DESCRIPTION LITHIUM SECONDARY BATTERY TECHNICAL FIELD [0001] The present invention relates to a lithium secondary battery. BACKGROUND ART [0002] Lithium secondary batteries are widely utilized for the purpose such as portable electronic devices or personal computers. Improvement of the safety of the lithium secondary battery such as flame retardancy is required, and a secondary battery using an electrolyte liquid containing a phosphate compound is proposed as described in the following documents. [0003] Patent document 1 discloses a secondary battery using an electrolyte liquid comprising of a phosphate compound, a cyclic-type carbonate containing a halogen, a linear-type carbonate and a lithium salt. Patent document 1 shows that the safety can be improved by using this electrolyte liquid and that the irreversible capacity can be decreased by combination of a carbon negative electrode and the electrolyte liquid. [0004] Patent Document 2 discloses that, even if lithium metal is precipitated on the negative electrode, high safety can be ensured by mixing a phosphate. [0005] Patent Document 3 discloses a secondary battery which uses an electrolyte liquid containing a phosphate, a cyclic-type carbonate and either vinylene carbonate compound or vinyl ethylene carbonate compound. [0006] Patent Document 4 discloses a secondary battery having an electrolyte liquid which contains a phosphate containing fluorine. [0007] Also, although safety is required in the lithium secondary battery, the improvement of the energy density of the battery is an important technical problem. [0008] There are some methods for improving the energy density of the lithium secondary battery, among these, it is effective to increase the operating potential of the battery. In the lithium secondary battery using a conventional lithium cobaltate or a lithium manganate as the positive electrode active substance, both operating potentials come to be 4 V class (average operating potential = 3.6 to 3.8 V: with respect to lithium potential). This is because the developed potential is defined by oxidation and reduction reaction of Co ion or Mn ion (Co3+ <—> Co4+ or Mn3+ <—» Mn4+). [0009] In contrast, it is known, for example, that operating potential of 5 V class can be realized by using as the active substance a spinel compound obtained by substituting Mn of a lithium manganate to Ni or the like. Specifically, it is known that a spinel compound such as LiNio.5Mn1.5O4 has a potential plateau in a field of 4.5 V or higher as shown in Patent Document 5. In this spinel compound, Mn exists in a state of quaternary, and the developed potential is defined by oxidation and reduction of Ni2+ <—> Ni + instead of oxidation and reduction of Mn3+ <—► Mn4+. [0010] The capacity of LiNio.5Mn1.5O4 is 130 mAh/g or more, and the average operating voltage is 4.6 V or higher with respect to metal lithium. Although the capacity is smaller than that of LiCo02, the energy density of the battery is higher than that of LiCo02. From these reasons, LiNio.5Mm.5O4 is promising as a future positive electrode material. CITATION LIST PATENT DOCUMENT [0011] Patent Document 1: JP 3961597 B Patent Document 2: JP 3821495 B Patent Document 3: JP 4187965 B Patent Document 4: JP 2008-021560 A Patent Document 5: JP 2009-123707 A NON-PATENT DOCUMENTS [0012] Non-Patent Document 1: J. Electrochem. Soc., vol. 144,204 (1997) SUMMARY OF THE INVENTION PROBLEM TO BE SOLVED BY THE INVENTION [0013] However, in the battery in which a positive electrode material having a high discharge potential such as LiNio.5Mn1.5O4 as the active substance is used, since the potential of the positive electrode comes to be further higher than that in the case of using LiCo02 or LiMn2C>4, decomposition reaction of the electrolyte liquid easily occurs at a contact portion with the positive electrode. Thus, the capacity may remarkably decrease due to the charge and discharge cycle. In particular, the electrolyte liquid tends to remarkably deteriorate with increase of the temperature, and it is required to improve the operating life when operating at a high temperature such as 40°C or higher. [0014] As the electrolyte liquid, a carbonate material is mainly used, but, in the positive electrode active substance which operates at 4.5 V or higher with respect to lithium, there is room for improving the operating life property at a high temperature as described above. [0015] Also, the batteries disclosed in Patent Documents 1 to 4 have a 4 V class positive electrode active substance such as LiMn204 or LiCoC>2, and do not solve the particular problem in the case of using a positive electrode active substance having high discharge potential. [0016] Thus, an object of an exemplary embodiment of the invention is to provide a lithium secondary battery which has high energy density by containing a positive electrode active substance operating at a potential of 4.5 V or higher with respect to lithium and which has excellent cycle property. MEANS OF SOLVING THE PROBLEM [0017] An exemplary embodiment of the invention is a lithium secondary battery, which comprises a positive electrode comprising a positive electrode active substance and an electrolyte liquid comprising a nonaqueous electrolyte solvent; wherein the positive electrode active substance operates at a potential of 4.5 V or higher with respect to lithium; and wherein the nonaqueous electrolyte solvent comprises a fluorine-containing phosphate represented by following formula (1): [0018] [0019] wherein, in formula (1), Ri, R2 and R3 are each independently a substituted or non-substituted alkyl group, and at least one of R], R2 and R3 is a fluorine-containing alkyl group. EFFECT OF THE INVENTION [0020] The constitution of an exemplary embodiment of the invention can provide a secondary battery having excellent cycle property even if a positive electrode active substance operating at a potential of 4.5 V or higher with respect to lithium is used. Thus, a lithium secondary battery having high energy density and an excellent cycle property can be provided. BRIEF DESCRIPTION OF DRAWINGS [0021] FIG 1 is a view showing a cross-sectional conformation of a secondary battery according to an exemplary embodiment of the invention. MODE FOR CARRYING OUT THE INVENTION [0022] A lithium secondary battery of an exemplary embodiment of the invention has a positive electrode containing a positive electrode active substance and an electrolyte liquid containing a nonaqueous electrolyte solvent. The positive electrode active substance operates at a potential of 4.5 V or higher with respect to lithium. The nonaqueous electrolyte solvent contains a phosphate represented by above-mentioned formula (1) (hereinafter, also referred to as fluorine-containing phosphate). In the case where the positive electrode active substance operating at a potential of 4.5 V or higher with respect to lithium is used, the capacity retention ratio can be improved by using the nonaqueous electrolyte solvent including a fluorine-containing phosphate. [0023] (Electrolyte liquid) The electrolyte liquid contains a supporting salt and a nonaqueous electrolyte solvent, and the nonaqueous electrolyte solvent contain a fluorine-containing phosphate represented by above-mentioned formula (1). [0024] The content of the fluorine-containing phosphate contained in the nonaqueous electrolyte solvent is preferably, but should not be limited to, 10 vol% or more and 95 vol% or less in the nonaqueous electrolyte solvent. When the content of the fluorine-containing phosphate in the nonaqueous electrolyte solvent is 10 vol% or more, the effect of increasing the voltage resistance is improved more. Also, when the content of the fluorine-containing phosphate in the nonaqueous electrolyte solvent is 95 vol% or less, the ion conductivity of the electrolyte liquid is improved and the charge and discharge rate of the battery becomes better. Also, the content of the fluorine-containing phosphate in the nonaqueous electrolyte solvent is more preferably 20 vol% or more, is further preferably 31 vol% or more, and is particularly preferably 35 vol% or more. Also, the content of the fluorine-containing phosphate in the nonaqueous electrolyte solvent is more preferably 70 vol% or less, is further preferably 60 vol% less, is particularly preferably 59 vol% or less, and is more particularly preferably 55 vol% or less. [0025] In the fluorine-containing phosphate represented by formula (1), Ri, R2 and R3 are each independently a substituted or non-substituted alkyl group, and at least one of Ri, R2 and R3 is a fluorine-containing alkyl group. The fluorme-containing alkyl group is an alkyl group having at least one fluorine atom. The carbon numbers of alkyl group Ri, R2 and R3 are preferably 1 or more and 4 or less and are more preferably 1 or more and 3 or less, each independently. When the carbon number of the alkyl group is 4 or less, the increase of the viscosity of the electrolyte liquid is suppressed and the electrolyte liquid is easy to be penetrated into the pore in the electrode and the separator, and the ion conductivity is improved and the current value becomes good in the charge and discharge property of the battery. [0026] Also, in formula (1), it is preferable that all Ri, R2 and R3 be a fluorine-containing alkyl group. [0027] Also, at least one of Ri, R2 and R3 is preferably a fluorine-containing alkyl group in which 50 % or more of hydrogen atoms of a corresponding non-substituted alkyl group are substituted by a fluorine atom. Also, it is more preferable that all Ri, R2 and R3 are a fluorine-containing alkyl group and that the Ri, R2 and R3 are a fluorine-containing alkyl group in which 50 % or more of hydrogen atoms of a corresponding non-substituted alkyl group are substituted by a fluorine atom. If the content of the fluorine atom is large, the voltage resistance is improved more, and in the case of using a positive electrode active substance operating at a potential of 4.5 V or higher with respect to lithium, deterioration of the battery capacity after the cycle can be further reduced. Also, the ratio of fluorine atom in the substituent groups including hydrogen atom in the fluorine-containing alkyl group is preferably 55% or more. [0028] Also, Ri to R3 may have a substituent group other than fluorine atom, and examples of the substituent group include at least one selected from the group consisting of among amino group, carboxy group, hydroxy group, cyano group and halogen atoms (for example, chlorine atom and bromine atom). Note that, the above-mentioned carbon number includes the substituent group in concept. [0029] Examples of the fluorine-containing phosphate include, for example, tris(trifluoromethyl) phosphate, tris(trifluoroethyl) phosphate, tris(tetrafluoropropyl) phosphate, tris(pentafluoropropyl) phosphate, tris(heptafluorobutyl) phosphate and tris(octafluoropentyl) phosphate. Also, examples of the fluorine-containing phosphate include, for example, Trifluoroethyl dimethyl phosphate, bis(trifluoroethyl) methyl phosphate, bistrifluoroethyl ethyl phosphate, pentafluoropropyl dimethyl phosphate, heptafluorobutyl dimethyl phosphate, trifluoroethyl methyl ethyl phosphate, pentafluoropropyl methyl ethyl phosphate, heptafluorobutyl methyl ethyl phosphate, trifluoroethyl methyl propyl phosphate, pentafluoropropyl methyl propyl phosphate, heptafluorobutyl methyl propyl phosphate, trifluoroethyl methyl butyl phosphate, pentafluoropropyl methyl butyl phosphate, heptafluorobutyl methyl butyl phosphate, trifluoroethyl diethyl phosphate, pentafluoropropyl diethyl phosphate, heptafluorobutyl diethyl phosphate, trifluoroethyl ethyl propyl phosphate, pentafluoropropyl ethyl propyl phosphate, heptafluorobutyl ethyl propyl phosphate, trifluoroethyl ethyl butyl phosphate, pentafluoropropyl ethyl butyl phosphate, heptafluorobutyl ethyl butyl phosphate, trifluoroethyl dipropyl phosphate, pentafluoropropyl dipropyl phosphate, heptafluorobutyl dipropyl phosphate, trifluoroethyl propyl butyl phosphate, pentafluoropropyl propyl butyl phosphate, heptafluorobutyl propyl butyl phosphate, trifluoroethyl dibutyl phosphate, pentafluoropropyl dibutyl phosphate and heptafluorobutyl dibutyl phosphate. Examples of the tris(tetrafluoropropyI) phosphate include, for example, tris(2,2,3,3-tetrafluoro propyl) phosphate. Examples of the tris(pentafluoropropyl) phosphate include, for example, tris(2,2,3,3,3-pentafluoropropyl) phosphate. Examples of the tris(trifluoroethyl) phosphate include, for example, tris(2,2,2-trifluoroethyl) phosphate (hereinafter, also abbreviated to PTTFE). Examples of the tris(heptafluorobutyl) phosphate include, for example, tris(lH,lH-heptafluorobutyl) phosphate. Examples of the tris(octafluoropentyl) phosphate include, for example, tris(( 1H, 1 H,5H-octafluoropenryl) phosphate. Among these, since the effect of suppressing the decomposition of the electrolyte liquid at a high potential is high, tris(2,2,2-trifluoroethyl) phosphate represented by following formula (2) is preferable. The fluorine-containing phosphate can be used alone, or in combination with two or more kinds. [0030] [0031] It is preferable that the nonaqueous electrolyte solvent further contain a cyclic-type carbonate or a linear-type carbonate together with a fluorine-containing phosphate. [0032] Since the cyclic-type carbonate or the linear-type carbonate has relatively large dielectric constant, by adding this results, the dissociation property of the supporting salt is improved and it becomes easy to give a sufficient electroconductivity. Further, since the viscosity of the electrolyte liquid is decreased by adding this, there is an advantage that the ion mobility in the electrolyte liquid is improved. Also, since the cyclic-type carbonate and the linear-type carbonate have high voltage resistance and a high electroconductivity, it is suitable for the mixing with a fiuorme-containing phosphate. [0033] Examples of the cyclic-type carbonate includes, for example, but should not be limited to, ethylene carbonate (EC), propylene carbonate (PC) butylene carbonate (BC) or vinylene carbonate (VC). Also, the cyclic-type carbonate includes fluorinated cyclic-type carbonates. Examples of the fluorinated cyclic-type carbonate include, for example, compounds which are obtained by substituting a part or all of hydrogen atoms of ethylene carbonate (EC), propylene carbonate (PC), butylene carbonate (BC), vinylene carbonate (VC) or the like to fluorine atom. More specifically, for example, 4-fluoro-l,3-dioxolane-2-one, (cis- or trans-) 4,5-difluoro-l,3-dioxolane-2-one, 4,4-difluoro-l,3-dioxolane-2-one and 4-fluoro-5-methyl-l,3-dioxolane-2-one can be used as the fluorinated cyclic-type carbonate. Among the above-listed compounds, the cyclic-type carbonate is preferably ethylene carbonate, propylene carbonate or a compound which is obtained by fluorinating a part thereof from the viewpoint of the voltage resistance and the electroconductivity, and is more preferably ethylene carbonate. The cyclic-type carbonate can be used alone, or in combination with two or more kinds. [0034] The content of the cyclic-type carbonate in the nonaqueous electrolyte solvent is preferably 0.1 vol% or more from the viewpoint of the effect of increasing the dissociation of the supporting salt and the effect of increasing the electroconductivity of the electrolyte liquid, is more preferably 5 vol% or more, is further preferably 10 vol% or more, and is particularly preferably 15 vol% or more. Also, the content of the cyclic-type carbonate in the nonaqueous electrolyte solvent is preferably 70 vol% or less from the similar view point, is more preferably 50 vol% or less, and is further preferably 40 vol% or less. [0035] Examples of the linear-type carbonate include, for example, but should not be limited to, dimethyl carbonate (DMC), ethyl methyl carbonate (EMC), diethyl carbonate (DEC) and dipropyl carbonate (DPC). Also, the linear-type carbonate includes fluorinated linear-type carbonates. Examples of the fluorinated linear-type carbonate include, for example, compounds which are obtained by substituting a part or all of hydrogen atoms of ethyl methyl carbonate (EMC), dimethyl carbonate (DMC), diethyl carbonate (DEC), dipropyl carbonate (DPC) or the like to fluorine atom. More specific examples of the fluorinated linear-type carbonate include, for example, bis(fluoroethyl) carbonate, 3-fluoropropyl methyl carbonate, 3,3,3-trifluoropropyl methyl carbonate, 2,2,2-trifluoroethyl methyl carbonate, 2,2,2-trifluoroethyl ethyl carbonate, monofluoromethyl methyl carbonate, methyl-2,2,3,3-tetrafluoropropyl carbonate, ethyl-2,2,3,3-tetrafluoropropyl carbonate, bis(2,2,3,3-tetrafluoropropyl) carbonate, bis(2,2,2-trifluoroethyl) carbonate, 1-monofluoroethyl ethyl carbonate, 1-monofluoroethyl methyl carbonate, 2-monofluoroethyl methyl carbonate, bis(l-monofluoroethyl) carbonate, bis(2-monofluoroethyl) carbonate and bis(monofluoromethyl) carbonate. Among these, dimethyl carbonate, 2,2,2-trifluoroethyl methyl carbonate, monofluoromethyl methyl carbonate, methyl-2,2,3,3-tetrafluoropropyl carbonate are preferable from the viewpoint of the voltage resistance and the electroconductivity. The linear-type carbonate can be used alone, or in combination with two or more kinds. [0036] In the linear-type carbonate, in the case where the carbon number of the substituent group added to "-OCOO-" structure is small, there is an advantage that the viscosity is low. On the other hand, if the carbon number is too big, the viscosity of the electrolyte liquid may become high, and the electroconductivity of Li ion may be decreased. From these reasons, the total carbon number of the two substituent groups added to "-OCOO-" structure of the linear-type carbonate is preferably 2 or more and 6 or less. Also, in the case where the substituent group added to "-OCOO-" structure contains a fluorine atom, the oxidation resistance of the electrolyte liquid is improved. From these reasons, the linear-type carbonate is preferably a fluorinated linear-type carbonate represented by following formula (3): [0037] CnH2n+i.iF,-OCOO-CmH2m+,-icFk (3), [0038] wherein, in formula (3), n is 1,2 or 3, m is 1, 2 or 3,1 is any one integer from 0 to 2n+l, k is any one integer from 0 to 2m+l, and at least one of 1 and k is an integer of 1 or more. [0039] In the fluorinated linear-type carbonate represented by formula (3), when the substituted ratio by fluorine is small, the capacity retention ratio of the battery may be decreased and generation of the gas may occur due to the reaction of the fluorinated linear-type carbonate with the positive electrode with high voltage. On the other hand, when the substituted ratio by fluorine is too large, compatibility of the linear-type carbonate with another solvent may be decreased and the boiling point of the linear-type carbonate may be decreased. From these reasons, the substituted ratio by fluorine is preferably 1% or more and 90% or less, is more preferably 5% or more and 85% or less, and is further preferably 10% or more 80% or less. In other words, 1, m and n in formula (3) preferably satisfy the following equation: [0040] 0.01 < (1+k) / (2n+2m+2) < 0.9. [0041] The linear-type carbonate has effects of decreasing the viscosity of the electrolyte liquid and therefore can increase the electroconductivity of the electrolyte liquid. From the viewpoint of these, the content of the linear-type carbonate in the nonaqueous electrolyte solvent is preferably 5 vol% or more, is more preferably 10 vol% or more, and is further preferably 15 vol% or more. Also, the content of the linear-type carbonate in the nonaqueous electrolyte solvent is preferably 90 vol% or less, is more preferably 80 vol% or less, and further preferably 70 vol% or less. [0042] Also, the content of the fluorinated linear-type carbonate is preferably, but should not be limited to, 0.1 vol% or more and 70 vol% or less in the nonaqueous electrolyte solvent. When the content of the fluorinated linear-type carbonate in the nonaqueous electrolyte solvent is 0.1 vol% or more, the viscosity of the electrolyte liquid can be decreased and the electroconductivity can be increased. Also, the effect of increasing oxidation resistance is obtained. Also, when the content of the fluorinated linear-type carbonate in the nonaqueous electrolyte solvent is 70 vol% or less, the electroconductivity of the electrolyte liquid can be kept high. Also, the content of the fluorinated linear-type carbonate in the nonaqueous electrolyte solvent is more preferably 1 vol% or more, is further preferably 5 vol% or more, and is particularly preferably 10 vol% or more. Also, the content of the fluorinated linear-type carbonate in the nonaqueous electrolyte solvent is more preferably 65 vol% or less, is further preferably 60 vol% or less, and is particularly preferably 55 vol% or less. [0043] The nonaqueous electrolyte solvent can contain a carboxylate together with the fluorine-containing phosphate. [0044] Examples of the carboxylate include, for example, but should not be limited to, ethyl acetate, methyl propionate, ethyl formate, ethyl propionate, methyl butyrate, ethyl butyrate, methyl acetate and methyl formate. Also, the carboxylate includes fluorinated carboxylates. Examples of the fluorinated carboxylate include, for example, compounds which are obtained by substituting a part or all of hydrogen atoms of ethyl acetate, methyl propionate, ethyl formate, ethyl propionate, methyl butyrate, ethyl butyrate, methyl acetate or the methyl formate to fluorine atom. Also, specific examples of the fluorinated carboxylate include, for example, pentafluoroethyl propionate, ethyl 3,3,3-trifluoropropionate, methyl 2,2,3,3-tetrafluoropropionate, 2,2-difluoroethyl acetate, methyl heptafluoroisobutyrate, methyl 2,3,3,3-tetrafluoropropionate, methyl pentafluoropropionate, methyl 2-(trifluoromethyl)-3,3,3-trifluoropropionate, ethyl heptafluorobutyrate, methyl 3,3,3-trifluoropropionate, 2,2,2-trifluoroethyl acetate, isopropyl trifluoroacetate, tert-butyl trifluoroacetate, ethyl 4,4,4-trifiuorobutyrate, methyl 4,4,4-trifluorobutyrate, butyl 2,2-difluoroacetate, ethyl difluoroacetate, n-butyl trifluoroacetate, 2,2,3,3-tetrafluoropropyl acetate, ethyl 3-(trifluoromethyl)butyrate, methyl tetrafluoro-2-(methoxy)propionate, 3,3,3-trifluoropropyI 3,3,3-trifluoropropionate, methyl difluoroacetate, 2,2,3,3-tetrafluoropropyl trifluoroacetate, lH,lH-heptafluorobutyl acetate, methyl heptafluorobutyrate and ethyl trifluoroacetate. Among these, ethyl propionate, methyl acetate, methyl 2,2,3,3-tetrafluoropropionate and 2,2,3,3-tetrafluoropropyl trifluoroacetate are preferable as the carboxylate from the viewpoint of the voltage resistance and the boiling point. The carboxylate has an effect of decreasing the viscosity of the electrolyte liquid like the linear-type carbonate. Thus, for example, the carboxylate can be used instead of the linear-type carbonate, and can also be used together with the linear-type carbonate. [0045] The linear-type carboxylate has a low viscosity when the carbon number of the substituent group added to "-COO-" structure is small, but the boiling point tends to be also decreased. The linear-type carboxylate whose boiling point is low may be vaporized at the time of operation of the battery at a high temperature. On the other hand, when the carbon number is too large, the viscosity of the electrolyte liquid may become higher and the electroconductivity may be decreased. From these reasons, the total carbon number of two substituent groups added to "- COO" structure of the linear-type carboxylate is preferably 3 or more and 8 or less. Also, if the substituent group added to "-COO-" structure contains a fluorine atom, oxidation resistance of the electrolyte liquid can be improved. From these reasons, the linear-type carboxylate is preferably a fluorinated linear-type carboxylate represented by following formula (4): [0046] CnHzn+l-lFrCOO-CrnHzm+McFfc (4), [0047] Wherein, in formula (4), n is 1,2, 3 or 4, m is 1,2,3 or 4,1 is any one integer from 0 to 2n+l, k is any one integer from 0 to 2m+l, and at least one of 1 and k is an integer of 1 or more. [0048] In the fluorinated linear-type carboxylate represented by formula (4), when the substituted ratio by fluorine is small, the capacity retention ratio of the battery may be decreased and generation of the gas may occur due to the reaction of the fluorinated linear-type carboxylate with the positive electrode with high voltage. On the other hand, when the substituted ratio by fluorine is too large, compatibility of the fluorinated linear-type carboxylate with another solvent may be decreased and the boiling point of the linear-type carboxylate may be decreased. From these reasons, the substituted ratio by fluorine is preferably 1% or more and 90% or less, is more preferably 10% or more and 85% or less, and is further preferably 20% or more 80% or less. In other words, 1, m and n in formula (4) preferably satisfy the following equation: [0049] 0.01 < (1+k) / (2n+2m+2) < 0.9 [0050] The content of the carboxylate in the nonaqueous electrolyte solvent is preferably 0.1 vol% or more, is more preferably 0.2 vol% or more, is further preferably 0.5 vol% , and is particularly preferably 1 vol% or more. The content of the carboxylate in the nonaqueous electrolyte solvent is preferably 50 vol% or less, is more preferably 20 vol% or less, is further preferably 15 vol% or less, and is particularly preferably 10 vol% or less. When the content of the carboxylate is 0.1 vol% or more, low-temperature characteristic can be improved more and the electroconductivity can be also improved more. Also, when the content of the carboxylate is 50 vol% or less, moisture pressure can be prevented from becoming too high in the case where the battery was left at a high temperature. [0051] Also, the content of the fluorinated linear-type carboxylate is preferably, but should not be limited to, 0.1 vol% more and 50 vol% or less in the nonaqueous electrolyte solvent. When the content of the fluorinated linear-type carboxylate in the nonaqueous electrolyte solvent is 0.1 vol% or more, the viscosity of the electrolyte liquid can be decreased and the electroconductivity can be increased. Also, the effect of increasing oxidation resistance is obtained. Also, when the content of the fluorinated linear-type carboxylate in the nonaqueous electrolyte solvent is 50 vol% or less, the electroconductivity of the electrolyte liquid can be kept high, and compatibility of the electrolyte liquid can be ensured. Also, the content of the fluorinated linear-type carboxylate in the nonaqueous electrolyte solvent is more preferably 1 vol% or more, is further preferably 5 vol% or more, and is particularly preferably 10 vol% or more. Also, the content of the fluorinated linear-type carboxylate in the nonaqueous electrolyte solvent is more preferably 45 voI% or less, is further preferably 40 vol% or less, and is particularly preferably 35 vol% or less. [0052] The nonaqueous electrolyte solvent can contain an alkylene biscarbonate represented by following formula (5) together with the fluorine-containing phosphate. Since the oxidation resistance of the alkylene biscarbonate is equal to or higher than that of the linear-type carbonate, the voltage resistance of the electrolyte liquid can be improved. [0053] [0054] wherein R4 and R$ each independently represent a substituted or non-substituted alkyl group, and R5 represents a substituted or non-substituted alkylene group. [0055] In formula (5), the alkyl group includes linear-type groups or branched-type groups. The carbon number is preferably 1 to 6 and the carbon number is more preferably 1 to 4. The alkylene group is a bivalent saturated hydrocarbon group, and includes linear-type groups or branched-type groups. The carbon number is preferably 1 to 4, and the carbon number is more preferably 1 to 3. [0056] Examples of the alkylene biscarbonate represented by formula (5) include, for example, l,2-bis(methoxycarbonyloxy) ethane, l,2-bis(ethoxycarbonyloxy) ethane, 1,2-bis (methoxycarbonyloxy) propane or l-ethoxycarbonyloxy-2-methoxycarbonyloxy ethane. Among these, 1,2-bis(methoxycarbonyloxy) ethane is preferable. [0057] The content of the alkylene biscarbonate in the nonaqueous electrolyte solvent is preferably 0.1 vol% or more, is more preferably 0.5 vol% or more, is further preferably 1 vol% or more, and is particularly preferably 1.5 vol% or more. The content of the alkylene biscarbonate in the nonaqueous electrolyte solvent is preferably 70 vol% or less, is more preferably 60 vol% or less, is further preferably 50 vol% or less, and is particularly preferably 40 vol% or less. [0058] The alkylene biscarbonate is a material having a low dielectric constant. Therefore, for example, it can be used instead of the linear-type carbonate, or it can be used together with the linear-type carbonate. [0059] The nonaqueous electrolyte solvent can contain a linear-type ether together with the fluorine-containing phosphate. [0060] Examples of the linear-type ether include, for example, but should not be limited to, 1,2-ethoxyethane (DEE) or ethoxy methoxy ethane (EME). Also, the linear-type ether includes fluorinated linear-type ethers. The fluorinated linear-type ether has high oxidation resistance, and is preferable in the case of the positive electrode operating at a high potential. Examples of the fluorinated linear-type ether include, for example, compounds which are obtained by substituting a part or all of hydrogen atoms of 1,2-ethoxyethane (DEE) or ethoxy methoxy ethane (EME) to fluorine atom. Also, examples of the fluorinated linear-type ether include, for example, 2,2,3,3,3-pentafluoropropyl 1,1,2,2-tetrafluoroethyl ether, 1,1,2,2-tetrafluoroethyl 2,2,2-trifluoroethyl ether, lH,lH,2'H,3H-decafluorodipropyl ether, 1,1,1,2,3,3-hexafluoropropyl-2,2-difluoroethyl ether, isopropyl 1,1,2,2-tetrafluoroethyl ether, propyl 1,1,2,2-tetrafluoroethyl ether, 1,1,2,2-tetrafluoroethyl 2,2,3,3-tetrafluoropropyl ether, lH,lH,5H-perfluoropentyl-1,1,2,2-tetrafluoroethyl ether, lH,lH,2'H-perfluorodipropyl ether, lH-perfluorobutyl-lH-perfluoroethyl ether, methyl perfluoropentyl ether, methyl perfluorohexyl ether, methyl l,l,3,3,3-pentafluoro-2-(trifluoromethyl)propyl ether, 1,1,2,3,3,3-hexafluoropropyl 2,2,2-trifluoroethyl ether, ethyl nonafluorobutyl ether, ethyl 1,1,2,3,3,3-hexafluoropropyl ether, lH,lH,5H-octa fluoropentyl 1,1,2,2-tetrafluoroethyl ether, 1H,1H,2 'H-perfluorodipropyl ether, heptafluoropropyl 1,2,2,2-tetrafluoroethyl ether, 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether, 2,2,3,3,3-pentafluoropropyl-1,1,2,2-tetrafluoroethyl ether, ethyl nonafluorobutyl ether and methyl nonafluorobutyl ether. Among these, 1,1,2,2-tetrafluoroethy 1-2,2,3,3 -tetrafluoropropyl ether, lH,lH,2'H,3H-decafluorodipropyl ether, 1H,1H,2' H-perfluorodipropyl ether and ethyl nonafluorobutyl ether are preferable from the viewpoint of the voltage resistance and the boiling point. The linear-type ether has an effect of decreasing the viscosity of the electrolyte liquid like the linear-type carbonate. Thus, for example, the linear-type ether can be used instead of the linear-type carbonate or the carboxylate, and can also be used together with the linear-type carbonate or the carboxylate. [0061] When the carbon number of the linear-type ether is small, the boiling point tends to be decreased, and therefore it may be vaporized at the time of operation of the battery at a high temperature. On the other hand, when the carbon number is too large, the viscosity of the linear-type ether may become higher, and electroconductivity of the electrolyte liquid may be decreased. Thus, the carbon number is preferably 4 or more and 10 or less. From these reasons, the linear-type ether is a fluorinated linear-type ether represented by following formula (6): [0062] [0063] wherein, in formula (6), n is 1, 2, 3,4, 5 or 6, m is 1,2,3 or 4,1 is any one integer from 0 to 2n+l, k is any one integer from 0 to 2m+l, and at least one of 1 and k is an integer of 1 or more. [0064] In the fluorinated linear-type ether represented by formula (6), when the substituted ratio by fluorine is small, the capacity retention ratio of the battery may be decreased and generation of the gas may occur due to the reaction of the fluorinated linear-type ether with the positive electrode with high voltage. On the other hand, when the substituted ratio by fluorine is too large, compatibility of the fluorinated linear-type ether with another solvent may be decreased and the boiling point of the fluorinated linear-type ether may be decreased. From these reasons, the substituted ratio by fluorine is preferably 10% or more and 90% or less, is more preferably 20% or more and 85% or less, and is further preferably 30% or more 80% or less. In other words, 1, m and n in formula (6) preferably satisfy the following equation: [0065] [0066] Also, the content of the fluorinated linear-type ether is preferably, but should not be limited to, 0.1 vol% or more and 70 vol% or less in the nonaqueous electrolyte solvent. When the content of the fluorinated linear-type ether in the nonaqueous electrolyte solvent is 0.1 vol% or more, the viscosity of the electrolyte liquid can be decreased and the electroconductivity can be increased. Also, the effect of increasing oxidation resistance is obtained. Also, when the content of the fluorinated linear-type ether in the nonaqueous electrolyte solvent is 70 vol% or less, the electroconductivity of the electrolyte liquid can be kept high, and compatibility of the electrolyte liquid can also be ensured.. Also, the content of the fluorinated linear-type ether in the nonaqueous electrolyte solvent is more preferably 1 vol% or more, is further preferably 5 vol% or more, and is particularly preferably 10 vol% or more. Also, the content of the fluorinated linear-type ether in the nonaqueous electrolyte solvent is more preferably 65 vol% or less, is further preferably 60 vol% or less, and is particularly preferably 55 vol% or less. [0067] The nonaqueous electrolyte solvent may contain a following compound together with the above-mentioned compound. For example, the nonaqueous electrolyte solvent is a y-lactone such as y-butyrolactone, a linear-type ether such as 1,2-ethoxyethane (DEE) or ethoxy methoxy ethane (EME), a cyclic-type ether such as tetrahydrofuran or 2-methyltetrahydrofuran, or the like. Also, a compound which is obtained by substituting a part hydrogen atoms of this compound to fluorine atom can be contained. Also, in addition, an aprotic organic solvent such as dimethylsulfoxide, 1,3-dioxolane, formamide, acetamide, dimethylformamide, dioxolane, acetonitrile, propylnitrile, nitromethane, ethyl monoglyme, trimethoxymethane, a dioxolane derivative, sulfolane, methyl sulfolane, l,3-dimemyl-2-imidazolidinone, 3-methyl-2-oxazolidinone, a propylene carbonate derivative, a tetrahydrofuran derivative, ethyl ether, 1,3-propane sultone, anisole or N-methylpyrrolidone may be contained. . [0068] Example of the supporting salt include, for example, lithium salts such as LiPF6, LiAsF6, LiAlCU, LiC104, LiBF4, LiSbF6, LiCF3S03, LiC4F9C03, LiC(CF3S02)2, LiN(CF3S02)2, LiN (C2F5S02)2 and LiBioClio. Also, additional examples of the supporting salt include lithium salts of lower aliphatic carboxylic acids, chloroborane lithium, lithium tetraphenylborate, LiBr, Lil, LiSCN and LiCl. The supporting salt can be used alone, or in combination with two or more kinds. [0069] Also, an ion conductive polymer can be added to the nonaqueous electrolyte solvent. Examples of the ion conductive polymer include, for example, polyethers such as polyethylene oxides and polypropylene oxides, and polyolefins such as polyethylenes and polypropylenes. Also, examples of the ion conductive polymer include, for example, polyvinylidene fluorides, polytetrafluoroethylenes, polyvinyl fluorides, polyvinyl chlorides, polyvinylidene chlorides, polymethyl methacrylates, polymethyl acrylates, polyvinyl alcohols, polymethacrylonitriles, polyvinyl acetates, polyvinyl pyrrolidones, polycarbonates, polyethylene terephthalates, polyhexamethylene adipamides, polycaprolactams, polyurethanes, polyethyleneimines, polybutadienes, polystyrenes or polyisoprenes, or derivatives thereof. The ion conductive polymer can be used alone, or in combination with two or more kinds. Also, a polymer containing a variety of a monomer which constitutes the above-mentioned polymer may be used. [0070] (Positive electrode) A positive electrode contains a positive electrode active substance, and the positive electrode active substance operates at a potential of 4.5 V or higher with respect to lithium. For example, the positive electrode is formed by binding a positive electrode active substance on a positive electrode collector with a positive electrode binder so that the positive electrode active substance covers the positive electrode collector. [0071] . Also, a positive electrode active substance operating at a potential of 4.5 V or higher with respect to lithium can be selected, for example, by a following method. First, a positive electrode containing a positive electrode active substance and Li metal are oppositely disposed through a separator in a battery and an electrolyte liquid is injected to produce a battery. After that, when charge and discharge are carried out at a constant current of, for example, 5 mAh/g per the mass of the positive electrode active substance in the positive electrode, an active substance which has a charge and discharge capacity of 10 mAh/g or more per the mass of the active substance at a potential of 4.5 V or higher with respect to lithium can be assume to be a positive electrode active substance operating at a potential of 4.5 V or higher with respect to lithium. Also, when charge and discharge are carried out at a constant current of 5 mAh/g per the mass of the positive electrode active substance in the positive electrode, the charge and discharge capacity per the mass of the active substance at a potential of 4.5 V or higher with respect to lithium is preferably 20 mAh/g or more, is more preferably 50 mAh/g or more, and is further preferably 100 mAh/g or more. The shape of the battery can be, for example, coin-type. [0072] The positive electrode active substance contains an active substance which operates at a potential of 4.5 V or higher with respect to lithium and preferably contains a lithium manganese complex oxide represented by following formula (4). The lithium manganese complex oxide represented by following formula (4) is an active substance which operates at a potential of 4.5 V or higher with respect to lithium. [0073] Wherein, in the formula, it satisfies 0.5 < x < 1.2, 0 < y, x+y < 2, 0 2, NiO, Fe2C>3, Ti02, B2O3, CoO, U2CO3, MgO, AI2O3 and LiF, and they were weighed so as to be in a intended ratio and were pulverized and mixed. A powder after a mixing of the raw materials was calcined at a calcining temperature of 500 to 1000°C for 8 hours to obtain a following positive electrode active substance. [0129] [0130] As the result of evaluating specific surface areas of the obtained positive electrode active substances by the BET method, they were 0.1 to 2.0 m /g. [0131] The average discharge potential with respect to lithium of the obtained positive electrode active substances was measured as follows. [0132] The obtained positive electrode active substance, a polyvinylidene fluoride as a binder (5 mass%) and carbon black as a electroconductive agent (5 mass%) were mixed to be a positive electrode mixture. The positive electrode mixture was dispersed in N-methyl-2-pyrrolidone to prepare slurry for measure. This slurry for measure was uniformly applied on one side of a 1 collector made of aluminum with a thickness of 20 um. The thickness of the applied film was adjusted so that the first charge capacity per unit area became 2.5 mAh/cm . After dried, it was compressed and molded with a roll press to produce a positive electrode for measure. [0133] Lithium metal was used as a negative electrode for measure. [0134] The positive electrode for measure and the negative electrode for measure which were cut to circle shape with a diameter of 12 mm were oppositely disposed through a separator. As the separator, a fine-porous polypropylene film with a thickness of 25 um was used. [0135] As a nonaqueous electrolyte solvent, a mixed solvent of ethylene carbonate (EC) and diethyl carbonate (DEC) at a volume ratio of 30/70 was used. LiPF6 was dissolved in this nonaqueous electrolyte solvent in a concentration of 1 mol/1 to prepare an electrolyte liquid. [0136] The positive electrode, the negative electrode and the electrolyte liquid were disposed and enclosed in a coin-type battery to produce a coin-type battery. The first charge capacity of this battery is about 2.83 mAh from the first charge capacity of 2.5 mAh/cm and the area of the 12 mm diameter. [0137] In the coin-type battery produced in this way, charge and discharge were carried out within the range of the upper limit voltage of 5 V and the lower limit voltage of 3 V with the constant current of 70 uA which is 0.025 times the value of the first charge capacity (2.83 x 0.025 x 1000). The discharge curve was plotted (discharge potential vs. discharge capacity), and the average discharge potential was derived from this discharge curve. [0138] (Example 1) LiNio.5Mn1.5O4 as the positive electrode active substance, a polyvinylidene fluoride (5 mass%) as the binder and carbon black as the electroconductive agent (5 mass%) were mixed to be a positive electrode mixture. The positive electrode mixture was dispersed in N-methyl-2-pyrrolidone to prepare a positive electrode slurry. This positive electrode slurry was uniformly applied to one side of a collector made of aluminum with a thickness of 20 um. The thickness of the applied film was adjusted so that the first charge capacity per unit area became 2.5 mAh/cm2. After dried, it was compressed and molded with a roll press to produce a positive electrode. [0139] Synthetic graphite was used as a negative electrode active substance. The synthetic graphite was dispersed in N-methylpyrrolidone in which a PVDF was dissolved, to prepare a negative electrode slurry. The mass ratio of the negative electrode active substance and the binder was set to be 90/10. This negative electrode slurry was uniformly applied on a Cu collector with a thickness of 10 urn. The thickness of the applied film was adjusted so that the first charge capacity became 3.0 mAh/cm . After dried, it was compressed and molded with a roll press to produce a negative electrode. [0140] The positive electrode and the negative electrode which were cut to 3 cm x 3 cm were oppositely disposed through a separator. As the separator, a fine-porous polypropylene film with a thickness of 25 urn was used. [0141] As the nonaqueous electrolyte solvent, a solvent, which was obtained by mixing ethylene carbonate (EC), diethyl carbonate (DEC) and tris(2,2,2-trifluoroethyl) phosphate at a volume ratio of 24/56/20, was used. LiPF6 was dissolved in this nonaqueous electrolyte solvent in a concentration of 1 mol/1 to prepare an electrolyte liquid. Hereinafter, the solvent, which was obtained by mixing EC, DEC and tris(2,2,2-trifluoroethyl) phosphate at a volume ratio of 24/56/20 is also abbreviated to solvent EC/DEC/PTTFE. [0142] The above-mentioned positive electrode, the negative electrode, the separator and the electrolyte liquid were disposed in a laminate package, and then the laminate was sealed to produce a lithium secondary battery. The positive electrode and the negative electrode were connected to tabs and were electrically connected to the outside of the laminate. [0143] At a temperature of 20°C, charge and discharge were carried out in the following charge conditions and discharge conditions. [0144] Charge conditions: constant current and constant voltage system, charge final voltage of 4.8 V, charge current of 22.5 mA, total charge time of 2.5 hours Discharge condition: constant current discharge, discharge final voltage of 3.0 V, discharge current of 20 mA [0145] The discharge capacity of the produced battery was about 20 mAh. [0146] Then, the charge and discharge cycle tests of these batteries were carried out. The charge and discharge cycle test was carried out at a temperature of 45 °C in the following conditions. [0147] Charge conditions: constant current and constant voltage system, charge final voltage of 4.8 V, charge current of 20 mA, total charge time of 2.5 hours Discharge condition: constant current discharge, discharge final voltage of 3.0 V, discharge current of 20 mA [0148] The capacity retention ratio (%) is the percentage of the discharge capacity (rnAh) after 100 cycles with respect to the discharge capacity (mAh) at the 1st cycle. LiNio.5Mn1.5O4 was used as the positive electrode active substance. [0149] [Example 2) A solvent was prepared by mixing ethylene carbonate (EC), dimethyl carbonate (DMC) and tris(2,2,2-trifluoroethyl) phosphate at a volume ratio of 24/56/20. Hereinafter, this solvent is also abbreviated to solvent EC/DMC/PTTFE. [0150] And, a secondary battery was produced and evaluated in the same manner as in Example 1 sxcept that solvent EC/DMC/PTTFE was used as the nonaqueous electrolyte solvent. The result is shown in TABLE 1. [0151] (Comparative Example 1) A secondary battery was produced in the same manner as in Example 1 except that Li(Mni.9Lio.i)04 was used as the positive electrode active substance and that a solvent obtained by mixing EC and DEC) at a volume ratio of 30/70 (hereinafter, also abbreviated to solvent EC/DEC) was used as the nonaqueous electrolyte solvent. And, it was estimated in the same manner as in Example 1 except that the charge final voltage was set to be 4.2 V. The result is shown in TABLE 1. The average discharge potential was estimated in the same manner as in Example 1 except that the range of charge and discharge voltage was set to be from 4.3 V to 3 V. The result is shown in TABLE 1. [0152] (Comparative Example 2) A secondary battery was produced in the same manner as in Example 1 except that Li(Mni.9Lio.i)C>4 was used as the positive electrode active substance. And, it was estimated in the same manner as in Example 1 except that the charge final voltage was set to be 4.2 V. The result is shown in TABLE 1. The average discharge potential was estimated in the same manner as in Example 1 except that the range of charge and discharge voltage was set to be from 4.3 V to 3 V. The result is shown in TABLE 1. [0153] (Comparative Example 3) A secondary battery was produced in the same manner as in Example 1 except that LiNii/3Coi/3Mni/302 was used as the positive electrode active substance and that solvent EC/DEC was used as the nonaqueous electrolyte solvent. And, it was estimated in the same manner as in Example 1 except that the charge final voltage was set to be 4.2 V. The result is shown in TABLE 1. The average discharge potential was estimated in the same manner as in Example 1 except that the range of charge and discharge voltage was set to be from 4.3 V to 3 V. The result is shown in TABLE 1. [0154] (Comparative Example 4) A secondary battery was produced in the same manner as in Example 1 except that LiNij/3Coi/3Mni/302 was used as the positive electrode active substance. And, it was estimated in the same manner as in Example 1 except that the charge final voltage was set to be 4.2 V. The result is shown in TABLE 1. The average discharge potential was estimated in the same manner as in Example 1 except that the range of charge and discharge voltage was set to be from 4.3 V to 3 V. The result is shown in TABLE 1. [0155] (Comparative Example 5) A secondary battery was produced in the same manner as in Example 1 except that LiNio.5Mn1.5O4 was used as the positive electrode active substance and that solvent EC/DEC was used as the nonaqueous electrolyte solvent. And, it was estimated in the same manner as in Example 1. The result is shown in TABLE 1. The average discharge potential was estimated in the same manner as in Example 1. The result is shown in TABLE 1. [0156] (Comparative Example 6) A solvent was prepared by mixing ethylene carbonate (EC) and dimethyl carbonate (DMC) at a volume ratio of 30/70. Hereinafter, this solvent is also abbreviated to solvent EC/DMC. And, a secondary battery was produced in the same manner as in Example 1 except that LiNio.5Mn1.5O4 was used as the positive electrode active substance and that solvent EC/DMC was used as the nonaqueous electrolyte solvent. And, it was estimated in the same manner as in Example 1. The result is shown in TABLE 1. The average discharge potential was estimated in the same manner as in Example 1. The result is shown in TABLE 1. [0157] u o o o o r—< U, CQ g, H U [0158] In the case where a positive electrode active substance operating at a potential of 4.2 V or lower with respect to lithium such as Li(Mni.9Lio.i)04 of Comparative Examples 1 and 2 or LiNii/3Coi/3Mni/302 of Comparative Examples 3 and 4 was used, the capacity retention ratio by using solvent EC/DEC/PTTFE was equivalent or was decreased more in comparison with using solvent EC/DEC. Because, in the range of normal charge final voltage 4.2V, the decomposition in the positive electrode side is not so remarkable, it is assumed that the improving effect by the addition of PTTFE to the electrolyte liquid cannot have been observed. [0159] On the other hand, in Examples 1 and 2 where a positive electrode active substance operating at a potential of 4.5 V or higher with respect to lithium was used, the capacity retention ratio was improved by mixing PTTFE. Note that, in Comparative Examples 5 and 6 where a positive electrode active substance having a potential of 4.5 V or higher with respect to lithium was used, decrease of the capacity was remarkable in the case of solvent EC/DEC and solvent EC/DMC. [0160] As the reason why the capacity retention ratio is improved by the addition of PTTFE in the case where a positive electrode active substance operating at a potential of 4.5 V or higher with respect to lithium was used, it is assumed that PTTFE has high oxidation resistance and is effective in suppressing the decomposition reaction of the electrolyte liquid in the positive electrode side. [0161] Then, the positive electrode active substances shown in TABLE 2 were used as the positive electrode active substance operating at a potential of 4.5 V or higher with respect to lithium, and they were evaluated in the same manner as in Example 1. All positive electrode active substances are a material operating at a potential of 4.5 V or higher with respect to lithium. [0162] (Example 3) A secondary battery was produced and evaluated in the same manner as in Example 1 except that LiNio.5Mn1.5O4 was used as the positive electrode active substance. The result is shown in TABLE 2. [0163] (Example 4) A secondary battery was produced and evaluated in the same manner as in Example 1 except that LiNio.5Mn1.35Tio.15O4 was used as the positive electrode active substance. [0164] (Example 5) A secondary battery was produced and evaluated in the same manner as in Example 1 except that LiNio.5Mn1.48Alo.02O4 was used as the positive electrode active substance. The result is shown in TABLE 2. [0165] (Example 6) A secondary battery was produced and evaluated in the same manner as in Example 1 except that LiNio.5Mn1.4gMgo.02O4 was used as the positive electrode active substance. The result is shown in TABLE 2. [0166] (Example 7) A secondary battery was produced and evaluated in the same manner as in Example 1 except that LiNio.5Mn1.49Bo.01O4 was used as the positive electrode active substance. The result is shown in TABLE 2. [0167] (Example 8) A secondary battery was produced and evaluated in the same manner as in Example 1 except that LiNi0.5Mn1.45Al0.05O3.95F0.05 was used as the positive electrode active substance. The result is shown in TABLE 2. [0168] (Example 9) A secondary battery was produced and evaluated in the same manner as in Example 1 except that LiNio.5Mn14gSio.02O3.95Fo.05 was used as the positive electrode active substance. The result is shown in TABLE 2. [0169] (Example 10) A secondary battery was produced and evaluated in the same manner as in Example 1 except that LiNio.4Coo.2Mn1.25^0.1504 was used as the positive electrode active substance. The result is shown in TABLE 2. [0170] (Example 11) A secondary battery was produced and evaluated in the same manner as in Example 1 except that LiNio.4Feo.2Mn1.25Tio.15O4 was used as the positive electrode active substance. The result is shown in TABLE 2. [0171] (Example 12) A secondary battery was produced and evaluated in the same manner as in Example 1 except that LiNio.sMni .35^0.1504 was used as the positive electrode active substance and except that an Si/SiO/C negative electrode active substance was used instead of graphite. The result is shown in TABLE 2. [0172] The Si/SiO/C negative electrode active substance is a material containing above-mentioned carbon material (a), metal (b) and metal oxide (c). A silicon having an average particle diameter of 5 um as metal (b), an amorphous silicon oxide (SiOx, 0 < x < 2) having an average particle diameter of 13 urn as metal oxide (c), and graphite having an average particle diameter of 3 0 um as carbon material (a) were weighed at a mass ratio of 2 9:61:10. Then, these materials were mixed by so-called mechanical milling for 24 hours to obtain a negative electrode active substance. Note that, in this negative electrode active substance, the silicon that is metal (b) was dispersed in the silicon oxide (SiOx, 0 < x < 2) that is metal oxide (c). [0173] (Example 13) A secondary battery was produced and evaluated in the same manner as in Example 1 except that LiNio.sMni .35^0.1504 was used as the positive electrode active substance and except that a hard carbon (HC) was used as the negative electrode active substance instead of graphite. The result is shown in TABLE 2. [0174] (Comparative Example 7) A secondary battery was produced and evaluated in the same manner as in Example 3 except that solvent EC/DEC was used instead of solvent EC/DEC/PTTFE. The result is shown in TABLE 2. [0175] (Comparative Example 8) A secondary battery was produced and evaluated in the same manner as in Example 4 except that solvent EC/DEC was used instead of solvent EC/DEC/PTTFE. The result is shown in TABLE 2. [0176] (Comparative Example 9) A secondary battery was produced and evaluated in the same manner as in Example 5 except that solvent EC/DEC was used instead of solvent EC/DEC/PTTFE. The result is shown in TABLE 2. [0177] (Comparative Example 10) A secondary battery was produced and evaluated in the same manner as in Example 6 except that solvent EC/DEC was used instead of solvent EC/DEC/PTTFE. The result is shown in TABLE 2. [0178] (Comparative Example 11) A secondary battery was produced and evaluated in the same manner as in Example 7 except that solvent EC/DEC was used instead of solvent EC/DEC/PTTFE. The result is shown in TABLE 2. [0179] (Comparative Example 12) A secondary battery was produced and evaluated in the same manner as in Example 8 except that solvent EC/DEC was used instead of solvent EC/DEC/PTTFE. The result is shown in TABLE 2. [0180] (Comparative Example 13) A secondary battery was produced and evaluated in the same manner as in Example 9 except that solvent EC/DEC was used instead of solvent EC/DEC/PTTFE. The result is shown in TABLE 2. [0181] (Comparative Example 14) A secondary battery was produced and evaluated in the same manner as in Example 10 except that solvent EC/DEC was used instead of solvent EC/DEC/PTTFE. The result is shown in TABLE 2. [0182] (Comparative Example 15) A secondary battery was produced and evaluated in the same manner as in Example 11 except that solvent EC/DEC was used instead of solvent EC/DEC/PTTFE. The result is shown in TABLE 2. [0183] (Comparative Example 16) A secondary battery was produced and evaluated in the same manner as in Example 12 except that solvent EC/DEC was used instead of solvent EC/DEC/PTTFE. The result is shown in TABLE 2. [0184] (Comparative Example 17) A secondary battery was produced and evaluated in the same manner as in Example 13 except that solvent EC/DEC was used instead of solvent EC/DEC/PTTFE. The result is shown in TABLE 2. [0185] [0186] As a result of TABLE 2, in a variety of the positive electrode active substances operating at a potential of 4.5 V or higher with respect to lithium, a large improving effect was observed in the electrolyte liquid containing PTTFE. From these results, in the case of using the positive electrode active substance operating at a potential of 4.5 V or higher with respect to lithium, it has been confirmed that the operating life can be improved by using the electrolyte liquid containing a fluorine-containing phosphate. In particular, it is known that high capacity is obtained in the case of the 5 V class positive electrode containing Ni such as LiNio.5Mn1.5O4, and it is expected that a battery having high capacity and long operating life is obtained by using these positive electrode active substances. [0187] Also, as shown in Examples 12 and 13, even if the negative electrode material was changed, a similar effect was obtained. From the result, the effect of the present invention is an effect of improving the positive electrode operating at a high potential and the electrolyte liquid, and no matter what the negative electrode material is, a similar effect is expected. [0188] Subsequently, the kind of the fluorine-containing phosphate was studied. [0189] (Example 14) A secondary battery was produced and evaluated in the same manner as in Example 1 except that a solvent obtained by mixing EC/DEC/fluorine-containing phosphate at a ratio of 30/40/30 was used as the nonaqueous electrolyte solvent and except that LiNio.5Mn1.35Tio.15O4 was used as the positive electrode active substance. Tris(2,2,2-trifluoroethyl) phosphate was used as the fluorine-containing phosphate. The result is shown in TABLE 3. [0190] (Example 15) A secondary battery was produced and evaluated in the same manner as in Example 14 except that tris(2,2,3,3-tetrafluoropropyl) phosphate was used as the fluorine-containing phosphate instead of tris(2,2,2-trifluoroethyi) phosphate. The result is shown in TABLE 3. [0191] (Example 16) A secondary battery was produced and evaluated in the same manner as in Example 14 except that tris(2,2,3,3,3-pentafluoropropyl) phosphate was used as the fluorine-containing phosphate instead of tris(2,2,2-trifluoroethyl) phosphate. The result is shown in TABLE 3. [0192] (Comparative Example 18) A secondary battery was produced and evaluated in the same manner as in Example 14 except that trimethyl phosphate was used instead of the fluorine-containing phosphate. The result is shown in TABLE 3. [0193] (Comparative Example 19) A secondary battery was produced and evaluated in the same manner as in Example 14 except that triethyl phosphate was used instead of the fluorine-containing phosphate. The result is shown in TABLE 3. [0194] (Comparative Example 20) A secondary battery was produced and evaluated in the same manner as in Example 14 except that solvent EC/DEC (30/70) was used instead of the nonaqueous electrolyte solvent of Example 14. [0195] TABLE 3 [0196] As shown in TABLE 3, by using the electrolyte liquid containing a variety of the fluorine-containing phosphates, the capacity retention ratio was improved. In particular, tris(2,2,2-trifluoroethyl) phosphate used in Example 14 has high effect. [0197] Subsequently, the content of the fluorine-containing phosphate in the nonaqueous electrolyte solvent was studied. [0198] (Examples 17 to 24 and Comparative Example 21) Secondary batteries were produced and evaluated in the same manner as in Example 2 except that the following nonaqueous electrolyte solvent was used. As the nonaqueous electrolyte solvent, a solvent obtained by mixing the mixed solvent of EC/DMC = 30/70 (solvent EC/DMC) and PTTFE at a volume ratio of (100-x):x was used. The values x and the results are shown in TABLE 4. Note that, the condition of Comparative Example 21 is the same as that of Comparative Example 6. [0199] TABLE 4 capacity retention x EC/DMC/PTTFE ratio Ex.17 10 27/63/10 66% Ex.18 20 24/56/20 72% Ex. 19 30 21/49/30 77% Ex.20 40 18/42/40 76% Ex.21 50 15/35/50 76% Ex.22 60 12/28/60 70% Ex.23 70 9/21/70 67% Ex.24 80 6/14/80 65~% Comp. Ex. 21 0 30/70/0 52% [0200] As mentioned above, the capacity retention ratio was high when the content of PTTFE was in a range of 10 vol% or more and 70 vol% or less, and the capacity retention ratio was higher when it was in a range of 20 vol% or more and 60 vol% or less. [0201] Subsequently, the combinations of the fluorine-containing phosphate and a variety of the solvents were studied. The cases, in which ethylene carbonate (EC), diethyl carbonate (DEC), dimethyl carbonate (DMC), ethyl methyl carbonate (EMC), fluorinated ethyl methyl carbonate (CF3OCOOC2H5, also referred to as fluorinated EMC), methyl propionate, ethyl acetate, 1 -ethoxycarbonyloxy-2-methoxycarbonyloxyethane (C2H5-OCOO-CH2CH2-OCOO-CH3) or 1,2-bis(methoxycarbonyloxy)ethane (CH3-OCOO-CH2CH2-OCOO-CH3) was mixed, were studied. [0202] (Examples 25 to 32, and Comparative Examples 22 and 23) -r-r Secondary battery were produced and evaluated in the same manner as in Example 1 except that LiNio. 5Mn1. 35Tio. 15O4 was used as the positive electrode active substance and except that the nonaqueous electrolyte solvent described in TABLE 5 was used. The results are shown in TABLE 5. [0203] TABLE 5 [0204] In all the nonaqueous electrolyte solvents used in the Examples, the effect was observed. In particular, in the case where an alkylene biscarbonate was contained together with the fluorine-containing phosphate, a good capacity retention ratio was obtained. [0205] Subsequently, a stacked laminate type battery was produced, and the cycle property and the generated gas amount after the cycle evaluation were evaluated. [0206] (Example 2-1) LiNio.5Mn1.35Tio.15O4 as the positive electrode active substance, a polyvinylidene fluoride (5 mass%) as the binder and carbon black as the electroconductive agent (5 mass%) were mixed to be a positive electrode mixture. The positive electrode mixture was dispersed in N-methyl-2- pyrrolidone to prepare a positive electrode slurry. This positive electrode slurry was uniformly applied to both sides of a collector made of aluminum with a thickness of 20 urn. The thickness of the applied film was adjusted so that the first charge capacity per unit area of the electrode at one side of the collector became 2.5 mAh/cm2. After dried, it was compressed and molded with a roll press to produce a positive electrode. [0207] A synthetic graphite was used as a negative electrode active substance. The synthetic graphite was dispersed in N-methylpyrrolidone in which a PVDF was dissolved, to prepare a negative electrode slurry. The mass ratio of the negative electrode active substance and the binder was set to be 90/10. This negative electrode slurry was uniformly applied on both side of a Cu collector with a thickness of 10 um. The thickness of the applied film was adjusted so that the first charge capacity of the electrode at one side of the collector became 3.0 mAh/cm2. After dried, it was compressed and molded with a roll press to produce a negative electrode. [0208] The positive electrode which was cut to 28 mm x 28 mm and the negative electrode which was cut to 30 mm x 30 mm were oppositely disposed through a separator. As the separator, a fine-porous polypropylene film with a thickness of 25 um was used. The size of the separator is set to be 34 mm x 34 mm. It was designed so that the collector part of 7 mm x 5 mm appeared to the outside of the separator from the electrode because both the positive electrode and the negative electrode can be electrically connected to the outside. [0209] The electrolyte liquid was prepared by dissolving LiPF6 in a concentration of 1 mol/1 in the nonaqueous electrolyte solvent having a composition (EC/DMC/PTTFE = 30/35/35) of following TABLE 6. [0210] These were stacked in the order of the negative electrode, the separator, the positive electrode, the separator and negative electrode. 6 layers of the negative electrode, 5 layers of the positive electrode and 10 layers of separators were stacked. In the positive electrodes and the negative electrodes, the projection parts of the collectors electrically connected to each layer were welded with electrode tabs. This stacked product was disposes in a laminate package and was sealed by lamination to produce a lithium secondary battery. The positive electrode and the negative electrode were connected to tabs and were electrically connected to the outside of the laminate. The electrolyte liquid was injected to the battery of this stacked product and it was sealed with vacuum by lamination to produce a stacked laminate type battery. [0211] At a temperature of 20°C, charge and discharge were carried out in the following charge conditions and discharge conditions. [0212] Charge conditions: constant current and constant voltage system, charge final voltage of 4.8 V, charge current of 40 mA, total charge time of 2.5 hours Discharge condition: constant current discharge, discharge final voltage of 3.0 V, discharge current of 180 mA [0213] The discharge capacity of the produced battery was about 180 mAh. [0214] At this time, the volume of the cell was evaluated. The volume of the cell was measured by the Archimedes method. Specifically, the volume of the cell was calculated by the difference of the cell masses which were measured in air and in water. [0215] Then, the charge and discharge cycle tests of these batteries were carried out. The charge and discharge cycle test was carried out at a temperature of 45°C in the following conditions. [0216] Charge conditions: constant current and constant voltage system, charge final voltage of 4.8 V, charge current of 180 mA, total charge time of 2.5 hours Discharge condition: constant current discharge, discharge final voltage of 3.0 V, discharge current of 180 mA [0217] The capacity retention ratio (%) is the percentage of the discharge capacity (mAh) after 100 cycles with respect to the discharge capacity (mAh) at the 1st cycle. [0218] After 100 cycles at 45°C, the volume of the cell was evaluated again. The volume of the cell was measured by the Archimedes method like before cycle. The increasing rate of the cell volume was calculated from the change of the volume after 100 cycles at 45 °C with respect to the volume before cycle. [0219] (Examples 2-2 to 2-4) Secondary batteries were produced and evaluated in the same manner as in Example 2-1 except that the nonaqueous electrolyte solvent having a composition of following TABLE 6 was used. [0220] In Examples 2-1 to 2-4, as the nonaqueous electrolyte solvent, the concentration of EC (volume ratio) was fixed and the concentrations of DMC and PTTFE were changed. [0221] The results of the capacity retention ratio and the cell volume change after 100 cycles at 45°C are shown in TABLE 6. [0222] TABLE 6 [0223] As shown in TABLE 6, when the composition of DMC and PTTFE was changed, the capacity retention ratio was slightly decreased in the case of using much PTTFE. However, all the battery in the Examples had high capacity retention ratio. On the other hand, it was confirm that the cell volumetric change was largely decreased by replacing DMC with PTTFE. This cell volume change is due to the generation of the gas in the cell. Since the gas generated in the cell resulted may result in the swollenness or the like, the amount of the generated gas was preferably small. In the case where the positive electrode operates at a high potential, the electrolyte liquid may be decomposed at a high temperature such as 45°C and the gas may be generated. It is thought that the amount of the generated gas can have been drastically decreased by replacing DMC with PTTFE having high oxidation resistance. Note that, since many fluorinated solvents have low compatibility with the non-fluorinated solvent such as EC, the solvent may be isolated by the mixing. However, the fluorinated phosphate had high compatibility with the non-fluorinated solvent such as EC, and the solvent was not isolated. Since the electrolyte liquid is preferably a uniform mixed solvent, the fluorinated phosphate is excellent from the viewpoint of uniformity. As mentioned above, it has been confirmed that the positive electrode substance operating at a high potential also has high capacity retention ratio and the generation of the gas in the cell was suppressed. [0224] (Examples 3-1 to 3-5) In Examples 3-1 to 3-5, the experiments were carried out with changing the volume ratio of EC and PTTFE in Example 2-4. In other words, secondary batteries was produced and evaluated in the same manner as in Example 2-4 except that the nonaqueous electrolyte solvent having a composition of following TABLE 7 was used. The results are shown in TABLE 7. [0225] (Examples 3-6 to 3-8) In Examples 3-6 to 3-8, the experiments were carried out with changing a part of EC as the cyclic-type carbonate in Example 2-4 to PC, BC or 4-fluoro-l ,3-dioxolane-2-one (FEC). In other words, secondary batteries were produced and evaluated in the same manner as in Example 2-4 except that the nonaqueous electrolyte solvent having a composition of following TABLE 7 was used. The results are shown in TABLE 7. [0226] TABLE 7 composition of capacity cell volume change nonaqueous electrolyte solvent retention (generated gas amount) (volume ratio) ratio Ex. 2-4 EC/PTTFE = 30/70 74% 2.0% Ex. 3-1 EC/PTTFE = 20/80 74% 1.5% Ex. 3-2 EC/PTTFE =10/90 77% 1.2% Ex. 3-3 EC/PTTFE = 5/95 70% L~0% Ex. 3-4 EC/PTTFE = 50/50 74% 4.0 % Ex. 3-5 EC/PTTFE = 70/30 68% 7.0 % Ex. 3-6 EC/PC/PTTFE = 20/5/75 74% 2.5 % Ex. 3-7 EC/BC/PTTFE = 20/5/75 75~% 2.0 % Ex. 3-8 EC/FEC/PTTFE = 20/5/75 73~% 3.5 % [0227] The results of the good capacity retention ratio and the amount of the generated gas were obtained in the case where the content of the cyclic-type carbonate such as EC, PC, BC and FEC were 5 % or more. [0228] As shown in Example 3-5, since the capacity retention ratio in the case where the content of the EC was 70 vol% was slightly decreased in comparison with the case of 50 vol%, it has been found that the content of the cyclic-type carbonate in the nonaqueous electrolyte solvent is preferably 70 vol% or less, and is more preferably 50 vol% or less. Also, from Example 3-5, it has been found that the content of the fluorinated phosphate in the nonaqueous electrolyte solvent is preferably 30 vol% or more. [0229] As shown in Example 3-3, also in the case where the fluorinated phosphate is 95 vol%, the results of the capacity retention ratio and the amount of the generated gas were good. From these results, it has been found that the composition range of the fluorinated phosphate is preferably 95 vol% or less. [0230] From the above-mentioned results, the nonaqueous electrolyte solvent preferably contains a fluorinated phosphate and a cyclic-type carbonate, and the content of the fluorinated phosphate in the nonaqueous electrolyte solvent is preferably 30 vol% or more and 95 vol% or less, and the content of the cyclic-type carbonate in the nonaqueous electrolyte solvent is 5 vol% or more and 70 vol% or less. [0231] Subsequently, mixed solvents of a cyclic-type carbonate, a fluorinated phosphate and a fluorinated linear-type carbonate were studied. As the fluorinated linear-type carbonate, 2,2,2-trifluoroethyl methyl carbonate (hereinafter, FC1), monofluoromethyl methyl carbonate (hereinafter, FC2), methyl-2,2,3,3-tetrafluoropropyl carbonate (hereinafter, FC3) and bis(2,2,2-trifluoroethyl) carbonate (hereinafter, FC4) were used. As the fluorinated phosphate, tris(2,2,2-trifluoroethyl) phosphate (PTTFE), tris(lH,lH-heptafluorobutyl) phosphate (FP1) and tris(lH,lH,5H-octafluoropentyl) phosphate (FP2) were used. [0232] (Example 4-1) A secondary battery was produced and evaluated in the same manner as in Example 2-4 except that the nonaqueous electrolyte solvent having a composition of following TABLE 8 was used. The results are shown in TABLE 8. [0233] (Examples 4-2 to 4-12) Secondary batteries were produced and evaluated in the same manner as in Example 2-4 except that the nonaqueous electrolyte solvent having a composition of following TABLE 8 was used. The results are shown in TABLE 8. [0234] TABLE 8 [0235] As indicated in Examples 4-1 to 4-12, the high capacity retention ratio was obtained in the secondary battery using the electrolyte liquid containing a mixed solvent with a cyclic-type carbonate, a linear-type carbonate and a fluorinated phosphate. [0236] Also, in the case of containing a fluorinated linear-type carbonate as the linear-type carbonate, it has been found that the amount of the generated gas can keep small and the capacity retention ratio is improved (Examples 4-2 to 4-12). Also, an effect of improving the capacity retention ratio and an effect of decreasing the amount of the generated gas have been confirmed in the case where the content of the fluorinated linear-type carbonate in the nonaqueous electrolyte solvent was at least in a range of 5 vol% or more and 60 vol% or less. [0237] Also, as the fluorinated linear-type carbonate, 2,2,2-trifluoroethyl methyl carbonate, monofluoromethyl methyl carbonate and the like are preferably used. [0238] Also, in Examples 4-2 to 4-7, an effect of improving the capacity retention ratio and an effect of decreasing the amount of the generated gas have been confirmed in the case where the content of the fluorinated phosphate in the nonaqueous electrolyte solvent was at least in a range of 10 vol% or more and 65 vol% or less. [0239] Also, as shown in Examples 4-11 and 4-12, also in the case of using a nonaqueous electrolyte solvent containing tris(lH,lH-heptafluorobutyl) phosphate (FP1) or tris(lH,lH,5H-octafluoropentyl) phosphate (FP2) as the fluorinated phosphate, similar effects were obtained. [0240] From these results, an effect of improving the capacity retention ratio and an effect of decreasing the amount of the generated gas have been confirmed when using a nonaqueous electrolyte solvent containing a cyclic-type carbonate, a fluorinated linear-type carbonate and a fluorinated phosphate. [0241] Subsequently, mixed solvents of a cyclic-type carbonate, a fluorinated phosphate and a fluorinated linear-type ether compound was studied. As the fluorinated linear-type ether compound, l,l,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (FET1), 1,1,1,2,3,3-hexafluoropropyl-2,2-difluoroethyl ether (FET2), lH,lH,2'H-perfluorodipropyl ether (FET3) and 1H,1H,2'H,3H- decafluorodipropyl ether (FET4) were used. Also, ET1 of TABLE 9 represents dipropyl ether. [0242] As the fluorinated phosphate, tris(2,2,2-trifluoroethyl) phosphate (PTTFE), tris(lH,lH-heptafluorobutyl) phosphate (FP1) and tris(lH,lH,5H-octafluoropentyl) phosphate (FP2) were used. [0243] (Examples 5-1 to 5-10) Secondary batteries were produced and evaluated in the same manner as in Example 2-4 except that the nonaqueous electrolyte solvent having a composition of following TABLE 9 was used. The results are shown in TABLE 9. [0244] (Example 5-11) A secondary battery was produced and evaluated in the same manner as in Example 2-4 except that the nonaqueous electrolyte solvent having a composition of following TABLE 9 was used. The results are shown in TABLE 9. [0245] (Examples 5-12 to 5-13) Secondary batteries were produced and evaluated in the same manner as in Example 2-4 except that the nonaqueous electrolyte solvent having a composition of following TABLE 9 was used. The results are shown in TABLE 9. [0246] [0247] In the nonaqueous electrolyte solvent consisting of a mixed solvent of a cyclic-type carbonate, a linear-type ether compound and a fluorinated phosphate, in the case of using a fluorinated linear-type ether as the linear-type ether compound, it has been found that the amount of the generated gas can keep small and the capacity retention ratio is improved. [0248] The content of the fluorinated linear-type ether in the nonaqueous electrolyte solvent is preferably 5 vol% or more and 60 vol% or less. Also, as the fluorinated linear-type ether, 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether, 1,1,1,2,3,3-hexafluoropropyl-2,2-difluoroethyl ether, lH,lH,2'H-perfluorodipropyl ether, lH,lH,2'H,3H-decafluorodipropyl ether and the like are preferable. [0249] The effect was obtained in the case where the content of the fluorinated phosphate in the nonaqueous electrolyte solvent was at least in a range of 10 vol% or more and 60 vol% or less. Also, in the electrolyte liquid containing tris(lH,lH-heptafluorobutyl) phosphate (FP1) or tris(lH,lH,5H-octafluoropentyl) phosphate (FP2) as the fluorinated phosphate, similar effect was obtained. [0250] From these results, an effect of improving the capacity retention ratio and an effect of decreasing the amount of the generated gas have been confirmed when using a nonaqueous electrolyte solvent containing a cyclic-type carbonate, a fluorinated linear-type ether and a fluorinated phosphate. [0251] Subsequently, mixed solvents of a cyclic-type carbonate, a fluorinated phosphate and a fluorinated carboxylate was studied. As the fluorinated carboxylate compound, 2,2,3,3-tetrafluoromethyl propionate (FCX1), methyl heptafluoroisobutylate (FCX2) and 2,2,3,3-tetrafluoropropyl trifluoroacetate (FCX3) were used. Also, CXI of TABLE 10 represents methyl propionate. [0252] (Examples 6-1 to 6-3) Secondary batteries were produced and evaluated in the same manner as in Example 2-4 except that the nonaqueous electrolyte solvent having a composition of following TABLE 10 was used. The results are shown in TABLE 10. [0253] (Example 6-4) A secondary battery was produced and evaluated in the same manner as in Example 2-4 except that the nonaqueous electrolyte solvent having a composition of following TABLE 10 was used. The results are shown in TABLE 10. [0254] [0255] From these results, an effect of improving the capacity retention ratio and an effect of decreasing the amount of the generated gas have been confirmed when using a nonaqueous electrolyte solvent containing a cyclic-type carbonate, a fluorinated linear-type carboxylate and a fluorinated phosphate. [0256] Subsequently, secondary batteries were produced using another material as the positive electrode active substance operating at 4.5 V or higher with respect to lithium, and they were evaluated. [0257] (Examples 7-1 to 7-8) In the Examples shown below, the following material was selected as the positive electrode active substance. [0258] Example 7-1 : UC0PO4 Example 7-2 : LiCoo.8Mno.2PO4 Example 7-3 : LiCoo.sNio.2PO4 Example 7-4 : Li(Lio.2Nio.2Mno.6)02 Example 7-5 : Li(Lio.2Ni0.2Coo.iMno.5)02 Example 7-6 : Li(Lio.i5Ni0.i5Mn0.7)02 Example 7-7 : Li(Lio.iNio.4sMno.45)02 Example 7-8 : LiNii/3Coi/3Mni/302 [0259] Each active substance has a voltage region at which Li is stably inserted and released therein. Thus, the charge voltage was set by every Example to be a value at which Li is stably inserted and released and by which a high capacity can be obtained. [0260] In Examples 7-1 to7-3 (LiCoP04, LiCoo.gMno.2PO4, LiCoo.sNio.2PO4), the charge voltage was set to be 5.0 V. In Examples 7-4 to 7-7 (Li(Li0.2Nio.2Mno.6)02, Li(Lio.2Nio.2Co0.iMno.5)02, Li(Li0. isNio.i5Mno.7)02, Li(Li0.iNio.45Mno.45)02), the charge voltage was set to be 4.6 V. In Example 7-8 (LiNii/3Coi/3Mni/302), it was set to be 4.5 V. [0261] A positive electrode was produced in the same manner as in Example 2-1 except that the film thickness of the electrode was adjusted as explained in the following. [0262] At the time of producing the electrode, the thickness of the applied film was adjusted so that the first charge capacity per unit area of the one side of the positive electrode became 2.5 mAh/cm . Since the graphite negative electrode operates at approximately 0.1 V with respect to Li, the capacity in the potential obtained by adding 0.1 V to the upper voltage of the battery of each material was evaluated, and the film thickness of the electrode was adjusted based on the value. [0263] Specifically, in Examples 7-1 to 7-3, the thickness of the applied film was adjusted so that the first charge capacity per unit area became 2.5 mAh/cm2 based on the charge capacity when it was charged at 5.1 V with respect to Li. In Examples 7-4 to 7-7, the thickness of the applied film was adjusted so that the first charge capacity per unit area became 2.5 mAh/cm2 based on the charge capacity when it was charged at 4.7 V with respect to Li. In Example 7-8, the thickness of the applied film was adjusted so that the first charge capacity per unit area became 2.5 mAh/cm2 based on the charge capacity when it was charged at 4.6 V with respect to Li. [0264] Secondary batteries were produced in the same manner as in Example 5-2 except that the above-mentioned positive electrode was used. Also, the secondary batteries were estimated in the same manner as in Example 5-2 except that the range of charge and discharge was set as shown in TABLE 11. The results are shown in TABLE 11. [0265] (Comparative Examples 7-1 to 7-8) Secondary batteries were produced and evaluated in the same manner as in Examples 7-1 to 7-8, respectively, except that mixed solvent (EC/DEC = 30/70) was used as the nonaqueous electrolyte solvent. [0266] [0267] In Examples 7-1 to 7-8, even if any positive electrode active substance was used, a large effect of improving the cycle property was obtained by using the electrolyte liquid containing a fluorinated phosphate. [0268] It is thought that the effect by the electrolyte liquid is a characteristic obtained commonly in a positive electrode material operating at a high potential. As the positive electrode material operating at a high voltage, lithium metal complex oxides are preferably used. Examples of the lithium metal complex oxide include, for example, OMPO4 (M is at least one of Co and Ni), Li(Mi.zMnz)02 (0.7 > z > 0.33, M is at least one of Li, Co and Ni) and Li(LixMi.x.zMnz)02 (0.3 > x > 0.1, 0.7 > z > 0.33, M is at least one of Co and Ni). [0269] Also, the secondary battery which has a positive electrode material operating at a high potential and an electrolyte liquid containing a fluorinated phosphate can provide the decrease of the amount of the generated gas with a high capacity retention ratio. In particular, in the secondary battery using the laminate package, much amount of the generated gas becomes a large problem regarding the appearance of the cell. However, this problem can be improved by using the electrolyte liquid containing a fluorinated phosphate. [0270] As described above, the constitution of an exemplary embodiment of the invention can provide a lithium secondary battery having high operation voltage and high energy density with suppressing the decrease of reliability in a high temperature. [0271] As follows, the Examples using a surface-treated graphite are mainly explained. [0272] (Example 8-1) LiNio.5Mn1.5O4 as the positive electrode active substance, a polyvinylidene fluoride (5 mass %) as the binder and carbon black as the electroconductive agent (5 mass%) were mixed to be a positive electrode mixture. The positive electrode mixture was dispersed in N-methyl-2-pyrrolidone to prepare positive electrode slurry. This positive electrode slurry was uniformly applied to one side of a collector made of aluminum with a thickness of 20 urn. The thickness of the applied film was adjusted so that the first charge capacity per unit area became 2.5 mAh/cm. After dried, it was compressed and molded with a roll press to produce a positive electrode. [0273] Surface-treated graphite consisting of graphite whose surface was coated with a low crystalline carbon material was dispersed in N-methylpyrrolidone in which a PVDF was dissolved, to prepare a negative electrode slurry. The mass ratio of the negative electrode active substance and the binder was set to be 90/10. This negative electrode slurry was uniformly applied on a Cu collector with a thickness of 10 um. The thickness of the applied film was adjusted so that the first charge capacity became 3.0 mAh/cm . After dried, it was compressed and molded with a roll press to produce a negative electrode. [0274] The positive electrode and the negative electrode which were cut to 3 cm x 3 cm were oppositely disposed through a separator. As the separator, a fine-porous polypropylene film with a thickness of 25 urn was used. [0275] As the nonaqueous electrolyte solvent, a mixed solvent, which was obtained by mixing ethylene carbonate (EC), diethyl carbonate (DEC) and tris(2,2,2-trifluoroethyl) phosphate at a volume ratio of 24/56/20, was used. LiPF6 was dissolved in this nonaqueous electrolyte solvent in a concentration of 1 mol/I to prepare an electrolyte liquid. Hereinafter, the solvent, which was obtained by mixing EC, DEC and tris(2,2,2-trifluoroethyl) phosphate at a mass ratio of 24/56/20 is also abbreviated to solvent EC/DEC/PTTFE. [0276] The above-mentioned positive electrode, the negative electrode, the separator and the electrolyte liquid were disposed in a laminate package and were sealed by lamination to produce a lithium secondary battery. The positive electrode and the negative electrode were connected to tabs and were electrically connected to the outside of the laminate. [0277] At a temperature of 20°C, charge and discharge were carried out in the following charge conditions and discharge conditions. [0278] Charge conditions: constant current and constant voltage system, charge final voltage of 4.8 V, charge current of 22.5 mA, total charge time of 2.5 hours Discharge condition: constant current discharge, discharge final voltage of 3.0 V, discharge current of 20 mA [0279] The discharge capacity of the produced battery was about 20 mAh. [0280] Then, the charge and discharge cycle tests of these batteries were carried out. The charge and discharge cycle test was carried out at a temperature of 45 °C in the following conditions. [0281] Charge conditions: constant current and constant voltage system, charge final voltage of 4.8 V, charge current of 20 mA, total charge time of 2.5 hours Discharge condition: constant current discharge, discharge final voltage of 3.0 V, discharge current of 20 mA [0282] The capacity retention ratio (%) is the percentage of the discharge capacity (mAh) after 100 cycles with respect to the discharge capacity (mAh) at the 1st cycle. LiNio.5Mn1.5O4 was used as the positive electrode active substance as the Example. [0283] (Example 8-2) A solvent was prepared by mixing ethylene carbonate (EC), dimethyl carbonate (DMC) and tris(2,2,2-trifluoroethyl) phosphate at a volume ratio of 24/56/20. Hereinafter, this solvent is also abbreviated to solvent EC/DMC/PTTFE. [0284] And, a secondary battery was produced and evaluated in the same manner as in Example 8-1 except that solvent EC/DMC/PTTFE was used as the nonaqueous electrolyte solvent. The result is shown in TABLE 12. [0285] (Example 8-3) A secondary battery was produced in the same manner as in Example 8-1 except that high crystalline graphite having no surface coating was used as the negative electrode active substance. And, it was evaluated in the same manner as in Example 8-1. The result is shown in TABLE 12. [0286] (Example 8-4) A secondary battery was produced in the same manner as in Example 8-2 except that high crystalline graphite having no surface coating was used as the negative electrode active substance. And, it was evaluated in the same manner as in Example 8-2. The result is shown in TABLE 12. [0287] (Comparative Example 8-1) A secondary battery was produced in the same manner as in Example 8-1 except that a solvent obtained by mixing ethylene carbonate (EC) and diethyl carbonate (DEC) at a volume ratio of 30/70 (hereinafter, also abbreviated to solvent EC/DEC) was used as the nonaqueous electrolyte solvent. And, it was evaluated in the same manner as in Example 8-1. The result is shown in TABLE 12. [0288] (Comparative Example 8-2) A secondary battery was produced in the same manner as in Example 1 except that a solvent obtained by mixing ethylene carbonate (EC) and dimethyl carbonate (DMC) at a volume ratio of 30/70 (hereinafter, also abbreviated to solvent EC/DMC) was used as the nonaqueous electrolyte solvent. And, it was evaluated in the same manner as in Example 8-1. The result is shown in TABLE 12. [0289] (Comparative Example 8-3) A secondary battery was produced in the same manner as in Example 8-3 except that high crystalline graphite having no surface coating was used as the negative electrode active substance and that solvent EC/DEC was used as the nonaqueous electrolyte solvent. And, it was evaluated in the same manner as in Example 8-1. The result is shown in TABLE 12. [0290] (Comparative Example 8-4) A secondary battery was produced in the same manner as in Example 8-4 except that high crystalline graphite having no surface coating was used as the negative electrode active substance and that solvent EC/DMC was used as the nonaqueous electrolyte solvent. And, it was evaluated in the same manner as in Example 8-1. The result is shown in TABLE 12. [0291] (Reference Example 8-1) A secondary battery was produced in the same manner as in Example 8-1 except that Li(Mni.9Lio.i)C>4 was used as the positive electrode active substance. And, it was evaluated in the same manner as in Example 8-1 except that the charge final voltage was set to be 4.2 V. The result is shown in TABLE 12. The average discharge potential was evaluated in the same manner as in Example 8-1, but the voltage range of charge and discharge was set to be from 4.2 V to 3 V. Results are shown in TABLE 12. [0292] (Reference Example 8-2) A secondary battery was produced in the same manner as in Example 8-1 except that Li(Mni.9Lio.i)04 was used as the positive electrode active substance and except that high crystalline graphite having no surface coating was used as the negative electrode active substance. And, it was evaluated in the same manner as in Example 8-1 except that the charge final voltage was set to be 4.2 V. The result is shown in TABLE 12. The average discharge potential was evaluated in the same manner as in Example 8-1, but the voltage range of charge and discharge was set to be from 4.2 V to 3 V. Results are shown in TABLE 12. [0293] (Reference Example 8-3) A secondary battery was produced in the same manner as in Example 8-1 except that Li(Mni.9Lio.i)04 was used as the positive electrode active substance, except that high crystalline graphite having no surface coating was used as the negative electrode active substance, and except that solvent EC/DEC was used as the nonaqueous electrolyte solvent. And, it was evaluated in the same manner as in Example 8-1 except that the charge final voltage was set to be 4.2 V. The result is shown in TABLE 12. The average discharge potential was evaluated in the same manner as in Example 8-1, but the voltage range of charge and discharge was set to be from 4.2 V to 3 V. Results are shown in TABLE 12. [0294] [0295] At first, by comparison regarding the cases of using a positive electrode active substance operating at a potential of 4.2 V or lower with respect to lithium (Reference Examples 8-1 to 8-3), the capacity retention ratio in the case where solvent EC/DEC was used and the negative electrode active substance was graphite (Reference Example 8-3) was most excellent. On the other hand, the capacity retention ratios in Reference Example 8-1 and Reference Example 8-2 where solvent EC/DEC/PTTFE was used were decreased than that of Reference Example 8-3. As the reason, it is assumed that the capacity was decreased due to a low ion conductivity of the electrolyte liquid because the dielectric constant of PTTFE is lower than that of carbonates such as EC and the viscosity is higher than that of DEC or the like, or due to a decreased electroconductivity of lithium because a coating caused by a side reaction of PTTFE on the surface is formed. Also, when solvent EC/DEC/PTTFE is used, the capacity retention ratio in the case where the negative electrode active substance was a surface-treated graphite (Reference Example 8-1) was slightly higher than that in the case of graphite (Reference Example 8-2). [0296]Then, by comparison regarding the cases of using a positive electrode active substance operating a potential of 4.5 V or higher with respect to lithium and using solvent EC/DEC, both in the case where the negative electrode active substance was surface-treated graphite (Comparative Example 8-1) and in the case where it was graphite (Comparative Example 8-3), the capacity retention ratio was greatly decreased. This reason can be assumed why solvent EC/DEC is decomposed on the surface of the positive electrode due to the high charge potential. [0297] Also, when solvent EC/DMC was used, both in the case where the negative electrode active substance was surface-treated graphite (Comparative Example 8-2) and in the case where it was graphite (Comparative Example 8-4), the capacity retention ratio was decreased. However, the decreasing range was smaller than that in the case using solvent EC/DEC. This reason can be assumed why the oxidation resistance of DMC was higher than that of DEC and the amount of the decomposition on the surface of the positive electrode of DMC was smaller than that of DEC. [0298] Then, the comparison is made regarding Comparative Examples 8-1 to 8-4 which are the cases of using a positive electrode active substance operating a potential of 4.5 V or higher with respect to lithium and using solvent EC/DEC or solvent EC/DMC. Both in the case where the negative electrode active substance was surface-treated graphite (Comparative Examples 8-1 and 8-2) and in the case where it was graphite (Comparative Examples 8-3 and 8-4), the capacity retention ratio was greatly decreased. This reason can be assumed why solvent EC/DEC or solvent EC/DMC is decomposed on the surface of the positive electrode due to the high charge potential. Also, since the influence of this decomposition of the electrolyte liquid on the surface of the positive electrode to the capacity retention ratio is large, the difference of the negative electrode active substance does not greatly appear to the capacity retention ratio. [0299] On the other hand, in Examples 8-1 to 8-4 where the electrolyte liquid mixed with PTTFE was used with the positive electrode active substance operating at potential 4.5V or higher with respect to lithium, the capacity retention ratio was greatly improved in comparison to Comparative Examples 8-1 to 8-4 where PTTFE was not mixed. This reason can be assumed why the decomposition amount of EC, DEC or DMC on the surface of the positive electrode was decreased by using PTTFE which has high oxidation resistance as the nonaqueous electrolyte solvent. [0300] Further, the comparison is made regarding the difference of negative electrode active substance. The secondary batteries obtained by using surface-treated graphite as the negative electrode active substance (Examples 8-1 and 8-2) had a better capacity retention ratio than the secondary batteries obtained by using non-surface-treated graphite (Examples 8-3 and 8-4). These results show that the decomposition of the electrolyte liquid on the surface of the positive electrode can be suppressed and the side reaction of the electrolyte liquid on the surface of the negative electrode by using the fluorine-containing phosphate which has excellent oxidation resistance such as PTTFE together with surface-treated graphite. Thus, even if positive electrode active substance whose average discharge potential is 4.5V or higher was used, a good capacity retention ratio of the secondary battery can be realized by using a fluorine-containing phosphate as the solvent together with surface-treated graphite as the negative electrode active substance. [0301] The combined effect by using a fluorine-containing phosphate together with surface-treated graphite as mentioned above is not an effect which is not observed in an operating potential range of a conventional the case of a 4 V class positive electrode material and is a new effect which is observed in a combination with a positive electrode active substance operating at 4.5 V or higher. [0302] Then, a secondary battery was produced by using the positive electrode active substance shown in TABLE 13 as the positive electrode active substance having an average discharge potential of 4.5V or higher with respect to lithium, and it was evaluated. All the positive electrode materials shown in TABLE 13 are a material in which the positive electrode active substance operates at a potential of 4.5 V or higher with respect to lithium. [0303] (Example 9-1) A secondary battery was produced and evaluated in the same manner as in Example 8-1 except that LiNio.5Mn1.35Tio.15O4 was used as the positive electrode active substance was used. [0304] (Example 9-2) A secondary battery was produced and evaluated in the same manner as in Example 8-1 except that LiNio.5Mn1.4gAlo.02O4 was used as the positive electrode active substance was used. The result is shown in TABLE 13. [0305] (Example 9-3) A secondary battery was produced and evaluated in the same manner as in Example 8-1 except that LiNio.5Mn1.4gMgo.02O4 was used as the positive electrode active substance was used. The result is shown in TABLE 13. [0306] (Example 9-4) A secondary battery was produced and evaluated in the same manner as in Example 8-1 except that LiNio.5Mn1.49Bo.01O4 was used as the positive electrode active substance was used. The result is shown in TABLE 13. [0307] (Example 9-5) A secondary battery was produced and evaluated in the same manner as in Example 8-1 except that LiNio.5Mn1.45Alo.05O3.95Fo.05 was used as the positive electrode active substance was used. The result is shown in TABLE 13. 1 [0308] (Example 9-6) A secondary battery was produced and evaluated in the same manner as in Example 8-1 except that LiNi0.5Mn1.4gSi0.02O3.95F0.05 was used as the positive electrode active substance was used. The result is shown in TABLE 13. [0309] (Example 9-7) A secondary battery was produced and evaluated in the same manner as in Example 8-1 except that LiNio.4Coo.2Mn1.25Tio.15O4 was used as the positive electrode active substance was used. The result is shown in TABLE 13. [0310] (Example 9-8) A secondary battery was produced and evaluated in the same manner as in Example 8-1 except that LiNio.4Feo.2Mn1.25Tio.15O4 was used as the positive electrode active substance was used. The result is shown in TABLE 13. [0311] (Example 10-1) A secondary battery was produced and evaluated in the same manner as in Example 8-1 except that a non-surface-treated graphite (product name: MAG, made by Hitachi Chemical Co., Ltd.) was used as the negative electrode active substance was used. The result is shown in TABLE 13. Note that the condition of this Comparative Example is the same as those of Comparative Example 1. [0312] (Example 10-2) A secondary battery was produced and evaluated in the same manner as in Example 9-1 except that the non-surface-treated graphite was used as the negative electrode active substance was used. The result is shown in TABLE 13. [0313] (Example 10-3) A secondary battery was produced and evaluated in the same manner as in Example 9-2 except that the non-surface-treated graphite was used as the negative electrode active substance was used. The result is shown in TABLE 13. [0314] (Example 10-4) A secondary battery was produced and evaluated in the same manner as in Example 9-3 except that the non-surface-treated graphite was used as the negative electrode active substance was used. The result is shown in TABLE 13. [0315] (Example 10-5) A secondary battery was produced and evaluated in the same manner as in Example 9-4 except that the non-surface-treated graphite was used as the negative electrode active substance was used. The result is shown in TABLE 13. [0316] (Example 10-6) A secondary battery was produced and evaluated in the same manner as in Example 9-5 except that the non-surface-treated graphite was used as the negative electrode active substance was used. The result is shown in TABLE 13. [0317] (Example 10-7) A secondary battery was produced and evaluated in the same manner as in Example 9-6 except that the non-surface-treated graphite was used as the negative electrode active substance was used. The result is shown in TABLE 13. [0318] (Example 10-8) A secondary battery was produced and evaluated in the same manner as in Example 9-7 except that the non-surface-treated graphite was used as the negative electrode active substance was used. The result is shown in TABLE 13. [0319] (Example 10-9) A secondary battery was produced and evaluated in the same manner as in Example 9-8 except that the non-surface-treated graphite was used as the negative electrode active substance was used. The result is shown in TABLE 13. [0320] [0321] From the results of TABLE 13, in a variety of the positive electrode active substances operating at a potential of 4.5 V or higher with respect to lithium, it was found that the operating life of the battery can be improved more effectively by selecting a combination of an electrolyte liquid containing PTTFE and a negative electrode active substance consisting of a surface-coated graphite. From these results, it has been confirmed that the operating life was improved by using an electrolyte liquid containing a fluorine-containing phosphate when the positive electrode active substance operating at a potential of 4.5 V or higher is used. [0322] In particular, in the case of a 5 V class positive electrode containing Ni such as LiNio.5Mn1.5O4, it is known that the high capacity is obtained. Thus, by using a 5 V class positive electrode active substance containing Ni, it is expected that a battery having high capacity and long operating life is obtained. [0323] Subsequently, the kind of the fluorine-containing phosphate was studied. [0324] (Example 11-1) A secondary battery was produced and evaluated in the same manner as in Example 8-1 except that the solvent obtained by mixing EC/DEC/fluorine-containing phosphate at a ratio of 30/40/30 was used as the nonaqueous electrolyte solvent and except that LiNio.5Mn1.35Tio.15O4 was used as the positive electrode active substance. Tris(2,2,2-trifiuoroethyl) phosphate was used as the fluorine-containing phosphate. The result is shown in TABLE 14. [0325] (Example 11-2) A secondary battery was produced and evaluated in the same manner as in Example 11-1 except that tris(2,2,3,3-tetrafluoropropyl) phosphate was used as the fluorine-containing phosphate instead of tris(2,2,2-trifluoroethyI) phosphate. The result is shown in TABLE 14. [0326] (Example 11-3) A secondary battery was produced and evaluated in the same manner as in Example 11-1 except that tris(2,2,3,3,3-pentafluoropropyl) phosphate was used as the fluorine-containing phosphate instead of tris(2,2,2-trifluoroethyl) phosphate. The result is shown in TABLE 14. [0327] (Comparative Example 11-1) A secondary battery was produced and evaluated in the same manner as in Example 11-1 except that trimethyl phosphate was used instead of the fluorine-containing phosphate. The result is shown in TABLE 14. [0328] (Comparative Example 11-2) A secondary battery was produced and evaluated in the same manner as in Example 11-1 except that triethyl phosphate was used instead of the fluorine-containing phosphate. The result is shown in TABLE 14. [0329] (Comparative Example 11-3) A secondary battery was produced and evaluated in the same manner as in Example 11-1 except that solvent EC/DEC (30/70) was used instead of the nonaqueous electrolyte solvent of Example 11-1. [0330] [0331] As shown in TABLE 14, the capacity retention ratio was improved by using the electrolyte liquid containing a variety of the fluorine-containing phosphates. In particular, the effect by tris(2,2,2-trifluoroethyl) phosphate used in Example 11-1 was high. [0332] Subsequently, the content of the fluorine-containing phosphate in the nonaqueous electrolyte solvent was studied. [0333] (Examples 12-1 to 12-8 and Comparative Example 12-1) Secondary batteries were produced and evaluated in the same manner as in Example 8-1 except that the following nonaqueous electrolyte solvent was used. As the nonaqueous electrolyte solvent, a solvent obtained by mixing the mixed solvent of EC/DMC = 30/70 (solvent EC/DMC) and PTTFE at a mass ratio of (100-x):x was used. The values x and the results are shown in TABLE 15. Note that, the condition of Comparative Example 12-1 is the same as that of Comparative Example 8-2. [0334] [0335] As mentioned above, the capacity retention ratio was high when the content of PTTFE was in a range of 10 vol% or more and 70 vol% or less, and the capacity retention ratio was higher when the content of PTTFE was in a range of 20 vol% or more and 60 vol% or less. [0336] As described above, the constitution of an exemplary embodiment of the invention can provide a lithium secondary battery having high operation voltage and high energy density with suppressing the decrease of reliability in a high temperature. [0337] Subsequently, various graphite materials were studied. [0338] (Examples 13-1 to 13-6 and Comparative Examples 13-1 to 13-3)9 graphite materials were obtained as the negative electrode active substance, and the surface crystal Unity was evaluated by laser Raman scattering. The ratio (ID/IG) of the peak intensity (ID) of D-band (around 1,360 cm"1) with respect to the peak intensity (IQ) of G-band (around 1,600 cm") obtained by laser Raman analysis was measured. The results are shown in TABLE 16. [0339] Also, as for the obtained negative electrode active substance, the internal crystallinity was evaluated by X-ray diffraction. The interlayer spacing doo2 of 002 layer of the graphite was measured. [0340] (Example 13-1) A secondary battery was produced and evaluated in the same manner as in Example 8-1 except that the negative electrode active substance of TABLE 16 was used as the negative electrode active substance and except that EC/DMC/PTTFE = 50/40/10 (volume ratio) was used as the electrolyte liquid solvent. The result is shown in TABLE 16. [0341] [0342] In the Examples in which graphite covered with a low crystalline carbon on the surface was used, the capacity decrease after charge and discharge cycle was effectively suppressed. [0343] The present application claims the priority based on Japanese Patent Application No. 2010-272523, filed on December 7, 2010, all the disclosure of which is incorporated herein by reference. [0344] The present invention was explained with reference to embodiments and Examples, but the present invention is not limited to the above-mentioned embodiments and the Examples. In the constituents and the detail of the present invention, various changings which are understood by a person ordinarily skilled in the art can be made within the scope of the invention. REFERENCE SIGNS LIST [0345] 1 positive electrode active substance layer 2 negative electrode active substance layer 3 positive electrode collector 4 negative electrode collector 5 separator 6 laminate package 7 laminate package 8 negative electrode tab 9 positive electrode tab What is claimed is: 1. An lithium secondary battery, which comprises a positive electrode comprising a positive electrode active substance and an electrolyte liquid comprising a nonaqueous electrolyte solvent; wherein the positive electrode active substance operates at a potential of 4.5 V or higher with respect to lithium; and wherein the nonaqueous electrolyte solvent comprises a fluorine-containing phosphate represented by following formula (1): wherein, in formula (1), Ri, R2 and R3 are each independently a substituted or non-substituted alkyl group, and at least one of Ri, R2 and R3 is a fluorine-containing alkyl group. 2. The lithium secondary battery according to claim 1, wherein a content of the fluorine-containing phosphate is 10 vol% or more and 95 vol% or less in the nonaqueous electrolyte solvent. 3. The lithium secondary battery according to claim 1, wherein a content of the fluorine-containing phosphate is 20 vol% or more and 70 vol% or less in the nonaqueous electrolyte solvent. 4. The lithium secondary battery according to any one of claims 1 to 3, wherein at least one of Ri, R2 and R3 is a fluorine-containing alkyl group in which 50 % or more of hydrogen atoms of a corresponding non-substituted alkyl group are substituted by a fluorine atom. 5. The lithium secondary battery according to any one of claims 1 to 4, wherein the fluorine-containing phosphate is a compound represented by following formula (2): 6. The lithium secondary battery according to any one of claims 1 to 5, wherein the nonaqueous electrolyte solvent comprises a cyclic-type carbonate. 7. The lithium secondary battery according to claim 6, wherein the cyclic-type carbonate is at least one selected from the group consisting of among ethylene carbonate, propylene carbonate, butylene carbonate and vinylene carbonate, and compounds having a structure in which a part or all of hydrogen atoms of these are substituted by a fluorine atom. 8. The lithium secondary battery according to any one of claims 1 to 7, wherein the nonaqueous electrolyte solvent comprises a linear-type carbonate. 9. The lithium secondary battery according to claim 8, wherein the linear-type carbonate is at least one selected from the group consisting of among dimethyl carbonate, diethyl carbonate, ethyl methyl carbonate and dipropyl carbonate, and compounds having a structure in which a part or all of hydrogen atoms of these are substituted by a fluorine atom. 10. The lithium secondary battery according to any one of claims 1 to 9, wherein the nonaqueous electrolyte solvent comprises a carboxylate. 11. The lithium secondary battery according to claim 10, wherein a content of the carboxylate is 0.1 vol% or more and 50 vol% or less in the nonaqueous electrolyte solvent. 12. The lithium secondary battery according to claim 10 or 11, wherein the carboxylate is at least one selected from the group consisting of among ethyl acetate and methyl propionate. 13. The lithium secondary battery according to any one of claims 1 to 12, wherein the nonaqueous electrolyte solvent comprises an alkylene biscarbonate represented by following formula (3V wherein R4 and R$ each independently represent a substituted or non-substituted alkyl group, and R5 represents a substituted or non-substituted alkylene group. 14. The lithium secondary battery according to claim 13, wherein a content of the alkylene biscarbonate is 0.1 vol% or more and 70 vol% or less in the nonaqueous electrolyte solvent. 15. The lithium secondary battery according to any one of claims 1 to 14, wherein the positive electrode active substance comprises a lithium manganese complex oxide represented by following formula (4): wherein, in the formula, it satisfies 0.5 < x < 1.2, 0 < y, x+y < 2, 0 < a < 1.2, and 0 < w < 1, M is at least one selected from the group consisting of among Co, Ni, Fe, Cr and Cu, Y is at least one selected from the group consisting of among Li, B, Na, Al, Mg, Ti, Si, K and Ca, and Z is at least one selected from the group consisting of among F and CI. 16. The lithium secondary battery according to claim 15, wherein the lithium manganese complex oxide comprises at least Ni as the M. 17. The lithium secondary battery according to claim 8, wherein the linear-type carbonate is a fluorinated linear-type carbonate represented by following formula (5): wherein, in formula (5), n is 1, 2 or 3, m is 1, 2 or 3,1 is any one integer from 0 to 2n+l, k is any one integer from 0 to 2m+l, and at least one of 1 and k is an integer of 1 or more. 18. The lithium secondary battery according to claim 17, wherein a content of the fluorinated linear-type carbonate is 0.1 vol% or more and 70 vol% or less in the nonaqueous electrolyte solvent. 19. The lithium secondary battery according to claim 10, wherein the carboxylate is a fluorinated carboxylate represented by following formula (6): wherein n is 1, 2, 3 or 4, m is 1,2, 3 or 4,1 is any one integer from 0 to 2n+l, k is any one integer from 0 to 2m+l, and at least one of 1 and k is an integer of 1 or more. 20. The lithium secondary battery according to any one of claims 1 to 7, wherein the nonaqueous electrolyte solvent comprises a linear-type ether. 21. The lithium secondary battery according to claim 20, wherein the linear-type carbonate is a fluorinated linear-type ether represented by following formula (7): wherein, in formula (7), n is 1, 2, 3,4, 5 or 6, m is 1, 2, 3 or 4,1 is any one integer from 0 to 2n+l, k is any one integer from 0 to 2m+l, and at least one of 1 and k is an integer of 1 or more. 22. The lithium secondary battery according to claim 21, wherein a content of the fluorinated linear-type ether is 0.1 vol% or more and 70 vol% or less in the nonaqueous electrolyte solvent. 23. The lithium secondary battery according to any one of claims 1 to 22, wherein the positive electrode active substance comprises a lithium metal complex oxide represented by following formula (8), (9) or (10): LiMP04 (8), wherein, in formula (8), M is at least one of Co and Ni; Li(M!.zMnz)02 (9), wherein, in formula (9), it satisfies 0.7 > z > 0.33, and M is at least one of Li, Co and Ni; and LiCLixMj.x.zMnOOz (10), wherein, in formula (10), it satisfies 0.3 > x > 0.1 and 0.7 > z > 0.33, and M is at least one of Co and Ni). 24. The lithium secondary battery according to any one of claims 1 to 23, comprising a package which encloses the positive electrode and the electrolyte liquid, wherein the package is constituted of a aluminum laminate. 25. The lithium secondary battery according to any one of claims 1 to 24, comprising a negative electrode comprising a negative electrode active substance, wherein the negative electrode active substance comprises graphite covered with a low crystalline carbon material. 26. The lithium secondary battery according to claim 25, wherein ID/IG of the low crystalline carbon material is 0.08 or more and 0.5 or less. 27. The lithium secondary battery according to claim 25 or 26, wherein interlayer spacing d002 of 002 layer of the graphite is 0.33 nm or more and 0.34 nm or less.