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Lithium Ion Capacitor Utilizing Anode Made From Chemically Pre Lithiated Nitrogen Doped Reduced Graphene Oxide

Abstract: The present invention relates to a lithium-ion capacitor (200). A method to fabricate an anode (202) of the lithium-ion capacitor (200) includes preparing nitrogen-doped reduced graphene oxide (N-rGO) from graphene oxide (GO) by simultaneously performing reduction and nitrogen-doping operations at a high temperature in presence of a nitrogen source. The N-rGO is lithiated, for obtaining lithiated N-rGO (208), by dispersion of the N-rGO in an organic solvent and gradually adding and mixing a solution of long alkyl chain-Li into the N-rGO at a predefined temperature. A precipitate is prepared by heating the lithiated N-rGO (208) at a predefined temperature. The precipitate is coated on a first current collector (212), thereby obtaining the anode (202).

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Notices, Deadlines & Correspondence

Patent Information

Application #
Filing Date
07 November 2022
Publication Number
04/2023
Publication Type
INA
Invention Field
ELECTRICAL
Status
Email
Parent Application
Patent Number
Legal Status
Grant Date
2024-11-29
Renewal Date

Applicants

GODI INDIA PVT. LTD.
12(p), 13, 14(p), Road No:2, Hardware Park, Near International Airport, Hyderabad – 500005, India

Inventors

1. Jana, Milan
GODI INDIA PVT. LTD., 12(p), 13, 14(p), Road No:2, Hardware Park, Near International Airport, Hyderabad – 500005, India
2. Gola, Pushpendra Sing
GODI INDIA PVT. LTD., 12(p), 13, 14(p), Road No:2, Hardware Park, Near International Airport, Hyderabad – 500005, India
3. Maitra, Anirban
GODI INDIA PVT. LTD., 12(p), 13, 14(p), Road No:2, Hardware Park, Near International Airport, Hyderabad – 500005, India

Specification

WE CLAIM:
1. A lithium-ion capacitor (200) comprising:
an anode (202) fabricated through deposition of nitrogen-doped reduced graphene
oxide (N-rGO) lithiated by long alkyl chain-Lithium (Li), over a first current collector
(212);
a cathode (204) fabricated through deposition of activated carbon (210) over a
second current collector (214); and
an electrolyte (206) for allowing ion exchange between the anode (202) and the
cathode (204).
2. The lithium-ion capacitor (200) as claimed in claim 1, wherein the N-rGO is synthesized
from graphene oxide (GO) by simultaneously performing reduction and nitrogen doping
operations at a high temperature in presence of a nitrogen source.
3. The lithium-ion capacitor (200) as claimed in claim 1, wherein lithiation of the N-rGO is
optimized by changing a volume of a solution of the long alkyl chain-Li.
4. The lithium-ion capacitor (200) as claimed in claim 3, wherein the long alkyl chain-Li is
n-butyl Li.
5. The lithium-ion capacitor (200) as claim in claim 1, wherein a porosity of the N-rGO is
increased by one or more of steam activation or chemical activation.
6. The lithium-ion capacitor (200) as claimed in claim 1, wherein the first current collector
(212) is made of copper and the second current collector (214) is made of aluminium.
7. A method of fabrication of an anode (202) for use in a lithium-ion capacitor (200), the
method comprising:
preparing nitrogen-doped reduced graphene oxide (N-rGO) from graphene oxide
(GO) by simultaneously performing reduction and nitrogen-doping operations at a high
temperature in presence of a nitrogen source;
performing lithiation of the N-rGO, to obtain lithiated N-rGO (208), by:
dispersing the N-rGO in an organic solvent; and
12
gradually adding and mixing a solution of long alkyl chain-Lithium (Li) into
the N-rGO dispersed in the organic solvent;
preparing a precipitate by heating the lithiated N-rGO (208) at a predefined
temperature; and
coating the precipitate on a first current collector (212), thereby obtaining the anode
(202).
8. The method as claimed in claim 7, wherein the lithiation of the N-rGO is optimized by
changing a volume of the solution of the long alkyl chain-Li.
9. The method as claimed in claim 8, wherein the long alkyl chain-Li is n-butyl Li.
10. The method as claimed in claim 7, wherein a porosity of the N-rGO is increased by one
or more of steam activation and chemical activation.
11. The method as claimed in claim 7, wherein the lithiation of the N-rGO is performed in
an inert atmosphere.
12. The method as claimed in claim 7, wherein the precipitate is coated on the first current
collector (212) at a relative humidity (RH) of less than or equal to 10.
13. The method as claimed in claim 7, wherein the organic solvent is Hexane.
14. The method as claimed in claim 7, wherein the first current collector (212) is made of
copper.
15. The method as claimed in claim 7, wherein the predefined temperature ranges from 45
0C to 55 0C.

Documents

Application Documents

# Name Date
1 202241063482-STATEMENT OF UNDERTAKING (FORM 3) [07-11-2022(online)].pdf 2022-11-07
2 202241063482-FORM FOR STARTUP [07-11-2022(online)].pdf 2022-11-07
3 202241063482-FORM FOR SMALL ENTITY(FORM-28) [07-11-2022(online)].pdf 2022-11-07
4 202241063482-FORM 1 [07-11-2022(online)].pdf 2022-11-07
5 202241063482-EVIDENCE FOR REGISTRATION UNDER SSI(FORM-28) [07-11-2022(online)].pdf 2022-11-07
6 202241063482-EVIDENCE FOR REGISTRATION UNDER SSI [07-11-2022(online)].pdf 2022-11-07
7 202241063482-DRAWINGS [07-11-2022(online)].pdf 2022-11-07
8 202241063482-DECLARATION OF INVENTORSHIP (FORM 5) [07-11-2022(online)].pdf 2022-11-07
9 202241063482-COMPLETE SPECIFICATION [07-11-2022(online)].pdf 2022-11-07
10 202241063482-STARTUP [11-11-2022(online)].pdf 2022-11-11
11 202241063482-FORM28 [11-11-2022(online)].pdf 2022-11-11
12 202241063482-FORM-9 [11-11-2022(online)].pdf 2022-11-11
13 202241063482-FORM 18A [11-11-2022(online)].pdf 2022-11-11
14 202241063482-Proof of Right [06-12-2022(online)].pdf 2022-12-06
15 202241063482-FORM-26 [06-12-2022(online)].pdf 2022-12-06
16 202241063482-Request Letter-Correspondence [15-11-2023(online)].pdf 2023-11-15
17 202241063482-Form 1 (Submitted on date of filing) [15-11-2023(online)].pdf 2023-11-15
18 202241063482-Covering Letter [15-11-2023(online)].pdf 2023-11-15
19 202241063482-CERTIFIED COPIES TRANSMISSION TO IB [15-11-2023(online)].pdf 2023-11-15
20 202241063482-FER.pdf 2024-03-07
21 202241063482-FORM-8 [06-08-2024(online)].pdf 2024-08-06
22 202241063482-FER_SER_REPLY [02-09-2024(online)].pdf 2024-09-02
23 202241063482-CORRESPONDENCE [02-09-2024(online)].pdf 2024-09-02
24 202241063482-CLAIMS [02-09-2024(online)].pdf 2024-09-02
25 202241063482-US(14)-HearingNotice-(HearingDate-29-10-2024).pdf 2024-09-20
26 202241063482-Correspondence to notify the Controller [28-10-2024(online)].pdf 2024-10-28
27 202241063482-Written submissions and relevant documents [12-11-2024(online)].pdf 2024-11-12
28 202241063482-PatentCertificate29-11-2024.pdf 2024-11-29
29 202241063482-IntimationOfGrant29-11-2024.pdf 2024-11-29
30 202241063482-POWER OF AUTHORITY [17-12-2024(online)].pdf 2024-12-17
31 202241063482-POWER OF AUTHORITY [17-12-2024(online)]-1.pdf 2024-12-17
32 202241063482-FORM-28 [17-12-2024(online)].pdf 2024-12-17
33 202241063482-FORM-28 [17-12-2024(online)]-1.pdf 2024-12-17
34 202241063482-FORM-16 [17-12-2024(online)].pdf 2024-12-17
35 202241063482-FORM-16 [17-12-2024(online)]-1.pdf 2024-12-17
36 202241063482-FORM FOR STARTUP [17-12-2024(online)].pdf 2024-12-17
37 202241063482-FORM FOR STARTUP [17-12-2024(online)]-1.pdf 2024-12-17
38 202241063482-ASSIGNMENT WITH VERIFIED COPY [17-12-2024(online)].pdf 2024-12-17
39 202241063482-ASSIGNMENT WITH VERIFIED COPY [17-12-2024(online)]-1.pdf 2024-12-17
40 202241063482-POWER OF AUTHORITY [29-03-2025(online)].pdf 2025-03-29
41 202241063482-POWER OF AUTHORITY [29-03-2025(online)]-1.pdf 2025-03-29
42 202241063482-FORM-28 [29-03-2025(online)].pdf 2025-03-29
43 202241063482-FORM-28 [29-03-2025(online)]-1.pdf 2025-03-29
44 202241063482-FORM-16 [29-03-2025(online)].pdf 2025-03-29
45 202241063482-FORM-16 [29-03-2025(online)]-1.pdf 2025-03-29
46 202241063482-ASSIGNMENT WITH VERIFIED COPY [29-03-2025(online)].pdf 2025-03-29
47 202241063482-ASSIGNMENT WITH VERIFIED COPY [29-03-2025(online)]-1.pdf 2025-03-29
48 202241063482-FORM FOR STARTUP [30-03-2025(online)].pdf 2025-03-30
49 202241063482-FORM FOR STARTUP [30-03-2025(online)]-1.pdf 2025-03-30

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