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An Improved Giant Magneto Impedance (Gmi) Based Sensing Device

Abstract: The present invention relates to a compound exhibiting Giant Magneto-Impedance (GMI) properties. The general chemical formula of the compound is (FeXCo100-X)100-(a+ß+?)CraSißB?, characterized in that a<ß and a

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Patent Information

Application #
Filing Date
15 July 2015
Publication Number
03/2017
Publication Type
INA
Invention Field
PHYSICS
Status
Email
mail@lexorbis.com
Parent Application
Patent Number
Legal Status
Grant Date
2019-04-08
Renewal Date

Applicants

Indian Oil Corporation Limited
G-9, Ali Yavar Jung Marg, Bandra (East), Mumbai-400 051, India
Council of Scientific and Industrial Research
Anusandhan Bhawan, 2, Rafi Marg, New Delhi-110001, India

Inventors

1. BHATTACHARYA, Sova
c/o Indian Oil Corporation Limited, R&D Centre, Sector-13, Faridabad-121007, Haryana, India
2. AMIR, Qazi Mohammad
c/o Indian Oil Corporation Limited, R&D Centre, Sector-13, Faridabad-121007, Haryana, India
3. KANNAN, Chandrasekaran
c/o Indian Oil Corporation Limited, R&D Centre, Sector-13, Faridabad-121007, Haryana, India
4. KUMAR, Brijesh
c/o Indian Oil Corporation Limited, R&D Centre, Sector-13, Faridabad-121007, Haryana, India
5. DAS, Biswapriya
c/o Indian Oil Corporation Limited, R&D Centre, Sector-13, Faridabad-121007, Haryana, India
6. PANDA, Ashish Kumar
National Metallurgical Laboratory, Jamshedpur – 831007, Jharkhand, India
7. ROY, Rajat Kumar
National Metallurgical Laboratory, Jamshedpur – 831007, Jharkhand, India
8. DAS, Tarun Kumar
National Metallurgical Laboratory, Jamshedpur – 831007, Jharkhand, India
9. DAS, Swapan Kumar
National Metallurgical Laboratory, Jamshedpur – 831007, Jharkhand, India
10. MITRA, Amitava
National Metallurgical Laboratory, Jamshedpur – 831007, Jharkhand, India

Specification

DESC:DESCRIPTION
FIELD OF THE INVENTION
The present invention relates to a composition exhibiting Giant Magneto-Impedance (GMI) properties. The present invention also relates to a giant magneto-impedance (GMI) based sensing device for detection of carburization in austenitic stainless steel.

BACKGROUND OF THE INVENTION
Damage assessment of structural components used in industries like power, petrochemical, steel etc. is required for prevention of premature failure. Carburization is one of the causes for the failure of steel components in petrochemical industries. Carburization occurs at elevated temperature in the presence of carbon rich gases. Associated phenomenon such as metal dusting, microstructure alteration and brittleness reduce the service life of the industrial components. Thus, evaluation and monitoring of carburization is necessary to avoid catastrophic failure of components. The process of high temperature carburization involves the steps of formation of carbon layer on the surface, inward diffusion of dissolved carbon into the metal, reaction of carbon with carbide forming elements to form carbides of the type Cr23C6 and C7C3. The carbides and the austenitic steel are paramagnetic in nature. However, the formation of these chromium carbides leads to depletion of chromium in the matrix. Consequently there is enrichment of Fe and Ni in the matrix and the material becomes ferromagnetic in nature.
PZT-based sensors are widely used to determine the flaws in structural components. Inductive sensors using ferrite cores are also extensively used for nondestructive testing (NDT). Magnetic sensors with high sensitivity have been investigated for some years to improve the performances of sensing device. Anisotropic magneto-resistance (AMR), giant magneto-resistance (GMR), fluxgate and SQUID sensors have been explored not only for the flaw identification but also evaluation of damages that occur prior to the formation of cracks. Attempts have been made to develop sensing devices using GMI materials.
Austenitic stainless steel have high amount of chromium (16 to 20 %) and nickel (8 to 10 %). Due to high nickel and chromium content the steel remains in austenitic phase even in the room temperature. Hence the material exhibits paramagnetic property. Carburization results in the formation of chromium carbides in the austenitic stainless steel. Chromium carbides are formed because chromium has more affinity to form Carbides than nickel and iron which are present in the material. The carbides generally formed are Cr23C6 and Cr7C3. Due to the formation of these carbides small chromium depleted areas is formed near to carbide sites. These chromium depleted areas will have high relative concentration of iron and nickel. Due to the increase in the concentration of iron and nickel these areas will transform from paramagnetic to ferromagnetic state.
GB 1517096 discloses a device for monitoring carburization by measuring permeability in which the energizing coil is excited at a certain frequency and the e.m.f induced in detecting coil coupled to the energizing coil is measured. The method is not suitable as the ferromagnetic oxides formed in outer surface of tubes also influence the measurement. EP 81304158.9 discloses measurement of carburization in furnace tubes using the method of differential permeability technique. However, such technique has limitation owing to frequency selection criteria to meet the desired penetration depths.
Ferromagnetic behavior of stainless steel due to carburization is studied by various authors. In these studies, the level of carburization of the samples was determined by nondestructive magnetic flux density measurements before they were removed from the tubes. This technique measures the magnetic flux density near the external surface of the tubes by means of a magnetoresistive sensor biased by a small ferrite magnet.

SUMMARY OF INVENTION
This summary is provided to introduce a selection of concepts in a simplified form that are further described below in the detailed description. This summary is not intended to identify key features or essential features of the claimed subject matter, nor is it intended as an aid in determining the scope of the claimed subject matter.
According to one aspect of the invention, a compound of following chemical formula is provided: (FeXCo100-X)100-(a+ß+?)CraSißB?, characterized in that a<ß and a

Documents

Application Documents

# Name Date
1 2679-MUM-2015-RELEVANT DOCUMENTS [30-08-2022(online)].pdf 2022-08-30
1 REQUEST FOR CERTIFIED COPY [13-01-2016(online)].pdf 2016-01-13
2 2679-MUM-2015-RELEVANT DOCUMENTS [25-08-2021(online)].pdf 2021-08-25
2 Drawing [27-01-2016(online)].pdf 2016-01-27
3 Description(Complete) [27-01-2016(online)].pdf 2016-01-27
3 2679-MUM-2015-RELEVANT DOCUMENTS [16-03-2020(online)].pdf 2020-03-16
4 Form 3 [22-07-2016(online)].pdf_38.pdf 2016-07-22
4 2679-MUM-2015-IntimationOfGrant08-04-2019.pdf 2019-04-08
5 Form 3 [22-07-2016(online)].pdf 2016-07-22
5 2679-MUM-2015-PatentCertificate08-04-2019.pdf 2019-04-08
6 Other Patent Document [20-08-2016(online)].pdf_200.pdf 2016-08-20
6 2679-MUM-2015-ABSTRACT [22-03-2019(online)].pdf 2019-03-22
7 Other Patent Document [20-08-2016(online)].pdf_199.pdf 2016-08-20
7 2679-MUM-2015-CLAIMS [22-03-2019(online)].pdf 2019-03-22
8 Other Patent Document [20-08-2016(online)].pdf 2016-08-20
8 2679-MUM-2015-FER_SER_REPLY [22-03-2019(online)].pdf 2019-03-22
9 2679-MUM-2015-OTHERS [22-03-2019(online)].pdf 2019-03-22
9 Request For Certified Copy-Online.pdf 2018-08-11
10 2679-MUM-2015-PETITION UNDER RULE 137 [22-03-2019(online)].pdf 2019-03-22
10 Provisional Specification.pdf 2018-08-11
11 2679-MUM-2015-FER.pdf 2018-09-27
11 Form-2(Online).pdf 2018-08-11
12 2679-MUM-2015-Correspondence-030815.pdf 2018-08-11
12 FORM 5.pdf 2018-08-11
13 2679-MUM-2015-Correspondence-240816.pdf 2018-08-11
13 FORM 3.pdf 2018-08-11
14 2679-MUM-2015-Form 1-240816.pdf 2018-08-11
14 Drawings.pdf 2018-08-11
15 2679-MUM-2015-Power of Attorney-030815.pdf 2018-08-11
15 Council of Scientific & Industrial Research_2286DEL2011_2179US001.pdf 2018-08-11
16 ABSTRACT1.jpg 2018-08-11
17 Council of Scientific & Industrial Research_2286DEL2011_2179US001.pdf 2018-08-11
17 2679-MUM-2015-Power of Attorney-030815.pdf 2018-08-11
18 Drawings.pdf 2018-08-11
18 2679-MUM-2015-Form 1-240816.pdf 2018-08-11
19 2679-MUM-2015-Correspondence-240816.pdf 2018-08-11
19 FORM 3.pdf 2018-08-11
20 2679-MUM-2015-Correspondence-030815.pdf 2018-08-11
20 FORM 5.pdf 2018-08-11
21 2679-MUM-2015-FER.pdf 2018-09-27
21 Form-2(Online).pdf 2018-08-11
22 2679-MUM-2015-PETITION UNDER RULE 137 [22-03-2019(online)].pdf 2019-03-22
22 Provisional Specification.pdf 2018-08-11
23 2679-MUM-2015-OTHERS [22-03-2019(online)].pdf 2019-03-22
23 Request For Certified Copy-Online.pdf 2018-08-11
24 Other Patent Document [20-08-2016(online)].pdf 2016-08-20
24 2679-MUM-2015-FER_SER_REPLY [22-03-2019(online)].pdf 2019-03-22
25 Other Patent Document [20-08-2016(online)].pdf_199.pdf 2016-08-20
25 2679-MUM-2015-CLAIMS [22-03-2019(online)].pdf 2019-03-22
26 Other Patent Document [20-08-2016(online)].pdf_200.pdf 2016-08-20
26 2679-MUM-2015-ABSTRACT [22-03-2019(online)].pdf 2019-03-22
27 Form 3 [22-07-2016(online)].pdf 2016-07-22
27 2679-MUM-2015-PatentCertificate08-04-2019.pdf 2019-04-08
28 Form 3 [22-07-2016(online)].pdf_38.pdf 2016-07-22
28 2679-MUM-2015-IntimationOfGrant08-04-2019.pdf 2019-04-08
29 Description(Complete) [27-01-2016(online)].pdf 2016-01-27
29 2679-MUM-2015-RELEVANT DOCUMENTS [16-03-2020(online)].pdf 2020-03-16
30 Drawing [27-01-2016(online)].pdf 2016-01-27
30 2679-MUM-2015-RELEVANT DOCUMENTS [25-08-2021(online)].pdf 2021-08-25
31 2679-MUM-2015-RELEVANT DOCUMENTS [30-08-2022(online)].pdf 2022-08-30
31 REQUEST FOR CERTIFIED COPY [13-01-2016(online)].pdf 2016-01-13

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