FIELD OF THE INVENTION:

The present invention relates to synergistic pesticidal compositions comprising bioactive amounts of (A) Tolfenpyrad; (B) an insecticide selected from class of diamide, metadiamide, isoxazoline or mixtures thereof; (C) at least one insecticide selected from chordotonal organ modulators or mixture thereof. The present invention further relates to process of preparing said composition along with at least one inactive excipients and formulation thereof.
BACKGROUND OF THE INVENTION:
Combination of insecticides and chordotonal organ modulators are used to broaden the spectrum of control of insect to improve the pest control with synergistc effect, reduce dosage, thereby reducing environmental impact, to broaden the spectrum of control, i.e. chewing and sucking insects at a time, decrease chances of resistance development and to enhance residual control so lesser the number of sprays for crop protections and minimizing the pesticidal load in ecosystem. The combination of insecticides at times demonstrate an additive or synergistic effect that results in an improved control on the pests.
Insecticide or pesticides are used widely and very frequently in commercial agriculture and have enabled an enormous increase in crop yields and product quality which ultimately increased the ease to farmers in term of economic advantage as well as ease of farming activities.
There are many combinations of insecticide along with chordotonal organ modulators known in the art for the control of pests.
IN201621004267 relates to an insecticidal composition comprising Tolfenpyrad and an insecticide selected from, Pymetrozine, and Fenpyroximate. The present invention also relates to process for preparing the said composition comprising of bioactive amounts of Tolfenpyrad and an insecticide along with one or more inactive excipients.
IN201721003731 relates to an insecticidal formulation comprising Afidopyropen and one more insecticide selected from Diafenthiuron, Pyriproxyfen, Tolfenpyrad and

Acephate with one or more inactive excipient wherein the ratio of Afidopyropen and one more insecticide selected from Diafenthiuron, Pyriproxyfen, Tolfenpyrad and Acephate is 1:50 to 10:1.
CN102726410 relates to method to control striped flea-beetle for one kind, it is characterized in that the preparation that contains Rynaxypyr (Chlorantraniliprole) and Tolfenpyrad to act on plant seed, the weight ratio of described Rynaxypyr and Tolfenpyrad is 1:20-20:1; and described preparation formulation is selected from missible oil, suspending agent, seed coat agent, water dispersible granules, wetting powder, suspension emulsion, extrudes granule, coated granule, aerosol, aqueous emulsion.
CN106614607 relates to a kind of insecticides containing Tolfenpyrad and bromine cyanogen insect amide, it is characterised in that : By active ingredient Tolfenpyrad, Bromine cyanogen insect amide and auxiliary material component are constituted, and the mass ratio of Tolfenpyrad and bromine cyanogen insect amide is 80:1-1:80; and the formulation of the insecticides is breast Oil, suspending agent, water-dispersible granules, wettable powder, aqueous emulsion, micro-capsule suspension.
There is however a need for improvement of these combinations. Single active combinations used over a long period of time has resulted in resistance. With the onset of resistance to certain pests, there is a need in the art for a combination of actives that decreases chances of resistance and improves the spectrum of pest control, and enhance the residual control.
However still there is a need for a composition comprises Tolfenpyrad; an insecticide selected from class of diamide, metadiamide and isoxazoline or mixtures thereof; and at least one insecticide selected from chordotonal organ modulators, which overcomes some of the existing problems and can be prepared easily without much complex manufacturing process.
In general use, the pesticide actives are used in the form of a dilute aqueous composition because it can attain a good interaction with the target organism, such as plants and insects. However, most active pesticide compounds that are used as pesticides are only sparingly or even insoluble in water. The low solubility of such compounds present the challenges and difficulties to formulator in formulating pesticide compounds in stable formulations that can be easily stored for a long time and which still have a high stability

and effective activity until end use. This problem especially occurs and may get worsen if more than one active compound is present in the composition.
Most pesticides are applied at low rate which makes it difficult for the user to apply uniformly in the field conditions. Many pesticides are unstable in terms of their active ingredients. There are frmulations unable to put together more than one active ingredients in a stable firm which is helful to the growers to apply them uniformly in the field conditions.
Therefore, one object of the present invention is to provide improved combinations of 3 different insecticides with different mode of action for the control of chewing, sucking and piercing type insects, Foliage feeder and soil hibernating insects for which there is no insecticide which can overcome these problems.
Yet another object of the present invention is to provide improved combinations of three different insecticides that promote plant health.
Embodiment of the present invention can ameliorate one or more of the above-mentioned problems.
Inventors of the present invention have surprisingly found that the novel synergistic pesticidal composition of Tolfenpyrad; an insecticide selected from diamde, metadiamide and isoxazoline or mixtures thereof and insecticides selected from class of chordotonal organs modulators or mixture thereof; which can provide solution to the above-mentioned problems.
SUMMARY OF THE INVENTION
Therefore, an aspect of the present invention provides a synergistic pesticidal compositions comprising bioactive amounts of (A) Tolfenpyrad; (B) an insecticide selected from class of diamde, metadiamide and isoxazoloines or mixtures thereof; (C) at least one insecticide selected from class of chordotonal organ modulators or mixture thereof.
Further aspect of the present invention provides a synergistic pesticidal composition comprising bioactive amounts of (A) Tolfenpyrad; (B) an insecticide selected from

diamide like chlorantraniliprole, cyantraniliprole, cyclaniliprole, cyproflanilide, tetrachlorantraniliprole, tyclopyrazoflor, cyhalodiamide, flubendiamide, tetraniliprole or mixture thereof; metadiamide such as broflanilide; isoxazoline like fluxametamide, isocycloseram or mixtures thereof (C) at least one more insecticide selected from the class of chordotonal organ modulators like are afidopyropen, flonicamid, pymetrozine or pyrifluquinazon or mixture thereof.
Accordingly, in a further aspect, the present invention provides a method of protecting a plant propagation material, a plant, parts of a plant and/or plant organs that grow at a later point in time against insect-pests and mite damage or pest damage by applying to the plant propagation material a composition comprising a pesticidal composition defined in the first aspect.
As per one embodiment formulation for the pesticidal composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR); and and one or more customary formulation adjuvants such as a) dispersant b) wetting agent c) anti-foaming agent d) biocides e) anti-freezing agent f) suspending agent g) thickener h) coating agent and i) buffering agent.
The remainder of the aqueous formulation is preferably wholly water but may comprise other materials, such as inorganic salts. The formulation is preferably, with lower amount or completely free from organic solvents.
Accordingly, in a first aspect, the present invention provides a synergistic pesticidal
compositions comprising bioactive amounts of (A) Tolfenpyrad; (B) an insecticide
selected from diamide like chlorantraniliprole, cyantraniliprole, cyclaniliprole,
cyproflanilide, tetrachlorantraniliprole, tyclopyrazoflor, cyhalodiamide,

flubendiamide, tetraniliprole or mixture thereof; metadiamide such as broflanilide; isoxazoline like fluxametamide, isocycloseram or mixtures thereof (C) at least one more insecticide selected from the class of chordotonal organ modulators like are afidopyropen, flonicamid, pymetrozine or pyrifluquinazon or mixture thereof; and one or more customary formulation adjuvants; shows synergistic activity.
DETAILED DESCRIPTION OF THE INVENTION:
The term "synergistic", as used herein, refers the combined action of three or more active agents blended together and administered conjointly that is greater than the sum of their individual effects.
"Bioactive amounts" as mentioned herein means that amount which, when applied treatment of crops, is sufficient to effect such treatment.
Therefore an aspect of the present invention provides a synergistic pesticidal compositions comprising bioactive amounts of (A) Tolfenpyrad; (B) an insecticide selected from class of diamide, metadiamide and isoxazoline or mixtures thereof; (C) at least one insecticide selected from chordotonal organ modulators or mixture thereof.
More particularly, a further aspect of the present invention provides a synergistic pesticidal composition comprising bioactive amounts of (A) Tolfenpyrad; (B) an insecticide selected from diamide like chlorantraniliprole, cyantraniliprole, cyclaniliprole, cyproflanilide, tetrachlorantraniliprole, tyclopyrazoflor, cyhalodiamide, flubendiamide, tetraniliprole or mixture thereof; metadiamide such as broflanilide; isoxazoline like fluxametamide, isocycloseram or mixtures thereof (C) at least one more insecticide selected from the class of chordotonal organ modulators like are afidopyropen, flonicamid, pymetrozine or pyrifluquinazon or mixture thereof.
In an embodiment of the present invention an Insecticide from the class of diamide is selected from chlorantraniliprole, cyantraniliprole, cyclaniliprole, cyhalodiamide, cyproflanilide, flubendiamide, tetraniliprole, tetrachlorantraniliprole, tyclopyrazoflor.
In an embodiment of the present invention an Insecticide from the class of metadiamide is broflanilide.

In an embodiment of the present invention an Insecticide from the class of Isoxazoline is selected from fiuxametamide, isocycloseram.
Diamide group of insecticides:
Cyantraniliprole is an insecticide of the ryanoid class. It is approved for use in the United States, Canada, China, and India. Because of its uncommon mechanism of action as a ryanoid, it has activity against pests such as Diaphorina citri that have developed resistance to other classes of insecticides. Cyantraniliprole is highly toxic to bees. It is a new second-generation ryanodine receptor insecticide whose pesticidal mode of action is through unregulated activation of insect ryanodine receptor channels, which leads to internal calcium store depletion and impaired regulation of muscle contraction, causing paralysis and eventual death of the insect. Cyantraniliprole is used to control insect pests in fruit crops, tree nuts, oil seed crops, cotton, grapes, rice, vegetables, ornamentals and turf around the world.
Chordotonal organ modulators:
Afidopyropen was discovered from biological fermentation, which is a propene compound, being a new insecticide for control of piercing-sucking mouthparts. It has the features of fast action, high efficiency and broad spectrum. Its ingredient is included by Insecticide Resistance Action Committee (IRAC) as the first of the Group 9D, as well as the sole insecticidal ingredient, which has no cross resistance to the existing insect pest management system.
Afidopyropen interferes with the chordotonal organ of the insect, which causes insects to lose their reaction to gravity, balance, sound, position and movement, resulting in epicophosis and loss of direction, further leading to food and water loss, and thus causes insect deaths from hunger.
Afidopyropen effectively reduces viral and bacterial diseases transmitted by insect vector, being very effective in the control of aphid and whitefly, with a long-lasting effect. It is also effective against different stages of insects (ineffective to ovum). It has an outstanding foliar infiltration capacity, and is resistant to rain wash due to its unique formulation.

Flonicamid exhibits excellent aphicidal activity and also shows good insecticidal activity against other sucking insect pests such as thrips, white ies, planthoppers, leafhoppers, plant bugs, and mealybugs in fruit trees, cereals, rice, potatoes, cotton, vegetables and ornamentals. Flonicamid soil applications also provide control of the foliar pests mentioned above. Flonicamid rapidly inhibits the feeding behavior of aphids, and has better action through ingestion than by contact. Its mode of action is different from other insecticides such as neonicotinoids, pymetrozine and pyri uquinazon. Flonicamid belongs to IRAC Group 29 and is the only insecticide in this class.
Pymetrozine is a new insecticide, highly active and specific against sucking insect pests. Pymetrozine is the only representative of the pyridine azomethines, a new class of insecticides, and is currently being developed worldwide for control of aphids and whiteflies in field crops, vegetables, ornamentals, cotton, hop, deciduous fruit, and citrus, and of the brown planthopper, Nilaparvata lugens (Staol), in rice. The compound appears to have great promise in integrated pest management (TPM) programs due to its high degree of selectivity, low mammalian toxicity, and safety to birds, fish, and non-target arthropods.
Pyrifluquinazon is a recently commercialized insecticide that interferes with chordotonal receptor neuron function. Eggs, first-instar nymphs, and mid-instar nymphs of Bemisia tabaci Middle East Asia Minor 1 (Gennadius) (Hemiptera: Aleyrodidae) were treated on cotton leaves with 0.057 g. ai./liter Pyrifluquinazon 20 SC in a growth room study. When 5-d-old eggs were treated, there was essentially no survival among emerging crawlers. When crawlers and first instars were treated, survival and development to subsequent instars was drastically reduced compared with the untreated control. Treatment of mid instars had no effect on mortality.
The present inventors believe that the combination of the present invention surprisingly results in a synergistic action. The combination of the present invention allows for a broad spectrum of pest control and has surprisingly improved plant vigour and yield. The broad spectrum of the present combination also provides a solution for preventing the development of resistance and residual control of insect-pests.

The synergistic agrochemical composition has advantageous curative, preventive and systemic pesticidal properties for protecting cultivated plants. As has been mentioned, said active ingredient composition can be used to inhibit or destroy the Insect-pests and mites that occur on plants or parts of plants of different crops or useful plants. The synergistic agrochemical composition of specific active ingredient has the special advantage of being highly active against insect pests. The present inventors believe that the combination of the present invention surprisingly results in a synergistic action. The combinations of the present invention allow for a broad spectrum of pest control and has surprisingly improved plant vigour and yield. The broad spectrum of the present combination also provides a solution for preventing the development of resistance.
The synergistic composition of pesticide are used to protect the crops and plants from insect pests. Examples of the crops on which the present compositions may be used include but are not limited to GMO (Genetically Modified Organism) and Non GMO varieties of Cotton (Gossypium spp.), Paddy (Oryza sativa), Wheat (Triticum aestavum), Barley {Hordeum vulgare), Maize (Zea mays), Sorghum (Sorghum bicolor), Oat (Avena sativa), Pearl millet (Pennisetum glaucum), Sugarcane (Saccharum officinarum) , Sugarbeet (Beta vulgaris), Soybean (Glycin max), Peanut (Arachis hypogaea), Sunflower (Helianthus annuus), Mustard (Brassica juncea), Rape seed (Brassica napus), Linseed (Linum usitatissimum), Sesame (Sesamum indicum), Green gram (Vigna radiata), Black gram (Vigna mungo), Chickpea (Cicer aritinum), Cowpea (Vigna unguiculata), Redgram (Cajanus cajan), Frenchbean (Phaseolus vulgaris), Indian bean (Lablab purpureus), Horse gram (Macrotyloma uniflorum), Field pea (Pisum sativum), Cluster bean (Cyamopsis tetragonoloba), Lentils (Lens culinaris), Brinjal (Solanum melongena), Cabbage (Brassica oleracea var. capitata), Cauliflower (Brassica oleracea var. botrytis), Okra (Abelmoschus esculentus) , Onion (Allium cepa L.), Tomato (Solanum lycopersicun) , Potato (Solanum tuberosum) , Sweet potato (Ipomoea batatas), Chilly (Capsicum annum), Garlic (Allium sativum), Cucumber (Cucumis sativus), Muskmelons (Cucumis melo), Watermelon (Citrullus lanatus), Bottle gourd (Lagenaria siceraria), Bitter gourd (Momordica charantia), Radish (Raphanus sativus), Carrot (Dacus carota subsp. sativus), Turnip (Brassica rapa subsp rapa), Apple (Melus domestica), Banana (Musa spp.), Citrus groups (Citrus spp.), Grape (Vitis vinifera), Guava (Psidium guajava), Litchi (Litchi chinensis), Mango (Mangifera indica), Papaya (Carica papaya), Pineapple (Ananas comosus),

Pomegranate (Punica granatum), Sapota (Manilkara zapota), Tea (Camellia sinensis), Coffea (Coffea Arabica), Turmeric (Curcuma longa), Ginger (Zingiber officinale), Cumin (Cuminum cyminum), Fenugreek (Trigonella foenum-graecum), Fennel (Foeniculum vulgare), Coriander (Coriandrum sativum), Ajwain (Trachyspermum ammi), Psyllium (Plantago ovate), Black Pepper (Piper nigrum), Stevia {Stevia rebaudiana), Safed musli (Chlorophytum tuberosum), Drum stick (Moringa oleifera), Coconut (Coco nucifera), Mentha (Mentha spp.), Rose (Rosa spp.), Jasmine (Jasminum spp.), Marigold ( Tagetes spp.), Common daisy (Bellis perennis), Dahlia (Dahlia hortnesis), Gerbera ( Gerbera jamesonii), Carnation (Dianthus caryophyllus), vegetables: solanaceous vegetables such as eggplant, tomato, pimento, pepper, potato, etc., cucurbit vegetables such as cucumber, pumpkin, zucchini, water melon, melon, squash, etc., cruciferous vegetables such as radish, white turnip, horseradish, kohlrabi, Chinese cabbage, cabbage, leaf mustard, broccoli, cauliflower, etc., asteraceous vegetables such as burdock, crown daisy, artichoke, lettuce, etc, liliaceous vegetables such as green onion, onion, garlic, and asparagus, ammiaceous vegetables such as carrot, parsley, celery, parsnip, etc., chenopodiaceous vegetables such as spinach, Swiss chard, etc., lamiaceous vegetables such as Perilla frutescens, mint, basil, etc, strawberry, sweet potato, Dioscorea japonica, colocasia, etc., flowers, foliage plants, turf grasses, fruits: pome fruits such apple, pear, quince, etc, stone fleshy fruits such as peach, plum, nectarine, Prunus mume, cherry fruit, apricot, prune, etc., citrus fruits such as orange, lemon, rime, grapefruit, etc., nuts such as chestnuts, walnuts, hazelnuts, almond, pistachio, cashew nuts, macadamia nuts, etc. berries such as blueberry, cranberry, blackberry, raspberry, etc., grape, kaki fruit, olive, plum, banana, coffee, date palm, coconuts, etc. , trees other than fruit trees; tea, mulberry, flowering plant, trees such as ash, birch, dogwood, Eucalyptus, Ginkgo biloba, lilac, maple, Quercus, poplar, Judas tree, Liquidambar formosana, plane tree, zelkova, Japanese arborvitae, fir wood, hemlock, juniper, Pinus, Picea, and Taxus cuspidate, etc.
The synergistic combination of the present invention used to control the insects-pests and mites.
The major insects pests are belongs to the order Hemiptera, for example, rice leafhopper Nephotettix nigropictus, rice brown plant hopper Nilaparvata lugen, rice white backed plant hopper, Apple Mealy bug Phenococcus aceris, bean aphid Aphis fabae, black citrus aphid Toxoptera aurantii, citrus black scale Saissetia oleae, cabbage aphid Brevicoryne brassicae, Lipaphis erysimi, citrus red scale Aonidiella aurantii,

yellow scale Aonidiella citrine, citrus mealybug Planococcus citri, corn leaf aphid Rhopalosiphum maidis, cotton aphid Aphis gossypii, cotton jassid Amrasca biguttula biguttla, cotton mealy bug Planococcus spp. And Pseudococcus spp., cotton stainer Dysdercus suturellus, cotton whitefly Bemisia tabaci, cowpea aphid Aphis crassivora, grain aphid Sitobion avenae, golden glow aphid Uroleucon spp., grape mealybug Pseudococcus maritimus, green peach aphid Myzus persicae, greenhouse whitefly Trialeurodes vaporariorum, papaya mealy bug Pracoccus marginatus, pea aphid Acyrthosiphon pisum, sugarcane mealybug Saccharicoccus sacchari, potato aphid Myzus persicae, potato leaf hopper Empoasca fabae, cotton whitefly Bemisia tabaci, tarnished plant bug Lygus lineolaris, wooly apple aphid Eriosoma lanigerum, mango hopper Amritodus atkinsoni, Idioscopus spp. ; order Lepidoptera, army worm Mythimna unipuncta, asiatic rice borer Chilo suppressalis, bean pod borer Maruca vitrata, beet armyworm Spodoptera exigua, black cutworm Agrotis ipsilon, bollworm Helicoverpa armigera, cabbage looper Trichoplusia ni, codling moth Cydia pomonella, croton caterpillar Achea Janata, diamond backmoth Plutella xylostella, cabbage worm Pieris rapae, pink bollworm Pectinophora gossypiella, sugarcane borer Diatraea saccharalis, tobacco budworm Heliothis virescens, tomato fruitworm Helicoverpa zea, velvet bean caterpillar Anticarsia gemmatalis, yellow stem borer Scirpophaga incertulas, spotted bollworm Earias vittella, rice leaffolder Cnaphalocrocis medinalis, pink stem borer Sesamia spp., tobacco leafeating caterpillar Spodoptera litura; brinjal fruit and shoot borer Leucinodes orbonalis, bean pod borer Maruca vitrata, Maruca testulalis, armyworm Mythimna separata, cotton pinkbollworm Pectinophora gossypiella, citrus leafminer Phyllocnistis citrella, cabbage butterfly Pieris bras-sicae, diamond backmoth Plutella xylostella, paddy stem borer Scirpophaga excerptallis, Scirpophaga incertulas, Scirpophaga innotata, wheat stem borer Sesamia inferens, Sitotroga cerealella, Spilosoma obliqua, Spodoptera frugiperda, Spodoptera littoralis, Spodoptera litura, Trichoplusia ni, Tryporyza novella, Tuta absoluta. from the order Coleoptera, for example, apple twig borer Amphicerus spp., corn root worm Diabrotica virgifera, cucumber beetle diabrotica balteata, boll weevil Anthonomus grandis, grape flea beetle Altica chalybea, grape root worm Fidia viticola, grape trunk borer Clytoleptus albofasciatus, radish flea beetle Phyllotreta armoraciae, maize weevil Sitophilus zeamais, northern corn rootworm Diabrotica barberi, rice water weevil Lissorhoptrus oryzophilus, Anthonomus grandis, Bruchus lentis, Diabrotica semipunctata, Diabrotica virgifera, Dicladispa armigera, Epila-chna varivestis, various

species of white grubs are Holotrichia bicolor, Holotrichia consanguinea, Holotrichia serrata, Leptinotarsa decemlineata, Phyllotreta chrysocephala, Popillia japonica etc; from the order Orthoptera, for example, Gryllotalpa spp., Locusta spp., and Schistocerca is spp.; from the order Thysanoptera, for example, Frankliniella spp., Thrips palmi, Thrips tabaci and Scirtothrips dorsalis; termites (Isoptera), e.g. Calotermes flavicollis, Coptotermes formosanus, Heterotermes aureus, Leucotermes flavipes, Microtermes obesi, Odontotermes obesus, Reticulitermes flavipes, Termes natalensis; from the order Heteroptera, for example, Dysdercus spp., Leptocorisa spp., from the order Hymenoptera, for example, Solenopsis spp. ; from the order Diptera, for example, Antherigona soccata, Dacus spp., Liriomyza spp., Melanagromyza spp., from the order Acarina, for example, Aceria mangiferae, Brevipalpus spp., Eriophyes spp., Oligonychus mangiferus, Oligonychus punicae, Panonychus citri, Panonychus ulmi, Polyphagotarsonemus latus, Tarsonemus spp., Tetranychus urticae, Tetranychus cinnabarinus.
The term "health of a plant" or "plant health" is defined as a condition of the plant and/or its products. As a result of the improved health, yield, plant vigor, quality and tolerance to abiotic or biotic stress are increased. Noteworthy, the health of a plant when applying the method according to the invention, is increased independently of the pesticidal properties of the active ingredients used because the increase in health is not based upon the reduced disease pressure but instead on complex physiological and metabolic reactions which result for example in an activation of the plant's own natural defense system. As a result, the health of a plant is increased even in the absence of diseases pressure. Accordingly, in an especially preferred embodiment of the method according to the invention, the health of a plant is increased both in the presence and absence of biotic or abiotic stress factors. The above identified indicators for the health condition of a plant may be interdependent or they may result from each other. An increase in plant vigor may for example result in an increased yield and/or tolerance to abiotic or biotic stress. One indicator for the condition of the plant is the yield. "Yield" is to be understood as any plant product of economic value that is produced by the plant such as grains, fruits in the proper sense, vegetables, nuts, grains, seeds, wood (e.g. in the case of silviculture plants) or even flowers (e.g. in the case of gardening plants, ornamentals). The plant products may in addition be further utilized and/or processed after harvesting.

In an especially preferred embodiment of the invention, the yield of the treated plant is increased.
In another preferred embodiment of the invention, the yield of the plants treated according to the method of the invention, is increased synergistically.
According to the present invention, "increased yield" of a plant, in particular of an agricultural, silvi cultural and/or horticultural plant means that the yield of a product of the respective plant is increased by a measurable amount over the yield of the same product of the plant produced under the same conditions, but without the application of the mixture according to the invention.
Increased yield can be characterized, among others, by the following improved proper¬ties of the plant: increased plant, weight, increased plant height, increased biomass such as higher overall fresh weight (FW), increased number of flowers per plant, higher grain yield, more tillers or side shoots (branches), larger leaves, increased shoot growth, increased protein content, increased oil content, increased starch content, increased pigment content, increased leaf are index.
According to the present invention, the yield is increased by at least 5 %, preferable by 5 to 10 %, more preferable by 10 to 20 %, or even 20 to 30 % compared to the untreated control plants or plants treated with pesticides in a way different from the method according to the present invention. In general, the yield increase may even be higher.
A further indicator for the condition of the plant is the plant vigor. The plant vigor becomes manifest in several aspects such as the general visual appearance. In another especially preferred embodiment of the invention, the plant vigor of the treated plant is increased. In another preferred embodiment of the invention, the plant vigor of the plants treated according to the method of the invention, is increased synergistically. Improved plant vigor can be characterized, among others, by the following improved properties of the plant: improved vitality of the plant, improved plant growth, improved plant development, improved visual appearance, improved plant stand (less plant verse/lodging), improved emergence, enhanced root growth and/or more developed root system, enhanced nodulation, in particular rhizobium nodulation, bigger leaf blade, bigger size, increased plant weight, increased plant height, increased tiller number, increased number of side shoots, increased number of flowers per plant, increased shoot growth, increased root growth (extensive root system), increased yield when grown on

poor soils or unfavorable climate, enhanced photosynthetic activity (e.g. based on increased stomatal conductance and/or increased C02 assimilation rate), increased stomatal conductance, increased C02 assimilation rate, enhanced pigment content (e.g. chlorophyll content), earlier flowering, earlier fruiting, earlier and improved germination, earlier grain maturity, improved self-defense mechanisms, improved stress tolerance and resistance of the plants against biotic and abiotic stress factors such as fungi, bacteria, viruses, heat stress, cold stress, drought stress, UV stress and/or salt stress, less non-productive tillers, less dead basal leaves, less input needed (such as fertilizers or water), greener leaves, complete maturation under shortened vegetation periods, less fertilizers needed, less seeds needed, easier harvesting, faster and more uniform ripening, longer shelf-life, longer panicles, delay of senescence, stronger and/or more productive tillers, better extractability of ingredients, improved quality of seeds (for being seeded in the following seasons for seed production), better nitrogen uptake, improved reproduction, reduced production of ethylene and/or the inhibition of its reception by the plant.
The improvement of the plant vigor according to the present invention particularly means that the improvement of any one or several or all of the above mentioned plant characteristics are improved independently of the pesticidal action of the mixture or active ingredients (components).
Another indicator for the condition of the plant is the "quality" of a plant and/or its products.
In an especially preferred embodiment of the invention, the quality of the treated plant is increased.
In another preferred embodiment of the invention, the quality of the plants treated according to the method of the invention, is increased synergistically.
According to the present invention, enhanced quality means that certain plant characteristics such as the content or composition of certain ingredients are increased or improved by a measurable or noticeable amount over the same factor of the plant produced under the same conditions, but without the application of the mixtures of the present invention. Enhanced quality can be characterized, among others, by following improved properties of the plant or its product: increased nutrient content, increased protein content, increased content of fatty acids, increased metabolite content,

increased carotenoid content, increased sugar content, increased amount of essential amino acids, improved nutrient composition, improved protein composition, improved composition of fatty acids, improved metabolite composition, improved carotenoid composition, improved sugar composition, improved amino acids composition, improved or optimal fruit color, improved leaf color, higher storage capacity, higher processability of the harvested products.
Another indicator for the condition of the plant is the plant's tolerance or resistance to biotic and/or abiotic stress factors. Biotic and abiotic stress, especially over longer terms, can have harmful effects on plants. Biotic stress is caused by living organisms while abiotic stress is caused for example by environmental extremes. According to the present invention, "enhanced tolerance or resistance to biotic and/or abiotic stress factors" means (1.) that certain negative factors caused by biotic and/or abiotic stress are diminished in a measurable or noticeable amount as compared to plants exposed to the same conditions, but without being treated with a mixture according to the invention and (2.) that the negative effects are not diminished by a direct action of the mixture according to the invention on the stress factors, e.g. by its fungicidal action which directly destroys the microorganisms or diseases, but rather by a stimulation of the plants' own defensive reactions against said stress factors.
Formulation of the present invention can be in any of the formulations selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR).
One or more of the active ingredients is encapsulated for various purposes, such as to increase the residual biological activity, or to reduce the acute toxicity, or to obtain a physical or chemically stable water-based formulation. The purpose determines

whether the "free" active ingredient and the "release rate" are relevant properties of a specific product.
Further pesticidal composition comprising (A) Tolfenpyrad; (B) an insecticide selected from the class of diamide, metadiamide, isoxazoline or mixtures theref; (C) at least one insecticide selected from class of chordotonal organ modulators or mixture thereof are present in the said composition in specific fixed ratio.
In further aspect the present invention relates to the synergistic pesticidal composition comprising bioactive amounts of (A) is 0.1 to 40% w/w of the composition; (B) is 0.1 to 40% w/w of the composition; and (C) is 0.1 to 30% w/w of the composition.

Active Ingredients Compound A Compound B Compound C
Examples Tolfenpyrad Insecticdes selected frm diamide, metadiamide, isoxazoline One more
insecticide(s)
from
chordotonal
organ
modulators
% of Active Ingredient 0.1 to 40% 0.1 to 40% 0.1 to 30%
The preferred combinations for the present invention may be selected from below:

Compound A Tolfenpyrad Compound B
Insecticide selected from the class
of diamde, metadiamde,
isoxazoline or mixture thereof. Compound C Insecticide selected from from the class of chordotonal organs modulators or mixture thereof.
Tolfenpyrad Cyantraniliprole Afidopyropen
Tolfenpyrad Cyantraniliprole Flonicamid
Tolfenpyrad Cyantraniliprole Pymetrozine
Tolfenpyrad Cyantraniliprole Pyrifluquinazon
Tolfenpyrad Chlorantraniliprole Afidopyropen
Tolfenpyrad Chlorantraniliprole Flonicamid
Tolfenpyrad Chlorantraniliprole Pymetrozine
Tolfenpyrad Chlorantraniliprole Pyrifluquinazon

Tolfenpyrad Cyclaniliprole Afidopyropen
Tolfenpyrad Cyclaniliprole Flonicamid
Tolfenpyrad Cyclaniliprole Pymetrozine
Tolfenpyrad Cyclaniliprole Pyrifluquinazon
Tolfenpyrad Cyhalodi amide Afidopyropen
Tolfenpyrad Cyhalodi amide Flonicamid
Tolfenpyrad Cyhalodi amide Pymetrozine
Tolfenpyrad Cyhalodi amide Pyrifluquinazon
Tolfenpyrad Cyproflanilide Afidopyropen
Tolfenpyrad Cyproflanilide Flonicamid
Tolfenpyrad Cyproflanilide Pymetrozine
Tolfenpyrad Cyproflanilide Pyrifluquinazon
Tolfenpyrad Tetraniliprole Afidopyropen
Tolfenpyrad Tetraniliprole Flonicamid
Tolfenpyrad Tetraniliprole Pymetrozine
Tolfenpyrad Tetraniliprole Pyrifluquinazon
Tolfenpyrad Broflanilide Afidopyropen
Tolfenpyrad Broflanilide Flonicamid
Tolfenpyrad Broflanilide Pymetrozine
Tolfenpyrad Broflanilide Pyrifluquinazon
Tolfenpyrad Fluxametamide Afidopyropen
Tolfenpyrad Fluxametamide Flonicamid
Tolfenpyrad Fluxametamide Pymetrozine
Tolfenpyrad Fluxametamide Pyrifluquinazon
Tolfenpyrad Isocyclaseram Afidopyropen
Tolfenpyrad Isocyclaseram Flonicamid
Tolfenpyrad Isocyclaseram Pymetrozine
Tolfenpyrad Isocyclaseram Pyrifluquinazon
Tolfenpyrad Tyclopyrazoflor Afidopyropen
Tolfenpyrad Tyclopyrazoflor Flonicamid
Tolfenpyrad Tyclopyrazoflor Pymetrozine
Tolfenpyrad Tyclopyrazoflor Pyrifluquinazon
Tolfenpyrad Cyantraniliprole Fl oni cami d+Pyri fluquinazon
Tolfenpyrad Cyantraniliprole Afidopyropen+Pyrifluquinazon
Tolfenpyrad Cyantraniliprole Pymetrozine+Pyri fluquinazon
Tolfenpyrad Cyantraniliprole Pymetrozine+Afidopyropen
Tolfenpyrad Cyantraniliprole Pym etrozi ne+Fl oni cami d
The composition of the present invention in addition to bioactive amounts of active ingredients further comprises inactive excipients including but not limited to wetting agents, wetting-spreading-penetrating agent, dispersant or dispersing agent, anti-

freezing agent, anti-foam agent, preservatives, solvents, carriers, suspension aid, thickener, and buffering agent.
A wetting agent is a substance that when added to a liquid increases the spreading or penetration power of the liquid by reducing the interfacial tension between the liquid and the surface on which it is spreading. Wetting agents are used for two main functions in agrochemical formulations: during processing and manufacture to increase the rate of wetting of powders in water to make concentrates for soluble liquids or suspension concentrates; and during mixing of a product with water in a spray tank or other vessel to reduce the wetting time of wettable powders and to improve the penetration of water into water-dispersible granules.
Examples of wetting agent used herein for SC (Suspension concentrate) formulation include but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, polyalkoxylated butyl ether, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate.
Examples of wetting agent used herein for Oil dispersion (OD) formulation includes but not limited to ethylene oxide/propylene oxide block copolymer, polyarylphenyl ether phosphate, ethoxylated fatty alcohol, sodium dioctyl sulfosuccinate, sodium lauryl sulfate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, alkyl naphthalene sulfonate.
Examples of wetting agent used herein for SE (Suspo Emulsion) formulation includes but not limited to Ethylene oxide/propylene oxide block copolymer, Polyarylphenyl ether phosphate, Ethoxylated Fatty Alcohol, Sodium dioctyl sulfosuccinate, sodium lauryl sulphate and sodium dodecyl benzene sulfonate, alkyl diphenyl sulfonates, sodium isopropyl naphthalene sulfonate, Alkyl naphthalene sulfonate, Octyl phenol ethoxylate, alkyl phenol ethoxylate and aliphatic alcohol ethoxylate or mixture thereof.
Examples of Wetting-spreading-penetrating agent used herein for Oil dispersion (OD)
formulation, Suspension Concentrate (SC) formulation, Suspo-emulsion (SE)
formulation include but not limited to Organo-silicone surfactants includes
trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane,

polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, modified heptamethyl trisiloxane, polyether modified polysiloxane, 10 mole ethylene oxide adduct of octylphenol, may or may not be in modified form, may be liquid or powder form or mixture thereof etc;
A dispersant or a dispersing agent is a substance which adsorbs onto the surface of particles and helps to preserve the state of dispersion of the particles and prevents them from re-aggregating. Dispersants are added to agrochemical formulations to facilitate dispersion and suspension during manufacture, and to ensure the particles re-disperse into water in a spray tank. They are widely used in wettable powders, suspension concentrates and water-dispersible granules. Surfactants that are used as dispersants have the ability to adsorb strongly onto a particle surface and provide a charged or steric barrier to re-aggregation of particles. The most commonly used surfactants are anionic, non-ionic, or mixtures of the two types. For wettable powder formulations, the most common dispersants are sodium lingo sulphonates. In recent years, new types of very high molecular weight polymeric surfactants have been developed as dispersants. These have very long hydrophobic 'backbones' and a large number of ethylene oxide chains forming the 'teeth' of a 'comb' surfactant. These high molecular weight polymers can give very good long-term stability to suspension concentrates because the hydrophobic backbones have many anchoring points onto the particle surfaces.
Examples of dispersants or dispersing agent used herein for SC (Suspension concentrate) formulation include but not limited to alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Examples of dispersants or dispersing agent used herein for Oil dispersion (OD) formulation includes but not limited to alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkylphenolalkoxylates, tristyrylphenol ethoxylates, natural or

synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butyl ene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploycarboxylate,EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide.
Examples of dispersants or dispersing agent used herein for SE (Suspo Emulsion) formulation includes but not limited to be a conventionally available for example polyesters, polyamides, poly- carbonates, polyurea and polyurethanes, acrylic polymers, acrylic graft copolymer, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol, vinylacetate and vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins and define copolymers and mixtures thereof. Examples of preferred polymers are acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly(styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these. Polymers that are biodegradable are also useful in the present invention. As used herein, a polymer is biodegradable if is not water soluble, but is degraded over a period of several weeks when placed in an application environment. Examples of biodegradable polymers that are useful in the present invention include biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate),

wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof. The examples of dispersing agents are alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium salt of alkyl naphthalene sulfonate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycol ether with 9-10 moles ethylene oxide.
Antifoaming agent for the present formulation is selected from various compounds and selectively used according to the formulation. Generally, there are two types of antifoam agents, namely silicones and non-silicones. Silicones are usually aqueous emulsions of dimethyl poly siloxane while the non-silicone anti-foam agents are water-insoluble oils, such as octanol and nonanol, or silica. In both cases, the function of the anti-foam agent is to displace the surfactant from the air-water interface.
Examples of Antifoaming agent used herein for SC (Suspension concentrate), Oil dispersion (OD) formulation and SE (Suspo Emulsion) formulation include but not limited to silicone oil, silicone compound, C10~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, poly dimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, polyalkylene oxide modified polydimethylsiloxane.
Examples of Anti-freezing agent used herein for SC (Suspension concentrate) and Oil dispersion (OD) formulation and SE (Suspo Emulsion) formulation include but not limited to ethylene glycol, propane diols, glycerine or the urea, glycol (monoethylene glycol, diethylene glycol, polypropylene glycol, polyethylene glycol), glycerine, urea, magnesium sulfate heptahydrate, sodium chloride.
Preservative used herein for the SC (Suspension concentrate) formulation and Oil dispersion (OD) formulation include but not limited to l,2-benzisothiazolin-3(2H)-one, sodium salt, Sodium benzoate, 2-bromo-2-nitropropane-l,3-diol, Formaldehyde,

Sodium o-phenylphenate, 5-chloro-2-methyl-4-isothiazolin-3-one & 2-methyl-4-i sothi azolin-3 -one.
Preservative used herein for the SE (Suspo Emulsion) formulation include but not limited to propionic acid and its sodium salt, sorbic acid and its sodium or potassium salt, benzoic acid and its sodium salt, p-hydroxy benzoic acid sodium salt; methyl p-hydroxy benzoate; and biocide such as sodium benzoate, l,2-benzisothiazoline-3-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2- methyl-4-isothiazolin-3-one, potassium sorbate, para hydroxy benzoates or mixtures thereof.
Thickeners or gelling agents are used mainly in the formulation of suspension concentrates, emulsions and suspo-emulsions to modify the rheology or flow properties of the liquid and to prevent separation and settling of the dispersed particles or droplets. Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers.
Examples of thickeners used herein for SC (Suspension concentrate) formulation include but not limited to xanthan gum, PVK, carboxymethylcelluloses, polyvinyl alcohols, gelatin, sodium carboxy methylcellulose, hydroxyethyl cellulose, sodium polyacrylate, modified starch.
Examples of thickeners used herein for SE (Suspo Emulsion) formulation include various compound depending upon the nature of the composition. Thickening, gelling, and anti-settling agents generally fall into two categories, namely water-insoluble particulates and water-soluble polymers. It is possible to produce suspension concentrate formulations using clays and silicas. Examples of these types of materials, include, but are limited to, montmorillonite, e.g. bentonite; magnesium aluminum silicate; and attapulgite. Water-soluble polysaccharides have been used as thickening-gelling agents for many years. The types of polysaccharides most commonly used are natural extracts of seeds and 15 seaweeds are synthetic derivatives of cellulose or mixtures thereof. Examples of these types of materials include, but are not limited to, guar gum; locust bean gum; carrageenam; xanthan gum; alginates; methyl cellulose; sodium carboxymethyl cellulose (SCMC); hydroxyethyl cellulose (HEC) or mixtures thereof. Other types of anti-settling agents are based on modified starches, polyacrylates, polyvinyl 20 alcohol and polyethylene oxide or mixtures.

Suspension aid or the suspending agent in the present description denotes a natural or synthetic, organic or inorganic material with which the active substance is combined in order to facilitate its application to the plant, to the seeds or to the soil. This carrier is hence generally inert, and it must be agriculturally acceptable, in particular to the plant being treated. The carrier may be solid (clays, natural or synthetic silicates, silica, resins, waxes, solid fertilizers, and the like or mixtures thereof) or liquid (water, alcohols, ketones, petroleum fractions, aromatic or paraffinic hydrocarbons, chlorinated hydrocarbons, liquefied gases, and the like or mixtures thereof).
Examples of suspending agent used herein for SC (Suspension concentrate) formulation, SE (Suspo Emulsion) formulation include but not limited to Aluminium Magnesium Silicate, Bentonite clay, Silica, Attapulgite clay.
Example of solvents used herein for the Oil dispersion (OD) formulation includes but not limited to vegetable oil (plant, seed or tree) or its alkylated or ethoxylated or esterified. The alkylated vegetable oil may be methylated vegetable oil or ethylated vegetable oil. The vegetable oils include olive oil, kapok oil, castor oil, papaya oil, camellia oil, sesame oil, corn oil, rice bran oil, cotton seed oil, soybean oil, groundnut oil, rapeseed-mustard oil, linseed oil, tung oil, sunflower oil, safflower oil, coconut oil. The alkyl ester of vegetable oils includes methyl ester, ethyl ester, propyl ester or butyl ester of vegetable oils. Some of the examples are methylated seed oil, polyalkyleneoxide modified polydimethylsiloxane alkylphenol ethoxylate, rapeseed oil methyl ester, rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, soybean oil methyl ester, soybean oil ethyl ester, soybean oil propyl ester, soybean oil butyl ester, castor oil methyl ester, castor oil ethyl ester, castor oil propyl ester, castor oil butyl ester, cotton seed oil methyl ester, cotton seed oil ethyl ester, cotton seed oil butyl ester, cotton seed oil propyl ester, tall oil fatty acids esters-tallow methyl ester, tallow ethyl ester, tallow propyl ester, bio-diesel, mineral oil (aromatic solvents, isoparaffin, base solvent), fatty acid amides (e.g. CI -C3 amines, alkylamines or alkanolamines with C6-C18 carboxylic acids), fatty acids, alkyl esters of fatty acids, methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols. The above oil based carrier/diluting agents may be used as solo or mixture of two or more if desired.

Example of co-solvents used herein for the Oil dispersion (OD) formulation includes but not limited to Cyclohexanone, Acetophenone, NMP, Dimethyl sulfoxide, Benzyl alcohol, Butanol, N-octanol, N-Propanol, 2-ethyl hexanol, Tetrahydro furfuryl alcohol, Isophorone, Fatty acid dimethyl amide, 2-hexylethyl lactate, Propylene carbonate.
Example of solvents used herein for the SE (Suspo Emulsion) formulation includes but not limited to water, water soluble alcohols and dihydroxy alcohol ethers. Water soluble alcohol or lower alcohol (1-4 carbon atoms) includes-methanol, ethanol, n-propanol, isopropanol, n-butanol, tert-butanol. Macromolecular alcohol includes polyethylene glycol, sorbitol, glucitol etc., dihydroxy alcohol ethers includes dihydroxy alcohol alkyl ether or dihydroxy alcohol aryl ethers. The examples of dihydroxy alcohol alkyl ether include ethylene glycol methyl ether, diethylene glycol methyl ether, propylene glycol methyl ether, di-propylene glycol methyl ether, ethylene glycol ethyl ether, diethylene glycol ethyl ether, propylene glycol ethyl ether, di-propylene glycol ethyl ether, etc. The examples of dihydroxy alcohol aryl ethers include ethylene glycol phenyl ether, 5 diethylene glycol phenyl ether, propylene glycol phenyl ether, di-propylene glycol phenyl ether, and the like. Any of the mentioned solvent can be used either alone or in combinations thereof. Paraffinic hydrocarbons, cyclohexanone, isophorone and ester solvents such as methyloleate, dimethylamide and morpholineamide derivatives of C6-C16 fatty acids, and mono-alkylene carbonates such as ethylene carbonate, propylene carbonate and butylene carbonates, dimethylsulfoxide (DMSO), 2-ethylhexanol and n-butanol, n-alkylpyrrolidones, fatty acid dimethyl esters, fatty acid esters, dibasic esters, aromatic hydrocarbons and/or aliphatic hydrocarbons, one or more dimethylamides, such as C8-dimethylamide, CTO-dimethylamide, CT2-dimethylamide, ethylene glycol, propylene glycol, polyalkylene glycols, aromatic hydrocarbons, methylpyrrolidinone (NMP); dimethylformamide (DMF); dimethylisosorbide (DMI); isophorone; acetophenone; l,3-dimethyl-2-imidazolidonone; lactate esters; dimethyl and diethylcarbonates; alcohols including methanol; ethanol; iso-propanol; n-propanol; n-butanol; iso-butanol; and tert-butanol; Methyl L-lactate, 2-Ethylhexyl L-lactate, Ethyl L-lactate, n-Butyl L-lactate, Octyl phenyl ethoxylates, N,N decanamide.
Emulsifying agent used herein for the Oil dispersion (OD) formulation includes but not limited to castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecylbenzene sulphonate, alkylammonium salts of alkylbenzene sulphonate, alkyl sulphosuccinate salts, ethylene

oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylenesorbitan monolaurate.
Example of emulsifier used herein for the Suspo-emulsion (SE) formulation includes but not limited to salts of dodecylbenzene sulphonate, e.g. Ca-salts or amine salts, and sulphonates of other C11-C16 alkylbenzenes, alkyl ether sulphates, alkylphenoletherphosphates and ester phosphates; non-ionic surfactants such as alkoxylated alcohols and alkylphenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid esters, e.g. of sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; and catanionic emulsifiers such as a cationic amine, optionally in combination with an alkyl sulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkylphenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol; fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkylbenzenes in the range C11-C16 and salts thereof; alkylether sulphates; alkyletherphosphates; alkylphenoletherphosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenol; or a catanionic system, wherein a cationic amine is present in combination with an alkylsulphonate, an alkylethersulphonate, an ether sulphate, or an ether phosphate such as an alkyletherphosphate, nonylphenol polyethoxy ethanols, castor oil polyglycol ethers, polyadducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol.
Stabilizers or stabilizing agent used herein for the Oil dispersion (OD) formulation includes but not limited to hectorite clay, aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.
Examples of Stabilizers or stabilizing agent used herein for the Suspo-emulsion (SE) formulation includes but not limited to butylated hydroxytoluene (BHT) and epoxidized soybean oil (ESBO), Epichlorhydrin.
Buffering agent used herein for the SE (Suspo Emulsion) formulation includes but not limited to calcium hydroxyapatite, Potassium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate, sodium bicarbonate, tricalcium

phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.
While the foregoing written description of the invention enables one of ordinary skill to make and use what is considered presently to be the best mode thereof, those of ordinary skill will understand and appreciate the existence of variations, combinations, and equivalents of the specific embodiment, method, and examples herein. The invention should therefore not be limited by the above described embodiment, method, and examples, but by all embodiments and methods within the scope and spirit of the invention. The invention shall now be described with reference to the following specific examples. It should be noted that the example(s) appended below illustrate rather than limit the invention, and that those skilled in the art will be able to design many alternative embodiments without departing from the scope of the present invention.
These and other aspects of the invention may become more apparent from the examples set forth herein below. These examples are provided merely as illustrations of the invention and are not intended to be construed as a limitation thereof.
EXAMPLE 1:
OD (Oil Dispersion) formulation of Tolfenpyrad 10%+Tetraniliprole 5%+Pyrifluquinazon 5%

Ingredients Percent (w/w)
Tolfenpyrad a.i. 10.00
Tetraniliprole a.i. 5.00
Pyrifluquinazon a.i. 5.00
Wetting-spreading-penetrating agent-Trisiloxane ethoxylate 5.00
Dispersing agent- Tristyrylphenol-polyglycolether-phosphate 8.00
Emulsifying agent 1-Calcium salts of dodecylbenzene sulphonate 5.00
Emulsifying agent 2-Tristryphenole with 16 moles EO 3.50
Stabilizer-Bentonite clay 1.50
Antifoaming agent-Polydimethyl siloxane 0.50
Preservative- 2-bromo-2-nitropropane-l,3 -diol 0.10
Antifreezing agent- Polypropylene glycol 5.00
Solvent-Methylated seed oil 51.40
Total 100.00

Storage stability- Tolfenpyrad 10%+Tetraniliprole 5%+Pyrifluquinazon 5% OD (Oil Dispersion)

Laboratory storage for 14 days
Parameters Specification (in house) Initial At
54+2 °C At 0+2
°C
Tolfenpyrad content percent by mass 9.50 to 10.50 10.25 10.21 10.25
Tetraniliprole content percent by mass 4.75 to 5.50 5.20 5.18 5.20
Pyrifluquinazon content percent by mass 4.75 to 5.50 5.21 5.19 5.20
Tolfenpyrad suspensibility percent min. 80 97.60 97.45 97.40
Tetraniliprole suspensibility percent min. 80 98.20 96.80 97.85
Pyrifluquinazon suspensibility percent min. 80 98.20 97.50 97.80
pH range (1% aq. Suspension) 4.5 to 7.5 6.00 6.10 6.12
Pourability 95% min. 97.60 97.20 97.50
Specific gravity 1.02-1.08 1.04 1.04 1.04
Viscosity at spindle no. 62, 20 rpm 350-800 cps 650 680 670
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 2 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Tolfenpyrad content percent by mass 9.50 to 10.50 10.25 10.21 10.25
Tetraniliprole content percent by mass 4.75 to 5.50 5.20 5.18 5.20
Pyrifluquinazon content percent by mass 4.75 to 5.50 5.21 5.19 5.20
Tolfenpyrad suspensibility percent min. 80 97.60 97.45 97.40
Tetraniliprole suspensibility percent min. 80 98.20 96.80 97.85
Pyrifluquinazon suspensibility percent min. 80 98.20 97.50 97.80
pH range (1% aq. Suspension) 4.5 to 7.5 6.00 6.10 6.12
Pourability 95% min. 97.60 97.20 97.50
Specific gravity 1.02-1.08 1.04 1.04 1.04
Viscosity at spindle no. 62, 20 rpm 350-800 cps 650 680 670
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 2 nil
Procedure: Manufacturing process of Oil dispersion (OD) formulation:
Preparation of Oil dispersion (OD) formulation:
Part A Preparation of the liquid premix

Step 1 Charge Vegetable oil or solvent or both into a vessel with anchor stirrer.
Step 2 Under stirring, add the emulsifier and dispersing agent and stir until all ingredients are dissolved completely.
PartB Preparation of the slurry
Step 1 Now, charge the liquid premix into a second vessel, equipped with a cooling and heating device and a high shear stirrer.
Step 2 Add the active ingredient and homogenize thoroughly. Pre-mill this mixture and finally mill it using a bead mill to achieve a particle size distribution as required by the specification.
PartC Preparation of the Thickener gel
Step 1 Charge the vegetable/plant/seed oil or solvent to the vessel, equipped with a high shear stirrer.
Step 2 Add gradually the thickener which is organophilic clay, maintaining high-shear mixing throughout. Stirring is continued until thoroughly mixed.
Step 3 Under stirring, the thickener activating agent propylene carbonate is added. Allow the gel to swell whilst maintaining mixing.
PartD Preparation of the final formulation
Step 1 Now add the thickener gel or silica and disperse the mixture by using a high shear stirrer.
Step 2 Finally add the recommended wetting and spreading agent or adjuvants (silicone or non-silicone based) to this formulation and disperse by using high shear stirrer.
Step 3 Check the finished formulation to specification.
Step 4 After approval, material is packed in required pack sizes.
EXAMPLE 2:
SE (Suspo Emulsion) formulation of Tolfenpyrad 10%+Chlorantraniliprole 2.5%+Flonicamid 5%

Ingredients Percent
(w/w)
Tolfenpyrad a.i. 10.00
Chlorantraniliprole a.i. 2.50
Flonicamid 5.00
Solvent -Aromatic hydrocarbon 15.00

Wetting-spreading-penetrating agent -Trisiloxane ethoxylate 5.00
Dispersing agent 1-Acrylic graft copolymer 4.50
Dispersing agent 2-Tristryphenole with 16 moles EO 3.50
Suspending agent -Attapulgite clay 2.00
Antifoaming agent -Polydimethyl siloxane 0.30
Preservative -1,2- benzisothiazoline-3-one 0.20
Antifreezing agent -1,2-Propylene glycol 5.00
Thickner -Xanthan gum 0.15
Diluent Water -Water 46.85
Total 100.00
Storage stability-
Tolfenpyrad 10% + Chlorantramliprole 2.5%+ Flonicamid 5% SE (Suspo Emulsion) formulation.

Laboratory storage for 14 days
Parameters Specification (in house) Initial At
54±2 °C At0±2
°C
Tolfenpyrad content percent by mass 9.50 to 10.50 10.25 10.20 10.25
Chlorantramliprole content percent by mass 2.375 to 2.75 2.55 2.53 2.55
Flonicamid content percent by mass 4.75 to 5.50 5.50 5.45 5.50
Tolfenpyrad suspensibility percent min. 80 97.50 96.50 97.30
Chlorantramliprole suspesnibility precent min. 80 98.50 97.50 98.30
Flonicamid suspesnibility precent min. 80 98.50 97.70 98.40
pH range (1% aq. Suspension) 4.5 to 6.5 5.50 5.45 5.50
Pourability 95% min. 98.00 97.10 97.20
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 850 860 865
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 3 nil
Room temperature storage
Parameters Specification (in house) 1 month 6 months 12 months
Tolfenpyrad content percent by mass 9.50 to 10.50 10.25 10.25 10.25
Chlorantramliprole content percent by mass 2.375 to 2.75 2.55 2.55 2.55
Flonicamid content percent by mass 4.75 to 5.50 5.50 5.50 5.50

Tolfenpyrad suspensibility percent min. 80 97.50 96.50 97.30
Chlorantraniliprole suspesnibility precent min. 80 98.50 97.50 98.30
Flonicamid suspesnibility precent min. 80 98.50 97.70 98.40
pH range (1% aq. Suspension) 4.5 to 6.5 5.50 5.50 5.50
Pourability 95% min. 98.00 97.10 97.20
Specific gravity 1.02-1.08 1.03 1.03 1.03
Viscosity at spindle no. 62, 20 rpm 350-800 cps 850 850 865
Particle size (micron) D50<3, D90<10 2.2,8.6 2.4,8.8 2.5,8.9
Persistent foam ml (after 1 minute) max. 60 nil 3 nil

'rocedure: Manufacturing process of Suspo Emulsion (SE) formulation:
Preparation of Suspo Emulsion (SE) formulation:
Step 1- 2% Gel Preparation: Charge the required quantity of water to a vessel, equipped with a high shear stirrer and start the agitation. Add the required amount of preservative. Mix until homogenous. Add the required amount of thickener and mix vigorously until it is fully wetted.
Step 2- Oil Phase: Charge solvent into the vessel and then add active technical slowly and if required, heat it for 50°C so that technical can be dissolved in solvent and then add emulsifier.
Step 3- Charge the required quantity of water to a vessel, equipped with bulk agitator and a high shear homogenizer and start agitation. Add the required amount of ant freezing agent and mix until uniform. Add the antifoaming agent and ensure that it is well dispersed. Add the wetting and dispersing agent and mix until uniform. Ensure that the dispersing agent is fully dispersed.
Step 4- Now add the active ingredient and continue agitating the vessel contents until all components get dissolved. Mill this pre-mix through a Colloid mill and subsequently through a Dyno mill to meet the specified particle size.
Step 5- Now add remaining antifoaming agent to this mill base to a vessel, equipped with bulk agitator. Mix until uniform.
Step 6- Now add oil phase in aqueous phase and stir for 30 minutes using homogenizer.
Step 7- Add the required amount of 2% aqueous pre-gel and also suspending agent and continue agitation until the formulation is homogeneous and has the target viscosity. Mix well.
Step 8- Final product is sent for QC approval.
Step 9- After approval, material is packed in required pack sizes.

EXAMPLE 3:
Lists of preferred combinations and formulations:

Compound
A Compound B Compound C in Active gredients (%) Formu-lation Strength
(%) Formu-lation Type

Compounds

A B C

Tolfenpyrad Chlorantraniliprole Afidopyropen 10 2.5 4 16.50 SE
Tolfenpyrad Chlorantraniliprole Flonicamid 10 2.5 5 17.50 SE
Tolfenpyrad Chlorantraniliprole Pymetrozine 10 2.5 10 22.50 WG
Tolfenpyrad Chlorantraniliprole Pyrifluquinazon 10 2.5 5 17.50 SE
Tolfenpyrad Cyantraniliprole Afidopyropen 10 5 4 19.00 OD
Tolfenpyrad Cyantraniliprole Flonicamid 10 5 5 20.00 WG
Tolfenpyrad Cyantraniliprole Pymetrozine 10 5 10 25.00 WG
Tolfenpyrad Cyantraniliprole Pyrifluquinazon 10 5 5 20.00 SC
Tolfenpyrad Cyclaniliprole Afidopyropen 10 5 4 19.00 SC
Tolfenpyrad Cyclaniliprole Flonicamid 10 5 5 20.00 WG
Tolfenpyrad Cyclaniliprole Pymetrozine 10 5 10 25.00 WG
Tolfenpyrad Cyclaniliprole Pyrifluquinazon 10 5 5 20.00 SC
Tolfenpyrad Cyproflanilide Afidopyropen 10 4 4 18.00 SC
Tolfenpyrad Cyproflanilide Flonicamid 10 4 5 19.00 WG
Tolfenpyrad Cyproflanilide Pymetrozine 10 4 10 24.00 WG
Tolfenpyrad Cyproflanilide Pyrifluquinazon 10 4 5 19.00 SC
Tolfenpyrad Tetrachlorantramliprole Afidopyropen 10 5 4 19.00 SC
Tolfenpyrad Tetrachlorantramliprole Flonicamid 10 5 5 20.00 WG
Tolfenpyrad Tetrachlorantramliprole Pymetrozine 10 5 10 25.00 WG
Tolfenpyrad Tetrachlorantramliprole Pyrifluquinazon 10 5 5 20.00 SC
Tolfenpyrad Tetraniliprole Afidopyropen 10 5 4 19.00 OD
Tolfenpyrad Tetraniliprole Flonicamid 10 5 5 20.00 OD
Tolfenpyrad Tetraniliprole Pymetrozine 10 5 10 25.00 WG
Tolfenpyrad Tetraniliprole Pyrifluquinazon 10 5 5 20.00 OD
Tolfenpyrad Tyclopyrazoflor Afidopyropen 10 5 4 19.00 SC
Tolfenpyrad Tyclopyrazoflor Flonicamid 10 5 5 20.00 WG
Tolfenpyrad Tyclopyrazoflor Pymetrozine 10 5 10 25.00 WG
Tolfenpyrad Tyclopyrazoflor Pyrifluquinazon 10 5 5 20.00 SC
Tolfenpyrad Broflanilide Afidopyropen 10 1 4 15.00 SE
Tolfenpyrad Broflanilide Flonicamid 10 1 5 16.00 SE
Tolfenpyrad Broflanilide Pymetrozine 10 1 10 21.00 WG
Tolfenpyrad Broflanilide Pyrifluquinazon 10 1 5 16.00 SE
Tolfenpyrad Cyhalodiamide Afidopyropen 10 4 4 18.00 SE
Tolfenpyrad Cyhalodiamide Flonicamid 10 4 5 19.00 SE
Tolfenpyrad Cyhalodiamide Pymetrozine 10 4 10 24.00 WG
Tolfenpyrad Cyhalodiamide Pyrifluquinazon 10 4 5 19.00 SC
Tolfenpyrad Fluxametamide Afidopyropen 10 1 4 15.00 SC
Tolfenpyrad Fluxametamide Flonicamid 10 1 5 16.00 WG
Tolfenpyrad Fluxametamide Pymetrozine 10 1 10 21.00 WG
Tolfenpyrad Fluxametamide Pyrifluquinazon 10 1 5 16.00 SC

Tolfenpyrad Isocycloseram Afidopyropen 10 5 4 19.00 OD
Tolfenpyrad Isocycloseram Flonicamid 10 5 5 20.00 OD
Tolfenpyrad Isocycloseram Pymetrozine 10 5 10 25.00 WG
Tolfenpyrad Isocycloseram Pyrifluquinazon 10 5 5 20.00 OD
SE Suspo Emulsion, OD Oil Dispersion, SC Suspension Concentrate, WG Water dispersible granule
Biological Examples:
A synergistic effect exists wherever the action of a combination of active ingredient is greater than the sum of the action of each of the components alone. Therefore, a synergistically effective amount or an effective amount of a synergistic composition or combination is an amount that exhibits greater pesticidal activity than the sum of the pesticidal activities of the individual components.
In the field of agriculture, it is often understood that the term "synergy" is as defined by Colby S.R. in an article entitled " Calculation of the synergistic and antagonistic responses of herbicide combinations" published in the journal Weeds, 1967, 15, p.20-22, incorporated herein by reference in its entirety. The action expected for a given combination of two or three active components can be calculated as follows:
Colby's formula for calculating synergism between three active ingredients
E = (X+Y+ Z ) - (XY + XZ + YZ) + (X Y Z)
100 10000
Where. E=Expectedpercent (%) control by mixture or combination of Compound A, Compound B and CompoundC in a defined dose X=Observed percent (%) control by Compound A Y=Observed percent (%) control by CompoundB Z=Observed percent (%) control by Compound C
Observed percent (%) control
Colby's Ratio =
Expected percent (%) control
If ratio of O/E >1, means synergism observed. O/E < 1, means antagonism, O/E = 1, means additive reaction. Higher the ratio means stronger the synergism

Colby's formula for calculating synergism between two active ingredient
XY
E = X + Y -
100 Where,
E=Expected percent (°'o) control by mixture or combination of Compound A and Compound B
in a defined dose X=Observed percent (%) control by Compound A Y=Observed percent (%) control by Compound B
Observed percent (0/o) control
Ratio =
Expected percent (%) control
Ratio of O/E > 1, means synergism observed, 0/E> 1, means antagonism. O/E = 1, means additive effect. Higher the ratio means stronger the synergism
The field studies have been conducted to evaluate the synergism and other benefits of innovative ready-mix combinations in comparison to conventional combinations. Experiment 1: Bioefficacy against insect-pests infesting brinjal crop
Crop : Brinjal
Target Insects : Sucking Insects (Whitefly, Jassid), Fruit and shoot borer
Treatments : as given in treatment details
Plot size : 30 sq.m
Spacing : 100 cm x 50 cm
Time of Application : 64 days after transplanting.
Method of Application: Foliar spray with knapsack sprayer
Water volume : 450 liter/hectare
Agronomic Practices : All agronomic practices followed as per the crop requirement
except insect control.
Observation Methods:
Fruit & shoot borer (Leucinoides orbonalis) control (%): Count the number of infested
and healthy shoots per plant. Record such observations from 10 plants per plot, at
before application and 7 days after application. Calculate % fruit & shoot borer
infestation and then recalculate percent control (observed value) by below given
formula.
number of infested shoots
Fruit & Shoot damage(%)= X 100
Total number of shoots observed
Fruit & shoot borer damage (%) in Untreated check (UTC) - Fniit & shoot borer damagc(%) in Treatment
Fruit & Shoot control (%)= X 100
Fruit & shoot borer damage in Untreated check (UTC)

Sucking Insects (whitefly-Bemisia tabaci, jassid-Amrasca biguttula biguttula) control (%): Count the number of live insects (all stages) per leaf. Observed 3 leaves per plant and 10 plants per plot. Record the observations at 7th day after spray. Calculate % insect control by given formula (observed value)
number of live insects in treatment
% sucking insect control = 100- X 100
number of live insects in untreated
Healthy Fruit count: Count the number of healthy brinjal fruits per plant, record observations from 10 plants per plot at 14 days after spray and calculate % increase in healthy fruits over untreated control (UTC). Apply Colby's formula to calculate expected control and check synergism.
Table 1-Treatment details

Treatment Number Treatment details Use Rate
g.a.i./h
Tl Tolfenpyrad 10%+Chlorantraniliprole 2.5%+Afidopyropen 4% SE 80+20+32
T2 Tolfenpyrad 10%+Chlorantraniliprole 2.5%+Flonicamid 5% SE 80+20+40
T3 Tolfenpyrad 10%+Chlorantraniliprole 2.5%+Pyrifluquinazon 5% SE 80+20+40
T4 Tolfenpyrad 10%+Tetraniliprole 5%+Afidopyropen 4% OD 80+40+32
T5 Tolfenpyrad 10%+Tetraniliprole 5%+Flonicamid 5% OD 80+40+40
T6 Tolfenpyrad 10%+Tetraniliprole 5%+Pyrifluquinazon 5% OD 80+40+40
T7 Tolfenpyrad 15% EC+Chlorantraniliprole 18.5% SC (tank mix) 80+20
T8 Tolfenpyrad 15% EC+Tetraniliprole 20% SC (tank mix) 80+40
T9 Tolfenpyrad 15% EC+Afidopyropen 5% DC (tank mix) 80+32
T10 Tolfenpyrad 15% EC+Flonicamid 50% WG (tank mix) 80+40
Til Tolfenpyrad 15% EC+Pyrifluquinazon 20% SC (tank mix) 80+40
T12 Chlorantraniliprole 18.5% SC+Afidopyropen 5% DC (tank mix) 20+32
T13 Chlorantraniliprole 18.5% SC+Flonicamid 50% WG (tank mix) 20+40
T14 Chlorantraniliprole 18.5% SC+Pyrifluquinazon 20% SC (tank mix) 20+40
T15 Tetraniliprole 20% SC+Afidopyropen 5% DC (tank mix) 40+32
T16 Tetraniliprole 20% SC+Flonicamid 50% WG (tank mix) 40+40
T17 Tetraniliprole 20% SC+Pyrifluquinazon 20% SC (tank mix) 40+40
T18 Tolfenpyrad 15% EC 80
T19 Chlorantraniliprole 18.5% SC 20
T20 Tetraniliprole 20% SC 40
T21 Afidopyropen 5% DC 32
T22 Flonicamid 50% WG 40
T23 Pyrifluquinazon 20% SC 40
T24 UTC (Untreated Control) 0
SE suspo emulsion, OD oil dispersion, SC suspension concentrate, DC dispersible concentrate, WG wettable granule, EC emulsifiable concentrate, Tl to T6 were innovative ready-mix treatments, T7 to T17 were conventional treatments.

Table 2-Control of sucking insects and fruit & shoot borer in brinjal crop

Treatment Number Sucking Pests control (%) Fruit & Shoot borer control (%) Synergism
(Y/N) Increase (%)
in healthy
fruits

OV EV Ratio O/E OV EV Ratio O/E

Tl 94.20 89.91 1.05 96.40 85.27 1.13 Y 118.4
T2 93.60 88.27 1.06 96.80 85.64 1.13 Y 113.6
T3 93.20 88.95 1.05 97.20 85.44 1.14 Y 117.5
T4 96.20 91.92 1.05 98.80 88.91 1.11 Y 121.5
T5 95.40 90.61 1.05 98.40 89.19 1.10 Y 119.6
T6 96.40 91.15 1.06 98.80 89.04 1.11 Y 124.8
T7 69.60 71.81 0.97 82.20 83.19 0.99 N 95.2
T8 74.60 77.42 0.96 85.60 87.34 0.98 N 98.6
T9 86.20 88.04 0.98 51.20 53.40 0.96 N 68.2
T10 84.80 86.11 0.98 52.40 54.57 0.96 N 61.2
Til 84.20 86.91 0.97 51.60 53.93 0.96 N 64.6
T12 67.80 69.78 0.97 70.40 72.32 0.97 N 78.6
T13 62.40 64.89 0.96 71.40 73.01 0.98 N 80.8
T14 64.60 66.92 0.97 70.60 72.63 0.97 N 79.6
T15 73.20 75.80 0.97 77.40 79.15 0.98 N 86.4
T16 68.80 71.88 0.96 76.80 79.67 0.96 N 85.2
T17 71.40 73.50 0.97 75.80 79.39 0.95 N 88.6
T18 66.60 46.80 48.2
T19 15.60 68.40 50.7
T20 32.40 76.20 58.4
T21 64.20 12.40 30.3
T22 58.40 14.60 24.8
T23 60.80 13.40 36.8
T24 0.00 0.00 0.0
OV observed value, EV expected value
All the innovative ready-mix treatments (Tl, T2, T3, T4, T5 & T6) provides synergistic control of sucking insects and fruit & shoot borer, and produces higher number of healthy fruits per plant as compared to their individual application and untreated check.
Experiment 2: Bio-efficacy against insect-pests infesting tomato crop
Crop : Tomato
Target insects : Fruit borer and whitefly
Treatments : as given in treatment details
Plot size : 40 sq.m
Spacing : 120 cm x 60 cm
Time of Application : 70 days after transplanting.

Method of Application: Foliar spray with knapsack sprayer
Water volume : 460 liter/hectare
Agronomic Practices : All agronomic practices followed as per the crop requirement
except insect control.
Observation Methods:
Whitefly (Bemisia tabaci) control (%): Count the number of whitefly per leaf and 3
leaves per plant. Record the observations from 10 plants per plot. Calculate %
whitefly control (observed value). Record the observations at before spray and 7 days
after spray.
Number of Whitefly in Untreated Check (UTC) - Number of Whitefly in Treatment
% Whitefly control = X 100
Number of Whitefly in Untreated Check (UTC)
Fruit borer (Helicoverpa armigera) larval control (%): Count the number of live larvae per plant. Record the observations from 10 plants per plot. Calculate % fruit borer larval control (observed value). Record the observations at before spray and 7 days after spray. Apply Colby's formula to whitefly control (%) and fruit borer larval control (%) data to calculate synergism.
Healthy Fruit count: Count the number of healthy tomato fruits per plant, record observations from 10 plants per plot at 14 days after spray and calculate % increase in healthy fruits over untreated control (UTC).
Table 3-Treatment details

Treatment Number Treatment details Use Rate
g.a.i./h
Tl Tolfenpyrad 10%+Broflanilide 1%+Afidopyropen 4% SE 80+8+32
T2 Tolfenpyrad 10%+Broflanilide 1%+Flonicamid 5% SE 80+8+40
T3 Tolfenpyrad 10%+Broflanilide 1%+Pyrifluquinazon 5% SE 80+8+40
T4 Tolfenpyrad 10%+Isocycloseram 5%+Afidopyropen 4% OD 80+40+32
T5 Tolfenpyrad 10%+Isocycloseram 5%+Flonicamid 5% OD 80+40+40
T6 Tolfenpyrad 10%+Isocycloseram 5%+Pyrifluquinazon 5% OD 80+40+40
T7 Tolfenpyrad 15% EC+Broflanilide 30% SC (tank mix) 80+8
T8 Tolfenpyrad 15% EC+Isocycloseram 20% SC (tank mix) 80+40
T9 Tolfenpyrad 15% EC+Afidopyropen 5% DC (tank mix) 80+32
T10 Tolfenpyrad 15% EC+Flonicamid 50% WG (tank mix) 80+40
Til Tolfenpyrad 15% EC+Pyrifluquinazon 20% SC (tank mix) 80+40
T12 Broflanilide 30% SC+Afidopyropen 5% DC (tank mix) 8+32
T13 Broflanilide 30% SC+Flonicamid 50% WG (tank mix) 8+40
T14 Broflanilide 30% SC+Pyrifluquinazon 20% SC (tank mix) 8+40
T15 Isocycloseram 20% SC+Afidopyropen 5% DC (tank mix) 40+32
T16 Isocycloseram 20% SC+Flonicamid 50% WG (tank mix) 40+40
T17 Isocycloseram 20% SC+Pyrifluquinazon 20% SC (tank mix) 40+40

T18 Tolfenpyradl5%EC 80
T19 Broflanilide 30% SC 8
T20 Isocycloseram 20% SC 40
T21 Afidopyropen 5% DC 32
T22 Flonicamid 50% WG 40
T23 Pyrifluquinazon 20% SC 40
T24 UTC (Untreated Control) 0
Tl to T6 were innovative ready-mix treatments, T7 to T17 were conventional treatments.
Table 4-Control of whitefly and fruit borer larvae in tomato crop.

Treatment Number Whitefly control (%) Fruit borer larval control (%) Synergism
(Y/N) Increase(%) in
healthy fruits
over T24

OV EV Ratio O/E OV EV Ratio O/E

Tl 96.20 91.39 1.05 96.80 88.44 1.09 Y 110.7
T2 95.80 90.52 1.06 95.20 88.67 1.07 Y 105.9
T3 94.60 89.94 1.05 96.40 88.54 1.09 Y 108.4
T4 93.80 89.59 1.05 94.20 86.40 1.09 Y 101.4
T5 95.20 88.55 1.08 95.60 86.68 1.10 Y 106.3
T6 94.40 87.85 1.07 93.80 86.53 1.08 Y 102.6
T7 73.60 75.94 0.97 85.60 87.04 0.98 N 92.6
T8 68.40 70.93 0.96 82.80 84.76 0.98 N 88.7
T9 85.80 87.18 0.98 58.60 60.93 0.96 N 68.3
T10 83.40 85.89 0.97 59.40 61.72 0.96 N 65.3
Til 84.20 85.04 0.99 60.20 61.28 0.98 N 70.4
T12 73.80 75.94 0.97 71.40 73.60 0.97 N 82.4
T13 71.20 73.52 0.97 72.40 74.13 0.98 N 81.5
T14 70.60 71.91 0.98 70.60 73.83 0.96 N 79.8
T15 68.60 70.93 0.97 65.80 68.96 0.95 N 77.4
T16 65.40 68.01 0.96 67.40 69.58 0.97 N 74.6
T17 64.60 66.06 0.98 66.80 69.24 0.96 N 72.7
T18 64.20 56.20 41.8
T19 32.80 70.40 54.8
T20 18.80 65.20 49.2
T21 64.20 10.80 25.8
T22 60.60 12.60 30.6
T23 58.20 11.60 27.3
T24 0.00 0.00 0.0
All the innovative ready-mix treatments (Tl to T6) provides synergistic control of whitefly and tomato fruit borer larvae and also yielded higher number of healthy fruits.

Overall summery of field trials:
The field trials results shows many benefits/advantages of innovative ready mix formulations.
• synergism observed in terms of sucking insects and fruit borer control
• Increase in level of insect-pests (sucking insects and fruit borer) control
• Increase in yield (increase in number of healthy fruits)
• Provides longer duration of control (residual control)
• Increases plant growth, vigor, height, produces a greater number of shoots, branches, flowers, leaves etc. and overall biomass of the crop, which directly increases the yield of the crop.

CLAIMS

We claim;

[CLAIM 1]. A synergistic pesticidal composition comprising:
a. an insecticide Tolfenpyrad present in amount of 0.1 to 40% w/w;
b. an insecticide selected from class of diamide; metadiamde;
isoxazoline or mixtures thereof present in amount of 0.1 to 40%;
c. at least one more insecticide selected from the class of
chordotonal organ modulators or mixture thereof present in
amount of 0.1 to 30%.
d. inactive formulation excipients.
[CLAIM 2]. The synergistic pesticidal composition as claimed in claim 1, wherein an insecticide from class of diamides is selected from chlorantraniliprole, cyantraniliprole, cyclaniliprole, cyproflanilide, tetrachlorantraniliprole, tyclopyrazoflor, cyhalodiamide, flubendiamide, tetraniliprole or mixture thereof; an insecticide from class of metadiamde is broflanilide; an insecticide from class of isoxazoline is selected from fluxametamide, isocycloseram or mixtures thereof; an insecticide from chordotonal organ modulators is selected from afidopyropen, flonicamid, pymetrozine or pyrifluquinazon or mixture thereof.
[CLAIM 3]. The synergistic pesticidal composition as claimed in claim 1, wherein the formulation for the said composition is selected from Capsule suspension (CS), Dispersible concentrate (DC), Emulsifiable concentrate (EC), Emulsion, water in oil (EO), Emulsion, oil in water (EW), Jambo balls or bags (bags in water soluble pouch), Micro-emulsion (ME), Oil dispersion (OD), Oil miscible flowable concentrate (oil miscible suspension (OF), Oil miscible liquid (OL), Suspension concentrate (SC), Suspo-emulsion (SE), Soluble concentrate (SL), Water dispersible granule (WG or WDG), Water soluble granule (SG), Water soluble powder (SP), Wettable powder (WP), A mixed

formulation of CS and SC (ZC), A mixed formulation of CS and SE (ZE), A mixed formulation of CS and EW (ZW), Granule (GR) / Soil Applied Granules (SAG), Controlled release granules (CR).

l. ii. iii. iv.
v.
vi.
vii.
[CLAIM 4]. The synergistic pesticidal composition as claimed in claim 1 and claim 3, wherein the preferred combinations of active ingredients in the composition of the Oil Dispersion (OD) formulation comprises:
TolfenpyradlO% +Tetraniliprole5%+ Afidopyropen4%; TolfenpyradlO% +Tetraniliprole5%+ Flonicamid5%; TolfenpyradlO% +Cyantraniliprole5%+ Afidopyropen4%; TolfenpyradlO% +Tetraniliprole5%+ Pyrifluquinazon5%; TolfenpyradlO% +Isocycloseram5%+ Afidopyropen4%; TolfenpyradlO% +Isocycloseram5%+ Flonicamid5%; TolfenpyradlO% +Isocycloseram5%+ Pyrifluquinazon5%.
[CLAIM 5]. The synergistic pesticidal composition as claimed in claim l-claim4, wherein, the Oil Dispersion (OD) formulation comprises:
i. an insecticide Tolfenpyrad present in amount of 0.1 to 40% w/w;
ii. an insecticide selected from Tetraniliprole, Cyantraniliprole,
Isocycloseram or mixtures thereof present in amount of 0.1 to
40%;
iii. at least one more insecticide selected from Afidopyropen,
Flonicamid, Pyrifluquinazon or mixture thereof present in
amount of 0.1 to 30%.
iv. Wetting-spreading-penetrating agent in an amount of 2 to 6 %
by weight; v. Dispersing agent in an amount of 2 to 8 % by weight; vi. Emulsifying agent in an amount of 6 to 10 % by weight; vii. Stabilizer in an amount of 0.5 to 4% by weight; viii. Antifoaming agent in an amount of 0.1 to 1.5 % by weight; ix. Preservative in an amount of 0.1 to 0.5 % by weight; x. Anti-freezing agent in an amount of 2 to 6 % by weight;

xi. Carrier as solvent in an amount of 40 to 70% by weight.
[CLAIM 6]. The synergistic pesticidal composition as claimed in claim 5, wherein Wetting-spreading-penetrating agent is selected from Organo silicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof.
[CLAIM 7]. The synergistic pesticidal composition as claimed in claim 5, wherein emulsifying agent is selected from castor oil ethoxylates, alcohol ethoxylates, fatty acid ethoxylates, sorbitan ester ethoxylates, sulphosuccinate, calcium salts of dodecyl benzene sulphonate, alkyl ammonium salts of alkyl benzene sulphonate, alkyl sulphosuccinate salts, ethylene oxide-propylene oxide block copolymers, ethoxylated alkylamines, ethoxylated alkyl phenols, polyoxyethylene sorbitan monolaurate.
[CLAIM 8]. The synergistic pesticidal composition as claimed in claim 5, wherein dispersing agent is selected from alkyl sulfonates, alkyl benzene sulfonates, alkyl aryl sulfonates, alkyl phenol alkoxylates, tristyryl phenol ethoxylates, natural or synthetic fatty ethoxylate alcohols, natural or synthetic fatty acid alkoxylates, natural or synthetic fatty alcohols alkoxylates, alkoxylated alcohols (such as n-butyl alcohol poly glycol ether), block copolymers (such as ethylene oxide-propylene oxide block copolymers and ethylene oxide-butylene oxide block copolymers), fatty acid-polyalkylene glycol condensates, polyamine-fatty acid condensates, polyester condensates, salts of polyolefin condensates, sodium ligno sulfonate, sodium ploy carboxylate, EO/PO based copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propylene oxide-ethylene oxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyryl phenol-poly

glycol ether-phosphate, tristyryl phenole with 16 moles EO, tristyryl phenol-poly glycol ether-phosphate, oleyl-polyglycol ether with ethylene oxide, tallow fatty amine polyethylene oxide, nonyl phenol poly glycol ether with 9-10 moles ethylene oxide.
[CLAIM 9]. The synergistic pesticidal composition as claimed in claim 5, wherein antifoaming agent is selected from silicone oil, silicone compound, CIO ~C20 saturated fat acid compounds or C8~C10 aliphatic alcohols compound, silicone antifoam emulsion, dimethyl siloxane, poly dimethyl siloxane, vegetable oil based antifoam, tallow based fatty acids, poly alkylene oxide modified polydimethylsiloxane.
[CLAIM 10]. The synergistic pesticidal composition as claimed in claim 5, wherein Carrier as solvent or diluting agent is selected from vegetable or plant or seed oil or its alkylated oil or alkylated oil of vegetable oil, alkylated oil (alkylated vegetable oil) may be methylated or ethylated oil of the vegetable oil, wherein vegetable oil are olive oil, kapok oil, castor oil, papaya oil, camellia oil, sesame oil, corn oil, rice bran oil, peanut oil, cotton seed oil, soybean oil, groundnut oil, rapeseed oil, linseed oil, tung oil, sunflower oil, safflower oil, coconut oil, alkyl ester of vegetable oils, (e.g. rapeseed oil methyl ester or rapeseed oil ethyl ester, rapeseed oil propyl esters, rapeseed oil butyl esters, neem oil, tall oil fatty acids esters etc.), diesel, mineral oil, fatty acid amides (e.g. CI -C3 amines, alkylamines or alkanolamines with C6 - Ci8 carboxylic acids), fatty acids, tall oil fatty acids, alkyl esters of fatty acids (e.g. Ci, Methyl and ethyl oleate, methyl and ethyl soyate, alkyl benzenes and alkylnaphthalenes, polyalkylene glycol ethers, fatty acid diesters, fatty alkylamides and diamides, dialkylene carbonates, ketones and alcohols or mixture thereof.
[CLAIM 11]. The synergistic pesticidal composition as claimed in claim 5, wherein stabiliser is selected from hectorite clay, aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.

[CLAIM 12]. The synergistic pesticidal composition as claimed in claim land claim 3, wherein preferred combinations of active ingredients in the composition of the Suspo-emulsion (SE) formulation comprises: i. Tolfenpyrad 10% +Chlorantraniliprole2.5% + Afidopyropen4%; ii. Tolfenpyrad 10% +Chlorantraniliprole2.5% + Flonicamid5%; iii. Tolfenpyrad 10% +Broflanilidel% +Afidopyropen4%; iv. Tolfenpyrad 10% +Broflanilidel% +Flonicamid5%; v. Tolfenpyrad 10% +Broflanilidel% +Pyrifluquinazon5%; vi. Tolfenpyrad 10% +Cyhalodiamide4% +Afidopyropen4%; vii. Tolfenpyrad 10% +Cyhalodiamide4% +Flonicamid5%; viii. Tolfenpyradl0%)+Chlorantraniliprole2.5%)+ Pyrifluquinazon5%);
[CLAIM 13]. The synergistic pesticidal composition as claimed in claim 1 and claim 3 wherein, the Suspo-emulsion (SE) formulation comprises:
i. an insecticide Tolfenpyrad present in amount of 0.1 to 40% w/w; ii. an insecticide selected from Chlorantraniliprole, Broflanilide, Cyhalodiamide or mixtures thereof present in amount of 0.1 to 40%; iii. at least one more insecticide selected from Afidopyropen, Flonicamid, Pyrifluquinazon or mixture thereof present in amount of 0.1 to 30%; iv. Solvent in an amount of 8 to 12 % by weight; v. Wetting-spreading-penetrating agent in an amount of 2 to 6 % %
by weight; vi. Dispersing agent 1 in an amount of 2 to 8 % by weight; vii. Dispersing agent 2 in an amount of 1 to 3 % by weight; viii. Suspending agent in an amount of 0.2 to 4.0 % by weight; ix. Antifoaming agent in an amount of 0.1 to 1.5 % by weight; x. Preservative in an amount of 0.1 to 0.5 % by weight; xi. Antifreezing agent in an amount of 2 to 6 % by weight; xii. Thickener in an amount of 0.1 to 1.0 % by weight; xiii. Diluent Water in an amount of 40 to 70 % by weight.

[CLAIM 14]. The synergistic pesticidal composition as claimed in claim 13, wherein Emulsifier is selected from salts of dodecyl benzene sulphonate, Ca-salts or amine salts, and sulphonates of other CI 1-CI6 alkyl benzenes, alkyl ether sulphates, alkyl phenol ether phosphates and ester phosphates; non-ionic surfactants such as alkoxylated alcohols and alkyl phenols, ethoxylated fatty acids, ethoxylated vegetable oils, e.g. ethoxylated castor oil, fatty acid esters, e.g. of sorbitol, and their ethoxylated derivatives, ethoxylated amines, and condensates of glycerol; and catanionic emulsifiers such as a cationic amine, optionally in combination with an alkyl sulphonate or ether sulphonate or ether phosphate, alkoxylated alcohols; alkoxylated alkyl phenols; ethoxylated fatty acids; ethoxylated vegetable oils; ethoxylated tristyrylphenol; fatty acid esters of sorbitol and ethoxylated derivatives thereof; ethoxylated amines and condensates of glycerol; sulfonated alkyl benzenes in the range C11-C16 and salts thereof; alkyl ether sulphates; alkyl ether phosphates; alkyl phenol ether phosphates; or combinations thereof; salts of phosphate esters of ethoxylated tristyrylphenol; salts of sulphated ethers of ethoxylated tristyrylphenol; or a catanionic system, wherein a cationic amine is present in combination with an alkyl sulphonate, an alkyl ether sulphonate, an ether sulphate, or an ether phosphate such as an alkyl ether phosphate, nonyl phenol poly ethoxy ethanols, castor oil polyglycol ethers, poly adducts of ethylene oxide and polypropylene, tributyl phenoxy polyethoxy ethanol, octyl phenoxy polyethoxy ethanol.
[CLAIM 15]. The synergistic pesticidal composition as claimed in claim 13, wherein Stabilizer is selected from butylated hydroxy toluene (BHT) and epoxidized soybean oil (ESBO), Epichlorhydrin.
[CLAIM 16]. The synergistic pesticidal composition as claimed in claim 13, wherein dispersing agent is selected from polyesters, polyamides, poly-carbonates, polyurea and polyurethanes, acrylic polymers and copolymers, styrene copolymers, butadiene copolymers, polysaccharides such as starch and cellulose derivatives, vinylalcohol,

vinylacetate and vinylpyrrolidone polymers and copolymers, polyethers, epoxy, phenolic and melamine resins, polyolefins and define copolymers and mixtures thereof, preferred polymers are acrylate polymers such as poly(methacrylate), poly(ethyl methacrylate), poly(methylmethacrylate), acrylate copoylmers and styrene-acrylic copolymers as defined herein below, poly (styrene-co maleic anhydride), cellulosic polymers such as ethyl cellulose, cellulose acetate, cellulose acetatebutyrate, acetylated mono, di, and triglycerides, poly(vinylpyrrolidone), vinyl acetate polymers and copolymers, poly(alkylene glycol), styrene butadiene copolymers, poly(orthoesters), alkyd resins, and mixtures of two or more of these, biodegradable polymers, biodegradable polyesters, starch, polylactic acid starch blends, polylactic acid, poly(lactic acid-glycolic acid) copolymers, polydioxanone, cellulose esters, ethyl cellulose, cellulose acetate butyrate, starch esters, starch esteraliphatic polyester blends, modified corn starch, polycaprolactone, poly(namylmethacrylate), wood rosin, polyanhydrides, polyvinylalcohol, polyhydroxybutyratevalerate, biodegradable aliphatic polyesters, and polyhydroxybutyrate or mixtures thereof. The examples of dispersing agents are alkylated naphthalene sulfonate, sodium salt, sodium salt of naphthalene sulfonate condensate, sodium ligno sulfonate, sodium ploycarboxylate, EO/PO block copolymer, phenol sulfonate, sodium methyl oleoyl taurate, styrene acrylic acid copolymer, propyleneoxide-ethyleneoxide-copolymer, polyethylene glycol 2,4,6-tristyrylphenyl ether, tristyrylphenol-polyglycolether-phosphate, tristyrylphenole with 16 moles EO, tristyrylphenol-polyglycolether-phosphate, oleyl-polyglycolether with ethylene oxide, tallow fattyamine polyethylene oxide, nonylphenol polyglycolether with 9-10 moles ethylene oxide
[CLAIM 17]. The synergistic pesticidal composition as claimed in claim 13, wherein buffering agent is selected from as used herein is selected from group consisting of calcium hydroxyapatite, Potassium Dihydrogen Phosphate, Sodium Hydroxide, carbonated apatite, calcium carbonate,

sodium bicarbonate, tricalcium phosphate, calcium phosphates, carbonated calcium phosphates, amine monomers, lactate dehydrogenase and magnesium hydroxide.
[CLAIM 18]. The synergistic pesticidal composition as claimed in claim 13, wherein Wetting-spreading-penetrating agent is selected from Organo silicone surfactants includes trisiloxane ethoxylate, polydimethylsiloxane, polyoxyethylene methyl polysiloxane, polyoxyalkylene methyl polysiloxane, polyether polymethyl siloxane copolymer, modified heptamethyl trisiloxane, polyether modified polysiloxane, may or may not be in modified form, may be liquid or powder form or mixture thereof.
[CLAIM 19]. The synergistic pesticidal composition as claimed in claim 13, wherein suspending agent is selected from aluminum magnesium silicate, bentonite clay, silica, attapulgite clay.