Abstract: Provided is a thermoplastic resin composition which exhibits excellent moldability and enables the achievement of a molded article that has excellent chemical resistance especially excellent chemical resistance in TD. A thermoplastic resin composition according to the present invention is obtained by blending in the presence of a rubbery polymer (r) 10 60 parts by weight of a graft copolymer (B) which is obtained by graft copolymerizing a vinyl monomer mixture (b) that contains at least 10 30% by weight of an aromatic vinyl monomer (b1) 30 80% by weight of an unsaturated carboxylic acid alkyl ester monomer (b2) and 1 10% by weight of a vinyl cyanide monomer (b3) into 40 90 parts by weight of a vinyl copolymer (A) which is obtained by copolymerizing a vinyl monomer mixture (a) that contains at least 5 40% by weight of an aromatic vinyl monomer (a1) 30 80% by weight of an unsaturated carboxylic acid alkyl ester monomer (a2) and 10 50% by weight of a vinyl cyanide monomer (a3). This thermoplastic resin composition is characterized in that the number average molecular weight of the acetone soluble fraction (C) in this thermoplastic resin composition is from 65 000 to 90 000.
CLAIMS: [Claim 1]
A thermoplastic resin composition which is a thermoplastic resin composition produced by blending 40 to 90 parts by weight of a vinyl copolymer (A) prepared by copolymerization of a vinyl monomer mixture (a) comprising at least 5 to 40% by weight of an aromatic vinyl monomer (al), 30 to 80% by weight of an unsaturated alkyl carboxylate ester monomer (a2) , and 10 to 50% by weight of a cyanated vinyl monomer (a3) and 10 to 6 0 parts by weight of a graft copolymer (B) prepared by graft copolymerization of a vinyl monomer mixture (b) comprising at least 10 to 30% by weight of an aromatic vinyl monomer (bl), 30 to 80% by weight of an unsaturated alkyl carboxylate ester monomer (b2), and 1 to 10% by weight of a cyanated vinyl monomer (b3) in the presence of a rubbery polymer (r) ; wherein acetone-soluble content (C) of the thermoplastic resin composition has a number average molecular weight of 65,000 to 90,000. [Claim 2]
A thermoplastic resin composition according to claim 1 wherein the acetone-soluble content (C) of the thermoplastic resin composition has an acrylonitrile content of 8 to 50% by weight, and acetone-insoluble content (D) of the thermoplastic resin composition has an acrylonitrile content of 1 to 5% by weight. [Claim 3]
A thermoplastic resin composition according to claim 1 or 2 wherein the acetone-soluble content (C) of the thermoplastic resin composition has a dispersity of 2 . 0 to 2 . 5, and the acetone-soluble content (C) of the thermoplastic resin composition has a content of the component having a molecular weight: of at least 250,000 of 15 to 30% by weight and content
of the component having a molecular weight of less than 50,000 of less than 30% by weight. [Claim 4]
A thermoplastic resin composition according to any one of claims 1 to 3 wherein the vinyl copolymer (A) has a number average molecular weight of 80,000 to 100,000. [Claim 5]
A thermoplastic resin composition according to any one of claim 1 to 4 wherein the vinyl copolymer (A) has a dispersity of up to 2.0. [Claim 6]
A thermoplastic resin composition according to any one of claims 1 to 5 wherein acetone-soluble content of the graft copolymer (B) has a number average molecular weight of 30,000 to 50,000. [Claim 7]
A thermoplastic resin composition according to any one of claims 1 to 6 wherein the acetone-soluble content of the graft copolymer (B) has a dispersity of 2.0 to 2.5. [Claim 8]
A method for producing a thermoplastic resin composition having an acetone-soluble content (C) with a number average molecular weight of 65,000 to 90,000 comprising the steps of: conducting copolymerization of a vinyl monomer mixture (a) comprising 5 to 40% by weight of an aromatic vinyl monomer (al) , 30 to 80% by weight of an unsaturated alkyl carboxylate ester monomer (a2 ) , and 10 to 50% by weight of a cyanated vinyl monomer (a3) to produce a vinyl copolymer (A); conducting graft copolymerization of a vinyl monomer mixture (b) comprising at least 10 to 30% by weight of an aromatic vinyl monomer (bl), 30 to 80% by weight of an unsaturated alkyl carboxylate ester monomer fb2) , and 1 to 10% by weight of a cyanated vinyl monomer
(b3) in the presence of a rubbery polymer (r) to produce a graft copolymer (B); and blending at least 40 to 90 parts by weight of the vinyl copolymer (A) and 10 to 60 parts by weight of the graft copolymer (B).
[Claim 9]
A molded article comprising the thermoplastic resin composition according to any one of claims.
| # | Name | Date |
|---|---|---|
| 1 | 201747019254-RELEVANT DOCUMENTS [30-09-2023(online)].pdf | 2023-09-30 |
| 1 | Description(Complete) [01-06-2017(online)].pdf_54.pdf | 2017-06-01 |
| 2 | 201747019254-Abstract_Granted 353090_07-12-2020.pdf | 2020-12-07 |
| 2 | Description(Complete) [01-06-2017(online)].pdf | 2017-06-01 |
| 3 | CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [01-06-2017(online)].pdf | 2017-06-01 |
| 3 | 201747019254-Claims_Granted 353090_07-12-2020.pdf | 2020-12-07 |
| 4 | 201747019254-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [01-06-2017(online)].pdf | 2017-06-01 |
| 4 | 201747019254-Description_Granted 353090_07-12-2020.pdf | 2020-12-07 |
| 5 | 201747019254-STATEMENT OF UNDERTAKING (FORM 3) [01-06-2017(online)].pdf | 2017-06-01 |
| 5 | 201747019254-Drawings_Granted 353090_07-12-2020.pdf | 2020-12-07 |
| 6 | 201747019254-PRIORITY DOCUMENTS [01-06-2017(online)].pdf | 2017-06-01 |
| 6 | 201747019254-IntimationOfGrant07-12-2020.pdf | 2020-12-07 |
| 7 | 201747019254-POWER OF AUTHORITY [01-06-2017(online)].pdf | 2017-06-01 |
| 7 | 201747019254-Marked up Claims_Granted 353090_07-12-2020.pdf | 2020-12-07 |
| 8 | 201747019254-PatentCertificate07-12-2020.pdf | 2020-12-07 |
| 8 | 201747019254-FORM 1 [01-06-2017(online)].pdf | 2017-06-01 |
| 9 | 201747019254-DRAWINGS [01-06-2017(online)].pdf | 2017-06-01 |
| 9 | 201747019254-FORM 3 [01-12-2020(online)].pdf | 2020-12-01 |
| 10 | 201747019254-DECLARATION OF INVENTORSHIP (FORM 5) [01-06-2017(online)].pdf | 2017-06-01 |
| 10 | 201747019254-FORM 3 [10-06-2020(online)].pdf | 2020-06-10 |
| 11 | 201747019254-COMPLETE SPECIFICATION [01-06-2017(online)].pdf | 2017-06-01 |
| 11 | 201747019254-PETITION UNDER RULE 137 [06-06-2020(online)].pdf | 2020-06-06 |
| 12 | 201747019254-ABSTRACT [05-06-2020(online)].pdf | 2020-06-05 |
| 12 | 201747019254-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [01-06-2017(online)].pdf | 2017-06-01 |
| 13 | 201747019254-CLAIMS [05-06-2020(online)].pdf | 2020-06-05 |
| 13 | 201747019254.pdf | 2017-06-06 |
| 14 | 201747019254-COMPLETE SPECIFICATION [05-06-2020(online)].pdf | 2020-06-05 |
| 14 | 201747019254-Proof of Right (MANDATORY) [24-08-2017(online)].pdf | 2017-08-24 |
| 15 | 201747019254-DRAWING [05-06-2020(online)].pdf | 2020-06-05 |
| 15 | Correspondence by Agent_Form1_28-08-2017.pdf | 2017-08-28 |
| 16 | 201747019254-FER_SER_REPLY [05-06-2020(online)].pdf | 2020-06-05 |
| 16 | 201747019254-FORM 3 [14-11-2017(online)].pdf | 2017-11-14 |
| 17 | 201747019254-OTHERS [05-06-2020(online)].pdf | 2020-06-05 |
| 17 | 201747019254-FORM 3 [30-05-2018(online)].pdf | 2018-05-30 |
| 18 | 201747019254-certified copy of translation [28-05-2020(online)].pdf | 2020-05-28 |
| 18 | 201747019254-FORM 18 [06-07-2018(online)].pdf | 2018-07-06 |
| 19 | 201747019254-FER.pdf | 2019-12-17 |
| 19 | 201747019254-FORM 3 [10-11-2018(online)].pdf | 2018-11-10 |
| 20 | 201747019254-FORM 3 [14-11-2019(online)].pdf | 2019-11-14 |
| 20 | 201747019254-FORM 3 [15-05-2019(online)].pdf | 2019-05-15 |
| 21 | 201747019254-FORM 3 [14-11-2019(online)].pdf | 2019-11-14 |
| 21 | 201747019254-FORM 3 [15-05-2019(online)].pdf | 2019-05-15 |
| 22 | 201747019254-FER.pdf | 2019-12-17 |
| 22 | 201747019254-FORM 3 [10-11-2018(online)].pdf | 2018-11-10 |
| 23 | 201747019254-certified copy of translation [28-05-2020(online)].pdf | 2020-05-28 |
| 23 | 201747019254-FORM 18 [06-07-2018(online)].pdf | 2018-07-06 |
| 24 | 201747019254-OTHERS [05-06-2020(online)].pdf | 2020-06-05 |
| 24 | 201747019254-FORM 3 [30-05-2018(online)].pdf | 2018-05-30 |
| 25 | 201747019254-FER_SER_REPLY [05-06-2020(online)].pdf | 2020-06-05 |
| 25 | 201747019254-FORM 3 [14-11-2017(online)].pdf | 2017-11-14 |
| 26 | 201747019254-DRAWING [05-06-2020(online)].pdf | 2020-06-05 |
| 26 | Correspondence by Agent_Form1_28-08-2017.pdf | 2017-08-28 |
| 27 | 201747019254-COMPLETE SPECIFICATION [05-06-2020(online)].pdf | 2020-06-05 |
| 27 | 201747019254-Proof of Right (MANDATORY) [24-08-2017(online)].pdf | 2017-08-24 |
| 28 | 201747019254-CLAIMS [05-06-2020(online)].pdf | 2020-06-05 |
| 28 | 201747019254.pdf | 2017-06-06 |
| 29 | 201747019254-ABSTRACT [05-06-2020(online)].pdf | 2020-06-05 |
| 29 | 201747019254-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [01-06-2017(online)].pdf | 2017-06-01 |
| 30 | 201747019254-COMPLETE SPECIFICATION [01-06-2017(online)].pdf | 2017-06-01 |
| 30 | 201747019254-PETITION UNDER RULE 137 [06-06-2020(online)].pdf | 2020-06-06 |
| 31 | 201747019254-DECLARATION OF INVENTORSHIP (FORM 5) [01-06-2017(online)].pdf | 2017-06-01 |
| 31 | 201747019254-FORM 3 [10-06-2020(online)].pdf | 2020-06-10 |
| 32 | 201747019254-DRAWINGS [01-06-2017(online)].pdf | 2017-06-01 |
| 32 | 201747019254-FORM 3 [01-12-2020(online)].pdf | 2020-12-01 |
| 33 | 201747019254-FORM 1 [01-06-2017(online)].pdf | 2017-06-01 |
| 33 | 201747019254-PatentCertificate07-12-2020.pdf | 2020-12-07 |
| 34 | 201747019254-Marked up Claims_Granted 353090_07-12-2020.pdf | 2020-12-07 |
| 34 | 201747019254-POWER OF AUTHORITY [01-06-2017(online)].pdf | 2017-06-01 |
| 35 | 201747019254-IntimationOfGrant07-12-2020.pdf | 2020-12-07 |
| 35 | 201747019254-PRIORITY DOCUMENTS [01-06-2017(online)].pdf | 2017-06-01 |
| 36 | 201747019254-Drawings_Granted 353090_07-12-2020.pdf | 2020-12-07 |
| 36 | 201747019254-STATEMENT OF UNDERTAKING (FORM 3) [01-06-2017(online)].pdf | 2017-06-01 |
| 37 | 201747019254-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [01-06-2017(online)].pdf | 2017-06-01 |
| 37 | 201747019254-Description_Granted 353090_07-12-2020.pdf | 2020-12-07 |
| 38 | CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [01-06-2017(online)].pdf | 2017-06-01 |
| 38 | 201747019254-Claims_Granted 353090_07-12-2020.pdf | 2020-12-07 |
| 39 | Description(Complete) [01-06-2017(online)].pdf | 2017-06-01 |
| 39 | 201747019254-Abstract_Granted 353090_07-12-2020.pdf | 2020-12-07 |
| 40 | Description(Complete) [01-06-2017(online)].pdf_54.pdf | 2017-06-01 |
| 40 | 201747019254-RELEVANT DOCUMENTS [30-09-2023(online)].pdf | 2023-09-30 |
| 1 | 2019-12-0517-14-07_06-12-2019.pdf |