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Thermoplastic Resin Composition Method For Producing Same And Molded Article Of Same

Abstract: Provided is a thermoplastic resin composition which exhibits excellent moldability and enables the achievement of a molded article that has excellent chemical resistance especially excellent chemical resistance in TD. A thermoplastic resin composition according to the present invention is obtained by blending in the presence of a rubbery polymer (r) 10 60 parts by weight of a graft copolymer (B) which is obtained by graft copolymerizing a vinyl monomer mixture (b) that contains at least 10 30% by weight of an aromatic vinyl monomer (b1) 30 80% by weight of an unsaturated carboxylic acid alkyl ester monomer (b2) and 1 10% by weight of a vinyl cyanide monomer (b3) into 40 90 parts by weight of a vinyl copolymer (A) which is obtained by copolymerizing a vinyl monomer mixture (a) that contains at least 5 40% by weight of an aromatic vinyl monomer (a1) 30 80% by weight of an unsaturated carboxylic acid alkyl ester monomer (a2) and 10 50% by weight of a vinyl cyanide monomer (a3). This thermoplastic resin composition is characterized in that the number average molecular weight of the acetone soluble fraction (C) in this thermoplastic resin composition is from 65 000 to 90 000.

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
01 June 2017
Publication Number
23/2017
Publication Type
INA
Invention Field
POLYMER TECHNOLOGY
Status
Email
Parent Application
Patent Number
Legal Status
Grant Date
2020-12-07
Renewal Date

Applicants

TORAY INDUSTRIES INC.
1 1 Nihonbashi Muromachi, 2 chome Chuo ku, Tokyo -1038666.

Inventors

1. SHIBATA Takuya
c/o Chiba Plant Toray Industries, Inc. 2 1 Chigusakaigan Ichihara shi Chiba, 2990196.
2. WATANUKI Noboru
c/o Chiba Plant Toray Industries Inc. 2 1 Chigusakaigan Ichihara shi Chiba 2990196
3. SUGA Takanori
c/o Chiba Plant Toray Industries Inc. 2 1 Chigusakaigan Ichihara shi Chiba 2990196
4. SHIODA Saburo
c/o Tokyo Head Office Toray Industries Inc. 1 1 Nihonbashi Muromachi 2 chome Chuo ku Tokyo 1038666

Specification

CLAIMS: [Claim 1]
A thermoplastic resin composition which is a thermoplastic resin composition produced by blending 40 to 90 parts by weight of a vinyl copolymer (A) prepared by copolymerization of a vinyl monomer mixture (a) comprising at least 5 to 40% by weight of an aromatic vinyl monomer (al), 30 to 80% by weight of an unsaturated alkyl carboxylate ester monomer (a2) , and 10 to 50% by weight of a cyanated vinyl monomer (a3) and 10 to 6 0 parts by weight of a graft copolymer (B) prepared by graft copolymerization of a vinyl monomer mixture (b) comprising at least 10 to 30% by weight of an aromatic vinyl monomer (bl), 30 to 80% by weight of an unsaturated alkyl carboxylate ester monomer (b2), and 1 to 10% by weight of a cyanated vinyl monomer (b3) in the presence of a rubbery polymer (r) ; wherein acetone-soluble content (C) of the thermoplastic resin composition has a number average molecular weight of 65,000 to 90,000. [Claim 2]
A thermoplastic resin composition according to claim 1 wherein the acetone-soluble content (C) of the thermoplastic resin composition has an acrylonitrile content of 8 to 50% by weight, and acetone-insoluble content (D) of the thermoplastic resin composition has an acrylonitrile content of 1 to 5% by weight. [Claim 3]
A thermoplastic resin composition according to claim 1 or 2 wherein the acetone-soluble content (C) of the thermoplastic resin composition has a dispersity of 2 . 0 to 2 . 5, and the acetone-soluble content (C) of the thermoplastic resin composition has a content of the component having a molecular weight: of at least 250,000 of 15 to 30% by weight and content

of the component having a molecular weight of less than 50,000 of less than 30% by weight. [Claim 4]
A thermoplastic resin composition according to any one of claims 1 to 3 wherein the vinyl copolymer (A) has a number average molecular weight of 80,000 to 100,000. [Claim 5]
A thermoplastic resin composition according to any one of claim 1 to 4 wherein the vinyl copolymer (A) has a dispersity of up to 2.0. [Claim 6]
A thermoplastic resin composition according to any one of claims 1 to 5 wherein acetone-soluble content of the graft copolymer (B) has a number average molecular weight of 30,000 to 50,000. [Claim 7]
A thermoplastic resin composition according to any one of claims 1 to 6 wherein the acetone-soluble content of the graft copolymer (B) has a dispersity of 2.0 to 2.5. [Claim 8]
A method for producing a thermoplastic resin composition having an acetone-soluble content (C) with a number average molecular weight of 65,000 to 90,000 comprising the steps of: conducting copolymerization of a vinyl monomer mixture (a) comprising 5 to 40% by weight of an aromatic vinyl monomer (al) , 30 to 80% by weight of an unsaturated alkyl carboxylate ester monomer (a2 ) , and 10 to 50% by weight of a cyanated vinyl monomer (a3) to produce a vinyl copolymer (A); conducting graft copolymerization of a vinyl monomer mixture (b) comprising at least 10 to 30% by weight of an aromatic vinyl monomer (bl), 30 to 80% by weight of an unsaturated alkyl carboxylate ester monomer fb2) , and 1 to 10% by weight of a cyanated vinyl monomer

(b3) in the presence of a rubbery polymer (r) to produce a graft copolymer (B); and blending at least 40 to 90 parts by weight of the vinyl copolymer (A) and 10 to 60 parts by weight of the graft copolymer (B).
[Claim 9]
A molded article comprising the thermoplastic resin composition according to any one of claims.

Documents

Application Documents

# Name Date
1 201747019254-RELEVANT DOCUMENTS [30-09-2023(online)].pdf 2023-09-30
1 Description(Complete) [01-06-2017(online)].pdf_54.pdf 2017-06-01
2 201747019254-Abstract_Granted 353090_07-12-2020.pdf 2020-12-07
2 Description(Complete) [01-06-2017(online)].pdf 2017-06-01
3 CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [01-06-2017(online)].pdf 2017-06-01
3 201747019254-Claims_Granted 353090_07-12-2020.pdf 2020-12-07
4 201747019254-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [01-06-2017(online)].pdf 2017-06-01
4 201747019254-Description_Granted 353090_07-12-2020.pdf 2020-12-07
5 201747019254-STATEMENT OF UNDERTAKING (FORM 3) [01-06-2017(online)].pdf 2017-06-01
5 201747019254-Drawings_Granted 353090_07-12-2020.pdf 2020-12-07
6 201747019254-PRIORITY DOCUMENTS [01-06-2017(online)].pdf 2017-06-01
6 201747019254-IntimationOfGrant07-12-2020.pdf 2020-12-07
7 201747019254-POWER OF AUTHORITY [01-06-2017(online)].pdf 2017-06-01
7 201747019254-Marked up Claims_Granted 353090_07-12-2020.pdf 2020-12-07
8 201747019254-PatentCertificate07-12-2020.pdf 2020-12-07
8 201747019254-FORM 1 [01-06-2017(online)].pdf 2017-06-01
9 201747019254-DRAWINGS [01-06-2017(online)].pdf 2017-06-01
9 201747019254-FORM 3 [01-12-2020(online)].pdf 2020-12-01
10 201747019254-DECLARATION OF INVENTORSHIP (FORM 5) [01-06-2017(online)].pdf 2017-06-01
10 201747019254-FORM 3 [10-06-2020(online)].pdf 2020-06-10
11 201747019254-COMPLETE SPECIFICATION [01-06-2017(online)].pdf 2017-06-01
11 201747019254-PETITION UNDER RULE 137 [06-06-2020(online)].pdf 2020-06-06
12 201747019254-ABSTRACT [05-06-2020(online)].pdf 2020-06-05
12 201747019254-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [01-06-2017(online)].pdf 2017-06-01
13 201747019254-CLAIMS [05-06-2020(online)].pdf 2020-06-05
13 201747019254.pdf 2017-06-06
14 201747019254-COMPLETE SPECIFICATION [05-06-2020(online)].pdf 2020-06-05
14 201747019254-Proof of Right (MANDATORY) [24-08-2017(online)].pdf 2017-08-24
15 201747019254-DRAWING [05-06-2020(online)].pdf 2020-06-05
15 Correspondence by Agent_Form1_28-08-2017.pdf 2017-08-28
16 201747019254-FER_SER_REPLY [05-06-2020(online)].pdf 2020-06-05
16 201747019254-FORM 3 [14-11-2017(online)].pdf 2017-11-14
17 201747019254-OTHERS [05-06-2020(online)].pdf 2020-06-05
17 201747019254-FORM 3 [30-05-2018(online)].pdf 2018-05-30
18 201747019254-certified copy of translation [28-05-2020(online)].pdf 2020-05-28
18 201747019254-FORM 18 [06-07-2018(online)].pdf 2018-07-06
19 201747019254-FER.pdf 2019-12-17
19 201747019254-FORM 3 [10-11-2018(online)].pdf 2018-11-10
20 201747019254-FORM 3 [14-11-2019(online)].pdf 2019-11-14
20 201747019254-FORM 3 [15-05-2019(online)].pdf 2019-05-15
21 201747019254-FORM 3 [14-11-2019(online)].pdf 2019-11-14
21 201747019254-FORM 3 [15-05-2019(online)].pdf 2019-05-15
22 201747019254-FER.pdf 2019-12-17
22 201747019254-FORM 3 [10-11-2018(online)].pdf 2018-11-10
23 201747019254-certified copy of translation [28-05-2020(online)].pdf 2020-05-28
23 201747019254-FORM 18 [06-07-2018(online)].pdf 2018-07-06
24 201747019254-OTHERS [05-06-2020(online)].pdf 2020-06-05
24 201747019254-FORM 3 [30-05-2018(online)].pdf 2018-05-30
25 201747019254-FER_SER_REPLY [05-06-2020(online)].pdf 2020-06-05
25 201747019254-FORM 3 [14-11-2017(online)].pdf 2017-11-14
26 201747019254-DRAWING [05-06-2020(online)].pdf 2020-06-05
26 Correspondence by Agent_Form1_28-08-2017.pdf 2017-08-28
27 201747019254-COMPLETE SPECIFICATION [05-06-2020(online)].pdf 2020-06-05
27 201747019254-Proof of Right (MANDATORY) [24-08-2017(online)].pdf 2017-08-24
28 201747019254-CLAIMS [05-06-2020(online)].pdf 2020-06-05
28 201747019254.pdf 2017-06-06
29 201747019254-ABSTRACT [05-06-2020(online)].pdf 2020-06-05
29 201747019254-CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [01-06-2017(online)].pdf 2017-06-01
30 201747019254-COMPLETE SPECIFICATION [01-06-2017(online)].pdf 2017-06-01
30 201747019254-PETITION UNDER RULE 137 [06-06-2020(online)].pdf 2020-06-06
31 201747019254-DECLARATION OF INVENTORSHIP (FORM 5) [01-06-2017(online)].pdf 2017-06-01
31 201747019254-FORM 3 [10-06-2020(online)].pdf 2020-06-10
32 201747019254-DRAWINGS [01-06-2017(online)].pdf 2017-06-01
32 201747019254-FORM 3 [01-12-2020(online)].pdf 2020-12-01
33 201747019254-FORM 1 [01-06-2017(online)].pdf 2017-06-01
33 201747019254-PatentCertificate07-12-2020.pdf 2020-12-07
34 201747019254-Marked up Claims_Granted 353090_07-12-2020.pdf 2020-12-07
34 201747019254-POWER OF AUTHORITY [01-06-2017(online)].pdf 2017-06-01
35 201747019254-IntimationOfGrant07-12-2020.pdf 2020-12-07
35 201747019254-PRIORITY DOCUMENTS [01-06-2017(online)].pdf 2017-06-01
36 201747019254-Drawings_Granted 353090_07-12-2020.pdf 2020-12-07
36 201747019254-STATEMENT OF UNDERTAKING (FORM 3) [01-06-2017(online)].pdf 2017-06-01
37 201747019254-TRANSLATIOIN OF PRIOIRTY DOCUMENTS ETC. [01-06-2017(online)].pdf 2017-06-01
37 201747019254-Description_Granted 353090_07-12-2020.pdf 2020-12-07
38 CLAIMS UNDER RULE 1 (PROVISIO) OF RULE 20 [01-06-2017(online)].pdf 2017-06-01
38 201747019254-Claims_Granted 353090_07-12-2020.pdf 2020-12-07
39 Description(Complete) [01-06-2017(online)].pdf 2017-06-01
39 201747019254-Abstract_Granted 353090_07-12-2020.pdf 2020-12-07
40 Description(Complete) [01-06-2017(online)].pdf_54.pdf 2017-06-01
40 201747019254-RELEVANT DOCUMENTS [30-09-2023(online)].pdf 2023-09-30

Search Strategy

1 2019-12-0517-14-07_06-12-2019.pdf

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