut oil, alkyl ester of vegetable oils, (e.g. rapeseed oil methyl ester or rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, neem oil, tall oil fatty acids esters etc.), diesel, mineral oil, fatty acid amides (e.g. C1 -C3 amines, alkylamines or alkanolamines with C6 - Ci8 carboxylic acids), fatty acids, tall oil fatty acids, alkyl esters of fatty acids (e.g. Ci, Methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols or mixture thereof.

[CLAIM 12]. The synergistic insecticidal composition as claimed in claim 6, wherein stabiliser is selected from hectorite clay, aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.

[CLAIM 13]. The synergistic insecticidal composition as claimed in claim 1 and claim 4, wherein preferred combinations of active ingredients in the composition of the Suspo-emulsion (SE) formulation comprises:
i. Dimpropyridaz 7.5% +Abamectin0.75% + Mepiquat chloride3%;
ii. Dimpropyridaz 7.5% +Emamectin benzoate0.75% + Mepiquat chloride3%;
iii. Dimpropyridaz 7.5% +Pyriproxyfen7.5% + Mepiquat chloride3%;
iv. Dimpropyridaz 7.5% +Abamectin0.75% + Paclobutrazol2.5%;
v. Dimpropyridaz 7.5% +Emamectin benzoate0.75% + Paclobutrazol2.5%;
vi. Dimpropyridaz 7.5% +Pyriproxyfen7.5% + Paclobutrazol2.5%;
vii. Dimpropyridaz 7.5% +Abamectin0.75% + Gibberellic acid 0.25%;
viii. Dimpropyridaz 7.5% +Emamectin benzoate0.75% +Gibberellic acid0.25%;
ix. Dimpropyridaz 7.5% +Pyriproxyfen7.5% + Gibberellic acid0.25%;
x. Dimpropyridaz 7.5% +Abamectin0.75% + Zinc lacto gluconate4%;
xi. Dimpropyridaz 7.5% +Emamectin benzoate0.75% + Zinc lacto gluconate4%;
xii. Dimpropyridaz 7.5% +Pyriproxyfen7.5% + Zinc lacto gluconate4%;
xiii. Dimpropyridaz 7.5% +Abamectin0.75% + Brassinolide0.025%;
xiv. Dimpropyridaz 8% +Emamectin benzoate0.75% + Brassinolide0.025%;
xv. Dimpropyridaz 7.5% +Pyriproxyfen7.5% + Brassinolide0.025%;
xvi. Dimpropyridaz 7.5% +Abamectin0.75% + Amino acid2%;
xvii. Dimpropyridaz 8% +Emamectin benzoate0.75% + Amino acid2%;
xviii. Dimpropyridaz 7.5% +Pyriproxyfen7.5%+ Amino acid2%;
xix. Dimpropyridaz 7.5% +Abamectin0.75% + Triacontanol0.025%;
xx. Dimpropyridaz 7.5% +Emamectin benzoate0.75%+ Triacontanol 0.025% ;
xxi. Dimpropyridaz 7.5% +Pyriproxyfen7.5%+ Triacontanol0.025%;
xxii. Dimpropyridaz 7.5% +Abamectin0.75%+ Fulvic acid2%;
xxiii. Dimpropyridaz 7.5% +Emamectin benzoate0.75%+ Fulvic acid2%;
xxiv. Dimpropyridaz 7.5% +Pyriproxyfen7.5%+ Fulvic acid2%.

[CLAIM 14]. The synergistic insecticidal composition as claimed in claim 1 and claim 3 wherein, the Suspo-emulsion (SE) formulation comprises:
i. an insecticide Dimpropyridaz present in amount of 0.01 to 30% w/w;
ii. an insecticide selected from Abamectin, Emamectin benzoate, Pyriproxyfen present in amount of 0.1 to 50%w/w;
iii. a plant health additive selected from Gibberellic acid, Paclobutrazol, Amino acid, Brassinolide, Fulvic acid, Triacontanol, Zinc lacto gluconate, Mepiquat chloride or mixture thereof present in amount of 0.001 to 20%w/w;
iv. Solvent in an amount of 8 to 12 % by weight;
v. Wetting-spreading-penetrating agent in an amount of 2 to 6 % % by weight;
vi. Dispersing agent 1 in an amount of 2 to 8 % by weight;
vii. Dispersing agent 2 in an amount of 1 to 3 % by weight;
viii. Suspending agent in an amount of 0.2 to 4.0 % by weight;
ix. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
x. Preservative in an amount of 0.1 to 0.5 % by weight;
xi. Antifreezing agent in an amount of 2 to 6 % by weight;
xii. Thickener in an amount of 0.1 to 1.0 % by weight;
xiii. Diluent Water in an amount of 40 to 70 % by weight.

[CLAIM 15]. The synergistic insecticidal composition as claimed in claim 14, wherein Emulsifier is selected from salts of dodecyl benzene sulphonate, Ca-salts or amine salts, and sulphonates of other C11-C16 alkyl benzenes, alkyl ether sulphates, alkyl phenol ether phosphates and ester phosphates; non-ionic surfactants such as alkoxylated alcohols and alkyl phenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid esters, e.g. of sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; and catanionic emulsifiers such as a cationic amine, optionally in combination with an alkyl sulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkyl phenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol; fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkyl benzenes in the range C11-C16 and salts thereof; alkyl ether sulphates; alkyl ether phosphates; alkyl phenol ether phosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenol; or a catanionic system, wherein a cationic amine is present in combination with an alkyl sulphonate, an alkyl ether sulphonate, an ether sulphate, or an ether phosphate such as an alkyl ether phosphate, nonyl phenol poly ethoxy ethanols, castor oil polyglycol ethers, poly adducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol.

[CLAIM 16]. The synergistic insecticidal composition as claimed in claim 14, wherein Stabilizer is selected from butylated hydroxy toluene (BHT) and epoxidized soybean oil (ESBO), Epichlorhydrin.

[CLAIM 17]. The synergistic insecticidal composition as claimed in claim 14, wherein dispersing agent is selected from polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylic polymers and copolymers, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol, vinylacetate and vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins and define copolymers and mixtures thereof, preferred polymers are acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly (styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these, biodegradable polymers, biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxy-butyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof. The examples of dispersing agents are alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide

[CLAIM 18]. The synergistic insecticidal composition as claimed in claim 14, wherein buffering agent is selected from as used herein is selected from group consisting of calcium hydroxyapatite, Potassium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.

[CLAIM 19]. The synergistic insecticidal composition as claimed in claim 14, wherein Wetting-spreading-penetrating agent is selected from Organo silicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof.

[CLAIM 20]. The synergistic insecticidal composition as claimed in claim 14, wherein suspending agent is selected from aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.

[CLAIM 21]. The synergistic insecticidal composition as claimed in claim 1 and claim 3, wherein preferred combinations of active ingredients in the composition of the Suspension Concentrate (SC) formulation comprises:
i. Dimpropyridaz 7.5% + Clothianidin 2% + Fulvic acid 2%;
ii. Dimpropyridaz7.5% + Dinotefuran 2% + Fulvic acid 2%;
iii. Dimpropyridaz15% + Hexythiazox4% + Fulvic acid 2%;
iv. Dimpropyridaz15% + Etoxazole4% + Fulvic acid 2%;
v. Dimpropyridaz7.5% + Diafenthiuron20% + Fulvic acid2%;
vi. Dimpropyridaz15% + Fenpyroximate4% + Fulvic acid2%;
vii. Dimpropyridaz7.5% + Spirodiclofen10% + Fulvic acid 2%;
viii. Dimpropyridaz7.5% + Spiromesifen10% + Fulvic acid2%;
ix. Dimpropyridaz7.5% + Spiropidion4% + Fulvic acid 2%;
x. Dimpropyridaz8% + Chlorantraniliprole2.5% + Fulvic acid 2% ;
xi. Dimpropyridaz8% + Tetraniliprole4% + Fulvic acid2%;
xii. Dimpropyridaz8% + Tyclopyrazoflor5% + Fulvic acid2%;
xiii. Dimpropyridaz8% + Broflanilide1% + Fulvic acid2%;
xiv. Dimpropyridaz7.5% + Benzpyrimoxan5% + Fulvic acid2%;
xv. Dimpropyridaz7.5% + Tolfenpyrad7.5% + Fulvic acid2%;
xvi. Dimpropyridaz7.5% + Clothianidin2% + Amino acid2%;
xvii. Dimpropyridaz7.5% + Dinotefuran2% + Amino acid2%;
xviii. Dimpropyridaz15% + Hexythiazox4% + Amino acid2%;
xix. Dimpropyridaz15% + Etoxazole4% + Amino acid2%;
xx. Dimpropyridaz7.5% + Diafenthiuron20% + Amino acid2%;
xxi. Dimpropyridaz15% + Fenpyroximate4% + Amino acid2%;
xxii. Dimpropyridaz7.5% + Spirodiclofen10% + Amino acid2%;
xxiii. Dimpropyridaz7.5% + Spiromesifen10% + Amino acid2%;
xxiv. Dimpropyridaz7.5% + Spiropidion4% + Amino acid2%;
xxv. Dimpropyridaz8% + Chlorantraniliprole2.5% + Amino acid 2%;
xxvi. Dimpropyridaz8% +Tetraniliprole4% + Amino acid2%;
xxvii. Dimpropyridaz8% + Tyclopyrazoflor5% + Amino acid2%;
xxviii. Dimpropyridaz8% + Broflanilide1% + Amino acid2%;
xxix. Dimpropyridaz7.5% + Benzpyrimoxan5% + Amino acid2%;
xxx. Dimpropyridaz7.5% + Tolfenpyrad7.5 + Amino acid2%;
xxxi. Dimpropyridaz7.5% + Clothianidin 2% + Brassinolide 0.025%;
xxxii. Dimpropyridaz7.5% + Dinotefuran2% + Brassinolide0.025%;
xxxiii. Dimpropyridaz15% + Hexythiazox4% + Brassinolide 0.05%;
xxxiv. Dimpropyridaz15% + Etoxazole4% + Brassinolide0.05%;
xxxv. Dimpropyridaz7.5% +Diafenthiuron20% + Brassinolide 0.025%;
xxxvi. Dimpropyridaz15% + Fenpyroximate4% + Brassinolide 0.05%;
xxxvii. Dimpropyridaz7.5% + Spirodiclofen10% + Brassinolide 0.025%;
xxxviii. Dimpropyridaz7.5% + Spiromesifen10% + Brassinolide 0.025%;
xxxix. Dimpropyridaz7.5% + Spiropidion4% + Brassinolide0.025%;
xl. Dimpropyridaz8% + Chlorantraniliprole2.5%+ Brassinolide 0.025%;
xli. Dimpropyridaz 8% + Tetraniliprole 4% + Brassinolide 0.025%;
xlii. Dimpropyridaz8% + Tyclopyrazoflor5% + Brassinolide 0.025%;
xliii. Dimpropyridaz8% + Broflanilide1% + Brassinolide 0.025%;
xliv. Dimpropyridaz7.5% + Benzpyrimoxan5% + Brassinolide 0.025%;
xlv. Dimpropyridaz7.5% +Tolfenpyrad7.5% + Brassinolide 0.025%;
xlvi. Dimpropyridaz7.5% +Clothianidin2% + Triacontanol0.025%;
xlvii. Dimpropyridaz7.5% + Dinotefuran2% + Triacontanol 0.025%;
xlviii. Dimpropyridaz15% + Hexythiazox4% + Triacontanol0.05%;
xlix. Dimpropyridaz15% + Etoxazole4% + Triacontanol0.05%;
l. Dimpropyridaz7.5% + Diafenthiuron20% + Triacontanol 0.025%;
li. Dimpropyridaz15% + Fenpyroximate4% + Triacontanol 0.05%;
lii. Dimpropyridaz7.5% + Spirodiclofen10% + Triacontanol 0.025%;
liii. Dimpropyridaz7.5% + Spiromesifen10% + Triacontanol 0.025%;
liv. Dimpropyridaz7.5% + Spiropidion4% + Triacontanol0.025%;
lv. Dimpropyridaz8% + Chlorantraniliprole 2.5% + Triacontanol 0.025%;
lvi. Dimpropyridaz8% + Tetraniliprole4% + Triacontanol0.025%;
lvii. Dimpropyridaz8% + Tyclopyrazoflor5% + Triacontanol 0.025%;
lviii. Dimpropyridaz8% + Broflanilide1% + Triacontanol0.025%;
lix. Dimpropyridaz7.5% + Benzpyrimoxan5% + Triacontanol 0.025%;
lx. Dimpropyridaz7.5% + Tolfenpyrad7.5% + Triacontanol 0.025%;
lxi. Dimpropyridaz7.5% + Clothianidin2% + Paclobutrazol2.5%;
lxii. Dimpropyridaz7.5% + Dinotefuran2% + Paclobutrazol2.5%;
lxiii. Dimpropyridaz15% + Hexythiazox4% + Paclobutrazol5%;
lxiv. Dimpropyridaz15% + Etoxazole4% + Paclobutrazol5%;
lxv. Dimpropyridaz7.5% + Diafenthiuron 20% + Paclobutrazol 2.5%;
lxvi. Dimpropyridaz15% + Fenpyroximate4% + Paclobutrazol5%;
lxvii. Dimpropyridaz7.5% + Spirodiclofen10% + Paclobutrazol 2.5%;
lxviii. Dimpropyridaz7.5% + Spiromesifen10% + Paclobutrazol2.5%;
lxix. Dimpropyridaz7.5% + Spiropidion4% + Paclobutrazol2.5%;
lxx. Dimpropyridaz8% + Chlorantraniliprole 2.5% + Paclobutrazol 2.5%;
lxxi. Dimpropyridaz8% + Tetraniliprole4% + Paclobutrazol2.5%;
lxxii. Dimpropyridaz8% + Tyclopyrazoflor5% + Paclobutrazol 2.5%;
lxxiii. Dimpropyridaz8% + Broflanilide1% + Paclobutrazol2.5%;
lxxiv. Dimpropyridaz7.5% + Benzpyrimoxan5% + Paclobutrazol2.5%;
lxxv. Dimpropyridaz7.5% + Tolfenpyrad7.5% + Paclobutrazol 2.5%;
lxxvi. Dimpropyridaz7.5% + Clothianidin2% + Gibberellic acid 0.25%;
lxxvii. Dimpropyridaz7.5% + Dinotefuran2% + Gibberellic acid 0.25%;
lxxviii. Dimpropyridaz15% + Hexythiazox4% + Gibberellic acid 0.5%;
lxxix. Dimpropyridaz15% + Etoxazole4% + Gibberellic acid0.5%;
lxxx. Dimpropyridaz7.5% +Diafenthiuron20% + Gibberellic acid 0.25%;
lxxxi. Dimpropyridaz15% + Fenpyroximate4% + Gibberellic acid0.5%;
lxxxii. Dimpropyridaz7.5% + Spirodiclofen10% + Gibberellic acid0.25%;
lxxxiii. Dimpropyridaz7.5% + Spiromesifen 10% + Gibberellic acid 0.25%;
lxxxiv. Dimpropyridaz7.5% + Spiropidion 4% + Gibberellic acid 0.25%;
lxxxv. Dimpropyridaz8% + Chlorantraniliprole2.5% + Gibberellic acid 0.25%;
lxxxvi. Dimpropyridaz8% + Tetraniliprole4% + Gibberellic acid 0.25%;
lxxxvii. Dimpropyridaz8% + Tyclopyrazoflor5% + Gibberellic acid 0.25%;
lxxxviii. Dimpropyridaz8% + Broflanilide1% + Gibberellic acid 0.25%;
lxxxix. Dimpropyridaz7.5% + Benzpyrimoxan5% + Gibberellic acid 0.25%;
xc. Dimpropyridaz7.5% + Tolfenpyrad7.5% + Gibberellic acid 0.25%;
xci. Dimpropyridaz7.5% + Clothianidin2% + Mepiquat chloride 3%;
xcii. Dimpropyridaz7.5% + Dinotefuran2% + Mepiquat chloride 3%;
xciii. Dimpropyridaz15% + Hexythiazox4% + Mepiquat chloride 6%;
xciv. Dimpropyridaz15% + Etoxazole4% + Mepiquat chloride6%;
xcv. Dimpropyridaz7.5% + Diafenthiuron 20% + Mepiquat chloride 3%;
xcvi. Dimpropyridaz15% + Fenpyroximate4% + Mepiquat chloride 6%;
xcvii. Dimpropyridaz7.5% + Spirodiclofen 10% + Mepiquat chloride 3%;
xcviii. Dimpropyridaz7.5% + Spiromesifen 10% + Mepiquat chloride 3%;
xcix. Dimpropyridaz7.5% + Spiropidion 4% + Mepiquat chloride 3%;
c. Dimpropyridaz8% + Chlorantraniliprole2.5% + Mepiquat chloride 3%;
ci. Dimpropyridaz 8% + Tetraniliprole 4% + Mepiquat chloride 3%;
cii. Dimpropyridaz 8% + Tyclopyrazoflor5% + Mepiquat chloride3%;
ciii. Dimpropyridaz 8% + Broflanilide1% + Mepiquat chloride3%;
civ. Dimpropyridaz 7.5% +Benzpyrimoxan5% + Mepiquat chloride 3%;
cv. Dimpropyridaz 7.5% + Tolfenpyrad 7.5% + Mepiquat chloride 3%;
cvi. Dimpropyridaz 7.5% + Clothianidin 2% + Zinc lacto gluconate4%;
cvii. Dimpropyridaz 7.5% + Dinotefuran 2% + Zinc lacto gluconate 4%;
cviii. Dimpropyridaz 15% + Hexythiazox 4% + Zinc lacto gluconate 8%;
cix. Dimpropyridaz 15% + Etoxazole 4% + Zinc lacto gluconate 8%;
cx. Dimpropyridaz 7.5% + Diafenthiuron20% + Zinc lacto gluconate 4%;
cxi. Dimpropyridaz 15% + Fenpyroximate4% + Zinc lacto gluconate 8%;
cxii. Dimpropyridaz 7.5% + Spirodiclofen10% + Zinc lacto gluconate 4%;
cxiii. Dimpropyridaz 7.5% + Spiromesifen10% + Zinc lacto gluconate 4%;
cxiv. Dimpropyridaz 7.5% + Spiropidion 4% + Zinc lacto gluconate 4%;
cxv. Dimpropyridaz 8% + Chlorantraniliprole2.5% + Zinc lacto gluconate 4%;
cxvi. Dimpropyridaz 8% + Tetraniliprole4%+ Zinc lacto gluconate 4%;
cxvii. Dimpropyridaz 8% + Tyclopyrazoflor5% + Zinc lacto gluconate 4%;
cxviii. Dimpropyridaz 8% + Broflanilide1% + Zinc lacto gluconate 4%;
cxix. Dimpropyridaz 7.5% + Benzpyrimoxan5% + Zinc lacto gluconate 4%;
cxx. Dimpropyridaz 7.5% + Tolfenpyrad 7.5% + Zinc lacto gluconate 4%.

[CLAIM 22]. The synergistic insecticidal composition as claimed in claim 1 and claim 12, wherein the Suspension Concentrate (SC) formulation comprises:
i. an insecticide Dimpropyridaz present in amount of 0.01 to 30% w/w;
ii. an insecticide selected from Clothianidin, Dinotefuran, Hexythiazox, Etoxazole, Diafenthiuron, Fenpyroximate, Spirodiclofen, Spiromesifen, Spiropidion, Chlorantraniliprole, Tetraniliprole, Tyclopyrazoflor, Broflanilide, Benzpyrimoxan, Tolfenpyrad, Spirodiclofen, Spiromesifen, Spiropidion, Chlorantraniliprole, Tetraniliprole, Tyclopyrazoflor, Broflanilide, Benzpyrimoxan, Tolfenpyrad present in amount of 0.1 to 50%w/w;
iii. a plant health additive selected from Gibberellic acid, Paclobutrazol, Amino acid, Brassinolide, Fulvic acid, Triacontanol, Zinc lacto gluconate, Mepiquat chloride or mixture thereof present in amount of 0.001 to 20%w/w;
iv. an insecticide selected from various class present in amount of 0.1% - 40% by weight of the composition is selected from Afidopyropen, Dimpropyridaz, Methoxyfenozide, Emamectin benzoate, Diafenthiuron, Pyrifluquinazon or Flupyrimin;
v. Wetting-spreading-penetrating agent in an amount of 2 to 6 % by weight;
vi. Dispersing agent 1 in an amount of 2 to 8 % by weight;
vii. Dispersing agent 2 in an amount of 1to 3 % by weight;
viii. Suspending agent in an amount of 0.2 to 4.0 % by weight;
ix. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
x. Preservative in an amount of 0.1 to 0.5 % by weight;
xi. Antifreezing agent in an amount of 2 to 6 % by weight;
xii. Thickner in an amount of 0.1 to 1.0 % by weight;
xiii. Diluent Water in an amount of 40 to 70 % by weight.

[CLAIM 23]. The synergistic insecticidal composition as claimed in claim 22, wherein Wetting-spreading-penetrating agent is selected from Organo silicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof.

[CLAIM 24]. The synergistic insecticidal composition as claimed in claim 22, wherein dispersing agent is selected from alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethylene oxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyryl phenol-polyglycol ether-phosphate, tristyryl phenole with 16 moles EO, tristyryl phenol-polyglycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonylphenol polyglycol ether with 9-10 moles ethylene oxide.

[CLAIM 25]. The synergistic insecticidal composition as claimed in claim 22, wherein suspending agent is selected from aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.

[CLAIM 26]. The synergistic insecticidal composition as claimed in claim 22, wherein anti-freezing agent is selected from ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.

[CLAIM 27]. The synergistic insecticidal composition as claimed in claim 1 and claim 4, wherein preferred combinations of active ingredients in the composition of the Water Dispersible Granules (WG) formulation comprises:
i. Dimpropyridaz 15% +Pymetrozine 10%+Gibberellic acid 0.5%;
ii. Dimpropyridaz 15% +Pymetrozine 10%+Triacontanol 0.05%;
iii. Dimpropyridaz 15% +Flonicamid 8%+Triacontanol 0.05%;
iv. Dimpropyridaz 15% +Flonicamid 8%+Gibberellic acid 0.5%;
v. Dimpropyridaz 15% +Flonicamid 8%+Paclobutrazol 5%;
vi. Dimpropyridaz 15% +Flonicamid 8%+Amino acid 4%;
vii. Dimpropyridaz 15% +Pymetrozine 10%+Fulvic acid 4%;
viii. Dimpropyridaz 15% +Flonicamid 8%+Fulvic acid 4%;
ix. Dimpropyridaz 15% +Pymetrozine 10%+Amino acid 4%;
x. Dimpropyridaz 15% +Pymetrozine 10%+Brassinolide 0.05%;
xi. Dimpropyridaz 15% +Flonicamid 8% +Brassinolide 0.05%;
xii. Dimpropyridaz 15% +Pymetrozine 10% +Mepiquat chloride 6%;
xiii. Dimpropyridaz 15% +Pymetrozine10% +Paclobutrazol 5%;
xiv. Dimpropyridaz 15% +Flonicamid8% +Mepiquat chloride 6%;
xv. Dimpropyridaz 15% +Pymetrozine10% +Zinc lacto gluconate 8%;
xvi. Dimpropyridaz 15% +Flonicamid8% +Zinc lacto gluconate 8%.

[CLAIM 28]. The synergistic insecticidal composition as claimed in claim 1 and claim 3 wherein, the Water Dispersible Granules (WG) formulation comprises:
i. an insecticide Dimpropyridaz present in amount of 0.01 to 30% w/w;
ii. an insecticide selected from Pymetrozine, Flonicamid present in amount of 0.1 to 50%w/w;
iii. a plant health additive selected from Gibberellic acid, Paclobutrazol, Amino acid, Brassinolide, Fulvic acid, Triacontanol, Zinc lacto gluconate, Mepiquat chloride or mixture thereof present in amount of 0.001 to 20%w/w;
iv. Wetting-spreading-penetrating agent in an amount of 2 to 8 % by weight;
v. Dispersing agent I in an amount of 2 to 8 % by weight;
vi. Dispersing agent II in an amount of 1 to 5 % by weight;
vii. Disintegrating agent in an amount of 0.2 to 0.8 % by weight;
viii. Antifoaming agent in an amount of 0.1 to 1.5 % by weight;
ix. Carrier in an amount of 30 to 80 % by weight.

[CLAIM 29]. The synergistic insecticidal composition as claimed in claim 28, wherein dispersing agent is selected from alkylnaphthalene sulfonate sodium salt, sodium polycarboxylate, naphthalene sulfonic acid, sodium salt condensates with formaldehyde, polyalcoxylated alkylphenol, naphthalene sulfonic acid formaldehyde condensate, methyl naphthalene-formaldehyde-condensate sodium salt, naphthalene condensates, lignosulfonates, polyacrylates and phosphate esters, calcium lignosulfonate, lignin sulfonate sodium salt.

[CLAIM 30]. The synergistic insecticidal composition as claimed in claim 28, wherein Wetting-spreading-penetrating agent is selected from Organo silicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof etc.

[CLAIM 31]. The synergistic insecticidal composition as claimed in claim 28, wherein Antifoaming agent is polydimethylsiloxane.

[CLAIM 32]. The synergistic insecticidal composition as claimed in claim 28, wherein carrier is selected from china clay, silica, lactose anhydrous, ammonium sulfate, sodium sulfate anhydrous, corn starch, urea, EDTA, urea formaldehyde resin, diatomaceous earth, kaolin, bentonite, kieselguhr, fuller's earth, attapulgite clay, bole, loess, talc, chalk, dolomite, limestone, lime, calcium carbonate, powdered magnesia, magnesium oxide, magnesium sulphate, sodium chloride, gypsum, calcium sulphate, pyrophyllite, silicates and silica gels; fertilizers such as, for example, ammonium sulphate, ammonium phosphate, ammonium nitrate and urea; natural products of vegetable origin such as, for example, grain meals and flours, bark meals, wood meals, nutshell meals and cellulosic powders; and synthetic polymeric materials such as, for example, ground or powdered plastics and resins, bentonites, zeolites, titanium dioxide, iron oxides and hydroxides, aluminium oxides and hydroxides, or organic materials such as bagasse, charcoal, or synthetic organic polymers.

[CLAIM 33]. The synergistic insecticidal composition as claimed in claim 28, wherein Disintegrating agent is selected from citric acid, succinic acid or the sodium bicarbonate.

[CLAIM 34]. The synergistic insecticidal composition as claimed in claim 1 and claim 4, wherein preferred combinations of active ingredients in the composition of the Zeon Concentrate (ZC) formulation comprises:
i. Dimpropyridaz 7.5%+Lambda cyhalothrin2% + Mepiquat chloride 3%;
ii. Dimpropyridaz 7.5%+Lambda cyhalothrin2% + Triacontanol 0.025%;
iii. Dimpropyridaz 7.5%+Lambda cyhalothrin2% + Fulvic acid 2%;
iv. Dimpropyridaz 7.5%+Lambda cyhalothrin2% + Brassinolide 0.025%;
v. Dimpropyridaz 7.5%+Lambda cyhalothrin2% + Amino acid 2%;
vi. Dimpropyridaz 7.5%+Lambda cyhalothrin2% + Gibberellic acid 0.25%;
vii. Dimpropyridaz 7.5%+Lambda cyhalothrin2% + Paclobutrazol 2.5%;
viii. Dimpropyridaz 7.5%+Lambda cyhalothrin2% + Zinc lacto gluconate 4%.

[CLAIM 35]. The synergistic insecticidal composition as claimed in claim 1 and claim 3 wherein, the Zeon Concentrate (ZC) comprises:
i. an insecticide Dimpropyridaz present in amount of 0.01 to 30% w/w;
ii. an insecticide selected from Lambda cyhalothrin present in amount of 0.1 to 50%w/w;
iii. a plant health additive selected from Gibberellic acid, Paclobutrazol, Amino acid, Brassinolide, Fulvic acid, Triacontanol, Zinc lacto gluconate, Mepiquat chloride or mixture thereof present in amount of 0.001 to 20%w/w;
iv. Wetting-spreading-penetrating agent in an amount of 2 to 6 % by weight;
v. Dispersing agent 1 in an amount of 2 to 8 % by weight;
vi. Dispersing agent 2 in an amount of 1to 3 % by weight;
vii. Solvent in an amount of 6 to 10 % by weight;
viii. Wall forming material 1 in an amount of 0.1 to 3 % by weight;
ix. Wall forming material 2 in an amount of 0.1 to 2 % by weight;
x. Suspending agent in an amount of 1 to 3 % by weight;
xi. Antifoaming agent in an amount of 0.1 to 1.0 % by weight;
xii. Buffering agent in an amount of 0.1 to 2.0 % by weight;
xiii. Preservative in an amount of 0.05 to 1.0 % by weight;
xiv. Antifreezing agent in an amount of 4 to 8 % by weight;
xv. Thickner in an amount of 0.05 to 2.0 % by weight;
xvi. Diluent Water in an amount of 40 to 70 % by weight

[CLAIM 36]. The synergistic insecticidal composition as claimed in claim 35, wherein wall forming material 1 is selected from Tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, toluene diisocyanate, diphenylmethene-4,4’-diisocyanate, polymethylene polyphenylene isocyanate, 2,4,4’-diphenyl ether tri-isocyanate, 3,3’-dimethyl-4,4’-diphenyl diisocyanate, 3,3’-dimethoxy-4,4’-diphenyl diisocyanate, 1,5-naphthylene diisocyanate and 4,4’4"-triphenylmethane tri-isocyanate, toluene diisocyanate or polymethylene polyphenylisocyanate, polyurethane comprising of polyfunctional iso cyanate and a polyamine in polarized form; and wall forming material 2 is selected from Ammonia, hexamine, ethylenediamine, propylene-1,3-diamine, tetramethylenediamine, pentamethylenediamine, 1,6-hexamethylenediamine, diethylenetriamine, triethylenetetramine, tetra ethylene pentamine, pentaethylenehexamine, 4,9-dioxadodecane-1, 12-diamine, 1,3- phenylenediamine, 2,4- and 2,6-toluenediamine and 4,4’-diaminodiphenylmethane, 1,3-phenylenediamine, 2,4- and 2,6-toluenediamine, 4,4'-diaminodiphenylmethane, 1,5-diaminonaphthalene, 1,3,5-triaminobenzene, 2,4,6-triaminotoluene, 1,3,6-triaminonaphthalene, 2,4,4'-triaminodiphenyl ether, 3,4,5-triamino-1,2,4-triazole and 1,4,5,8-tetraminoanthraquinone.

[CLAIM 37]. The synergistic insecticidal composition as claimed in claim 35, wherein Wetting-spreading-penetrating agent is selected from Organo silicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof etc.

[CLAIM 38]. The synergistic insecticidal composition as claimed in claim 28, wherein solvent is selected from Hydrocarbon solvent such a an aliphatic, cyclic and aromatic hydrocarbons (e.g. toluene, xylene, paraffin, tetrahydronaphthalene, alkylated naphthalene or their derivatives, mineral oil fractions of medium to high boiling point (such as kerosene, diesel oil, coal tar oils)); a vegetable oil such as corn oil, rapeseed oil; a fatty acid ester such as C1-C10-alkylester of a C10-C22-fatty acid; or, methyl- or ethyl esters of vegetable oils such as rapeseed oil methyl ester or corn oil methyl ester, acetophenone, 2-Heptanon , 3-heptanone, 2-hexanone, 5-methyl-2-hexanone , 5-methyl-3-heptanone, 3-methyl-2-hexanone , 4-methyl-2-hexanone, 2-methyl-3-hexanone, 4-methyl-3-hexanone , 5-methyl-3-hexanone , 3-ethyl-2-pentanone , 3,3-dimethyl-2-pentanone , 3,4-dimethyl-2-pentanone, 4,4-dimethyl-2-pentanone , 2,2-dimethyl-3-pentanone , 2,4-dimethyl-3-pentanone, 2-octanone , 2,5-dimethyl-3-hexanone , 2,2-dimethyl-3-hexanone , 3,3-dimethyl-2-hexanone, 3,4-dimethyl-2-hexanone, 4,4-dimethyl-3-hexanone , 3-ethyl-4-methyl-2-pentanone , 2-methyl-3-heptanone, 2-methyl-4-heptanone, 3-methyl-2-heptanone, 3-methyl-4-heptanone, 5-methyl-3-heptanone, 6-methyl-2-heptanone , 6-methyl-3-heptanone, 3-octanone, 4-octanone, 2,2,4-trimethyl-3-pentanone , 3-ethyl-3-methyl-2-pentanone, 5-methyl-2-heptanone, isoprene.

Dated this 20th day of Septemeber 2021.