Specification
The title of the invention: the perfume composition reproduce the flavor of orange kkotryu
Art
[1]
The present invention relates to a perfume composition which reproduce the flavor of orange kkotryu, more particularly citrus flower, hagyul flowers, younggyul flower, kumquat flower ( Citrus unshiu , Citrus natsudaidai , Citrus sudachi, and Fortunella japonica reproduces the fragrance of) It relates to a perfume composition.
[2]
This application claims the benefit of priority based on the date of February 06, 2015 Korea Patent Application No. 10-2015-0018549, and all information disclosed in the literature of the Korea patent application is included as part of the specification.
[3]
BACKGROUND
[4]
Citrus ( Citrus unshiu ) is sangrokseong arborescent genus of the Rutaceae Tangerine. Key is the kind that spread no visible 3 ~ 5m. The leaves are offset from the edge of the oval flat and indistinct petiole of the wings. The flowers are white, sepals and petals are 5 pieces each, and pistil is 1, surgery is often. It is distributed in Korea, Japan, Latin America, the Black Sea and elsewhere.
[5]
[6]
Hagyul ( Citrus natsudaidai ) also as sangrokseong arborescent belonging to the genus of the Rutaceae orange, is a key of the spreads 3 ~ 5m. Leaves are elliptical wings on petioles as said shifted thick. In addition, the shallow serrated leaf edge and has a preemption on the front. Flowers are white defendants one by one, the petals are five, pistil is 1, surgery is 30 or less. The fruit is spherical and said piece is a thick rind ripe rough diameter 10 ~ 15cm brass color. Matures in the fall, but depends on the long summer citrus trees called because next year they can eat in the summer. It tastes rich in vitamin C, and is native to Japan.
[7]
[8]
Younggyul ( Citrus sudachi ) is an evergreen shrub belonging to the genus of the Rutaceae Tangerine. Namyeo fruit is sour like lemons or limes, not unlike raw citrus harvested when new Parral. The white flowers bloom Between May and June, it is native to Japan.
[9]
[10]
Kumquats ( Fortunella japonica) is an evergreen shrub belonging to the genus of kumquat and Rutaceae, or a generic name of the fruit. And the average height is about 2.5 to about 4.5m, hear a dark foliage, and even that is visible in the dense branches. Which opens a small oval fruit of 2 ~ 4cm in length and width 3 ~ 5cm. It is native to China and cultivated in East Asia.
[11]
[12]
Citrus is well known to us as the island specialties, it is loved fruit in the winter. As well as the non-single citrus hagyul, younggyul, kumquat also familiar exposed tangerine (橘) is. However, studies on because the bar even though many people have a crush on the flavor of the tangerine kkotryu and is advanced yet research on fragrance composition reproduces the scent of tangerine kkotryu, citrus, hagyul, younggyul, floral scent of kumquat It was made in view of the present invention, based on.
[13]
[14]
As a way to reproduce the flavor of the tangerine kkotryu may be several. For example, it makes the conventional method in a solvent to create a fragrance ingredient of a tangerine flower essential oil in the form kkotryu (Absolute) extraction and fragrance components in essential oil (Essential oil) steam distillation. However, these methods have limitations that must be applied to high heat and because the process is complicated to take a long time may have a lot of difference from the original flavor of the extraction process.
[15]
[16]
Recently, solid phase micro-extraction in order to make up for these shortcomings; method was developed (Solid Phase Micro Extraction, following SPME method international SUPELCO, Vol.13, No.4, p.9-10) and the headspace (Head Space) . Among them, SPME method is disclosed in the literature (SUPELCO international, Vol.13, No.4, p.9-10), the paper is incorporated by reference herein in its entirety. SPME method Unlike conventional extraction without the use of solvents, also requires no pre-treatment, can quickly and easily analyze the fragrance ingredient. However, low affinity, if the production of only the main component of the perfume this way analysis of odor acceptability there are still not enough There limitation to reproduce the scent of the object.
[17]
[18]
Headspace method also has the advantage of not using solvent Unlike conventional extraction method, also requires no pre-treatment, it can quickly and easily analyze the fragrance ingredient. On the other hand, volatile flavor components are good the shortcomings analysis easier, but volatility is low and a large molecular weight flavor components are analyzed by this method is not easy.
[19]
[20]
On the other hand, a gas chromatography (Gas Chromatography: GC) is a very useful instrument for analyzing the qualitative and quantitative analysis of volatile materials have been used extensively for analysis all flavor ingredients. However, while there is also the strong flavor ingredients in the low-concentration threshold value of the fragrance ingredient is very low expression of incense, and its volatile ingredients present threshold value is not very high expression of incense in high concentrations. So simply volatile components that are found through the major quantitative GC is not necessarily to say that the main flavor component of certain substances. To solve this problem, there is used the development analysis using a GC-O (Gas Chromatography Olfactometry, Guth H, Grosch W (1993) Lebensm Wiss U Technol, 196, 22-28). CG-O is a method for identifying a component that really the effort while at the same time to take on the fragrance of analyzing odor components from the peak of the chromatogram peak, but not directly.
[21]
Detailed Description of the Invention
SUMMARY
[22]
The present invention was to solve a point, even though many people have a good impression about the fragrance of citrus flowers, hagyul flowers, younggyul flowers and kumquat flowers and fragrance compositions recreating the smell of these oranges kkotryu is not yet available to the public .
[23]
[24]
Accordingly, it is an object of the invention to provide a fragrance composition having an excellent palatability to reproduce the citrus flower, hagyul flowers, flower younggyul and unique fragrance of flowers each kumquat.
[25]
[26]
The inventors have used an effective method for analyzing the SPME fragrance ingredient of the natural product, it was to reproduce the citrus flower, flower hagyul, younggyul flowers and floral fragrance of kumquat. As a result, it was confirmed that the citrus flowers, hagyul flowers and flower younggyul Lee nalrul (Linalool), myrcene (Myrcene), including a common main ingredient in the fragrance of flowers belonging to the same. This has two components and determine the main fragrance of citrus flowers, and flowers hagyul younggyul flowers, in addition it was found that the main component that determines the presence of each flavor. Was the main component of the citrus flower and the flower hagyul neroli stone (Nerolidol), not bitter methyl carbonyl rate (Methyl anthranilate), the main component of the flowers was younggyul claim geraniol (Geraniol), β- O cymene (β-Ocimene). The main component of kumquat flowers β- O cymene (β-Ocimene), 6- methyl-5-heptene-2-circle (6-Methyl-5-hepten-2one), not bitter aldehyde carbonyl (Anthranilaldehyde), limonene (Limonene) , it was found to be not bitter methyl carbonyl rate (methyl anthranilate). This, but used to prepare a combined fragrance to reproduce the citrus flower, hagyul flowers, younggyul flowers and fragrance of kumquat flower, it was confirmed that the inventors are unable to reproduce the scent of the flowers alone result, these components have performed a sensory evaluation .
[27]
[28]
Accordingly, the specific object of the present invention can be reproduced each by separating the unique flavor difference citrus flower, flower hagyul, younggyul flowers and floral kumquat, to provide a fragrance composition having an excellent palatability.
[29]
[30]
It is another object of the invention is to provide an external preparation for skin containing the above perfume composition.
[31]
Problem solving means
[32]
In order to achieve the above objects, flavoring composition according to the invention additionally jaseumon (Jasmone), β- Caro propylene (β-Caryophyllene) to the main fragrance components of the extract and the analysis citrus flower by SPME method, γ- emitter pinene (γ-Terpinene), α- Parr nesen (α-Farnesene) and the one member selected from the group consisting of containing as an active ingredient, citrus flower, flower hagyul, younggyul fragrance reproducing the odor of flowers and floral kumquat It provides compositions.
[33]
[34]
To this end, the inventors citrus flower, hagyul flowers, younggyul flowers and kumquat to reproduce the scent of flowers a result of the study, citrus flower Li nalrul (Linalool), myrcene (Myrcene), Neroli stone (Nerolidol as a main component ), it was confirmed that the perfume composition containing a bitter not methyl carbonyl rate (methyl anthranilate), and containing, as an active ingredient jaseumon (Jasmone) to reproduce the unique fragrance of.
[35]
[36]
Hagyul flower is the Li nalrul (Linalool), myrcene (Myrcene), Neroli stone (Nerolidol), methyl acrylate not bitter carbonyl β- Caro propylene (β-Caryophyllene) as contained, and the active ingredient (Methyl anthranilate) as a main component the perfume composition containing it was confirmed that it is possible to reproduce the unique fragrance of.
[37]
[38]
Younggyul flowers Li nalrul (Linalool), myrcene (Myrcene), the geraniol (Geraniol), β- O cymene γ- emitter pinene (γ-Terpinene), the active ingredient contains (β-Ocimene) as a main component is a perfume composition containing it was confirmed that it is possible to reproduce the unique fragrance of.
[39]
[40]
Kumquat flowers as a main component β- O cymene (β-Ocimene), 6- methyl-5-heptene-2-circle (6-Methyl-5-hepten-2one), not bitter aldehyde carbonyl (Anthranilaldehyde), limonene (Limonene ), it was confirmed that the perfume composition containing a bitter not methyl carbonyl rate (methyl anthranilate), and containing a Parr nesen α- (α-Farnesene) as an active ingredient, can reproduce these inherent odor.
[41]
[42]
In addition, it was confirmed for all of the perfume composition represents excellent palatability, and completed the present invention.
[43]
[44]
Specifically, look at the means for the problem solution of the present invention, first, in order to reproduce the scent of citrus flower, Li nalrul (Linalool) 60 ~ 69% by weight of myrcene (Myrcene) 4.5 ~ 6.5 wt%, neroli stone (Nerolidol ) 4.2 ~ 5.6 wt.%, provides a perfume composition containing a bitter not add a carbonyl rate (methyl anthranilate) 3.8 ~ 5.3 flavor component and jaseumon (Jasmone) 0.9 ~ 5% by weight, including the weight percent methyl.
[45]
[46]
Second, in order to reproduce the scent of hagyul flowers, Li nalrul (Linalool) 50 ~ 60% by weight, methyl not bitter carbonyl rate (Methyl anthranilate) 18 ~ 23% by weight, neroli stone (Nerolidol) 8 ~ 12% by weight of myrcene (Myrcene) provides a fragrance composition containing a fragrance component and β- Caro propylene (β-Caryophyllene) adding 0.9 to 5% by weight containing 3.8 to 6 wt%.
[47]
[48]
Third, in order to reproduce the scent of flowers younggyul, Li nalrul (Linalool) 53 ~ 62% by weight of myrcene (Myrcene) 10 ~ 15% by weight, the geraniol (Geraniol) 3 ~ 7% by weight, o-cymene β- ( β-Ocimene) it provides a fragrance composition containing a fragrance component and γ- emitter pinene (γ-Terpinene) adding 0.9 to 5% by weight containing 3-5% by weight.
[49]
[50]
Fourth, in order to reproduce the scent of flowers kumquat, β- O cymene (β-Ocimene) 17 ~ 25% by weight of 6-methyl-5-heptene-2-circle (6-Methyl-5-hepten-2-one) 10 to 16% by weight, not bitter carbonyl aldehyde (Anthranilaldehyde) 9 ~ 14% by weight of limonene (limonene) 9 ~ 14% by weight, sore eyes methyl carbonyl rate (methyl anthranilate) 9 ~ flavor components including 14 wt% of α - Parr nesen (α-Farnesene) provides a perfume composition further contains 0.9 to 5% by weight.
[51]
Effects of the Invention
[52]
By perfume composition according to the present invention is to provide a fragrance composition which further comprises an extraction and each jaseumon, β- Caro propylene, γ- emitter pinene, α- Parr nesen the major components of the analysis by the SPME method kkotryu tangerine, tangerine as well as be able to reproduce the flowers, hagyul flowers, younggyul flowers and fragrance of flowers kumquat, also it has the effect of improving the flavor preference.
[53]
Best Mode for Carrying Out the Invention
[54]
The present invention relates to a fragrance reproducing the odor of orange kkotryu composition, the citrus flower, flower hagyul, younggyul flowers and floral fragrance components of kumquat, jaseumon (Jasmone), β- Caro propylene (β-Caryophyllene), γ- emitter to provide a fragrance composition which reproduced compare the fragrance of tangerine kkotryu containing one or more selected from pinene (γ-Terpinene) and α- Parr nesen (α-Farnesene) additionally as an active ingredient. Stage, is mixed with the Unless otherwise noted herein, the active ingredient is by itself to reproduce the flavor of orange kkotryu in the fragrance composition or other components means a component that provides the effect.
[55]
[56]
Tangerine kkotryu in the present invention is to refer to an embodiment the background includes a citrus floral, hagyul flowers, younggyul flowers and kumquat flowers, the scope of the present invention according to the aspects of the present invention is not limited by these examples the in the art to which this invention pertains will be apparent to a person of ordinary skill. Hereinafter, the present invention will be described in more detail.
[57]
[58]
A composition according to one embodiment of the present invention β- Caro propylene (β-Caryophyllene) the jaseumon (Jasmone) a flavor component in citrus flower, the odor component in hagyul flowers, γ- emitter -pinene the fragrance components of younggyul flowers ( the γ-Terpinene), the flavor components of the flower kumquat, by containing added Parr nesen α- (α-Farnesene), each active ingredient, it is possible to reproduce the unique flavor of gyulkkot, can exhibit excellent palatability.
[59]
[60]
Perfume composition of the citrus flower according to one embodiment of the present invention is Li nalrul (Linalool) 60 ~ 69% by weight relative to the total weight of the composition, myrcene (Myrcene) 4.5 ~ 6.5 wt%, neroli stone (Nerolidol) 4.2 ~ 5.6 wt. %, not bitter carbonyl methyl acrylate (methyl anthranilate) 3.8 ~ 5.3% by weight, not bitter aldehyde carbonyl (Anthranilaldehyde) 3 ~ 5.1% by weight of 3,7-dimethyl-octa-1,5-diene-3,7-dimethyl ol (3,7-dimethyl-1,5-octadiene-3,7-diol) 3 ~ 5% by weight, and phenyl acetonitrile (Phenylacetonitrile) 2.8 ~ 4% by weight of 6-methyl-5-heptene-2-circle (6-Methyl-5-hepten-2-one) 1.8 ~ 2.9 wt%, phenyl ethyl alcohol (phenylethyl alcohol) 1.3 ~ 2.6% by weight, limonene (limonene) 1 ~ 2% by weight, indole (indole) 0.1 ~ 1 wt. % and it contains a jaseumon (Jasmone) range of 0.9 to 5% by weight.
[61]
[62]
Perfume composition of hagyul flowers according to one embodiment of the present invention is Li nalrul (Linalool) 50 ~ 60% by weight, not bitter carbonyl rate (Methyl anthranilate) 18 ~ 23% by weight of methyl, neroli stone (Nerolidol) with respect to the total weight of the composition 8-12% by weight of myrcene (myrcene) 3.8 ~ 6 wt%, phenyl ethyl alcohol (phenylethyl alcohol) 1.2 ~ 3% by weight, and phenyl acetonitrile (Phenylacetonitrile) 1 ~ 2.2% by weight of 6-methyl-5-heptene 2-circle (6-methyl-5-hepten-2-one) 0.7 ~ 1.8 wt%, 3,7-dimethyl-octa-1,5-diene-3,7-diol (3,7-dimethyl -1,5-octadiene-3,7-diol) 0.6 ~ 1.2% by weight, limonene (limonene) 0.5 ~ 1 wt%, not bitter aldehyde carbonyl (Anthranilaldehyde) 0.4 ~ 0.9 wt%, indole (indole) 0.3 ~ 0.8 wt. % and contains a β- Caro propylene (β-Caryophyllene) range of 0.9 to 5 wt%.
[63]
[64]
Perfume composition of younggyul flowers according to one embodiment of the present invention is Li nalrul (Linalool) 53 ~ 62% by weight relative to the total weight of the composition, myrcene (Myrcene) 10 ~ 15% by weight, the geraniol (Geraniol) 3 ~ 7 % by weight, o-cymene β- (β-Ocimene) 3 ~ 5 wt%, 3,7-dimethyl-octa-1,5-diene-3,7-diol (3,7-dimethyl-1,5- octadiene-3,7-diol) 3 ~ 5 wt%, phenyl ethyl alcohol (phenylethyl alcohol) 2 ~ 4 wt%, and phenyl acetonitrile (Phenylacetonitrile) 1.9 ~ 3.7 wt%, β- Caro propylene (β-Caryophyllene) 1.7 to 3.3% by weight of limonene (limonene) 1.4 ~ 3% by weight of 6-methyl-5-heptene-2-circle (6-methyl-5-hepten-2-one) 1 ~ 2% by weight, no day-to-day (Nonanal) 0.7 ~ 1.5% by weight, indole (indole) contains 0.1 to 1 weight% and γ- emitter pinene (γ-Terpinene) range of 0.9 to 5% by weight.
[65]
[66]
Perfume compositions of the floral kumquat according to one embodiment of the present invention, based on the total weight of the composition β- O cymene (β-Ocimene) 17 ~ 25% by weight of 6-methyl-5-heptene-2-circle (6-Methyl- 5-hepten-2-one) 10 ~ 16% by weight, not bitter carbonyl aldehyde (Anthranilaldehyde) 9 ~ 14% by weight of limonene (limonene) 9 ~ 14% by weight, sore eyes methyl carbonyl rate (methyl anthranilate) 9 ~ 14 wt. %, ethyl acetate (ethyl acetate) 5 ~ 8 wt%, Li nalrul (Linalool) 4 ~ 6% by weight, no day-to-day (Nonanal) 4 ~ 6% by weight, decamethylene day (Decanal) 4 ~ 6% by weight of α- pinene contains an (α-Pinene) 3 ~ 5% by weight of acetophenone (acetophenone) 0.6 ~ 1.7 wt%, indole (indole) 0.1 ~ 1 wt% of α- Parr nesen (α-Farnesene) range of 0.9 to 5% by weight .
[67]
[68]
As a main component to reproduce the flavor of these orange kkotryu, citrus case of flowers and hagyul flower Li nalrul (Linalool), myrcene (Myrcene), Neroli stone (Nerolidol), methyl-not bitter carbonyl rate (Methyl anthranilate) of the range and it should be used within, and younggyul flowers Li nalrul (Linalool), myrcene (myrcene), the geraniol (geraniol), β- O cymene (β-Ocimene) a, kumquat flowers β- O cymene (β-Ocimene) , 6-methyl-5-heptene-2-circle (6-methyl-5-hepten-2-one), not bitter aldehyde carbonyl (Anthranilaldehyde), limonene (limonene), sore not methyl wherein the carbonyl rate (methyl anthranilate) It should be used as a suggested range. When used as other than the above-mentioned range, it is the low odor similarity, it is not preferable palatability of flavor also is lowered. In addition, as an active ingredient, the citrus flower jaseumon (Jasmone), the flower hagyul β- Caro propylene β-Caryophyllene, γ- of younggyul flower emitter pinene (γ-Terpinene) and α- Parr nesen (α-Farnesene) of kumquat flowers also not extend to within the above range can improve the fragrance similarity and preference.
[69]
[70]
By the secondary component other than they do not affect to simulate the flavor of orange kkotryu because preferably used within the proposed range, but does not significantly affect the flavor of orange kkotryu, even in out of the above-described range both It can be contained.
[71]
[72]
The composition according to the present invention perfume, may be blended in the skin external use of the cosmetic base or the like, the amount can be formulated according to conventional techniques in the art, suitably selected to achieve the desired effect. The skin external use based agents include, for example, ointment, lotion, available image, suspensions, emulsions, creams, gels, sprays, Pape claim, warning the patch claim, there is such mulpaseu is not limited to these, in the art the combined also well known compositions and skin external use of any base can be prepared.
[73]
[74]
On the other hand, in the present invention the analysis method of the fragrance ingredient of gyulkkot was used the solid-phase micro extraction (SPME). SPME method can be to quickly removable, injected into the GS-MS column, the fragrance components adsorbed on a fiber (Fiber) without special pre-treatment, because the analysis time can be greatly shortened, which is advantageous in analyzing the fragrance components of a volatile strong gyulkkot . In the present invention, based on the fragrance components of the gyulkkot analysis by the SPME method, the fragrance composition of the combination, and the other hand the preference of similarity and flavor with each gyulkkot odor was carried out through the olfactory sensory test. Sensory evaluation was conducted by an expert perfumer and the general public, citrus flowers, hagyul flowers, fragrance and flavor preference of similarity and younggyul flowers and kumquat flowers were assessed through questionnaires.
[75]
Mode for the Invention
[76]
More specifically the present invention through the following examples, but is of course that the invention is not limited to this, and also other applications and modifications of the invention will be apparent to those skilled in the art.
[77]
[78]
[Reference Example 1] The SPME method citrus flower based hagyul flowers , younggyul flowers , floral odor analysis of kumquat
[79]
By adsorbing the fragrance is strong citrus flower, hagyul flowers, flower younggyul and kumquat flower fragrance component in the fiber (Fiber Polyacrylate) coated with a polyacrylate in 85㎛ for 2 hours to pick one each was collected. Was the absorption for three hours made at a nearby island Seogwiposi farm, and then collecting the fragrance ingredient, and sealing the fiber (Fiber), this gas chromatograph mass spectrometer (Gas Chromatograph-Mass Spectrometer: GC-MS), plug moves to the inlet of then, and for 2 minutes desorption, it was subjected to the GC-MS analysis. GC-MS analysis conditions are as follows.
[80]
[81]
Analysis Conditions
[82]
. Analysis Instruments: HP 5890 II GC
[83]
. Detector: HP 5972 MSD
[84]
. Column (Column): DB-1 (60m X 0.25mm X 0.25um)
[85]
. Move gas (Carrier Gas): He
[86]
. Inlet temperature (Injection Temperature): 250 ℃
[87]
. Detector temperature (Detector Temperature): 280 ℃
[88]
. Oven temperature (Oven Temperature): 70 ℃ ~ (3 ℃ / min) 220 ℃
[89]
. The ionization voltage (Ionization Voltage): 70eV
[90]
. Desorption time: 2 minutes
[91]
[92]
As a result, the flavor components of the gyulkkot analyzed by the SPME method are as shown in Table 1-4.
[93]
TABLE 1
Citrus Floral fragrance ingredient Content ( % )
Lee nalrul 67.25
Myrcene 5.63
Neroli stones 5.17
Not bitter carbonyl methyl acrylate 4.72
Not bitter aldehyde carbonyl 1.57
3,7-dimethyl-octa-1,5-diene-3,7-diol 1.42
Phenyl acetonitrile 1.11
6-methyl-5-heptene-2-circle 0.74
Phenylethyl alcohol 0.57
Limonene 0.52
Indole 0.47
Etc 10.83
The total content 100

[94]
TABLE 2
Hagyul floral fragrance ingredient Content ( % )
Lee nalrul 48.92
Not bitter carbonyl methyl acrylate 18.21
Neroli stones 9.17
Myrcene 4.42
Phenylethyl alcohol 2.15
Phenyl acetonitrile 1.69
6-methyl-5-heptene-2-circle 1.09
3,7-dimethyl-octa-1,5-diene-3,7-diol 0.91
Limonene 0.80
Not bitter aldehyde carbonyl 0.71
Indole 0.64
Etc 11.29
The total content 100

[95]
TABLE 3
Younggyul floral fragrance ingredient Content ( % )
Lee nalrul 57.90
Myrcene 12.23
The geraniol 5.12
beta- 오 시멘 4.31
3,7-dimethyl-octa-1,5-diene-3,7-diol 1.69
Phenylethyl alcohol 1.34
Phenyl acetonitrile 1.25
beta- 카로 필렌 1.18
Limonene 0.82
6-methyl-5-heptene-2-circle 0.51
No-days 0.45
Indole 0.42
Etc 12.78
The total content 100

[96]
TABLE 4
Kumquat floral fragrance ingredient Content ( % )
beta- 오 시멘 20.11
6-methyl-5-heptene-2-circle 12.07
Not bitter aldehyde carbonyl 10.73
Limonene 10.73
Not bitter carbonyl methyl acrylate 10.73
Ethyl acetate 5.31
Lee nalrul 4.1
No-days 4.1
Big Day 4.1
a- 피넨 2.98
Acetophenone 1.2
Indole 0.73
Etc 13.11
The total content 100

[97]
[98]
Table 1, and and, the citrus flower and the hagyul flowers Li nalrul (Linalool), myrcene (Myrcene), Neroli stone (Nerolidol) and not bitter carbonyl rate (Methyl anthranilate) methyl main flavor component, as shown in Figure 2, the major component was found to account for 82.77% of the total, 80.72%, respectively. In addition, as shown in Table 3, younggyul flowers Li nalrul (Linalool), myrcene (Myrcene), the geraniol (Geraniol) and β- O and to the cement (β-Ocimene) as the main flavor component, the major component thereof It was found to account for 79.66% of the total. Finally, as shown in Table 4, kumquat flowers β- O cymene (β-Ocimene), 6- methyl-5-heptene-2-circle (6-Methyl-5-hepten-2one), not bitter carbonyl aldehyde ( Anthranilaldehyde), and and the limonene (limonene) and not bitter carbonyl rate (methyl anthranilate) methyl as the main flavor component, showed that the main component thereof, which accounts for 64.37% of the total.
[99]
[100]
[Reference Example 2] with the spices and natural flavor composition to gyulkkot analysis comparing the sensory evaluation
[101]
Creating a combination perfume (Samples E, F, G, H) having the following composition, based on the result of the analysis of Table 5-8, the fragrance similarity of the combination (scented) and natural gyulkkot verified by a sensory test.
[102]
Table 5
Citrus Floral Fragrance people Content ( % )
Lee nalrul 67.25
Myrcene 5.63
Neroli stones 5.17
Not bitter carbonyl methyl acrylate 4.72
Not bitter aldehyde carbonyl 1.57
3,7-dimethyl-octa-1,5-diene-3,7-diol 1.42
Phenyl acetonitrile 1.11
6-methyl-5-heptene-2-circle 0.74
Phenylethyl alcohol 0.57
Limonene 0.52
Indole 0.47
DPG(solvent) 10.83
The total content 100

[103]
TABLE 6
Hagyul floral fragrance name Content ( % )
Lee nalrul 48.92
Not bitter carbonyl methyl acrylate 18.21
Neroli stones 9.17
Myrcene 4.42
Phenylethyl alcohol 2.15
Phenyl acetonitrile 1.69
6-methyl-5-heptene-2-circle 1.09
3,7-dimethyl-octa-1,5-diene-3,7-diol 0.91
Limonene 0.80
Not bitter aldehyde carbonyl 0.71
Indole 0.64
DPG(solvent) 11.29
The total content 100

[104]
Table 7
Younggyul floral fragrance name Content ( % )
Lee nalrul 57.90
Myrcene 12.23
The geraniol 5.12
beta- 오 시멘 4.31
3,7-dimethyl-octa-1,5-diene-3,7-diol 1.69
Phenylethyl alcohol 1.34
Phenyl acetonitrile 1.25
beta- 카로 필렌 1.18
Limonene 0.82
6-methyl-5-heptene-2-circle 0.51
No-days 0.45
Indole 0.42
DPG(solvent) 12.78
The total content 100

[105]
Table 8
Kumquat flowers perfume person Content ( % )
beta- 오 시멘 20.11
6-methyl-5-heptene-2-circle 12.07
Not bitter aldehyde carbonyl 10.73
Limonene 10.73
Not bitter carbonyl methyl acrylate 10.73
Ethyl acetate 5.31
Lee nalrul 4.1
No-days 4.1
Big Day 4.1
a- 피넨 2.98
Acetophenone 1.2
Indole 0.73
DPG(solvent) 13.11
The total content 100

[106]
[107]
Sensory evaluation was for the general men and women 20 people of 20 to 45 years, citrus flower, a sample of hagyul flowers, younggyul flower, kumquat flower pots A, B, C, D and Sample E, F, G of the combined perfume , they were compared to evaluate the odor of H-functional, in order to prevent after numbness phenomenon was performed to evaluate every five minutes for each sample. By to answer a questionnaire evaluation of normal men and women were 20 to Table 9, were samples A and B Samples of the fragrance similarity (Q1) and the preference of fragrance (Question 2). The results are shown in Table 10.
[108]
Table 9
Survey (1) Question 1: sample A and sample B flavor autumn how similar (similar)? 1) it is not similar at all. 2) it is not similar to each. 3) Just so. 4) it is similar to a certain degree. 5) it is very similar. (2) Question 2: How do you like the smell of the sample B? 1) not good at all. 2) not good. 3) Just so. 4) a little better. 5) very good.

[109]
[Table 10]
Evaluation staff Citrus flowers Hagyul flowers Younggyul flowers Kumquat Flowers
Question 1 Question 2 Question 1 Question 2 Question 1 Question 2 Question 1 Question 2
1 2 2 3 1 1 2 3 2
2 2 3 2 2 2 2 1 1
3 2 2 2 2 2 2 2 2
4 3 3 4 1 3 3 3 3
5 2 3 2 3 2 3 2 3
6 3 1 3 2 3 2 3 4
7 2 3 2 3 2 3 2 2
8 3 2 3 2 3 2 3 2
9 2 2 2 2 2 2 2 2
10 2 1 1 1 1 1 1 1
11 2 3 2 3 2 3 2 3
12 2 2 2 2 1 2 2 2
13 3 2 3 2 3 2 3 2
14 2 4 2 4 2 1 2 4
15 3 2 3 2 3 2 3 2
16 3 3 3 3 3 3 3 3
17 2 3 2 3 2 3 2 3
18 1 4 1 4 1 3 1 4
19 3 2 3 2 3 2 3 2
20 2 1 2 1 2 1 2 1
Average 2.3 2.4 2.35 2.25 2.15 2.2 2.25 2.4

[110]
[111]
As can be seen from Table 10, the combined perfume samples E, F, G, smell of H is a citrus floral, hagyul flowers, younggyul flower, kumquat with pollen samples A, B, C, floral fragrance to the difference D of flowers was born to be displayed, preference is also significantly lower.
[112]
[113]
[Reference Example 3] Comparison of odor and the fragrance analysis and gyulkkot by professional assessors
[114]
The [Reference Example 1] A perfume composition as an ingredient joseonghan analyzed by the SPME method are in the Referential Example 2] As shown in, the low Odor and Germ similarities with each of the flowers. Therefore, the professional assessors consisting perfumer was conducted sensory test with respect to the citrus flower, flower hagyul, younggyul flower and each fragrance component of kumquat flowers. The result of the flavor components of citrus flowers and hagyul flowers, floral woody (floral woody) Lee nalrul, sweet balsamic (sweet balsamic) to create a fragrance and myrcene creating a fragrance refresh (refresh), green floral ( was identified as green floral) a neroli stone to create a fragrance, Murray ski fruity (musky fruity) a four component of the carbonyl-methyl acrylate bitter not produce the flavor is citrus flower and the main component to produce a unique fragrance of flower hagyul.
[115]
[116]
In addition, of the flavor components of younggyul flowers, floral woody (floral woody) one that Li nalrul, sweet balsamic make dreadlocks (sweet balsamic) and refresh (refresh) a fragrance myrcene, sweet floral (sweet floral) a fragrance to produce a that the geraniol, it was confirmed that the worm huh Bridge Earth (warm herbaceous) one of the four components β- five cement to create the fragrance are the main ingredients to create a unique fragrance of flowers make younggyul, of flavor components of kumquat flowers, Earth worms allowed Bridge (warm herbaceous) β- o-cymene, green allowed Bridge Earth (green herbaceous) 6- methyl-5-heptene-2-circle, sweet heavy (heavy sweet) to produce a fragrance to produce a fragrance one write not produce the fragrance carbonyl aldehyde, light sweet sheet rushes (light sweet citrusy) a fragrance inherent in limonene, Murray ski fruity the five components of the carbonyl rate write not methyl creating a odor (musky fruity) kumquat flower that produces dreadlocks It was identified that contain the main ingredient.
[117]
[118]
[ Example 1] Preparation of new perfume combination according to the Contents of the main component
[119]
The Referential Example 3 from a, it was confirmed that the main component of the original flavor of the citrus flower and hagyul flower Li nalrul, myrcene, neroli stone, sore eyes methyl carbonyl rate, the principal component of the younggyul flowers Li nalrul, myrcene, the geraniol, β- o-cymene, a main component of kumquat flower was found to be β- o-cymene, 6-methyl-5-heptene-2-circle, not bitter carbonyl aldehyde, limonene, methyl carbonyl rate not bitter. Thus, the present inventors have found that by containing these components indicating the citrus flower, hagyul flowers, younggyul floral fragrance of kumquat flowers as, palatability to in order to produce a good perfume # A1 ~ A4, # B1 ~ # B4, # C1 ~ # C4, # D1 ~ # D4 made the new combination of spices (represented by flowers from a to D). The combined perfume # A1 ~ A4, # B1 ~ # B4, # C1 ~ # C4, # D1 ~ # D4 are held relative proportion of these citrus flower, hagyul flowers, younggyul flower, kumquat the main fragrance components of the flower is constant while, the content of the main ingredient perfume was prepared by changing to a 60 to 90% by weight (see tables 11-14).
[120]
[Table 11]
Citrus Floral Fragrance people # A1 # A2 # A3 # A4
(60 wt%) (70%) (80 wt%) (90 wt%)
Lee nalrul 48.7 56.9 65.0 73.1
Myrcene 4.1 4.8 5.4 6.1
Neroli stones 3.7 4.4 5.0 5.6
Not bitter carbonyl methyl acrylate 3.4 4.0 4.6 5.1
Not bitter aldehyde carbonyl 9.8 7.2 4.9 2.6
3,7-dimethyl-octa-1,5-diene-3,7-diol 8.9 6.7 4.4 2.2
Phenyl acetonitrile 6.9 5.2 3.5 1.7
6-methyl-5-heptene-2-circle 4.6 3.5 2.3 1.2
Phenylethyl alcohol 3.7 2.7 1.8 0.9
Limonene 3.3 2.4 1.6 0.8
Indole 2.9 2.2 1.5 0.7
The total content 100.0 100.0 100.0 100.0

[121]
[Table 12]
Hagyul floral fragrance name #B1 # B2 # B3 # B4
(60 wt%) (70%) (80 wt%) (90 wt%)
Lee nalrul 36.4 42.4 48.5 54.5
Not bitter carbonyl methyl acrylate 13.5 15.8 18.0 20.3
Neroli stones 6.8 8.0 9.1 10.2
Myrcene 3.3 3.8 4.4 4.9
Phenylethyl alcohol 10.8 8.1 5.4 2.7
Phenyl acetonitrile 8.5 6.3 4.2 2.1
6-methyl-5-heptene-2-circle 5.5 4.1 2.7 1.5
3,7-dimethyl-octa-1,5-diene-3,7-diol 4.6 3.4 2.3 1.1
Limonene 4.0 3.0 2.0 1.0
Not bitter aldehyde carbonyl 3.6 2.7 1.8 0.9
Indole 3 2.4 1.6 0.8
The total content 100.0 100.0 100.0 100.0

[122]
[Table 13]
Younggyul floral fragrance name # C1 # C2 # C3 # C4
(60 wt%) (70%) (80 wt%) (90 wt%)
Lee nalrul 43.7 50.9 58.2 65.5
Myrcene 9.2 10.8 12.3 13.8
The geraniol 3.9 4.5 5.1 5.8
beta- 오 시멘 3.3 3.8 4.3 4.9
3,7-dimethyl-octa-1,5-diene-3,7-diol 8.8 6.6 4.4 2.2
Phenylethyl alcohol 7.0 5.2 3.5 1.7
Phenyl acetonitrile 6.5 4.9 3.3 1.6
beta- 카로 필렌 6.2 4.6 3.1 1.5
Limonene 4.3 3.2 2.1 1.1
6-methyl-5-heptene-2-circle 2.7 2.1 1.5 0.8
No-days 2.3 1.8 1.2 0.6
Indole 2.2 1.6 1.0 0.5
The total content 100.0 100.0 100.0 100.0

[123]
[Table 14]
Kumquat flowers perfume person #D1 # D2 # D3 # D4
(60 wt%) (70%) (80 wt%) (90 wt%)
beta- 오 시멘 18.7 21.9 25.0 28.1
6-methyl-5-heptene-2-circle 11.3 13.1 15.0 16.9
Not bitter aldehyde carbonyl 10.0 11.7 13.3 15.0
Limonene 10.0 11.7 13.3 15.0
Not bitter carbonyl methyl acrylate 10.0 11.7 13.3 15.0
Ethyl acetate 9.4 7.1 4.7 2.4
Lee nalrul 7.3 5.4 3.7 1.8
No-days 7.3 5.4 3.7 1.8
Big Day 7.3 5.4 3.7 1.8
a- 피넨 5.3 4.0 2.6 1.3
Acetophenone 2.1 1.6 1.1 0.6
Indole 1.3 1.0 0.6 0.3
The total content 100.0 100.0 100.0 100.0

[124]
[125]
[ Example 2] Example Sensory Evaluation of a new combination perfume is manufactured by first
[126]
Said Example 1 newly combined in # A1 ~ A4, # B1 ~ # B4, # C1 ~ # C4, # D1 ~ # D4 for fragrance, citrus and floral, hagyul flowers, younggyul flower, kumquat flowers the fragrance similarity and preference above Referential example 2 and was performed by a sensory test in the same way. On the other hand, it was so that the two then conducted to compare the sensory evaluation of the combination of flavors, sensations and then given a break of five minutes palsy symptoms. Sensory evaluation results for the new combination of fragrance and citrus flower, flower hagyul, younggyul floral fragrance similarity and preference of the kumquat flowers are given in Table 15-18.
[127]
[Table 15]
Evaluation staff Question 1 (similarity) Question 2 (preference)
Number citrus floral fragrance combining Number citrus floral fragrance combining
# A1 # A2 # A3 # A4 # A1 # A2 # A3 # A4
1 3.0 3.0 3.0 3.0 2.0 3.0 3.0 3.0
2 2.0 3.0 3.0 2.0 2.0 4.0 4.0 3.0
3 3.0 3.0 4.0 3.0 3.0 3.0 4.0 3.0
4 2.0 3.0 3.0 3.0 2.0 2.0 3.0 2.0
5 3.0 3.0 3.0 2.0 2.0 3.0 4.0 3.0
6 3.0 4.0 3.0 3.0 2.0 2.0 3.0 2.0
7 2.0 3.0 4.0 4.0 3.0 3.0 4.0 3.0
8 2.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0
9 3.0 3.0 4.0 3.0 3.0 3.0 3.0 3.0
10 2.0 2.0 3.0 2.0 2.0 2.0 3.0 2.0
11 2.0 2.0 4.0 3.0 3.0 3.0 4.0 2.0
12 1.0 3.0 3.0 2.0 3.0 2.0 3.0 4.0
13 2.0 2.0 4.0 3.0 2.0 3.0 4.0 3.0
14 2.0 3.0 3.0 2.0 3.0 3.0 3.0 3.0
15 3.0 3.0 3.0 3.0 3.0 3.0 4.0 3.0
16 2.0 2.0 4.0 3.0 2.0 2.0 3.0 2.0
17 1.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0
18 1.0 2.0 3.0 2.0 1.0 2.0 3.0 2.0
19 3.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0
20 2.0 3.0 3.0 3.0 3.0 3.0 2.0 3.0
Average 2.2 2.8 3.3 2.7 2.45 2.8 3.35 2.75

[128]
[Table 16]
Evaluation staff Question 1 (similarity) Question 2 (preference)
Hagyul flowers combined spices numbers Hagyul flowers combined spices numbers
#B1 # B2 # B3 # B4 #B1 # B2 # B3 # B4
1 1.0 2.0 3.0 4.0 1.0 2.0 2.0 3.0
2 2.0 2.0 3.0 3.0 2.0 3.0 3.0 4.0
3 1.0 2.0 3.0 4.0 3.0 3.0 3.0 4.0
4 1.0 3.0 3.0 3.0 2.0 2.0 3.0 3.0
5 3.0 3.0 3.0 3.0 2.0 3.0 3.0 4.0
6 3.0 3.0 3.0 3.0 2.0 2.0 2.0 3.0
7 2.0 3.0 3.0 4.0 3.0 3.0 3.0 4.0
8 2.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0
9 2.0 3.0 3.0 4.0 2.0 3.0 3.0 3.0
10 2.0 2.0 3.0 3.0 1.0 2.0 2.0 3.0
11 2.0 2.0 3.0 4.0 2.0 3.0 3.0 4.0
12 1.0 3.0 3.0 3.0 2.0 2.0 4.0 3.0
13 2.0 2.0 3.0 4.0 2.0 3.0 3.0 4.0
14 2.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0
15 1.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0
16 2.0 2.0 2.0 4.0 2.0 2.0 4.0 3.0
17 1.0 2.0 2.0 3.0 3.0 3.0 3.0 4.0
18 1.0 1.0 1.0 2.0 1.0 2.0 2.0 3.0
19 3.0 3.0 3.0 3.0 2.0 3.0 3.0 4.0
20 1.0 3.0 3.0 3.0 2.0 2.0 2.0 4.0
Average 1.75 2.5 2.8 3.3 2.15 2.6 2.85 3.45

[129]
[Table 17]
Evaluation staff Question 1 (similarity) Question 2 (preference)
Younggyul flowers combined spices numbers Younggyul flowers combined spices numbers
# C1 # C2 # C3 # C4 # C1 # C2 # C3 # C4
1 3.0 3.0 3.0 3.0 2.0 3.0 3.0 3.0
2 2.0 3.0 3.0 2.0 2.0 4.0 4.0 3.0
3 3.0 3.0 4.0 3.0 3.0 3.0 4.0 3.0
4 2.0 3.0 3.0 3.0 2.0 2.0 3.0 2.0
5 3.0 3.0 3.0 2.0 2.0 3.0 4.0 3.0
6 3.0 4.0 3.0 3.0 2.0 2.0 3.0 2.0
7 2.0 3.0 4.0 4.0 3.0 3.0 4.0 3.0
8 2.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0
9 3.0 3.0 4.0 3.0 3.0 3.0 3.0 3.0
10 2.0 2.0 3.0 2.0 2.0 2.0 3.0 2.0
11 2.0 2.0 4.0 3.0 3.0 3.0 4.0 2.0
12 1.0 3.0 3.0 2.0 3.0 2.0 3.0 4.0
13 2.0 2.0 4.0 3.0 2.0 3.0 4.0 3.0
14 2.0 3.0 3.0 2.0 3.0 3.0 3.0 2.0
15 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0
16 2.0 2.0 4.0 3.0 2.0 2.0 3.0 2.0
17 1.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0
18 1.0 1.0 2.0 2.0 1.0 2.0 3.0 2.0
19 3.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0
20 2.0 3.0 3.0 3.0 3.0 3.0 2.0 3.0
Average 2.2 2.75 3.25 2.7 2.45 2.8 3.3 2.7

[130]
[Table 18]
Evaluation staff Question 1 (similarity) Question 2 (preference)
Kumquat floral fragrance combining numbers Kumquat floral fragrance combining numbers
#D1 # D2 # D3 # D4 #D1 # D2 # D3 # D4
1 3.0 4.0 2.0 1.0 2.0 4.0 2.0 2.0
2 2.0 3.0 3.0 2.0 2.0 3.0 3.0 1.0
3 1.0 4.0 3.0 1.0 3.0 3.0 3.0 1.0
4 2.0 3.0 3.0 2.0 2.0 4.0 3.0 3.0
5 3.0 3.0 4.0 2.0 2.0 3.0 3.0 1.0
6 3.0 3.0 2.0 2.0 2.0 3.0 2.0 3.0
7 2.0 3.0 3.0 1.0 3.0 3.0 3.0 1.0
8 2.0 3.0 2.0 2.0 3.0 3.0 4.0 3.0
9 3.0 3.0 3.0 2.0 2.0 3.0 3.0 3.0
10 2.0 4.0 3.0 3.0 1.0 4.0 2.0 2.0
11 2.0 3.0 3.0 1.0 2.0 3.0 3.0 1.0
12 1.0 3.0 3.0 3.0 2.0 3.0 4.0 3.0
13 2.0 4.0 3.0 1.0 2.0 3.0 3.0 2.0
14 2.0 3.0 3.0 2.0 3.0 3.0 3.0 3.0
15 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0
16 2.0 3.0 2.0 1.0 2.0 4.0 3.0 3.0
17 2.0 3.0 2.0 1.0 3.0 3.0 1.0 1.0
18 2.0 4.0 2.0 2.0 1.0 3.0 2.0 3.0
19 3.0 3.0 4.0 3.0 2.0 3.0 3.0 1.0
20 3.0 4.0 3.0 2.0 2.0 3.0 2.0 1.0
Average 2.25 3.3 2.8 1.85 2.2 3.2 2.75 2.05

[131]
[132]
As shown in Table 15-18, citrus flower and younggyul flower sample # A3, # C3 are, hagyul Flower is 90% by weight of the total amount of the main four components the total amount occupies 80% by weight, of the leading four components occupying the sample # B4 is, kumquat flowers will not affect the jyeoteuna showed that the sample # D2 is the total amount of five major components, which account for 70% by weight, with the greatest similarity and preference of each of the combination of flavors, both similarity and preference expectation It showed.
[133]
[134]
[ Example 3] The flavor improving spices prepared by analysis of the professional assessors
[135]
Sample appeared to Table 15-18 The smell of citrus flower, hagyul flowers, younggyul flower, kumquat flower most similar in # A3, # B4, # C3, in order to improve the similarity and preference of the # D2 flavoring, the sample # using additional jaseumon (Jasmone) making have a distinctive flavor to Lee nalrul, myrcene, neroli stones, reproducing the citrus floral fragrance to not bitter containing carbonyl rate in an amount of 80% by weight, and this methyl as in A3 and were prepared the new combination perfume, the unique flavor of Li nalrul, methyl not bitter carbonyl rate, neroli stone, myrcene for the sample # B4 to reproduce the hagyul floral fragrance, and here contains a content of 90% by weight a β- Caro propylene (β-Caryophyllene) to create a new combination has been prepared by adding perfume as a.
[136]
[137]
Also γ- emitter pinene create have a distinctive flavor to Lee nalrul, myrcene, reproduction of the geraniol, younggyul floral fragrance a β- O cement in, and here contains a content of 80% by weight for the samples # C3 ( using an additional γ-Terpinene) was prepared in a novel combination perfume, for the sample # D2 β- o-cymene, 6-methyl-5-heptene-2-circle, not bitter carbonyl aldehyde, limonene, methyl carbonyl not bitter containing acrylate in an amount of 70% by weight, and here a new combination with additional flavoring Parr nesen α- (α-Farnesene) making have a distinctive flavor to the reproduction of kumquat floral fragrance was prepared to.
[138]
[139]
In this case, β- and jaseumon Caro propylene, γ- emitter pinene, α- Parr nesen is added in an amount of 0.9 wt%, 1.5 wt%, 2.1 wt.%, 2.7 wt%, 3.3 wt%, 3.9 wt% and 4.5 wt% It was. Their content was determined by reference to the evaluation of the perfumer experts. The composition of these new combination perfume is shown in Table 19-22.
[140]
[Table 19]
Spices number combination #end #I #All #la #hemp #bar #four
Citrus Floral Fragrance people content(%) content(%) content(%) content(%) content(%) content(%) content(%)
Lee nalrul 65.0 65.0 65.0 65.0 65.0 65.0 65.0
Myrcene 5.4 5.4 5.4 5.4 5.4 5.4 5.4
Neroli stones 5.0 5.0 5.0 5.0 5.0 5.0 5.0
Not bitter carbonyl methyl acrylate 4.6 4.6 4.6 4.6 4.6 4.6 4.6
Not bitter aldehyde carbonyl 4.4 4.3 4.3 4.2 4.2 4.0 4.0
3,7-dimethyl-octa-1,5-diene-3,7-diol 4.2 4.0 3.9 3.8 3.8 3.8 3.3
Phenyl acetonitrile 3.4 3.3 3.2 3.2 3.0 2.9 2.9
6-methyl-5-heptene-2-circle 2.2 2.1 2.0 1.9 1.9 1.8 1.8
Phenylethyl alcohol 1.8 1.7 1.7 1.7 1.6 1.6 1.6
Limonene 1.6 1.6 1.5 1.4 1.3 1.3 1.3
Indole 1.5 1.5 1.3 1.1 0.9 0.7 0.6
Jaseumon 0.9 1.5 2.1 2.7 3.3 3.9 4.5
The total content 100.0 100.0 100.0 100.0 100.0 100.0 100.0

[141]
[Table 20]
Spices number combination #end #I #All #la #hemp #bar #four
Hagyul floral fragrance name content(%) content(%) content(%) content(%) content(%) content(%) content(%)
Lee nalrul 54.5 54.5 54.5 54.5 54.5 54.5 54.5
Not bitter carbonyl methyl acrylate 20.3 20.3 20.3 20.3 20.3 20.3 20.3
Neroli stones 10.2 10.2 10.2 10.2 10.2 10.2 10.2
Myrcene 4.9 4.9 4.9 4.9 4.9 4.9 4.9
Phenylethyl alcohol 2.5 2.3 2.2 2.0 2.0 2.0 1.4
Phenyl acetonitrile 1.9 1.7 1.6 1.4 1.4 1.2 1.2
6-methyl-5-heptene-2-circle 1.4 1.2 1.2 1.0 1.0 0.8 0.8
3,7-dimethyl-octa-1,5-diene-3,7-diol 1.0 1.0 0.9 0.9 0.9 0.7 0.7
Limonene 0.9 0.9 0.8 0.8 0.6 0.6 0.6
Not bitter aldehyde carbonyl 0.8 0.8 0.7 0.7 0.5 0.5 0.5
Indole 0.7 0.7 0.6 0.6 0.4 0.4 0.4
beta- 카로 필렌 0.9 1.5 2.1 2.7 3.3 3.9 4.5
The total content 100.0 100.0 100.0 100.0 100.0 100.0 100.0

[142]
[Table 21]
Spices number combination #end #I #All #la #hemp #bar #four
Younggyul floral fragrance name content(%) content(%) content(%) content(%) content(%) content(%) content(%)
Lee nalrul 58.2 58.2 58.2 58.2 58.2 58.2 58.2
Myrcene 12.3 12.3 12.3 12.3 12.3 12.3 12.3
The geraniol 5.1 5.1 5.1 5.1 5.1 5.1 5.1
beta- 오 시멘 4.3 4.3 4.3 4.3 4.3 4.3 4.3
3,7-dimethyl-octa-1,5-diene-3,7-diol 4.1 4.1 4.0 3.9 3.8 3.8 3.5
Phenylethyl alcohol 3.2 3.2 3.2 3.1 3.0 2.9 2.8
Phenyl acetonitrile 3.1 3.1 2.9 2.9 2.8 2.6 2.5
beta- 카로 필렌 3.0 2.9 2.7 2.7 2.6 2.4 2.3
Limonene 2.1 1.9 1.9 1.8 1.8 1.8 1.8
6-methyl-5-heptene-2-circle 1.5 1.4 1.4 1.3 1.3 1.3 1.3
No-days 1.2 1.1 1.1 1.0 0.9 0.9 0.9
Indole 1.0 0.9 0.8 0.7 0.6 0.5 0.5
y- 터 피넨 0.9 1.5 2.1 2.7 3.3 3.9 4.5
The total content 100.0 100.0 100.0 100.0 100.0 100.0 100.0

[143]
[Table 22]
Spices number combination #end #I #All #la #hemp #bar #four
Kumquat flowers perfume person content(%) content(%) content(%) content(%) content(%) content(%) content(%)
beta- 오 시멘 21.9 21.9 21.9 21.9 21.9 21.9 21.9
6-methyl-5-heptene-2-circle 13.1 13.1 13.1 13.1 13.1 13.1 13.1
Not bitter aldehyde carbonyl 11.7 11.7 11.7 11.7 11.7 11.7 11.7
Limonene 11.7 11.7 11.7 11.7 11.7 11.7 11.7
Not bitter carbonyl methyl acrylate 11.7 11.7 11.7 11.7 11.7 11.7 11.7
Ethyl acetate 7.0 7.0 6.8 6.6 6.6 6.6 6.3
Lee nalrul 5.2 5.1 5.1 5.0 5.0 4.9 4.9
No-days 5.2 5.1 5.1 5.0 5.0 4.9 4.9
Big Day 5.2 5.1 5.1 5.0 5.0 4.9 4.9
a- 피넨 3.9 3.9 3.8 3.7 3.5 3.5 3.4
Acetophenone 1.5 1.3 1.1 1.1 0.9 0.7 0.7
Indole 1.0 0.9 0.8 0.8 0.6 0.5 0.3
a- 파르 네센 0.9 1.5 2.1 2.7 3.3 3.9 4.5
The total content 100.0 100.0 100.0 100.0 100.0 100.0 100.0

[144]
[145]
[ Example 4] Example Sensory evaluation of the combined perfume prepared from 3
[146]
It is in the # # and # the # d # e # bar # four citrus flowers for the combination of flavors, hagyul flowers, younggyul flowers, the [reference to the flavor preference of similarity and flavor of kumquats flowers subjected to the sensory evaluation was performed by the same method as in example 2. After being subjected to comparative sensory evaluation of two perfume combinations, given a break for five minutes, and then the feeling was so numb phenomenon. Results in flavor and fragrance similarity and preference of the new combination of spices and gyulkkot are shown in Table 23-26.
[147]
[Table 23]
Personnel evaluation Question 1 (similarity) Question 2 (preference)
Number citrus floral fragrance combining Number citrus floral fragrance combining
#end #I #All #la #hemp #bar #four #end #I #All #la #hemp #bar #four
1 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 3.0
2 2.0 4.0 4.0 5.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 5.0 4.0 2.0
3 3.0 3.0 3.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0
4 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0
5 4.0 4.0 4.0 5.0 4.0 4.0 4.0 4.0 4.0 4.0 3.0 5.0 4.0 3.0
6 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 4.0 4.0 5.0 5.0 3.0
7 3.0 3.0 4.0 3.0 5.0 4.0 4.0 3.0 4.0 3.0 4.0 4.0 3.0 3.0
8 3.0 4.0 4.0 4.0 4.0 3.0 3.0 2.0 3.0 3.0 4.0 5.0 4.0 2.0
9 2.0 2.0 3.0 3.0 4.0 4.0 3.0 3.0 4.0 3.0 4.0 5.0 4.0 3.0
10 3.0 3.0 3.0 4.0 4.0 4.0 3.0 2.0 3.0 4.0 3.0 4.0 3.0 3.0
11 2.0 4.0 4.0 4.0 4.0 5.0 4.0 4.0 3.0 4.0 4.0 5.0 4.0 2.0
12 3.0 3.0 3.0 4.0 5.0 4.0 3.0 3.0 4.0 4.0 4.0 5.0 5.0 4.0
13 2.0 4.0 4.0 4.0 5.0 3.0 3.0 3.0 3.0 4.0 5.0 5.0 4.0 4.0
14 3.0 3.0 3.0 5.0 5.0 4.0 3.0 3.0 4.0 5.0 4.0 4.0 4.0 3.0
15 4.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 4.0 5.0 4.0 4.0
16 3.0 4.0 4.0 4.0 4.0 5.0 3.0 2.0 3.0 4.0 5.0 4.0 4.0 3.0
17 2.0 3.0 3.0 4.0 5.0 4.0 2.0 3.0 4.0 3.0 4.0 4.0 4.0 3.0
18 4.0 3.0 4.0 4.0 4.0 5.0 3.0 3.0 4.0 4.0 4.0 5.0 5.0 2.0
19 3.0 3.0 3.0 3.0 4.0 4.0 3.0 2.0 3.0 3.0 3.0 4.0 3.0 3.0
20 2.0 3.0 4.0 4.0 5.0 4.0 3.0 2.0 3.0 3.0 4.0 5.0 4.0 2.0
Average 2.85 3.3 3.5 3.95 4.25 3.85 3.1 2.85 3.4 3.55 3.95 4.55 3.9 2.9

[148]
[149]
For citrus flower case be contained in, Li nalrul, myrcene, neroli stone Methyl not bitter add 1.5 to 3.9% by weight jaseumon the main fragrance components of the citrus flower of carbonyl rate as shown in Table 23, the citrus flower of the fragrance can be reproduced, it was confirmed that high palatability (average 3.3 or higher). In particular, if also contain additional jaseumon 2.7 to 3.9% by weight (# d # e # f), the fragrance similarity and preference of fragrance and citrus flower could see very weak (3.8 or later).
[150]
[Table 24]
Personnel evaluation Question 1 (similarity) Question 2 (preference)
Hagyul flowers combined spices numbers Hagyul flowers combined spices numbers
#end #I #All #la #hemp #bar #four #end #I #All #la #hemp #bar #four
1 4.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 5.0 4.0 2.0 2.0
2 3.0 4.0 5.0 3.0 3.0 3.0 2.0 3.0 3.0 4.0 5.0 4.0 3.0 2.0
3 3.0 3.0 4.0 4.0 4.0 3.0 2.0 4.0 4.0 4.0 5.0 4.0 2.0 2.0
4 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 3.0 3.0
5 4.0 4.0 5.0 4.0 4.0 4.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0
6 3.0 3.0 4.0 5.0 4.0 3.0 2.0 4.0 4.0 3.0 3.0 4.0 3.0 3.0
7 3.0 4.0 4.0 5.0 4.0 4.0 3.0 3.0 4.0 3.0 4.0 5.0 4.0 2.0
8 4.0 4.0 4.0 4.0 3.0 3.0 2.0 4.0 4.0 5.0 5.0 4.0 3.0 3.0
9 2.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 2.0 2.0
10 3.0 3.0 4.0 4.0 4.0 3.0 3.0 4.0 4.0 4.0 5.0 4.0 3.0 3.0
11 4.0 4.0 4.0 4.0 5.0 4.0 3.0 3.0 4.0 3.0 4.0 3.0 3.0 3.0
12 3.0 4.0 4.0 5.0 4.0 3.0 2.0 3.0 4.0 4.0 5.0 4.0 2.0 2.0
13 4.0 4.0 4.0 5.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 2.0 2.0
14 3.0 3.0 5.0 5.0 4.0 3.0 3.0 3.0 4.0 5.0 5.0 4.0 4.0 3.0
15 3.0 3.0 3.0 4.0 4.0 3.0 3.0 4.0 3.0 4.0 4.0 3.0 3.0 3.0
16 4.0 4.0 4.0 4.0 5.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0
17 3.0 3.0 4.0 5.0 4.0 2.0 2.0 3.0 4.0 5.0 4.0 3.0 4.0 4.0
18 2.0 3.0 4.0 4.0 5.0 3.0 3.0 4.0 4.0 4.0 4.0 4.0 3.0 3.0
19 3.0 4.0 3.0 4.0 4.0 3.0 3.0 4.0 4.0 4.0 4.0 4.0 3.0 2.0
20 3.0 4.0 4.0 5.0 4.0 3.0 3.0 3.0 3.0 3.0 4.0 3.0 3.0 3.0
Average 3.2 3.55 4.0 4.25 3.9 3.1 2.7 3.35 3.55 3.8 4.25 3.75 2.95 2.7

[151]
[152]
For hagyul flowers, as, Li nalrul, when contained at a rate not bitter carbonyl, neroli stone, adding the propylene β- Caro 0.9 ~ 3.9% by weight of the flower hagyul main flavor component of myrcene methyl seen from Table 24, it is possible to reproduce the fragrance of flowers hagyul, it was found that the palatability is high (average of 2.95 or higher). In particular, when to further contain the propylene β- Caro 2.1 ~ 3.3 weight% (# is # d # e), the fragrance similarity and preference of fragrance and hagyul flowers showed a very excellent (average 3.8 or higher).
[153]
[Table 25]
Personnel evaluation Question 1 (similarity) Question 2 (preference)
Younggyul flowers combined spices numbers Younggyul flowers combined spices numbers
#end #I #All #la #hemp #bar #four #end #I #All #la #hemp #bar #four
1 3.0 3.0 3.0 4.0 4.0 4.0 3.0 2.0 4.0 5.0 4.0 3.0 3.0 2.0
2 3.0 3.0 3.0 5.0 4.0 4.0 2.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0
3 3.0 4.0 4.0 4.0 3.0 3.0 3.0 2.0 4.0 5.0 4.0 4.0 4.0 3.0
4 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0
5 4.0 4.0 4.0 5.0 4.0 4.0 4.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0
6 3.0 3.0 3.0 4.0 3.0 3.0 3.0 3.0 4.0 3.0 3.0 4.0 4.0 4.0
7 4.0 4.0 5.0 3.0 4.0 3.0 3.0 3.0 5.0 4.0 3.0 4.0 3.0 3.0
8 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 4.0 4.0 3.0 4.0 3.0
9 3.0 4.0 4.0 3.0 3.0 2.0 2.0 2.0 4.0 4.0 3.0 3.0 3.0 2.0
10 3.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0 4.0 5.0 4.0 3.0 4.0 3.0
11 4.0 5.0 4.0 4.0 4.0 4.0 2.0 3.0 3.0 4.0 3.0 4.0 3.0 2.0
12 3.0 4.0 5.0 4.0 4.0 3.0 3.0 2.0 4.0 5.0 4.0 4.0 3.0 4.0
13 3.0 3.0 5.0 4.0 4.0 4.0 2.0 2.0 3.0 3.0 3.0 3.0 3.0 3.0
14 3.0 4.0 5.0 5.0 3.0 3.0 3.0 4.0 4.0 5.0 5.0 4.0 3.0 3.0
15 3.0 4.0 4.0 3.0 3.0 3.0 4.0 3.0 3.0 4.0 4.0 3.0 4.0 3.0
16 3.0 5.0 4.0 4.0 4.0 4.0 3.0 4.0 4.0 4.0 3.0 3.0 3.0 3.0
17 2.0 4.0 5.0 4.0 3.0 3.0 2.0 4.0 3.0 4.0 5.0 4.0 3.0 2.0
18 3.0 5.0 4.0 4.0 4.0 3.0 4.0 3.0 3.0 4.0 4.0 3.0 4.0 3.0
19 3.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0
20 3.0 4.0 5.0 4.0 4.0 3.0 2.0 3.0 3.0 4.0 3.0 3.0 3.0 3.0
Average 3.1 3.85 4.15 3.95 3.55 3.3 2.85 2.9 3.55 4.15 3.7 3.4 3.35 2.9

[154]
[155]
For younggyul flower, as seen from Table 25, Li nalrul, myrcene, geraniol claim, when further contain γ- emitter pinene 0.9 ~ 3.9% by weight of the flower younggyul main flavor component of β- o-cymene, it is possible to reproduce the fragrance of flowers younggyul, it was found that the palatability is high (2.9 or higher). In particular, γ- emitter cases to further contain pinene 1.5 ~ 2.7 weight% (or the #, #, #, D), the fragrance similarity and preference of fragrance and younggyul flowers showed a very excellent (average of 3.55 or more).
[156]
[Table 26]
Personnel evaluation Question 1 (similarity) Question 2 (preference)
Kumquat floral fragrance combining numbers Kumquat floral fragrance combining numbers
#end #I #All #la #hemp #bar #four #end #I #All #la #hemp #bar #four
1 3.0 4.0 4.0 4.0 3.0 3.0 3.0 2.0 3.0 3.0 3.0 4.0 4.0 2.0
2 2.0 4.0 4.0 5.0 3.0 3.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0
3 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 4.0 4.0 5.0 4.0 2.0
4 3.0 3.0 3.0 4.0 4.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0
5 4.0 4.0 4.0 5.0 4.0 4.0 4.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0
6 2.0 3.0 3.0 4.0 3.0 3.0 2.0 4.0 3.0 4.0 3.0 3.0 4.0 3.0
7 3.0 3.0 4.0 3.0 5.0 4.0 4.0 3.0 3.0 4.0 3.0 4.0 5.0 3.0
8 3.0 4.0 4.0 4.0 4.0 3.0 3.0 3.0 4.0 3.0 4.0 4.0 3.0 3.0
9 2.0 2.0 3.0 3.0 3.0 4.0 3.0 2.0 3.0 3.0 3.0 4.0 4.0 2.0
10 3.0 3.0 3.0 4.0 4.0 4.0 3.0 3.0 4.0 3.0 4.0 5.0 4.0 3.0
11 2.0 4.0 4.0 3.0 4.0 5.0 4.0 2.0 3.0 4.0 3.0 3.0 3.0 3.0
12 3.0 3.0 4.0 4.0 5.0 4.0 3.0 4.0 4.0 3.0 4.0 5.0 4.0 2.0
13 2.0 4.0 4.0 3.0 5.0 3.0 3.0 3.0 3.0 4.0 3.0 3.0 4.0 2.0
14 3.0 3.0 3.0 5.0 5.0 4.0 3.0 3.0 3.0 4.0 5.0 5.0 4.0 4.0
15 4.0 3.0 4.0 3.0 4.0 4.0 3.0 3.0 4.0 3.0 4.0 4.0 3.0 3.0
16 3.0 4.0 4.0 4.0 4.0 5.0 3.0 3.0 3.0 3.0 3.0 4.0 4.0 4.0
17 2.0 3.0 3.0 4.0 5.0 4.0 2.0 2.0 3.0 4.0 5.0 4.0 3.0 4.0
18 4.0 3.0 4.0 4.0 4.0 5.0 3.0 3.0 4.0 3.0 4.0 4.0 3.0 3.0
19 3.0 3.0 3.0 3.0 4.0 4.0 3.0 3.0 4.0 4.0 4.0 4.0 3.0 3.0
20 2.0 3.0 4.0 4.0 5.0 4.0 3.0 3.0 3.0 3.0 3.0 4.0 3.0 3.0
Average 2.8 3.3 3.6 3.8 4.1 3.85 3.05 2.9 3.3 3.4 3.65 4.05 3.6 2.9

[157]
[158]
Finally, kumquat case of flowers,, β- o-cymene, 6-methyl-5-heptene-2-circle, not bitter carbonyl aldehyde, limonene, not bitter of the main kumquat floral fragrance of carbonyl methyl acrylate as shown in Table 26 when additionally contains α- Parr nesen 1.5 ~ 3.9% by weight of the component, it is possible to reproduce the scent of flowers kumquat, palatability was confirmed that the high (2.9 or higher). In particular, in the case to contain 2.7 to 3.9% by weight α- Parr nesen (# d # e # f), the fragrance similarity and preference of fragrance and kumquat flowers showed a very excellent (average 3.6 or higher).
[159]
[160]
On the other hand, jaseumon, β- Caro propylene, γ- emitter pinene, when containing α- Parr nesen to less than or greater than the reference range but rather similarity and preference of the fragrance was found lower.
[161]
[162]
[ Preparation Example 1] Preparation of perfume
[163]
By mixing the perfume composition with a citrus floral, hagyul flowers, flower younggyul, dreadlocks similarity kumquat flower as in the above, to prepare a perfume having a composition of the following Table 27.
[164]
[Table 27]
Perfume containing perfume composition reproduces the fragrance of gyulkkot
Gyulkkot fragrance reproduces the combination of alcohol Spices water pigments sunscreen 15% by weight 83% by weight 2% by weight Suitable amount Suitable amount

[165]
Industrial Applicability
[166]
Perfume composition reproduces the unique flavor of each citrus flower, hagyul flowers, flower younggyul and kumquat flower according to the present invention can be prepared in combination in the skin external-use base of perfume, cosmetics and the like.

Claims
[Claim 1]
Tangerine flavor components of kkotryu; And jaseumon (Jasmone), β- Caro propylene (β-Caryophyllene), γ- emitter pinene (γ-Terpinene) and α- Parr nesen (α-Farnesene) and a combination thereof one member selected from the group consisting of; an effective fragrance composition containing as a component.
[Claim 2]
The method of claim 1 wherein the perfume composition is Li nalrul (Linalool), myrcene (Myrcene), Neroli stone (Nerolidol) and methyl-carbonyl rate not bitter flavor component of orange kkotryu containing (Methyl anthranilate); And jaseumon (Jasmone); perfume composition characterized in that it contains a.
[Claim 3]
The method of claim 1 wherein the perfume composition is Li nalrul (Linalool), myrcene (Myrcene), Neroli stone (Nerolidol) and methyl-carbonyl rate not bitter flavor component of orange kkotryu containing (Methyl anthranilate); And Caro propylene β- (β-Caryophyllene); perfume composition characterized in that it contains a.
[Claim 4]
The method of claim 1 wherein the perfume composition is Li nalrul (Linalool), myrcene (Myrcene), the geraniol (Geraniol) and β- O cymene flavor component of orange kkotryu comprising a (β-Ocimene); Perfume composition characterized in that it contains a; and γ- emitter pinene (γ-Terpinene).
[Claim 5]
The method of claim 1 wherein the perfume composition is a β- O cymene (β-Ocimene), 6- methyl-5-heptene-2-circle (6-Methyl-5-hepten-2one), not bitter aldehyde carbonyl (Anthranilaldehyde) , limonene (limonene) and methyl-carbonyl rate not bitter flavor component of orange kkotryu containing (methyl anthranilate); And α- Parr nesen (α-Farnesene); perfume composition characterized in that it contains a.
[Claim 6]
The method of claim 2, wherein the perfume composition is Li nalrul (Linalool) 60 ~ 69% by weight of myrcene (Myrcene) 4.5 ~ 6.5 wt%, neroli stone (Nerolidol) 4.2 ~ 5.6 wt% of methyl not bitter carbonyl rate (Methyl anthranilate) 3.8 ~ flavor component of orange kkotryu containing 5.3% by weight; And jaseumon (Jasmone) 0.9 ~ 5% by weight; perfume composition characterized in that it contains a.
[Claim 7]
4. The method of claim 3 wherein the perfume composition is Li nalrul (Linalool) 50 ~ 60% by weight, methyl not bitter carbonyl rate (Methyl anthranilate) 18 ~ 23% by weight, neroli stone (Nerolidol) 8 ~ 12 wt% and myrcene ( Myrcene) flavor component of orange kkotryu containing 3.8 to 6 wt%; And Caro propylene β- (β-Caryophyllene) 0.9 ~ 5% by weight; perfume composition characterized in that it contains a.
[Claim 8]
The method of claim 4 wherein the perfume composition is Li nalrul (Linalool) 53 ~ 62% by weight of myrcene (Myrcene) 10 ~ 15% by weight, the geraniol (Geraniol) 3 ~ 7% by weight and β- O cymene (β -Ocimene) flavor component of orange kkotryu containing 3-5% by weight; And γ- emitter pinene (γ-Terpinene) 0.9 ~ 5% by weight; perfume composition characterized in that it contains a.
[Claim 9]
The method of claim 5, wherein the perfume composition is a β- O cymene (β-Ocimene) 17 ~ 25% by weight of 6-methyl-5-heptene-2-circle (6-Methyl-5-hepten-2-one) 10 to 16% by weight, not bitter carbonyl aldehyde (Anthranilaldehyde) 9 ~ 14% by weight of limonene (limonene) 9 ~ 14% by weight, sore eyes methyl carbonyl rate (methyl anthranilate) 9 ~ flavor component of orange kkotryu containing 14 wt% .; And α- Parr nesen (α-Farnesene) 0.9 ~ 5% by weight; perfume composition characterized in that it contains a.
[Claim 10]
The method of claim 2, wherein the fragrance component of the tangerine kkotryu is not bitter aldehyde carbonyl (Anthranilaldehyde), 3,7- dimethyl-octa-1,5-diene-3,7-diol (3,7-dimethyl-1 , 5-octadiene-3,7-diol), phenyl acetonitrile (Phenylacetonitrile), 6- methyl-5-heptene-2-circle (6-methyl-5-hepten-2-one), phenylethyl alcohol (phenylethyl alcohol), limonene (limonene) and indole (perfume composition according to claim 1, further containing at least one member selected from the group consisting of indole).
[Claim 11]
The method of claim 3 wherein the fragrance ingredient of the orange kkotryu is not bitter aldehyde carbonyl (Anthranilaldehyde), 3,7- dimethyl-octa-1,5-diene-3,7-diol (3,7-dimethyl-1 , 5-octadiene-3,7-diol), phenyl acetonitrile (Phenylacetonitrile), 6- methyl-5-heptene-2-circle (6-methyl-5-hepten-2-one), phenylethyl alcohol (phenylethyl alcohol), limonene (limonene) and indole (perfume composition according to claim 1, further containing at least one member selected from the group consisting of indole).
[Claim 12]
The method of claim 4, wherein the fragrance component of the tangerine kkotryu is 3,7-dimethyl-octa-1,5-diene-3,7-diol (3,7-dimethyl-1,5-octadiene-3,7 -diol), phenyl acetonitrile (Phenylacetonitrile), 6- methyl-5-heptene-2-circle (6-methyl-5-hepten-2-one), phenylethyl alcohol (phenylethyl alcohol), limonene (limonene), indole (indole), β- Caro propylene (β-Caryophyllene) and day-to-day no-perfume composition according to claim 1, further containing at least one member selected from the group consisting of (Nonal).
[Claim 13]
The method of claim 5, wherein the flavor ingredient of the orange is kkotryu ethyl acetate (Ethyl acetate), Li nalrul (Linalool), day-to-day furnace (Nonanal), deca-day (Decanal), α- pinene (α-Pinene), acetophenone ( Acetophenone) and a perfume composition to one or more selected from a group consisting of indole (indole) characterized in that it further comprises.
[Claim 14]
Of claim 1, claim 2, claim 6 and claim 10 which flavor components of orange kkotryu of claim wherein the citrus flower ( Citrus unshiu perfume composition characterized in that the flavor components of).
[Claim 15]
Of claim 1, claim 3, claim 7 and claim 11 of any one of the flavor component of orange kkotryu term hagyul flower ( Citrus natsudaidai perfume composition characterized in that the flavor components of).
[Claim 16]
Of claim 1, claim 4, claim 8 and claim 12 of any one of the flavor component of orange kkotryu term younggyul flower ( Citrus sudachi perfume composition characterized in that the flavor components of).
[Claim 17]
Of claim 1, claim 5, claim 9 and claim 13 of any one of the flavor component of orange kkotryu term kumquat flower ( Fortunella japonica perfume composition characterized in that the flavor components of).
[Claim 18]
Any one of claims 1 to 13, the external preparation for skin containing a perfume composition of any one of claims.